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WO2012071815A1 - Anti-clogging raw water drinking machine for removing heavy metal - Google Patents

Anti-clogging raw water drinking machine for removing heavy metal Download PDF

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Publication number
WO2012071815A1
WO2012071815A1 PCT/CN2011/071376 CN2011071376W WO2012071815A1 WO 2012071815 A1 WO2012071815 A1 WO 2012071815A1 CN 2011071376 W CN2011071376 W CN 2011071376W WO 2012071815 A1 WO2012071815 A1 WO 2012071815A1
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WO
WIPO (PCT)
Prior art keywords
purification unit
membrane
raw water
water dispenser
inner core
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/CN2011/071376
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French (fr)
Chinese (zh)
Inventor
郭大磊
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KUNSHAN HUAKE INSTITUTE OF BIOPOLYMER Co Ltd
Original Assignee
KUNSHAN HUAKE INSTITUTE OF BIOPOLYMER Co Ltd
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Publication of WO2012071815A1 publication Critical patent/WO2012071815A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/18Apparatus therefor
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D61/00Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/14Ultrafiltration; Microfiltration
    • B01D61/20Accessories; Auxiliary operations
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • C02F9/20Portable or detachable small-scale multistage treatment devices, e.g. point of use or laboratory water purification systems
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2311/00Details relating to membrane separation process operations and control
    • B01D2311/26Further operations combined with membrane separation processes
    • B01D2311/2626Absorption or adsorption
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2313/00Details relating to membrane modules or apparatus
    • B01D2313/24Specific pressurizing or depressurizing means
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2321/00Details relating to membrane cleaning, regeneration, sterilization or to the prevention of fouling
    • B01D2321/04Backflushing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/285Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • C02F1/444Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis by ultrafiltration or microfiltration
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/20Heavy metals or heavy metal compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/009Apparatus with independent power supply, e.g. solar cells, windpower or fuel cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20Controlling water pollution; Waste water treatment
    • Y02A20/208Off-grid powered water treatment
    • Y02A20/211Solar-powered water purification
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A20/00Water conservation; Efficient water supply; Efficient water use
    • Y02A20/20Controlling water pollution; Waste water treatment
    • Y02A20/208Off-grid powered water treatment
    • Y02A20/212Solar-powered wastewater sewage treatment, e.g. spray evaporation

