WO2011126023A1 - 異方性ボンド磁石の製造方法およびその製造装置 - Google Patents
異方性ボンド磁石の製造方法およびその製造装置 Download PDFInfo
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- WO2011126023A1 WO2011126023A1 PCT/JP2011/058636 JP2011058636W WO2011126023A1 WO 2011126023 A1 WO2011126023 A1 WO 2011126023A1 JP 2011058636 W JP2011058636 W JP 2011058636W WO 2011126023 A1 WO2011126023 A1 WO 2011126023A1
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- H01F41/02—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets
- H01F41/0253—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets for manufacturing permanent magnets
- H01F41/0266—Moulding; Pressing
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- B29C43/00—Compression moulding, i.e. applying external pressure to flow the moulding material; Apparatus therefor
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- H01F1/08—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together
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- H01F1/083—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials metals or alloys in the form of particles, e.g. powder pressed, sintered, or bound together in a bonding agent
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- H01F1/12—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials
- H01F1/14—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys
- H01F1/20—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder
- H01F1/28—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of soft-magnetic materials metals or alloys in the form of particles, e.g. powder dispersed or suspended in a bonding agent
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- H01F41/0253—Apparatus or processes specially adapted for manufacturing or assembling magnets, inductances or transformers; Apparatus or processes specially adapted for manufacturing materials characterised by their magnetic properties for manufacturing cores, coils, or magnets for manufacturing permanent magnets
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- H02K15/02—Processes or apparatus specially adapted for manufacturing, assembling, maintaining or repairing of dynamo-electric machines of stator or rotor bodies
- H02K15/03—Processes or apparatus specially adapted for manufacturing, assembling, maintaining or repairing of dynamo-electric machines of stator or rotor bodies having permanent magnets
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- H01F1/032—Magnets or magnetic bodies characterised by the magnetic materials therefor; Selection of materials for their magnetic properties of inorganic materials characterised by their coercivity of hard-magnetic materials
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- H01F1/047—Alloys characterised by their composition
- H01F1/053—Alloys characterised by their composition containing rare earth metals
- H01F1/055—Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5
- H01F1/057—Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B
- H01F1/0571—Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B in the form of particles, e.g. rapid quenched powders or ribbon flakes
- H01F1/0575—Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B in the form of particles, e.g. rapid quenched powders or ribbon flakes pressed, sintered or bonded together
- H01F1/0578—Alloys characterised by their composition containing rare earth metals and magnetic transition metals, e.g. SmCo5 and IIIa elements, e.g. Nd2Fe14B in the form of particles, e.g. rapid quenched powders or ribbon flakes pressed, sintered or bonded together bonded together
Definitions
- the present invention relates to a manufacturing method and a manufacturing apparatus suitable for manufacturing a high-performance annular anisotropic bonded magnet.
- bonded magnet An anisotropic bonded magnet (hereinafter referred to as “bonded magnet” as appropriate) formed by compression molding a compound comprising a rare earth anisotropic magnet powder and a binder resin has a shape in which a large magnetic flux density is obtained even if it is small, and the thickness is reduced. The degree of freedom is also great. For this reason, the demand for bond magnets is increasing as field permanent magnets used in multi-pole motors that are strongly demanded for miniaturization and light weight as well as high output and energy saving. With this increase in demand, there is a growing demand for lower prices for bonded magnets.
- the orientation step is a step in which magnetic particles (orientation magnetic field) are applied to the compound filled in the cavity of the mold, and the constituent particles of the anisotropic magnet powder are arranged in the direction of the easy axis of magnetization.
- the rare earth anisotropic magnet powder itself has a large coercive force and is often difficult to be oriented.
- the constituent particles hereinafter referred to as “magnet particles” as appropriate
- magnet particles can be rotated or moved in the softened or melted binder resin, the magnetization easy axis of the crystal is aligned with the direction of the orientation magnetic field.
- Such an alignment process is indispensable for obtaining an anisotropic bonded magnet having a high magnetic flux density.
- JP-A-2-59993 JP-A-8-111337 Japanese Patent Laid-Open No. 2004-23085 JP-A-11-87164 WO2006 / 1304 Publication
- Patent Document 1 a first permanent magnet whose magnetic direction is a radial direction and a second permanent magnet whose magnetic direction is a circumferential direction are arranged in four poles by a magnetic field molding apparatus in which the outer periphery of a molding die (cavity) is alternately arranged. Proposes to produce molded bodies. According to this apparatus, the leakage flux of the first permanent magnet is effectively directed to the radial orientation magnetic field by the second permanent magnet, thereby enabling more efficient orientation.
- Patent Document 1 is premised on injection molding or extrusion molding and is not related to compression molding. Specifically, an injection-molded or extrusion-molded molded body is taken out after being cooled and solidified to ensure predetermined dimensions and prevention of deformation, but a compression-molded molded body is cured by a binder resin. Taken out before. For this reason, in the case of patent document 1, the problem which arises in the compression-molded molded object does not arise, but patent document 1 differs in the premise from the case of compression molding.
- Patent Document 2 proposes that a permanent magnet is molded in a magnetic field using a magnetic field source, and then the permanent magnet is rotated away from the molded body. As a result, the molded body is demagnetized and can be taken out while maintaining its shape without being self-destructed by its own magnetic force.
- a correspondingly complicated mechanism and space are required. As a result, it is impossible to reduce the size of the apparatus, and it is difficult to increase the number of processes and reduce the tact time of the bonded magnet.
- the complicated operation as described above is to perform demagnetization to converge the magnetic flux density B to almost zero as in the conventional electromagnetic demagnetization method (paragraph [0036] of the same publication). .
- Patent Document 3 describes that by using a permanent magnet for the orientation magnetic field, a plurality of molded bodies can be obtained at one time while using a conventional size die ([0026] of FIG. 6, FIG. 6). And FIG. 7).
- a conventional size die [0026] of FIG. 6, FIG. 6).
- FIG. 7 there is no description regarding taking out the molded body from the mold after molding in a magnetic field, and the tact time of the bonded magnet can be shortened or its cost can be simply reduced as it is. I can't.
- Patent Document 4 in order to manufacture a small magnet with a compact facility, a spray-granulated rare earth-containing alloy powder is compression-molded while orienting a permanent magnet as a magnetic field source, and then separated from an orienting apparatus. A method for forming a rare earth sintered magnet is described in which a magnetic device is used to reverse the magnetic field to demagnetize and take out the formed body.
- Patent Document 4 relates to a compact sintered magnet compact, and does not relate to a bonded magnet compact that is taken out before the binder resin is completely cured.
- Patent Document 5 describes a method of manufacturing a yoke-integrated rare earth bonded magnet in which a bonded magnet molded body is press-fitted into a ring-shaped yoke by using a spring back, and both are integrated without using an adhesive. ing.
- Patent Document 5 does not describe anything about the rare earth magnet powder constituting the molded body being anisotropic magnet powder, orientation treatment, and demagnetization or demagnetization.
- Patent Document 5 has no description regarding semi-radial orientation, or even using a permanent magnet as a magnetic field source for the orientation magnetic field, and no description regarding the self-disintegration property and shape retention of the compact.
- the present invention has been made in view of such circumstances, and a method for producing an anisotropic bonded magnet capable of improving the mass productivity of an annular anisotropic bonded magnet and reducing the price thereof, and It aims at providing the manufacturing apparatus.
- the present inventor has made a permanent magnet as a magnetic field source of an orienting magnetic field when performing an orienting step necessary for manufacturing an annular anisotropic bonded magnet. After forming in the orientation magnetic field (molding in the magnetic field), demagnetizing the molded body by rotating the permanent magnet relative to the obtained molded body, and then taking out the molded body It was. By developing this result, the present inventor has completed various inventions described below.
- a method for producing an anisotropic bonded magnet according to the present invention includes a filling step of filling a circular cavity with a magnet raw material containing one or more rare earth anisotropic magnet powders and a binder resin, and a permanent magnet as a magnetic field source.
- An orientation magnetic field is applied to the magnet raw material in the annular cavity from an orientation magnetic pole body that is disposed evenly around the outer periphery of the annular cavity and with the direction of the magnetic field alternately reversed, and is in a softened or molten state.
- a permanent magnet is used as a magnetic field source for the orientation magnetic field. Therefore, compared to the case where an electromagnetic coil or the like is used, the mold, the apparatus, etc. Can be made compact. For this reason, it is possible to efficiently mass-produce an annular anisotropic bonded magnet (referred to as “bonded magnet” as appropriate) while using equipment of the same size as the conventional one.
- the annular molded body according to the present invention obtained by molding in a magnetic field using a permanent magnet as a magnetic field source for the orientation magnetic field is in a state where N poles and S poles are alternately distributed on the circumferential side surface. If this molded body is taken out of the annular cavity (hereinafter referred to as “cavity” as appropriate) immediately after molding, the molded body can self-collapse due to the attractive force acting between its magnetic poles. In other words, the molded body immediately after the molding process does not have sufficient shape retention to maintain its own shape.
- the molded body after the molding step is sufficiently cooled in the annular cavity to solidify the binder resin, or if the binder resin is a thermosetting resin, the binder resin may be cured by curing heat treatment.
- such a method is not preferable at least from the current technical level because it causes an increase in the takt time of the bonded magnet.
- the demagnetization step of demagnetizing the magnetization of the molded body is performed before the discharging step of discharging the molded body after the molding process from the cavity. Accordingly, the attractive force acting between the magnetic poles of the compact is reduced, and the compact can be taken out from the cavity while maintaining its shape.
