WO2009123227A1 - Steel material, process for producing steel material, and apparatus for producing steel material - Google Patents
Steel material, process for producing steel material, and apparatus for producing steel material Download PDFInfo
- Publication number
- WO2009123227A1 WO2009123227A1 PCT/JP2009/056733 JP2009056733W WO2009123227A1 WO 2009123227 A1 WO2009123227 A1 WO 2009123227A1 JP 2009056733 W JP2009056733 W JP 2009056733W WO 2009123227 A1 WO2009123227 A1 WO 2009123227A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- steel material
- heating
- heat treatment
- tempering
- steel
- Prior art date
Links
- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 206
- 239000010959 steel Substances 0.000 title claims abstract description 206
- 239000000463 material Substances 0.000 title claims abstract description 165
- 238000000034 method Methods 0.000 title claims abstract description 47
- 230000008569 process Effects 0.000 title claims abstract description 26
- 238000010438 heat treatment Methods 0.000 claims abstract description 346
- 238000001816 cooling Methods 0.000 claims abstract description 69
- 230000006698 induction Effects 0.000 claims abstract description 21
- 230000009466 transformation Effects 0.000 claims abstract description 7
- 238000005496 tempering Methods 0.000 claims description 104
- 239000002344 surface layer Substances 0.000 claims description 85
- 238000004519 manufacturing process Methods 0.000 claims description 36
- 238000012545 processing Methods 0.000 claims description 35
- 238000010791 quenching Methods 0.000 claims description 28
- 230000000171 quenching effect Effects 0.000 claims description 28
- 238000012360 testing method Methods 0.000 claims description 25
- 238000012546 transfer Methods 0.000 claims description 17
- 239000002436 steel type Substances 0.000 claims description 14
- 238000009864 tensile test Methods 0.000 claims description 6
- 229910000734 martensite Inorganic materials 0.000 claims description 5
- 238000004364 calculation method Methods 0.000 claims description 2
- 230000000052 comparative effect Effects 0.000 description 53
- 229910000639 Spring steel Inorganic materials 0.000 description 32
- 230000003111 delayed effect Effects 0.000 description 31
- 238000009826 distribution Methods 0.000 description 29
- 230000008859 change Effects 0.000 description 11
- 238000004088 simulation Methods 0.000 description 11
- 238000004458 analytical method Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- 238000009661 fatigue test Methods 0.000 description 7
- 239000010410 layer Substances 0.000 description 7
- 238000005452 bending Methods 0.000 description 6
- 230000001186 cumulative effect Effects 0.000 description 6
- 230000002123 temporal effect Effects 0.000 description 6
- 239000000470 constituent Substances 0.000 description 4
- 239000000110 cooling liquid Substances 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000005261 decarburization Methods 0.000 description 2
- 230000002028 premature Effects 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 238000002791 soaking Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 229910001209 Low-carbon steel Inorganic materials 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000001066 destructive effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 238000007689 inspection Methods 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 238000005121 nitriding Methods 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 102200003959 rs11556986 Human genes 0.000 description 1
- 238000005480 shot peening Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/62—Quenching devices
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/60—Continuous furnaces for strip or wire with induction heating
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D9/00—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor
- C21D9/52—Heat treatment, e.g. annealing, hardening, quenching or tempering, adapted for particular articles; Furnaces therefor for wires; for strips ; for rods of unlimited length
- C21D9/54—Furnaces for treating strips or wire
- C21D9/56—Continuous furnaces for strip or wire
- C21D9/62—Continuous furnaces for strip or wire with direct resistance heating
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/14—Ferrous alloys, e.g. steel alloys containing titanium or zirconium
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/25—Process efficiency
Definitions
- the present invention relates to a steel material, a steel material manufacturing method, and a steel material manufacturing apparatus, and more particularly to a material whose hardness varies depending on a part.
- a rolled material which is a raw material of a bar or wire
- a technique for changing the tensile strength (hardness) is provided.
- ultra-low carbon steel such as pure iron
- decarburization and decarburization such as clad steel
- a technique for improving delayed fracture resistance there is a technique for performing chemical surface treatment such as plating or nitriding, or a technique for applying a non-metallic coating material with excellent delayed fracture resistance to the surface.
- chemical surface treatment such as plating or nitriding
- a technique for applying a non-metallic coating material with excellent delayed fracture resistance to the surface are known.
- pre-treatment is necessary because secondary processing (heat treatment) is performed after producing a decarburized layer by producing clad steel or heating at a temperature of Ac1 to Ac3 at the stage of the rolled material.
- secondary processing heat treatment
- an object of the present invention is to provide a steel material, a steel material manufacturing method, and a steel material manufacturing apparatus that have different hardness depending on the site by a simple process.
- a method for manufacturing a steel material according to one aspect of the present invention is a method for manufacturing a steel material in which the hardness of a part of the steel material is made lower than the hardness of the other part of the steel material by performing a heat treatment on the steel material having increased strength.
- the heat treatment includes a heating step of rapidly heating the steel material from a skin to a certain depth by induction heating or direct current heating, and a rapid cooling of the steel material after the heating step after a predetermined time after the heating step.
- a cooling step wherein the heating temperature in the heating step is equal to or higher than the Ac1 transformation point.
- the time from the heating step to the cooling step is not more than a predetermined time determined according to the steel type, wire diameter, heating temperature, and heating time.
- the heat treatment conditions are determined based on heat transfer characteristics after rapid heating of the surface of the steel material.
- the treatment condition of the heat treatment is a time integral value of the temperature of the steel material, and is determined based on a tempering progress value indicating a progress state of the tempering of the steel material.
- the present invention is characterized in that the heat treatment conditions include a combination including at least two of frequency, input electric energy, heating temperature, heating time, and cooling time.
- the present invention includes, as another aspect, a step of calculating the heat transfer characteristic of the steel material or the tempering progress value, and the heat treatment condition is set to the calculated heat transfer characteristic or the tempering progress value. It is determined based on.
- the heat treatment conditions are set so that the tempering progress value in the surface layer portion is 1.5 times or more the tempering progress value in the center portion.
- the time from the heating step to the cooling step is such that the tempering progress value in the surface layer portion is 1.5 times or more the central tempering progress value. It is characterized by setting as follows.
- the steel material is linear or rod-shaped.
- the heating process and the cooling process are each performed once as a tempering process.
- Another embodiment of the present invention is the steel material that has undergone the heating step and the cooling step, and the difference between the hardness in the vicinity of the surface layer portion and the hardness on the center side from the position of 10% from the surface layer in the radial direction.
- Is HV50 or more, and the tensile strength when a tensile test is performed with a No. 2 test piece of JISZ2201 is 1420 N / mm 2 or more.
- the entire cross-section tempered martensite structure is obtained, the hardness of the surface layer portion is HV380 or less, and a tensile test is performed with a No. 2 test piece of JISZ2201.
- the tensile strength is 1420 N / mm 2 or more, and the hardness on the center side of the surface layer is uniform.
- the hardness of the surface layer portion is HV420 or less, and a tensile test is performed with a No. 2 test piece of JISZ2201
- the tensile strength is 1600 N / mm 2 or more, and the center side hardness is more uniform than the surface layer.
- Another embodiment of the present invention is an apparatus for manufacturing a steel material, wherein the hardness of a part of the steel material is made lower than the hardness of the other part of the steel material by performing a heat treatment on the strengthened steel material,
- a heating means that rapidly heats the steel material from the skin to a certain depth by induction heating or direct current heating, and a cooling means that rapidly cools the heated steel material after a predetermined time after the heating
- the steel manufacturing apparatus is characterized in that the heating temperature is equal to or higher than the Ac1 transformation point.
- the present invention is further characterized by further comprising control means for controlling processing conditions of the heat treatment based on a heat transfer characteristic of the steel material or a calculation result of the tempering progress value.
- FIG. 1 is an explanatory view schematically showing the configuration of a heat treatment apparatus according to the first embodiment of the present invention.
- FIG. 2 is an explanatory view schematically showing a heat treatment step of the same embodiment.
- FIG. 3 is a side view showing the configuration of the PC steel rod in the same embodiment.
- FIG. 4 is a table showing components of the PC steel bar in the same embodiment.
- FIG. 5 is a graph showing the relationship between the number of coil turns and the wire diameter in the heat treatment apparatus of the same embodiment.
- FIG. 6 is a table showing the heat treatment conditions of the embodiment and the conventional example.
- FIG. 7 is a graph showing the relationship between the elapsed time and the temperature distribution by heat transfer analysis of the PC steel rod of the same embodiment.
- FIG. 8 is a graph showing a relationship between a cooling time and a temperature distribution by heat transfer analysis of the PC steel rod of the same embodiment.
- FIG. 9 is a graph showing the relationship between the hardness of the PC steel rod of the same embodiment and the distance in the diameter direction.
