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WO2011069618A2 - Composition de coiffage - Google Patents

Composition de coiffage Download PDF

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Publication number
WO2011069618A2
WO2011069618A2 PCT/EP2010/007344 EP2010007344W WO2011069618A2 WO 2011069618 A2 WO2011069618 A2 WO 2011069618A2 EP 2010007344 W EP2010007344 W EP 2010007344W WO 2011069618 A2 WO2011069618 A2 WO 2011069618A2
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WO
WIPO (PCT)
Prior art keywords
dipeptide
composition according
composition
concentration
acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2010/007344
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English (en)
Other versions
WO2011069618A3 (fr
Inventor
Mustafa Grit
Jonathan Wood
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Germany GmbH
Original Assignee
KPSS Kao Professional Salon Services GmbH
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KPSS Kao Professional Salon Services GmbH filed Critical KPSS Kao Professional Salon Services GmbH
Priority to US13/512,930 priority Critical patent/US20130017157A1/en
Priority to EP10785358.2A priority patent/EP2509572B1/fr
Publication of WO2011069618A2 publication Critical patent/WO2011069618A2/fr
Publication of WO2011069618A3 publication Critical patent/WO2011069618A3/fr
Anticipated expiration legal-status Critical
Priority to US15/402,382 priority patent/US20170119651A1/en
Ceased legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8182—Copolymers of vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A45—HAND OR TRAVELLING ARTICLES
    • A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
    • A45D7/00—Processes of waving, straightening or curling hair
    • A45D7/04—Processes of waving, straightening or curling hair chemical
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/042—Gels
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/046—Aerosols; Foams
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/64—Proteins; Peptides; Derivatives or degradation products thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/8141—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • A61K8/8158—Homopolymers or copolymers of amides or imides, e.g. (meth) acrylamide; Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/81—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • A61K8/817—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a single or double bond to nitrogen or by a heterocyclic ring containing nitrogen; Compositions or derivatives of such polymers, e.g. vinylimidazol, vinylcaprolactame, allylamines (Polyquaternium 6)
    • A61K8/8176—Homopolymers of N-vinyl-pyrrolidones. Compositions of derivatives of such polymers
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/06—Preparations for styling the hair, e.g. by temporary shaping or colouring
    • A61Q5/065—Preparations for temporary colouring the hair, e.g. direct dyes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/42—Colour properties
    • A61K2800/43—Pigments; Dyes
    • A61K2800/432—Direct dyes