- the demagnetization process of the present invention is performed by relatively changing the corresponding positions on the circumference of the oriented magnetic pole body used in the orientation process and the shaped body after the molding process. That is, the permanent magnet used as the magnetic field source for the orientation magnetic field in the orientation process is used as the magnetic field source for the demagnetization magnetic field that cancels the magnetization applied to the compact in the orientation process.
- the oriented magnetic pole body is moved relative to the molded body in the circumferential direction, and the circumference of the molded body and the oriented magnetic pole body is changed during the orientation process and the demagnetization process. Only the relative position is changed. For example, in the case of a four-pole alternately oriented molded body, if the relative rotation is performed by 90 ° which is an angle corresponding to one magnetic pole (magnetic pole unit angle: 360 ° divided by the number of magnetic poles), the molded body is formed. A demagnetizing magnetic field can be easily applied, and the magnetization of the compact can be demagnetized.
- the demagnetization step is performed from the time of the alignment step by an odd multiple of the magnetic pole unit angle, which is the minimum angle necessary for reversing the magnetic pole of the alignment magnetic pole disposed with respect to the molded body. It is preferable that the step of rotating the body relative to the molded body.
- the discharging step is a press-fitting step of press-fitting the molded body into the cylindrical body that is disposed coaxially with the annular cavity and has an inner peripheral surface that can contact the outer peripheral surface of the molded body while discharging the molded body from the annular cavity.
- the manufacturing process can be simplified by directly assembling the molded body after the molding process to the cylindrical body.
- the cylinder is a motor yoke or housing, the air gap between the yoke and the magnet and the air gap between the magnet and the armature can be reduced, which is preferable.
- press-fit refers to fitting a molded body having an outer diameter larger than the inner diameter of the cylinder into the cylinder.
- the outer diameter of the molded body at this time refers to the outer diameter of the molded body in a shape-retaining state that is taken out from the annular cavity immediately after being discharged.
- insertion in the present specification is a superordinate concept including the above-described “press-fit”, gap fitting, and the like. Therefore, unless otherwise specified, “insertion” includes “press-fit”.
- the pressed body is an elastic body or not. If the binder resin is completely cured (or solidified), it is considered that the press-fitted molded body behaves as an elastic body. Specifically, it is considered that the stress that accompanies elastic deformation acts on the press-fitted molded body and is fixed to the cylindrical body. On the other hand, if the binder resin is uncured (or unsolidified), it is considered that the plastic body alone or both the plastic body and the elastic body behave. Specifically, it is considered that the press-fitted molded body deforms following the inner shape of the cylindrical body, and comes into close contact with the inner peripheral surface of the cylindrical body and is easily fixed to the cylindrical body.
- curing in the present specification includes not only the case where a binder resin made of a thermosetting resin is thermally cured but also the case where a binder resin in a softened state or a molten state is cooled and solidified. If the binder resin is cured (or solidified) when the molded body is discharged from the annular cavity, the molded body already has shape retention, so the above demagnetization step does not necessarily have to be performed. An anisotropic bonded magnet can also be obtained by a manufacturing method.
- the present invention provides a filling process in which an annular cavity is filled with a magnet raw material containing one or more rare earth anisotropic magnet powders and a binder resin, and an even magnetic field is formed evenly around the outer circumference of the annular cavity using a permanent magnet as a magnetic field source.
- the rare earth anisotropic magnet powder in the softened or melted state by applying an orientation magnetic field to the magnet raw material in the annular cavity from the oriented magnetic poles arranged with the orientations of the magnets alternately reversed An orientation step for orienting the core, a molding step for forming a magnet raw material during or after the orientation step to obtain an annular shaped body, and a discharging step for discharging the shaped body from the annular cavity.
- a method for manufacturing an anisotropic bonded magnet wherein the discharging step is arranged such that the molded body is formed into a cylindrical body that is disposed coaxially with the annular cavity and has an inner circumferential surface that can contact an outer circumferential surface of the molded body.
- Annular carrier It may be a method for producing an anisotropic bonded magnet, which is a fitting step of fitting while discharged from tee.
- the molded body after the molding process is received in a cylindrical body having an inner shape adapted to the outer shape, so that it can be discharged from the cavity. That is, even with a magnetized molded body, the cylindrical body ensures the shape retention of the molded body and prevents the molded body from self-destructing.
- the cylinder is preferably a magnetic cylinder made of a magnetic material.
- the molded body inserted into the soft magnetic cylinder has a smaller acting magnetic circuit than the molded body inserted into the molded body alone or a nonmagnetic cylinder made of a nonmagnetic material. That is, the magnetic loop from one magnetic pole formed on the molded body after the orientation process to the adjacent magnetic pole becomes small.
- the mutual magnetic attractive force between the adjacent magnetic poles decreases, the shape retention of the molded body is more easily ensured, and the molded body is more effectively prevented from self-destructing. Furthermore, it is preferable that the molded body is press-fitted into the cylindrical body. Since there is no air gap, the magnetic loop is efficiently formed, and self-collapse of the molded body is more efficiently prevented.
- FIGS. 16A and 16B Such a magnetic loop is shown in FIGS. 16A and 16B.
- FIG. 16A shows a magnetic closed loop when the molded body G after the orientation process is fitted into the soft magnetic cylinder M.
- FIG. 16B shows the magnetic open loop of the compact G after the alignment step.
- the “soft magnetic material” constituting the soft magnetic cylinder does not need to be a soft magnetic material in a strict sense, and may be somewhat magnetized. If it dares to say, the soft magnetic material should just be a permanent magnet whose residual magnetization is weaker than the molded object after an orientation process. In this sense, “soft magnetic material” can be called “magnetic material”, and “soft magnetic cylinder” can be called “magnetic cylinder”.
- demagnetization or demagnetization when the molded body after the molding process is discharged from the cavity is not necessarily required.
- the molded body is demagnetized or demagnetized. Therefore, in the present invention, it is preferable to provide a demagnetizing step of applying a demagnetizing magnetic field in a direction to cancel the magnetization due to the orientation magnetic field to the molded body inserted into the cylindrical body during or after the inserting step. Moreover, it may replace with a demagnetizing process and may combine the demagnetizing process and insertion process which were mentioned above. As a result, it is possible to prevent foreign matter from adhering during conveyance.
- magnetization or “demagnetization” is to reduce or eliminate the magnetization of a compact formed by an orientation magnetic field and is basically a common concept. However, in this specification, it is referred to as “demagnetization” when almost complete no magnetic field is possible, and “demagnetization” when no complete magnetic field is not included. Incidentally, the almost complete non-magnetic field is achieved, for example, by demagnetizing by resonance damping using a so-called demagnetizing coil and a demagnetizing power source.
- the annular anisotropic bonded magnet obtained by the present invention has a high magnetic flux density even if it is thin, it is suitable for an electric motor that has a strong demand for reduction in size and weight.
- the molded body is fitted or press-fitted into the yoke.
- the soft magnetic cylinder described above is a yoke (a casing, a case, etc.) of an electric motor, since the discharge of the molded body and the incorporation of the molded body into the yoke of the electric motor are performed at the same time. .
- the present invention can be grasped not only as a manufacturing method of the above-mentioned anisotropic bonded magnet but also as a manufacturing apparatus suitable for its implementation.
- the present invention provides a cylindrical or columnar core, a mold that surrounds the core and forms an annular cavity with the core, and an even number in the vicinity of the outer periphery of the mold And an orientation magnetic pole body including a permanent magnet that is arranged by alternately reversing the direction of the magnetic field and that can supply an orientation magnetic field to the annular cavity.
- An annular anisotropic bonded magnet manufacturing apparatus may be provided that includes a driving unit that relatively changes only the corresponding positions on the circumference between the cavity and the oriented magnetic pole body.
- the present invention also provides a cylindrical or columnar core, a mold that surrounds the core and forms an annular cavity with the core, and an even number in the vicinity of the outer periphery of the mold.
- an orientation magnetic pole body including a permanent magnet that is arranged by alternately reversing the direction of the magnetic field and that can supply an orientation magnetic field to the annular cavity.
- An apparatus for manufacturing an annular anisotropic bonded magnet may be provided.
- the number of magnetic poles formed on the circumferential side surface of the annular molded body or bond magnet is not particularly limited as long as it is 2 or more (2, 4, 6, 8, 10, etc.). Considering higher performance, higher efficiency, etc. of the equipment in which the bond magnet is used, the number of magnetic poles is preferably 4 or more (4, 6, 8, 10, etc.).
- the manufacturing method of the anisotropic bonded magnet of the present invention includes the above-described filling step, orientation step, molding step, a densification step in which the compact is further compressed (heat-compressed) to be densified, and a magnet raw material. It also includes a curing heat treatment step (curing heat treatment step) for strongly curing the used thermosetting resin, a magnetizing step for magnetizing the molded body to form an annular anisotropic bonded magnet, and a corrosion prevention treatment step. Good. Each step may be performed independently, or may be performed jointly or synchronously.
- the magnet material filled into the annular cavity is a compound obtained by kneading and granulating a rare earth anisotropic magnet powder and a binder resin, but preliminarily compressing the weighed rare earth anisotropic magnet powder and the binder resin.
- a molded preform or the like may be used.
