[go: up one dir, main page]

WO2011045592A1 - Procédé, composition, dispositif et utilisation de ceux-ci pour réduire le volume d'une mousse - Google Patents

Procédé, composition, dispositif et utilisation de ceux-ci pour réduire le volume d'une mousse Download PDF

Info

Publication number
WO2011045592A1
WO2011045592A1 PCT/GB2010/051711 GB2010051711W WO2011045592A1 WO 2011045592 A1 WO2011045592 A1 WO 2011045592A1 GB 2010051711 W GB2010051711 W GB 2010051711W WO 2011045592 A1 WO2011045592 A1 WO 2011045592A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
foam
aluminium
aluminium salt
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/GB2010/051711
Other languages
English (en)
Inventor
John Craven
Gordon Craven
Stuart Craven
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
SUD OFF Ltd
Original Assignee
SUD OFF Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by SUD OFF Ltd filed Critical SUD OFF Ltd
Publication of WO2011045592A1 publication Critical patent/WO2011045592A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0026—Low foaming or foam regulating compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D19/00—Degasification of liquids
    • B01D19/02—Foam dispersion or prevention
    • B01D19/04—Foam dispersion or prevention by addition of chemical substances
    • B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D19/00—Degasification of liquids
    • B01D19/02—Foam dispersion or prevention
    • B01D19/04—Foam dispersion or prevention by addition of chemical substances
    • B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
    • B01D19/0409—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing Si-atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D19/00—Degasification of liquids
    • B01D19/02—Foam dispersion or prevention
    • B01D19/04—Foam dispersion or prevention by addition of chemical substances
    • B01D19/0404—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance
    • B01D19/0427—Foam dispersion or prevention by addition of chemical substances characterised by the nature of the chemical substance compounds containing halogen-atoms
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02—Inorganic compounds ; Elemental compounds
    • C11D3/04—Water-soluble compounds
    • C11D3/042—Acids

