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WO2010148374A3 - Réseaux organométalliques et leurs procédés de fabrication - Google Patents

Réseaux organométalliques et leurs procédés de fabrication Download PDF

Info

Publication number
WO2010148374A3
WO2010148374A3 PCT/US2010/039284 US2010039284W WO2010148374A3 WO 2010148374 A3 WO2010148374 A3 WO 2010148374A3 US 2010039284 W US2010039284 W US 2010039284W WO 2010148374 A3 WO2010148374 A3 WO 2010148374A3
Authority
WO
WIPO (PCT)
Prior art keywords
organo
methods
making same
metallic frameworks
frameworks
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2010/039284
Other languages
English (en)
Other versions
WO2010148374A2 (fr
Inventor
Christian J. Doonan
William Morris
Omar M. Yaghi
Bo Wang
Hexiang Deng
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
University of California Berkeley
University of California San Diego UCSD
Original Assignee
University of California Berkeley
University of California San Diego UCSD
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by University of California Berkeley, University of California San Diego UCSD filed Critical University of California Berkeley
Priority to EP10790310A priority Critical patent/EP2443133A4/fr
Priority to US13/378,342 priority patent/US20120259117A1/en
Priority to JP2012516363A priority patent/JP2012530722A/ja
Priority to CN2010800369497A priority patent/CN102574886A/zh
Publication of WO2010148374A2 publication Critical patent/WO2010148374A2/fr
Priority to IN6714DEN2012 priority patent/IN2012DN06714A/en
Priority to US13/578,579 priority patent/US20130131344A1/en
Priority to BR112012019874A priority patent/BR112012019874A2/pt
Priority to JP2012553065A priority patent/JP2013519687A/ja
Priority to MX2012008941A priority patent/MX2012008941A/es
Priority to KR1020127020992A priority patent/KR20120129905A/ko
Priority to RU2012138958/04A priority patent/RU2012138958A/ru
Priority to CA2788132A priority patent/CA2788132A1/fr
Priority to CN2011800093706A priority patent/CN102858455A/zh
Priority to PCT/US2011/024671 priority patent/WO2011146155A2/fr
Priority to AU2011256793A priority patent/AU2011256793A1/en
Publication of WO2010148374A3 publication Critical patent/WO2010148374A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F3/00—Compounds containing elements of Groups 2 or 12 of the Periodic Table
    • C07F3/003—Compounds containing elements of Groups 2 or 12 of the Periodic Table without C-Metal linkages
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F19/00—Metal compounds according to more than one of main groups C07F1/00 - C07F17/00
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/22—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material
    • B01J20/223—Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising organic material containing metals, e.g. organo-metallic compounds, coordination complexes
    • B01J20/226—Coordination polymers, e.g. metal-organic frameworks [MOF], zeolitic imidazolate frameworks [ZIF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/1691—Coordination polymers, e.g. metal-organic frameworks [MOF]
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/22—Organic complexes
    • B01J31/2265—Carbenes or carbynes, i.e.(image)
    • B01J31/2269—Heterocyclic carbenes
    • B01J31/2273—Heterocyclic carbenes with only nitrogen as heteroatomic ring members, e.g. 1,3-diarylimidazoline-2-ylidenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D235/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings
    • C07D235/02—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, condensed with other rings condensed with carbocyclic rings or ring systems
    • C07D235/04—Benzimidazoles; Hydrogenated benzimidazoles
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/006—Palladium compounds
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C11/00—Use of gas-solvents or gas-sorbents in vessels
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2253/00—Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/20—Organic adsorbents
    • B01D2253/204—Metal organic frameworks (MOF's)
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2257/00—Components to be removed
    • B01D2257/50—Carbon oxides
    • B01D2257/504—Carbon dioxide
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/82—Metals of the platinum group
    • B01J2531/824—Palladium
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02C—CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
    • Y02C20/00—Capture or disposal of greenhouse gases
    • Y02C20/40—Capture or disposal of greenhouse gases of CO2
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/151—Reduction of greenhouse gas [GHG] emissions, e.g. CO2