- the molding process according to the present invention may be a compression molding process in which the magnet raw material filled in the annular cavity is compression molded by the upper punch and the lower punch, or the annular cavity formed by the movable mold and the fixed mold is filled.
- an injection molding process for cooling and solidifying the magnet raw material may be used.
- the binder resin is not limited to a thermosetting resin, and may be a thermoplastic resin.
- the “softened state” or “molten state” in the present invention is not strictly distinguished. In short, it is sufficient if the resin is heated to lower its viscosity and each particle of the rare earth anisotropic magnet powder can be rotated and moved.
- Oriented magnetic pole body as used in the present invention is a single oriented magnetic pole body that has a permanent magnet as a magnetic field source and is arranged evenly and alternately in the direction of the magnetic field around the outer periphery of the annular cavity. Produces a radial magnetic field in the annular cavity.
- the oriented magnetic pole body can change and invert the direction of the magnetic field applied to the annular cavity during the orientation process and the demagnetization process. For this reason, in the present invention, a case where only a desired radial magnetic field is applied to the annular cavity only at one step of the alignment step or the demagnetization step is excluded from the alignment pole body.
- the oriented magnetic pole body may be only a permanent magnet that is the magnetic field source, or may be a combination of a yoke that relays the magnetic field and a permanent magnet.
- the permanent magnet may be singular or plural, and when there are a plurality of permanent magnets, their form and material may be single or plural.
- the magnetic field source of the oriented magnetic pole body it is possible to quickly switch from the orientation process to the demagnetization process, and the tact time of the bond magnet is likely to be shortened. Further, the material, form, combination, and the like of the permanent magnet and the yoke constituting the oriented magnetic pole body are appropriately selected according to the stress level acting from the mold during compression molding.
- Orientation as used in the present invention means that the magnetic particles are aligned so that the easy axis of magnetization follows the orientation magnetic field, and it does not matter to a specific orientation state.
- the easy magnetization axes are arranged and distributed outward in the radial direction (radial direction) due to the orientation.
- a first region composed of a group of magnet particles and a second region composed of a group of magnet particles in which easy axes of magnetization are arrayed inward in the radial direction (radial direction) are alternately generated. In other words, it is sufficient that at least the first region and the second region are formed, and a more specific orientation state is not required.
- the orientation state in the transition region formed between these regions is not questioned.
- the bonded magnet of the present invention is used for a field of a motor or the like, if the magnet particles are distributed so that the direction of the easy magnetization axis changes smoothly in the transition region, the motor output can be improved and stabilized. Etc. are preferable. Therefore, the orientation referred to in the present invention is preferably so-called semi-radial orientation (the definition will be described later).
- the “cylindrical body” referred to in the present invention has an inner shape (inner cylinder shape) into which an annular shaped body is inserted, and the outer shape (cross-sectional outer shape) thereof is circular, rectangular, rectangular, etc. Either of these may be used.
- the inner shape of the “tubular body” is not limited to a simple cylindrical inner surface shape, and may be a “mountain” shape having a convex portion (supporting portion).
- the “annular cavity” may have not only an annular shape but also a square shape, a hexagonal shape, an angular shape such as an octagonal shape, etc.
- the “molding die” may have not only a cylindrical shape but also a square shape, a hexagonal shape, an octagonal shape, etc. Any of them can take various shapes within the scope of the gist of the present invention.
- a configuration related to a method can be a configuration related to “thing” if understood as a product-by-process.
- a magnetic raw material consists of 1 or more types of rare earth anisotropic magnet powder and binder resin. Specifically, for example, a mixed powder of rare earth anisotropic magnet powder and resin powder, a compound obtained by heating and kneading the mixed powder, a preform formed by compression molding the mixed powder or compound, or a rare earth anisotropic magnet powder and melting And a mixture with the prepared resin.
- the magnet raw material may include additives such as a lubricant, a curing agent, a curing aid, and a surfactant in addition to the rare earth anisotropic magnet powder and the resin.
- the composition, type and the like of the rare earth anisotropic magnet powder are not limited, and any known magnet powder can be adopted.
- typical rare earth anisotropic magnet powders include Nd—Fe—B based magnet powder, Sm—Fe—N based magnet powder, SmCo based magnet powder and the like. These magnet powders may be manufactured by a so-called rapid solidification method or may be manufactured by a hydrotreating method (d-HDDR method, HDDR method).
- the rare earth anisotropic magnet powder may be one kind or plural kinds. For example, a coarse powder having a relatively large average particle diameter (for example, 1 to 250 ⁇ m) and a fine powder having a relatively small average particle diameter (for example, 1 to 10 ⁇ m) may be mixed.
- the magnet raw material may contain magnet powder other than the rare earth anisotropic magnet powder. For example, various isotropic magnet powders, ferrite magnet powders, and the like.
- binder resin known materials including rubber can be used. Examples thereof include thermosetting resins such as epoxy resins, unsaturated polyester resins, amino resins, phenol resins, polyamide resins, polyimide resins, polyamideimide resins, urea resins, and melamine resins.
- thermosetting resins such as epoxy resins, unsaturated polyester resins, amino resins, phenol resins, polyamide resins, polyimide resins, polyamideimide resins, urea resins, and melamine resins.
- the presence form of binder resin is not ask
- the binder resin is softened or melted during the alignment process to assist the alignment of the rare earth anisotropic magnet powder.
- the binder resin may be a thermoplastic resin.
- ⁇ Small amounts of various additives may be added to improve the mold release properties, the adjustment of molding timing, the wettability and adhesion between the magnet powder and the molten resin, and the like.
- additives include various metal soaps, lubricants such as alcohol lubricants, titanate or silane coupling agents, various curing agents, various curing accelerators, and the like.
- the mixing ratio of the rare earth anisotropic magnet powder and the resin is, as a volume ratio, magnet powder: 76 to 90% by volume, and the total of resin and additive: about 10 to 24% by volume.
- the magnet powder is 90 to 99% by mass, and the total of resin and additives is about 1 to 10% by mass.
- the anisotropic bonded magnet according to the present invention may be any size, magnetic property, application, etc., as long as it is cylindrical or annular. A typical application is the field of a motor. Examples of the motor include a direct current (DC) motor and an alternating current (AC) motor.
- the position of the anisotropic bonded magnet may be on the rotor (rotor) side, the stator (stator) side, the inner peripheral side or the outer peripheral side with respect to the stator.
- a thin-walled annular field permanent magnet disposed in a casing of a 4-pole DC brush motor is taken up. More specifically, the field permanent magnet is a ring-shaped bonded magnet R having a cross section as shown in FIG.
- the ring-shaped bonded magnet R is filled with a compound (magnet raw material) made of Nd—Fe—B rare earth rare earth anisotropic magnet powder (referred to as “magnet powder”) and a binder resin, heated, oriented, compressed, molded. Obtained by thermosetting and magnetizing.
- This ring-shaped bonded magnet R has four magnetic poles (A pole to D pole) formed on the circumferential side surface by semi-radial orientation.
- Each magnetic pole includes main pole portions Ia, Ib, Ic, and Id and transition portions IIab, IIbc, IIcd, and IIda formed between adjacent main pole portions.
- the direction in which the constituent particles (magnet particles) of the ring-shaped bonded magnet R in each main pole part and transition part are oriented is indicated by arrows on FIG.
- the orientation means that the constituent particles (magnet particles) of the rare earth anisotropic magnet powder are moved or rotated in response to the orientation magnetic field and aligned so that the easy axis of magnetization is along the direction of the orientation magnetic field.
- Semi-radial orientation means that the magnetic particles are distributed in the main pole so that the easy magnetization axis is in the normal direction of the circumferential side surface, and gradually move toward the tangential direction as the easy magnetization axis approaches the neutral point in the transition part. The magnet particles are distributed so as to gradually turn to the normal direction of the circumferential side surface as they move away from the neutral point after turning to the neutral point.
- the semi-radial orientation is different from the radial orientation in which all the easy magnetization axes are directed in the radial (radiation) direction in that the orientation of the easy magnetization axis varies depending on the position. Even in the semi-radial orientation, the direction of the easy axis of magnetization of the magnet particles does not change critically in the vicinity of the boundary between the main pole part and the transition part, but changes smoothly.
- Example 1 A cross section of a mold 1 that can be used in the manufacturing method of the present invention is shown in FIG. Although only one mold 1 is shown in FIG. 2, a plurality of compact molds 1 are arranged vertically and horizontally on a die of an actual manufacturing apparatus. This makes it possible to take a plurality of molded bodies in a space-saving manner.
- the mold 1 includes a columnar core 11 made of a magnetic material and also serving as a central yoke, and a cylindrical mold 12 made of a nonmagnetic material coaxially disposed on the outer periphery of the core 11; Intermediate yokes 13 a, 13 b, 13 c, 13 d (collectively referred to as “intermediate yoke 13”) made of fan-shaped magnetic material, which are equally arranged at four locations on the outer peripheral surface side of the mold 12, and the intermediate yoke 13. Fan-shaped main permanent magnets 14a, 14b, 14c, 14d (collectively referred to as “main permanent magnet 14”) and adjacent intermediate yokes 13a, 1313b, 13c, 13d, respectively.
- Fan-shaped first auxiliary permanent magnets 15a, 15b, 15c, 15d (collectively referred to as “first auxiliary permanent magnet 15”) that are interposed in the gap so as to be flush with the outer peripheral side surfaces thereof, and the first.