- FIG. 10 is a graph showing the temperature distribution from the surface layer portion to the center in the tempering process in the same embodiment.
- FIG. 11 is a graph showing the efficiency of the N parameter in the same embodiment.
- FIG. 12 is a graph showing the relationship between the ratio of the N parameter between the surface and the center, the heating process and the cooling time in the same embodiment.
- FIG. 13 is a graph which shows the cross-sectional hardness distribution of the PC steel bar obtained by the heat processing which concerns on the same embodiment, and the conventional heat processing.
- FIG. 14 is a graph showing the cross-sectional hardness distribution in the axial direction of the PC steel bar manufactured by the heat treatment of the same embodiment.
- FIG. 15 is a table showing the components of a plurality of types of PC steel bars used for the heat treatment of the same embodiment.
- FIG. 16 is a table showing the delayed fracture test results of the PC steel bar W by the heat treatment of the same embodiment and the conventional heat treatment.
- FIG. 17 is a graph showing the delayed fracture test results.
- FIG. 18 is a side view showing the configuration of the PC steel bar W1 of the same embodiment.
- FIG. 19 is a side view showing the configuration of the notch of the PC steel bar W1 of the same embodiment.
- FIG. 20 is a table showing the delayed fracture test results of the PC steel bar by the heat treatment of the same embodiment and the conventional heat treatment.
- FIG. 21 is a graph showing the delayed fracture test results.
- FIG. 22 is a graph showing the relationship between the depth of the notch formed in the PC steel bar W1 of the same embodiment and the fracture time.
- FIG. 23 is an explanatory view schematically showing a configuration of a heat treatment apparatus according to another embodiment of the present invention.
- FIG. 24 is a side view showing the configuration of the deformed PC steel bar according to the second embodiment of the present invention.
- FIG. 25 is a table showing components of the deformed PC steel bar in the same embodiment.
- FIG. 26 is a table showing heat treatment conditions for heat treatment and comparative heat treatment according to the embodiment.
- FIG. 27 is a graph showing a simulation result by heat transfer analysis of elapsed time and temperature change in heat treatment of the deformed PC steel bar in the same embodiment.
- FIG. 28 is a perspective view showing a configuration of a spring steel wire according to a third embodiment of the present invention.
- FIG. 29 is a table showing components of the spring steel wire in the same embodiment.
- FIG. 30 is a table showing heat treatment conditions in the heat treatment and the comparative heat treatment according to the embodiment.
- FIG. 31 is a graph showing a simulation result by heat transfer analysis of elapsed time and temperature change in the heat treatment according to the embodiment.
- FIG. 32 is a graph showing the cross-sectional hardness distribution of the spring steel wire after the heat treatment according to the embodiment and the comparative heat treatment.
- FIG. 33 is a graph showing the relationship between the hardness of the heat-treated material and the fatigue limit.
- FIG. 34 is a table showing the results of the rotational bending fatigue test of the comparative heat-treated material.
- FIG. 35 is a graph showing the relationship between the distance from the surface layer of the comparative heat-treated material and the number of durability.
- FIG. 36 is a table showing the rotational bending fatigue test results of the spring steel wire by the heat treatment according to the embodiment.
- FIG. 37 is a graph showing the cross-sectional hardness, residual stress, and stress amplitude of the spring steel wire by the heat treatment and the spring steel wire by the comparative heat treatment material according to the embodiment.
- FIG. 38 is a table showing an example of components of a spring steel wire according to another embodiment.
- FIG. 39 is a perspective view showing a configuration of a bolt according to the fourth embodiment of the present invention.
- FIG. 40 is a table showing the components of the bolt according to the embodiment.
- FIG. 41 is a table showing the heat treatment conditions in the heat treatment and the comparative heat treatment according to the embodiment.
- FIG. 42 is a graph showing a simulation result by heat transfer analysis of elapsed time and temperature change in the heat treatment of the bolt Wb in the same embodiment.
- FIG. 43 is a graph showing the cross-sectional hardness distribution of the bolts obtained by the heat treatment according to the embodiment and the comparative heat treatment.
- FIG. 44 is a table showing the delayed fracture test results of the bolts obtained by the heat treatment according to the embodiment and the comparative heat treatment.
- FIG. 45 is a graph showing the cumulative failure probability and failure time of the bolts obtained by the heat treatment according to the embodiment and the comparative heat treatment.
- FIG. 1 is a conceptual diagram of a heat treatment apparatus 10 of the present embodiment.
- FIG. 2 is a flowchart of the manufacturing process of the PC steel bar in the present embodiment.
- a heat treatment apparatus 10 as an example of a steel material manufacturing apparatus includes a pinch roll 11 (conveying means) that conveys a PC steel bar W that is an example of a steel material, and a quenching heating coil that is a quenching means. 12, a quenching cooling jacket 13, a pinch roll 14 (conveying means), a tempering heating coil 15 as a heating means for performing high-frequency induction heating, a cooling jacket 16 as a cooling means, and a pinch roll 17 (conveying means).
- a pinch roll 11 conveys a PC steel bar W that is an example of a steel material
- a quenching heating coil that is a quenching means.
- a quenching cooling jacket 13 conveys a quenching cooling jacket 13
- a pinch roll 14 conveying means
- a tempering heating coil 15 as a heating means for performing high-frequency induction heating
- a cooling jacket 16 as a cooling means
- a pinch roll 17 conveying means.
- the PC steel bar W to be processed is, for example, a solid round bar as shown in FIG. 3 and is continuously conveyed along the axial direction.
- the PC steel bar W is configured to include the components shown in FIG. 4, for example, but is not limited thereto.
- the tempering heating coil 15 has a function of high-frequency induction heating of the PC steel rod W passing there between.
- the tempering heating coil 15 is set to an appropriate number of coil turns in accordance with the wire diameter and the conveyance speed.
- the number of turns of the tempering heating coil 15 in this embodiment is, for example, 6 turns, but is not limited to this.
- FIG. 5 shows the relationship among the general number of coil turns, wire diameter, and conveyance speed.
- the PC steel rod W itself generates heat.
- the depth of the heat generating portion depends on the number and frequency of coil turns of the tempering heating coil 15, input electric energy, heating temperature, heating time, and cooling time. It can be adjusted by the combination.
- the cooling jacket 16 has a function of injecting a cooling liquid onto the passing PC steel rod W to cool it.
- the distance from the tempering heating coil 15 to the cooling jacket 16 is set to 500 mm or less, for example. In a normal processing apparatus, this distance is about 1900 mm. However, in this embodiment, the distance between the heating process and the cooling process is set short in order to shorten the time.
- FIG. 1 An example of the heat treatment conditions in this embodiment is shown in FIG.
- This processing condition was discovered by the applicant based on the principle described later, using the temporal change of the heating temperature pattern at the moment of high-frequency induction heating and the tempering characteristics of steel.
- it has a low hardness layer in the surface layer part by one tempering and has a uniform hardness distribution from a certain depth, and a strength of 1420 N / mm 2 or more It becomes possible to manufacture the steel rod W which becomes a level.
- the processing conditions of this embodiment are a frequency of 50 kHz, a quenching heating temperature of 1000 ° C., a tempering heating temperature of 805 ° C., a tempering heating time of 0.17 s, and a time from tempering heating to cooling of 0.63 s.
- the PC steel bar used here is a thin PC steel bar having a diameter d (nominal name) of 7.1 mm, and the tempering heating temperature is adjusted so that the tensile strength is about 1440 N / mm 2 .
- the processing conditions of the conventional product to be compared are a frequency of 9.5 kHz, a quenching heating temperature of 1000 ° C., a tempering heating temperature of 603 ° C., a tempering heating time of 0.59 s, and a time from tempering heating to cooling of 3.48 s.
- This conventional product is also a small-diameter PC steel rod having a diameter d (nominal name) of 7.1 mm, and the tempering heating temperature is adjusted so that the total tensile average tensile strength is about 1440 N / mm 2 .
- the component of this embodiment and a conventional product be the same component.
- the tempering heating temperature of this embodiment is higher than that of the conventional product to be compared, and the time from tempering heating to cooling is set shorter than that of the conventional product.
- tempering temperature As for the tempering temperature, according to the conventional common sense, heating at the tempering temperature not lower than the Ac1 transformation point (727 ° C.) is “impossible because tempering occurs”. By using heating and controlling rapid heating of the surface and rapid cooling immediately after completion of heating, it is possible to prevent quenching by combining rapid cooling even at temperatures above the Ac1 transformation point. I found out.
- the feed speed by the pinch roll 11 or the like, the heating temperature by the tempering heating coil 15, the heating time, the distance between the tempering heating coil 15 and the cooling jacket 16 , Etc. can be appropriately set and adjusted to obtain a PC steel bar W having a desired hardness distribution.
