WO2011155203A1 - Composition cosmétique - Google Patents
Composition cosmétique Download PDFInfo
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- WO2011155203A1 WO2011155203A1 PCT/JP2011/003256 JP2011003256W WO2011155203A1 WO 2011155203 A1 WO2011155203 A1 WO 2011155203A1 JP 2011003256 W JP2011003256 W JP 2011003256W WO 2011155203 A1 WO2011155203 A1 WO 2011155203A1
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- cosmetic composition
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- cosmetic
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0241—Containing particulates characterized by their shape and/or structure
- A61K8/025—Explicitly spheroidal or spherical shape
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/347—Phenols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
- A61K8/66—Enzymes
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/67—Vitamins
- A61K8/678—Tocopherol, i.e. vitamin E
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/86—Polyethers
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q17/00—Barrier preparations; Preparations brought into direct contact with the skin for affording protection against external influences, e.g. sunlight, X-rays or other harmful rays, corrosive materials, bacteria or insect stings
- A61Q17/005—Antimicrobial preparations
Definitions
- the present invention relates to a cosmetic composition.
- Patent Document 1 describes a liquid deodorant containing an unsaturated fatty acid as an essential component and containing a bactericide, an antioxidant, an aqueous medium and the like.
- the conventional cosmetic composition can be applied even if the sticky feeling immediately after application is suppressed. It has been found that there is a new problem that the feeling of sliminess of time has not been solved at all, and is rather strongly recognized. In addition, there is still room for improvement in terms of suppressing the sticky feeling even after the application time has elapsed.
- the present invention has been completed on the basis of such new knowledge that has not been known so far, and a cosmetic composition that can reduce the sticky feeling during the application while reducing the sticky feeling at the time of application. It provides things.
- the present invention is a method for using cosmetics in which a cosmetic composition is applied to the skin.
- the present inventors have found that the above problem can be solved by combining tris (hydroxymethyl) aminomethane, a specific bactericide, and a specific antioxidant.
- a cosmetic composition capable of reducing the sticky feeling during application and suppressing the sticky feeling over time.
- Tris (hydroxymethyl) aminomethane is widely known as a buffering agent, and is also known as a component that reduces odor due to sebum (Patent Document 2).
- Patent Document 2 discloses that the preparation containing tris (hydroxymethyl) aminomethane is safe even if it is in contact with the human body, but does not disclose the use as a cosmetic.
- there has been no conventional example focusing on using tris (hydroxymethyl) aminomethane to improve the feeling of use of cosmetics.
- tris (hydroxymethyl) aminomethane, a specific (B) fungicide and (C) antioxidant and (D) water, and a medium containing ethanol By combining them, the usability is improved.
- the content of the component (A) is 0.01% by mass or more, more preferably 0.05% by mass or more, and still more preferably 0.25%, based on the total composition, from the viewpoint of reducing the feeling of stickiness during coating. It is at least mass%. Moreover, from a viewpoint of reducing the stickiness after application
- the fungicide is a group consisting of triclosan, isopropylmethylphenol (IPMP), silver-supported inorganic particles, lysozyme chloride, benzalkonium chloride, cetylpyridinium chloride (CPC), 3,4,4′-trichlorocarbanilide It is at least 1 or more types chosen from.
- the silver-supporting inorganic particles include silver-supporting zeolite and silver-supporting cancrinite.
- triclosan, isopropylmethylphenol (IPMP), and benzalkonium chloride are preferable from the viewpoint of the durability of the smooth feeling and the less wetness. These fungicides may be used alone or in combination of two or more.
- the content of the component (B) is preferably 0.001% by mass or more, particularly 0.01% by mass or more, based on the total composition, from the viewpoint of the bactericidal effect. Further, from the viewpoint of skin irritation, 5.0% by mass or less, particularly 1.0% by mass or less is preferable with respect to the total composition.
- the content ratio of component (A): component (B) is preferably 5000: 1 to 1: 500 from the viewpoints of bactericidal effect and low sliminess, and particularly 40: 1 to 1: from the viewpoint of low sliminess. 4, more preferably 20: 1 to 1: 4. In particular, 10: 1 to 1: 2 is preferable.