- Outside auxiliary permanent magnet 15 Fan-shaped second auxiliary permanent magnets 16a, 16b, 16c, 16d (collectively “second auxiliary permanent magnets”, which are respectively arranged on the side and interposed in the gap between the main permanent magnets 14 so as to be flush with the outer peripheral side surface thereof.
- second auxiliary permanent magnets which are respectively arranged on the side and interposed in the gap between the main permanent magnets 14 so as to be flush with the outer peripheral side surface thereof.
- a cylindrical back yoke 17 disposed in contact with the outer peripheral side surfaces of the main permanent magnet 14 and the second auxiliary permanent magnet 16.
- annular cavity c annular cavity, cylindrical cavity
- An annular upper magnet and a lower punch provided coaxially with the annular cavity c compress the compound filled in the annular cavity c to form an annular bond magnet R.
- a molded body is obtained.
- the main permanent magnet 14 corresponds to the oriented magnetic pole body referred to in the present invention.
- An orientation magnetic field is applied from the main permanent magnet 14 to the annular cavity c through the intermediate yoke 13.
- the intermediate yoke 13 can be included in the oriented magnetic pole body.
- the molding die 12 is made of a non-magnetic material, the magnetic circuit is not short-circuited by the molding die 12, and the orientation magnetic field can surely reach the annular cavity c.
- the mold 12 is a magnetic material, the easy axis of magnetization at the transition portion can be changed more continuously and smoothly when the mold is semi-radially oriented.
- the mold 12 is preferably a magnetic material rather than a nonmagnetic material.
- the main permanent magnet 14 has an N pole and an S pole in the radial direction, and the adjacent main permanent magnets 14a, 14b, 14c, and 14d have opposite polarities.
- the direction of the orientation magnetic field formed by these main permanent magnets 14 is indicated by white arrows on FIG.
- the first auxiliary permanent magnets 15a, 15b, 15c, 15d and the second auxiliary permanent magnets 16a, 16b, 16c, 16d suppress magnetic flux leakage in the circumferential direction of the intermediate yoke 13 and the main permanent magnet 14. For this reason, the 1st auxiliary
- the intermediate yoke 13a and the main permanent magnet 14a have an N pole on the inner peripheral side and an S pole on the outer peripheral side, and form an orientation magnetic field toward the center of the annular cavity c
- the N poles of the first auxiliary permanent magnets 15a and 15d and the second auxiliary permanent magnets 16a and 16d are arranged on the inner side (opposite side) and the S pole is on the outer side so as to form a magnetic field in a direction that sandwiches the orientation magnetic field from both sides. It is arranged on the (back side).
- the orientation magnetic field generated from the intermediate yoke 13a and the main permanent magnet 14a is prevented from leaking in the circumferential direction and converges toward the center of the annular cavity c.
- the relationship between the other intermediate yoke 13, the main permanent magnet 14, the first auxiliary permanent magnet 15, and the second auxiliary permanent magnet 16 is the same.
- the first auxiliary permanent magnet 15 or the second auxiliary permanent magnet 16 contributes to the orientation of the magnet powder, but does not basically contribute to the formation of a demagnetizing magnetic field described later. Therefore, in this embodiment, the first auxiliary permanent magnet 15 and the second auxiliary permanent magnet 16 are not included in the “oriented magnetic pole body”.
- the back yoke 17 magnetically connects the outer peripheral surfaces of the main permanent magnets 14 so that a closed magnetic circuit is formed in the mold 1.
- the cylindrical back yoke 17 is provided individually, but a common one may be used for a plurality of molds.
- the mold 1 is divided into an inner peripheral portion including the intermediate yoke 13 and the first auxiliary permanent magnet 15 and an outer peripheral portion including the main permanent magnet 14 and the second auxiliary permanent magnet 16.
- the divided inner peripheral portion and outer peripheral portion can rotate relative to each other along a circular dividing line l1 (Elwan).
- the inner peripheral portion is a fixed portion and the outer peripheral portion is a movable portion.
- the back yoke 17 serves as a movable portion, but the back yoke 17 may be a fixed portion.
- FIG. 3 shows a state where the movable part is rotated 90 ° (magnetic pole unit angle) to the left.
- the movable part may be directly driven by a motor capable of controlling the rotation angle provided with an encoder or the like, or may be driven via a gear or a toothed belt linked to the motor.
- a motor capable of such rotation angle control corresponds to the drive means in the present invention.
- the directions of the magnetic fields in the circumferential direction of the first auxiliary permanent magnet 15 and the second auxiliary permanent magnet 16 adjacent in the radial direction are opposite to each other (direction of canceling the magnetic flux) by rotating the movable part by 90 °. .
- the magnetic field generated in the radial direction from the intermediate yoke 13 and the main permanent magnet 14 is not so converged by the first auxiliary permanent magnet 15 and the second auxiliary permanent magnet 16 and is more than the magnetic field before the movable part is rotated by 90 °. descend.
- the orientation magnetic field (magnetic flux) to the annular cavity c before rotating the movable part is indicated by a thick arrow in FIG.
- the demagnetizing magnetic field (magnetic flux) to the annular cavity c after rotating the movable part is indicated by a thick arrow in FIG.
- FIGS. 4 and 5 only the 1 ⁇ 4 portion of the mold 1 is exemplarily shown, but the same applies to other portions. In this way, if a demagnetizing magnetic field that is opposite in direction to the orientation magnetic field and smaller than the orientation magnetic field is supplied, the compact is naturally demagnetized (as described above), and it has been confirmed that the compact does not collapse. .
- the molded body is molded and discharged as follows. First, the mold 1 is placed in the arrangement shown in FIG. 2 or 4 (referred to as “orientation arrangement”), and the compound is filled into the annular cavity c (filling step). The filled compound is heated to perform alignment (alignment process). A compact is obtained by compression-molding the magnet raw material in this state (molding step).
- the mold 1 is placed in the arrangement after rotation shown in FIG. 3 or 5 (this is called “demagnetization arrangement”).
- a reverse magnetic field demagnetizing magnetic field
- the magnetization of the molded body is significantly demagnetized compared to immediately after molding (demagnetization process, demagnetization process).
- the molded body is easily discharged from the annular cavity c (discharge process) and does not self-collapse by its own magnetic force.
- the rotation angle of the movable part of the mold 1 is one magnetic pole formed by the intermediate yoke 13 and the main permanent magnet 14 (magnetic pole unit angle: 90 ° in this embodiment). ) Or an odd multiple of them, the orientation magnetic field (magnetic flux) and the demagnetizing magnetic field (magnetic flux) are different in magnitude but opposite in direction. Accordingly, the magnetization of the compact produced by the orientation magnetic field is efficiently demagnetized efficiently by the demagnetizing magnetic field.
- the movable part of the mold 1 is rotated from the position (reference position) shown in FIG. 2 or 4 by an intermediate angle (between 0 ° and 90 °) that is less than the magnetic pole unit angle (90 ° in this embodiment). It is possible to make it. Such a case can also be included in the present invention. However, when the movable part of the mold 1 is rotated by an intermediate angle, a part that is demagnetized and a part that is not demagnetized may be generated or may not be demagnetized. For example, when viewing the magnetic field in the upper one magnetic pole shown in FIG. 6, the magnitude is smaller than the case shown in FIG. 4, and the direction is the same as the orientation direction shown in FIG. In such a case, demagnetization is not performed.
- the demagnetization of the entire molded body becomes insufficient and the shape retaining property can be lowered. Therefore, it can be seen that it is preferable to rotate the movable part of the mold 1 so that the demagnetizing magnetic field is directed in the opposite direction to the orientation magnetic field (in this embodiment, an odd multiple of the magnetic pole unit angle (90 °) which is the angle between the magnetic poles). .
- the movable part of the mold 1 is rotated from the reference position (position shown in FIG. 2 or 4) to the reverse position (position shown in FIG. 3 or 5) where the direction of the magnetic field acting on the annular cavity c is reversed.
- the amount of demagnetization (the amount of decrease in magnetic flux density) generated in the compact can be estimated using a demagnetization curve (second quadrant of the magnetization curve).
- FIG. 7 shows BH curves, 4 ⁇ IH curves, which are magnetization curves, and operating lines based on permeance coefficients.
- the operation line P 0 is drawn on the demagnetization curve of FIG.
- the intersection A between the operating line P 0 and the BH curve is the operating point at that time.
- the magnetic flux density emanating to the outside from the shaped body at this time is B 0.
- the intersection B between the perpendicular line raised from the operating point A and the 4 ⁇ IH curve indicates the magnetizing force in consideration of the self-demagnetizing field of the magnetized molded body when no external magnetic field acts.
- the compact has been irreversibly demagnetized by the magnetic flux density (B 0 -B 2 ) due to the action of the demagnetizing magnetic field. That is, when a demagnetizing magnetic field is applied to a molded body molded in a magnetic field, the amount of demagnetization of the molded body becomes a magnetic flux density (B 0 -B 2 ). This amount of demagnetization can be affected by the temperature change of the compact.
- the demagnetization amount of the molded body was evaluated on the assumption that the steps of heating orientation, molding, and discharging are performed within a short time at substantially the same temperature.
- FIGS. 8 shows the arrangement (orientation arrangement) of the mold 2 when an orientation magnetic field is applied.
- FIG. 9 shows the arrangement (demagnetization arrangement) of the mold 2 when a demagnetizing magnetic field is applied. The demagnetization arrangement in FIG. 9 is obtained by rotating the orientation arrangement in FIG. 8 90 ° to the left.