Definitions

  • the invention belongs to the field of raw water treatment equipment, and particularly relates to a portable raw water dispenser which is resistant to heavy metal and is resistant to clogging, and is suitable for use in harsh conditions such as disaster areas, fields or battlefields.
  • the invention aims to overcome the deficiencies of the prior art, and provides a manual convenient drinking water dispenser, which has stronger purifying function, higher purifying efficiency, and anti-blocking function, and can satisfy people's health in the absence of electric power.
  • the demand for drinking water is a manual convenient drinking water dispenser, which has stronger purifying function, higher purifying efficiency, and anti-blocking function, and can satisfy people's health in the absence of electric power. The demand for drinking water.
  • the technical solution adopted by the present invention is:
  • a raw water dispenser for removing heavy metal from clogging comprising:
  • a cylinder having a water inlet at the bottom and a water outlet at the top;
  • a piston rod the lower end portion of which is vertically inserted into the cylinder body and slidably disposed along the height direction of the cylinder body, and the upper end portion of the piston rod is connected with a handle;
  • the raw water dispenser further includes:
  • a primary purification unit comprising a filter element disposed at a bottom of the cylinder, the filter element comprising a porous stainless steel inner core and a microfiltration membrane disposed on a periphery of the stainless steel inner core, the inner space of the filter element forming a primary passage through which the water supply passes;
  • a secondary purification unit which is located above the primary purification unit, and includes an inner core made of an adsorbent material extending along a height direction of the cylinder, and a polymer adsorption membrane surrounding the outer periphery of the inner core, and is disposed around An ultrafiltration membrane on the outer periphery of the polymer adsorption membrane, the inner space of the inner core constitutes a secondary passage through which the water is supplied;
  • the primary purification unit and the water inlet are connected by a water inlet passage, the first passage is connected with the secondary passage, and a check valve is arranged between the two, the primary purification unit and the secondary purification unit Separated by a partition, and the partition is provided with at least one through hole having a diameter of between 0.8 mm and 1.2 mm;
  • the lower end of the piston rod is located in the secondary passage, and the piston is sealingly connected to the inner wall of the secondary passage.
  • the microfiltration membrane is pleated, in order to increase the surface area of the microfiltration membrane to achieve a better purification effect; more preferably, the surface area of the microfiltration membrane can be set to 1.1 to 2 times the surface area of the ultrafiltration membrane. .
  • the primary purification unit further comprises a nylon mesh disposed at a periphery of the microfiltration membrane.
  • the one-way valve is disposed on the partition, and the corresponding opening of the one-way valve has a diameter of between 2.0 and 2.6 mm.
  • the primary channel coincides with the axial centerline of the secondary channel.
  • the microfiltration membrane is made of polytetrafluoroethylene, and the membrane pore diameter is between 0.4 and 0.6 micrometers, which can filter out most of the large particulate matter and suspended matter in the water body.
  • the inner core of the secondary purification unit is composed of a sintered activated carbon rod or an activated carbon-activated zeolite mixed sintered rod, and has a good adsorption effect on ammonia nitrogen substances, pigments and odor substances in the water body.
  • the polymer adsorption membrane is a ⁇ -polyglutamic acid adsorption membrane having a pore diameter of between 0.3 and 1 ⁇ m, and more preferably a ⁇ -polyglutamic acid composite membrane disclosed in the patent of the publication No. CN100560192C.
  • This adsorption membrane has a strong complexing ability to heavy metal ions and radioactive elements in water, so that they can be filtered out.
  • the ultrafiltration membrane is made of polyvinylidene fluoride, and the pore diameter of the membrane is between 30 and 60 nanometers, which not only removes insoluble heavy metal components such as iron, aluminum, manganese and lead in water, but also filters out water.
  • Bacteria and viruses such as Cryptosporidium and Piriflagellate.
  • the filter materials used in the above primary purification unit or secondary purification unit can be prepared commercially or by known methods.
  • the raw water dispenser of the invention can also be equipped with a water inlet pipe, and the water inlet pipe can be placed in the water inlet of the raw water dispenser to connect the two.
  • the raw water dispenser of the present invention further includes a cup cover that is disposed on the barrel.
  • the raw water dispenser of the invention has many advantages compared with the existing water dispenser:
  • the raw water dispenser of the invention When the raw water dispenser of the invention is used, the raw water is purified by the two-stage purification unit, and the raw water is sequentially filtered through the microfiltration membrane, the adsorption material, the polymer adsorption membrane, and the ultrafiltration membrane to filter the water body.
  • Suspended impurities and heterochromatic odor substances, etc. can also remove a variety of heavy metals and radioactive metal elements in water, as well as a variety of bacteria and viruses, to obtain pure drinking water that meets drinking water standards; a small through hole is formed in the partition between the secondary purification unit, so that a small portion of the water can be returned from the small through hole to the primary purification unit during the passage of the secondary purification unit, and The suspended impurities trapped by the primary purification unit are backwashed, so that the microfiltration membrane is not easily clogged, thereby enabling the raw water dispenser to have an anti-clogging function, thereby improving the purification efficiency of the raw water dispenser.
  • the piston pumping arrangement enables the raw water dispenser to be used without power supply, which can satisfy people's health without drinking electricity, especially in the harsh environment of wild survival, natural disasters and battlefield operations. Water demand.
  • FIG. 1 is a schematic view showing the structure of a façade using the raw water dispenser of the present invention
  • Figure 2 is a front elevational view showing the partition plate and the check valve used in the raw water dispenser of the present invention
  • Figure 3 is a top plan view of the partition plate and the check valve used in the raw water dispenser of the present invention.
  • FIG. 4 is a schematic top plan view of a filter element in a primary purification unit of a raw water dispenser of the present invention
  • the raw water dispenser according to this embodiment includes:
  • a cylinder 1 having a water inlet 2 at the bottom and a water outlet 3 at the top;
  • the piston rod 4 the lower end portion of the piston rod 4 is vertically inserted in the cylinder body 1 and is slidably disposed along the height direction of the cylinder body 1, the upper end portion of the piston rod 4 is connected with a handle 40;
  • the raw water dispenser further includes:
  • the primary purification unit comprises a filter element 6 disposed at the bottom of the barrel 1, the filter element 6 comprising a porous stainless steel inner core 60 and a microfiltration membrane 61 disposed at the periphery of the stainless steel inner core 60, the internal space of the filter element 6 constituting a water supply Passing through the primary channel 5;
  • a secondary purification unit which is located above the primary purification unit, and includes an inner core 9 made of an adsorbent material extending in a height direction of the cylinder 1, and a polymer adsorption film 10 surrounding the outer periphery of the inner core 9.
  • the ultrafiltration membrane 11 surrounding the outer periphery of the polymer adsorption membrane 10, the internal space of the inner core 9 constitutes a secondary passage 8 through which water is supplied;
  • the primary channel 5 is in communication with the secondary channel 8, and the primary channel 5 coincides with the axis of the secondary channel 8, with a check valve 12 disposed therebetween; the primary purification unit and the secondary
  • the cleaning units are separated by a partition plate 13, and the partition plate 13 is provided with two through holes having a hole diameter of 0.8 mm to 1.2 mm.
  • the check valve 12 is disposed at the center of the partition plate 13,
  • the diameter of the opening corresponding to the one-way valve 12 is 2.5 mm;
  • the first-stage purification unit and the water inlet 2 are connected through the water inlet passage 7, and the water inlet passage 7 is provided with a plastic support member 70, and the support member 70 is located at a
  • the lower part of the purification unit is about 2 cm high, mainly functions to support the upper material, and the inside of the support member 70 is arranged in a grid type, and water can pass through the gap of the grid of the support member 70;
  • the lower end of the piston rod 4 is located in the secondary passage 8, and the piston 41 is sealingly connected to the inner wall of the secondary passage 8.
  • the top view of the filter element 6 is shown in FIG. 4.
  • the porous stainless steel inner core 60 mainly functions to support and fix the microfiltration membrane 61.
  • the microfiltration membrane 61 is arranged to fold into the stainless steel inner core 60, specifically referring to the authorization bulletin number.
  • the material of the microfiltration membrane 61 is polytetrafluoroethylene, and the membrane pore diameter is between 0.4 and 0.6 micrometers;
  • the inner core 9 of the secondary purification unit is composed of a commercially available sintered activated carbon rod;
  • the polymer adsorption membrane 10 is a self-made ⁇ -polyglutamic acid composite adsorption membrane (the production method is referred to Chinese patent CN100560192C), and the membrane pore size is about 0.3 ⁇ m;
  • the ultrafiltration membrane 11 is made of polyvinylidene fluoride and has a membrane pore size of about 35 nm.
  • the raw water dispenser of this embodiment further includes a cup cover that is disposed on the barrel 1 and a rubber tube 14 that can communicate with the water inlet 2.
  • the water used in the operation of the raw water dispenser is tap water with heavy metal ions, and the content of suspended solids, bacteria and heavy metal ions in the tap water to be filtered is detected before filtering.
  • the cup lid of the raw water dispenser is removed, and the rubber tube 14 is installed to communicate with the water inlet 2, the other end of the rubber tube 14 is immersed in the tap water, and the piston rod 4 is slowly lifted up until it is lifted up.
  • the one-way valve 12 is automatically opened, and the water body is purified by the water inlet passage 2 through the water inlet passage 7 into the primary purification unit, and then flows into the primary passage 5, and then flows into the secondary passage through the one-way valve 12.
  • the inner core 9, the polymer adsorption film 10 and the ultrafiltration membrane 11 obtain pure water, and another portion of the water in the secondary passage 8 is returned to the primary passage 5 through the minute through holes 130 opened in the partition plate 13, and further passes through
  • the stainless steel inner core 60 flows to the microfiltration membrane 61 and the nylon mesh 62, so that the suspended matter and impurities trapped outside the microfiltration membrane 61 and the nylon mesh 62 can be flushed away from the outer surfaces of the microfiltration membrane 61 and the nylon mesh 62 to achieve a pair. Backwashing of the primary purification unit.
  • the raw water dispenser of the embodiment about 80% of the purified water can be obtained at one time, and the other 20% of the water can realize the backwashing of the first-stage purification unit, so that it is not easy to block, thereby improving the purification efficiency of the raw water dispenser. And service life.
  • the filtered water was tested for the content of suspended solids, bacteria and heavy metal ions, and compared with the tap water before filtration, it was found that the raw water dispenser of this example can filter 99.9% of suspended solids, bacteria and heavy metal ions in tap water.
  • the purified water obtained by the raw water dispenser of the present embodiment can reach the standard of healthy drinking water.