Definitions

  • the present invention is related to hair styling composition for keratin fibres especially for hair.
  • Aerosol hair styling compositions have been widely used either as a spray, aerosol or non-aerosol, or as foam.
  • they comprise hair fixing polymers in an aqueous or aqueous alcoholic medium together with a propellant in case of an aerosol composition.
  • Many fixing polymers have been suggested in the literature either synthetic or natural origin. Natural polymers so far suggested do not satisfy the expectations of consumers in terms of hair feel and hold of hair style for a long time and, therefore, overwhelmingly synthetic polymers are used.
  • a preferred styling composition must have certain performance. It is clear that it must have certain level of hair setting effect and additionally it must not take away hair shine and especially importantly it must allow easy hair styling, diminish flyaways, does not effect negatively hair shine, allow restyling and styled hair must feel as natural as possible. Especially in the latter, there is a lot of need for new developments.
  • compositions comprising at least one film forming polymer and at least one dipeptide in an aqueous, aqueous- alcoholic or alcoholic medium has excellent hair styling and restyling benefits together with excellent volumizing and bodifying effects.
  • the hair feels excellently natural upon touching and looks excellently shiny.
  • the object of the present invention is a composition for keratin fibres especially for hair based on an aqueous, aqueous- alcoholic or alcoholic medium comprising at least one film forming polymer and at least one dipeptide.
  • Another object of the present invention is the use of a composition based on an aqueous, aqueous- alcoholic or alcoholic medium comprising at least one film forming polymer and at least one dipeptide for styling and restyling keratin fibres especially hair.
  • Still another subject of the present invention is a process for styling keratin fibres especially hair wherein a composition based on an aqueous, aqueous- alcoholic or alcoholic medium comprising at least one film forming polymer and at least one dipeptide is applied onto wet and/or dry hair and hair is styled without rinsing off the composition.
  • styling it is meant that the hair is freshly styled.
  • restyling it is meant that hair is already styled with an aqueous, aqueous- alcoholic or alcoholic composition of the present invention and after lapse of certain period of time a new style is given without using further composition of the present invention.
  • further object of the present invention is a process for restyling hair wherein keratin fibres especially hair is already styled with a composition based on an aqueous, aqueous- alcoholic or alcoholic medium comprising at least one film forming polymer and at least one dipeptide and afterwards a new style is given with or without wetting.
  • dipeptide compounds with two amino acid moieties are meant.
  • Composition of the present invention comprise at least one dipeptide.
  • the dipeptide compounds according to the present invention comprise two amino acid moieties.
  • any dipeptide available either natural or synthetic is suitable for the purposes of the present invention.
  • the synthetic ones are preferred.
  • the amino acid moeities of dipeptide are selected from arginine, tyrosine, valine, tryptophan, alanine, cysteine, glycine, lysine, proline, hydroxyproline and histidine.
  • the dipetides according to the present invention may certainly be of two different amino acids but at the same time two of the same amino acids.
  • the two amino acid moieties are of different amino acids when one of the amino acid moieties is glycine. More preferably the two amino acid moieties are of two different amino acids.
  • suitable dipeptides are the ones commercially available and known with their INCI name as Dipeptide-1 , Dipeptide-2, Dipeptide-3, Dipeptide- 4, Dipeptide-5, Dipeptide-6, Dipeptide-7, Dipeptide-8, and carnosine. The most preferred is carnosine and is of ⁇ -alanin and L-histidine.
  • Concentration of at least one dipeptide is in the range of 0.01 to 5%, preferably 0.05 to 3% and more preferably 0.1 to 2.5% and most preferably 0.2 to 1.5% by weight calculated to the total composition.
  • compositions of the present invention comprise at least one film forming polymer at a concentration of 0.1 to 25%, preferably 1.5 to 20%, more preferably 2.5 to 15 and most preferably 4 to 15% by weight calculated to total composition.