- auxiliary permanent magnet 23 are the first auxiliary permanent magnets 15a, 15b, 15c, and 15d of the mold 1 and the second auxiliary permanent magnet. Magnets 16a, 16b, 16c, and 16d are each integrated. Conversely, the first intermediate yokes 25a, 25b, 25c, and 25d (collectively referred to as “first intermediate yoke 25”) and the second intermediate yokes 26a, 26b, 26c, and 26d (collectively “second intermediate”) of the mold 2.
- Yoke 26 is obtained by separating the intermediate yokes 13a, 13b, 13c, and 13d of the mold 1 on the inner peripheral side and the outer peripheral side of the dividing line l2, respectively.
- the same reference numerals as those used in FIGS. 2 and 3 are used in FIGS. 8 and 9.
- FIG. 3 A mold 3 according to another embodiment is shown in FIG.
- the mold 3 includes a core referred to as the mold 1 or 2, a split mold 31 integrating the mold 312, the intermediate yoke 313 and the nonmagnetic material 314, a main permanent magnet referred to as the mold 1 or the mold 2, It consists of a split mold 32 in which an auxiliary permanent magnet and a back yoke are integrated.
- the split mold 31 When demagnetizing the magnetized molded body, first, the split mold 31 is moved relative to the split mold 32 together with the molded body. Next, the split mold 32 is rotated by one magnetic pole (90 ° in this embodiment). Finally, the split mold 31 is relatively moved upward, and the split mold 31 and the split mold 32 are merged as they were. By this operation, the molded body held by the split mold 31 is demagnetized by applying a demagnetizing magnetic field by the split mold 32. The demagnetizing magnetic field at this time is the same in strength as the orientation magnetic field, and only the opposite direction.
- the mold 3 does not need to divide the auxiliary permanent magnet and the intermediate yoke. For this reason, the number of parts can be significantly reduced. Further, when the mold 3 is used, unlike the case where the mold 1 is used, a demagnetizing magnetic field having the same strength as the orientation magnetic field can be applied to the molded body. However, even in this case, the actual demagnetization level is determined by the permeance coefficient, temperature, magnetic characteristics, magnitude of the orientation magnetic field, etc. of the molded body, and complete demagnetization is not always performed.
- Example 4 The metal mold
- the demagnetizing magnetic field is applied to the magnetized molded body G by relatively rotating the mold 4 and the molded body G.
- FIG. 11 shows the case where the mold 4 itself is rotated with respect to the molded body G by one magnetic pole (90 ° in this embodiment).
- FIG. 12 shows a case where the molded body G itself is rotated by one magnetic pole (90 ° in this embodiment) with respect to the mold 4.
- the demagnetizing magnetic field at this time also has the same strength as the orientation magnetic field, and is only opposite in direction, so that the magnetized molded body can be efficiently demagnetized.
- the molded body G immediately after being molded under high temperature and pressure is in close contact with the inner wall surface of the annular cavity of the mold 4. Therefore, in order to smoothly rotate the molded body G and the mold 4 relative to each other, it is preferable to slightly knock out (KO) the molded body G and release the adhesion.
- the core 41, the lower punch 42, and the upper punch 43 may move slightly upward or downward while sandwiching the molded body G. Also, as shown in FIG. 12, when the molded body G is rotated, the core 41, the lower punch 42, and the upper punch 43 may be rotated while sandwiching the molded body G.
- Example 5 Another embodiment is shown in FIG.
- the present embodiment includes a mold 5, a magnetic shield 53 placed on the upper surface side thereof, and a demagnetizing device 54 placed on the upper surface side thereof.
- the mold 5 compresses and molds the compound in the annular cavity in an orientation magnetic field, but does not demagnetize the obtained molded body G.
- the magnetic shield 53 blocks leakage of the orientation magnetic field applied to the annular cavity of the mold 5 to the demagnetizer 54.
- the magnetic shield 53 is made of a nonmagnetic material such as nonmagnetic stainless steel, aluminum, or ceramics. Note that it is preferable to form a magnetic shield portion in the core 51 at a position corresponding to the magnetic shield 53.
- the demagnetizer 54 includes a cylindrical body 541 (tubular body) made of a non-magnetic material and an electromagnet that applies a demagnetizing magnetic field from the outer periphery thereof.
- the molded body G molded in the magnetic field in the annular cavity of the mold 5 is knocked upward (discharge process) by the lower punch 52 using the core 51 as a guide, and is inserted into the cylindrical body 541 (cylinder) (inserted). Process).
- the cylindrical body 541 and the lower punch 52 correspond to the fitting means referred to in the present invention.
- the demagnetizing device 54 applies a demagnetizing magnetic field (or demagnetizing magnetic field) in the direction indicated by the white arrow (FIG. 13) (the direction opposite to the orientation magnetic field) to the compact G inserted in the cylindrical body 541. (Demagnetization process, demagnetization process). Thereby, the compact G is demagnetized or demagnetized.
- the compact G is directly pressed into the cylindrical body 541 after performing the demagnetization process or the demagnetization process as described in the first to fourth embodiments.
- a press-fitting process may be performed.
- the press-fitting process also serves as the discharging process.
- the demagnetizer 54 may use a permanent magnet as a magnetic field source for a demagnetizing magnetic field.
- an electromagnet as a magnetic field source, a complete magnetic field can be obtained.
- the molded body G can be more easily taken out from the mold 5 while maintaining its shape.
- the present inventor has confirmed that when the demagnetization step or the demagnetization step is not performed, the molded body does not collapse and is easily retained by press-fitting rather than simply fitting.
- FIG. 6 Another embodiment is shown in FIG. This embodiment is basically the same as the embodiment 5 shown in FIG. However, unlike the demagnetizer 54, the demagnetizer 55 can move in the left-right direction in the figure. For this reason, the molded object G accommodated in the cylindrical body 551 can be conveyed to the next process together with the demagnetizing device 55 after demagnetization (and demagnetization).
- the molded body G is originally thin and lightweight, and the outer peripheral surface of the molded body G is in contact with at least the inner peripheral surface of the cylindrical body 551 (particularly, if the fitting process is a press-fitting process, the molded body G is in close contact). For this reason, the molded body G is unlikely to fall off the cylindrical body 551 even after demagnetization and demagnetization. Further, when the application of the demagnetizing magnetic field from the demagnetizer 55 to the compact G is continued, the compact G continues to be magnetically attracted to the cylindrical body 551 and does not fall off during conveyance. Further, when the magnetic field source of the demagnetizing device 55 is an electromagnet, the molded body G can be easily taken out by interrupting the supply current after the conveyance. In this way, by smoothly performing discharge, demagnetization / demagnetization, and conveyance of the compact G as a series of steps, the tact time of the ring-shaped bonded magnet R can be further shortened.
- the demagnetizing device 55 since the demagnetizing device 55 is movable, the upper end of the core 515 (the upper surface in the pressurizing direction) is made to coincide with the upper surface of the mold 5. As a result, the manufacturing (molding) apparatus can be reduced in size, and the leakage of the orientation magnetic field toward the demagnetizing apparatus 55 can be suppressed without forming a magnetic shield portion on the core 515. Further, since the upper end portion of the core 515 does not advance into the cylindrical body 551, the core 515 does not serve as a guide for the molded body G to be fitted into the cylindrical body 551. However, since the molded body G is demagnetized or demagnetized by the demagnetizer 55, its shape retention is not affected.
- the demagnetizer 55 uses a permanent magnet as a magnetic field source of a demagnetizing magnetic field.
- the molded body G held by the cylindrical body 551 may be subjected to a heat treatment (curing heat treatment) for thermosetting the binder resin as it is.
- a heat treatment curing heat treatment
- a magnet having a Curie point higher than the cure heat treatment temperature may be used.
- the molded body G after the binder resin is cured no longer self-collapses, it can be taken out from the cylindrical body 551 by knockout by a punch or the like.
- magnetization is performed (magnetization step), and a ring-shaped bonded magnet R is obtained.
- the demagnetizing device 55 uses an electromagnet as the magnetic field source of the demagnetizing magnetic field, the compact G is completely demagnetized and there is no risk of self-destructing any longer. For this reason, it suffices to take out only the molded body G from the cylindrical body 551 and transport it to the next process, and it is not necessary to perform a curing heat treatment or the like together with the demagnetizing device 55 or the cylindrical body 551.
- Example 7 As a modification of the sixth embodiment, a case where the entire demagnetizer 55 is a soft magnetic cylinder made of a soft magnetic material (when no magnetic field source is provided) can be considered.
- the outer surface of the molded body G is magnetically attracted to the inner peripheral surface of the soft magnetic cylinder and is in close contact (closely contacted or in contact). It becomes.
- the molded body G is shape-retained and protected by the soft magnetic cylindrical body, and its conveyance and handling become easy.
- a ring-shaped bonded magnet R can be obtained by taking out and magnetizing the molded body G cured and heat-treated together with the soft magnetic cylindrical body from the soft magnetic cylindrical body.
- the molded body G is removed from the soft magnetic cylindrical body by knockout by a punch or the like.
- Example 8 Another embodiment is shown in FIG.
- the soft magnetic cylindrical body of the seventh embodiment is used as the motor housing H. That is, it is a case where the compact G molded in the magnetic field in the mold 6 is directly fitted into the motor housing H made of a soft magnetic material.
