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WO2010009376A8 - Continuous process for converting natural gas to liquid hydrocarbons - Google Patents

Continuous process for converting natural gas to liquid hydrocarbons Download PDF

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Publication number
WO2010009376A8
WO2010009376A8 PCT/US2009/050955 US2009050955W WO2010009376A8 WO 2010009376 A8 WO2010009376 A8 WO 2010009376A8 US 2009050955 W US2009050955 W US 2009050955W WO 2010009376 A8 WO2010009376 A8 WO 2010009376A8
Authority
WO
WIPO (PCT)
Prior art keywords
stream
natural gas
continuous process
liquid hydrocarbons
converting natural
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2009/050955
Other languages
French (fr)
Other versions
WO2010009376A1 (en
Inventor
Sagar Gadewar
Aihua Zhang
Vivek Julka
Eric W. Mcfarland
Philip Grosso
Krishna Janmanchi
Saydul Amin Sardar
Peter Stoimenov
Zachary J.A. Komon
Hongfei Lin
Charles Ian Cutler
Jihong Cheng
Jean Wheeler
Shouli Sun
Daniel J. Auerbach
Michael D. Wyrsta
Charles J. Coronella
Shawn Huff
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GRT Inc
Original Assignee
GRT Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US12/496,348 external-priority patent/US8053616B2/en
Priority to CA2730934A priority Critical patent/CA2730934C/en
Priority to JP2011518928A priority patent/JP5681106B2/en
Priority to MX2011000558A priority patent/MX2011000558A/en
Priority to KR1020167011390A priority patent/KR101740419B1/en
Priority to PL09798794T priority patent/PL2326610T3/en
Priority to EP09798794A priority patent/EP2326610B1/en
Priority to EA201170229A priority patent/EA022995B1/en
Priority to AP2011005567A priority patent/AP2828A/en
Application filed by GRT Inc filed Critical GRT Inc
Priority to CN200980128134.9A priority patent/CN102099316B/en
Priority to AU2009270801A priority patent/AU2009270801B2/en
Priority to NZ591207A priority patent/NZ591207A/en
Publication of WO2010009376A1 publication Critical patent/WO2010009376A1/en
Priority to IL210606A priority patent/IL210606A/en
Priority to TN2011000017A priority patent/TN2011000017A1/en
Priority to ZA2011/00384A priority patent/ZA201100384B/en
Anticipated expiration legal-status Critical
Publication of WO2010009376A8 publication Critical patent/WO2010009376A8/en
Priority to IL234260A priority patent/IL234260A/en
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/093—Preparation of halogenated hydrocarbons by replacement by halogens
    • C07C17/10—Preparation of halogenated hydrocarbons by replacement by halogens of hydrogen atoms
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/44—Noble metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing iron group metals, noble metals or copper
    • B01J29/46—Iron group metals or copper
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B01J29/48—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively containing arsenic, antimony, bismuth, vanadium, niobium tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/82—Phosphates
    • B01J29/84—Aluminophosphates containing other elements, e.g. metals, boron
    • B01J29/85—Silicoaluminophosphates [SAPO compounds]
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/01—Chlorine; Hydrogen chloride
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/09—Bromine; Hydrogen bromide
    • C01B7/093—Hydrogen bromide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/09—Bromine; Hydrogen bromide
    • C01B7/096—Bromine
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/13—Iodine; Hydrogen iodide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B7/00—Halogens; Halogen acids
    • C01B7/19—Fluorine; Hydrogen fluoride
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/26—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only halogen atoms as hetero-atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C17/00—Preparation of halogenated hydrocarbons
    • C07C17/37—Preparation of halogenated hydrocarbons by disproportionation of halogenated hydrocarbons
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/16—After treatment, characterised by the effect to be obtained to increase the Si/Al ratio; Dealumination
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/183—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/10—After treatment, characterised by the effect to be obtained
    • B01J2229/18—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself
    • B01J2229/186—After treatment, characterised by the effect to be obtained to introduce other elements into or onto the molecular sieve itself not in framework positions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/90—Regeneration or reactivation
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C07C2529/42—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11 containing iron group metals, noble metals or copper
    • C07C2529/46—Iron group metals or copper
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/83—Aluminophosphates (APO compounds)
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/82—Phosphates
    • C07C2529/84—Aluminophosphates containing other elements, e.g. metals, boron
    • C07C2529/85—Silicoaluminophosphates (SAPO compounds)
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/584—Recycling of catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

A method comprising: providing a first halogen stream; providing a first alkane stream; reacting at least a portion of the first halogen stream with at least a portion of the first alkane stream in a first reaction vessel to form a first halogenated stream; providing a second alkane stream comprising C2 and higher hydrocarbons; providing a second halogen stream; and reacting at least a portion of the second halogen stream with at least a portion of the second alkane stream in a second reaction vessel to form a second halogenated stream.
PCT/US2009/050955 2008-07-18 2009-07-17 Continuous process for converting natural gas to liquid hydrocarbons Ceased WO2010009376A1 (en)

Priority Applications (15)

