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WO2010032263A3 - Process and equipment for recovery of valuable materials from terephthalic acid manufacture - Google Patents

Process and equipment for recovery of valuable materials from terephthalic acid manufacture Download PDF

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Publication number
WO2010032263A3
WO2010032263A3 PCT/IN2009/000468 IN2009000468W WO2010032263A3 WO 2010032263 A3 WO2010032263 A3 WO 2010032263A3 IN 2009000468 W IN2009000468 W IN 2009000468W WO 2010032263 A3 WO2010032263 A3 WO 2010032263A3
Authority
WO
WIPO (PCT)
Prior art keywords
recovery
terephthalic acid
valuable materials
equipment
acid manufacture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IN2009/000468
Other languages
French (fr)
Other versions
WO2010032263A2 (en
Inventor
Mathew Thomas
Sarda Subhash
Ghadge Rajaram
Aduri Pavankumar
Chougule Subhash
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Reliance Industries Ltd
Original Assignee
Reliance Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Reliance Industries Ltd filed Critical Reliance Industries Ltd
Priority to BRPI0918260 priority Critical patent/BRPI0918260B1/en
Priority to CN2009801337289A priority patent/CN102137707B/en
Publication of WO2010032263A2 publication Critical patent/WO2010032263A2/en
Publication of WO2010032263A3 publication Critical patent/WO2010032263A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/04—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing carboxylic acids or their salts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/025—Reverse osmosis; Hyperfiltration
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/025—Reverse osmosis; Hyperfiltration
    • B01D61/026—Reverse osmosis; Hyperfiltration comprising multiple reverse osmosis steps
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D61/00—Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor
    • B01D61/02—Reverse osmosis; Hyperfiltration ; Nanofiltration
    • B01D61/04—Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4023—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper
    • B01J31/403—Regeneration or reactivation of catalysts containing metals containing iron group metals, noble metals or copper containing iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/40—Regeneration or reactivation
    • B01J31/4015—Regeneration or reactivation of catalysts containing metals
    • B01J31/4053—Regeneration or reactivation of catalysts containing metals with recovery of phosphorous catalyst system constituents
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J38/00—Regeneration or reactivation of catalysts, in general
    • B01J38/48—Liquid treating or treating in liquid phase, e.g. dissolved or suspended
    • B01J38/60—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids
    • B01J38/62—Liquid treating or treating in liquid phase, e.g. dissolved or suspended using acids organic
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/41—Preparation of salts of carboxylic acids
    • C07C51/412—Preparation of salts of carboxylic acids by conversion of the acids, their salts, esters or anhydrides with the same carboxylic acid part
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/43—Separation; Purification; Stabilisation; Use of additives by change of the physical state, e.g. crystallisation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/47—Separation; Purification; Stabilisation; Use of additives by solid-liquid treatment; by chemisorption
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/42—Separation; Purification; Stabilisation; Use of additives
    • C07C51/487—Separation; Purification; Stabilisation; Use of additives by treatment giving rise to chemical modification
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2311/00—Details relating to membrane separation process operations and control
    • B01D2311/04—Specific process operations in the feed stream; Feed pretreatment
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2317/00—Membrane module arrangements within a plant or an apparatus
    • B01D2317/02—Elements in series
    • B01D2317/025—Permeate series
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2317/00—Membrane module arrangements within a plant or an apparatus
    • B01D2317/02—Elements in series
    • B01D2317/027—Christmas tree arrangements
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2317/00—Membrane module arrangements within a plant or an apparatus
    • B01D2317/04—Elements in parallel
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/32—Manganese, technetium or rhenium
    • B01J23/34—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/74—Iron group metals
    • B01J23/75—Cobalt
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/70—Complexes comprising metals of Group VII (VIIB) as the central metal
    • B01J2531/72—Manganese
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/80—Complexes comprising metals of Group VIII as the central metal
    • B01J2531/84—Metals of the iron group
    • B01J2531/845—Cobalt
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Water Supply & Treatment (AREA)
  • Nanotechnology (AREA)
  • Materials Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)

Abstract

A process for recovery of valuable materials from terephthalic acid manufacture. The process comprises the steps of diluting the reactor effluent from terephthalic acid manufacture with water in the weight ratio 1:1 to 1:12 and chilling the dilution of the effluent to 5 to 20 °C under stirring. The aqueous phase rich in the spent oxidation catalyst is separated from the solid phase rich in organic compounds and concentrated to recover the spent oxidation catalyst and water. Also equipment for recovery of valuable materials from the reactor effluent.
PCT/IN2009/000468 2008-08-26 2009-08-26 Process and equipment for recovery of valuable materials from terephthalic acid manufacture Ceased WO2010032263A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
BRPI0918260 BRPI0918260B1 (en) 2008-08-26 2009-08-26 process and equipment for the recovery of valuable terephthalic acid preparation materials
CN2009801337289A CN102137707B (en) 2008-08-26 2009-08-26 Method and apparatus for recovering valuable substances from terephthalic acid production

