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WO2011069979A1 - Produit alimentaire gélifié - Google Patents

Produit alimentaire gélifié Download PDF

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Publication number
WO2011069979A1
WO2011069979A1 PCT/EP2010/069004 EP2010069004W WO2011069979A1 WO 2011069979 A1 WO2011069979 A1 WO 2011069979A1 EP 2010069004 W EP2010069004 W EP 2010069004W WO 2011069979 A1 WO2011069979 A1 WO 2011069979A1
Authority
WO
WIPO (PCT)
Prior art keywords
gas
food product
acid
product
product according
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2010/069004
Other languages
English (en)
Inventor
Jean-François Chevalier
Rafael Marcilla
Hermann Knauf
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nestec SA
Original Assignee
Nestec SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=42026693&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=WO2011069979(A1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Priority to AU2010329982A priority Critical patent/AU2010329982B2/en
Priority to PH1/2012/500879A priority patent/PH12012500879A1/en
Priority to EP10790395.7A priority patent/EP2509443B1/fr
Priority to MX2012006051A priority patent/MX2012006051A/es
Priority to CN2010800562206A priority patent/CN102651976A/zh
Application filed by Nestec SA filed Critical Nestec SA
Priority to IN4231DEN2012 priority patent/IN2012DN04231A/en
Priority to ES10790395.7T priority patent/ES2452528T3/es
Priority to BR112012013976A priority patent/BR112012013976A2/pt
Publication of WO2011069979A1 publication Critical patent/WO2011069979A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
    • A23L2/52—Adding ingredients
    • A23L2/54—Mixing with gases
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING OR TREATMENT THEREOF
    • A23C9/00—Milk preparations; Milk powder or milk powder preparations
    • A23C9/152—Milk preparations; Milk powder or milk powder preparations containing additives
    • A23C9/1524—Inert gases, noble gases, oxygen, aerosol gases; Processes for foaming
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23C—DAIRY PRODUCTS, e.g. MILK, BUTTER OR CHEESE; MILK OR CHEESE SUBSTITUTES; MAKING OR TREATMENT THEREOF
    • A23C9/00—Milk preparations; Milk powder or milk powder preparations
    • A23C9/152—Milk preparations; Milk powder or milk powder preparations containing additives
    • A23C9/154—Milk preparations; Milk powder or milk powder preparations containing additives containing thickening substances, eggs or cereal preparations; Milk gels
    • A23C9/1542—Acidified milk products containing thickening agents or acidified milk gels, e.g. acidified by fruit juices
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
    • A23L2/52—Adding ingredients
    • A23L2/68—Acidifying substances
    • A—HUMAN NECESSITIES
    • A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
    • A23L29/00—Foods or foodstuffs containing additives; Preparation or treatment thereof
    • A23L29/20—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents
    • A23L29/206—Foods or foodstuffs containing additives; Preparation or treatment thereof containing gelling or thickening agents of vegetable origin
    • A23L29/231—Pectin; Derivatives thereof