  • At least one film forming polymer is selected from the anionic, non-ionic, cationic and/or amphoteric or zwitterionic ones.
  • Suitable non-ionic polymer is first of all vinylpyrrolidon polymers either homopolymers or copolymers with, especially, vinylacetate. Those are known with the trade name "Luviskol” as homopolymers Luviskol K 30, K 60 or K 90 as well copolymers Luviskol VA 55, VA 64, Plus from BASF AG and advantage LS-E from ISP.
  • Natural non-ionic polymers are as well suitable for the composition of the present invention. Those are such as cellulose, chitosan, guar gum, neutralised shellac and their derivatives.
  • amphoteric polymers which can be used alone or in mixture with at least one additional nonionic polymer, reference is here made in particular to copolymers of N- octyl acrylamide, (meth)acrylic acid and tert.-butyl aminoethyl methacrylate of the type "Amphomer®”; copolymers from methacryloyl ethyl betaine and alkyl meth- acrylates of the type "Yukaformer®", e.g.. the butyl methacrylate copolymer
  • Yukaformer® Am75 copolymers from monomers containing carboxyl groups and sulfonic groups, e.g.. (meth)acrylic acid and itaconic acid, with monomers such as mono- or dialkyl aminoalkyl (meth)acrylates or mono- or dialkyl aminoalkyl (meth)- acrylamides containing basic groups, in particular amino groups; copolymers from N- octyl acrylamide, methyl methacrylate, hydroxypropyl methacrylate, N-tert.-butyl aminoethyl methacrylate and acrylic acid, as well as the copolymers known from US- A 3,927,199.
  • Suitable anionic polymers alone or in combination with non-ionic polymers are vinyl - alkyl ether, in particular methyl vinyl ether/maleic acid copolymers, obtained by hydrolysis of vinyl ether/maleic anhydride copolymers, distributed under the trade name "Gantrez® AN or ES”. These polymers may also be partly esterified, as for example, “Gantrez® ES 225" or “ES 435", the ethyl ester of an ethyl vinyl vinyl
  • anionic polymers are in particular vinyl acetate/crotonic acid or vinyl acetate/vinyl neodecanoate/crotonic acid copolymers of the type "Resyn®”; sodium acrylate/vinyl alcohol copolymers of the type “Hydagen® F", sodium polystyrene sulfonate, e.g..
  • anionic polymers are Acrylate copolymers available under trade name Salcare SC 81 , PEG/PPG 25/25 dimethicone / acrylate copolymer available under trade name Luviglex Silk from BASF, Acrylates/t-butylacrylamide copolymer available under trade name Ultrahold Strong, Advantage LC-E which is
  • Composition of the present invention can comprise cationic polymers alone or in combination with non-ionic polymer.
  • cationic cellulose type polymers know as Polymer JR type from Amerchol such as Polyquaternium 10 or cationic guar gum known with trade name Jaguar from Rhone-Poulenc and chemically for example Guar hydroxypropyl trimonium chloride.
  • chitosan and chitin can also be included in the compositions as cationic natural polymers.
  • Polyquaternium may as well be added into the compositions of the present invention. Typical examples of those are Polyquaternium 6, Polyquaternium 7, Polyquaternium
  • Polyquaternium 11 Polyquaternium 16, Polyquaternium 22 and Polyquaternium 28, Polyquaternium 30, Polyquaternium 37, Polyquaternium 36, Polyquaternium 46, Polyquaternium 24, Polyquaternium 67, and Polyquaternium 72.
  • the cationic polymers also include the quaternized products of graft polymers from organopolysiloxanes and polyethyl oxazolines described in EP-A 524 612 and EP-A 640 643. Among these especially preferred is the compound know with the INCI name Polysilicone-9.
  • composition can comprise at least one natural starch.
  • Preferred are wheat, rice, potato, corn starches.
  • Most preferred is rice starch and at a concentration of 0.1 to 25%, preferably 1.5 to 20%, more preferably 2.5 to 15 and most preferably 4 to 15% by weight calculated to total composition.
  • compositions of the present invention comprises at least one synthetic or natural oil.
  • any oil allowed for cosmetic use is suitable for the compositions of the present invention.
  • Oils are those of synthetic and of natural ones. Natural oils are in principal any triglyceride suitable for cosmetic use. Non-limiting examples are avocado oil, coconut
  • compositions of the present invention can contain mixture of one or more natural oils and mineral oil.
