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WO2009154239A1 - Electric wire conductor for wiring, electric wire for wiring, and method for manufacturing electric wire conductor for wiring - Google Patents

Electric wire conductor for wiring, electric wire for wiring, and method for manufacturing electric wire conductor for wiring Download PDF

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Publication number
WO2009154239A1
WO2009154239A1 PCT/JP2009/061049 JP2009061049W WO2009154239A1 WO 2009154239 A1 WO2009154239 A1 WO 2009154239A1 JP 2009061049 W JP2009061049 W JP 2009061049W WO 2009154239 A1 WO2009154239 A1 WO 2009154239A1
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mass
wiring
wire
copper alloy
conductor
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Japanese (ja)
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功 高橋
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Furukawa Electric Co Ltd
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Furukawa Electric Co Ltd
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Priority to JP2010517949A priority Critical patent/JPWO2009154239A1/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C9/00Alloys based on copper
    • C22C9/06Alloys based on copper with nickel or cobalt as the next major constituent
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22FCHANGING THE PHYSICAL STRUCTURE OF NON-FERROUS METALS AND NON-FERROUS ALLOYS
    • C22F1/00Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working
    • C22F1/08Changing the physical structure of non-ferrous metals or alloys by heat treatment or by hot or cold working of copper or alloys based thereon
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B1/00Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors
    • H01B1/02Conductors or conductive bodies characterised by the conductive materials; Selection of materials as conductors mainly consisting of metals or alloys
    • H01B1/026Alloys based on copper

