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WO2010100309A1 - Procédé et dispositif pour le recyclage et la valorisation de déchets domestiques biodégradables produits dans des habitations de communautés de voisins, au moyen d'installations de production de biogaz pour produire de l'électricité, de l'engrais et pour chauffer l'eau - Google Patents

Procédé et dispositif pour le recyclage et la valorisation de déchets domestiques biodégradables produits dans des habitations de communautés de voisins, au moyen d'installations de production de biogaz pour produire de l'électricité, de l'engrais et pour chauffer l'eau Download PDF

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Publication number
WO2010100309A1
WO2010100309A1 PCT/ES2010/070120 ES2010070120W WO2010100309A1 WO 2010100309 A1 WO2010100309 A1 WO 2010100309A1 ES 2010070120 W ES2010070120 W ES 2010070120W WO 2010100309 A1 WO2010100309 A1 WO 2010100309A1
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WO
WIPO (PCT)
Prior art keywords
biogas
fertilizer
recycling
kitchens
heat water
Prior art date
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Ceased
Application number
PCT/ES2010/070120
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English (en)
Spanish (es)
Inventor
Antonio NÚÑEZ JARAMILLO
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Individual
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Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of WO2010100309A1 publication Critical patent/WO2010100309A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • C02F11/04Anaerobic treatment; Production of methane by such processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M1/00Apparatus for enzymology or microbiology
    • C12M1/107Apparatus for enzymology or microbiology with means for collecting fermentation gases, e.g. methane
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M21/00Bioreactors or fermenters specially adapted for specific uses
    • C12M21/04Bioreactors or fermenters specially adapted for specific uses for producing gas, e.g. biogas
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M43/00Combinations of bioreactors or fermenters with other apparatus
    • C12M43/08Bioreactors or fermenters combined with devices or plants for production of electricity
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M45/00Means for pre-treatment of biological substances
    • C12M45/02Means for pre-treatment of biological substances by mechanical forces; Stirring; Trituration; Comminuting
    • CCHEMISTRY; METALLURGY
    • C12BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
    • C12MAPPARATUS FOR ENZYMOLOGY OR MICROBIOLOGY; APPARATUS FOR CULTURING MICROORGANISMS FOR PRODUCING BIOMASS, FOR GROWING CELLS OR FOR OBTAINING FERMENTATION OR METABOLIC PRODUCTS, i.e. BIOREACTORS OR FERMENTERS
    • C12M45/00Means for pre-treatment of biological substances
    • C12M45/04Phase separators; Separation of non fermentable material; Fractionation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/008Control or steering systems not provided for elsewhere in subclass C02F
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/005Black water originating from toilets
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/10Energy recovery
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/26Reducing the size of particles, liquid droplets or bubbles, e.g. by crushing, grinding, spraying, creation of microbubbles or nanobubbles
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/30Wastewater or sewage treatment systems using renewable energies