Definitions

  • the present invention relates to a method, composition and device for reducing the volume of foam, and to the use of said method, composition and device.
  • the present invention relates to the use of a composition and optionally an associated device in the destruction of foam as is typically formed by surfactants on the surface of fluids, and as is typically deposited on surfaces.
  • foam on the surface of fluids, such as water
  • fluids such as water
  • Foam is often formed when surfactants are added to water.
  • the use of washing up liquid, soap or bubble bath in water can create a layer of foam on top of the water.
  • this layer of foam often settles on the vessel in which the water was held, for example, a bath or sink.
  • the problems outlined above can reduce the speed at which fluids can be processed and can reduce the availability of process equipment due to, for example, cleaning of the vessels. Cleaning of the vessels can also prove problematic as foam often forms on the top of cleaning solutions used to clean such vessels. This fluid may also be deposited on the surface of the vessel when the cleaning solutions are drained from the vessels. Again, in order to remove the foam, it is common practice to rinse the vessel with water several times. This rinsing process uses copious amounts of water, and thus is environmentally unsound and expensive.
  • a further object of the invention is to provide a composition and method of use thereof to destroy, or at least reduce the volume of, foam.
  • composition comprising an aluminium salt in the reduction in volume of foam.
  • volume of foam is reduced by at least 50 % by volume
  • the reduction in volume may result in the destruction of foam.
  • the foam is typically a surfactant-based foam.
  • the surfactant-based foam may be the result of the use of a domestic and/or industrial cleaning agent.
  • Typical domestic and industrial cleaning agents include: soap, shower gel, washing up liquid, bubble bath and industrial cleaning solutions.
  • composition comprises from about 2 % w/w to about 8 % w/w aluminium salt.
  • the composition comprises at least about 2 % w/w aluminium salt, more typically at least about 4 % w/w aluminium salt, most typically at least about 8 % w/w aluminium salt.
  • the particle size of the aluminium salt may be from about 0.1 to about 200 ⁇ .
  • the mean particle size may be from about 3 to about 20 ⁇ .
  • the mean particle size is from about 20 to about 50 ⁇ . In another alternative, the mean particle size is from about 0.1 to about 3 ⁇ .
  • the aluminium salt may be selected from the group consisting of:
  • aluminium chlorohydrate aluminium chloride, aluminium zirconium tetrachlorohydrex and aluminium zirconium chlorohydrate.
  • the aluminium salt is aluminium chlorohydrate.
  • the inventors have surprisingly found that aluminium salts and, in particular, aluminium chlorohydrate and the like, substantially reduce the volume of foam, typically destroying the foam.
  • the foam may be residual foam left on the surfaces of vessels (such as baths, or reactor vessels), or foam that has formed on top of a fluid, such as an aqueous surfactant solution.
  • composition may further comprise a carrier.
  • composition comprises from about 3.1 % w/w to about 12.4 % w/w carrier.
  • the carrier may be selected from the group consisting of: cyclomethicone, dimethicone, and dimethicone copolyol.
  • the carrier is cyclomethicone.
  • composition may further comprise an anti-settling agent.
  • composition comprises from about 0.16 % w/w to about 0.64 % w/w anti-settling agent.
  • the anti-settling agent may be selected from the group consisting of: bentonites, hectorites and montmorillonites.
  • the anti-settling agent is disteardimonium hectorite.
  • composition may further comprise a propellant.
  • the composition typically comprises from about 78.8 % w/w to about 94.8 % w/w propellant.
  • the propellant may be selected from the group consisting of: butane- isobutane-propane and compressed air.
  • the propellant is butane-isobutane-propane.
  • the butane- isobutane-propane may comprise 54 % by volume butane, 24 % by volume isobutane, and 22 % by volume propane.
  • the composition may further comprise an activator.
  • the composition typically comprises from about 0.03 % w/w to about 0.12 % w/w activator.
  • the activator can be chosen from the group consisting of: propylene carbonate and ethanol. Typically, the activator is propylene carbonate.
  • compositions for the reduction in volume of foam comprising at least about 2 % w/w aluminium salt, from about 3.1 % w/w to about 12.4 % w/w carrier, and from about 0.16 % w/w to about 0.64 % w/w anti-settling agent.
