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WO2011070006A1 - Batterie et procédé d'utilisation d'une batterie - Google Patents

Batterie et procédé d'utilisation d'une batterie Download PDF

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Publication number
WO2011070006A1
WO2011070006A1 PCT/EP2010/069059 EP2010069059W WO2011070006A1 WO 2011070006 A1 WO2011070006 A1 WO 2011070006A1 EP 2010069059 W EP2010069059 W EP 2010069059W WO 2011070006 A1 WO2011070006 A1 WO 2011070006A1
Authority
WO
WIPO (PCT)
Prior art keywords
electrode
battery
gas
anode
battery according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2010/069059
Other languages
German (de)
English (en)
Inventor
Harald Landes
Alessandro Zampieri
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens AG
Siemens Corp
Original Assignee
Siemens AG
Siemens Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens AG, Siemens Corp filed Critical Siemens AG
Priority to AU2010330009A priority Critical patent/AU2010330009B2/en
Priority to CN201080056048.4A priority patent/CN102652379B/zh
Priority to CA2783916A priority patent/CA2783916C/fr
Priority to JP2012542513A priority patent/JP5744051B2/ja
Priority to KR1020127017799A priority patent/KR101296431B1/ko
Priority to US13/515,128 priority patent/US9005826B2/en
Priority to ES10798746.3T priority patent/ES2561218T3/es
Priority to BR112012014054A priority patent/BR112012014054A2/pt
Priority to EP10798746.3A priority patent/EP2510573B1/fr
Publication of WO2011070006A1 publication Critical patent/WO2011070006A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
    • H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00—Hybrid cells; Manufacture thereof
    • H01M12/08—Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/134—Electrodes based on metals, Si or alloys
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H01M4/8605—Porous electrodes
    • H01M4/8615—Bifunctional electrodes for rechargeable cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the invention relates to a battery according to the preamble of patent claim 1 and to a method for operating a battery according to claim 12.
  • Rechargeable batteries such as lithium ion on base, have in the mobile world gained a steadily increasing Be ⁇ importance. In particular, it is about increasing the energy density, which can be stored, steadily.
  • the object of the invention is to represent a battery with the highest possible energy density, which has a high process reliability.
  • Claim 1 comprises a battery having a first electrode, in the discharge process of the battery of a cathode and a second electrode, which in the discharge process the
  • Anode represents, between which a solid electrolyte is arranged to ⁇ , wherein a cathode-side process gas supply takes place.
  • the invention is characterized in that a reservoir which is open relative to an environment and is closed relative to an environment is arranged on the surface of the second electrode, which firstly comprises a porous, ie gas-permeable, oxidizable material and a gaseous at an operating temperature of the battery Redox couple think.
  • the term "closed environment” is understood here to mean the opposite of the process gas feed, usually in the form of air from the atmosphere.
  • the second electrode is thus completed in particular by the free atmosphere.
  • An anode means the electrode at which an oxidation reaction takes place. Electrons are taken up from a chemical reaction and released via an electrical connection. An electrochemical reaction always takes place at a phase boundary between an electrode, an ion-conducting solid electrolyte or a
  • Electrolyte solution instead. Therefore, in electrolysis, the anode is the positive electrode. (Electrolyses consume electrical energy.)
  • the same electrode can operate alternately as an anode or a cathode, depending on whether the battery is charged or discharged.
  • each electrode retains the sign ih ⁇ res potential, so that the positive electrode when discharging the battery works as a cathode, when charging the battery but as an anode.
  • the negative electrode works as an anode during discharge and when charging as a cathode.
  • the positive elec ⁇ trode and the electrode on the side of the oxidizable mate ⁇ rials is the negative electrode.
  • the handle of the first electrode is equated with the term cathode and the term second electrode is used with the term anode.
  • the reservoir with the oxidizable material is arranged in a preferred embodiment of the invention in a chamber which is formed by a support body, which in turn is attached to the anode.