Application Number Priority Date Filing Date Title
AU2009270801A AU2009270801B2 (en) 2008-07-18 2009-07-17 Continuous process for converting natural gas to liquid hydrocarbons
JP2011518928A JP5681106B2 (en) 2008-07-18 2009-07-17 A continuous process for adding natural gas to liquefied hydrocarbons.
MX2011000558A MX2011000558A (en) 2008-07-18 2009-07-17 Continuous process for converting natural gas to liquid hydrocarbons.
KR1020167011390A KR101740419B1 (en) 2008-07-18 2009-07-17 Continuous process for converting natural gas to liquid hydrocarbons
PL09798794T PL2326610T3 (en) 2008-07-18 2009-07-17 Continuous process for converting natural gas to liquid hydrocarbons
EP09798794A EP2326610B1 (en) 2008-07-18 2009-07-17 Continuous process for converting natural gas to liquid hydrocarbons
EA201170229A EA022995B1 (en) 2008-07-18 2009-07-17 Continuous process for converting natural gas to liquid hydrocarbons
AP2011005567A AP2828A (en) 2008-07-18 2009-07-17 Continuous process for converting natural gas to liquid hydrocarbons
CN200980128134.9A CN102099316B (en) 2008-07-18 2009-07-17 Continuous process for converting natural gas to liquid hydrocarbons
CA2730934A CA2730934C (en) 2008-07-18 2009-07-17 Continuous process for converting natural gas to liquid hydrocarbons
NZ591207A NZ591207A (en) 2008-07-18 2009-07-17 Continuous process for converting natural gas to liquid hydrocarbons
IL210606A IL210606A (en) 2008-07-18 2011-01-13 Methods for producing liquid hydrocarbons from halogen and alkane gas
TN2011000017A TN2011000017A1 (en) 2009-07-17 2011-01-13 Continuous process for converting natural gas to liquid hydrocarbons
ZA2011/00384A ZA201100384B (en) 2008-07-18 2011-01-14 Continuous process for converting natural gas to liquid hydrocarbons
IL234260A IL234260A (en) 2008-07-18 2014-08-24 Continuous process for converting natural gas to liquid hydrocarbons

Applications Claiming Priority (10)

Application Number Priority Date Filing Date Title
US8197608P 2008-07-18 2008-07-18
US8214308P 2008-07-18 2008-07-18
US8200008P 2008-07-18 2008-07-18
US8211508P 2008-07-18 2008-07-18
US61/082,000 2008-07-18
US61/082,115 2008-07-18
US61/082,143 2008-07-18
US61/081,976 2008-07-18
US12/496,348 US8053616B2 (en) 2006-02-03 2009-07-01 Continuous process for converting natural gas to liquid hydrocarbons
US12/496,348 2009-07-01

Publications (2)

Publication Number Publication Date
WO2010009376A1 WO2010009376A1 (en) 2010-01-21
WO2010009376A8 true WO2010009376A8 (en) 2011-02-10

Family

ID=41550728

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2009/050955 Ceased WO2010009376A1 (en) 2008-07-18 2009-07-17 Continuous process for converting natural gas to liquid hydrocarbons

Country Status (12)

Country Link
EP (2) EP2326610B1 (en)
JP (1) JP5681106B2 (en)
KR (1) KR20110043676A (en)
CN (1) CN102099316B (en)
AP (1) AP2828A (en)
CO (1) CO6341606A2 (en)
EA (1) EA022995B1 (en)
EC (1) ECSP11010771A (en)
IL (1) IL210606A (en)
MX (1) MX2011000558A (en)
PL (1) PL2326610T3 (en)
WO (1) WO2010009376A1 (en)

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NZ591207A (en) 2008-07-18 2013-03-28 Grt Inc Continuous process for converting natural gas to liquid hydrocarbons
US8198495B2 (en) 2010-03-02 2012-06-12 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
US8367884B2 (en) * 2010-03-02 2013-02-05 Marathon Gtf Technology, Ltd. Processes and systems for the staged synthesis of alkyl bromides
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US20160362349A1 (en) * 2014-07-03 2016-12-15 Ashim Kumar Ghosh Stable conversion of alkyl halide to olefins
CN107001179A (en) * 2015-08-24 2017-08-01 沙特基础工业全球技术公司 It is used as the SSZ 13 for the catalyst that chloromethanes is converted into alkene
CN106146239B (en) * 2016-07-07 2018-12-11 浙江大学 A method for preparing aromatics by continuous conversion of methane
CN106117002B (en) * 2016-07-07 2019-05-07 浙江大学 A kind of double metal oxide supported catalyst catalyzes the method for aromatization of methyl bromide
CN108192685B (en) * 2017-12-28 2020-12-29 上海天汉环境资源有限公司 Online chemical decoking agent and decoking process based on hazardous waste incineration coking
WO2021099551A1 (en) * 2019-11-22 2021-05-27 Total Se Process for converting one or more methyl halides into c3-c5 alpha olefins
WO2021198172A1 (en) 2020-03-30 2021-10-07 Total Se Gas to olefins processes with coproduction of hydrogen
WO2021198168A1 (en) * 2020-03-30 2021-10-07 Total Se Gas to hydrogen process with co-production of carbon
WO2021198166A1 (en) 2020-03-30 2021-10-07 Total Se Gas to olefins process with coproduction of hydrogen together with heat integration process
WO2023220731A2 (en) * 2022-05-13 2023-11-16 The Regents Of The University Of California Halogen mediated production of hydrogen and carbon from hydrocarbons
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