  • the reduction in volume may be the destruction of foam, and the foam may be a surfactant-based foam.
  • the surfactant-based foam may be the result of the use of a domestic and/or industrial cleaning agent.
  • the domestic and/or industrial cleaning agent is selected from the group consisting of: soap, shower gel, washing up liquid, bubble bath and industrial cleaning solutions.
  • the composition comprises at least about 4 % w/w aluminium salt, more typically at least about 8 % w/w aluminium salt.
  • composition comprises from about 2 % w/w to about 8 % w/w aluminium salt.
  • the particle size of the aluminium salt is from about 0.1 to about 200 ⁇ .
  • the mean particle size of the aluminium salt may be from about 3 to about 20 ⁇ .
  • the aluminium salt may be selected from the group consisting of:
  • aluminium chlorohydrate aluminium chloride, aluminium zirconium tetrachlorohydrex and aluminium zirconium chlorohydrate.
  • aluminium salt is aluminium chlorohydrate.
  • the carrier may be selected from the group consisting of: cyclomethicone, dimethicone, and dimethicone copolyol.
  • the carrier is cyclomethicone.
  • the anti-settling agent may be selected from the group consisting of: bentonites, hectorites and montmorillonites.
  • the anti-settling agent is disteardimonium hectorite.
  • composition may further comprise a propellant.
  • the composition comprises from about 78.8 % w/w to about 94.8 % w/w propellant.
  • the propellant may be selected from the group consisting of: butane- isobutane-propane and compressed air.
  • the propellant is butane-isobutane-propane.
  • the butane- isobutane-propane may comprise 54 % by volume butane, 24 % by volume isobutane, and 22 % by volume propane.
  • composition may further comprise an activator.
  • the composition typically comprises from about 0.03 % w/w to about 0.12 % w/w activator.
  • the activator can be chosen from the group consisting of: propylene carbonate and ethanol. Typically, the activator is propylene carbonate.
  • a method of reducing the volume of foam said method involving the step of applying to a body of foam the composition as described herein.
  • composition is applied as an aerosol.
  • a device for reducing the volume of foam comprising the composition as described herein, wherein said device is configured to dispense the composition as an aerosol.
  • composition in accordance with the invention was prepared as follows.
  • a portion of cyclomethicone was added to a mixing vessel containing a high shear mixer.
  • the mixer was operated at high shear and
  • chlorohydrate powder was then added with high shear mixing and the mixing was continued until all of the powder was added, and a
  • the resultant product is a dispersion of aluminium chlorohydrate powder in a volatile silicone oil carrier.
  • An aerosol device (dispenser device) was prepared as follows.
  • a measured amount of the components of the composition (without the butane-isobutane-propane) was added to a can suitable for use as an aerosol can.
  • a measured amount of fragrance can be added.
  • a valve was added to the top of the can and crimped into place. The can was then filled with the suitable measured amount of butane-isobutane- propane (propellant) through the valve.
  • An actuator was placed on the valve stem and was covered with a cap.
  • valve and can are of the conventional type well known in the field of aerosols and propellants, and the valve may include the following components such that it interacts with the actuator, and such that it may allow delivery of substances from within the can.
  • the valve can comprise of a valve cup which sits on top of the can and which contains an orifice through which a stem protrudes.
  • the proximal end of the stem attaches to an actuator, whilst the distal end is in contact with a stem gasket, and a spring that sits in a housing.
  • the housing is attached to a dip tube which extends into the can such that the contents thereof can be delivered through the valve.
  • the aerosol device containing the composition was used to destroy residual foam, which remained in a domestic bath after use, as follows.
  • Test 2 a second test (Test 2) was carried out using the conventional repeated rinsing method to remove the foam from the bath.
  • Test 2 Conventional method
  • the present invention provides a composition for use in the reduction in volume of foam, and in particular in the destruction of foam that has settled on the surface of liquids or solids. Having described examples of specific embodiments, the invention will now be described in general terms.