Definitions

  • the present invention concerns a drinkable gas containing products having a flowing gel texture.
  • it relates to food products comprising a gas and having a gel texture which exhibit a pleasant sparkling effect in the mouth when consumed as a drink.
  • the present invention also concerns a process for the preparation of a drinkable gas containing food product having a flowing gel texture.
  • Drinkable gas containing beverages are well known to everybody. Examples of drinkable gas containing beverages are carbonated soft drinks such as lemonades. Further, carbonated milk products are available on the market. In addition, carbonated drinks on the basis of fruit juices and vegetable extracts are also well accepted by the consumers.
  • the invention relates to a gas containing food product having a gel texture with a still state, that can be set by the consumer to a sparkling state by mechanical agitation such as hand shaking, preferably reversibly, said product comprising pectin, an acid, a liquid and a gas wherein the pH of the composition is in a range of 2.5 to 5.0.
  • the viscosity of the product is below 2000 centipoises measured in a Brookfield viscosimeter with module 93-C at a speed of 5RPM at 8°C, so that the product can be preferably consumed by drinking or sipping.
  • the product is drinkable, although being only a preferred embodiment.
  • a second aspect of the present invention concerns a process for the preparation of a gas containing food product having a gel texture with a still state, that can be, preferably reversibly, set by the consumer to a sparkling state by mechanical agitation such as hand shaking, said process comprising the steps of: mixing a pectin, an acid and a liquid and optionally at least one of sweeteners and flavoring agents; pasteurizing the mixture; injecting a gas to form a gas containing product; holding the gas containing product for a period between 0.25 to 5, preferably 0.5 to 2.5 minutes; storing the product under isobaric conditions and filling the product in containers under isobaric conditions.
  • Figure 1 is a process diagram illustrating a way how to produce the drinkable gas containing food product of the present invention.
  • the drinkable gas containing food product of the present invention has a gel texture which is flowable.
  • a suitable container such as a bottle, cup, etc.
  • the gel is in a still state, i.e., no bubbles are visible in the product, because the major part of the volume of gas is uniformly dissolved in the gel matrix.
  • the gas in the food product de-gases from the gel matrix and exhibits a sparkling effect.
  • I n addition to th is still-to-sparkling effect, the consumer experiences a sparkling mouthfeel, whether the gas is dissolved in the gel matrix (still state) or not (sparkling state).
  • the consumer has the possibility to adapt the intensity of the sparkling effect that is desired.
  • the consumer can consume the product as such, without agitating it, or the consumer can shake more or less the product in order to obtain or corresponding more or less sparkling effect.
  • the shaking force required to trigger the sparkling effect from the still product is progressive. This means that if the shaking force that is applied by the consumer is not high, the gas released from the gel matrix into gas bubbles will be low, so that the sparkling effect and sparkling mouthfeel will also be low.
  • the sparkling perception in mouth between a non-shaken product in the still state, and a shaken product in the sparkling state, will also be different due to the tixotropy of the gel, which makes it less viscous once energy is brought to the gel matrix by shaking.
  • the force applied during shaking by the consumer is higher, and/or longer in time, the gas dissolved in the gel matrix will be released as gas bubbles in higher quantities.
  • shaking force No values for the shaking force are given herein; as such a shaking force may vary from one person to another, depending on age, gender, physical condition, etc. But it is typically admitted for the present invention that the shaking force is that which can be applied by any person being older than 5.
  • the product is cooled down to refrigerator temperature (typically at a temperature comprised between 4°C and 8°C)
  • the gas bubbles are dissolved back in the product again and the gel texture is the same as before shaking, that is to say in a still state, i.e. with no noticeable sparkling appearance.
  • the volume of gas undissolved - i.e. present in a gaseous state as gas bubbles - is so low that substantially no gas bubbles are visually noticeable by the consumer.
  • the volume of gas in the product is comprised between 1 g/l and 10 g per liter of gel product and said product has a sparkling mouthfeel.
  • the pH of the food product is in the acid range.
  • the pH of the composition is in a range of 2.5 to 5.0.
  • the pH is in a range of 3 to 4.5, with a range of 3.5 to 4.0 being more preferred.
  • the viscosity of the product is preferably below 2000 centipoises measured in a Brookfield viscosimeter with module 93-C at a speed of 5RP M at 8°C, so that the product is sufficiently fluid to be consumed by drinking.
  • the drinkable gas containing food product of the present invention comprises pectin as a gelling agent to provide the flowing gel characteristic of the product.
  • the pectin that is suitable for the food product of the present invention is a high methylated pectin (HM pectin) or low methylated pectin (LM pectin).
  • the amount of the pectin contained in the food product of the present invention is preferably from 0.1 to 5.0 wt.-%, more preferably 0.5 to 2.5 wt.-%, with a range of 1 .0 to 2.0 wt.-% being most preferred.
  • the food product of the present invention also comprises an acid to adjust the pH in the required range.
  • the presence of an acid in the food product of the present invention causes pH reduction which allows a better solution of the gas in the product.
  • an acid pH contributes to a refreshing sensation and also works as a product preservative.
  • the amount of the acid in the product is preferably 0.01 to 1 .0 wt.-%, more preferred 0.1 to 0.5 wt.-%, most preferred 0.2 to 0.4 wt.-%.
  • the liquid providing the matrix - in combination with the pectin - for the gas of the drinkable gas containing food product is preferably contained in an amount of 70.0 to 95.0 wt.-%, more preferred 80 to 90 wt.-%, with 85 to 88 wt.-% being most preferred.
  • a gas is added to the drinkable food product of the present invention to provide the sparkling effect upon agitation by the consumer.
  • the concentration of gas in the product is preferably 1.0 to 10 g/l, more preferred 2.0 to 5.0 g/l and most preferred 2.0 to 4.0 g/i.
  • the pH is kept in a range of 2.5 to 5.0 in the product.
  • the pH is in a range of 3 to 4.5, with a range of 3.5 to 4.0 being most preferred.
  • the acid contained in the food product of the present invention may be any food-grade organic or inorganic acid.
  • the organic acid is preferably selected from citric acid, lactic acid, acetic acid and mixtures thereof, with citric acid being more preferred.
  • the inorganic acids may be any inorganic acid which is of food-grade quality.