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
IN1794MU2008 2008-08-26
IN1794/MUM/2008 2008-08-26

Publications (2)

Publication Number Publication Date
WO2010032263A2 WO2010032263A2 (en) 2010-03-25
WO2010032263A3 true WO2010032263A3 (en) 2010-09-16

Family

ID=41600313

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/IN2009/000468 Ceased WO2010032263A2 (en) 2008-08-26 2009-08-26 Process and equipment for recovery of valuable materials from terephthalic acid manufacture

Country Status (5)

Country Link
CN (1) CN102137707B (en)
BR (1) BRPI0918260B1 (en)
PL (1) PL217166B1 (en)
PT (1) PT2010032263W (en)
WO (1) WO2010032263A2 (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9776943B2 (en) 2014-02-20 2017-10-03 Reliance Industries Limited Catalyst recovery and recycling process during aromatic carboxylic acid production

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102381964A (en) * 2010-09-01 2012-03-21 天华化工机械及自动化研究设计院 Integral process for washing and filtering terephthalic acid and water recovery
GB201314561D0 (en) * 2013-08-14 2013-09-25 Davy Process Techn Ltd Process
KR20170030553A (en) * 2014-07-09 2017-03-17 릴라이언스 인더스트리즈 리미티드 Method for recovery of ionic liquid and system thereof
CN116262649B (en) * 2022-01-27 2025-04-18 大连波美科技有限公司 A bromine-containing inorganic salt and organic acid (salt) wastewater treatment system and application method

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3170768A (en) * 1959-04-22 1965-02-23 Standard Oil Co System for continuous preparation of terephthalic acid
GB1460941A (en) * 1973-03-30 1977-01-06 Matsuyama Petrochemicals Inc Method of recovering cobalt and or manganese-bromine liquid- phase oxidation catalyst
WO1985002353A1 (en) * 1983-11-30 1985-06-06 Ecolochem, Inc. Recovery of organic acids, catalysts and water from terephthalic acid manufacture
EP1167336A2 (en) * 2000-06-27 2002-01-02 Mitsubishi Gas Chemical Company, Inc. Process for recovering catalyst components from a mother liquor of liquid phase oxidation
WO2006009571A1 (en) * 2004-06-23 2006-01-26 Eastman Chemical Company Process for removal of impurities from mother liquor in the synthesis of carboxylic acid using pressure filtration

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5693856A (en) * 1996-01-16 1997-12-02 The Boc Group, Inc. Production of terephthalic acid
CN1960961B (en) * 2004-05-28 2011-06-22 三菱化学株式会社 Method for producing high-purity terephthalic acid
CN101152969B (en) * 2006-09-29 2011-01-19 中国石油化工股份有限公司石油化工科学研究院 Treatment method of terephthalic acid production wastewater
CN101134628A (en) * 2007-07-31 2008-03-05 凯能高科技工程（上海）有限公司 Comprehensive processing utilization method for PTA refining waste-water

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3170768A (en) * 1959-04-22 1965-02-23 Standard Oil Co System for continuous preparation of terephthalic acid
GB1460941A (en) * 1973-03-30 1977-01-06 Matsuyama Petrochemicals Inc Method of recovering cobalt and or manganese-bromine liquid- phase oxidation catalyst
WO1985002353A1 (en) * 1983-11-30 1985-06-06 Ecolochem, Inc. Recovery of organic acids, catalysts and water from terephthalic acid manufacture
EP1167336A2 (en) * 2000-06-27 2002-01-02 Mitsubishi Gas Chemical Company, Inc. Process for recovering catalyst components from a mother liquor of liquid phase oxidation
WO2006009571A1 (en) * 2004-06-23 2006-01-26 Eastman Chemical Company Process for removal of impurities from mother liquor in the synthesis of carboxylic acid using pressure filtration

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US9776943B2 (en) 2014-02-20 2017-10-03 Reliance Industries Limited Catalyst recovery and recycling process during aromatic carboxylic acid production

Also Published As

Publication number Publication date
CN102137707B (en) 2013-08-21
BRPI0918260B1 (en) 2019-12-03
CN102137707A (en) 2011-07-27
PT2010032263W (en) 2011-09-14
PL395933A1 (en) 2011-12-05
BRPI0918260A2 (en) 2015-12-15
WO2010032263A2 (en) 2010-03-25
PL217166B1 (en) 2014-06-30

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