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WO2010049393A2 - Procédé de production d'une matière de synthèse, en particulier d'un combustible ou d'une matière première de synthèse, dispositif correspondant et applications de ce procédé - Google Patents

Procédé de production d'une matière de synthèse, en particulier d'un combustible ou d'une matière première de synthèse, dispositif correspondant et applications de ce procédé Download PDF

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Publication number
WO2010049393A2
WO2010049393A2 PCT/EP2009/064090 EP2009064090W WO2010049393A2 WO 2010049393 A2 WO2010049393 A2 WO 2010049393A2 EP 2009064090 W EP2009064090 W EP 2009064090W WO 2010049393 A2 WO2010049393 A2 WO 2010049393A2
Authority
WO
WIPO (PCT)
Prior art keywords
synthetic
carbon dioxide
electrolysis
temperature
synthesis gas
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2009/064090
Other languages
German (de)
English (en)
Other versions
WO2010049393A3 (fr
Inventor
Joachim Hoffmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Siemens AG
Siemens Corp
Original Assignee
Siemens AG
Siemens Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Siemens AG, Siemens Corp filed Critical Siemens AG
Priority to CN2009801523456A priority Critical patent/CN102264949A/zh
Priority to US13/125,818 priority patent/US20110253550A1/en
Priority to EP09753058A priority patent/EP2350349A2/fr
Publication of WO2010049393A2 publication Critical patent/WO2010049393A2/fr
Publication of WO2010049393A3 publication Critical patent/WO2010049393A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/50—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon dioxide with hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/10—Process efficiency
    • Y02P20/133—Renewable energy sources, e.g. sunlight

Definitions

  • the invention relates to a process for producing a synthetic substance, in particular a synthetic fuel or raw material.
  • the invention also relates to the associated device for carrying out the method and to applications of this device in different branches of industry.
  • the invention In addition to the production of artificial fuels (“SynFuel”), the invention also deals with the production of artificial raw materials for the chemical industry. These production processes include energy and, on the other hand, hydrogen (H2), oxygen (O2) and In particular, wind or other renewable energies are used as the energy base, whereby as a substance basis, CO2 from other industrial processes can also be utilized.
  • H2 hydrogen
  • O2 oxygen
  • wind or other renewable energies are used as the energy base, whereby as a substance basis, CO2 from other industrial processes can also be utilized.
  • the object of the invention is to specify methods with which substances can be produced in a suitable manner and to provide the associated devices.
  • different applications relevant to industrial practice are proposed.
  • GTL gas T_o L_iquid
  • Synthetic fuels "SynFuel”
  • a carbon base is needed, for which purpose now used in industrial processes CO 2 -containing exhaust gases are used.
  • the invention is also suitable as a solution approach for current issues of environmentally sound treatment of CO 2 and defusing the global climate problem.
  • the invention makes use of the chemistry of water electrolysis in a special way.
  • Carbon dioxide can be recycled from biogenic sources or separated from industrial waste gases in the catalytic process:
  • hydrocarbons may be either aliphatic (straight-chain, branched) and aromatic (also hetero- and po ⁇ lyaromatician systems), and saturated (single / multiple) un- saturated (z. B. olefinic, etc.) have structures and generally by heteroatoms (in particular 0, N, S, halogen, Si) have functionalized structural elements, for.
  • heteroatoms in particular 0, N, S, halogen, Si
  • the above-mentioned metabolic conversion process (analogous to GTL or methamation) is economically available, in which synthetic hydrocarbons are produced via the gasification and the known Fischer-Tropsch synthesis, which can be used, for example, as diesel fuel or as gasoline are.
  • An economical approach seems conceivable, since a comparatively low degree of carbon utilization ⁇ c is realized.
  • an ecological approach appears to be in place, which has higher C0 2 emissions than in the case of are fine ⁇ ecommunn and utilized accordingly Kings ⁇ nen.
  • the single FIGURE schematically shows the conversion of electrical energy via a high-temperature electrolysis to He ⁇ generation of synthetic materials, such as synthetic fuel, or other raw materials.
  • 1 denotes a unit for generating electrical energy.
  • This electrical energy is provided in particular according to unit Ia by wind energy converter. But it can also according to unit Ib in the form of solar energy or according to unit Ic in other forms, for example, generally purchased on a power source, are provided.
  • the electric power is to a unit 2 for Hochtem ⁇ peraturelektrolyse given ((PEM electrolysers other / alkaline solution) are also conceivable, but not as effective).
  • the unit 2 is followed by a catalytic reactor 3 and a further unit 4 for conditioning the substances produced.
  • the carbon dioxide from biogenic sources or separated from exhaust gases is recycled in the catalytic process.
  • the power source for high-temperature electrolysis is realized by using wind energy
  • the substances produced can also fuels in addition to the Rohstof ⁇ fen, which can be used as fuels for cars and the like.
  • the proposed processes a re ⁇ production of C ⁇ done 2 emissions compared to the known GTL process. There is no CO 2 released, but consumed.
  • the method is therefore suitable to ensure processing of the obtained in many industrial processes ⁇ -industrial CO 2 ⁇ s, which otherwise has a clinical maschadliches gas global negative effects.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Abstract