  • the oxidizable material is preferably in a porous form. Since this Mate ⁇ rial by oxygen absorption increases in volume during discharge of the battery and thus from an oxygen ion conductive solid-state structure (eg. As the electrolyte) could replace, the oxygen is preferably supplied by diffusion of the gaseous redox couple the oxidizable material. The redox pair is regenerated at the anode by absorbing oxygen from the electrolyte.
  • the oxidizable material is preferably less noble than the material selected in the anode, so that this is thus protected from oxidation, which could lead to loss of the conductivity of the anode and its mechanical destruction.
  • the power output of the battery is dependent on a cathode-side process gas supply, with tearing off this process gas supply any discharge reactions are immediately suppressed, especially because forms a nitrogen cushion in the gas feeds of the cathode side with air as the process gas, which also z.
  • the breakage of the electrolyte protects the oxidizable material by long diffusion paths from further oxygen attack.
  • the battery according to the invention thus has a much higher safety at a very high energy density than a conventional rechargeable battery, in which both reactants are stored.
  • the anode material simultaneously has electrical and ionic conductivity, wherein both types of conductivity can be present in a single phase or in several phases.
  • an electrically conductive material a material having a metal such as an electrical Lei ⁇ tung by electron flow.
  • An electrolytically conductive material has a line through pure ion transport.
  • anode material in the form of a metal-ceramic composite material, in particular a so-called cermet.
  • a metal-ceramic composite material an electrically conductive metal can be used in conjunction with an electrolytically conductive material, for example a doped metal oxide.
  • an electrolytically conductive material for example a doped metal oxide.
  • a single-phase system has the advantage that stands for both conductivity types, the entire Volu ⁇ men available, which lowers the resistance.
  • the electrically conductive material of the anode has a greater electronegativity (or can be oxidized only at a higher oxygen partial pressure) than the oxidizable material in the reservoir or in the chamber of the support body.
  • the oxidizable material in the chamber of the support body serves to chemically store the process gas and is to be oxidized by the gaseous redox couple. This process is chemically easier to design if this material has a lower electronegativity than the anode conductive material, so that this material of the anode is not unnecessarily drawn into a redox reaction.
  • the material of the chamber to be oxidized is a metal.
  • the electronically conductive material of the anode comprises a metal such as nickel, manganese, molybdenum, tungsten or iron.
  • a metal such as nickel, manganese, molybdenum, tungsten or iron.
  • the oxidizable material in the chamber is a metal.
  • the metals lithium, manganese, iron or titanium or an alloy of these metals have proven.
  • the battery which is particularly preferably between 600 ° C and 800 ° C, consists of the redox couple in an advantageous embodiment of hydrogen and water vapor.
  • a reaction occurs between the (gaseous) water and the oxidizable material in the chamber.
  • the oxidizable material is oxidized by the water, which usually produces a metal oxide and hydrogen.
  • a process gas distributor is arranged in the battery on the positive side, which distributes the process gas, usually air, uniformly at the cathode in an advantageous manner.
  • the support body has a U-shaped cross-section, which is traversed with optionally perforated webs, so that on the one hand to the anode through-going cavities arise, which allow the gas transport of the redox couple and the other hand, the anode contact electronically to transmit the current to the cathode of an adjacent cell.
  • the oxidizable material that is to say preferably one of the metals lithium, manganese, iron or titanium, may preferably be incorporated in a surface-rich form.
  • the chamber is again open towards the anode, so that the stream of the redox couple Res as free as possible can get into the chamber with the oxidizable material.
  • a further component of the invention is a method for operating a battery, wherein an electronegative gas is conducted at a first electrode, in the discharge process a cathode, the gas at the interface between the cathode and the adjacent electrolyte layer (more precisely at the three-phase boundary between gas, Ion conductor and electron conductor) is converted into negative ions and then migrates in this form through the electrolyte layer to the anode (second electrode).