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  • Engineering & Computer Science (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Clinical Laboratory Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

Provided is an anti-clogging raw water drinking machine for removing heavy metal, which comprises a cylinder body (1), a piston rod (4), a piston (41), a first stage purification unit and a second stage purification unit. The first stage purification unit comprises a filter core (6) provided at the bottom of the cylinder body (1). The inner space of the filter core (6) forms a first channel (5) for the water passing therethrough. The second stage purification unit located above the first stage purification unit comprises an inner core (9) made from an adsorbent material, a macromolecule adsorption membrane (10) surrounding the periphery of the inner core (9), and an ultrafiltration membrane (11) surrounding the periphery of the macromolecule adsorption membrane (10). The inner space of the inner core (9) forms a second channel (8) for the water passing therethrough, which is communicated with the first channel (5). The lower end part of the piston rod (4) is located in the second channel (8). The two stage purification units are used for removing pollutants in the water, for example, heavy metal etc., so as to obtain the potable water which meets the potable water standard. Moreover, the raw water drinking machine has backwashing function. The piston type water pumping device provided can use the machine in the absence of power supply.

Description

除重金属抗堵塞的生饮水机  Raw water dispenser with heavy metal anti-blocking

技术领域Technical field

本发明属于生饮水处理设备领域,具体涉及一种除重金属抗堵塞的便捷式生饮水机,适合在灾区、野外或战地等恶劣条件下使用。The invention belongs to the field of raw water treatment equipment, and particularly relates to a portable raw water dispenser which is resistant to heavy metal and is resistant to clogging, and is suitable for use in harsh conditions such as disaster areas, fields or battlefields.

背景技术Background technique

现如今,来自电镀、采矿、冶金、化工、印染等工业的重金属污染已经成为水环境污染中主要的污染物之一,诸如铅、铬、汞等重金属对人体的危害很大。目前市场上的生饮水机多用于家用,这些生饮水机一般能除去生水中的大部分杂质,能够满足人们普通生活对饮用水的需求,但对于野外生存、自然灾害或战地供应等恶劣环境条件,尤其当无电力供给时,普通生饮水机难以满足要求。另外,现有的生饮水机在使用一段时间后,滤芯容易堵塞,这不但会影响生饮水机的使用效率,也会缩短生饮水机的使用寿命。因此,特别需要一种净化功能强、净化效率高且无需电力就能达到饮用水要求的生饮水处理设备。Nowadays, heavy metal pollution from electroplating, mining, metallurgy, chemical, printing and dyeing industries has become one of the main pollutants in water pollution. Heavy metals such as lead, chromium and mercury are harmful to the human body. At present, the raw water dispensers on the market are mostly used in households. These raw water dispensers can generally remove most of the impurities in the raw water, and can meet the needs of ordinary people for drinking water, but for harsh environmental conditions such as wild survival, natural disasters or battlefield supply. Especially when there is no power supply, the ordinary raw water dispenser is difficult to meet the requirements. In addition, after the existing raw water dispenser is used for a period of time, the filter element is easily blocked, which not only affects the use efficiency of the raw water dispenser, but also shortens the service life of the raw water dispenser. Therefore, there is a particular need for a raw water treatment device that has a strong purification function, high purification efficiency, and can meet drinking water requirements without requiring electricity.

发明内容Summary of the invention

本发明旨在克服现有技术的不足,提供一种手动的便捷式生饮水机,其净化功能更强,净化效率更高,且具有抗堵塞的功能,可满足人们在无电力情况下对健康饮用水的需求。The invention aims to overcome the deficiencies of the prior art, and provides a manual convenient drinking water dispenser, which has stronger purifying function, higher purifying efficiency, and anti-blocking function, and can satisfy people's health in the absence of electric power. The demand for drinking water.