Definitions

  • the present invention relates to a method of manufacturing a wire conductor for wiring, a wire for wiring, and a wire conductor for wiring for automobiles, robots, electric / electronic devices and the like.
  • an annealed copper wire as stipulated in JIS C 3102 or a stranded wire obtained by twisting a wire plated with tin is used as a conductor, and this conductor is made of vinyl chloride, crosslinked.
  • An electric wire in which an insulator such as polyethylene is coated concentrically has been used.
  • Crimp connection is a method of wrapping an electric wire with a plate material and connecting it by caulking.
  • As a method for confirming the connection state by pressure bonding there is a measurement of pressure bonding strength.
  • the crimped section has a conductor cross-sectional area that is 20-30% smaller by caulking (hereinafter, the ratio of the cross-sectional area decreased by caulking is referred to as “cross-sectional reduction rate”), and the absolute value of the conductor strength decreases. Therefore, the breakage occurs at the caulked portion.
  • the present invention has been made, and it is an object of the present invention to provide a wiring electric wire conductor excellent in terminal crimping strength and a method of manufacturing the wiring electric wire conductor.
  • the present inventors have used an aging precipitation type copper alloy having a specific composition, the ratio of 0.2% proof stress to tensile strength is 0.70 to 0.92, and the work hardening index is 0.04. It has been found that by using a copper alloy wire of 0.17 or less, it is possible to produce a wire conductor for wiring that is excellent in tensile strength, has a low absolute strength during crimping, and has high terminal crimping strength. Moreover, it discovered that the said wire conductor for wiring can be obtained with sufficient reproducibility by performing the aging heat processing performed at the last process before formation of an insulation coating layer on specific conditions. The present invention has been completed based on these findings.
  • a plurality of copper alloy wires containing 1.0 to 4.5% by mass of Ni, 0.2 to 1.1% by mass of Si, and the balance of Cu and inevitable impurities are twisted together.
  • a wire conductor for wiring comprising at least one selected from the group consisting of a plurality of copper alloy wires having a composition comprising Cu and inevitable impurities, the balance being 0.2% of the copper alloy wire
  • a wire conductor for wiring wherein the ratio of proof stress and tensile strength is 0.70 or more and 0.92 or less, and the work hardening index is 0.04 or more and 0.17 or less, (3)
  • the composition of the copper alloy wire further includes at least one selected from the group consisting of 0.01 to 0.5% by mass of Mn and 0.05 to 0.5% by mass of Mg.
  • a method of manufacturing a wire conductor for wiring comprising each step of performing aging annealing at 550 ° C. for 1 minute to 5 hours; and (8) It contains 1.0 to 4.5% by mass of Ni, 0.2 to 1.1% by mass of Si, 0.005 to 1.0% by mass of Sn, and 0.005 to 0.005% of Fe. 2 mass%, Cr 0.005-0.2 mass%, Co 0.05-2 mass%, P 0.005-0.1 mass%, Ag 0.005-0.3 mass%
  • a copper alloy containing at least one selected from the group consisting of a composition consisting of Cu and inevitable impurities, and a solution treatment is applied to the resulting ingot or a round bar obtained therefrom.
  • a copper alloy wire is obtained by wire drawing to a wire diameter of 2 mm, and a plurality of the copper alloy wires are twisted, further compressed, and then subjected to aging annealing at 350 to 550 ° C. for 1 minute to 5 hours.
  • the ingot includes billets.
  • the wire conductor for wiring of the present invention is excellent in terminal crimping strength. Moreover, the electric wire conductor for wiring according to the present invention can be prevented from hot cracking when the conductor is produced, and can be excellent in workability when the wire is drawn into a small diameter. According to the method for manufacturing a wire conductor for wiring of the present invention, a wire conductor for wiring having the above-described excellent physical properties can be manufactured.
  • the wiring wire of the present invention can reduce the weight of the conductor by reducing the diameter of the conductor, and is suitable as a wiring wire for other signal wires for automobiles and robots, and electric / electronic devices. According to the method for manufacturing a wiring wire of the present invention, a wiring wire having the above-described excellent characteristics can be manufactured.
  • a preferred embodiment of the copper (Cu) alloy wire used for the wiring conductor of the present invention will be described in detail. First, the effect of each alloy element and the range of its content will be described.
  • Nickel (Ni) and silicon (Si) improve the strength of the copper alloy by forming Ni—Si precipitates (Ni 2 Si) in the matrix by controlling the content ratio of Ni and Si, thereby strengthening the precipitation. It is an element to be contained.
  • Ni content is 1.0 to 4.5% by mass, preferably 1.2 to 4.2% by mass. If the amount of Ni is too small, the precipitation hardening amount is small and the strength is insufficient. If the amount is too large, grain boundary precipitation occurs during heat treatment, and the strength decreases.
  • the Si content is 0.2 to 1.1% by mass, preferably 0.3 to 1.0% by mass.
  • the copper alloy material used in the present invention may contain at least one of tin (Sn), iron (Fe), chromium (Cr), cobalt (Co), phosphorus (P), and silver (Ag). preferable. These elements have a similar function in terms of improving strength, and when included, at least one selected from Sn, Fe, Cr, Co, P, and Ag, The total amount is preferably 0.005 to 2% by mass, more preferably 0.01 to 1.5% by mass.
  • Sn can be dissolved in copper and the strength can be improved by distorting the lattice.
  • the preferable content range when Sn is added is 0.005 to 1.0% by mass, and more preferably 0.05 to 0.2% by mass.
  • Fe and Cr combine with Si to form an Fe—Si compound and a Cr—Si compound, thereby improving the strength.
  • Fe—Si compounds and Cr—Si compounds have low precipitation hardening ability (age hardening ability), it is not a good idea from the viewpoint of improving strength to produce more of these compounds than necessary.
  • the contents in the case of containing Fe and Cr are preferably 0.005 to 0.2% by mass, more preferably 0.03 to 0.15% by mass, respectively.
  • Co like Ni, forms a compound with Si and improves the strength. Since Co is more expensive than Ni, the wire conductor for wiring as a preferred embodiment of the present invention uses a Cu—Ni—Si-based alloy. A —Si alloy or a Cu—Ni—Co—Si alloy may be selected. Cu-Co-Si alloys tend to be slightly better in strength and conductivity than Cu-Ni-Si alloys when aged. Therefore, it is effective for applications that place importance on these.
  • the content in the case of containing Co is preferably 0.05 to 2% by mass, and more preferably 0.08 to 1.5% by mass.
  • P has the effect of increasing strength. However, if a large amount is contained, the electrical conductivity is lowered, and grain boundary precipitation is promoted to lower the strength. Therefore, the preferable content range when P is added is 0.005 to 0.1 mass%, more preferably 0.01 to 0.05 mass%. Ag improves the strength. If the Ag content is too small, the effect cannot be obtained sufficiently. If the Ag content is too large, the effect is saturated but the effect is saturated, and the cost increases. From these viewpoints, the content when Ag is contained is preferably 0.005 to 0.3% by mass, and more preferably 0.01 to 0.2% by mass.
  • Mg magnesium
  • Mn manganese
  • the Mn content is preferably 0.01 to 0.5% by mass, and more preferably 0.1 to 0.35% by mass.
  • Zn zinc