La production de combustibles artificiels (combustibles de synthèse) se fait généralement de façon connue par le principe du procédé GTL (transformation du gaz en liquide). Selon l'invention, on fait fonctionner un électrolyseur haute température avec une source d'énergie avantageuse et on fait réagir le gaz hydrogène produit avec du CO2 par voie catalytique, ce qui permet de produire des matières premières artificielles, en particulier pour l'industrie chimique et d'autre part comme combustibles pour des véhicules automobiles. Outre la production de ces matières, le procédé selon l'invention est adapté au traitement du CO2 produit dans de nombreux processus industriels, ce CO2 pouvant autrement avoir des effets globaux négatifs en tant que gaz nocif pour le climat.
PCT/EP2009/064090 2008-10-27 2009-10-26 Procédé de production d'une matière de synthèse, en particulier d'un combustible ou d'une matière première de synthèse, dispositif correspondant et applications de ce procédé Ceased WO2010049393A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
CN2009801523456A CN102264949A (zh) 2008-10-27 2009-10-26 合成物质、特别是合成燃料或原料的制备方法以及该方法的相关设备和应用
US13/125,818 US20110253550A1 (en) 2008-10-27 2009-10-26 Method for producing a synthetic material, in particular a synthetic fuel or raw material, an associated device and applications for said method
EP09753058A EP2350349A2 (fr) 2008-10-27 2009-10-26 Procédé de production d'une matière de synthèse, en particulier d'un combustible ou d'une matière première de synthèse, dispositif correspondant et applications de ce procédé

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102008053334A DE102008053334A1 (de) 2008-10-27 2008-10-27 Verfahren zur Herstellung eines synthetischen Stoffes, insb. eines synthetischen Brennstoffes oder Rohstoffes, zugehörige Vorrichtung und Anwendungen dieses Verfahrens
DE102008053334.3 2008-10-27

Publications (2)

Publication Number Publication Date
WO2010049393A2 true WO2010049393A2 (fr) 2010-05-06
WO2010049393A3 WO2010049393A3 (fr) 2010-06-24

Family

ID=42102296

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2009/064090 Ceased WO2010049393A2 (fr) 2008-10-27 2009-10-26 Procédé de production d'une matière de synthèse, en particulier d'un combustible ou d'une matière première de synthèse, dispositif correspondant et applications de ce procédé

Country Status (5)

Country Link
US (1) US20110253550A1 (fr)
EP (1) EP2350349A2 (fr)
CN (1) CN102264949A (fr)
DE (1) DE102008053334A1 (fr)
WO (1) WO2010049393A2 (fr)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012206541A1 (de) * 2012-04-20 2013-10-24 Siemens Aktiengesellschaft Verfahren und Anordnung für die Hochtemperaturelektrolyse
RU2497748C1 (ru) * 2012-05-03 2013-11-10 Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт" Способ получения водорода
WO2013171107A3 (fr) * 2012-05-14 2014-01-23 Christian Mair Système d'alimentation en carburant pour véhicules à stockage de dioxyde de carbone