  • the negative ions are converted into the oxidizing partner with the reducing partner of a gaseous redox couple.
  • the released electrons are derived in the form of an electric current flow.
  • the gaseous oxidizing reaction product diffuses into the cavities in which it reacts with an oxidizable material contained therein.
  • the described method can, in turn, a battery having a comparatively high energy density ge ⁇ Stalten as a reservoir is provided of solid oxidizable material that can be designed relatively large volume, since the process gas can be derived to its ultimate oxidation partner by gaseous products.
  • the anode itself is largely excluded from the reaction and is not consumed.
  • the method described has a high process reliability, since no rapid spontaneous discharge of the battery can occur when the process gas flow is interrupted.
  • the process gas is oxygen, which reacts on the anode surface with the reactant hydrogen to water.
  • the water which is present in gaseous vapor at the process temperature of the battery is added to the oxidizing gas.
  • ren material that is preferably passed to a metal, which in turn is oxidized at the process temperature of the battery to Me ⁇ talloxid and in this reaction, hydrogen in molecular form, which migrates back to the anode and this again with the process gas oxygen, the in ionic form, reacts to water.
  • the method for operating a battery is preferably a rechargeable battery, wherein the polarization of the anode and cathode for the charging process of the battery is reversed and the redox process proceeds in the opposite direction, whereby the oxidized material is reduced again.
  • Figure 1 is a schematic representation of a rechargeable
  • Figure 2 is a schematic representation of a battery
  • Solid electrolyte and a reservoir of oxidizable material Solid electrolyte and a reservoir of oxidizable material.
  • FIG 1 is a schematic representation of a rechargeable battery 1 with a Oxidionentransport, a so-called Rechargeable Oxide-Ion Battery (ROB), Darge ⁇ represents, based on the principle of the battery described here.
  • This includes an electrode which forms the Ka ⁇ Thode in the discharge process, wherein the cathode is a continuous air ⁇ current is supplied, which is the so-called process gas.
  • the battery comprises a further electrode, in the discharge process of the battery, the anode, which is separated from the cathode by a solid electrolyte, wherein between the anode and cathode ionic transport of oxygen (O 2- ) takes place.
  • ROB Rechargeable Oxide-Ion Battery
  • This oxygen-ion flow takes place in the discharge process from the cathode (process gas electrode) to the anode (coupled via the redox couple to the oxidizable metal), in the charge process in the reverse direction, but the polarity of the electrodes is maintained.
  • the operating temperature of this battery is between 500 ° C and 800 °, especially at about 600 ° C. This temperature is particularly useful for the ionic transport in the solid electrolyte.
  • FIG. Figure 2 shows a battery 2 with a gas distributor 4, the guide ribs 7, between which gas channels 5 are located.
  • the process gas is passed through the gas channels 5 and guided to a cathode 6 (first electrode Elek ⁇ ).
  • the process gas for example the oxygen from the air, is reduced to 0 2 ⁇ ions and passed through a solid electrolyte 8 through an ionic line to an anode 10 (second electrode).
  • the solid electrolyte is advantageously made of a metal oxide, such as. As zirconium oxide or cerium oxide, which in turn with a metal, for. B. scandium, is doped.
  • the doping material is used to generate oxygen vacancies in the solid electrolyte for transport of the ionized gas, eg. . B. of the O 2 "at the anode 10 is located on the surface of a preferably gaseous reducing agent, in particular, as molecular hydrogen (H 2) may be present with which the ionic oxygen O reacts 2- to H 2 0 according to the following equation: H 2 + 0 -> H 2 O + 2e- (Eq. 1)
  • the electrons released in this process flow via an electronically conductive supporting body 12 (for example of stainless steel) and via a bipolar plate 13 to the neighboring cell.
  • This excess of electrons in discharging the cell at the anode coupled with the lack of electrons at the cathode results in an electrical current flow in the outer circuit of the battery.
  • the gas distributor 4 has with its gas channels 5, which are arranged between the guide ribs 7, an overall height in the order of about 1 mm.
  • the cathode applied to the gas distributor 4 has a thickness of the order of approximately 100 .mu.m.
  • the cathode may consist of a perovskite, for example LaSrMn0 4 , for example.