- antioxidants include dibutylhydroxytoluene (BHT); vitamin E such as butylhydroxyanisole and ⁇ tocopherol, and derivatives thereof; thiotaurine, evening primrose extract, ⁇ -carotene, catechin compounds, flavonoid compounds, polyphenol compounds can do.
- the catechin compound can be used as a green tea extract or the like.
- dibutylhydroxytoluene (BHT) or ⁇ tocopherol is preferable from the viewpoint of improving the feeling in use.
- These antioxidants may be used individually by 1 type, and may combine 2 or more types.
- the content of the component (C) is 0.001% by mass or more, particularly 0.005% by mass or more in the entire composition from the viewpoint of preventing oxidation, and 1% by mass or less from the viewpoint of reducing stickiness after coating.
- the content is preferably 0.5% by mass or less.
- Component (D) A medium in which water and ethanol are in a mass ratio of 99: 1 to 10:90 is a cosmetic medium of the cosmetic composition of the present invention. Thereby, a fresh feeling of use is obtained and a sticky feeling can be reduced. Moreover, quick-drying and a refreshing feeling can be improved by using ethanol together.
- the mass ratio of water to ethanol is preferably 95: 5 to 70:30.
- the total amount of the mixed medium is (D) the content of the medium.
- Water is a cosmetic medium of the cosmetic composition of the present invention, and is preferably 50% by mass or more, more preferably 60% by mass or more in the entire composition. Preferably it is 99 mass% or less as an upper limit, More preferably, it is 98 mass% or less.
- the pH of the cosmetic composition of the present invention is preferably 5 or more and 10.5 or less from the viewpoint of preventing irritation to the skin. Moreover, from a viewpoint of reducing stickiness, More preferably, it is 6 or more, More preferably, it is 6.5 or more. On the other hand, it is more preferably 9 or less, and still more preferably 8.5 or less, from the viewpoint of suppressing the feeling of stickiness during application.
- Nonionic surfactants include, for example, polyoxyalkylene sorbitan fatty acid esters, polyoxyalkylene sorbit fatty acid esters, polyoxyalkylene glycerin fatty acid esters, polyoxyalkylene fatty acid esters, polyoxyalkylene alkyl ethers , Polyoxyalkylene alkyl phenyl ethers, polyoxyalkylene (hardened) castor oils, sucrose fatty acid esters, polyglycerin alkyl ethers, polyglycerin fatty acid esters, fatty acid alkanolamides, alkyl glycosides and the like.
- polyoxyalkylene alkyl ethers alkyl glycosides, polyoxyalkylene C8-C20 fatty acid esters, polyoxyethylene sorbitan fatty acid esters, polyoxyethylene hydrogenated castor oil, and fatty acid alkanolamides are preferred.
- polyoxyalkylene alkyl ethers include polyoxyethylene hexyl decyl ether, polyoxyethylene octyl decyl ether, polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene.
- Polyoxyethylene alkyl ethers such as nonylphenyl ether, polyoxypropylene alkyl ether, polyoxyethylene, and polyoxypropylene alkyl ether are preferred.
- alkyl glycosides those having an alkyl group having 8 to 14 carbon atoms and a sugar (glucose) condensation degree of 1 to 2 are preferable.
- fatty acid alkanolamide those having an acyl group having 8 to 18 carbon atoms, particularly 10 to 16 carbon atoms are preferable, and either a monoalkanolamide or a dialkanolamide may be used, but a hydroxyalkyl group having 2 to 3 carbon atoms may be used. What has is preferable.
- fatty acid alkanolamides include oleic acid diethanolamide, palm kernel oil fatty acid diethanolamide, coconut oil fatty acid diethanolamide, lauric acid diethanolamide, polyoxyethylene coconut oil fatty acid monoethanolamide, coconut oil fatty acid monoethanolamide, laurin Acid monoisopropanolamide, lauric acid monoethanolamide, palm kernel oil fatty acid methylethanolamide, coconut oil fatty acid methylethanolamide and the like can be mentioned.