为解决以上技术问题,本发明采取的技术方案是:In order to solve the above technical problems, the technical solution adopted by the present invention is:

一种除重金属抗堵塞的生饮水机,其包括:A raw water dispenser for removing heavy metal from clogging, comprising:

筒体,其在底部具有进水口,在顶部具有出水口;a cylinder having a water inlet at the bottom and a water outlet at the top;

活塞杆,其下端部垂直插设在筒体内且沿着筒体的高度方向能够滑动地设置,该活塞杆的上端部连接有手柄;a piston rod, the lower end portion of which is vertically inserted into the cylinder body and slidably disposed along the height direction of the cylinder body, and the upper end portion of the piston rod is connected with a handle;

活塞,其固定连接在活塞杆的下端部;a piston fixedly coupled to a lower end of the piston rod;

所述生饮水机还包括:The raw water dispenser further includes:

一级净化单元,包括设置在筒体底部的滤芯,所述滤芯包括多孔不锈钢内芯和设置在不锈钢内芯的外围的微滤膜,所述滤芯的内部空间构成供水通过的一级通道;a primary purification unit comprising a filter element disposed at a bottom of the cylinder, the filter element comprising a porous stainless steel inner core and a microfiltration membrane disposed on a periphery of the stainless steel inner core, the inner space of the filter element forming a primary passage through which the water supply passes;

二级净化单元,其位于所述一级净化单元的上方,包括沿着筒体的高度方向延伸的由吸附材料制成的内芯、围设在内芯外周的高分子吸附膜、围设在高分子吸附膜外周的超滤膜,内芯的内部空间构成供水通过的二级通道;a secondary purification unit, which is located above the primary purification unit, and includes an inner core made of an adsorbent material extending along a height direction of the cylinder, and a polymer adsorption membrane surrounding the outer periphery of the inner core, and is disposed around An ultrafiltration membrane on the outer periphery of the polymer adsorption membrane, the inner space of the inner core constitutes a secondary passage through which the water is supplied;

一级净化单元与进水口之间通过进水通道相连通,所述一级通道与二级通道相连通,且在二者之间设置有单向阀,一级净化单元与二级净化单元之间通过隔板隔开,且隔板上设有至少一个孔径在0.8毫米~1.2毫米之间的通孔;The primary purification unit and the water inlet are connected by a water inlet passage, the first passage is connected with the secondary passage, and a check valve is arranged between the two, the primary purification unit and the secondary purification unit Separated by a partition, and the partition is provided with at least one through hole having a diameter of between 0.8 mm and 1.2 mm;

活塞杆的下端部位于二级通道内,且活塞与二级通道的内壁相密封连接。The lower end of the piston rod is located in the secondary passage, and the piston is sealingly connected to the inner wall of the secondary passage.

优选地,微滤膜为褶皱状,这是为了增加微滤膜的表面积,以达到更好的净化效果;更优选地,微滤膜的表面积可设置为超滤膜的表面积的1.1~2倍。Preferably, the microfiltration membrane is pleated, in order to increase the surface area of the microfiltration membrane to achieve a better purification effect; more preferably, the surface area of the microfiltration membrane can be set to 1.1 to 2 times the surface area of the ultrafiltration membrane. .

优选地,一级净化单元还包括设置在微滤膜外围的尼龙网。Preferably, the primary purification unit further comprises a nylon mesh disposed at a periphery of the microfiltration membrane.

优选地,单向阀设置在隔板上,且单向阀对应的开口的直径在2.0~2.6毫米之间。Preferably, the one-way valve is disposed on the partition, and the corresponding opening of the one-way valve has a diameter of between 2.0 and 2.6 mm.

优选地,一级通道与二级通道的轴心线相重合。Preferably, the primary channel coincides with the axial centerline of the secondary channel.

优选地,微滤膜的材质为聚四氟乙烯,膜孔径在0.4~0.6微米之间,能够滤去水体中的大部分大颗粒物质及悬浮物等。Preferably, the microfiltration membrane is made of polytetrafluoroethylene, and the membrane pore diameter is between 0.4 and 0.6 micrometers, which can filter out most of the large particulate matter and suspended matter in the water body.

优选地,二级净化单元中的内芯由烧结活性炭棒或活性炭-活化沸石混合烧结棒构成,对水体中的氨氮物质、色素和异味物质等有很好的吸附作用。Preferably, the inner core of the secondary purification unit is composed of a sintered activated carbon rod or an activated carbon-activated zeolite mixed sintered rod, and has a good adsorption effect on ammonia nitrogen substances, pigments and odor substances in the water body.

优选地,高分子吸附膜为γ-聚谷氨酸吸附膜,膜孔径在0.3~1微米之间,且更优选为授权公告号CN100560192C的专利中所公布的γ-聚谷氨酸复合膜,这种吸附膜对水体中的重金属离子和放射性元素有极强的络合能力,因而能将它们滤除。Preferably, the polymer adsorption membrane is a γ-polyglutamic acid adsorption membrane having a pore diameter of between 0.3 and 1 μm, and more preferably a γ-polyglutamic acid composite membrane disclosed in the patent of the publication No. CN100560192C. This adsorption membrane has a strong complexing ability to heavy metal ions and radioactive elements in water, so that they can be filtered out.