  • examples of inorganic acids are phosphoric acid, fumaric acid, carbonic acid and mixtures thereof, wherein phosphoric acid is more preferred.
  • the majority of the drinkable gas containing food product of the present invention consists of a liquid base which can be any liquid suitable for forming a drink.
  • the liquid base is selected from water, fruit juice, fruit pulp, coffee, tea, milk and derivates, soy based drinks, natural extracts, chocolate based drinks, smoothies and mixtures thereof, with water and fruit juice being more preferred.
  • gases are, for example, C0 2 , N 2 , 0 2 , or even atmospheric air that would be filtered to match food safety requirements Mixtures of gases are also appropriate.
  • C0 2 is the gas that offers the best properties in terms of dissolution in the food matrix, especially when pectin is used as a gelling agent such that the still to sparkling effect is reversible.
  • the drinkable gas containing food product of the present invention may also comprise up to 20 wt.-%, preferably 3.0 to 15.0, more preferred 10 to 13 wt.-% of at least one natural sugar.
  • natural sugars are saccharose, all types of syrup glucose or syrup fructose.
  • the natural sugar can be replaced, in fewer quantities for obtaining the same sweetening effect, by high intensity sweeteners, either natural or artificial.
  • natural high intensity sweeteners are plant extracts like stevia extracts, or rebaudioside A.
  • artificial sweeteners are aspartame, acesulfame, sucralose, saccharin, neotame and mixtures thereof. Mixtures of natural sugars and artificial sweeteners are also appropriate.
  • the food product of the present invention may also comprise up to 2.0 wt.-%, preferably 0.1 to 1 .0 wt.-% of a flavoring agent.
  • a flavoring agent is one or a combination of food-grade flavoring agents used in soft-drink applications. Examples of flavoring agents are those selected from lemon flavor, orange flavor, raspberry flavor, cola flavor, banana flavor, coffee flavor or blackcurrant flavor.
  • the drinkable gas containing food product of the present invention may be an alcohol-free food product or a food product which contains alcohol.
  • an alcohol such as ethanol is externally added.
  • An alcoholic food product may contain up to 10 wt.-%, preferably 4.5 to 8 wt.-% of ethanol.
  • the food product may further comprise additives such as vitamins, minerals and probiotics.
  • the drinkable gas containing food product of the present invention can be a beverage, preferably a carbonated beverage.
  • a beverage preferably a carbonated beverage.
  • Examples are carbonated soft drinks on the basis of water, flavored or not flavored, fruit juice, vegetables and an alcoholic fruit juice.
  • Further products of the present invention are so-called "ready to drink” beverages such as spirit mixtures.
  • the drinkable gas containing food product having a flowing gel structure can be produced by a process using the injection of a liquid gas such as liquid C0 2 .
  • the process comprises the steps of mixing, heat treatment, gas injection, holding time, isobaric storage and isobaric filling.
  • one way of manufacturing the food prod ucts of the present invention is a process, as shown in Figure 1 , which comprises the following steps:
  • ingredients such as pectin, an acid and a liquid and optionally at least one of the sweeteners and flavoring agents are mixed with standard agitation i n a conventional mixing machine.
  • the temperature is set at 85 to 140°C, preferably about 90°C during a period of 10 sec to 10 min, preferably 6 to 8 minutes followed by a temperature decrease of 8°C.
  • a gas for example C0 2
  • C0 2 is injected in a rotor-stator device at a continuous temperature of 2 to 30 °C, preferably 6 to 10°C.
  • the amount of injected C0 2 is regulated according to the flow of the pre-mixed product.
  • a control pressure valve is provided that ensures the holding time and a proper absorption of the gas by the product at the outlet of the rotor-stator system.
  • the working pressure in the control pressure valve is 50 to 400, preferably 80 to 200 kPa. 4. Holding time
  • This step is provided to ensure a proper absorption of the gas in the liquid. This is first achieved after a suitable contact between the two phases.
  • the holding time is set in a range of between 0.25 to 5, preferably 0.5 to 2.5, most preferred 0.5 to 1.5 minutes. 5.
  • the stabilized product is stored in an isobaric tank previous to the filling step, having a head space pressure of 50kPa to 400 kPa.
  • the temperature remains constant being the preferred a constant temperature of 5 °C.
  • a control pressure valve is provided in the manufacturing system, which ensures the holding time and a proper absorption of the gas by the product at the outlet of the rotor-stator system.
  • the working pressure in the control pressure valve is 50 to 400 kPa, preferably 80 to 200 kPa. 6.
  • the filling is carried out by an isobaric filling system which can be carried out under aseptic conditions. If the filling is performed in non-isobaric devices, the final product will have a lower gas content.
  • the product is stored at a temperature of between 2 to 12°C for at least 45 days without losing gas under maintaining the gel texture.
  • an acid selected from organic and inorganic acids for example those as mentioned above and a liquid selected from water, fruit juice, fruit pulp, coffee, tea, milk and derivates, soy based drinks, natural extracts, chocolate based drinks, smoothies and mixtures thereof are used.
  • any food-grade gas may be used.
  • a C0 2 stream is preferably used to produce a carbonated drinkable food product of the invention that exhibits an excellent sparkling effect.
  • the product of the present invention is filled up in suitable containers such as bottles and cups made of glass, aluminum or plastic. After filling, the containers are air- tightly sealed according to standard procedures.
  • suitable containers such as bottles and cups made of glass, aluminum or plastic.
  • the containers are air- tightly sealed according to standard procedures.
  • the process described provides a stable gas containing food product having a flowing gel structure.
  • the product exhibits a pleasant sparkling effect when consumed as a drink.
  • the product remains stable i n the conta i ner for at least 45 d ays i n cooled environments of 2 to 12°C.
  • the ingredients are mixed with standard agitation at a temperature of about
  • the pH of the product (mixture) at this stage is within the same range of the pH for the final product, pH of 3 to 4.5.
  • C0 2 is injected in a rotor-stator device at a conti n uous temperature of 8°C.
  • the amount of injected C0 2 is regulated according to the flow of the pre- mixed product.
  • the working pressure in the control pressure valve is 100kPa.
  • the final concentration of C0 2 gas in the product is 1 .5 to 5 g/L (measured with Steinfurth equipment).
  • the product is stored in an isobaric tank having a head space pressure of 100kPa. Thereafter the product is filled in plastic bottles using in isobaric filler system. The bottled products are stored at 5°C.
  • the product has been tested and found to be a raspberry-taste refreshing drink that exhibits a pleasant sparkling mouth-feel when consumed.