  • the Zn content is preferably 0.1 to 1.5% by mass, and more preferably 0.4 to 1.2% by mass. If the content is too small, the above effect is not obtained, and if the content is too large, the electrical conductivity may decrease.
  • the copper alloy used in the present invention is an aging precipitation type alloy.
  • the copper alloy wire can be obtained as follows. First, an ingot obtained by casting by a conventional method so as to have an alloy composition specified in the present invention, a round bar obtained from the ingot by hot extrusion, hot forging, or rough drawing wire (hereinafter referred to as these The ingot, round bar, and rough wire are also referred to as wire material), and the solution wire material is drawn to a specified diameter (wire diameter) and then subjected to aging heat treatment. Apply. In the aging heat treatment, the above-described precipitation of Ni 2 Si occurs, and the strength and conductivity are improved.
  • the aging heat treatment conditions for decreasing the Y / T ratio vary depending on the degree of wire drawing ( ⁇ ), but in the present invention, the aging heat treatment conditions are preferably maintained at 350 to 550 ° C. for 1 minute to 5 hours.
  • the preferred aging heat treatment temperature is 450 to 550 ° C.
  • the preferred aging heat treatment temperature is 380 to 500 ° C. It is.
  • the preferable aging heat treatment temperature is 400 to 500 ° C.
  • the wire drawing degree ( ⁇ ) is larger than 4 (usually from 4).
  • the preferable aging heat treatment temperature is 380 to 480 ° C.
  • this Y / T ratio is 0.70 to 0.92, preferably 0.72 to 0.90.
  • the strain is not sufficiently released, so that the conductor itself has a small work hardening at the time of crimping, and the component or manufacturing process reduces the strength after aging heat treatment.
  • the cross-sectional reduction rate of the crimp terminal is 40% or less, the strength reduction of the crimp portion becomes large.
  • the cross-sectional area reduction rate at the time of crimping is the ratio at which the cross-sectional area is reduced by caulking at the time of crimping, and the cross-sectional area of the entire conductor strand before crimping is A 0 (mm 2 ).
  • the cross-section reduction rate of the crimp terminal is preferably 40% or less, more preferably 30% or less. Also, if the cross-section reduction rate during crimping is less than 5%, the conductor portion is likely to come out from the crimped portion of the terminal, and the electrical connection that is the original purpose becomes insufficient. Is 5% or more, more preferably 10% or more.
  • the wire material may be subjected to an aging heat treatment after a wire drawing process and then a twisting process.
  • a compression process may be added after the stranded wire process and before the aging heat treatment.
  • the compression may be performed after the aging heat treatment. In that case, it is preferable that the cross-section reduction rate of the crimping is 40% or less in consideration of the cross-section reduction in the compression.
  • C C is a coefficient
  • the material of the copper alloy wire constituting the wire conductor for wiring of the present invention can be manufactured by any of manufacturing methods such as hot extrusion of billets, hot forging of ingots, or continuous casting.
  • the wire conductor for wiring of the present invention is not only suitable as a wire conductor but also suitable as a wire for wiring provided with an insulating coating.
  • olefin resins such as polyethylene and polypropylene, or polyvinyl chloride (PVC) resins are preferable.
  • PVC polyvinyl chloride
  • a flame retardant, a cross-linking agent, or the like may be added to these to improve flame retardancy, mechanical strength, or the like.
  • the number of copper alloy wires as conductor wires to be twisted and the diameter of each strand, and the layer thickness of the insulating coating layer disposed on the strands It can be determined as appropriate according to the use of the wire for wiring. For example, 7 to 100 copper alloy wires having a diameter of 0.1 to 0.4 mm can be twisted to provide an insulation coating having a thickness of 0.1 to 1.0 mm.
  • the concept of the present invention can be applied to an aging precipitation type alloy other than the Cu—Ni—Si system of the present invention.
  • an aging precipitation type alloy such as Cu—Fe or Cu—Cr may be employed.
  • Example 1 An alloy having the composition shown in Table 1 was melted in a high frequency melting furnace, and each billet was cast. Next, the billet was hot extruded at 900 ° C. and immediately quenched in water to obtain a round bar (diameter 16 mm). Next, the round bar was drawn cold to obtain a copper alloy wire having a circular cross section with a diameter of 0.14 mm. The drawing work degree ( ⁇ ) from the round bar to the drawing was 9.5 (note that the drawing work degree was the same in the following Example 2, Comparative Example, and Reference Example). Seven wires were twisted and further compressed to obtain a stranded wire having a cross-sectional area of about 0.1 mm 2 . The stranded wire was subjected to an aging heat treatment at 430 ° C. for 2 hours, and further covered with an insulator (polyethylene) to produce a wiring wire having a length of 1 km.
  • insulator polyethylene
  • Example 2 shows the results of the crimping strength when the cross-sectional reduction rate of crimping is 10, 20, 30, and 40% for inventive examples 4 and 11 in Table 1. As the cross-sectional reduction rate of crimping increases, the crimping strength decreases, but in both cases, a practically satisfactory 50N or more is obtained as the crimping strength.
  • Table 3 shows examples 4 and 11 of the present invention in Table 1, with the aging heat treatment conditions after twisting being changed as follows, with Y / T ratios of 0.93 and 0.69, and n value 0.03 and 0.18 respectively, and comparative examples in which both are outside the scope of the present invention, and reference examples when the cross-section reduction rate of crimping is 50% and 60% are shown together with the test results, respectively. It is.
  • the aging heat treatment conditions were 390 ° C. for 2 hours in Comparative Examples 1 to 4, and 500 ° C. for 2 hours in Comparative Examples 5 to 8.
  • the crimping strength that is the same as that of the present invention is obtained when the cross-section reduction rate of the crimping is 10 to 30%.
  • the decrease in absolute strength due to the decrease in area is greater than 50N.
  • the crimping strength is 50 N or more until the cross-section reduction rate of crimping is 10 or 20%, but in the case of 30 or 40%. Below 50N.
  • Reference examples 1 to 4 in which the cross-section reduction rate of the crimping is 50% and 60% are also shown, but these all have a crimping strength of less than 50N.
  • Table 4 shows conventional examples together with test results.
  • the conventional example was manufactured by the following steps. That is, the conventional examples 1 and 2 are for soft copper (tough pitch copper), and the conventional examples 3 and 4 are for alloys having the compositions shown in Table 4 by the method described in paragraph 0032 of Patent Document 1 by a continuous casting and rolling apparatus. A rough-drawn wire was manufactured at, and then drawn in the cold to obtain a strand having a diameter of 0.14 mm. Seven strands were twisted and further compressed to obtain a stranded wire having a cross-sectional area of about 0.1 mm 2 , and further covered with an insulator (polyethylene) to obtain a wiring electric wire.
  • an insulator polyethylene
  • Conventional examples 1 and 3 were obtained by annealing the stranded wire with an electric heating device, and conventional examples 2 and 4 were obtained by performing no annealing. Each characteristic was measured by the same method as [1] to [4] described above. In the conventional examples, the pressure bonding strength is less than 50N, which is not practical.