  • all percentages are by weight based on the entire formulation, including the propellant unless otherwise stated. It will be understood that the amount of propellant used can be varied to ensure that the total amount of components in the formulation adds up to 100 % w/w.
  • compositions as described herein comprise an aluminium salt.
  • the particle size of the aluminium salts often falls within the range of 0.1 to 200 ⁇ with a mean particle size often from 3 to 20 ⁇ . Both larger and smaller mean particle sizes can also be contemplated such as from 20 to 50 m or 0.1 to 3 ⁇ .
  • the aluminium salt used can typically be of the type used in
  • antiperspirants including, for example, aluminium chlorohydrate, aluminium chloride, aluminium zirconium tetrachlorohydrex and aluminium zirconium chlorohydrate.
  • compositions as described herein typically also comprise a carrier.
  • the carrier can be selected from both volatile and non-volatile liquids and mixtures which contain both a volatile and a non-volatile liquid.
  • the relative proportions of the volatile and non-volatile liquids are at the discretion of the user and will usually be chosen in association with the other formulation constituents in order that the formulation exhibits the desired combination of properties.
  • the carrier includes a volatile liquid silicone, i.e. liquid polyorganosiloxane.
  • Volatile polyorganosiloxanes can be linear or cyclic or mixtures thereof. Preferred cyclic siloxanes include
  • polydimethylsiloxanes and particularly those containing from 3 to 9 silicon atoms and preferably not more than 7 silicon atoms and most preferably 4, 5 and/or 6 silicon atoms, otherwise often referred to as cyclomethicones.
  • Preferred linear siloxanes include polydimethylsiloxanes containing from 3 to 9 silicon atoms.
  • the volatile silicones can also comprise branched linear or cyclic siloxanes such as the aforementioned linear or cyclic siloxanes substituted by one or more pendant -O-Si(CH 3 ) 3 groups.
  • examples of commercially available silicone oils include oils having grade designations 344, 345, 244, 245 and 246 from Dow Corning Corporation; Silicone 7207 and Silicone 7158 from Union Carbide Corporation; and SF1202 from General Electric.
  • the carrier employed in many compositions herein can alternatively or additionally comprise non-volatile silicone oils, which include polyalkyl siloxanes, polyalkylaryl siloxanes and polyethersiloxane copolymers.
  • dimethicone and dimethicone copolyols can suitably be selected from dimethicone and dimethicone copolyols.
  • Commercially available non-volatile silicone oils include Dow Corning 556 and Dow Corning 200 series.
  • Silicon-free carriers can be used instead of, or in addition to liquid silicones.
  • Silicon-free hydrophobic organic liquids which can be employed include volatile or non-volatile liquid aliphatic hydrocarbons such as mineral oils or branched aliphatic hydrocarbons often selected to exhibit a low viscosity. Examples of liquid hydrocarbons are hydrogenated polyisobutene, polydecene, and paraffins and/or isoparaffins of at least 10 carbon atoms.
  • Other suitable constituents of hydrophobic carriers are liquid aliphatic or aromatic esters.
  • Suitable aliphatic esters contain at least one long chain alkyl group, such as esters derived from Ci to C20 alkanols esterified with a Cs to C22 alkanoic acid or Ce to C10 alkanedioic acid. These esters include isopropyl myristate, lauryl myristate, isopropyl palmitate, diisopropyl sebacate and diisopropyl adipate.
  • Suitable liquid aromatic esters include fatty alkyl benzoates alkylene dibenzoate, alkoxylated alkyl benzoate or a polyalkylene oxide dibenzoate, or a mixture of two or more.
  • the alkyl group is linear or branched and often contains at least 8 carbons, in many instances up to 25 carbons, e.g. from Cs to C18 or is a mixture, e.g. Ci2 to Ci 5 .
  • the term alkylated herein includes alkylene groups which are terminated at each end with a benzoate group.
  • the alkylene group often contains from 2 to 6 carbons and can be linear or branched, a suitable example of linear being propylene.
  • compositions as described herein typically also comprise an anti- settling agent.
  • the anti-settling agent can be an inorganic material.
  • Commonly used inorganic anti-settling agents are fine particulate silica or silicates. These include fumed silica, e.g. those available from Degussa under the tradename Aerosil.
  • the silicates include complex silicates such as clays, such as bentonite, hectorite or montmorillonite.