  • suitable synthetic oil components are in particular fatty alcohol fatty acid esters such as isopropyl myristate, palmitate, stearate and isostearate, oleyl oleate, isocetyl stearate, hexyl laurate, dibutyl adipate, dioctyl adipate, myristyl myristate, oleyl erucate, polyethylene glycol and polyglyceryl fatty acid esters, cetyl palmitate, etc.
  • fatty alcohol fatty acid esters such as isopropyl myristate, palmitate, stearate and isostearate, oleyl oleate, isocetyl stearate, hexyl laurate, dibutyl adipate, dioctyl adipate, myristyl myristate, oleyl erucate, polyethylene glycol and polyglyceryl fatty acid esters, cetyl palmitate
  • Synthetic ones are those of silicone oils.
  • any silicone oil either volatile and/or non-volatile is suitable for the compositions of the present invention.
  • Preferred silicone oils are non-volatile silicone oils known with their INCI name as dimethicone and dimethiconol.
  • Volatile silicone oils such as cyclomethicones may be used in combination with non-volatile silicones and/or other wax and/or oils mentioned above.
  • Commercially, they are available from various companies for example Dow Corning with the known DC series, Wacker Chemie and Toray silicones. All commercially available non volatile silicones are suitable in the compositions of the present invention. Examples to those are DC 200 series, DC1401 , DC 1403, DC 1501 and DC 1503.
  • aminated silicones such as amodimethicone and arylated silicones comprising at least one aryl group in its molecule such as phenyl methicone, phenyl trimethicone, diphenyl dimethicone, diphenylsiloxy phenyl trimethicone, tetramethyl tetraphenyl trisiloxane, triphenyl trimethicone, tetramethyl tetraphenyl trisiloxane and trimethyl pentaphenyl trisiloxane can be advantageously comprised in the compositions of the present invention.
  • Concentration of one or more oil in the compositions of the present invention is between 0.01 and 10%, preferably 0.05 and 7.5% more preferably 0.1 and 5% and most preferably 0.25 and 2.5% by weight calculated to total composition.
  • compositions of the present invention may also comprise wax. Suitable and preferred examples are petrolatum, ozokerit, carnauba wax, paraffin, lanolin wax, candelila wax, bees wax, microcrystalline wax and cocoglycerides. Concentration of wax may be in the range of 0.01 to 10%, preferably 0.05 to 5% by weight calculated to total composition.
  • Compositions of the present invention may comprise one or more surfactant for solubilising of one or more ingredients not soluble in the medium used or especially for the foam aerosol composition for achieving required foam especially the styling polymer when present does not have such properties. Suitable ones are of anionic, non-ionic, amphoteric and cationic surfactants or their mixtures.
  • any cationic surfactant is suitable for the compositions of the present invention.
  • at least one cationic surfactant is selected from the compounds with the general formula
  • Ris a saturated or unsaturated, branched or non-branched alkyl chain with 8- 22 C atoms or
  • R 5 CO NH (CH 2 ) n where R 5 is saturated or unsaturated, branched or non-branched alkyl chain with 7- 21 C atoms and n has typical value of 0 - 4 or
  • R 6 CO O (CH 2 ) n where R 6 is saturated or unsaturated, branched or non-branched alkyl chain with 7- 21 C atoms and n has typical value of 0 - 4, and and R 2 , Rs and R 4 are independent from each other H or lower alkyl chain with 1 to 4 carbon atoms or ethoxy or propoxy group with number of ethoxy or propoxy groups varying in the range of 0 to 4, and X is chloride, bromide or methosulfate.
  • Non-limiting examples to suitable cationic surfactants are cetyl trimethyl ammonium chloride, myristoyi trimethyl ammonium chloride, behentrimonium chloride, trimethyl cetyl ammonium bromide, stearyl trimethyl ammonium chloride, dimethyl stearyl ammonium chloride, stearamidopropyldimethyl ammonium chloride.
  • Suitable non-ionic surfactants are alkyl polyglucosides of the general formula
  • R 7 - 0 - (R 8 0) n O - Z x wherein R 7 is an alkyl group with 8 to 18 carbon atoms, Rs is an ethylene or propylene group, Z is a saccharide group with 5 to 6 carbon atoms, n is a number from 0 to 10 and x is a number between 1 and 5. Examples are decyl polyglucoside, cocoyl polyglucoside both are commercially available.
  • nonionic surfactant components are, for example, long-chain fatty acid mono- and dialkanolamides, such as coco fatty acid mono and di ethanolamide and myristic fatty acid mono and di ethanolamide.
  • nonionic surfactants are, for example, the various sorbitan esters, such as polyethylene glycol sorbitan stearic acid ester, fatty acid polyglycol esters or poly-condensates of ethyleneoxide and propyleneoxide, as they are on the market, for example, under the trade name "Pluronics R ".