- a continuous wire W0 which is a continuous wire or rod-shaped steel material drawn in the material process, is continuously conveyed from the left side to the right side in FIG. 1 by a pinch roll 11 (conveying means).
- the continuous wire W0 to be conveyed is rapidly heated to the quenching temperature by induction heating by the quenching heating coil 12 in the quenching process, and then rapidly quenched by quenching cooling liquid injection by the quenching cooling jacket 13 and continuously quenched. Is done.
- the continuous wire W0 subjected to the quenching process is heated while passing through the tempering heating coil 15.
- the continuous wire W0 heated to a predetermined tempering temperature is conveyed to the cooling jacket 16 to which the cooling liquid is continuously sprayed, and the cooling jacket 16 starts rapid cooling. Passing through the cooling jacket 16, the entire length of the continuous wire W0 is cooled, and the tempering heat treatment is completed. And W0 is carried out by the pinch roll 17. After completing the heat treatment, the continuous wire W0 (PC steel bar W) is processed into a product (PC steel bar W) through a processing / inspection process.
- the N parameter value (tempering progress value), which is a new parameter serving as a reference for setting the processing conditions, will be described.
- Fig. 7 shows the simulation results by heat transfer analysis using a finite element model (FEM) of the elapsed time and temperature change from the start of heating of a cross section of a steel material during continuous heat treatment to 0.8 s.
- FEM finite element model
- the elapsed time is shown on the horizontal axis and the temperature is shown on the vertical axis.
- the heating time is 0.17 s, so out of 0.8 s in the graph, the first (left side of graph) 0.17 s is the heating time, and the remaining 0.63 s on the right side of the graph is allowed to cool. It will be time.
- the Larson Miller parameter P T ⁇ (A + logt) [T: temperature (K), A: constant, t: time (h)] established in the case of long-time heating is known. ing. As the value of the parameter P increases, the tempering progresses (low hardness).
- N value is the time integral of the temperature of the PC steel bar W, and is represented by the following formula (1).
- T temperature (° C.)
- t time (s)
- t0 heat treatment time (s).
- this N parameter value is an area enclosed below each curve in the graph. As the value of the N parameter value increases, the tempering progresses (low hardness).
- t0 is 0.8, that is, at the time of 0.8 s from the start of heating and when the cooling time is 0.63 s
- the N parameter value indicated by the area is compared
- the portion is larger than the N parameter value in the central portion, and the difference in the N parameter hardly changes at a depth of about 2 mm or more. Therefore, if it cools at this time, as shown in FIG. 9, the surface layer part is low-hardness and the state which has a substantially uniform hardness distribution from a low-hardness layer end part to a center part is realizable.
- t0 is set to 0.8, but the present invention is not limited to this, and an appropriate value can be applied according to various conditions depending on the wire diameter, steel type, and the like.
- FIG. 8 is a graph showing the relationship between the cooling time and the temperature distribution by heat transfer analysis of a PC steel rod using FEM.
- the horizontal axis of r (distance from the center) / R (radius) and the vertical axis of temperature are shown every 0.3 s.
- the analysis conditions were: shape: solid round bar, radius: 3.65 mm, material: S40C, heating layer depth 0.154 mm, heating time 0.17 s, cooling time 0.63 s, and initial temperature 20 ° C.
- the heat generated by the heat generated in the surface layer is transmitted to the center of the PC steel bar and to the outside with time.
- the surface layer has a high temperature distribution and the center has a low temperature distribution, but the temperature of the surface layer and the center becomes uniform over time.
- FIG. 9 shows the measurement of the cross-sectional hardness of the PC steel bar W, with the horizontal axis indicating the position in the diameter direction and the vertical axis indicating the Vickers hardness.
- the hardness corresponds to the tensile strength, and the surface layer portion has a low hardness (low strength), and a state having a substantially uniform hardness distribution from the end portion to the center portion of the low hardness layer is realized.
- FIG. 10 shows the N parameter value and Vickers hardness after 0.8 s from the start of heating of the PC steel bar W. It can be seen that the N parameter value and the Vickers hardness have a symmetric relationship and are in good agreement, and the hardness can be organized by the N parameter.
- the tensile strength of the PC steel bar W is determined by the N parameter value, which is the progress of tempering from the surface to the center, so there is a certain range to satisfy the standard. I understand. Further, it is understood that a steel material having desired characteristics can be obtained by controlling the temperature distribution and the time until cooling so that the difference between the N parameter values of the surface layer portion and the central portion is as large as possible within this range. .
- the PC steel bar W having a low hardness portion on the surface is a PC steel bar having both excellent delayed fracture resistance and a predetermined tensile strength, and such a PC steel bar W is obtained by the above method. be able to.
- the depth of the heat generating part can be adjusted by selecting an appropriate coil and frequency, input electric energy, heating temperature, heating time, and cooling time, and a pattern calculated by simulation can be realized. Therefore, by adjusting the time until cooling in high frequency heating, only the surface layer portion can be made low in hardness while satisfying the standard tensile strength of the PC steel bar.
- radiation-type external heating such as furnace heating other than high-frequency heating, does not raise temperature or soak in a short period of time, and continues to heat slowly, so the strength difference in the radial direction due to the tempering characteristics of steel.
- high-frequency heating there is an advantage that the internal hardness other than the surface layer portion is made uniform because of a short time such as 1 s or less.
- the hardness distribution of the surface layer can be adjusted by one tempering using the temperature distribution (difference in N parameter) peculiar to induction heat treatment, and the standard of tensile strength of steel bars A continuous high-frequency heat treatment line that satisfies the values can be realized.
- desired good surface layer softening can be achieved by setting the N parameter of the surface layer to be 1.5 times or more the central N parameter.
- the N parameter can be suitably used for steel materials of 100 kg / mm grade 2 or higher, and C: 0.1 mass% to 0.5 mass% of ordinary steel is preferable because of tempering temperature limitations.
- the diameter range for the N parameter to act as a principle is preferably, for example, a range of 5 mm to 40 mm.
- the N parameter uses the tempering of high-strength steel, and uses the overshoot due to rapid heating and the rapid transition to soaking due to the heat transfer of the steel, which are characteristic of high-frequency induction heating.
- tempering is performed in such a range that the desired surface layer softening can be achieved (the N parameter of the center and the surface layer is 1.5 times or more), and the entire surface is uniform and within the specified strength. It is difficult to do.
- the present invention is not limited to this range, and can be applied to large wire diameters exceeding this range in terms of induction tempering.
- FIG. 11 shows the relationship between the N parameter and Vickers hardness. Since the N parameter value and hardness are determined by the formula in the figure, select an appropriate coil and frequency, input electrical energy, heating temperature, heating time, and cooling time, and estimate the N parameter value by simulation. The desired hardness can be obtained.
- Fig. 12 shows the ratio of the N parameter between the center and the surface layer of the PC steel bar W and the elapsed time from the start of heating. From the start of heating to about 1 s, the parameter value was 1.5 times or more, and only the surface layer portion had low hardness.
- the PC steel bar W obtained by the above heat treatment method has a full-section tempered martensite structure.
- FIG. 13 shows the cross-sectional hardness distribution of the PC steel bar W obtained by the above heat treatment method.
- the horizontal axis indicates the distance from the surface layer
- the vertical axis indicates the Vickers hardness.
- the cross-sectional hardness distribution of a normal PC steel bar is uniform, whereas the PC steel bar according to the present invention has a uniform hardness at the center, although the hardness near the surface layer is low. It was confirmed that there was.
- FIG. 14 shows the cross-sectional hardness distribution in the axial direction of the PC steel bar manufactured by the heat treatment of this embodiment. About six places where the distance from a surface layer differs, a Vickers hardness is shown on a vertical axis
- FIG. 17 is a graphical representation of the test results shown in FIG. 16, with the vertical axis representing the fracture time and the horizontal axis representing the cumulative fracture probability. The longer the fracture time, the better the delayed fracture resistance. It shows that.
- the delayed fracture test was carried out by applying a load of 1420 ⁇ 0.7 N / mm 2 while immersed in a 20% NH 4 SCN solution kept at 50 ° C.
- FIG. 17 shows that the delayed fracture resistance is better when the plot is generally on the top (that is, the fracture time is longer). That is, in FIG. 17, it can be seen that the PC steel bar treated under the conditions of the present embodiment is more excellent in delayed fracture resistance than the conventional product.
- the delayed fracture test was performed by applying a load of 1420 ⁇ 0.8 N / mm 2 in a state of being immersed in a 20% NH 4 SCN solution kept at 50 ° C.
- FIG. 21 shows the results shown in FIG. 20 with the fracture time on the vertical axis and the cumulative fracture probability on the horizontal axis. The longer the fracture time, the better the delayed fracture resistance.