- nonionic surfactants may be used alone or in combination of two or more.
- polyoxyalkylene alkyl ethers more specifically, polyoxyethylene lauryl ether is preferable from the viewpoint of reducing stickiness immediately after coating.
- the content of the component (E) is 0.05% by weight or more, particularly 0.1% by weight or more in the total composition, from the viewpoint of reducing stickiness immediately after coating, from the viewpoint of reducing stickiness after 3 hours of coating, It is preferable to contain 2% by mass or less, particularly 1% by mass or less.
- Polypropylene glycols can moderately moisturize the skin as a moisturizing agent.
- examples of polypropylene glycols include dipropylene glycol, tripropylene glycol, and higher polypropylene glycols.
- the preferred degree of polymerization of the polypropylene glycols is 2-12.
- the content of the component (F) is 0.1% by mass or more, particularly 0.5% by mass or more in the whole composition from the viewpoint of reducing stickiness immediately after coating, and 5% from the viewpoint of non-stickiness after coating. It is preferable to contain 3 mass% or less, especially 3 mass% or less.
- Component (G) (G) By blending a water-soluble polymer, spherical powder, oily substance, etc. can be stably present while being uniformly dispersed, and usability can be improved. In addition, it is possible to improve the convenience such as imparting an appropriate viscosity to an appropriate cosmetic composition, not dripping down when taken on the hand, and being easy to adjust when stretched to the skin.
- any of natural polymers, semi-synthetic polymers, and synthetic polymers can be used.
- natural polymers include xanthan gum, carrageenan, alginic acid and the like.
- semisynthetic polysaccharide polymers include modified polysaccharides such as hydroxycellulose, hydroxypropylcellulose, methylcellulose, hydroxymethylcellulose, and cationized cellulose.
- Synthetic polymers include carbomers (cross-linked polyacrylic acid), polyacrylic acid, polyacrylic acid Na, acrylic polymers such as acrylic acid / alkyl methacrylate copolymers; polyvinyl pyrrolidone, polyvinyl alcohol, cationized polyvinyl pyrrolidone, etc. It is done. Of these, carbomer, acrylic acid / alkyl methacrylate copolymer, hydroxypropylcellulose, carboxymethylcellulose and the like are preferable.
- crosslinked polyacrylic acid examples include Carbopol 910, Carbopol 934, Carbopol 940, Carbopol 941, Carbopol 980, Carbopol 981 (above Lubrizol Advanced Materials, Inc.), etc., acrylic acid / methacrylic acid
- alkyl copolymers examples include Carbopol 1382, Carbopol ETD2020, PEMULEN TR-1, and PEMULEN TR-2 (manufactured by Lubrizol Advanced Materials, Inc.), and the like.
- Examples of commercially available products of HPC-H (manufactured by Nippon Soda) and sodium carboxymethyl cellulose examples include CMC Daicel (manufactured by Daicel Chemical Industries). Of these, sodium carboxymethylcellulose is particularly preferable.
- the content of the component (G) is 0.01% by weight or more, particularly 0.05% by weight or more in the total composition, from the viewpoint of reducing stickiness immediately after coating, from the viewpoint of reducing stickiness after coating. It is preferable to contain 3% by mass or less, particularly 1% by mass or less.
- the spherical powder can give a smooth feeling.
- the spherical powder refers to a powder having a substantially spherical shape, and does not need to be a perfect spherical shape.
- spherical powder a spherical powder or an inorganic powder made of an organic synthetic polymer usually obtained by suspension polymerization or the like can be used.
- nylon resins polystyrene resins, polyethylene resins, polymethyl methacrylate resins, polyurethane resins, phenol resins, polymethylsilsesquion sun, silicone resins such as organopolysiloxane elastomers, crosslinked (meth) acrylic acid
- examples include synthetic polymer powders such as ester resins.