优选地,超滤膜的材质为聚偏氟乙烯,膜孔径在30~60纳米之间,它不仅可除去水中的铁、铝、锰、铅等不溶性的重金属成分,而且还能滤掉水体中诸如隐孢子虫及梨形鞭毛虫等细菌和病毒。Preferably, the ultrafiltration membrane is made of polyvinylidene fluoride, and the pore diameter of the membrane is between 30 and 60 nanometers, which not only removes insoluble heavy metal components such as iron, aluminum, manganese and lead in water, but also filters out water. Bacteria and viruses such as Cryptosporidium and Piriflagellate.

以上一级净化单元或二级净化单元中所用过滤材料均可通过市购或通过已知方法制备得到。The filter materials used in the above primary purification unit or secondary purification unit can be prepared commercially or by known methods.

为使设备取水方便,还可为本发明生饮水机配备一进水管,使用时将该进水管套在生饮水机的进水口使二者相连通即可。In order to make the equipment easy to take water, the raw water dispenser of the invention can also be equipped with a water inlet pipe, and the water inlet pipe can be placed in the water inlet of the raw water dispenser to connect the two.

为方便使用者喝水,本发明生饮水机还包括一个罩设在所述筒体上的杯盖。In order to facilitate the user to drink water, the raw water dispenser of the present invention further includes a cup cover that is disposed on the barrel.

通过以上技术方案的实施,使本发明生饮水机与现有饮水机相比具有诸多优点:Through the implementation of the above technical solutions, the raw water dispenser of the invention has many advantages compared with the existing water dispenser:

本发明生饮水机在使用时,使生水经过两级净化单元的净化,生水依次通过微滤膜、吸附材料、高分子吸附膜、超滤膜四道滤层的过滤,不仅可除去水体中的悬浮杂质和异色异味物质等,还可除去水体中的多种重金属和放射性金属元素,以及多种细菌和病毒,得到符合饮用水标准的纯净的饮用水;另外,在一级净化单元与二级净化单元之间的隔板上开设孔径较小的通孔,使得生水在经过二级净化单元的过程中有一小部分水能够从该微小通孔回流至一级净化单元,并对一级净化单元所截留的悬浮杂质等进行反冲洗,使微滤膜不易堵塞,进而使生饮水机具有抗堵塞的功能,可提高生饮水机的净化效率。而活塞式抽水设置又使得该生饮水机在不须电源的情况下也能够使用,可满足人们在无电力供应下,特别是在野外生存、自然灾害、战地作战的恶劣环境条件下对健康饮用水的需求。When the raw water dispenser of the invention is used, the raw water is purified by the two-stage purification unit, and the raw water is sequentially filtered through the microfiltration membrane, the adsorption material, the polymer adsorption membrane, and the ultrafiltration membrane to filter the water body. Suspended impurities and heterochromatic odor substances, etc., can also remove a variety of heavy metals and radioactive metal elements in water, as well as a variety of bacteria and viruses, to obtain pure drinking water that meets drinking water standards; a small through hole is formed in the partition between the secondary purification unit, so that a small portion of the water can be returned from the small through hole to the primary purification unit during the passage of the secondary purification unit, and The suspended impurities trapped by the primary purification unit are backwashed, so that the microfiltration membrane is not easily clogged, thereby enabling the raw water dispenser to have an anti-clogging function, thereby improving the purification efficiency of the raw water dispenser. The piston pumping arrangement enables the raw water dispenser to be used without power supply, which can satisfy people's health without drinking electricity, especially in the harsh environment of wild survival, natural disasters and battlefield operations. Water demand.

附图说明DRAWINGS

下面结合附图和具体的实施方式对本发明做进一步详细的说明:The present invention will be further described in detail below with reference to the accompanying drawings and specific embodiments.

图1为采用本发明生饮水机的立面结构示意图;1 is a schematic view showing the structure of a façade using the raw water dispenser of the present invention;

图2为本发明生饮水机所用隔板和单向阀的主视示意图;Figure 2 is a front elevational view showing the partition plate and the check valve used in the raw water dispenser of the present invention;

图3为本发明生饮水机所用隔板和单向阀的俯视示意图;Figure 3 is a top plan view of the partition plate and the check valve used in the raw water dispenser of the present invention;

图4为本发明生饮水机一级净化单元中的滤芯的俯视结构示意图;4 is a schematic top plan view of a filter element in a primary purification unit of a raw water dispenser of the present invention;

其中:1、筒体;2、进水口;3、出水口;4、活塞杆;40、手柄;41、活塞;5、一级通道;6、滤芯;60、不锈钢内芯;61、微滤膜;62、尼龙网;7、进水通道;8、二级通道;9、内芯;10、高分子吸附膜;11、超滤膜;12、单向阀;13、隔板;130、通孔;14、橡胶管。Among them: 1, cylinder; 2, water inlet; 3, water outlet; 4, piston rod; 40, handle; 41, piston; 5, primary passage; 6, filter; 60, stainless steel core; Membrane; 62, nylon mesh; 7, water inlet channel; 8, secondary channel; 9, inner core; 10, polymer adsorption membrane; 11, ultrafiltration membrane; 12, check valve; 13, partition; Through hole; 14, rubber tube.

具体实施方式detailed description

下面结合具体的实施例对本发明做进一步详细的说明,但不限于这些实施例。The present invention will be further described in detail below with reference to specific embodiments, but is not limited to the embodiments.