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Abstract

Disclosed is an electric wire conductor for wiring, comprising a plurality of copper alloy wire rods which have been twisted together, the copper alloy wire rod having a composition comprising 1.0 to 4.5% by mass of Ni and 0.2 to 1.1% by mass of Si with the balance consisting of Cu and unavoidable impurities.  The copper alloy wire rod has a 0.2% proof stress to tensile strength ratio of 0.70 to 0.92 and a work hardening index of 0.04 to 0.17.  Also disclosed is an electric wire for wiring, comprising an insulating covering provided on the electric wire conductor for wiring.

Description

配線用電線導体、配線用電線および配線用電線導体の製造方法Wire conductor for wiring, wire for wiring, and method for manufacturing wire conductor for wiring

 この発明は、自動車、ロボット、電気・電子機器等の配線用電線導体、配線用電線および配線用電線導体の製造方法に関するものである。 The present invention relates to a method of manufacturing a wire conductor for wiring, a wire for wiring, and a wire conductor for wiring for automobiles, robots, electric / electronic devices and the like.

 従来、配線用電線の導体として、主にJIS C 3102に規定されるような軟銅線、またはこれに錫メッキ等を施した線を撚り合わせた撚線を導体とし、この導体に塩化ビニル、架橋ポリエチレン等の絶縁体を同心円状に被覆した電線が使用されてきた。
 これらの電線を機器と接続する場合、通常、圧着端子と呼ばれる端子を用いて圧着接続される。圧着接続とは、板材で電線を包み込み、かしめを行って接続する方法である。
 圧着による接続状態を確認する方法として圧着強度の測定がある。これは、電線を圧着端子に接続後、電線と端子とを掴んで引張試験を行い、破断が生じる時の強度を測定するものである。一般に圧着部はかしめにより導体の断面積が2~3割小さくなっており(以下、かしめにより断面積が減少した割合を「断面減少率」とする)、導体の強度の絶対値は低下しているため、破断はかしめ部分で生じる。
Conventionally, as a conductor of an electric wire for wiring, an annealed copper wire as stipulated in JIS C 3102 or a stranded wire obtained by twisting a wire plated with tin is used as a conductor, and this conductor is made of vinyl chloride, crosslinked. An electric wire in which an insulator such as polyethylene is coated concentrically has been used.
When these electric wires are connected to a device, they are usually crimp-connected using terminals called crimp terminals. Crimp connection is a method of wrapping an electric wire with a plate material and connecting it by caulking.
As a method for confirming the connection state by pressure bonding, there is a measurement of pressure bonding strength. In this method, after connecting an electric wire to a crimping terminal, the electric wire and the terminal are grasped, a tensile test is performed, and the strength at the time when breakage occurs is measured. In general, the crimped section has a conductor cross-sectional area that is 20-30% smaller by caulking (hereinafter, the ratio of the cross-sectional area decreased by caulking is referred to as “cross-sectional reduction rate”), and the absolute value of the conductor strength decreases. Therefore, the breakage occurs at the caulked portion.

 ところで、特に自動車配線回路においては、制御用等の信号電流回路の占める割合が高まり、使用する電線の本数および重量が増加してきた。
 一方、省エネルギの立場等からは、一つの手段として自動車重量の軽減化が要求されるようになってきた。そして、その対策の一つとして、電線導体の細径化による重量軽減化が求められている。しかしながら、従来の電線導体である銅の軟質材は、通電容量には十分余裕があるにもかかわらず、電線導体自体の機械的強度が低いため細径化することは困難であった。軟銅線の圧着強度は、かしめにより導体の断面積が低下しても、導体自身が加工硬化する余地があるため、圧着部の強度が未圧着部の強度とほぼ同等であり圧着強度の安定性は高いが、軟銅であるため強度そのものが低いという問題が大きい。
 そこで、機械的強度の向上策として、たとえば銅合金の硬質材の使用が検討されている(特許文献1参照)。
By the way, especially in an automobile wiring circuit, the ratio of signal current circuits for control and the like has increased, and the number and weight of electric wires used have increased.
On the other hand, from the standpoint of energy saving, etc., reduction of automobile weight has been required as one means. And as one of the countermeasures, weight reduction by reducing the diameter of the wire conductor is required. However, it has been difficult to reduce the diameter of a copper soft material, which is a conventional electric wire conductor, because the mechanical strength of the electric wire conductor itself is low, although the current carrying capacity has a sufficient margin. Even if the cross-sectional area of the conductor is reduced by caulking, there is room for the conductor itself to work and harden, so the strength of the crimped part is almost the same as that of the non-crimped part and the stability of the crimped strength However, the strength itself is low because of the soft copper.
Therefore, as a measure for improving the mechanical strength, for example, the use of a hard material of a copper alloy has been studied (see Patent Document 1).

特開2008-16284号公報JP 2008-16284 A

 ところで、特許文献1に記載された電線導体は、それ自身の加工硬化がほぼ飽和していると考えられる。この場合には、圧着端子を電線導体に接続する際のかしめによる断面積低下により電線導体の圧着部における絶対強度が低下するため、安定した圧着強度が得られないおそれがある。 Incidentally, it is considered that the electric wire conductor described in Patent Document 1 is almost saturated in its own work hardening. In this case, since the absolute strength in the crimping portion of the wire conductor is reduced due to a reduction in the cross-sectional area due to caulking when the crimp terminal is connected to the wire conductor, there is a possibility that a stable crimp strength cannot be obtained.

 このような問題に鑑み、本発明はなされたもので、端子圧着強度に優れる配線用電線導体、ならびにその配線用電線導体の製造方法を提供することを課題とするものである。 In view of such problems, the present invention has been made, and it is an object of the present invention to provide a wiring electric wire conductor excellent in terminal crimping strength and a method of manufacturing the wiring electric wire conductor.

 本発明者らは鋭意検討した結果、特定の組成の時効析出型銅合金を用い、0.2%耐力と引張強さとの比を0.70以上0.92以下、加工硬化指数を0.04以上0.17以下の銅合金線材を用いて構成することによって、引張強度に優れ、圧着時の絶対強度の低下が少なく端子圧着強度が高い配線用電線導体を製造し得ることを見出した。また、絶縁被覆層の形成前の最終工程で行う時効熱処理を特定の条件下で施すことによって、上記配線用電線導体を再現性よく得ることができることを見出した。本発明はこれらの知見に基づいて完成するに至ったものである。 As a result of intensive studies, the present inventors have used an aging precipitation type copper alloy having a specific composition, the ratio of 0.2% proof stress to tensile strength is 0.70 to 0.92, and the work hardening index is 0.04. It has been found that by using a copper alloy wire of 0.17 or less, it is possible to produce a wire conductor for wiring that is excellent in tensile strength, has a low absolute strength during crimping, and has high terminal crimping strength. Moreover, it discovered that the said wire conductor for wiring can be obtained with sufficient reproducibility by performing the aging heat processing performed at the last process before formation of an insulation coating layer on specific conditions. The present invention has been completed based on these findings.