- the inorganic powder include powders such as silicic anhydride.
- nylon resin SP-500 (manufactured by Toray Industries, Inc.), etc .
- polystyrene resin fine pearl (manufactured by Sumitomo Chemical Co., Ltd.), Techpolymer SB (manufactured by Sekisui Plastics Co., Ltd.), fine powder SGP (soken chemical) Etc.); polyethylene beads, flow beads (manufactured by Sumitomo Seika), etc .
- polymethyl methacrylate resins such as Matsumoto Microsphere M (Matsumoto Yushi Seiyaku), Techpolymer MB (manufactured by Sekisui Chemicals), Fine Powder MP (manufactured by Soken Chemical Co., Ltd.), etc .
- silicone resins such as KMP-590 (manufactured by Shin-Etsu Chemical Co., Ltd.), Tospearl 130, Tospearl 145, Tospearl 2000B (above GE Toshiba Silicone), cross-
- KMP-590 manufactured by Shin-Etsu Chemical Co., Ltd.
- (lauryl methacrylate / sodium methacrylate) crosspolymer are preferred. One or two or more of these can be used.
- the spherical powder may be subjected to hydrophobic treatment such as silicone treatment, fluorine treatment, metal soap treatment, and fatty acid treatment.
- the particle size of the spherical powder is preferably in the range of 0.5 to 30 ⁇ m in which 60% by mass or more of the total powder is present in order to improve the skin feel, and the powder having a particle size of 1 to 10 ⁇ m. Is more preferably 80% by mass or more of the total powder.
- a powder with a particle size of less than 0.5 ⁇ m has little effect on the feel of the skin, or is preferably less because it gives a squeaky discomfort, and a powder with a particle size of more than 30 ⁇ m is mixed. Is better. Therefore, the amount of these powders is preferably less than 40% by mass of the total powder, and more preferably 10% by mass or less. Further, from the viewpoint of skin feel, it is desirable that a powder having a particle size of 200 ⁇ m or more is not substantially contained.
- the content of the component (H) is 0.1% by mass or more, particularly 1% by mass or more in the entire composition from the viewpoint of improving the touch, and 40% by mass or less, particularly 20% from the viewpoint of not becoming whitish after application. It is preferable to contain it by mass% or less.
- a moisturizing component in addition to the above essential components, a moisturizing component, an anti-inflammatory agent, a whitening agent, an ultraviolet absorber, an antiperspirant, a fragrance, etc., as necessary, as long as the effects of the present invention are not impaired.
- other components that are usually blended in cosmetics may be blended.
- moisturizing ingredients include 1,3-butylene glycol, isoprene glycol, polyethylene glycols, glycerin, sorbitol, lactic acid, glycine betaine, amino acids, N-amidino-L-proline, ceramide, and cholesteryl ester.
- Anti-inflammatory agents include glycyrrhizinate, ⁇ -glycyrrhetinic acid, allantoin, indomethacin, guaiazulene, guaiazulene sulfonate, and the like.
- vitamin C derivatives ascorbic acid magnesium phosphate ester, etc.
- arbutin as whitening agents and UV care agents, vitamin C derivatives (ascorbic acid magnesium phosphate ester, etc.), arbutin, kojic acid, chamomile extract, ethylhexyl methoxycinnamate, dimethoxybenzylidene dioxoimidazolidinepropionate 2-ethylhexyl, salicylate octyl, oxybenzone Etc.
- antiperspirants examples include aluminum chloride, chlorohydroxyaluminum, aluminum lactate, allantoin aluminum derivatives, zinc p-phenolsulfonate, aluminum-zirconium-chlorohydrex-glycine complex (AZG), and the like.
- the acid component normally used for cosmetics is mentioned.
- Specific examples of such acid components include hydroxy acids such as citric acid, tartaric acid, malic acid, lactic acid and glycolic acid, amino acids such as glutamic acid and aspartic acid, dicarboxylic acids such as malonic acid, succinic acid and adipic acid, hydrochloric acid, Examples include inorganic acids such as phosphoric acid.