Definitions

  • the invention relates to a method and device for recycling and efficientlyzing all biodegradable household waste produced in homes in neighboring communities, as well as optionally biodegradable waste from gardens.
  • Biodegradable household waste is first crushed by means of a disposer disposed in the kitchen sinks and then conducted through a separate network independent from the faecal network of the building to a biogas production plant formed by a group of biogas digesters in phases or single stage, the necessary safety and control mechanisms, a biogas consumer, a biogas tank and a place for the deposition of inert material resulting from the biodigestion of organic waste.
  • composition of the biogas generated is as follows: methane (CH4), CO2 and other chemical compounds.
  • Biogas can be used energy through combustion, its calorific value being 4000 to 6000 Kcal / cubic meter.
  • the digesters will be fed with the crushed material from the kitchens, and the PH, temperature, dilution of the digester content and biogas pressure will be controlled at all times.
  • the system will be equipped at all points with the control mechanisms that guarantee the correct functioning of the device and its safety.
  • the system includes a gas storage device.
  • a gas storage device As a result of the fermentation of the waste, it throws an inert product that will be removed from the digesters. Once properly dried, it can be used as fertilizer. The volume and weight of this product is less than the volume and weight of the waste entering the system.
  • the entire solid by-product of the invention is an organic fertilizer whose weight and dry volume are less than the weight and volume of biodegradable waste that is introduced into the device.
  • the present invention involves a separation of the biodegradable fraction from household waste, so as to facilitate the efficiency of selective collection of urban waste.
  • the present invention assumes, even in the case of landfill disposal of waste residues, a decrease in the volume deposited in landfill.
  • the present invention involves the energy use of biogas.
  • a ton of biodegradable household waste can produce 330 to 550 cubic meters of biogas.
  • landfills and under normal conditions it is not possible to recover more than 220 cubic meters of biogas per ton throughout the life of the landfill, and this through the use of complex design and exploitation technologies and only viable in large landfills. In this way, at least about 110 cubic meters of biogas per ton of biodegradable waste would escape into the atmosphere.
  • Methane is a potent greenhouse gas. A cubic meter of methane has the same greenhouse effect as 23 cubic meters of CO2.
  • leachates whose characteristics vary depending on their age. In general, they are leachates that initially have acidic pH (although over time years tend to equilibrium pH), they have very high rates of BOD (Biochemical Oxygen Demand) and COD (Chemical Oxygen Demand), and may contain a high number of hazardous pollutants, by mobilizing them by dissolution because of their acidic pH. If they are not collected in a controlled manner, they are a potential source of contamination for surface, groundwater and soil in the landfill environment, due to their high potential for ecotoxicity. Even in the case of their collection in a controlled manner, they require very expensive treatments in general to be able to comply with the limits of discharges to channels imposed by water legislation.
  • the present invention prevents the emission of biogas produced by the decomposition of organic matter in landfills.
  • the present invention reduces the risk of combustion and explosions insofar as it uses biodegradable waste by avoiding landfill.
  • the present invention reduces instabilities in landfills by sliding to the extent that it prevents depositing in landfills of biodegradable waste.
  • the present invention facilitates the final closure of the landfill by reducing instability due to the lower deposit in the landfill of biodegradable waste.
  • it reduces the difficulty of vegetation in landfill closure works as a result of the displacement of oxygen in the substrate.
  • To the extent that it reduces the deposit in landfills of biodegradable waste it reduces the generation of leachate and with it the risks of contamination of water and soil.
  • the present invention involves the energy use of biogas.
  • a ton of biodegradable household waste can produce 330 to 550 cubic meters of biogas.
  • In landfills and under normal conditions it is not possible to recover more than 220 cubic meters of biogas per ton throughout the life of the landfill, and this through the use of complex and only viable design and exploitation technologies in large landfills. In this way, at least about 110 cubic meters of biogas per ton of biodegradable waste would escape into the atmosphere.
  • Methane is a potent greenhouse gas. A cubic meter of methane has the same greenhouse effect as 23 cubic meters of CO2.
  • As an order of magnitude, in Spain, 35% of the methane generated comes from landfills and represents 5% of the total greenhouse gases.
  • the waste disposal in landfill is a series of drawbacks, such as:
  • leachates whose characteristics vary depending on their age. In general, they are leachates that initially have acidic pH (although over time years tend to equilibrium pH), they have very high rates of BOD (Biochemical Oxygen Demand) and COD (Chemical Oxygen Demand), and may contain a high number of hazardous pollutants, by mobilizing them by dissolution because of their acidic pH. If they are not collected in a controlled manner, they are a potential source of contamination for surface, groundwater and soil in the landfill environment, due to their high potential for ecotoxicity. Even in the case of their collection in a controlled manner, they require very expensive treatments in general to be able to comply with the limits of discharges to channels imposed by water legislation.
  • Biodegradable household waste is first crushed by a disposer disposed in kitchen sinks, preferably under them and then conducted through a separate network independent from the faecal network of the building to a biogas production plant formed by a group of digesters in phases or single-stage, the necessary safety and control mechanisms, a biogas consumer, a biogas tank and a place for the deposition of inert material resulting from the biodigestion of organic waste.
  • composition of the biogas generated is as follows: methane (CH4), CO2 and other chemical compounds.
  • Biogas can be used energy through combustion, its calorific value being 4000 to 6000 Kcal / cubic meter.
  • This biogas is consumed in the biogas consumer, and used to produce electrical, mechanical or water heating.
  • the digesters will be fed with the crushed material from the kitchens, and the PH, temperature, dilution of the digester content and biogas pressure will be controlled at all times.
  • the system includes a gas storage device.
  • the volume and weight of the inert product that is formed as a result of the biodigestion of organic waste is less than the volume and weight of the waste entering the system.
  • the entire inert by-product of the invention is an organic fertilizer whose weight and dry volume are less than the weight and volume of biodegradable waste that is introduced into the device.
  • the present invention reduces the emission into the atmosphere of biogas, one of whose components is methane gas, which has a potent greenhouse effect.
  • Biogas can be used energy through combustion, its calorific value being 4000 to 6000 Kcal / cubic meter.
  • the invention yields an inert product that will be removed from the digesters. Once properly dried It can be used as fertilizer. [57] The volume and weight of this product is less than the volume and weight of the waste entering the system. [58] The present invention reduces the risk of combustion and explosions insofar as it uses biodegradable waste by avoiding landfill. [59] The present invention reduces instabilities in landfills by sliding to the extent that it prevents depositing in landfills of biodegradable waste. [60] The present invention facilitates the final closure of the landfill by reducing instability due to the lower deposit in the landfill of biodegradable waste.
  • FIGURE 1 schematically depicts the operation of the invention, which consists of the following elements: [64] • Crusher of organic waste in each of the community kitchens
  • Biogas plant (4) which is schematically represented by:

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Organic Chemistry (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Microbiology (AREA)
  • Genetics & Genomics (AREA)
  • Molecular Biology (AREA)
  • Biotechnology (AREA)
  • Sustainable Development (AREA)
  • General Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Biomedical Technology (AREA)
  • General Health & Medical Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Analytical Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • Processing Of Solid Wastes (AREA)
  • Fertilizers (AREA)

Abstract

La présente invention concerne un procédé et un dispositif pour le recyclage et la valorisation de déchets domestiques biodégradables produits dans des habitations de communautés de voisins, au moyen d'installations de production de biogaz préfabriquées pour produire de l'électricité, de l'engrais et pour chauffer l'eau. Les déchets sont broyés dans un broyeur placé dans les éviers des cuisines et sont conduits par un réseau séparé du réseau des matières fécales jusqu'à une installation de production de biogaz formée de digesteurs dans lesquels est produit du biogaz suite à la digestion anaérobie. Des mécanismes de sécurité et de contrôle, un brûleur de biogaz, un réservoir de biogaz et un lieu pour l'entreposage de la matière inerte résultant de la biodigestion sont prévus. Cette matière peut être utilisée comme engrais. Éventuellement les déchets peuvent provenir de jardins. Le biogaz est consumé dans le brûleur de biogaz et on l'utilise pour la production d'énergie électrique, mécanique ou pour le chauffage de l'eau. L'énergie électrique générée peut être injectée dans le réseau.
PCT/ES2010/070120 2009-03-06 2010-03-04 Procédé et dispositif pour le recyclage et la valorisation de déchets domestiques biodégradables produits dans des habitations de communautés de voisins, au moyen d'installations de production de biogaz pour produire de l'électricité, de l'engrais et pour chauffer l'eau Ceased WO2010100309A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
ESP200900646 2009-03-06
ES200900646A ES2410261B1 (es) 2009-03-06 2009-03-06 Procedimiento para reciclaje y valoración de los residuos orgánicos producidos en las cocinas en comunidades de vecinos, mediante plantas de biogás prefabricadas para producir electricidad y abono.

Publications (1)

Publication Number Publication Date
WO2010100309A1 true WO2010100309A1 (fr) 2010-09-10

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PCT/ES2010/070120 Ceased WO2010100309A1 (fr) 2009-03-06 2010-03-04 Procédé et dispositif pour le recyclage et la valorisation de déchets domestiques biodégradables produits dans des habitations de communautés de voisins, au moyen d'installations de production de biogaz pour produire de l'électricité, de l'engrais et pour chauffer l'eau

Country Status (2)

Country Link
ES (1) ES2410261B1 (fr)
WO (1) WO2010100309A1 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013190361A1 (fr) * 2012-06-20 2013-12-27 Teller Yair Système et procédé pour la production de biogaz et d'engrais à partir de déchets organiques domestiques
US9688585B2 (en) 2013-06-18 2017-06-27 Ecogas Israel Ltd Lightweight assemblable appliance and respective method for production of biogas and liquid fertilizer
US11866381B2 (en) 2017-06-25 2024-01-09 Home Biogas Ltd Lightweight appliance with exoskeletal support respective kit-of-parts and method for production of biogas and liquid fertilizer