 本発明によれば、以下の手段が提供される:
(1)Niを1.0~4.5質量%、Siを0.2~1.1質量%含有し、残部がCuと不可避不純物からなる組成を有する銅合金線材を複数本撚り合わせてなる配線用電線導体であって、前記銅合金線材の0.2%耐力と引張強さの比が0.70以上0.92以下であり、かつ加工硬化指数が0.04以上0.17以下であることを特徴とする配線用電線導体、
(2)Niを1.0~4.5質量%、Siを0.2~1.1質量%含有し、さらにSnを0.005~1.0質量%、Feを0.005~0.2質量%、Crを0.005~0.2質量%、Coを0.05~2質量%、Pを0.005~0.1質量%、Agを0.005~0.3質量%からなる群から選ばれる少なくとも1種を含有し、残部がCuと不可避不純物からなる組成を有する銅合金線材を複数本撚り合わせてなる配線用電線導体であって、前記銅合金線材の0.2%耐力と引張強さの比が0.70以上0.92以下であり、加工硬化指数が0.04以上0.17以下であることを特徴とする配線用電線導体、
(3)前記銅合金線材の組成が、Mnを0.01~0.5質量%、Mgを0.05~0.5質量%からなる群から選ばれる少なくとも1種をさらに含有することを特徴とする、(1)又は(2)に記載の配線用電線導体、
(4)前記銅合金線材の組成が、さらにZnを0.1~1.5質量%含有することを特徴とする、(1)~(3)のいずれか1項に記載の配線用電線導体、
(5)断面積が0.03~0.13mmであることを特徴とする、前記(1)~(4)のいずれか1項に記載の配線用電線導体、
(6)前記(1)~(5)のいずれか1項に記載の配線用電線導体が、その周囲に絶縁被覆を有してなることを特徴とする配線用電線、
(7)Niを1.0~4.5質量%、Siを0.2~1.1質量%含有し、残部がCuと不可避不純物からなる組成を有する銅合金を鋳造し、得られた鋳塊又はそれから得た丸棒に溶体化処理を施し、これを所定の線径に伸線加工して銅合金線材を得て、該銅合金線材を複数本撚り合わせ、さらに圧縮した後、350~550℃で、1分~5時間時効焼鈍を行う各工程を含んでなることを特徴とする配線用電線導体の製造方法、および、
(8)Niを1.0~4.5質量%、Siを0.2~1.1質量%含有し、さらにSnを0.005~1.0質量%、Feを0.005~0.2質量%、Crを0.005~0.2質量%、Coを0.05~2質量%、Pを0.005~0.1質量%、Agを0.005~0.3質量%からなる群から選ばれる少なくとも1種を含有し、残部がCuと不可避不純物からなる組成を有する銅合金を鋳造し、得られた鋳塊又はそれから得た丸棒に溶体化処理を施し、これを所定の線径に伸線加工して銅合金線材を得て、該銅合金線材を複数本撚り合わせ、さらに圧縮した後、350~550℃で、1分~5時間時効焼鈍を行う各工程を含んでなることを特徴とする配線用電線導体の製造方法。
 ここで、鋳塊にはビレットも含むものとする。
According to the present invention, the following means are provided:
(1) A plurality of copper alloy wires containing 1.0 to 4.5% by mass of Ni, 0.2 to 1.1% by mass of Si, and the balance of Cu and inevitable impurities are twisted together. A wire conductor for wiring, wherein the ratio of 0.2% yield strength and tensile strength of the copper alloy wire is 0.70 or more and 0.92 or less, and the work hardening index is 0.04 or more and 0.17 or less. A wire conductor for wiring, characterized by
(2) It contains 1.0 to 4.5% by mass of Ni, 0.2 to 1.1% by mass of Si, 0.005 to 1.0% by mass of Sn, and 0.005 to 0. 0% of Fe. 2 mass%, Cr 0.005-0.2 mass%, Co 0.05-2 mass%, P 0.005-0.1 mass%, Ag 0.005-0.3 mass% A wire conductor for wiring comprising at least one selected from the group consisting of a plurality of copper alloy wires having a composition comprising Cu and inevitable impurities, the balance being 0.2% of the copper alloy wire A wire conductor for wiring, wherein the ratio of proof stress and tensile strength is 0.70 or more and 0.92 or less, and the work hardening index is 0.04 or more and 0.17 or less,
(3) The composition of the copper alloy wire further includes at least one selected from the group consisting of 0.01 to 0.5% by mass of Mn and 0.05 to 0.5% by mass of Mg. The wire conductor for wiring according to (1) or (2),
(4) The wire conductor for wiring according to any one of (1) to (3), wherein the composition of the copper alloy wire further contains 0.1 to 1.5% by mass of Zn. ,
(5) The electric wire conductor for wiring according to any one of (1) to (4) above, wherein the cross-sectional area is 0.03 to 0.13 mm 2 ;
(6) The electric wire for wiring according to any one of the above (1) to (5), wherein the electric wire conductor for wiring has an insulating coating around it,
(7) A copper alloy containing 1.0 to 4.5% by mass of Ni and 0.2 to 1.1% by mass of Si, with the balance being composed of Cu and inevitable impurities, A solution treatment is applied to the lump or the round bar obtained from the lump, and this is drawn to a predetermined wire diameter to obtain a copper alloy wire, and a plurality of the copper alloy wires are twisted and further compressed. A method of manufacturing a wire conductor for wiring, comprising each step of performing aging annealing at 550 ° C. for 1 minute to 5 hours; and
(8) It contains 1.0 to 4.5% by mass of Ni, 0.2 to 1.1% by mass of Si, 0.005 to 1.0% by mass of Sn, and 0.005 to 0.005% of Fe. 2 mass%, Cr 0.005-0.2 mass%, Co 0.05-2 mass%, P 0.005-0.1 mass%, Ag 0.005-0.3 mass% A copper alloy containing at least one selected from the group consisting of a composition consisting of Cu and inevitable impurities, and a solution treatment is applied to the resulting ingot or a round bar obtained therefrom. A copper alloy wire is obtained by wire drawing to a wire diameter of 2 mm, and a plurality of the copper alloy wires are twisted, further compressed, and then subjected to aging annealing at 350 to 550 ° C. for 1 minute to 5 hours. The manufacturing method of the electric wire conductor for wiring characterized by these.
Here, the ingot includes billets.