- base components such as alkali metal carbonates, alkali metal hydroxides, inorganic bases such as ammonia, alkanolamines such as monoethanolamine, triethanolamine, and aminomethylpropanediol can also be used.
- these base components may increase the stickiness during coating and the stickiness over time.
- the tris (hydroxymethyl) aminomethane of the component (A) of the present invention also has a function as a base component. Therefore, it is preferable that the content of these base components is small.
- the cosmetic composition of the present invention is used by applying to the skin, for example.
- the cosmetic composition may be taken in hand or applied in a woven fabric or non-woven fabric. Specifically, it can be used by being filled into a pump mist container or a roll-on container, or impregnated into a woven fabric or non-woven fabric and used as a sheet-like cosmetic.
- a commonly used pump container for mist spraying as shown in FIG. 1 can be used.
- the pump mist container for example, a commonly used pump container for mist spraying as shown in FIG. 1 can be used.
- By filling and using such a container it is not necessary to spread the composition by hand, and the application to the head or the whole body becomes simple. Further, since it is sprayed and applied to the skin in the form of a mist, it can be uniformly applied over a wide range, so that even if the application amount is large, no stickiness or stickiness is felt and a good feeling is given.
- the roll-on container for example, a roll-on container that is used for general purposes can be used, as shown in FIG.
- a roll-on container that is used for general purposes can be used, as shown in FIG.
- Such a container is filled, and the tip roll is applied to the skin and rolled.
- the tip roll is applied to the skin and rolled.
- the present composition is less sticky and sticky, it feels good even when applied in a concentrated manner.
- the cosmetic composition of the present invention can also be used as a sheet-like cosmetic material by impregnating a sheet base material with a liquid cosmetic material.
- a sheet base material any of natural fiber non-woven fabrics and woven fabrics, synthetic fiber non-woven fabrics and woven fabrics, and mixed non-woven fabrics and woven fabrics can be used. Specifically, for example, rayon, acetate, acrylic, polyester, polyethylene, polypropylene, polyurethane, polyamide, cotton, cupra, and non-woven fabrics or woven fabrics of these blends, wet or dry pulp sheets, thermoplastic resins (polyethylene, polypropylene) Pulp sheet reinforced with polyethylene terephthalate, etc.).
- a sheet base material mainly composed of pulp, rayon, lyocell, cotton, polyethylene, polyethylene terephthalate, and cupra is preferable in terms of excellent usability and transferability of active ingredients to the skin.
- the production method of the sheet base material is not particularly limited, and each purpose, sheet base, such as spun lace type, thermal bond type, immersion bonding type, needle punch type, spun bond type, stitch bond type, and melt blown type It is possible to select appropriately according to the material quality, the use site and the like.
- the sheet base material may be composed of only one sheet, or may be composed of two or more sheets.
- the pulp it is preferable to use a thin pulp in order to achieve both softness and strength.
- the pulp reinforced with a thermoplastic resin can be given an appropriate thickness (bulk) by embossing treatment, and the skin It is preferable because it does not get wet too much.
- the impregnation rate of the cosmetic composition impregnated into the sheet base material is preferably 20 to 700 parts by weight, particularly 150 to 700 parts by weight with respect to 100 parts by weight of the sheet base. 500 parts by weight is preferred.
- the sheet-like cosmetic is preferably a puff having a side of 2 to 5 cm or a sheet cut for a paper towel of about 10 to 30 cm because it is easy to use. Any container can be used as long as it can be sealed, and a stationary box or a portable bag-like one is preferably used.
- the cosmetic-containing sheet is stored in these containers as they are, or folded or rolled up.
- the cosmetic-containing sheet may be packaged by storing several to several hundred sheets in a single container, or may be individually packaged.
- the sheet-like cosmetic is used by directly wiping the skin such as the face, arms and neck. There are no restrictions on the place and time of use, and it can be suitably used at any time, either outdoors or indoors. Since the cosmetic-containing sheet of the present invention is excellent in non-stickiness after wiping and the durability of the smooth feeling, it can maintain a comfortable skin feel when used before going out or when going out, which is particularly likely to sweat. .