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4594078A (en) 1982-12-08 1986-06-10 Maurice Guerin Continuous digester of the production of biomethane for organic substances
JPH0824891A (ja) * 1994-07-08 1996-01-30 Chiyoda Corp 生ゴミの生物処理方法及びその装置
DE4446661C1 (de) * 1994-12-19 1996-02-08 B A N S Biolog Abfall Nutzungs Verfahren und Anlage zur anaeroben Aufbereitung von Lebensmittelabfällen
DE19538579C1 (de) 1995-10-17 1997-04-03 Karl Weitz Anlage zur Herstellung von Biogas aus organischen Stoffen
DE19800900A1 (de) * 1998-01-13 1999-07-15 Bsbg Bremer Sonderabfall Berat Verfahren zur Behandlung biogener Rest- und/oder Abfallstoffe
EP0934938A1 (fr) 1996-10-24 1999-08-11 Zeria Pharmaceutical Co., Ltd. Derives de benzoylaminothiazole substitues et medicaments les contenant
WO2002006439A2 (fr) * 2000-07-14 2002-01-24 Bekon Energy Technologies Gmbh Bioreacteur destine a la methanisation de biomasse, dispositif de gaz biologique destine a la production d'energie thermique, electrique ou mecanique a partir de biomasse, comportant un tel bioreacteur, et procede de regulation et commande d'un tel dispositif de gaz biologique
ES2268798T3 (es) 1995-03-09 2007-03-16 Badhey, Mohan R. Composicion de azadiractina, extractos de azadiractina indica, composiciones y sus usos como insecticidas.
DE102008002812A1 (de) * 2008-03-26 2009-10-01 Bilfinger Berger Umwelttechnik Gmbh Verfahren zum Aufbereiten von in Haushalten anfallendem häuslichen Abwasser

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4594078A (en) 1982-12-08 1986-06-10 Maurice Guerin Continuous digester of the production of biomethane for organic substances
JPH0824891A (ja) * 1994-07-08 1996-01-30 Chiyoda Corp 生ゴミの生物処理方法及びその装置
DE4446661C1 (de) * 1994-12-19 1996-02-08 B A N S Biolog Abfall Nutzungs Verfahren und Anlage zur anaeroben Aufbereitung von Lebensmittelabfällen
ES2268798T3 (es) 1995-03-09 2007-03-16 Badhey, Mohan R. Composicion de azadiractina, extractos de azadiractina indica, composiciones y sus usos como insecticidas.
DE19538579C1 (de) 1995-10-17 1997-04-03 Karl Weitz Anlage zur Herstellung von Biogas aus organischen Stoffen
EP0934938A1 (fr) 1996-10-24 1999-08-11 Zeria Pharmaceutical Co., Ltd. Derives de benzoylaminothiazole substitues et medicaments les contenant
DE19800900A1 (de) * 1998-01-13 1999-07-15 Bsbg Bremer Sonderabfall Berat Verfahren zur Behandlung biogener Rest- und/oder Abfallstoffe
WO2002006439A2 (fr) * 2000-07-14 2002-01-24 Bekon Energy Technologies Gmbh Bioreacteur destine a la methanisation de biomasse, dispositif de gaz biologique destine a la production d'energie thermique, electrique ou mecanique a partir de biomasse, comportant un tel bioreacteur, et procede de regulation et commande d'un tel dispositif de gaz biologique
ES2233667T3 (es) 2000-07-14 2005-06-16 Bekon Energy Technologies Gmbh Biorreactor para metanizacion de biomasa y una planta de biogas para generar energia termica, electrica o mecanica a partir de biomasa, con un biorreactor de este tipo asi como procedimiento para regular y controlar una planta de biogas de este tipo.
DE102008002812A1 (de) * 2008-03-26 2009-10-01 Bilfinger Berger Umwelttechnik Gmbh Verfahren zum Aufbereiten von in Haushalten anfallendem häuslichen Abwasser

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
LEE KYUNG JOO: "UNITED TREATMENT PROCESS OF ORGANIC KITCHEN GARBAGE AND DOMESTIC WASTEWATER", EPODOC,, 5 July 2000 (2000-07-05), XP002557672 *

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013190361A1 (fr) * 2012-06-20 2013-12-27 Teller Yair Système et procédé pour la production de biogaz et d'engrais à partir de déchets organiques domestiques
US9688585B2 (en) 2013-06-18 2017-06-27 Ecogas Israel Ltd Lightweight assemblable appliance and respective method for production of biogas and liquid fertilizer
US11866381B2 (en) 2017-06-25 2024-01-09 Home Biogas Ltd Lightweight appliance with exoskeletal support respective kit-of-parts and method for production of biogas and liquid fertilizer

Also Published As

Publication number Publication date
ES2410261B1 (es) 2014-04-28
ES2410261A1 (es) 2013-07-01

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