 本発明の配線用電線導体は、端子圧着強度に優れる。
 また、本発明の配線用電線導体は、導体を製造する際の熱間割れが抑制され、細径に伸線加工する時の加工性に優れたものとすることができる。
 本発明の配線用電線導体の製造方法によれば、上述の優れた物性を有する配線用電線導体を製造できる。
 本発明の配線用電線は、導体の細径化により電線重量を低減することができ、自動車およびロボット用その他の信号用電線や、電気・電子機器等の配線用電線として好適である。
 本発明の配線用電線の製造方法によれば、上述の優れた特性を有する配線用電線を製造できる。
 本発明の上記及び他の特徴及び利点は、下記の記載からより明らかになるであろう。
The wire conductor for wiring of the present invention is excellent in terminal crimping strength.
Moreover, the electric wire conductor for wiring according to the present invention can be prevented from hot cracking when the conductor is produced, and can be excellent in workability when the wire is drawn into a small diameter.
According to the method for manufacturing a wire conductor for wiring of the present invention, a wire conductor for wiring having the above-described excellent physical properties can be manufactured.
The wiring wire of the present invention can reduce the weight of the conductor by reducing the diameter of the conductor, and is suitable as a wiring wire for other signal wires for automobiles and robots, and electric / electronic devices.
According to the method for manufacturing a wiring wire of the present invention, a wiring wire having the above-described excellent characteristics can be manufactured.
These and other features and advantages of the present invention will become more apparent from the following description.

 本発明の配線用電線導体に用いられる銅(Cu)合金線材の好ましい実施の態様について、詳細に説明する。まず、各合金元素の作用効果とその含有量の範囲について説明する。 A preferred embodiment of the copper (Cu) alloy wire used for the wiring conductor of the present invention will be described in detail. First, the effect of each alloy element and the range of its content will be described.

 ニッケル(Ni)とケイ素(Si)は、NiとSiの含有比を制御することによりマトリクス中にNi-Si析出物(NiSi)を形成させて析出強化を行い銅合金の強度を向上させるために含有する元素である。 Nickel (Ni) and silicon (Si) improve the strength of the copper alloy by forming Ni—Si precipitates (Ni 2 Si) in the matrix by controlling the content ratio of Ni and Si, thereby strengthening the precipitation. It is an element to be contained.

 Niの含有量は1.0~4.5質量%であり、1.2~4.2質量%であることが好ましい。Ni量が少なすぎるとその析出硬化量が小さく強度が不足する。多すぎれば熱処理時に粒界析出が生じ、強度が低下する。 Ni content is 1.0 to 4.5% by mass, preferably 1.2 to 4.2% by mass. If the amount of Ni is too small, the precipitation hardening amount is small and the strength is insufficient. If the amount is too large, grain boundary precipitation occurs during heat treatment, and the strength decreases.

 Siは質量%で計算するときはNi含有量の約1/4の時に最も強化量が大きくなる(強度が向上する)ことが知られている。本発明において、Siの含有量は0.2~1.1質量%であり、0.3~1.0質量%であることが好ましい。 It is known that when the Si is calculated by mass%, the strengthening amount becomes the largest (strength is improved) when the Ni content is about 1/4. In the present invention, the Si content is 0.2 to 1.1% by mass, preferably 0.3 to 1.0% by mass.

 また、本発明に用いられる銅合金材は、スズ(Sn)、鉄(Fe)、クロム(Cr)、コバルト(Co)、リン(P)および銀(Ag)の少なくとも1種を含有することが好ましい。これらの元素は強度を向上させるという点で類似の機能を有しているものであり、含有させる場合には、Sn、Fe、Cr、Co、P、Agの中から選ばれる少なくとも1種を、合計量として0.005~2質量%含有させることが好ましく、0.01~1.5質量%含有させることがより好ましい。 The copper alloy material used in the present invention may contain at least one of tin (Sn), iron (Fe), chromium (Cr), cobalt (Co), phosphorus (P), and silver (Ag). preferable. These elements have a similar function in terms of improving strength, and when included, at least one selected from Sn, Fe, Cr, Co, P, and Ag, The total amount is preferably 0.005 to 2% by mass, more preferably 0.01 to 1.5% by mass.