- the dispersion was poured into a four-necked flask and purged with nitrogen for 30 minutes while stirring. The temperature inside the flask was heated to 80 ° C. with an oil bath. After reaching 80 ° C., polymerization was performed for 5 hours, and then cooled to room temperature. The dispersion of polymerized particles was neutralized by adding 3.9 g of 1N NaOH to obtain a resin particle dispersion. The resin particle dispersion was freeze-dried and water was dried to obtain a crosslinked (meth) acrylate resin powder (average particle size 2.2 ⁇ m).
- Non-smooth evaluation criteria 6 Not very slippery 5: Almost non-slippery 4: Not very slippery 3: Neither can be said 2: Slightly slippery 1: Slightly slippery
- Examples 25 to 29 Each component shown in Table 3 was uniformly mixed by a conventional method so that the total amount was 100 (% by mass) to prepare a deodorant agent. The obtained deodorant agent was used in each of the following usage forms. Further, the sheet-shaped cosmetic was used after impregnating the sheet base material with an impregnation ratio of 500% and a liquid composition. The pH of the deodorant was measured with HORIBA pH METER F-22 and is shown in Table 3 together. [Pumping container] A container having a discharge diameter of 3 mm was used (manufactured by Takemoto container: P-27 one-touch cap). [Pump Mist Container] The container shown in FIG.
- Non-smooth evaluation criteria 6 Not very slippery 5: Almost non-slippery 4: Not very slippery 3: Neither can be said 2: Slightly slippery 1: Slightly slippery
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- Life Sciences & Earth Sciences (AREA)
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- Veterinary Medicine (AREA)
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Abstract
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201180027766.3A CN102933196B (zh) | 2010-06-09 | 2011-06-09 | 化妆品组合物 |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2010-131878 | 2010-06-09 | ||
| JP2010131878 | 2010-06-09 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2011155203A1 true WO2011155203A1 (fr) | 2011-12-15 |
Family
ID=45097818
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2011/003256 Ceased WO2011155203A1 (fr) | 2010-06-09 | 2011-06-09 | Composition cosmétique |
Country Status (4)
| Country | Link |
|---|---|
| JP (1) | JP5771073B2 (fr) |
| CN (1) | CN102933196B (fr) |
| MY (1) | MY158441A (fr) |
| WO (1) | WO2011155203A1 (fr) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013108736A1 (fr) * | 2012-01-20 | 2013-07-25 | 花王株式会社 | Composition cosmétique |
| JP2017178846A (ja) * | 2016-03-30 | 2017-10-05 | 小林製薬株式会社 | 外用組成物 |
| GB2576637A (en) * | 2018-08-15 | 2020-02-26 | Henkel Ag & Co Kgaa | Tris(hydroxymethyl)aminomethane or its salts as an active substance for reducing sweat secretion |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP5548117B2 (ja) * | 2010-12-28 | 2014-07-16 | 花王株式会社 | 化粧料含有シート |
| JP5965803B2 (ja) * | 2012-09-27 | 2016-08-10 | 株式会社マンダム | デオドラント組成物及びデオドラント剤 |
| JP6401093B2 (ja) * | 2014-04-03 | 2018-10-03 | ライオン株式会社 | デオドラント組成物 |
| JP6472978B2 (ja) * | 2014-10-28 | 2019-02-20 | 花王株式会社 | シート状化粧料 |