  • the anti-settling agent can be disteardimonium hectorite.
  • the surface of the particulate clay can be treated with a hydrophobe so as to render it more compatible with the carrier, as for example in Bentone(TM) 38.
  • Suitable anti-settling agents include structurants such as polyamides as discussed in U.S. Pat. No. 5,500,209, including in particular terpolymers (e.g.
  • Elvvamide 8061 (TM) and polyamides based on complex fatty acids.
  • Such polyamides may be derived from organic diamines containing 2 to 12, preferably 2 to 8 carbon atoms, condensed with di- or poly carboxylic acids containing 4 to 20 carbon atoms per carboxylic acid group
  • Aromatic polyamide resins having pendant silyl groups are described in U.S. Pat. No. 5,243,010.
  • the polyamides can be modified with silicon-containing moieties such as siloxanes containing lower alkyl or phenyl groups, as described for example in U.S. Pat. No. 5,874,069.
  • Alternative polymers are described in U.S. Pat. No. 5,919,441 which are copolymers of organosiloxane diamines with dimeric acids.
  • Related polymers described in U.S. Pat. No. 5,919,441 comprise polyurea in which organosiloxane diamines are reacted with a isocyanurate.
  • a still further class of polymer which are also commonly regarded as a structurant, and that can be used as an anti-settling agent are siloxane elastomers, namely organic polysiloxanes ⁇ , ⁇ which have been cross linked, either lightly or extensively. Cross linking can arise in one way from reaction between Si-H groups and unsaturated groups, such as Si- vinyl groups or ⁇ , ⁇ dienes, typically Pt catalysed.
  • the elastomers are often blends containing absorbed volatile silicones. Examples include DC9010, DC9040 and DC9070 (Dow Corning Inc) KSG-17 (Shin-Etsu).
  • the dispenser can be in the form of an aerosol, typically containing a propellant gas (or gas mixture) such as a butane-isobutane-propane mix.
  • a propellant gas such as a butane-isobutane-propane mix.
  • the butane-isobutane-propane typically comprises 54 % by volume butane, 24 % by volume isobutane, and 22 % by volume propane, although other ratios of components as are known in the art can also be used.
  • An aerosol is understood to be a suspension of fine solid particles or liquid droplets in a gas.
  • Alternative propellant gases include
  • the aerosol can be in the form of a pump spray which are well known mechanisms of providing a fine spray of a composition.
  • compositions as described herein typically also comprise an activator, suitable for activating the anti-settling agent.
  • Suitable activators are polar activators such as low molecular weight compounds of a polar nature.
  • the most commonly used polar activators are propylene carbonate, acetone, methanol/water and ethanol/water.
  • polar activators are propylene carbonate, acetone, methanol/water and ethanol/water.
  • Several other low molecular weight alcohols are also used in the field. When using an alcohol as a polar activator, it may contain at least 5% water. If water is absent the polar activator will not function efficiently, thus reducing final product
  • the activator comprises propylene carbonate or ethanol, or mixtures thereof.
  • the composition described herein can be used in the manufacture of an aerosol. The use of the composition and the aerosol device described herein is effective in the reduction in volume of and/or in the destruction of foam.
  • Optional ingredients in compositions of this invention can include deodorants, for example at a concentration of up to about 10% w/w.
  • Suitable deodorant actives can comprise deoperfumes, and/or
  • microbicides including particularly bactericides, such as chlorinated aromatics, including biguanide derivatives, of which materials known as Triclosan (Igasan DP300(TM)), Tricloban(TM), and Chlorhexidine warrant specific mention.
  • bactericides such as chlorinated aromatics
  • biguanide derivatives of which materials known as Triclosan (Igasan DP300(TM)), Tricloban(TM), and Chlorhexidine warrant specific mention.
  • Another class comprises biguanide salts such as available under the trade mark Cosmosil(TM). Bleaching and/or sanitising agents can also be added to the compositions as described herein.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Toxicology (AREA)
  • Health & Medical Sciences (AREA)
  • Dispersion Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Emulsifying, Dispersing, Foam-Producing Or Wetting Agents (AREA)
  • Inorganic Chemistry (AREA)
  • Detergent Compositions (AREA)
  • Cosmetics (AREA)