- FIG. 22 shows the relationship between the depth of the notch 20 formed in W1 and the breaking time. It was confirmed that even the PC steel bar W1 provided with the notch 20 was superior in delayed fracture resistance to the steel bar by this heat treatment compared to the steel bar by normal heat treatment.
- the vertical axis represents the average rupture time, and the horizontal axis represents the notch 20 depth. It can be seen that the delayed fracture resistance improving effect according to the present embodiment is drastically reduced from the depth of 0.4 mm. Since the diameter of the PC steel rod W1 used this time is 7.2 mm, the effect of this embodiment can be confirmed up to 10% of the sample radius from the surface layer, that is, about 0.36 mm from the surface layer.
- the PC steel bar heat treatment method and the heat treatment apparatus According to the PC steel bar, the PC steel bar heat treatment method and the heat treatment apparatus according to the present embodiment, the following effects can be obtained.
- a PC steel rod excellent in delayed fracture resistance can be obtained by simple processing. That is, by using the temporal change of the temperature pattern at the moment of heating and the tempering characteristics, it is possible to obtain a steel material having different hardness depending on the part by a simple treatment by a single tempering that satisfies a predetermined processing condition. it can.
- high-frequency induction heating can apply a temperature of 720 ° C. or higher, which is not generally applied due to quenching, and can form a sufficiently soft surface layer. Furthermore, quenching and tempering heat treatment that rapidly heats at high frequency provides high strength and high toughness compared to heat treatment by ordinary furnace heating. By finding the heat treatment conditions based on the thermal characteristics, it is possible to easily find appropriate conditions corresponding to all steel materials.
- the present invention is not limited to the above-described embodiment as it is, and can be embodied by modifying constituent elements without departing from the scope of the invention in the implementation stage.
- specific processing conditions can be appropriately changed according to the steel type of the target steel material, the required strength standard, hardness distribution, apparatus specifications, and the like.
- the heat treatment conditions to be set are not limited to the above.
- the detection means 21 for detecting various kinds of information about the steel material to be treated and the finite element method described above are used. , 8 for calculating a simulation result, a control unit 23 such as a CPU for controlling each condition of the apparatus 101 according to the simulation result, and various settings according to the control of the control unit 23.
- the adjusting means 24 for adjusting may be provided so that the heat treatment conditions can be controlled and adjusted based on the information of the corresponding steel material. In this case, for example, the time from tempering to cooling can be controlled by adjusting the speed of the feed mechanism of the pinch rolls 11, 14, and 17 and the position of the cooling jacket 16.
- the heat treatment according to the present embodiment is a surface softening treatment
- the steel material by this surface softening treatment (here, a deformed PC steel bar Wc) is a surface softening material
- the heat treatment as a comparative example to be compared is a comparative heat treatment
- this comparative heat treatment The deformed PC steel bar is referred to as a comparative heat treatment material.
- a deformed PC steel rod Wc having a uniform spiral groove continuous in the surface layer was treated as a steel material.
- the manufacturing apparatus and the manufacturing process were performed by the manufacturing process shown in FIG. 2 using the heat treatment apparatus 10 shown in FIG. That is, since the present embodiment is different only in the shape, component, diameter, etc. of the steel material to be processed, the heat treatment conditions are determined based on the same principle and the same parameters as in the first embodiment.
- FIG. 26 shows the heat treatment conditions for the deformed PC steel bar Wc according to the present embodiment and the heat treatment conditions for the comparative heat treatment to be compared.
- the heat treatment conditions of the deformed PC steel bar Wc of this embodiment are: frequency 50 kHz, quenching heating temperature 1000 ° C., tempering heating temperature 805 ° C., tempering heating time 0.17 s, tempering heating to cooling The time is 0.63 s.
- the deformed PC steel bar Wc used here is a deformed PC steel bar having a diameter db (nominal name) of 7.1 mm, and the total cross-sectional tensile strength is adjusted to be about 1400 N / mm 2 .
- the comparative processing conditions are a frequency of 9.5 kHz, a quenching heating temperature of 1000 ° C., a tempering heating temperature of 603 ° C., a tempering heating time of 0.59 s, and a time from tempering heating to cooling of 3.48 s.
- This comparative heat-treated material is also a deformed PC steel bar having a diameter of 7.1 mm, and is adjusted so that the average tensile strength of the entire cross section is about 1400 N / mm 2 .
- the component of the deformed PC steel bar Wc of the surface softening material of this embodiment and the component of the comparative heat treatment material are the same components.
- FIG. 27 shows a simulation result of the relationship between the elapsed time of heat treatment of the deformed PC steel bar Wc and the temperature change in this embodiment. Here, the relationship between the elapsed time and temperature according to the distance from the surface is shown.
- the area of the hatched portion in the figure is larger in the surface layer than in the center. That is, in this surface layer part, it will be in the state hold
- the same effect as the first embodiment can be obtained. That is, by combining the surface heating by high frequency induction heating and the tempering performance of steel, a deformed PC steel bar having excellent delayed fracture resistance can be obtained by a simple treatment. In other words, by using temporal changes in the temperature pattern at the moment of heating and tempering characteristics, a deformed PC steel bar with different hardness depending on the site can be obtained by simple tempering that satisfies a predetermined processing condition. Obtainable. Furthermore, the quenching and tempering heat treatment, which is rapidly heated by high frequency for a short time, provides high strength and high toughness as compared with heat treatment by ordinary furnace heating.
- the heat treatment according to the present embodiment is a surface softening treatment
- the steel material by this surface softening treatment (here, the spring steel wire Ws) is a surface softening material
- the heat treatment as a comparative example is a comparative heat treatment
- the spring steel wire by this comparative heat treatment is compared. It is called a heat treatment material.
- the steel material to be processed is the spring steel wire Ws shown in FIG.
- the heat treatment apparatus and the manufacturing process are the same as those in the first embodiment, and the heat treatment apparatus 10 shown in FIG. 1 is used and the process is performed in the manufacturing process shown in FIG. That is, this embodiment is different only in the components, diameters, and the like of the steel material to be processed. Therefore, the heat treatment conditions are determined using the same principle and the same parameters as in the first embodiment.
- FIG. 30 shows heat treatment conditions for the heat treatment according to the present embodiment and a comparative heat treatment as a comparative example.
- the heat treatment conditions for the surface softening treatment according to the present embodiment are: frequency 50 kHz, quenching heating temperature 950 ° C., tempering heating temperature 789 ° C., tempering heating time 0.4 s, time from tempering heating to cooling 2.6 s. To do.
- Comparative heat treatment conditions as a comparative example are a frequency of 9.5 kHz, a quenching heating temperature of 950 ° C., a tempering heating temperature of 495 ° C., a tempering heating time of 1.7 s, and a time from tempering heating to cooling of 11.1 s.
- the comparative heat-treated material is also a spring steel wire having a diameter of 12.0 mm, and the total cross-sectional average tensile strength is adjusted to be about 1900 N / mm 2 .
- the spring steel wire Ws and the comparative heat treatment material of the present embodiment have the same components.
- FIG. 31 shows a simulation result of the relationship between the elapsed time of the heat treatment of the spring steel wire Ws and the temperature change in the present embodiment. Here, the relationship between the elapsed time and temperature according to the distance from the surface is shown.
- the area of the hatched portion in the figure is larger in the surface layer than in the center. That is, in this surface layer part, it will be in the state hold
- FIG. 32 shows the distance from the surface layer and the hardness distribution.
- the vertical axis represents hardness [HV0.3], and the horizontal axis represents distance [mm] from the surface layer.
- FIG. 32 shows the hardness distributions of a spring steel wire (comparative heat treatment material) subjected to heat treatment as a comparative example and a spring steel wire Ws (surface softening material) treated under the heat treatment conditions of this embodiment.
- the hardness of the comparative heat treatment material hardly changed even when the distance from the surface layer was changed.
- the hardness changes in the vicinity of the surface layer as the distance from the surface layer increases. That is, Hv ⁇ 500 in the range of 1 mm from the surface layer.
- FIG. 34 shows the relationship between the distance from the surface layer to inclusions and the number of durability as a result of the rotational bending fatigue test of the comparative heat-treated material as a comparative example.
- FIG. 35 is a graph showing the relationship between the distance from the surface layer to inclusions and the number of durability times in the comparative heat-treated material. From FIG. 34 and FIG. 35, in the comparative heat treatment material, the tendency that the number of durability increases as the distance from the surface layer to the inclusion increases is recognized.
- FIG. 36 shows the relationship between the distance from the surface layer to inclusions and the number of durability in the spring steel wire Ws as a result of the rotational bending fatigue test of the spring steel wire Ws (surface softening material) processed according to the present embodiment.
- the results of the rotating bending fatigue test are all exemplified when the rotating bending fatigue test is performed after shot peening.