  • nonionic surfactants useful in the compositions according to invention are C 10 -C 2 2-fatty alcohol ethoxylates. Suitable non-limiting examples are oleth-10, oleth- 11 , oleth-12, oleth-15, oleth-16, oleth-20, oleth-25, oleth-30, oleth-35, oleth-40, laureth-10, laureth-1 , laureth-12, laureth-13, laureth-15, laureth-16, laureth-20, laureth-25, laureth-30, laureth-35, laureth-40, laureth-50, ceteth-10, ceteth-12, ceteth-14, ceteth-15, ceteth-16, ceteth-17, ceteth-20, ceteth-25, ceteth-30, ceteth-40, ceteth-45, cetoleth-10, cetoleth-12, cetoleth-14, cetoleth-15, cetoleth-16, cetoleth-17
  • non-ionic surfactants within the meaning of the present invention are:
  • polyalkyleneglycol ether of fatty acid glyceride or partial glyceride with at least 30 polyalkylene units are with 30 to 1000, preferably 30 to 500, more preferably 30 to 200 and most preferably 40 to 100 polyethyleneglycol units.
  • Examples to those are PEG-30 hydrogenated castor oil, PEG-35 hydrogenated castor oil, PEG-40 hydrogenated castor oil, PEG-45 hydrogenated castor oil, PEG-50 hydrogenated castor oil, PEG-55 hydrogenated castor oil, PEG-60 hydrogenated castor oil, PEG-65 hydrogenated castor oil, PEG-80 hydrogenated castor oil, PEG-100 hydrogenated castor oil, PEG-200 hydrogenated castor oil, PEG-35 castor oil, PEG-50 castor oil, PEG-55 castor oil, PEG- 60 castor oil, PEG-80 castor oil, PEG-100 castor oil, PEG-200 castor oil. Additional examples of similar compounds can be found in the cosmetic ingredient dictionaries and cosmetic textbooks.
  • non-ionic surfactants are monoglycerides such as glyceryl stearate, glyceryl palmitate, glyceryl myristate, glyceryl behenate.
  • compositions according to the invention can also contain amphoteric or zwitterionic surfactants.
  • amphoteric or zwitterionic surfactants Useful as such are in particular the various known betaines such as alkyl betaines, fatty acid amidoalkyl betaines and sulfobetaines, for example, lauryl hydroxysulfobetaine; long-chain alkyl amino acids, such as cocoaminoacetate, cocoaminopropionate and sodium cocoamphopropionate and -acetate.
  • anionic surfactants of the sulfate, sulfonate, carboxylate and alkyl phosphate type for example, the known C-i 0 -Ci8-alkyl sulfates, and in particular the respective ether sulfates, for example, C 12- Ci 4 -alkyl ether sulfate, lauryl ether sulfate, especially with 1 to 4
  • ether monoglyceride (ether) sulfates, fatty acid amide sulfates obtained by ethoxylation and subsequent sulfatation of fatty acid alkanolamides, and the alkali salts thereof, as well as the salts of long-chain mono-, di- or tri alkyl phosphates.
  • Additional anionic surfactants useful are a-olefin sulfonates or the salts thereof, and in particular alkali salts of sulfosuccinic acid semiesters, for example, the disodium salt of monooctyl sulfosuccinate and alkali salts of long-chain monoalkyl
  • Suitable surfactants of the carboxylate type are alkyl polyether carboxylic acids and the salts thereof of the formula
  • R 9 - (C 2 H 4 O) n - O - CH 2 COOX wherein Rg is a C8-C 2 o-alkyl group, preferably a Ci 2 -Ci 4 -alkyl group, n is a number from 1 to 20, preferably 2 to 17, and X is H or preferably a cation of the group sodium, potassium, magnesium and ammonium, which can optionally be
  • anionic surfactants are also Cs-C ⁇ -acyl aminocarboxylic acids or the water-soluble salts thereof.
  • N-lauroyl glutamate in particular as sodium salt, as well as, for example, N-lauroyl sarcosinate, N-C ⁇ -C ⁇ -acyl asparaginic acid, N-myristoyl sarcosinate, N-oleoyl sarcosinate, N-lauroyl
  • Concentration of one or more surfactant in the compositions according to present invention is in the range of 0.01 to 5%, preferably 0.05 to 2.5% and more preferably 0.1 to 1 % by weight calculated to total composition.
  • Preferred surfactants are non- ionic, amphoteric and cationic ones. The most preferred is non-ionic surfactants.
  • composition of the present invention may comprise polyols at a concentration of 0.5 to 15%, preferably 1 to 10%, more preferably 2 to 5% by weight calculated to the total concentration .
  • the most preferred ones are glycerine, propylene glycols, butylene glycol and hexylene glycol.
  • the compositions according to the invention may also comprise further agents, such as proteins, for example bamboo protein, and protein hydrolyzates and polypeptides, e.g. keratin hydrolyzates, collagen hydrolyzates of the type "Nutrilan ® " or elastin hydrolyzates, as well as, in particular vegetable, optionally cationized protein hydrolyzates, for example "Gluadin ®” .