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Dispersion Chemistry (AREA)
  • Jellies, Jams, And Syrups (AREA)
  • Non-Alcoholic Beverages (AREA)

Abstract

La présente invention concerne un produit alimentaire buvable contenant du gaz ayant une texture de gel fluide comprenant un agent gélifiant, un acide, un liquide et un gaz où le pH du produit alimentaire est dans la plage de 2,5 à 6,0, où le gaz est dissous dans la matrice de gel de sorte que ledit produit ait un état stationnaire et une sensation moussante en bouche, et le volume de gaz dans le produit est inférieur à 10 g/l, de préférence entre 2 et 5 g/l.
PCT/EP2010/069004 2009-12-11 2010-12-06 Produit alimentaire gélifié Ceased WO2011069979A1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
BR112012013976A BR112012013976A2 (pt) 2009-12-11 2010-12-06 produto alimentício gelatinizado
PH1/2012/500879A PH12012500879A1 (en) 2009-12-11 2010-12-06 A jellified food product
EP10790395.7A EP2509443B1 (fr) 2009-12-11 2010-12-06 Produit alimentaire gélifié
MX2012006051A MX2012006051A (es) 2009-12-11 2010-12-06 Producto alimenticio gelatinoso.
CN2010800562206A CN102651976A (zh) 2009-12-11 2010-12-06 成凝胶状的食物产品
AU2010329982A AU2010329982B2 (en) 2009-12-11 2010-12-06 A jellified food product
IN4231DEN2012 IN2012DN04231A (fr) 2009-12-11 2010-12-06
ES10790395.7T ES2452528T3 (es) 2009-12-11 2010-12-06 Producto alimentario gelificado

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP09178784.6 2009-12-11
EP09178784A EP2335497A1 (fr) 2009-12-11 2009-12-11 Produit alimentaire gélifié

Publications (1)

Publication Number Publication Date
WO2011069979A1 true WO2011069979A1 (fr) 2011-06-16

Family

ID=42026693

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2010/069004 Ceased WO2011069979A1 (fr) 2009-12-11 2010-12-06 Produit alimentaire gélifié

Country Status (12)