- the test conditions were stress amplitude: 700 MPa, rotation speed: 2000 rpm.
- the test was conducted up to 10 million times. In the graph, “> 1000” indicates that no breakage occurred after 10 million times.
- the spring steel wire Ws (surface softening material) of the present embodiment has a significantly increased durability compared to the spring steel wire (comparative heat treatment material) of the comparative example, and fatigue characteristics. It can be seen that is improved. In the spring steel wire Ws surface softening material of this embodiment, it is recognized that all breakage occurs starting from the surface layer.
- FIG. 37 is a graph showing the distribution of cross-sectional hardness, residual stress, and stress amplitude.
- the horizontal axis shows the distance [mm] from the surface layer.
- the vertical axis represents hardness [HV0.3], stress amplitude [MPa], and residual stress [MPa].
- the distribution of the residual stress is the same in all cases, and after showing the maximum compressive stress in the vicinity of 0.1 mm from the surface layer, it shows the tensile stress at 0.2 mm or more.
- the comparative heat-treated material has high hardness and low toughness in the case of the same stress amplitude, so that the residual stress is in the range of 0.2 to 1.0 mm from the tensile surface layer. Premature breakage occurs.
- the spring steel wire Ws of the present embodiment which is a surface layer softening material
- the surface layer has low hardness and high toughness
- inclusions originate from inclusions in the range close to the surface layer of about 0.2 to 1.0 mm. Generation of fatigue cracks is suppressed. For this reason, the number of times of durability is greatly improved.
- the same effect as the first embodiment can be obtained. That is, by combining surface heating by high-frequency induction heating and tempering performance of steel, a spring steel wire having excellent delayed fracture resistance can be obtained by simple processing. That is, by using temporal changes in the temperature pattern at the moment of heating and tempering characteristics, a spring steel wire having different hardness depending on the part is obtained by simple tempering with a single tempering condition that satisfies a predetermined processing condition. be able to. Furthermore, the quenching and tempering heat treatment, which is rapidly heated by high frequency for a short time, provides high strength and high toughness as compared with heat treatment by ordinary furnace heating.
- premature breakage starting from inclusions hardly occurs by softening in the range of 0.2 to 1.0 mm from the surface layer where the residual stress is tensile. The effect of doing is obtained.
- the component shown in FIG. 29 was shown as an example, it is not restricted to this.
- Other examples include steel types E to I including components as shown in FIG. Even in the case of these steel materials, the surface layer vicinity can be softened by the same treatment as described above, high strength and high toughness can be obtained, and early breakage starting from inclusions can be prevented.
- surface of FIG. 38 shows each component contained in the illustrated some spring steel wire in the range.
- the heat treatment according to this embodiment is referred to as a surface softening treatment
- the bolt Wb resulting from this surface softening treatment is referred to as a surface softening material
- the heat treatment as a comparative example is referred to as a comparative heat treatment
- the bolt resulting from this comparative heat treatment is referred to as a comparative heat treatment material.
- the bolt Wb shown in FIG. The manufacturing apparatus and the manufacturing process are the same as those in the first embodiment.
- the manufacturing apparatus shown in FIG. 1 was used, and processing was performed by the manufacturing process shown in FIG. That is, since the present embodiment is different only in the shape, component, diameter, etc. of the steel material to be processed, the heat treatment conditions are determined based on the same principle and the same parameters as in the first embodiment.
- FIG. 41 shows the heat treatment conditions for the bolt Wb in the heat treatment according to this embodiment and the comparative heat treatment.
- the heat treatment conditions of this embodiment are as follows: frequency 50 kHz, quenching heating temperature 1000 ° C., tempering heating temperature 780 ° C., tempering heating time 0.15 s, and time from tempering heating to cooling 0.61 s. Yes.
- the comparative heat treatment conditions were a frequency of 9.5 kHz, a quenching heating temperature of 1000 ° C., a tempering heating temperature of 480 ° C., a tempering heating time of 0.61 s, and a time from tempering heating to cooling of 3.50 s.
- This comparative heat-treated material is also a bolt having a diameter of 7.1 mm, and the total cross-sectional average tensile strength is adjusted to be about 1600 N / mm 2 .
- the component of the bolt Wb of the surface softening material of this embodiment and the component of the comparative heat treatment material are the same components.
- any heat treatment is performed before the screw is rolled into the bar material Wb1 of the bolt.
- FIG. 43 shows the hardness distributions of bolts (comparative heat treatment material) treated under comparative heat treatment conditions as comparative examples and bolts Wb (surface softening material) treated under the heat treatment conditions of this embodiment.
- the vertical axis represents hardness [HV0.3], and the horizontal axis represents distance [mm] from the surface layer.
- FIG. 44 shows a table comparing delayed fracture test results of the bolt Wb (surface layer softening material) of this embodiment and the comparative heat treatment material.
- the delayed fracture test was carried out after thread rolling the entire length of the bar material Wb1 of the bolt Wb.
- the depth of the screw was 0.7 mm.
- the conditions for the delayed fracture test were as follows: the test temperature was 50 ° C. in a state of being immersed in a 20% NH 4 SCN solution, and a tensile strength of 1530 N / mm 2 ⁇ 0.7 of the threaded portion was given.
- the test was conducted up to 200 hours using a loading method and a constant strain method. In the figure, “> 200” indicates that no fracture occurred even after 200 hours.
- FIG. 45 is a graph showing the relationship between the cumulative rupture probability and the rupture time of the surface softening material and the comparative heat treatment material of the present embodiment.
- the abscissa indicates the cumulative rupture probability [%], and the ordinate indicates the rupture time [h].
- the same effect as the first embodiment can be obtained. That is, by combining surface heating by high-frequency induction heating and tempering performance of steel, a bolt excellent in delayed fracture resistance can be obtained by simple processing. That is, by using the temporal change of the temperature pattern at the moment of heating and the tempering characteristics, it is possible to obtain bolts having different hardness depending on the site by simple tempering that satisfies a predetermined processing condition. it can. Furthermore, the quenching and tempering heat treatment, which is rapidly heated by high frequency for a short time, provides high strength and high toughness as compared with heat treatment by ordinary furnace heating.
- the present invention is not limited to the above-described embodiments as they are, and can be embodied by modifying constituent elements without departing from the scope of the invention in the implementation stage.
- specific processing conditions can be appropriately changed according to the shape, steel type, component, strength standard and hardness distribution to be obtained, and apparatus specifications.
- the heat treatment conditions to be set are not limited to the above.
- a strengthened steel material may be used.
- various inventions can be formed by appropriately combining a plurality of constituent elements disclosed in the above embodiments. For example, some components may be deleted from all the components shown in the embodiment. Furthermore, constituent elements over different embodiments may be appropriately combined.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Articles (AREA)
- Heat Treatment Of Strip Materials And Filament Materials (AREA)
- Heat Treatment Of Steel (AREA)
Abstract
Description
高周波誘導加熱による表面加熱と鋼の焼戻性能を融合させることで、単純な処理で耐遅れ破壊性に優れたPC鋼棒を得ることができる。すなわち、加熱した瞬間の温度パターンの時間的な変化と、焼戻特性を用いることにより、所定の処理条件を満たす一度の焼戻しで、単純な処理で、部位によって硬さが異なる鋼材を得ることができる。 According to the PC steel bar, the PC steel bar heat treatment method and the heat treatment apparatus according to the present embodiment, the following effects can be obtained.
By combining surface heating by high-frequency induction heating and tempering performance of steel, a PC steel rod excellent in delayed fracture resistance can be obtained by simple processing. That is, by using the temporal change of the temperature pattern at the moment of heating and the tempering characteristics, it is possible to obtain a steel material having different hardness depending on the part by a simple treatment by a single tempering that satisfies a predetermined processing condition. it can.
また、上記のようにシミュレーション結果を用いて、焼戻特性と伝熱特性とに基づいた熱処理条件を見出すことにより、あらゆる鋼材に対応する適切な条件を容易に見出すことができる。 The present inventors have found that high-frequency induction heating can apply a temperature of 720 ° C. or higher, which is not generally applied due to quenching, and can form a sufficiently soft surface layer. Furthermore, quenching and tempering heat treatment that rapidly heats at high frequency provides high strength and high toughness compared to heat treatment by ordinary furnace heating. By finding the heat treatment conditions based on the thermal characteristics, it is possible to easily find appropriate conditions corresponding to all steel materials.
以下本発明の第2実施形態について、図24乃至図27を参照して説明する。なお、処理の対象となる鋼材を異形PC鋼棒Wcとした点以外については上記第1実施形態と同様であるため、共通する説明を省略する。 [Second Embodiment]
Hereinafter, a second embodiment of the present invention will be described with reference to FIGS. In addition, since it is the same as that of the said 1st Embodiment except the point which changed the steel material used as the object of a process into the unusual shape PC steel bar Wc, common description is abbreviate | omitted.