Abstract

L'invention concerne une composition comprenant des sels d'aluminium tels que du chlorhydrate d'aluminium, ainsi que des supports et des agents stabilisateurs associés servant à réduire le volume d'une mousse, et l'utilisation de cette composition. Elle concerne en particulier un procédé de fabrication d'une composition d'aérosol et un dispositif d'aérosol associé servant à réduire le volume d'une mousse.
PCT/GB2010/051711 2009-10-12 2010-10-12 Procédé, composition, dispositif et utilisation de ceux-ci pour réduire le volume d'une mousse Ceased WO2011045592A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB0917802A GB0917802D0 (en) 2009-10-12 2009-10-12 Method, composition, device and the use thereof for the reduction in volume of foam
GB0917802.1 2009-10-12

Publications (1)

Publication Number Publication Date
WO2011045592A1 true WO2011045592A1 (fr) 2011-04-21

Family

ID=41402864

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/GB2010/051711 Ceased WO2011045592A1 (fr) 2009-10-12 2010-10-12 Procédé, composition, dispositif et utilisation de ceux-ci pour réduire le volume d'une mousse

Country Status (2)

Country Link
GB (1) GB0917802D0 (fr)
WO (1) WO2011045592A1 (fr)

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1290444A (fr) * 1970-02-02 1972-09-27
US4341656A (en) * 1978-11-03 1982-07-27 Ciba-Geigy Corporation Foam inhibitors and their use for defoaming aqueous systems
US5243010A (en) 1991-03-14 1993-09-07 Korea Research Institute Of Chemical Technology Aromatic polyamide containing pendant silyl groups
EP0578423A2 (fr) * 1992-07-09 1994-01-12 Dow Corning S.A. Méthode pour contrôler de la mousse à l'aide de polyorganosiloxanes
US5500209A (en) 1994-03-17 1996-03-19 The Mennen Company Deodorant and antiperspirant compositions containing polyamide gelling agent
US5874069A (en) 1997-01-24 1999-02-23 Colgate-Palmolive Company Cosmetic composition containing silicon-modified amides as thickening agents and method of forming same
US5919441A (en) 1996-04-01 1999-07-06 Colgate-Palmolive Company Cosmetic composition containing thickening agent of siloxane polymer with hydrogen-bonding groups
US5922308A (en) 1996-06-28 1999-07-13 Chesebrough-Pond's Usa Co., Underarm compositions

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1290444A (fr) * 1970-02-02 1972-09-27
US4341656A (en) * 1978-11-03 1982-07-27 Ciba-Geigy Corporation Foam inhibitors and their use for defoaming aqueous systems
US5243010A (en) 1991-03-14 1993-09-07 Korea Research Institute Of Chemical Technology Aromatic polyamide containing pendant silyl groups
EP0578423A2 (fr) * 1992-07-09 1994-01-12 Dow Corning S.A. Méthode pour contrôler de la mousse à l'aide de polyorganosiloxanes
US5500209A (en) 1994-03-17 1996-03-19 The Mennen Company Deodorant and antiperspirant compositions containing polyamide gelling agent
US5919441A (en) 1996-04-01 1999-07-06 Colgate-Palmolive Company Cosmetic composition containing thickening agent of siloxane polymer with hydrogen-bonding groups
US5922308A (en) 1996-06-28 1999-07-13 Chesebrough-Pond's Usa Co., Underarm compositions
US5874069A (en) 1997-01-24 1999-02-23 Colgate-Palmolive Company Cosmetic composition containing silicon-modified amides as thickening agents and method of forming same

Also Published As

Publication number Publication date
GB0917802D0 (en) 2009-11-25

Similar Documents

Publication Publication Date Title
AU724163B2 (en) Process for preparing silicone elastomer compositions
JP3813179B2 (ja) シリコーンエラストマー類を含有する粉体化粧品組成物
CN1308428C (zh) 香料组合物
CA2631897C (fr) Composition pulverisable de lavage et de cirage a sec et methode d'utilisation
EP3033160B1 (fr) Procédé de formation d'un granule antimousse
KR20040047867A (ko) 유체 흡수성 고체 및 접착성 유체를 함유하는 국소용 조성물
CN105407859A (zh) 氨基有机硅纳米乳液
BG97579A (en) Continuous method for the preparation of paste-like material
EP0812182B1 (fr) Compositions antitranspiration
ZA200308540B (en) Two-phase roll-on cosmetic product.
AU2002348377A1 (en) Viscosity modification of petroleum distillates
EP1439903A2 (fr) Modification de la viscosite de distillats de petrole
US5246972A (en) Polish containing highly adsorptive polymer
JP5257949B2 (ja) シリコーン消泡粒子
EP1811939B1 (fr) Produit aerosol antisudoral dont le conditionnement est traite contre la corrosion
JPH08127719A (ja) アルキルメチルシロキサン含有のゲル
JP4181498B2 (ja) 家具用つや出し組成物
CN1646089A (zh) 防汗剂或者除臭剂组合物
WO2011045592A1 (fr) Procédé, composition, dispositif et utilisation de ceux-ci pour réduire le volume d'une mousse
JP2023086847A (ja) 凍結融解安定性の油中水型乳化洗浄剤及び／又は研磨組成物
AU2004283417B2 (en) Antiperspirant spray compositions
TW200423965A (en) Deodorant spray composition
EP1643963A1 (fr) Principes actifs et compositions antisudorifiques
US20240052268A1 (en) Surface treating formulation and method of making and using the same
WO2025126851A1 (fr) Produit cosmétique eau-dans-huile

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 10775867

Country of ref document: EP

Kind code of ref document: A1

NENP Non-entry into the national phase

Ref country code: DE

122 Ep: pct application non-entry in european phase

Ref document number: 10775867

Country of ref document: EP

Kind code of ref document: A1