  • Additional natural plant extracts can as well form part of the compositions of the present invention. Those are incorporated usually in an amount of about 0.01 % to about 5 %, preferably 0.05 % to 3.5 %, in particular 0.1 % to 2 % by weight, calculated as dry residue thereof to the total composition .
  • Suitable aqueous e.g.
  • alcoholic or hydro-alcoholic plant extracts known per se are in particular extracts from leaves, fruits, blossoms, roots, rinds or stems of aloe, pineapple, artichoke, arnica, avocado, valerian, bamboo, henbane, birch, stinging nettle, echinacea, ivy, wild angelica, gentian, ferns, pine needles, silver weed, ginseng, broom, oat, rose hip, hamamelis, hay flowers, elderberry, hop, coltsfoot, currants, chamomile, carrots, chestnuts, clover, burr root, coconut, cornflower, lime blossom, lily of the valley, marine algae, balm, mistletoe, passion flower, ratanhia, marigold, rosemary, horse chestnut, pink hawthorn, sage, horsetail, yarrow, primrose, nettle, thyme, walnut, wine leaves, white hawthorn, etc.
  • Suitable trade products are, for example, the various "Extrapon®" products,
  • compositions of the present invention may contain UV filters either for stabilization of the product colour and/or for protection of hair from environmental influences such as loss of elasticity, loss of hair colour (bleaching effect of sun light).
  • Suitable UV- absorbing substance are Polysilicone-15, 4-Aminobenzoic acid and the esters and salts thereof, 2-phenyl benzimidazole-5-sulfonic acid and the alkali and amine salts thereof, 4-dimethyl aminobenzoic acid and the esters and salts thereof, cinnamic acid and the esters and salts thereof, 4-methoxycinnamic acid and the esters and salts thereof, salicylic acid and the esters and salts thereof, 2,4-dihydroxybenzophenone, 2 > 2',4,4'-tetrahydroxy- benzophenone, 2-hydroxy-4-methoxybenzophenone and its 5- sulfonic acid or the sodium salt thereof, 2,2'-dihydroxy-4,4'-dimethoxybenzophenone, 2-hydroxy
  • the suitable amount of the UV-absorber ranges from about 0.01 % to 1% by weight, calculated to the total composition . Attention should be paid to the stability and solubility especially when using UV filter as salts, e.g. anionic UV filter salts.
  • compositions of the present invention can contain one or more organic solvents within the scope of the invention, Suitable ones are ethanol, propanol, isopropanol, isopentane, n-pentane, n.hexane, dimethoxymethane, benzyl alcohol,
  • benzyloxyethanol alkylene carbonates such as ethylene carbonate and propylene carbonate, phenoxyethanol, butanol, isobutanol, cyclohexane, cyclohexanol, ethylenecarbonate, ethyleneglycol monoethylether, ethylene glycol monobutyl ether, ethylene glycol monophenyl ether, 1-phenylethylalcohol, 2-phenylethylalcohol, o- methoxyphenol.
  • the most preferred organic solvents are ethanol, isopropanol and propanol. Concentration of solvents is in the range of 0 to 80% and preferably 5 to 70%, more preferably 10 to 60% and most preferably 10 to 50% by weight calculated to total composition.
  • compositions of the present invention may further comprise polyethyleneglycols Suitable non- limiting examples are PEG-14, PEG-20, PEG-23, PEG-25, PEG-90, PEG-115, PEG-160, PEG-14M, PEG-20M, PEG-23M, PEG-25M, PEG-90M, PEG- 115M, PEG-160M, etc.
  • PEG-14 PEG-20, PEG-23, PEG-25, PEG-90, PEG-115, PEG-160, etc.
  • polyethyleneglycol one or mixture of more than one, is in the range of 0.05% to 2.5%, preferably 0.1 % to 1.5% and most preferably between 0.1 to 1.0% by weight calculated to total composition.
  • the compositions comprise at least one direct dye for colouring hair.
  • Suitable direct dyes are cationic, anionic, neutral dyes and their mixtures as available commercially from various suppliers and used mainly in semipermanent hair coloration.
  • Non-limiting examples to cationic dyes are Basic Blue 6, Basic Blue 7, Basic Blue 9, Basic Blue 26, Basic Blue 41 , Basic Blue 99, Basic Brown 4, Basic Brown 16, Basic Brown 17, Basic Orange 31 , Natural Brown 7, Basic Green 1 , Basic Red 2, Basic Red 12 Basic Red 22, Basic Red 51 , Basic Red 76, Basic Violet 1 , Basic Violet 2, Basic Violet 3, Basic Violet 10, Basic Violet 14, Basic Yellow 57 and Basic Yellow 87.
  • Suitable direct dyes are anionic dye.