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Analytical Chemistry (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)

Abstract

La présente invention concerne des structures organiques qui comportent une plus grande stabilité.
PCT/US2010/039284 2009-06-19 2010-06-19 Réseaux organométalliques et leurs procédés de fabrication Ceased WO2010148374A2 (fr)

Priority Applications (15)

Application Number Priority Date Filing Date Title
EP10790310A EP2443133A4 (fr) 2009-06-19 2010-06-19 Réseaux organométalliques et leurs procédés de fabrication
US13/378,342 US20120259117A1 (en) 2009-06-19 2010-06-19 Organo-metallic frameworks and methods of making same
JP2012516363A JP2012530722A (ja) 2009-06-19 2010-06-19 有機金属骨格およびその製造方法
CN2010800369497A CN102574886A (zh) 2009-06-19 2010-06-19 有机金属骨架和其制造方法
AU2011256793A AU2011256793A1 (en) 2010-02-12 2011-02-12 Organo-metallic frameworks derived from carbenophilic metals and method of making same
MX2012008941A MX2012008941A (es) 2010-02-12 2011-02-12 Estructuras organometalicas derivadas de metales carbenofilicos y metodos para hacerlas.
CA2788132A CA2788132A1 (fr) 2010-02-12 2011-02-12 Edifices organometalliques issus de metaux carbenophiles et leur procede de fabrication
BR112012019874A BR112012019874A2 (pt) 2010-02-12 2011-02-12 "armações organometálicas derivadas a partir de metais carbenofilicos e método de produção das mesmas."
JP2012553065A JP2013519687A (ja) 2010-02-12 2011-02-12 カルベン親和性金属から誘導される有機金属骨格およびその製造方法
IN6714DEN2012 IN2012DN06714A (fr) 2010-02-12 2011-02-12
KR1020127020992A KR20120129905A (ko) 2010-02-12 2011-02-12 카베노필릭 금속으로부터 유도된 유기-금속 프레임워크 및 그의 제조방법
RU2012138958/04A RU2012138958A (ru) 2010-02-12 2011-02-12 Металлоорганические каркасные структуры, полученные из карбенофильных металлов и способ их получения
US13/578,579 US20130131344A1 (en) 2010-02-12 2011-02-12 Organo-metallic frameworks derived from carbenophilic metals and methods of making same
CN2011800093706A CN102858455A (zh) 2010-02-12 2011-02-12 衍生自亲卡宾金属的有机金属骨架及其制造方法
PCT/US2011/024671 WO2011146155A2 (fr) 2010-02-12 2011-02-12 Édifices organométalliques issus de métaux carbénophiles et leur procédé de fabrication

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US21889109P 2009-06-19 2009-06-19
US61/218,891 2009-06-19
US24735109P 2009-09-30 2009-09-30
US61/247,351 2009-09-30
US30430010P 2010-02-12 2010-02-12
US61/304,300 2010-02-12

Publications (2)

Publication Number Publication Date
WO2010148374A2 WO2010148374A2 (fr) 2010-12-23
WO2010148374A3 true WO2010148374A3 (fr) 2011-04-28

Family

ID=43357084

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2010/039284 Ceased WO2010148374A2 (fr) 2009-06-19 2010-06-19 Réseaux organométalliques et leurs procédés de fabrication

Country Status (5)

Country Link
EP (1) EP2443133A4 (fr)
JP (1) JP2012530722A (fr)
KR (1) KR20120096454A (fr)
CN (1) CN102574886A (fr)
WO (1) WO2010148374A2 (fr)