实施例1Example 1

如图1所示,按照本实施例的生饮水机包括:As shown in FIG. 1, the raw water dispenser according to this embodiment includes:

筒体1,其在底部具有进水口2,在顶部具有出水口3;a cylinder 1 having a water inlet 2 at the bottom and a water outlet 3 at the top;

活塞杆4,其下端部垂直插设在筒体1内且沿着筒体1的高度方向能够滑动地设置,该活塞杆4的上端部连接有手柄40;The piston rod 4, the lower end portion of the piston rod 4 is vertically inserted in the cylinder body 1 and is slidably disposed along the height direction of the cylinder body 1, the upper end portion of the piston rod 4 is connected with a handle 40;

活塞41,其固定连接在活塞杆4的下端部;a piston 41 fixedly coupled to a lower end portion of the piston rod 4;

所述生饮水机还包括:The raw water dispenser further includes:

一级净化单元,包括设置在筒体1底部的滤芯6,所述滤芯6包括多孔不锈钢内芯60和设置在不锈钢内芯60的外围的微滤膜61,所述滤芯6的内部空间构成供水通过的一级通道5;The primary purification unit comprises a filter element 6 disposed at the bottom of the barrel 1, the filter element 6 comprising a porous stainless steel inner core 60 and a microfiltration membrane 61 disposed at the periphery of the stainless steel inner core 60, the internal space of the filter element 6 constituting a water supply Passing through the primary channel 5;

二级净化单元,其位于所述一级净化单元的上方,包括沿着筒体1的高度方向延伸的由吸附材料制成的内芯9、围设在内芯9外周的高分子吸附膜10、围设在高分子吸附膜10外周的超滤膜11,内芯9的内部空间构成供水通过的二级通道8;a secondary purification unit, which is located above the primary purification unit, and includes an inner core 9 made of an adsorbent material extending in a height direction of the cylinder 1, and a polymer adsorption film 10 surrounding the outer periphery of the inner core 9. , the ultrafiltration membrane 11 surrounding the outer periphery of the polymer adsorption membrane 10, the internal space of the inner core 9 constitutes a secondary passage 8 through which water is supplied;

所述一级通道5与二级通道8相连通,且一级通道5与二级通道8的轴心线相重合,在二者之间设置有单向阀12;一级净化单元与二级净化单元之间通过隔板13隔开,且隔板13上设有2个孔径在0.8毫米~1.2毫米之间的通孔;本实施例中,单向阀12设置在隔板13的中央,且单向阀12对应的开口的直径为2.5毫米;一级净化单元与进水口2之间通过进水通道7相连通,进水通道7内设置有塑料支撑件70,该支撑件70位于一级净化单元的下方,高约2厘米,主要起支撑上部材料的作用,支撑件70内部为格栅式设置,水可从支撑件70的格栅空隙中通过;The primary channel 5 is in communication with the secondary channel 8, and the primary channel 5 coincides with the axis of the secondary channel 8, with a check valve 12 disposed therebetween; the primary purification unit and the secondary The cleaning units are separated by a partition plate 13, and the partition plate 13 is provided with two through holes having a hole diameter of 0.8 mm to 1.2 mm. In this embodiment, the check valve 12 is disposed at the center of the partition plate 13, The diameter of the opening corresponding to the one-way valve 12 is 2.5 mm; the first-stage purification unit and the water inlet 2 are connected through the water inlet passage 7, and the water inlet passage 7 is provided with a plastic support member 70, and the support member 70 is located at a The lower part of the purification unit is about 2 cm high, mainly functions to support the upper material, and the inside of the support member 70 is arranged in a grid type, and water can pass through the gap of the grid of the support member 70;

活塞杆4的下端部位于二级通道8内,且活塞41与二级通道8的内壁相密封连接。The lower end of the piston rod 4 is located in the secondary passage 8, and the piston 41 is sealingly connected to the inner wall of the secondary passage 8.

滤芯6的俯视结构示意图示于图4,多孔不锈钢内芯60主要起支撑和固定微滤膜61的作用,微滤膜61设置为向不锈钢内芯60折叠的褶皱状,具体是借鉴授权公告号CN101219299B的专利中一种滤芯的制作方法,以增加微滤膜61的表面积,达到更好的净化效果;本实施例中,微滤膜61的表面积设置为超滤膜11的表面积的1.5倍;另外,微滤膜61的外围还设置有尼龙网62。The top view of the filter element 6 is shown in FIG. 4. The porous stainless steel inner core 60 mainly functions to support and fix the microfiltration membrane 61. The microfiltration membrane 61 is arranged to fold into the stainless steel inner core 60, specifically referring to the authorization bulletin number. A method for fabricating a filter element in the patent CN101219299B to increase the surface area of the microfiltration membrane 61 to achieve a better purification effect; in this embodiment, the surface area of the microfiltration membrane 61 is set to 1.5 times the surface area of the ultrafiltration membrane 11; Further, a nylon mesh 62 is provided on the periphery of the microfiltration membrane 61.

本实施例中,微滤膜61的材质为聚四氟乙烯,膜孔径在0.4~0.6微米之间; In this embodiment, the material of the microfiltration membrane 61 is polytetrafluoroethylene, and the membrane pore diameter is between 0.4 and 0.6 micrometers;

二级净化单元中的内芯9由市购烧结活性炭棒构成;高分子吸附膜10为自制的γ-聚谷氨酸复合吸附膜(制作方法参照中国专利CN100560192C),膜孔径约为0.3微米;超滤膜11的材质为聚偏氟乙烯,膜孔径约为35纳米。The inner core 9 of the secondary purification unit is composed of a commercially available sintered activated carbon rod; the polymer adsorption membrane 10 is a self-made γ-polyglutamic acid composite adsorption membrane (the production method is referred to Chinese patent CN100560192C), and the membrane pore size is about 0.3 μm; The ultrafiltration membrane 11 is made of polyvinylidene fluoride and has a membrane pore size of about 35 nm.