- the molded product G was transferred to the motor housing H (housing) by raising the lower punch 62. During this transfer, the core 61 guides the molded body G only halfway.
- the molded body G is magnetically adsorbed in the motor housing H made of a soft magnetic material and is retained by the motor housing H.
- the molded body G When the outer peripheral surface of the molded body G contacts only a part of the inner peripheral surface of the motor housing H, the molded body G may be fixed in the motor housing H by using an adhesive or the like. In any case, the molded body G integrated with the motor housing H is cured and then magnetized to obtain a motor housing with magnets.
- a press-fitting process for directly press-fitting the molded body G into the motor housing H ( Also used as a discharge process).
- the step of press-fitting the ring-shaped bonded magnet R into the motor housing H can be omitted, and the tact time of the motor-equipped motor housing can be shortened.
- the motor housing H also serves as a means for conveying the molded body G while retaining its shape.
- Example 9 The manufacturing method of the field permanent magnet (anisotropic bonded magnet) described in the first embodiment may be changed as follows.
- Example 1 the filling process is performed in a state where the mold 1 is arranged in advance (position shown in FIG. 2 or FIG. 4). In this case, an alignment magnetic field is applied to the annular cavity c by the main permanent magnet 14 or the like. For this reason, the compound thrown into the annular cavity c adheres to the opening and inner peripheral surface of the annular cavity c by magnetic force, and smooth filling is hindered.
- the filling step is preferably performed in a state where no magnetic field is applied to the annular cavity c (this is referred to as “no magnetic field state”).
- no magnetic field state is easily realized by rotating the movable part of the mold 1 by a specific angle ( ⁇ S ) from the orientation arrangement state as shown in FIG.
- At least one specific angle ( ⁇ S ) always exists in the section [ ⁇ 1 , ⁇ 2 ] where ⁇ 1 ⁇ S ⁇ 2 (see FIG. 18).
- the rotation angle of the movable portion of the mold 1 is ⁇ 1 (for example, 0 °)
- the magnet is demagnetized by rotating counterclockwise (positive rotation) by the magnetic pole unit angle.
- the rotation angle at the time of arrangement was ⁇ 2 (for example, 90 °).
- the reason is as follows.
- the magnetic field that acts on the annular cavity c as the movable part of the mold 1 rotates changes continuously from the orientation arrangement ( ⁇ 1 ) to the demagnetization arrangement ( ⁇ 2 ).
- the orientation of the orientation magnetic field in the orientation arrangement ( ⁇ 1 ) and the direction of the demagnetization magnetic field in the demagnetization arrangement ( ⁇ 2 ) are reversed.
- the magnetic field continuously changes from a positive number to a negative number in the section [ ⁇ 1 , ⁇ 2 ].
- the magnetic field acting on the annular cavity c always has at least one boundary in the section [ ⁇ 1 , ⁇ 2 ] whose direction changes (that is, the zero point where the polarity of the magnetic field is switched). Will do. Moreover, actually, the magnetic field acting on the annular cavity c changes monotonically from the orientation arrangement ( ⁇ 1 ) to the demagnetization arrangement ( ⁇ 2 ). Therefore, one rotation angle ( ⁇ S ) at which the magnetic field becomes zero exists in the section [ ⁇ 1 , ⁇ 2 ].
- the arrangement of the mold 1 at this time is referred to as “no magnetic field arrangement”.
- the magnetic field in the mold 1 when in this magnetic field-free arrangement is indicated by a thick arrow in FIG.
- the magnetic field does not act at all on the annular cavity c when the mold 1 is in a magnetic field-free arrangement, between the adjacent main permanent magnets 14 via the intermediate yoke 13 between them. It can be seen that this is because the magnetic circuit is completely short-circuited.
- the reason why the magnetic field can be realized by the mold 1 is that if the mold 1 is placed in such a magnetic field in advance before the filling process, it is not affected by the magnetic field during the filling process.
- the compound or its preform (blank material) can be filled more smoothly into the annular cavity c.
- the present invention includes a filling preparation step of arranging the oriented magnetic pole body at a magnetic field-free position where no magnetic field is applied to the annular cavity before the filling step.
- the term “no magnetic field position” naturally includes not only the single position (rotation angle) at which no magnetic field acts on the annular cavity, but also its neighboring positions. In consideration of industrial production, any position that reflects the above-described purpose is sufficient. In the above example, it is sufficient that the rotation angle of the movable part of the mold 1 is close to ⁇ S during the filling preparation step.
- the present invention includes a discharge preparation step in which the orientation magnetic pole body is disposed at a magnetic field-free position where no magnetic field is applied to the annular cavity before the discharge step (after the demagnetization step).
- a molded object can be more smoothly discharged
- FIG. 18 shows an example of the relationship between the rotation angle of the movable part of the mold 1 and the magnetic field acting on the annular cavity c in the latter case.
- the correspondence between the rotation angle of the movable part of the mold 1 and each process is as follows.
- the filling process is performed in this state.
- the rotation angle of the movable part of the mold 1 changes from ⁇ S to ⁇ 1
- the mold 1 changes from the non-magnetic field arrangement Q S to the orientation arrangement Q 1 .
- Mold 1 demagnetization of the molded body begins around past the field-free placement Q S, substantially complete demagnetization step where mold 1 becomes demagnetized arrangement Q 2.
- the rotation angle of the movable part of the mold 1 changes from ⁇ 2 to ⁇ S again, and the mold 1 changes from the demagnetization arrangement Q S to the non-magnetic field arrangement Q S.
- the discharge process is performed immediately after the discharge preparation process is completed.
- the rotation angle of the movable part of the mold 1 is set to ⁇ S ⁇ ⁇ 1 (change I), ⁇ 1 ⁇ ⁇ 2 (change II), ⁇ 2 ⁇ ⁇ S (when manufacturing one molded body. It changes in three stages: Change III) And by repeating each process according to each step, a molded object and also a permanent magnet for field are produced quickly and efficiently.
- Example 10 (1) In the above-described Examples 1 to 9, a molded body is manufactured by compression molding the compound filled in the annular cavity c formed by the core 11 and the molding die 12 with the upper punch and the lower punch. explained. However, the contents described in the above embodiments are basically not limited to the case where a molded body is manufactured by compression molding, but can be similarly applied to the case where a molded body is manufactured by injection molding.
- a soft or molten magnet raw material is filled by injection into an annular cavity formed by a movable mold and a fixed mold (molding mold) for injection molding (filling step).
- An orientation magnetic field is applied to this magnet material in the same manner as in the above-described embodiment (orientation step).
- the mold is cooled in this state, a molded body in which the binder resin is cooled and solidified is obtained (molding process).
- the movable mold is retracted upward or sideward and the discharge mechanism provided in the fixed mold is operated, the molded body is discharged (discharge process).
- the binder resin has already been cooled and solidified, the molded body already has a suitable strength and hardly undergoes self-collapse.
- the demagnetization process is not necessarily performed, it is easy to press-fit the formed body into the cylindrical body in parallel with the discharge process (press-fit process).
- the molded body is a rare earth anisotropic bonded magnet and the thickness of the molded body is very thin, the molded body may undergo self-collapse or deformation due to its strong magnetic force. In such a case, it is effective to appropriately perform a demagnetization process and a demagnetization process after the molding process.
- thermoplastic resin when performing injection molding, it is preferable to use a thermoplastic resin as the binder resin. This is because the thermoplastic resin cools and solidifies within an extremely short time. In this case, the curing heat treatment and the like necessary for the thermosetting resin as described above become unnecessary.
- a manufacturing apparatus for obtaining a molded body by injection molding includes, for example, a mold composed of a movable mold and a fixed mold that form an annular cavity, and an even number of magnetic fields in the vicinity of the outer periphery of the mold.
- An anisotropic magnetic pole magnet comprising a permanent magnet including permanent magnets that are alternately reversed in direction and that can supply an orientation magnetic field to the annular cavity. It is preferable that a driving means for relatively moving the orientation magnetic pole body only in the circumferential direction is provided.
- the manufacturing apparatus provides a molding die composed of a movable die and a fixed die that form an annular cavity, and an even and even magnetic field direction in the vicinity of the outer periphery of the die. And a magnetic pole body including a permanent magnet including permanent magnets that are alternately reversed and can supply an orientation magnetic field to the annular cavity. It is provided with fitting means for fitting a molded body that can be molded into a cylindrical body that is disposed coaxially with the annular cavity and has an inner circumferential surface that can contact the outer circumferential surface of the molded body while being discharged from the annular cavity. This is preferable.
- the fitting means is preferably a press-fitting means for press-fitting the molded body into the cylinder.
- a part of the fixed mold serves as the press-fitting means, and a press-fitting process that also serves as a discharge process is performed by an operation of a discharge mechanism provided in the fixed mold.
- the present invention is not limited to the case where the annular anisotropic bonded magnet is manufactured by compression molding, and may be manufactured by injection molding.
- the mold used for the injection molding may be a vertical type or a horizontal type. Good.