  • the electrolyte 8 is applied, the OA ⁇ SHORT- a layer thickness between 30 m and 50 pm, aeration vorzugt 40 ⁇ having.
  • This electrolyte may preferably consist of a metal-doped metal oxide, as already described.
  • the electrolyte 8 is followed by the anode 10, which has a layer thickness between 40 m and 60 ⁇ , preferably 50 ⁇ having.
  • the anode is preferably made of a metal-ceramic composite material, a so-called cermet.
  • the anode 10 has metallic phases that ensure electronic conductivity.
  • Advantageous metals for the metallic phase of the anode are lithium, manganese, iron, titanium or nickel.
  • the anode optionally an electrolytically conductive phase in the form of a metal oxide on, it can be oriented ⁇ staltet for example in the form of zirconium oxide.
  • a support body 12 is attached to a surface 13 of the anode 10, which optionally has perforated webs 20, which in turn separate chambers 16 from each other (see also enlarged section of Figure 2).
  • These chambers 16 are filled with an oxidizable material, preferably in the form of an elemental metal.
  • This elemental metal which preferably consists of the group of lithium, manganese, iron or titanium, is present as a powder or as a porous compact.
  • the redox couple H 2 / H 2 0, which serves as a carrier material for the oxygen in the gaseous phase, is diffused (see FIG.
  • Arrows 18) through the chamber 14 (cavity) in the oxidizable material 16 by the porosity through and reacts with the oxidised ⁇ Baren Material 16 is the following equation: y H 2 O + x Me -> Me x O y + y H 2 , (equation 2) where Me stands for a metal.
  • the metal Me should preferably have a lower electronegativity than the metal of the anode 10, which forms the electronically conducting phase there. If so, the tendency of the ionized oxygen to react with the H 2 and the resulting H 2 O to react again with the oxidizable metal 16 is higher than reacting with the anode metal, thereby protecting the anode material from oxidation.
  • redox couple H 2 / H 2 O is a preferred redox couple, but which can be replaced by a ande ⁇ res redox pair whose components and liquid at the operating temperature of the battery of about 600 ° C in gaseous, may Form in sufficient concentration.
  • the condition is that the oxidized component, analogous to H 2 O, undergoes an oxidation reaction with the oxidizable material 16 (eg MnFe) present in the chamber.
  • a redox couple should proceed according to the following reaction equation.
  • This chemical reaction equation should fulfill the following properties: 1.
  • a Xx ( xn0y ⁇ AGMe, MepOq (Equation 4), ie the free Gibbs free enthalpy released in the reaction (of the reaction of the redox couple X: XC> 2 ) should be approximately equal to the Gibbs free energy is the equivalent of the reaction between the metal and the metal oxide, which results from the oxidation of the metal Me according to Equation 2.
  • the partial pressure p x and the partial pressure p Xn o m must be large enough to have a current density in the range of about
  • hydroxides or hydrides offer themselves in ⁇ game as metal vapors and their volatile oxides.
  • the advantage of such a battery structure is that a high current density can be achieved.
  • the course of the reaction is dependent on the incoming process gas. As soon as the stream of process gas breaks down, the battery can no longer generate electricity and it can not lead to an uncontrolled discharge with uncontrolled heat generation or even to a fire.
  • the structure of the battery 2 is also particularly suitable for stacking, which is indicated in Figure 2 in that above the support body 12 again another gas distributor 4 'is arranged, which is the lower part of another cell.
  • the base area of a cell can be, for example, 150 mm x 150 mm.
  • the entire battery 2 is thermally insulated and encapsulated, since the operating temperature is approximately at 600 ° C. When recuperation of the entrained in the process heat to the process gas inlet side by a heat exchanger and a sufficiently large volume-to-surface ratio with good insulation of the entire battery 2 maintaining the operating temperature can be obtained solely by the inevitably occurring power loss through the internal resistances in the battery. If necessary, a small current must be maintained in no-load operation to prevent slow cooling.
  • Such a battery described is particularly suitable as a stationary energy storage in continuous operation. It can but also serve to absorb excess grid energy, for example, when wind turbines or other renewable energy sources produce energy and this energy should not be needed on the grid. Thus, excess energy from renewable energy sources can be fed into such batteries.