  • Suitable non-limiting examples are Acid Black 1 , Acid Blue 1 , Acid Blue 3, Food Blue 5, Acid Blue 7, Acid Blue 9, Acid Blue 74, Acid Orange 3, Acid Orange 6, Acid Orange 7, Acid Orange 10, Acid Red 1 , Acid Red 14, Acid Red 18, Acid Red 27, Acid Red 50, Acid Red 52, Acid Red 73, Acid Red 87, Acid Red 88, Acid Red 92, Acid Red 155, Acid Red 180, Acid Violet 9, Acid Violet 43, Acid Violet 49, Acid Yellow 1 , Acid Yellow 23, Acid Yellow 3, Food Yellow No. 8, D&C Brown No. 1 , D&C Green No. 5, D&C Green No. 8, D&C Orange No. 4, D&C Orange No. 10, D&C Orange No. 11 , D&C Red No.
  • Suitable dyes for colouring hair within the meaning of the present invention are those of neutral nitro dyes.
  • Suitable non-limiting examples are HC Blue No.2, HC Blue No.4, HC Blue No.5, HC Blue No.6, HC Blue No.7, HC Blue No.8, HC Blue No.9, HC Blue No.10, HC Blue No.11 , HC Blue No.12, HC Blue No.13, HC Brown No.1 , HC Brown No.2, HC Green No.1 , HC Orange No.1 , HC Orange No.2, HC Orange No.3, HC Orange No.5, HC Red BN, HC Red No.1 , HC Red No.3, HC Red No.7, HC Red No.8, HC Red No.9, HC Red No.10, HC Red No.11 , HC Red No.13, HC Red No.54, HC Red No.14, HC Violet BS, HC Violet No.1 , HC Violet No.2, HC Yellow No
  • dyestuffs are also used especially the anionic ones for product colouring at reduced concentrations.
  • Concentration of direct dyes in the compositions of the present invention is within the range of 0.001 to 5%, preferably 0.01 to 3% and more preferably 0.05 to 2%, and most preferably 0.1 to 1% by weight calculated to total composition, calculated to total composition.
  • composition of the present invention comprises additionally at least one propellant.
  • compositions of the present invention comprises at least one propellant at a concentration of 5 to 60%, preferably 5 to 50% more preferably 10 to 50% by weight calculated to total composition.
  • Suitable propellants are lower alkanes such as n- butane, i-butane, propane, butane or their mixtures, as well as dimethylether (DME) either alone or in mixture with lower alkanes.
  • Further suitable propellants are fluorinated hydrocarbons such as 1 ,1-difluoro ethane or tetrafluoroethane or their mixtures with each other, carbon dioxide and nitogen or their mixtures with the above mentioned propellants.
  • Preferred are lower alkanes such as propane, butane, n- butane, i-butane, and their mixtures and their mixture with DME at a alkane to DME weight ratio 10:1 to 1 :10.
  • compositions of the present invention can comprise all substances customarily found in such preparations. Examples of such substances are
  • the above composition was prepared by dissolving - dispersing all ingredients one by one in ethanol.
  • composition was filled into an aerosol can with 55% by weight bulk, 40% by weight propane/butane and 5% by weight dimethylether, all values are calculated to total composition.
  • the hair styled with the above composition is excellently styled and has excellent natural touch and has not lost its shine.
  • Polymers and carnosine are dissolved/dispersed in ethanol, fragrance and trimethyl pentaphenyl trisiloxane is dissolved/mixed first with PEG-40 hydrogenated castor oil and than added to the solution of polymers in ethanol. Finally, the composition is made up to 100% by adding water.
  • Vinylacetate/crotonic acid copolymer 3.6 (Aristoflex A 60)
  • composition is prepared in the same way as in Example 2.
  • Example 5 The composition is prepared in the same way as in Example 2.
  • Example 5 The composition is prepared in the same way as in Example 2.
  • composition is prepared in the same way as in Example 2.
  • Neutralizing agents q.s to pH 6.5
  • Polyquaternium-11 2.0 (Gafquat 440)
  • VPA A Copolymer (Luviskol VA 64W) 4.0
  • Example 11 The composition is prepared in the same way as in Example 2. The solution into an aerosol can with a propellant mixture of propane/butane at a liquid composition to propellant ratio of 90:10. Example 11
  • composition is prepared in the same way as in Example .
  • the solution is filled into an aerosol can with a propellant mixture of propane/butane at a liquid composition to propellant ratio of 95:5.
  • composition is filled at a weight ratio of 60 to 40 lotion to propellant mixture of Dimethylether and n-Pentane (1 :1)
  • the above composition is filled at a weight ratio of 55 to 45 lotion to propellant of n- Pentane.
  • the above formulation was filled with propane/butane as a propellant at a weight ratio of lotion to propellant of 90/10.
  • the above formulation was filled with propane/butane as a propellant at a weight ratio of lotion to propellant of 92/8.