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8480955B2 (en) 2008-12-29 2013-07-09 The Regents Of The University Of California Gas sensor incorporating a porous framework
US8480792B2 (en) 2007-07-17 2013-07-09 The Regents Of The University Of California Preparation of functionalized zeolitic frameworks
US8540802B2 (en) 2007-05-11 2013-09-24 The Regents Of The University Of California Adsorptive gas separation of multi-component gases
US8674128B2 (en) 2009-01-15 2014-03-18 The Regents Of The University Of California Conductive organometallic framework
US8691748B2 (en) 2007-09-25 2014-04-08 The Regents Of The University Of California Edible and biocompatible metal-organic frameworks
US8709134B2 (en) 2009-02-02 2014-04-29 The Regents Of The University Of California Reversible ethylene oxide capture in porous frameworks
US8742152B2 (en) 2011-02-04 2014-06-03 The Regents Of The University Of California Preparation of metal-catecholate frameworks
US8841471B2 (en) 2009-09-25 2014-09-23 The Regents Of The University Of California Open metal organic frameworks with exceptional surface area and high gas storage capacity
US8852320B2 (en) 2011-01-21 2014-10-07 The Regents Of The University Of California Preparation of metal-triazolate frameworks
US8876953B2 (en) 2009-06-19 2014-11-04 The Regents Of The University Of California Carbon dioxide capture and storage using open frameworks
US8916722B2 (en) 2009-06-19 2014-12-23 The Regents Of The University Of California Complex mixed ligand open framework materials
US8946454B2 (en) 2008-06-05 2015-02-03 The Regents Of The University Of California Chemical framework compositions and methods of use
US9045387B2 (en) 2009-07-27 2015-06-02 The Regents Of The University Of California Oxidative homo-coupling reactions of aryl boronic acids using a porous copper metal-organic framework as a highly efficient heterogeneous catalyst
US9102609B2 (en) 2010-07-20 2015-08-11 The Regents Of The University Of California Functionalization of organic molecules using metal-organic frameworks (MOFS) as catalysts
US9269473B2 (en) 2010-09-27 2016-02-23 The Regents Of The University Of California Conductive open frameworks
US10821417B2 (en) 2015-11-27 2020-11-03 The Regents Of The University Of California Zeolitic imidazolate frameworks