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FI20110409L (fi) 2011-12-05 2013-06-06 Outotec Oyj Menetelmä ja laite vedyn valmistamiseksi
DE102012204985A1 (de) * 2012-03-28 2013-10-02 Siemens Aktiengesellschaft Verfahren und Anordnung für die Hochtemperaturelektrolyse
DE102012105736A1 (de) * 2012-06-29 2014-01-02 Peter Volkmer Verfahren zur Speicherung von Elektroenergie
DE102014010812A1 (de) * 2014-07-23 2016-01-28 Etogas Gmbh Rahmen für eine Elektrolysevorrichtung, Elektrolysezellen-Modul und Elektrolysevorrichtung
DE102014010813B4 (de) * 2014-07-23 2025-11-20 Kanadevia lnova AG Rahmen für eine Elektrolysevorrichtung, Elektrolysezellen-Modul und Elektrolysevorrichtung
KR102753979B1 (ko) 2018-04-13 2025-01-14 토프쉐 에이/에스 합성 반응에서 사용하기 위한 일산화탄소와 이산화탄소를 포함하는 가스 혼합물의 생성 방법
WO2019197514A1 (fr) 2018-04-13 2019-10-17 Haldor Topsøe A/S Procédé de génération d'un gaz de synthèse destiné à être utilisé dans des réactions d'hydroformylation
WO2019228798A1 (fr) 2018-05-31 2019-12-05 Haldor Topsøe A/S Réactions endothermiques chauffées par chauffage par résistance
EP3574991A1 (fr) 2018-05-31 2019-12-04 Haldor Topsøe A/S Reformage à la vapeur chauffée par un chauffage à résistance
US12410054B2 (en) 2019-10-01 2025-09-09 Haldor Topsøe A/S Synthesis gas on demand
CA3148729A1 (fr) 2019-10-01 2021-04-08 Haldor Topsoe A/S Hydrogene a la demande a partir d'ammoniac
US12246965B2 (en) 2019-10-01 2025-03-11 Haldor Topsøe A/S On demand synthesis gas from methanol
CN114555220A (zh) 2019-10-01 2022-05-27 托普索公司 由甲醇按需制氢
CA3148730A1 (fr) 2019-10-01 2021-04-08 Haldor Topsoe A/S Cyanide a la demande
US12246298B2 (en) 2019-10-01 2025-03-11 Haldor Topsøe A/S Offshore reforming installation or vessel
BR112022009054A2 (pt) 2019-11-12 2022-08-09 Haldor Topsoe As Craqueador a vapor elétrico
CN116003197A (zh) * 2023-01-18 2023-04-25 中海石油气电集团有限责任公司 一种利用海上风电实现二氧化碳制备甲烷的方法

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JPH03200734A (ja) * 1989-12-28 1991-09-02 Mitsubishi Heavy Ind Ltd メタノールの合成方法
DE59911948D1 (de) * 1998-03-01 2005-05-25 Klaus Rennebeck Verfahren und vorrichtung zur gewinnung von synthesegas
DE10156975A1 (de) * 2001-11-20 2003-06-05 Stefan Geyer Verfahren zur Herstellung von Kohlenwasserstoffen
JP2003200734A (ja) * 2002-01-09 2003-07-15 Hitachi Ltd 移動体の防眩装置
US7045238B2 (en) * 2003-03-24 2006-05-16 Ion America Corporation SORFC power and oxygen generation method and system
DE102005017727B4 (de) * 2004-04-15 2015-09-17 Peter Volkmer Verfahren und Einrichtung zur Hochtemperatur-Dampf-Elektrolyse
DE102006035893A1 (de) * 2006-07-31 2008-02-07 Wolf, Bodo M., Dr. Verfahren zur Wiederaufarbeitung von Verbrennungsprodukten fossiler Brennstoffe
EP1887071A1 (fr) * 2006-07-31 2008-02-13 Edmund Dr.-Ing. Wagner Procédé de production d'hydrocarbures synthétiques et leurs dérivés à partir de dioxide de carbone et de dihydrogène utilisés comme gaz de synthèse
WO2009048685A1 (fr) * 2007-10-11 2009-04-16 Los Alamos National Security Llc Procédé de fabrication de combustibles et de produits chimiques organiques de synthèse à partir du dioxyde de carbone atmosphérique
US8366902B2 (en) * 2008-03-24 2013-02-05 Battelle Energy Alliance, Llc Methods and systems for producing syngas

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102012206541A1 (de) * 2012-04-20 2013-10-24 Siemens Aktiengesellschaft Verfahren und Anordnung für die Hochtemperaturelektrolyse
RU2497748C1 (ru) * 2012-05-03 2013-11-10 Федеральное государственное бюджетное учреждение "Национальный исследовательский центр "Курчатовский институт" Способ получения водорода
WO2013171107A3 (fr) * 2012-05-14 2014-01-23 Christian Mair Système d'alimentation en carburant pour véhicules à stockage de dioxyde de carbone

Also Published As

Publication number Publication date
US20110253550A1 (en) 2011-10-20
DE102008053334A1 (de) 2010-07-08
WO2010049393A3 (fr) 2010-06-24
CN102264949A (zh) 2011-11-30
EP2350349A2 (fr) 2011-08-03

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