 Snは銅に固溶し、格子を歪ませることで強度を向上させることができる。ただし、Snの含有量が多すぎると導電率が低下する。よって、Snを添加する場合の好ましい含有範囲は0.005~1.0質量%であり、0.05~0.2質量%であることがさらに好ましい。
 Fe、CrはSiと結合し、Fe-Si化合物、Cr-Si化合物を形成し、強度を向上させる。また、Niとの化合物を形成せずにCuマトリクス中に残存するSiをトラップし、導電性を改善する効果がある。一方で、Fe-Si化合物、Cr-Si化合物は析出硬化能(時効硬化能)が低いため、これらの化合物を必要以上に多く生成させることは強度向上の観点から得策ではない。また、Fe、Crはそれぞれその含有量が多すぎると強度が低下してくる。これらの観点から、Fe、Crを含有させる場合の含有量は、それぞれ0.005~0.2質量%であることが好ましく、それぞれ0.03~0.15質量%であることがより好ましい。
 CoはNiと同様にSiと化合物を形成し、強度を向上させる。CoはNiに比べて高価であるため、本発明の好ましい実施形態としての配線用電線導体はCu-Ni-Si系合金を利用しているが、コスト的に許されるのであれば、Cu-Co-Si系合金やCu-Ni-Co-Si系合金を選択してもよい。Cu-Co-Si系合金は時効析出させた場合に、Cu-Ni-Si系合金より強度、導電性ともにわずかによくなる傾向がある。したがって、これらを重視する用途には有効である。以上の観点から、Coを含有させる場合の含有量は、0.05~2質量%であることが好ましく、0.08~1.5質量%であることがより好ましい。
 Pは強度を上昇させる効果を有する。ただし多量の含有は導電率を低下させ、また粒界析出を助長して強度を低下させる。よって、Pを添加する場合の好ましい含有範囲は0.005~0.1質量%、さらに好ましくは0.01~0.05質量%である。
 Agは強度を向上させる。Ag含有量が少なすぎではその効果が充分に得られず、多すぎると特性上に悪影響はないもののその効果が飽和し、コスト高になる。これらの観点から、Agを含有させる場合の含有量は0.005質量%~0.3質量%とすることが好ましく、0.01~0.2質量%とすることがより好ましい。
Sn can be dissolved in copper and the strength can be improved by distorting the lattice. However, when there is too much content of Sn, electrical conductivity will fall. Therefore, the preferable content range when Sn is added is 0.005 to 1.0% by mass, and more preferably 0.05 to 0.2% by mass.
Fe and Cr combine with Si to form an Fe—Si compound and a Cr—Si compound, thereby improving the strength. In addition, there is an effect of improving the conductivity by trapping Si remaining in the Cu matrix without forming a compound with Ni. On the other hand, since Fe—Si compounds and Cr—Si compounds have low precipitation hardening ability (age hardening ability), it is not a good idea from the viewpoint of improving strength to produce more of these compounds than necessary. Further, when the content of Fe and Cr is too large, the strength decreases. From these viewpoints, the contents in the case of containing Fe and Cr are preferably 0.005 to 0.2% by mass, more preferably 0.03 to 0.15% by mass, respectively.
Co, like Ni, forms a compound with Si and improves the strength. Since Co is more expensive than Ni, the wire conductor for wiring as a preferred embodiment of the present invention uses a Cu—Ni—Si-based alloy. A —Si alloy or a Cu—Ni—Co—Si alloy may be selected. Cu-Co-Si alloys tend to be slightly better in strength and conductivity than Cu-Ni-Si alloys when aged. Therefore, it is effective for applications that place importance on these. From the above viewpoint, the content in the case of containing Co is preferably 0.05 to 2% by mass, and more preferably 0.08 to 1.5% by mass.
P has the effect of increasing strength. However, if a large amount is contained, the electrical conductivity is lowered, and grain boundary precipitation is promoted to lower the strength. Therefore, the preferable content range when P is added is 0.005 to 0.1 mass%, more preferably 0.01 to 0.05 mass%.
Ag improves the strength. If the Ag content is too small, the effect cannot be obtained sufficiently. If the Ag content is too large, the effect is saturated but the effect is saturated, and the cost increases. From these viewpoints, the content when Ag is contained is preferably 0.005 to 0.3% by mass, and more preferably 0.01 to 0.2% by mass.

 さらに、本発明においては、マグネシウム(Mg)、マンガン(Mn)の少なくとも1種を含有することが好ましい。これらの元素は加熱時の脆化を防ぎ熱間加工性を改善するという点で類似の機能を有している。特に、本発明では銅合金線材を細径化して用いるが、素材に脆化した部分が内在している場合には細径にまで伸線加工ができないため、これらの元素を含有させることが好ましい。MgないしはMnを含有させる場合には、Mg、Mnの中から少なくとも1種を、合計量として0.01~0.5質量%含有させることが好ましく、0.05~0.3質量%含有させることがより好ましい。
 Mgの含有量は0.05~0.5質量%であることが好ましく、0.09~0.3質量%であることがさらに好ましい。その含有量が少なすぎるとその効果が小さく、多すぎると導電性を劣化させ、さらに冷間加工性を低下させ細径にまで伸線加工ができなくなる。
 Mnはその含有量が少なすぎるとその効果が小さく、多すぎても、含有量に見合った効果が得られないばかりでなく、導電性を劣化させ得る。よって、Mnの含有量は0.01~0.5質量%が好ましく、0.1~0.35質量%とすることがより好ましい。
Furthermore, in this invention, it is preferable to contain at least 1 sort (s) of magnesium (Mg) and manganese (Mn). These elements have similar functions in that they prevent embrittlement during heating and improve hot workability. In particular, in the present invention, the copper alloy wire is used with a reduced diameter. However, when the embrittled portion is inherent in the material, it cannot be drawn to a smaller diameter, so it is preferable to contain these elements. . When Mg or Mn is contained, it is preferable to contain at least one of Mg and Mn in a total amount of 0.01 to 0.5% by mass, preferably 0.05 to 0.3% by mass. It is more preferable.
The content of Mg is preferably 0.05 to 0.5% by mass, and more preferably 0.09 to 0.3% by mass. If the content is too small, the effect is small. If the content is too large, the electrical conductivity is deteriorated, the cold workability is further reduced, and the wire drawing cannot be performed to a small diameter.
If the content of Mn is too small, the effect is small. If the content is too large, not only an effect commensurate with the content cannot be obtained, but also the conductivity can be deteriorated. Accordingly, the Mn content is preferably 0.01 to 0.5% by mass, and more preferably 0.1 to 0.35% by mass.