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Abstract

La présente invention concerne une composition de coiffage pour fibres kératiniques, notamment pour les cheveux, qui comprend au moins un polymère filmogène et au moins un dipeptide.
PCT/EP2010/007344 2009-12-10 2010-12-03 Composition de coiffage Ceased WO2011069618A2 (fr)

Priority Applications (3)

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US13/512,930 US20130017157A1 (en) 2009-12-10 2010-12-03 Hair styling composition
EP10785358.2A EP2509572B1 (fr) 2009-12-10 2010-12-03 Composition de coiffage
US15/402,382 US20170119651A1 (en) 2009-12-10 2017-01-10 Hair styling composition

Applications Claiming Priority (2)

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EP09015273.7 2009-12-10
EP09015273A EP2332518A1 (fr) 2009-12-10 2009-12-10 Composition de coiffure comprenant du dipeptide

Related Child Applications (2)

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US13/512,930 A-371-Of-International US20130017157A1 (en) 2009-12-10 2010-12-03 Hair styling composition
US15/402,382 Continuation US20170119651A1 (en) 2009-12-10 2017-01-10 Hair styling composition

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WO2011069618A2 true WO2011069618A2 (fr) 2011-06-16
WO2011069618A3 WO2011069618A3 (fr) 2012-03-08

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US9645391B2 (en) 2013-11-27 2017-05-09 Tokyo Electron Limited Substrate tuning system and method using optical projection
US20160306278A1 (en) * 2015-04-20 2016-10-20 Tokyo Ohka Kogyo Co., Ltd. Chemical for photolithography with improved liquid transfer property and resist composition comprising the same
CN114292541A (zh) * 2021-12-23 2022-04-08 南通纳尔材料科技有限公司 一种光学透明抗污耐刮擦保护膜组合物

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DE2521960A1 (de) 1974-05-16 1976-04-08 Oreal Neue kosmetische mittel auf der basis von quaternisierten polymeren
DE2811010A1 (de) 1977-03-15 1978-09-28 Oreal Mittel und verfahren zur behandlung von keratinmaterialien mit kationischen und anionischen polymeren
DE3044738A1 (de) 1979-11-28 1981-06-19 L'Oreal, 75008 Paris Mittel und verfahren zur behandlung von keratinfasern
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EP0337354A1 (fr) 1988-04-12 1989-10-18 Kao Corporation Composition détergente faiblement irritante
EP0524612A2 (fr) 1991-07-22 1993-01-27 Kao Corporation Composition cosmétique contenant du silicone modifié
EP0640643A2 (fr) 1993-08-10 1995-03-01 Kao Corporation Organopolysiloxanes et procédé de fixation de la chevelure les utilisant

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20140186270A1 (en) * 2012-12-28 2014-07-03 L'oreal Cosmetic compositions containing a silicone-organic polymer hybrid compound
US9456978B2 (en) * 2012-12-28 2016-10-04 L'oreal Cosmetic compositions containing a silicone-organic polymer hybrid compound

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US20130017157A1 (en) 2013-01-17
EP2509572A2 (fr) 2012-10-17
US20170119651A1 (en) 2017-05-04
WO2011069618A3 (fr) 2012-03-08
EP2509572B1 (fr) 2017-06-28
EP2332518A1 (fr) 2011-06-15

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