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Abstract
Description
(1)本発明の異方性ボンド磁石の製造方法は、一種以上の希土類異方性磁石粉末とバインダ樹脂とを含む磁石原料を環状キャビティへ充填する充填工程と、永久磁石を磁場源とし該環状キャビティの外周囲に偶数均等にかつ磁場の向きを交互に逆転して配設された配向磁極体から該環状キャビティ内の磁石原料へ配向磁場を印加して、軟化状態または溶融状態にある該バインダ樹脂中で該希土類異方性磁石粉末を配向させる配向工程と、該配向工程中または該配向工程後の磁石原料を成形して円環状の成形体を得る成形工程と、該成形体を該環状キャビティから排出する排出工程と、を備える異方性ボンド磁石の製造方法であって、さらに、前記成形工程後で前記排出工程前に、前記成形体に対して前記配向磁極体を周方向にのみ相対移動させ、前記配向磁場による該成形体の磁化を打ち消す向きの減磁磁場を該配向工程時とは異極の配向磁極体から該成形体へ印加する減磁工程を備えることを特徴とする。
(1)上述の製造方法の他、ボンド磁石のタクトタイム短縮や低価格化は、次のような本発明の製造方法によっても実現可能である。
すなわち本発明は、一種以上の希土類異方性磁石粉末とバインダ樹脂とを含む磁石原料を環状キャビティへ充填する充填工程と、永久磁石を磁場源とし該環状キャビティの外周囲に偶数均等にかつ磁場の向きを交互に逆転して配設された配向磁極体から該環状キャビティ内の磁石原料へ配向磁場を印加して、軟化状態または溶融状態にある該バインダ樹脂中で該希土類異方性磁石粉末を配向させる配向工程と、該配向工程中または該配向工程後の磁石原料を成形して円環状の成形体を得る成形工程と、該成形体を該環状キャビティから排出する排出工程と、を備える異方性ボンド磁石の製造方法であって、前記排出工程は、前記環状キャビティと同軸上に配設され前記成形体の外周面に接し得る内周面を有する筒体へ、該成形体を該環状キャビティから排出しつつ嵌入する嵌入工程であることを特徴とする異方性ボンド磁石の製造方法であってもよい。
本発明は上述した異方性ボンド磁石の製造方法としてのみならず、その実施に適した製造装置としても把握できる。
(1)すなわち本発明は、円筒状または円柱状のコアと、該コアを包囲し該コアとの間で環状キャビティを形成する成形型と、該成形型の外周囲に近接して偶数均等にかつ磁場の向きを交互に逆転して配設され該環状キャビティへ配向磁場を供給し得る永久磁石を含む配向磁極体と、を備える異方性ボンド磁石の製造装置であって、さらに、前記環状キャビティと前記配向磁極体との円周上の対応位置のみを相対的に変更させる駆動手段を備えることを特徴とする円環状の異方性ボンド磁石の製造装置でもよい。
(1)円環状の成形体またはボンド磁石の周側面に形成される磁極数は、2以上(2、4、6、8、10など)である限り特に問わない。ボンド磁石が使用される機器の高性能化、効率化等を考慮すると、その磁極数は4以上(4、6、8、10など)であると好ましい。
11 コア
12 成形型
13 中間ヨーク
14 主要永久磁石(配向磁極体)
15 第1補助永久磁石
16 第2補助永久磁石
17 バックヨーク
c 円環状キャビティ
G 成形体
M 軟磁性筒体
磁石原料は、一種以上の希土類異方性磁石粉末とバインダ樹脂とからなる。具体的には例えば、希土類異方性磁石粉末と樹脂粉末との混合粉末、その混合粉末を加熱混練したコンパウンド、その混合粉末やコンパウンドを圧縮成形した予備成形体や希土類異方性磁石粉末と溶融した樹脂との混合体などである。ちなみに、磁石原料は、希土類異方性磁石粉末および樹脂のみならず、その他に潤滑剤、硬化剤、硬化助剤、界面活性剤等の添加剤を含んでもよい。
本発明に係る異方性ボンド磁石は、筒状または環状であれば、そのサイズ、磁気特性、用途等を問わない。代表的な用途はモーターの界磁である。このモーターには、直流(DC)モーター、交流(AC)モーター等がある。異方性ボンド磁石の配設位置は、回転子(ローター)側でも固定子(ステーター)側でも、固定子に対して内周側でも外周側でもよい。
(1)本発明に係る異方性ボンド磁石の一例として、4極DCブラシモーターの筐体内に配設される薄肉円環状の界磁用永久磁石を取りあげる。具体的にいうと、界磁用永久磁石は図1に示すような横断面をもつリング状ボンド磁石Rである。リング状ボンド磁石Rは、Nd-Fe-B系の希土類希土類異方性磁石粉末(適宜「磁石粉末」という。)とバインダ樹脂からなるコンパウンド(磁石原料)を充填、加熱、配向、圧縮、成形、熱硬化および着磁して得られる。このリング状ボンド磁石Rは、セミラジアル配向により円周側面に4つの磁極(A極~D極)が形成される。各磁極は主極部Ia、Ib、Ic、Idと、隣接する主極部間に形成される遷移部IIab、IIbc、IIcd、IIdaからなる。それぞれの主極部および遷移部におけるリング状ボンド磁石Rの構成粒子(磁石粒子)が配向する向き(磁化容易軸の向き)を、図1上に矢印で示した。
リング状ボンド磁石Rの製造方法等に関しては公知であり、例えば既述の特許文献3にも詳しく記載されている。ここでは本発明に関係する部分について主に説明する。つまり、永久磁石を配向磁場源として用いて磁場中成形した成形体を、保形しつつ排出できる金型または方法に関して詳しく説明する。
(1)本発明の製造方法に用いることができる金型1の横断面を図2に示した。なお図2には1個の金型1だけが示されているが、実際の製造装置のダイスには、そのコンパクトな金型1が縦横に複数配列される。これにより省スペース内で、成形体の複数個取りが可能となる。
他の実施例である金型2を図8および図9に示した。金型2は、金型1よりも内周側にある分割ラインl2を境界として、その内周部と外周部との相対回転を可能としたものである。本実施例ではその内周部を固定部とし、その外周部を可動部とした。図8には配向磁場を印加する際の金型2の配置(配向配置)を示した。図9には、減磁磁場を印加する際の金型2の配置(減磁配置)を示した。図9の減磁配置は、図8の配向配置を左に90°回転したものである。
他の実施例である金型3を図10に示した。金型3は、金型1または金型2でいうコア、成形型312および中間ヨーク313および非磁性材314を一体化した分割型31と、金型1または金型2でいう主要永久磁石、補助永久磁石およびバックヨークを一体化した分割型32とからなる。
他の実施例である金型4を図11および図12に示した。金型4は、上述の金型とは異なり分割されない。本実施例では、金型4と成形体Gとを相対回転させて、磁化した成形体Gに減磁磁場を印加している。図11は金型4自体を成形体Gに対して一磁極分(本実施例なら90°)回転させた場合である。図12は、逆に、成形体G自体を金型4に対して一磁極分(本実施例なら90°)回転させた場合である。この際の減磁磁場も、配向磁場と強さが同じで向きだけが正反対となり、磁化した成形体を効率的に減磁し得る。
他の実施例を図13に示した。本実施例は、金型5と、その上面側に載置した磁気シールド53と、さらにその上面側に載置した脱磁装置54とを備える。金型5は、円環状キャビティ内のコンパウンドを配向磁場中で圧縮成形するが、得られた成形体Gの減磁はしない。磁気シールド53は、金型5の円環状キャビティへ印加された配向磁場の脱磁装置54への漏洩を遮断する。この磁気シールド53は非磁性ステンレス鋼、アルミ、セラミックス等の非磁性材料からなる。なお、コア51にも磁気シールド53に対応した位置に磁気シールド部を形成すると好ましい。
他の実施例を図14に示した。本実施例も基本的に図13に示した実施例5と同様である。ただし、減磁装置55は脱磁装置54と異なり、図上の左右方向へ移動し得る。このため円筒体551に収納された成形体Gは、減磁(さらには脱磁)後に、減磁装置55と共に次工程へ搬送され得る。
実施例6の変形例として、脱磁装置55全体を軟磁性材からなる軟磁性円筒体とした場合(磁場源を設けない場合)が考えられる。この軟磁性円筒体内へ成形体Gが圧入または嵌入されると、成形体Gは外周面が軟磁性円筒体の内周面に磁気的に吸着されて密接状態(密着した状態または接した状態)となる。この場合成形体Gは、軟磁性円筒体によって保形および保護され、その搬送やハンドリングが容易となる。軟磁性円筒体と共にキュアー熱処理した成形体Gを、軟磁性円筒体から取り出して着磁すればリング状ボンド磁石Rが得られる。なお、成形体Gの軟磁性円筒体からの取り出しはパンチによるノックアウト等によりなされる。
他の実施例を図15に示した。本実施例は、実施例7の軟磁性円筒体をモーターハウジングHとした場合である。つまり、金型6内で磁場中成形した成形体Gを軟磁性材からなるモーターハウジングH内へ直接嵌入した場合である。成形体GのモーターハウジングH(筐体)への移送は下パンチ62を上昇させて行った。この移送中、コア61は途中までしか成形体Gをガイドしない。しかし、実施例7で述べたように、成形体Gは軟磁性材からなるモーターハウジングH内に磁気的に吸着され、モーターハウジングHによって保形される。
実施例1で説明した界磁用永久磁石(異方性ボンド磁石)の製造方法は次のように変更してもよい。
(1)上述した実施例1~9では、コア11と成形型12により形成される円環状キャビティcへ充填したコンパウンドを、上パンチおよび下パンチにより圧縮成形することにより成形体を製造する場合について説明した。もっとも、上記の実施例で説明した内容は、基本的に、圧縮成形により成形体を製造する場合に限らず、射出成形により成形体を製造する場合についても同様に該当し得る。
Claims (16)
- 一種以上の希土類異方性磁石粉末とバインダ樹脂とを含む磁石原料を環状キャビティへ充填する充填工程と、
永久磁石を磁場源とし該環状キャビティの外周囲に偶数均等にかつ磁場の向きを交互に逆転して配設された配向磁極体から該環状キャビティ内の磁石原料へ配向磁場を印加して、軟化状態または溶融状態にある該バインダ樹脂中で該希土類異方性磁石粉末を配向させる配向工程と、
該配向工程中または該配向工程後の磁石原料を成形して円環状の成形体を得る成形工程と、
該成形体を該環状キャビティから排出する排出工程と、
を備える異方性ボンド磁石の製造方法であって、