以下本発明の第3実施形態について、図28乃至図37を参照して説明する。なお、処理の対象となる鋼材の一例としてばね鋼線Wsを用いた点以外については上記第1実施形態と同様であるため、共通する説明を省略する。 [Third Embodiment]
Hereinafter, a third embodiment of the present invention will be described with reference to FIGS. In addition, since it is the same as that of the said 1st Embodiment except the point which used the spring steel wire Ws as an example of the steel materials used as the object of a process, common description is abbreviate | omitted.
以下本発明の第4実施形態について、図39乃至図45を参照して説明する。なお、処理の対象となる鋼材の一例としてボルトWbを用いた点以外については上記第1実施形態と同様であるため、共通する説明を省略する。 [Fourth Embodiment]
A fourth embodiment of the present invention will be described below with reference to FIGS. 39 to 45. In addition, since it is the same as that of the said 1st Embodiment except the point which used the volt | bolt Wb as an example of the steel materials used as the object of a process, common description is abbreviate | omitted.
Claims (15)
- 高強度化された鋼材に熱処理を施すことにより、前記鋼材の一部分の硬さを前記鋼材の他の部分の硬さよりも低くする鋼材の製造方法であって、
前記熱処理は、誘導加熱または直接通電加熱により前記鋼材の表皮から一定深さまでを急速加熱する加熱工程と、該加熱工程の後所定時間後に、前記加熱工程を経た前記鋼材を急冷する冷却工程と、を備え、
前記加熱工程における加熱温度がAc1変態点以上であることを特徴とする鋼材の製造方法。 A method for producing a steel material in which the hardness of a part of the steel material is made lower than the hardness of the other part of the steel material by performing a heat treatment on the strengthened steel material,
The heat treatment is a heating step of rapidly heating from the skin of the steel material to a certain depth by induction heating or direct current heating, and a cooling step of rapidly cooling the steel material after the heating step after a predetermined time after the heating step, With
The method for producing a steel material, wherein a heating temperature in the heating step is equal to or higher than an Ac1 transformation point. - 前記加熱工程から前記冷却工程までの時間が、鋼種、線径、加熱温度、及び加熱時間に応じて決まる所定時間以下であることを特徴とする請求項1に記載の鋼材の製造方法。 The method for producing a steel material according to claim 1, wherein the time from the heating step to the cooling step is a predetermined time or less determined according to the steel type, wire diameter, heating temperature, and heating time.
- 前記熱処理の処理条件は、前記鋼材の表面急速加熱後の伝熱特性に基づいて決定されることを特徴とする請求項1または2に記載の鋼材の製造方法。 The method for manufacturing a steel material according to claim 1 or 2, wherein the treatment condition of the heat treatment is determined based on heat transfer characteristics after rapid heating of the surface of the steel material.
- 前記熱処理の処理条件は、前記鋼材の温度の時間積分値であり、前記鋼材の焼戻しの進行状態を示す焼戻進行値に基づいて決定されることを特徴とする請求項1乃至3のいずれか記載の鋼材の製造方法。 The processing condition of the heat treatment is a time integral value of the temperature of the steel material, and is determined based on a tempering progress value indicating a progress state of the tempering of the steel material. The manufacturing method of steel materials as described.
- 前記熱処理の処理条件は、周波数、入力電気エネルギー、加熱温度、加熱時間、放冷時間、の少なくとも2つを含む組み合わせとすることを特徴とする請求項1乃至4のいずれか記載の鋼材の製造方法。 5. The production of a steel material according to claim 1, wherein the treatment conditions of the heat treatment are a combination including at least two of frequency, input electric energy, heating temperature, heating time, and cooling time. Method.
- 前記鋼材の伝熱特性または前記焼戻進行値を算出する工程を備え、
前記熱処理の処理条件は、前記算出された伝熱特性または前記焼戻進行値に基づいて決定されることを特徴とする請求項4または5に記載の鋼材の製造方法。 A step of calculating heat transfer characteristics of the steel material or the tempering progress value;
The method for manufacturing a steel material according to claim 4 or 5, wherein the processing condition of the heat treatment is determined based on the calculated heat transfer characteristic or the tempering progress value. - 前記熱処理の処理条件は、表層部における前記焼戻進行値が、中心部における前記焼戻進行値の1.5倍以上の値になるよう設定することを特徴とする請求項4記載の鋼材の製造方法。 The treatment condition for the heat treatment is set such that the tempering progress value in the surface layer portion is 1.5 times or more of the tempering progress value in the center portion. Production method.
- 前記加熱工程から前記冷却工程までの時間は、表層部における前記焼戻進行値が、中心部の前記焼戻進行値の1.5倍以上の値になるよう設定することを特徴とする請求項4乃至7のいずれか記載の鋼材の製造方法。 The time from the heating step to the cooling step is set so that the tempering progress value in the surface layer portion is 1.5 times or more the central tempering progress value. The manufacturing method of the steel materials in any one of 4 thru | or 7.
- 前記鋼材は、線状または棒状であることを特徴とする請求項1乃至8のいずれか記載の鋼材の製造方法。 The method for manufacturing a steel material according to any one of claims 1 to 8, wherein the steel material is linear or rod-shaped.
- 前記鋼材に対して加熱処理及び冷却処理を含む焼入処理が施された後、焼戻処理として前記加熱工程及び前記冷却工程がそれぞれ一度ずつ行われることを特徴とする請求項1乃至9のいずれか記載の鋼材の製造方法。 The heating process and the cooling process are each performed once as a tempering process after the quenching process including the heating process and the cooling process is performed on the steel material. A method for producing the steel material according to claim 1.
- 請求項1乃至10のいずれか記載の前記加熱工程及び前記冷却工程を経た前記鋼材であって、
その表層部付近の硬さと、半径方向で表層から10%の位置よりも中心側の硬さの差がHV50以上であり、かつ、JISZ2201の2号試験片で引張試験を行った場合の引張強さが1420N/mm2以上であることを特徴とする鋼材。 The steel material having undergone the heating step and the cooling step according to any one of claims 1 to 10,
Tensile strength when the difference between the hardness near the surface layer portion and the hardness on the center side from the position 10% from the surface layer in the radial direction is HV50 or more, and a tensile test is performed with a No. 2 test piece of JISZ2201 A steel material having a thickness of 1420 N / mm 2 or more. - 請求項1乃至10のいずれか記載の前記加熱工程及び前記冷却工程を経た前記鋼材であって、
全断面焼き戻しマルテンサイト組織となっており、かつ、表層部の硬さがHV380以下であり、かつJISZ2201の2号試験片で引張試験を行った場合の引張強さが1420N/mm2以上であり、
表層よりも中心側の硬さが均一であることを特徴とする鋼材。 The steel material having undergone the heating step and the cooling step according to any one of claims 1 to 10,
It has a full-section tempered martensite structure, the hardness of the surface layer portion is HV380 or less, and the tensile strength when a tensile test is performed with a No. 2 test piece of JISZ2201 is 1420 N / mm 2 or more Yes,
A steel material having a uniform hardness on the center side than the surface layer. - 請求項1乃至10のいずれか記載の前記加熱工程及び前記冷却工程を経た前記鋼材であって、
全断面焼き戻しマルテンサイト組織となっており、かつ、その表層部の硬さがHV420以下であり、かつJISZ2201の2号試験片で引張試験を行った場合の引張強さが1600N/mm2以上であり、
表層よりも中心側の硬さが均一であることを特徴とする鋼材。 The steel material having undergone the heating step and the cooling step according to any one of claims 1 to 10,
It has a full-section tempered martensite structure, the surface layer has a hardness of HV420 or less, and the tensile strength when a tensile test is performed with a No. 2 test piece of JISZ2201 is 1600 N / mm 2 or more And
A steel material having a uniform hardness on the center side than the surface layer. - 高強度化された鋼材に熱処理を施すことにより、前記鋼材の一部分の硬さを前記鋼材の他の部分の硬さよりも低くする鋼材の製造装置であって、
誘導加熱または直接通電加熱により前記鋼材の表皮から一定深さまでを急速加熱する加熱手段と、
該加熱の後所定時間後に、加熱された前記鋼材を急冷する冷却手段と、を備え、
前記加熱手段における前記鋼材の加熱温度がAc1変態点以上であることを特徴とする鋼材の製造装置。 An apparatus for producing a steel material, wherein the hardness of a part of the steel material is made lower than the hardness of the other part of the steel material by performing a heat treatment on the strengthened steel material,
Heating means for rapidly heating the steel material from the skin to a certain depth by induction heating or direct current heating;
Cooling means for rapidly cooling the heated steel material after a predetermined time after the heating,
The apparatus for manufacturing a steel material, wherein the heating temperature of the steel material in the heating means is equal to or higher than the Ac1 transformation point. - 前記加熱手段での処理終了から前記冷却手段での処理開始までの時間が、鋼種、線径、加熱温度、加熱時間等に応じて決まる所定時間以下であり、
前記熱処理の処理条件は、前記鋼材の表面急速加熱後の伝熱特性、前記鋼材の焼戻しの進行状態を示す焼戻進行値、周波数、入力電気エネルギー、加熱温度、加熱時間、放冷時間、の少なくとも2つを含む組み合わせに基づいて決定され、
前記熱処理の処理条件は表層部の前記焼戻進行値が、中心部の前記焼戻進行値の1.5倍以上の値になるよう設定し、
前記加熱工程から前記冷却工程までの時間は、鋼種、線径、加熱温度、加熱時間等に応じて決まる所定時間以下に設定し、
前記鋼材は、線状または棒状であり、
前記鋼材を前記加熱手段及び前記冷却手段を通る所定の経路に沿って連続的に搬送する搬送手段をさらに備え、前記処理条件は、前記搬送経路における距離及び前記搬送速度を含み、
前記鋼材に対して加熱処理及び冷却処理を施す焼入手段を備え、
前記搬送経路における前記焼入手段の下流側に前記加熱手段及び前記冷却手段がそれぞれ一つずつ備えられ、
前記鋼材の伝熱特性または前記焼戻進行値の算出結果に基づいて前記熱処理の処理条件を制御する制御手段をさらに備えたことを特徴とする請求項14記載の鋼材の製造装置。 The time from the end of the treatment in the heating means to the start of the treatment in the cooling means is a predetermined time or less determined according to the steel type, wire diameter, heating temperature, heating time, etc.