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Hybrid Cells (AREA)
  • Secondary Cells (AREA)
  • Inert Electrodes (AREA)

Abstract

L'invention concerne une batterie comportant une cathode (6) et une anode (10) entre lesquelles est disposé un électrolyte solide (6). La batterie présente une amenée de gaz de traitement du côté de la cathode et est caractérisée en ce qu'un corps porteur (12) électroconducteur est disposé au niveau de la surface de la cathode (13). Ledit corps porteur présente à son tour au moins une chambre (14) reliée à l'anode, laquelle chambre contient d'une part un matériau poreux oxydable (16) et, d'autre part, un couple d'oxydoréduction sous forme gazeuse à une température de fonctionnement de la batterie.
PCT/EP2010/069059 2009-12-10 2010-12-07 Batterie et procédé d'utilisation d'une batterie Ceased WO2011070006A1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
AU2010330009A AU2010330009B2 (en) 2009-12-10 2010-12-07 Battery and method for operating a battery
CN201080056048.4A CN102652379B (zh) 2009-12-10 2010-12-07 电池和运行电池的方法
CA2783916A CA2783916C (fr) 2009-12-10 2010-12-07 Batterie et procede d'utilisation d'une batterie
JP2012542513A JP5744051B2 (ja) 2009-12-10 2010-12-07 電池および電池の作動方法
KR1020127017799A KR101296431B1 (ko) 2009-12-10 2010-12-07 배터리와 배터리 작동 방법
US13/515,128 US9005826B2 (en) 2009-12-10 2010-12-07 Electrochemical battery
ES10798746.3T ES2561218T3 (es) 2009-12-10 2010-12-07 Batería
BR112012014054A BR112012014054A2 (pt) 2009-12-10 2010-12-07 bateria e método para operar uma bateria
EP10798746.3A EP2510573B1 (fr) 2009-12-10 2010-12-07 Batterie

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102009057720.3 2009-12-10
DE102009057720A DE102009057720A1 (de) 2009-12-10 2009-12-10 Batterie und Verfahren zum Betreiben einer Batterie

Publications (1)

Publication Number Publication Date
WO2011070006A1 true WO2011070006A1 (fr) 2011-06-16

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Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2010/069059 Ceased WO2011070006A1 (fr) 2009-12-10 2010-12-07 Batterie et procédé d'utilisation d'une batterie

Country Status (11)

Country Link
US (1) US9005826B2 (fr)
EP (1) EP2510573B1 (fr)
JP (1) JP5744051B2 (fr)
KR (1) KR101296431B1 (fr)
CN (1) CN102652379B (fr)
AU (1) AU2010330009B2 (fr)
BR (1) BR112012014054A2 (fr)
CA (1) CA2783916C (fr)
DE (1) DE102009057720A1 (fr)
ES (1) ES2561218T3 (fr)
WO (1) WO2011070006A1 (fr)

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EP2650401A1 (fr) 2012-04-10 2013-10-16 Siemens Aktiengesellschaft Système de méthanation basée sur une centrale électrique
WO2014000984A1 (fr) * 2012-06-29 2014-01-03 Siemens Aktiengesellschaft Dispositif de stockage d'énergie électrique
CN104170144A (zh) * 2012-01-25 2014-11-26 西门子公司 用于电能存储器的堆
CN104396056A (zh) * 2012-06-29 2015-03-04 西门子公司 电蓄能电池的存储结构
US9005826B2 (en) 2009-12-10 2015-04-14 Siemens Aktiengesellschaft Electrochemical battery
JP2015517045A (ja) * 2012-03-16 2015-06-18 シーメンス アクチエンゲゼルシヤフトＳｉｅｍｅｎｓ Ａｋｔｉｅｎｇｅｓｅｌｌｓｃｈａｆｔ 蒸気タービン発電所に組み込まれた高温バッテリー
EP2894124A1 (fr) 2014-01-08 2015-07-15 Siemens Aktiengesellschaft Accumulateur d'énergie électrochimique doté d'un matériau d'accumulation chimique externe