本实施例的生饮水机还包括一个罩设在筒体1上的杯盖和一根可与进水口2相连通的橡胶管14。The raw water dispenser of this embodiment further includes a cup cover that is disposed on the barrel 1 and a rubber tube 14 that can communicate with the water inlet 2.

按照本实施例,该生饮水机工作时所用的水为加有重金属离子的自来水,过滤前先对须过滤的自来水中的悬浮物、细菌和重金属离子含量等进行检测。According to the embodiment, the water used in the operation of the raw water dispenser is tap water with heavy metal ions, and the content of suspended solids, bacteria and heavy metal ions in the tap water to be filtered is detected before filtering.

按照本实施例的生饮水机的工作原理如下:The working principle of the raw water dispenser according to this embodiment is as follows:

首先将生饮水机上罩设的杯盖取下,并将橡胶管14安装好使之与进水口2相连通,将橡胶管14的另一头浸入自来水中,缓慢向上提活塞杆4,直至提至筒体1的顶部,此时单向阀12自动打开,水体通过进水口2经进水通道7进入一级净化单元进行净化,然后流入一级通道5,再经单向阀12处流入二级通道8;再将位于筒体1顶部的活塞杆4缓慢向下压,单向阀12自动关闭,二级通道8中的一部分水经二级净化单元的进一步净化,水体依次经过吸附材料构成的内芯9、高分子吸附膜10和超滤膜11得到纯净的水,而二级通道8中的另一部分水通过隔板13上开设的微小通孔130回流至一级通道5,并进一步通过不锈钢内芯60流向微滤膜61和尼龙网62,因而可将微滤膜61和尼龙网62外所截留的悬浮物和杂质等冲离微滤膜61和尼龙网62的外表面,实现对一级净化单元的反冲洗。First, the cup lid of the raw water dispenser is removed, and the rubber tube 14 is installed to communicate with the water inlet 2, the other end of the rubber tube 14 is immersed in the tap water, and the piston rod 4 is slowly lifted up until it is lifted up. At the top of the cylinder 1, at this time, the one-way valve 12 is automatically opened, and the water body is purified by the water inlet passage 2 through the water inlet passage 7 into the primary purification unit, and then flows into the primary passage 5, and then flows into the secondary passage through the one-way valve 12. Channel 8; the piston rod 4 at the top of the cylinder 1 is slowly pressed downward, the one-way valve 12 is automatically closed, and a part of the water in the secondary passage 8 is further purified by the secondary purification unit, and the water body is sequentially composed of the adsorbent material. The inner core 9, the polymer adsorption film 10 and the ultrafiltration membrane 11 obtain pure water, and another portion of the water in the secondary passage 8 is returned to the primary passage 5 through the minute through holes 130 opened in the partition plate 13, and further passes through The stainless steel inner core 60 flows to the microfiltration membrane 61 and the nylon mesh 62, so that the suspended matter and impurities trapped outside the microfiltration membrane 61 and the nylon mesh 62 can be flushed away from the outer surfaces of the microfiltration membrane 61 and the nylon mesh 62 to achieve a pair. Backwashing of the primary purification unit.

按照本实施例的生饮水机,一次可获得约80%的纯净水,而另20%的水可实现对一级净化单元的反冲洗,使之不易堵塞,因而可提高生饮水机的净化效率和使用寿命。According to the raw water dispenser of the embodiment, about 80% of the purified water can be obtained at one time, and the other 20% of the water can realize the backwashing of the first-stage purification unit, so that it is not easy to block, thereby improving the purification efficiency of the raw water dispenser. And service life.

对滤出的水进行悬浮物、细菌和重金属离子等含量的检测,将其与过滤前的自来水进行对比,得出本实施例生饮水机可以过滤自来水中99.9%的悬浮物、细菌和重金属离子,经本实施例生饮水机过滤得到的纯净水能够达到健康饮用水的标准。The filtered water was tested for the content of suspended solids, bacteria and heavy metal ions, and compared with the tap water before filtration, it was found that the raw water dispenser of this example can filter 99.9% of suspended solids, bacteria and heavy metal ions in tap water. The purified water obtained by the raw water dispenser of the present embodiment can reach the standard of healthy drinking water.

以上对本发明做了详尽的描述,其目的在于让熟悉此领域技术的人士能够了解本发明的内容并加以实施,并不能以此限制本发明的保护范围,凡根据本发明的精神实质所作的等效变化或修饰,都应涵盖在本发明的保护范围内。The present invention has been described in detail above, and is intended to be understood by a person skilled in the art of the invention, and is not intended to limit the scope of the invention. Modifications or modifications are intended to be included within the scope of the invention.