The treatment conditions of the heat treatment are: heat transfer characteristics after rapid heating of the surface of the steel material, tempering progress value indicating the progress of tempering of the steel material, frequency, input electric energy, heating temperature, heating time, and cooling time. Determined based on a combination including at least two,
The treatment conditions for the heat treatment are set so that the tempering progress value of the surface layer part is 1.5 times or more of the tempering progress value of the center part,
The time from the heating step to the cooling step is set to a predetermined time or less determined according to the steel type, wire diameter, heating temperature, heating time, etc.
The steel material is linear or rod-shaped,
The apparatus further comprises conveying means for continuously conveying the steel material along a predetermined path passing through the heating means and the cooling means, and the processing condition includes a distance in the conveying path and the conveying speed,
A quenching means for performing a heat treatment and a cooling treatment on the steel material;
One each of the heating means and the cooling means are provided on the downstream side of the quenching means in the transport path,
The steel material manufacturing apparatus according to claim 14, further comprising a control unit that controls processing conditions of the heat treatment based on a heat transfer characteristic of the steel material or a calculation result of the tempering progress value.
Priority Applications (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN2009801122018A CN101983247B (en) | 2008-03-31 | 2009-03-31 | Steel material, process for producing steel material, and apparatus for producing steel material |
JP2010505952A JP5337792B2 (en) | 2008-03-31 | 2009-03-31 | Steel material, steel material manufacturing method and steel material manufacturing apparatus |
KR1020107021013A KR101286948B1 (en) | 2008-03-31 | 2009-03-31 | Steel material, process for producing steel material, and apparatus for producing steel material |
DE112009000750T DE112009000750B4 (en) | 2008-03-31 | 2009-03-31 | Steel article, method of making the steel article and apparatus for making a steel article |
US12/894,363 US20110017368A1 (en) | 2008-03-31 | 2010-09-30 | Steel Material, Process of Fabricating Steel Material, and Apparatus of Fabricating Steel Material |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2008-093760 | 2008-03-31 | ||
JP2008093760 | 2008-03-31 |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
US12/894,363 Continuation US20110017368A1 (en) | 2008-03-31 | 2010-09-30 | Steel Material, Process of Fabricating Steel Material, and Apparatus of Fabricating Steel Material |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2009123227A1 true WO2009123227A1 (en) | 2009-10-08 |
Family
ID=41135595
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2009/056733 WO2009123227A1 (en) | 2008-03-31 | 2009-03-31 | Steel material, process for producing steel material, and apparatus for producing steel material |
Country Status (6)
Country | Link |
---|---|
US (1) | US20110017368A1 (en) |
JP (1) | JP5337792B2 (en) |
KR (1) | KR101286948B1 (en) |
CN (1) | CN101983247B (en) |
DE (1) | DE112009000750B4 (en) |
WO (1) | WO2009123227A1 (en) |
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011140858A (en) * | 2009-12-07 | 2011-07-21 | Tokyo Electric Power Co Inc:The | Concrete column excelling in durability |
JP2011226138A (en) * | 2010-04-20 | 2011-11-10 | Tokyo Electric Power Co Inc:The | Concrete column excellent in durability |
DE102010035195A1 (en) * | 2010-08-24 | 2012-03-01 | Volkswagen Ag | Profile component and method for producing a profile component |
EP2559781A4 (en) * | 2010-04-14 | 2014-12-10 | Nhk Spring Co Ltd | SPRING AND METHOD FOR THE PRODUCTION THEREOF |
JP2015010238A (en) * | 2013-06-26 | 2015-01-19 | 高周波熱錬株式会社 | Heat treatment method |
JP2015161016A (en) * | 2014-02-28 | 2015-09-07 | 日立オートモティブシステムズ株式会社 | Manufacturing method of surface processing part and manufacturing installation of surface processing part |
JP2016017202A (en) * | 2014-07-08 | 2016-02-01 | Jfeスチール株式会社 | Heat treatment method for tempered high strength steel sheet |
WO2017037804A1 (en) * | 2015-08-28 | 2017-03-09 | 三菱重工コンプレッサ株式会社 | Method for producing turbine rotor and method for producing turbine |
JP2017179399A (en) * | 2016-03-28 | 2017-10-05 | 高周波熱錬株式会社 | Steel material for building |
WO2018061087A1 (en) * | 2016-09-27 | 2018-04-05 | 日産自動車株式会社 | Steel component manufacturing method |
JP2019073793A (en) * | 2017-10-11 | 2019-05-16 | トヨタ自動車株式会社 | Steel sheet member and manufacturing method of same |
JP2019173343A (en) * | 2018-03-28 | 2019-10-10 | 東京電力ホールディングス株式会社 | Prestressed concrete column |
JP2022070602A (en) * | 2020-10-27 | 2022-05-13 | トヨタ自動車株式会社 | Method and apparatus for manufacturing steel product |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101914488B1 (en) * | 2011-04-06 | 2018-11-05 | 삼성전자주식회사 | Server cluster and method for push notification service |
CN103131834B (en) * | 2011-11-25 | 2015-03-25 | 上海中国弹簧制造有限公司 | Spring steel wire processing process for increasing fatigue performance of high strength spring steel wire |
CN102828008B (en) * | 2012-09-04 | 2014-08-27 | 镇江市天祥精密机电有限公司 | Coreless quenching machine tool |
JP6572530B2 (en) | 2014-10-17 | 2019-09-11 | 株式会社ジェイテクト | Heat treatment apparatus and heat treatment method |
JP2016089183A (en) * | 2014-10-29 | 2016-05-23 | 高周波熱錬株式会社 | Heat treatment method for workpiece |
JP6368686B2 (en) * | 2015-06-10 | 2018-08-01 | 東京エレクトロン株式会社 | Heat treatment apparatus, method for adjusting heat treatment apparatus, and program |
KR20190088391A (en) | 2018-11-12 | 2019-07-26 | 임재학 | Method and apparatus for manufacturing PC steel rods |
CN109281214A (en) * | 2018-12-03 | 2019-01-29 | 江苏兴达钢帘线股份有限公司 | A kind of steel cord and its manufacturing method and the tire with this steel cord |
CN113106204A (en) * | 2021-04-01 | 2021-07-13 | 王思琪 | Elastic rod, production method thereof and mattress with elastic rod |
US20230262913A1 (en) * | 2022-02-16 | 2023-08-17 | Meta Platforms Technologies, Llc | Methods for forming electronic device housings |
CN116334369A (en) * | 2022-12-13 | 2023-06-27 | 宝钢集团南通线材制品有限公司 | Spring steel wire surface layer softening process |
Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05287450A (en) * | 1992-04-09 | 1993-11-02 | Nippon Steel Corp | Pc steel bar excellent in delayed fracture resistance |
JPH10141341A (en) * | 1996-11-13 | 1998-05-26 | Nkk Corp | High strength bolt with excellent delayed fracture characteristics |
JP2000026937A (en) * | 1998-07-09 | 2000-01-25 | Kawasaki Steel Corp | High-strength PC steel bar and method of manufacturing the same |
JP2001040423A (en) * | 1999-07-27 | 2001-02-13 | High Frequency Heattreat Co Ltd | Steel bar whose strength is partially changed and heat treatment method and heat treatment apparatus therefor |
JP2001294980A (en) * | 2000-04-07 | 2001-10-26 | Nippon Steel Corp | High-strength PC steel rod excellent in uniform elongation and delayed fracture characteristics, and method of manufacturing the same |
JP2004043843A (en) * | 2002-07-09 | 2004-02-12 | High Frequency Heattreat Co Ltd | Pc steel bar having improved relaxation, and continuous heat treatment method |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS62267420A (en) * | 1986-05-13 | 1987-11-20 | Kobe Steel Ltd | Manufacture of high tension and high toughness wire rod having superior delayed fracture resistance |