| JP6630533B2 (ja) * | 2014-12-25 | 2020-01-15 | ライオン株式会社 | デオドラント組成物 |
| JP6413815B2 (ja) * | 2015-02-06 | 2018-10-31 | ライオン株式会社 | 液体口腔用組成物 |
| JP6465701B2 (ja) * | 2015-03-10 | 2019-02-06 | 株式会社コーセー | 油性固形化粧料 |
| JP6468891B2 (ja) * | 2015-03-10 | 2019-02-13 | 株式会社コーセー | 油性メイクアップ化粧料 |
| JP6465700B2 (ja) * | 2015-03-10 | 2019-02-06 | 株式会社コーセー | ゲル状口唇化粧料 |
| JP6644606B2 (ja) * | 2015-03-30 | 2020-02-12 | 株式会社コーセー | 液状油性化粧料 |
| JP6650745B2 (ja) * | 2015-12-14 | 2020-02-19 | 花王株式会社 | 液状皮膚化粧料組成物 |
| JP6982305B2 (ja) * | 2017-12-06 | 2021-12-17 | 株式会社ダリヤ | 皮膚用化粧料 |
| IL258559A (en) | 2018-04-09 | 2018-05-31 | Noyberg Idan | Liquid timer |
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| US5650142A (en) * | 1995-09-27 | 1997-07-22 | Church & Dwight Co., Inc. | Bicarbonate-containing deodorant cosmetic stick compositions |
| US5863524A (en) * | 1997-03-26 | 1999-01-26 | Church & Dwight Co., Inc. | Transparent bicarbonate salt containing deodorant cosmetic stick product |
| EP1446090A2 (fr) * | 2001-11-13 | 2004-08-18 | The Procter & Gamble Company | Compositions contenant des enzymes stabilisees a l'aide de certains osmoprotecteurs et methodes d'utilisation de ces compositions dans des soins d'hygiene personnelle |
| JP2003221328A (ja) * | 2002-01-29 | 2003-08-05 | Soken Kk | 皮膚健全化剤 |
| JP5139639B2 (ja) * | 2006-03-03 | 2013-02-06 | 花王株式会社 | 消臭剤組成物 |
| JP5320016B2 (ja) * | 2008-10-23 | 2013-10-23 | 株式会社 資生堂 | 皮膚外用剤 |
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- 2011-06-09 WO PCT/JP2011/003256 patent/WO2011155203A1/fr not_active Ceased
- 2011-06-09 CN CN201180027766.3A patent/CN102933196B/zh not_active Expired - Fee Related
- 2011-06-09 MY MYPI2012004694A patent/MY158441A/en unknown
- 2011-06-09 JP JP2011128811A patent/JP5771073B2/ja active Active
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| JPH0597641A (ja) * | 1990-04-04 | 1993-04-20 | Bristol Myers Squibb Co | 透明な発汗防止剤スチツク |
| JP2006076997A (ja) * | 2004-08-09 | 2006-03-23 | Kao Corp | 液状デオドラント剤 |
| JP2006320711A (ja) * | 2005-04-21 | 2006-11-30 | Kao Corp | 消臭剤 |
| JP2009028071A (ja) * | 2007-07-24 | 2009-02-12 | Kao Corp | 水性消臭剤組成物 |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2013108736A1 (fr) * | 2012-01-20 | 2013-07-25 | 花王株式会社 | Composition cosmétique |
| CN104066421A (zh) * | 2012-01-20 | 2014-09-24 | 花王株式会社 | 化妆品组合物 |
| CN104066421B (zh) * | 2012-01-20 | 2017-11-14 | 花王株式会社 | 化妆品组合物 |
| JP2017178846A (ja) * | 2016-03-30 | 2017-10-05 | 小林製薬株式会社 | 外用組成物 |
| GB2576637A (en) * | 2018-08-15 | 2020-02-26 | Henkel Ag & Co Kgaa | Tris(hydroxymethyl)aminomethane or its salts as an active substance for reducing sweat secretion |
| GB2576637B (en) * | 2018-08-15 | 2021-03-10 | Henkel Ag & Co Kgaa | Tris(hydroxymethyl)aminomethane or its salts as an active substance for reducing sweat secretion |
Also Published As
| Publication number | Publication date |
|---|---|
| CN102933196B (zh) | 2016-04-13 |
| CN102933196A (zh) | 2013-02-13 |
| JP5771073B2 (ja) | 2015-08-26 |
| JP2012017324A (ja) | 2012-01-26 |
| MY158441A (en) | 2016-10-14 |
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