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US8894722B2 (en) * 2011-06-24 2014-11-25 Siemens Aktiengesellschaft Construction of planar rechargeable oxide-ion battery cells and stacks using stainless steel housing structures
DE102011078116A1 (de) * 2011-06-27 2012-12-27 Siemens Ag Energiespeicher und Verfahren zum Laden oder Entladen eines Energiespeichers
DE102011080237A1 (de) * 2011-08-02 2013-02-07 Siemens Aktiengesellschaft Elektrochemischer Speicher
DE102011083541A1 (de) * 2011-09-27 2013-03-28 Siemens Aktiengesellschaft Speicherelement
JP5817419B2 (ja) * 2011-10-17 2015-11-18 コニカミノルタ株式会社 ２次電池型燃料電池
EP2759007B1 (fr) * 2011-11-09 2017-06-28 Siemens Aktiengesellschaft Élément d'accumulation pour un accumulateur d'énergie à électrolyte solide
DE102012201066A1 (de) * 2012-01-25 2013-07-25 Siemens Aktiengesellschaft Elektrischer Energiespeicher
DE102012202978A1 (de) * 2012-02-28 2013-08-29 Siemens Aktiengesellschaft Verfahren zur Herstellung einer Speicherstruktur eines elektrischen Energiespeichers
DE102012203665A1 (de) 2012-03-08 2013-09-12 Siemens Aktiengesellschaft Gasturbinenbeheizte Hochtemperatur-Batterie
DE102012205077A1 (de) * 2012-03-12 2013-09-12 Siemens Aktiengesellschaft Elektrischer Energiespeicher
WO2013143921A1 (fr) * 2012-03-29 2013-10-03 Siemens Aktiengesellschaft Accumulateur d'énergie électrique
EP2844786B1 (fr) 2012-06-11 2016-08-24 Siemens Aktiengesellschaft Système de régulation de température pour batterie ou électrolyseur à haute température
DE102012211325A1 (de) 2012-06-29 2014-01-02 Siemens Aktiengesellschaft Elektrischer Energiespeicher
DE102012211318A1 (de) * 2012-06-29 2014-01-02 Siemens Aktiengesellschaft Elektrischer Energiespeicher
DE102012213037A1 (de) 2012-07-25 2014-01-30 Siemens Aktiengesellschaft Speichereinrichtung für elektrische Energie, insbesondere Batterie oder Batteriezelle
EP2865045B1 (fr) * 2012-08-14 2016-09-28 Siemens Aktiengesellschaft Système de centrale comportant une unité d'accumulation haute température
CN113753854A (zh) * 2020-12-31 2021-12-07 厦门大学 一种具有直孔结构的储氢燃料及其制备方法

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CN102652379A (zh) 2012-08-29
AU2010330009A1 (en) 2012-07-12
ES2561218T3 (es) 2016-02-25
KR101296431B1 (ko) 2013-08-13
JP5744051B2 (ja) 2015-07-01
CA2783916C (fr) 2016-03-22
US9005826B2 (en) 2015-04-14
CA2783916A1 (fr) 2011-06-16
AU2010330009B2 (en) 2014-02-20
US20130034784A1 (en) 2013-02-07
EP2510573A1 (fr) 2012-10-17
DE102009057720A1 (de) 2011-06-16
JP2013513910A (ja) 2013-04-22
KR20120104304A (ko) 2012-09-20
EP2510573B1 (fr) 2015-12-02
BR112012014054A2 (pt) 2016-04-12

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