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EP2766046B1 (fr) * 2011-10-13 2017-08-02 The Regents of The University of California Réseaux métal-organiques présentant des ouvertures à pores exceptionnellement grands
JP2013111563A (ja) * 2011-11-30 2013-06-10 Sumitomo Chemical Co Ltd 組成物及び該組成物を用いたアンモニア製造方法
JP5829924B2 (ja) * 2012-01-16 2015-12-09 東洋紡株式会社 多孔性複合材料とその製造方法、及び硫化水素ガス除去材
CN102936239B (zh) * 2012-11-16 2014-05-14 山东师范大学 有机配体和基于Cu(I)离子的金属有机框架、其合成方法和应用
CN105051269B (zh) * 2013-03-11 2019-03-19 乌第有限合伙公司 金属有机框架及其制备和用途
MY182759A (en) 2013-08-05 2021-02-05 Numat Tech Inc Metal organic frameworks for electronic gas storage
EP3074404B1 (fr) 2014-02-19 2020-01-01 The Regents of The University of California Ossatures organometalliques resistantes aux acides, aux solvants et a la chaleur
KR20160134644A (ko) 2014-03-18 2016-11-23 더 리젠츠 오브 더 유니버시티 오브 캘리포니아 미세다공성 금속 유기 구조체의 정렬된 초격자로 구성된 메조스코픽 물질
WO2015195179A2 (fr) 2014-03-28 2015-12-23 The Regents Of The University Of California Réseaux métal-organiques comprenant une pluralité de sbu avec différents ions métalliques et/ou une pluralité de ligands de liaison organique avec différents groupes fonctionnels
DE102014210464B4 (de) * 2014-06-03 2018-02-22 Hydrogenious Technologies Gmbh Verwendung eines Substrates zur Wasserstoffspeicherung
CN104056598A (zh) * 2014-06-20 2014-09-24 浙江大学 一种MOFs基二氧化碳吸附剂及其制备方法和应用
CN104710559B (zh) * 2015-02-15 2016-10-26 北京理工大学 一种制备金属有机骨架材料薄膜的方法
KR20180088422A (ko) * 2015-11-27 2018-08-03 더 리젠츠 오브 더 유니버시티 오브 캘리포니아 직조된 공유결합성 유기 골격체
CN106892945A (zh) * 2015-12-18 2017-06-27 温州大学 一种氮杂环卡宾-钯络合物、其制备方法及应用
CN105860958B (zh) * 2016-04-01 2018-07-06 山西大学 一种Cu2+化学传感器及其制备方法和应用
CN107855109A (zh) * 2017-11-03 2018-03-30 商丘师范学院 一种提高含锌沸石类唑基骨架材料co2吸附性能的方法
CN108152260B (zh) * 2017-12-23 2019-06-07 福州大学 一种检测尿酸的荧光传感器及其制备方法
JP7482786B2 (ja) 2018-04-25 2024-05-14 ユーティーアイ リミテッド パートナーシップ 亜鉛ｍｏｆ材料の合成
CN108503853B (zh) * 2018-05-04 2020-09-08 武汉大学 一种基于仲胺基键合的共价有机框架材料及其制备方法和应用
CN109174189B (zh) * 2018-09-07 2021-03-05 辽宁大学 基于PCN-222(Co)@TpPa-1的多孔结晶核壳杂化材料及其制备方法和应用
JP7461372B2 (ja) * 2019-04-01 2024-04-03 エクソンモービル テクノロジー アンド エンジニアリング カンパニー ジイミンビスサリチレート骨組みを含む金属－有機骨格物質及びそれらを製造するための方法
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Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8540802B2 (en) 2007-05-11 2013-09-24 The Regents Of The University Of California Adsorptive gas separation of multi-component gases
US8480792B2 (en) 2007-07-17 2013-07-09 The Regents Of The University Of California Preparation of functionalized zeolitic frameworks
US8691748B2 (en) 2007-09-25 2014-04-08 The Regents Of The University Of California Edible and biocompatible metal-organic frameworks
US8946454B2 (en) 2008-06-05 2015-02-03 The Regents Of The University Of California Chemical framework compositions and methods of use
US8735161B2 (en) 2008-12-29 2014-05-27 The Regents Of The University Of California Gas sensor incorporating a porous framework
US8480955B2 (en) 2008-12-29 2013-07-09 The Regents Of The University Of California Gas sensor incorporating a porous framework
US8674128B2 (en) 2009-01-15 2014-03-18 The Regents Of The University Of California Conductive organometallic framework
US8709134B2 (en) 2009-02-02 2014-04-29 The Regents Of The University Of California Reversible ethylene oxide capture in porous frameworks
US8876953B2 (en) 2009-06-19 2014-11-04 The Regents Of The University Of California Carbon dioxide capture and storage using open frameworks
US8916722B2 (en) 2009-06-19 2014-12-23 The Regents Of The University Of California Complex mixed ligand open framework materials
US9045387B2 (en) 2009-07-27 2015-06-02 The Regents Of The University Of California Oxidative homo-coupling reactions of aryl boronic acids using a porous copper metal-organic framework as a highly efficient heterogeneous catalyst
US8841471B2 (en) 2009-09-25 2014-09-23 The Regents Of The University Of California Open metal organic frameworks with exceptional surface area and high gas storage capacity
US9102609B2 (en) 2010-07-20 2015-08-11 The Regents Of The University Of California Functionalization of organic molecules using metal-organic frameworks (MOFS) as catalysts
US9269473B2 (en) 2010-09-27 2016-02-23 The Regents Of The University Of California Conductive open frameworks
US9978474B2 (en) 2010-09-27 2018-05-22 The Regents Of The University Of California Conductive open frameworks
US8852320B2 (en) 2011-01-21 2014-10-07 The Regents Of The University Of California Preparation of metal-triazolate frameworks
US8742152B2 (en) 2011-02-04 2014-06-03 The Regents Of The University Of California Preparation of metal-catecholate frameworks
US10821417B2 (en) 2015-11-27 2020-11-03 The Regents Of The University Of California Zeolitic imidazolate frameworks

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KR20120096454A (ko) 2012-08-30
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EP2443133A4 (fr) 2013-02-27
WO2010148374A2 (fr) 2010-12-23
CN102574886A (zh) 2012-07-11

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