さらに、前記成形工程後で前記排出工程前に、前記成形体に対して前記配向磁極体を周方向にのみ相対移動させ、前記配向磁場による該成形体の磁化を打ち消す向きの減磁磁場を該配向工程時とは異極の配向磁極体から該成形体へ印加する減磁工程を備えることを特徴とする異方性ボンド磁石の製造方法。
- 前記減磁工程は、前記成形体に対して配置された前記配向磁極体の磁極を反転させるために必要な最小の角度である磁極単位角の奇数倍だけ、前記配向工程時から該配向磁極体を該成形体に対して相対回転させる工程である請求項1に記載の異方性ボンド磁石の製造方法。
- 前記排出工程は、前記環状キャビティと同軸上に配設され前記成形体の外周面に接し得る内周面を有する筒体へ、該成形体を該環状キャビティから排出しつつ圧入する圧入工程である請求項1または2に記載の異方性ボンド磁石の製造方法。
- 一種以上の希土類異方性磁石粉末とバインダ樹脂とを含む磁石原料を環状キャビティへ充填する充填工程と、
永久磁石を磁場源とし該環状キャビティの外周囲に偶数均等にかつ磁場の向きを交互に逆転して配設された配向磁極体から該環状キャビティ内の磁石原料へ配向磁場を印加して、軟化状態または溶融状態にある該バインダ樹脂中で該希土類異方性磁石粉末を配向させる配向工程と、
該配向工程中または該配向工程後の磁石原料を成形して円環状の成形体を得る成形工程と、
該成形体を該環状キャビティから排出する排出工程と、
を備える異方性ボンド磁石の製造方法であって、
前記排出工程は、前記環状キャビティと同軸上に配設され前記成形体の外周面に接し得る内周面を有する筒体へ、該成形体を該環状キャビティから排出しつつ嵌入する嵌入工程であることを特徴とする異方性ボンド磁石の製造方法。 - 前記嵌入工程中または前記嵌入工程後に、前記筒体内に嵌入された成形体へ前記配向磁場による磁化を打ち消す向きの脱磁磁場を印加する脱磁工程を備える請求項4に記載の異方性ボンド磁石の製造方法。
- 前記嵌入工程は、前記成形体を前記筒体へ圧入する圧入工程である請求項4または5に記載の異方性ボンド磁石の製造方法。
- 前記成形工程は、圧縮成形工程または射出成形工程である請求項1または4に記載の異方性ボンド磁石の製造方法。
- さらに、前記充填工程前に、前記環状キャビティに磁場を及ぼさない無磁場位置に前記配向磁極体を配置する充填準備工程を備える請求項1~7のいずれかに記載の異方性ボンド磁石の製造方法。
- さらに、前記排出工程前に、前記環状キャビティに磁場を及ぼさない無磁場位置に前記配向磁極体を配置する排出準備工程を備える請求項1~8いずれかに記載の異方性ボンド磁石の製造方法。
- 前記筒体は、磁性材からなる磁性筒体である請求項3~9のいずれかに記載の異方性ボンド磁石の製造方法。
- 前記磁性筒体は、電動機のヨークである請求項10に記載の異方性ボンド磁石の製造方法。
- 円筒状または円柱状のコアと、
該コアを包囲し該コアとの間で環状キャビティを形成する成形型と、
該成形型の外周囲に近接して偶数均等にかつ磁場の向きを交互に逆転して配設され該環状キャビティへ配向磁場を供給し得る永久磁石を含む配向磁極体と、
を備える異方性ボンド磁石の製造装置であって、
さらに、前記環状キャビティに対して前記配向磁極体を周方向にのみ相対移動させる駆動手段を備えることを特徴とする円環状の異方性ボンド磁石の製造装置。 - 円筒状または円柱状のコアと、
該コアを包囲し該コアとの間で環状キャビティを形成する成形型と、
該成形型の外周囲に近接して偶数均等にかつ磁場の向きを交互に逆転して配設され該環状キャビティへ配向磁場を供給し得る永久磁石を含む配向磁極体と、
を備える異方性ボンド磁石の製造装置であって、
さらに、前記環状キャビティ内で成形され得る成形体を、該環状キャビティと同軸上に配設され該成形体の外周面に接し得る内周面を有する筒体へ、該環状キャビティから排出しつつ嵌入する嵌入手段を備えることを特徴とする円環状の異方性ボンド磁石の製造装置。 - 環状キャビティを形成する可動型と固定型からなる成形型と、
該成形型の外周囲に近接して偶数均等にかつ磁場の向きを交互に逆転して配設され該環状キャビティへ配向磁場を供給し得る永久磁石を含む配向磁極体と、
を備える異方性ボンド磁石の製造装置であって、
さらに、前記環状キャビティに対して前記配向磁極体を周方向にのみ相対移動させる駆動手段を備えることを特徴とする円環状の異方性ボンド磁石の製造装置。 - 環状キャビティを形成する可動型と固定型からなる成形型と、
該成形型の外周囲に近接して偶数均等にかつ磁場の向きを交互に逆転して配設され該環状キャビティへ配向磁場を供給し得る永久磁石を含む配向磁極体と、
を備える異方性ボンド磁石の製造装置であって、
さらに、前記環状キャビティ内で成形され得る成形体を、該環状キャビティと同軸上に配設され該成形体の外周面に接し得る内周面を有する筒体へ、該環状キャビティから排出しつつ嵌入する嵌入手段を備えることを特徴とする円環状の異方性ボンド磁石の製造装置。 - 前記嵌入手段は、前記成形体を前記筒体へ圧入する圧入手段である請求項13または15に記載の円環状の異方性ボンド磁石の製造装置。
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| JPWO2012105226A1 (ja) * | 2011-02-03 | 2014-07-03 | パナソニック株式会社 | 異方性ボンド磁石の製造方法およびモータ |
| JP5929153B2 (ja) * | 2011-12-14 | 2016-06-01 | 日産自動車株式会社 | 界磁極用磁石体の製造装置およびその製造方法 |
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2011
- 2011-04-05 KR KR1020127028899A patent/KR101390027B1/ko active Active
- 2011-04-05 CN CN201180017888.4A patent/CN102822916B/zh active Active
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- 2011-04-05 EP EP11765923.5A patent/EP2557577B1/en active Active
- 2011-04-05 WO PCT/JP2011/058644 patent/WO2011126026A1/ja not_active Ceased
- 2011-04-05 CN CN201180017988.7A patent/CN102844826B/zh active Active
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- 2011-04-05 EP EP11765926.8A patent/EP2562775B1/en active Active
- 2011-04-05 KR KR1020127028916A patent/KR101407837B1/ko active Active
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013172585A (ja) * | 2012-02-22 | 2013-09-02 | Mitsubishi Electric Corp | シャフト型リニアモータ可動子、永久磁石、リニアモータ、磁場中成形装置、シャフト型リニアモータ可動子の製造方法 |
| US9818521B2 (en) | 2013-12-13 | 2017-11-14 | Ntn Corporation | Compression-bonded magnet with case and method for producing the same |
| US9812239B2 (en) | 2014-01-21 | 2017-11-07 | Jtekt Corporation | Core manufacturing device |
Also Published As
| Publication number | Publication date |
|---|---|
| KR20120137428A (ko) | 2012-12-20 |
| US9799446B2 (en) | 2017-10-24 |
| EP2557577A4 (en) | 2014-04-02 |
| KR101390027B1 (ko) | 2014-04-29 |
| KR101407837B1 (ko) | 2014-06-16 |
| US20130093121A1 (en) | 2013-04-18 |
| US20170221631A1 (en) | 2017-08-03 |
| KR20120137427A (ko) | 2012-12-20 |
| CN102822916A (zh) | 2012-12-12 |
| JP5516723B2 (ja) | 2014-06-11 |
| JPWO2011126023A1 (ja) | 2013-07-11 |
| WO2011126026A1 (ja) | 2011-10-13 |
| JP5397540B2 (ja) | 2014-01-22 |
| EP2557577B1 (en) | 2016-08-24 |
| US9666341B2 (en) | 2017-05-30 |
| CN102822916B (zh) | 2014-09-03 |
| JPWO2011126026A1 (ja) | 2013-07-11 |
| CN102844826A (zh) | 2012-12-26 |
| EP2562775A4 (en) | 2014-04-09 |
| EP2557577A1 (en) | 2013-02-13 |
| EP2562775A1 (en) | 2013-02-27 |
| EP2562775B1 (en) | 2017-11-01 |
| CN102844826B (zh) | 2016-09-14 |
| US20130069747A1 (en) | 2013-03-21 |
| US9312055B2 (en) | 2016-04-12 |
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