Country Link
EP (2) EP2335497A1 (fr)
CN (1) CN102651976A (fr)
AU (1) AU2010329982B2 (fr)
BR (1) BR112012013976A2 (fr)
CL (1) CL2012001435A1 (fr)
ES (1) ES2452528T3 (fr)
IN (1) IN2012DN04231A (fr)
MX (1) MX2012006051A (fr)
MY (1) MY162059A (fr)
PH (1) PH12012500879A1 (fr)
PT (1) PT2509443E (fr)
WO (1) WO2011069979A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013017944A (ja) * 2011-07-11 2013-01-31 Iwai Kikai Kogyo Co Ltd 気体溶解装置及び気体溶解方法
WO2014184245A1 (fr) * 2013-05-14 2014-11-20 Nestec S.A. Produit alimentaire aere stable et son procede de preparation
US20190335795A1 (en) * 2017-01-12 2019-11-07 Shinryo Corporation Method for producing hydrogen gas-containing material and device for producing hydrogen gas-containing material
WO2020065240A1 (fr) * 2018-09-28 2020-04-02 Institut National De Recherche En Sciences Et Technologies Pour L'environnement Et L'agriculture - Irstea - Matrice alimentaire alvéolée à variation de volume

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105982038A (zh) * 2015-02-09 2016-10-05 可口可乐公司 用于再造粒的组合物和方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4197325A (en) * 1977-10-05 1980-04-08 Taiyo Fishery Co., Ltd. Carbon dioxide containing jelly and process for preparing the same
EP0117011A1 (fr) * 1983-02-22 1984-08-29 DMV-Campina B.V. Boisson gazeuse à base de lait fermenté
US4919960A (en) * 1987-09-08 1990-04-24 Dairy Research, Inc. Process of making a carbonated liquid dairy product
WO1996019925A1 (fr) * 1994-12-27 1996-07-04 Monsanto Company Boisson gazeifiee, sans alcool et gelifiee
WO1998004158A1 (fr) 1996-07-30 1998-02-05 Carlsberg-Tetley Brewing Limited Boisson gazeifiee presentant une structure de gel leger
EP0796046B1 (fr) 1994-12-12 2003-03-05 Brigham Young University Procede d'obtention de produits alimentaires carbonates semi-solides ou solides

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3826829A (en) * 1970-11-17 1974-07-30 Gen Foods Corp Slush beverages containing fine-grained ice crystals

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4197325A (en) * 1977-10-05 1980-04-08 Taiyo Fishery Co., Ltd. Carbon dioxide containing jelly and process for preparing the same
EP0117011A1 (fr) * 1983-02-22 1984-08-29 DMV-Campina B.V. Boisson gazeuse à base de lait fermenté
US4919960A (en) * 1987-09-08 1990-04-24 Dairy Research, Inc. Process of making a carbonated liquid dairy product
EP0796046B1 (fr) 1994-12-12 2003-03-05 Brigham Young University Procede d'obtention de produits alimentaires carbonates semi-solides ou solides
WO1996019925A1 (fr) * 1994-12-27 1996-07-04 Monsanto Company Boisson gazeifiee, sans alcool et gelifiee
WO1998004158A1 (fr) 1996-07-30 1998-02-05 Carlsberg-Tetley Brewing Limited Boisson gazeifiee presentant une structure de gel leger

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2013017944A (ja) * 2011-07-11 2013-01-31 Iwai Kikai Kogyo Co Ltd 気体溶解装置及び気体溶解方法
WO2014184245A1 (fr) * 2013-05-14 2014-11-20 Nestec S.A. Produit alimentaire aere stable et son procede de preparation
US20190335795A1 (en) * 2017-01-12 2019-11-07 Shinryo Corporation Method for producing hydrogen gas-containing material and device for producing hydrogen gas-containing material
WO2020065240A1 (fr) * 2018-09-28 2020-04-02 Institut National De Recherche En Sciences Et Technologies Pour L'environnement Et L'agriculture - Irstea - Matrice alimentaire alvéolée à variation de volume
FR3086506A1 (fr) * 2018-09-28 2020-04-03 Institut National De Recherche En Sciences Et Technologies Pour L'environnement Et L'agriculture - Irstea - Matrice alimentaire alveolee a variation de volume

Also Published As

Publication number Publication date
EP2509443B1 (fr) 2014-02-19
PH12012500879A1 (en) 2013-01-07
ES2452528T3 (es) 2014-04-01
MX2012006051A (es) 2012-06-27
CN102651976A (zh) 2012-08-29
IN2012DN04231A (fr) 2015-08-07
EP2335497A1 (fr) 2011-06-22
AU2010329982A1 (en) 2012-05-31
EP2509443A1 (fr) 2012-10-17
MY162059A (en) 2017-05-31
BR112012013976A2 (pt) 2015-09-15
PT2509443E (pt) 2014-04-07
CL2012001435A1 (es) 2012-08-17
AU2010329982B2 (en) 2014-09-18

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