Claims (9)

1、一种除重金属抗堵塞的生饮水机,其包括:1. A raw water dispenser for removing heavy metal from clogging, comprising: 筒体(1),该筒体在底部具有进水口(2),在顶部具有出水口(3);a cylinder (1) having a water inlet (2) at the bottom and a water outlet (3) at the top; 活塞杆(4),所述活塞杆(4)的下端部垂直插设在筒体(1)内且沿着筒体(1)的高度方向可滑动地设置,该活塞杆(4)的上端部连接有手柄(40);a piston rod (4), a lower end portion of the piston rod (4) is vertically inserted into the cylinder (1) and slidably disposed along a height direction of the cylinder (1), and an upper end of the piston rod (4) The handle is connected to the handle (40); 活塞(41),其固定连接在活塞杆(4)的下端部;a piston (41) fixedly coupled to a lower end portion of the piston rod (4); 其特征在于该生饮水机还包括:The utility model is characterized in that the raw water dispenser further comprises: 一级净化单元,它包括设置在筒体(1)的底部的滤芯(6),所述滤芯(6)包括多孔不锈钢内芯(60)和围绕不锈钢内芯(60)设置的微滤膜(61),所述滤芯(6)的内部空间构成供水通过的一级通道(5);a primary purification unit comprising a filter element (6) disposed at the bottom of the barrel (1), the filter element (6) comprising a porous stainless steel inner core (60) and a microfiltration membrane disposed around the stainless steel inner core (60) ( 61), the inner space of the filter element (6) constitutes a primary passage (5) through which water is supplied; 二级净化单元,其位于一级净化单元的上方,包括沿着筒体(1)的高度方向延伸的由吸附材料制成的内芯(9)、围设在内芯(9)外周的高分子吸附膜(10)、围设在高分子吸附膜(10)外周的超滤膜(11),所述内芯(9)的内部空间构成供水通过的二级通道(8);a secondary purification unit, located above the primary purification unit, comprising an inner core (9) made of an adsorbent material extending in a height direction of the cylinder (1), and surrounding the outer circumference of the inner core (9) a molecular adsorption film (10), an ultrafiltration membrane (11) surrounding the outer periphery of the polymer adsorption membrane (10), the inner space of the inner core (9) constitutes a secondary passage (8) through which water is supplied; 所述一级净化单元与进水口(2)之间通过进水通道(7)相连通,所述一级通道(5)与二级通道(8)相连通,且在二者之间设置有单向阀(12),所述一级净化单元与二级净化单元之间通过隔板(13)隔开,且隔板(13)上设有至少一个孔径为0.8毫米~1.2毫米的通孔(130);The primary purification unit is connected to the water inlet (2) through a water inlet passage (7), and the primary passage (5) is connected to the secondary passage (8), and is disposed between the two. a check valve (12), the primary purification unit and the secondary purification unit are separated by a partition (13), and the partition (13) is provided with at least one through hole having a diameter of 0.8 mm to 1.2 mm. (130); 所述活塞杆(4)的下端部位于二级通道(8)内,且所述活塞(41)与二级通道(8)的内壁相密封连接。The lower end of the piston rod (4) is located in the secondary passage (8), and the piston (41) is sealingly connected to the inner wall of the secondary passage (8). 2、根据权利要求1所述的生饮水机,其特征在于:所述的微滤膜(61)为褶皱状,所述微滤膜(61)的表面积为所述超滤膜(11)的表面积的1.1~2倍。The raw water dispenser according to claim 1, wherein the microfiltration membrane (61) is pleated, and the surface area of the microfiltration membrane (61) is the ultrafiltration membrane (11). 1.1 to 2 times the surface area. 3、根据权利要求1或2所述的生饮水机,其特征在于:所述一级净化单元还包括围绕所述微滤膜(61)设置的尼龙网(62)。3. A water dispenser according to claim 1 or 2, wherein the primary purification unit further comprises a nylon mesh (62) disposed around the microfiltration membrane (61). 4、根据权利要求1所述的生饮水机,其特征在于:所述单向阀(12)设置在所述隔板(13)上,所述单向阀(12)对应的开口直径为2.0~2.6毫米。The water dispenser according to claim 1, wherein the one-way valve (12) is disposed on the partition plate (13), and the one-way valve (12) has an opening diameter of 2.0. ~2.6 mm. 5、根据权利要求1所述的生饮水机,其特征在于:所述一级通道(5)与所述二级通道(8)的轴心线相重合。5. A water dispenser according to claim 1, characterized in that the primary channel (5) coincides with the axis of the secondary channel (8). 6、根据权利要求1所述的生饮水机,其特征在于:所述微滤膜(61)的材质为聚四氟乙烯,膜孔径为0.4~0.6微米。The raw water dispenser according to claim 1, wherein the microfiltration membrane (61) is made of polytetrafluoroethylene and has a membrane pore size of 0.4 to 0.6 μm. 7、根据权利要求1所述的生饮水机,其特征在于:所述二级净化单元中的内芯(9)由烧结活性炭棒或活性炭-活化沸石混合烧结棒构成。The raw water dispenser according to claim 1, characterized in that the inner core (9) in the secondary purification unit is composed of a sintered activated carbon rod or an activated carbon-activated zeolite mixed sintered rod. 8、根据权利要求1或7所述的生饮水机,其特征在于:所述高分子吸附膜(10)为γ-聚谷氨酸吸附膜,膜孔径为0.3~1微米。The raw water dispenser according to claim 1 or 7, wherein the polymer adsorption membrane (10) is a γ-polyglutamic acid adsorption membrane having a membrane pore size of 0.3 to 1 μm. 9、根据权利要求8所述的生饮水机,其特征在于:所述超滤膜(11)的材质为聚偏氟乙烯,膜孔径为30~60纳米。The raw water dispenser according to claim 8, wherein the ultrafiltration membrane (11) is made of polyvinylidene fluoride and has a membrane pore size of 30 to 60 nm.
PCT/CN2011/071376 2010-12-03 2011-02-28 Anti-clogging raw water drinking machine for removing heavy metal Ceased WO2012071815A1 (en)

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