US5027017A (en) | 1990-01-19 | 1991-06-25 | Rca Licensing Corporation | Sync tip clamp circuitry |
JPH0657367A (en) * | 1992-08-10 | 1994-03-01 | Nippon Steel Corp | PC steel rod excellent in delayed fracture resistance and method for producing the same |
JP2967018B2 (en) * | 1993-08-12 | 1999-10-25 | 住友電気工業株式会社 | Tensile steel |
JP4187334B2 (en) * | 1998-01-29 | 2008-11-26 | トピー工業株式会社 | Heat treatment method for hollow cylindrical workpiece |
-
2009
- 2009-03-31 CN CN2009801122018A patent/CN101983247B/en active Active
- 2009-03-31 JP JP2010505952A patent/JP5337792B2/en active Active
- 2009-03-31 WO PCT/JP2009/056733 patent/WO2009123227A1/en active Application Filing
- 2009-03-31 KR KR1020107021013A patent/KR101286948B1/en active Active
- 2009-03-31 DE DE112009000750T patent/DE112009000750B4/en active Active
-
2010
- 2010-09-30 US US12/894,363 patent/US20110017368A1/en not_active Abandoned
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH05287450A (en) * | 1992-04-09 | 1993-11-02 | Nippon Steel Corp | Pc steel bar excellent in delayed fracture resistance |
JPH10141341A (en) * | 1996-11-13 | 1998-05-26 | Nkk Corp | High strength bolt with excellent delayed fracture characteristics |
JP2000026937A (en) * | 1998-07-09 | 2000-01-25 | Kawasaki Steel Corp | High-strength PC steel bar and method of manufacturing the same |
JP2001040423A (en) * | 1999-07-27 | 2001-02-13 | High Frequency Heattreat Co Ltd | Steel bar whose strength is partially changed and heat treatment method and heat treatment apparatus therefor |
JP2001294980A (en) * | 2000-04-07 | 2001-10-26 | Nippon Steel Corp | High-strength PC steel rod excellent in uniform elongation and delayed fracture characteristics, and method of manufacturing the same |
JP2004043843A (en) * | 2002-07-09 | 2004-02-12 | High Frequency Heattreat Co Ltd | Pc steel bar having improved relaxation, and continuous heat treatment method |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011140858A (en) * | 2009-12-07 | 2011-07-21 | Tokyo Electric Power Co Inc:The | Concrete column excelling in durability |
EP2559781A4 (en) * | 2010-04-14 | 2014-12-10 | Nhk Spring Co Ltd | SPRING AND METHOD FOR THE PRODUCTION THEREOF |
JP2011226138A (en) * | 2010-04-20 | 2011-11-10 | Tokyo Electric Power Co Inc:The | Concrete column excellent in durability |
DE102010035195A1 (en) * | 2010-08-24 | 2012-03-01 | Volkswagen Ag | Profile component and method for producing a profile component |
JP2015010238A (en) * | 2013-06-26 | 2015-01-19 | 高周波熱錬株式会社 | Heat treatment method |
JP2015161016A (en) * | 2014-02-28 | 2015-09-07 | 日立オートモティブシステムズ株式会社 | Manufacturing method of surface processing part and manufacturing installation of surface processing part |
JP2016017202A (en) * | 2014-07-08 | 2016-02-01 | Jfeスチール株式会社 | Heat treatment method for tempered high strength steel sheet |
JPWO2017037804A1 (en) * | 2015-08-28 | 2018-06-07 | 三菱重工コンプレッサ株式会社 | Turbine rotor manufacturing method and turbine manufacturing method |
WO2017037804A1 (en) * | 2015-08-28 | 2017-03-09 | 三菱重工コンプレッサ株式会社 | Method for producing turbine rotor and method for producing turbine |
US10752970B2 (en) | 2015-08-28 | 2020-08-25 | Mitsubishi Heavy Industries Compressor Corporation | Method for producing turbine rotor and method for producing turbine |
JP2017179399A (en) * | 2016-03-28 | 2017-10-05 | 高周波熱錬株式会社 | Steel material for building |
WO2018061087A1 (en) * | 2016-09-27 | 2018-04-05 | 日産自動車株式会社 | Steel component manufacturing method |
JP2019073793A (en) * | 2017-10-11 | 2019-05-16 | トヨタ自動車株式会社 | Steel sheet member and manufacturing method of same |
JP7043958B2 (en) | 2017-10-11 | 2022-03-30 | トヨタ自動車株式会社 | Steel plate member and its manufacturing method |
JP2019173343A (en) * | 2018-03-28 | 2019-10-10 | 東京電力ホールディングス株式会社 | Prestressed concrete column |
JP7031432B2 (en) | 2018-03-28 | 2022-03-08 | 東京電力ホールディングス株式会社 | Prestressed concrete columns |
JP2022070602A (en) * | 2020-10-27 | 2022-05-13 | トヨタ自動車株式会社 | Method and apparatus for manufacturing steel product |
JP7428113B2 (en) | 2020-10-27 | 2024-02-06 | トヨタ自動車株式会社 | Steel product manufacturing method and steel product manufacturing equipment |
Also Published As
Publication number | Publication date |
---|---|
JP5337792B2 (en) | 2013-11-06 |
CN101983247B (en) | 2013-06-19 |
DE112009000750T5 (en) | 2011-03-03 |
JPWO2009123227A1 (en) | 2011-07-28 |
DE112009000750B4 (en) | 2013-05-29 |
KR20100122931A (en) | 2010-11-23 |
CN101983247A (en) | 2011-03-02 |
KR101286948B1 (en) | 2013-07-17 |
US20110017368A1 (en) | 2011-01-27 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP5337792B2 (en) | Steel material, steel material manufacturing method and steel material manufacturing apparatus | |
JP4415009B2 (en) | Method for thermal processing control of steel | |
US10359090B2 (en) | Compression coil spring and method for producing same | |
CN102378823A (en) | Steel wire for high-strength spring | |
JP5658934B2 (en) | Carburizing and quenching method | |
US11833561B2 (en) | Method of manufacturing a coiled tubing string | |
JP4676993B2 (en) | Bush making | |
CN105008573B (en) | Steel wire for spring and method for manufacturing same | |
JP4859240B2 (en) | Manufacturing method of ERW steel pipe for hollow stabilizer | |
JP2001220650A (en) | Steel wire, spring, and method for producing them | |
JPH03240919A (en) | Manufacturing method of steel wire rod for wire drawing | |
JP2978059B2 (en) | Link chain | |
JP4708158B2 (en) | Surface hardened steel and surface hardening method of steel | |
JP2018040488A (en) | High-strength screw including unhardening layer | |
JP2015172234A (en) | Slow cooling method for steel material | |
JP2589715B2 (en) | Method and apparatus for manufacturing high-strength spring material | |
JP2835057B2 (en) | Spring steel and manufacturing method thereof | |
US20080257460A1 (en) | Method of producing forgings having excellent tensile strength and elongation from steel wire rods | |
CN101240368A (en) | Method for manufacturing forged parts with tensile characteristics of 16.9+0.16 grade | |
JP2017179399A (en) | Steel material for building | |
JP2007107032A (en) | Method for producing steel pipe for hollow stabilizer, and producing method for producing hollow stabilizer | |
JPS61217525A (en) | Manufacture of coil spring | |
JPH0931540A (en) | Producing method of steel bar for prestressed concrete | |
CN115181849A (en) | Steel wire heat treatment method | |
JP2014145124A (en) | Spheroidization method of high carbon steel wire material, manufacturing method of steel wire, manufacturing device, steel wire and tire |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200980112201.8 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 09727915 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2010505952 Country of ref document: JP |
|
ENP | Entry into the national phase |
Ref document number: 20107021013 Country of ref document: KR Kind code of ref document: A |
|
RET | De translation (de og part 6b) |
Ref document number: 112009000750 Country of ref document: DE Date of ref document: 20110303 Kind code of ref document: P |
|
122 | Ep: pct application non-entry in european phase |
Ref document number: 09727915 Country of ref document: EP Kind code of ref document: A1 |