 さらに、本発明においては亜鉛(Zn)を含有することが好ましい。Znは、加熱による銅合金線材と半田との密着力低下を防止する効果を有する。本発明において、Znを含有させることにより、銅合金線材をその端部において他の導体等と半田接合した際の界面の脆化を著しく改善する。本発明におけるZnの含有量は、0.1~1.5質量%が好ましく、0.4~1.2質量%であることがさらに好ましい。その含有量が少なすぎると前記効果がなく、含有量が多すぎると導電率が低下する場合がある。 Furthermore, in the present invention, it is preferable to contain zinc (Zn). Zn has an effect of preventing a decrease in adhesion between the copper alloy wire and the solder due to heating. In the present invention, inclusion of Zn significantly improves the embrittlement of the interface when the copper alloy wire is soldered to other conductors or the like at the end. In the present invention, the Zn content is preferably 0.1 to 1.5% by mass, and more preferably 0.4 to 1.2% by mass. If the content is too small, the above effect is not obtained, and if the content is too large, the electrical conductivity may decrease.

 次いで、本発明に用いられる銅合金線材の製造工程および機械的特性について述べる。
 本発明に用いられる銅合金は時効析出型の合金であり、例えば以下のようにしてこの銅合金の線材を得ることができる。まず、本発明で規定する合金組成となるように常法により鋳造して得た鋳塊や該鋳塊から熱間押出、熱間鍛造等で得た丸棒や荒引き線(以下、これらの鋳塊と丸棒、荒引き線とを併せて線材の材料ともいう)に溶体化処理を施し、この溶体化した線材の材料を所定の直径(線径)に伸線加工後、時効熱処理を施す。時効熱処理では、前述のNiSiの析出が生じ、強度の向上および導電率の向上が見られるが、同時に伸線加工で導入された歪の開放が生じるために引張強さ(T)に対する0.2%耐力(Y)の割合(これをY/T比と呼ぶ)が低下する。Y/T比が低下する時効熱処理条件は伸線加工度(η)により異なるが、本発明においては、時効熱処理条件として、350~550℃で1分~5時間保持することが好ましい。伸線加工前の線材の材料の直径をD(mm)とし、伸線加工後の線材の直径をD(mm)とすると、伸線加工度はη=2×ln(D/D)で表される。例えば、伸線加工度(η)が0の場合、好ましい時効熱処理温度は450~550℃であり、また、伸線加工度(η)が0より大きい場合、好ましい時効熱処理温度は380~500℃である。後者においては、伸線加工度(η)が0より大きく4以下の場合、好ましい時効熱処理温度は400~500℃であり、さらに、伸線加工度(η)が4より大きい(通常、4より大きく15以下)場合、好ましい時効熱処理温度は380~480℃である。
Next, the manufacturing process and mechanical properties of the copper alloy wire used in the present invention will be described.
The copper alloy used in the present invention is an aging precipitation type alloy. For example, the copper alloy wire can be obtained as follows. First, an ingot obtained by casting by a conventional method so as to have an alloy composition specified in the present invention, a round bar obtained from the ingot by hot extrusion, hot forging, or rough drawing wire (hereinafter referred to as these The ingot, round bar, and rough wire are also referred to as wire material), and the solution wire material is drawn to a specified diameter (wire diameter) and then subjected to aging heat treatment. Apply. In the aging heat treatment, the above-described precipitation of Ni 2 Si occurs, and the strength and conductivity are improved. At the same time, the strain introduced by the wire drawing process is released, so that the tensile strength (T) is zero. The ratio of 2% proof stress (Y) (this is called Y / T ratio) decreases. The aging heat treatment conditions for decreasing the Y / T ratio vary depending on the degree of wire drawing (η), but in the present invention, the aging heat treatment conditions are preferably maintained at 350 to 550 ° C. for 1 minute to 5 hours. When the diameter of the wire material before wire drawing is D 0 (mm) and the diameter of the wire after wire drawing is D (mm), the degree of wire drawing is η = 2 × ln (D 0 / D). It is represented by For example, when the wire drawing degree (η) is 0, the preferred aging heat treatment temperature is 450 to 550 ° C., and when the wire drawing work degree (η) is greater than 0, the preferred aging heat treatment temperature is 380 to 500 ° C. It is. In the latter case, when the wire drawing degree (η) is greater than 0 and 4 or less, the preferable aging heat treatment temperature is 400 to 500 ° C., and the wire drawing degree (η) is larger than 4 (usually from 4). In the case of large (15 or less), the preferable aging heat treatment temperature is 380 to 480 ° C.

 本発明においては、このY/T比は0.70~0.92であり、好ましくは0.72~0.90である。Y/T比をこの範囲とすることにより、端子圧着時の導体自身の加工硬化を大きくすることができ、圧着部の強度低下が少ない配線用電線導体とすることができる。Y/T比が0.70未満となるような時効熱処理条件では、過時効により強度が低下しており、電線として使用するのに適さない。また、Y/T比が0.92を超える条件では歪の解放が不十分であるため圧着時の導体自身の加工硬化が小さく、時効熱処理上がりの強度が低くなるような成分や製造工程となった場合に、圧着端子の断面減少率が40%以下であっても圧着部の強度低下が大きくなる。
 圧着時の断面減少率とは、圧着時にかしめにより断面積が減少した割合であって、圧着前の導体撚り線全体の断面積をA(mm)、圧着後の導体撚り線全体の断面積をA(mm)とすると、(A-A)/Aで表される。断面減少率が40%を超えると、Y/T比にかかわらず絶対強度の低下が大きくなる傾向があるため、圧着端子の断面減少率は好ましくは40%以下、より好ましくは30%以下である。また、圧着時の断面減少率が5%を下回ると、端子のかしめ部より導体部が抜けやすく、本来の目的である電気的な接合が不十分となるため、圧着時の断面減少率は好ましくは5%以上、より好ましくは10%以上である。
In the present invention, this Y / T ratio is 0.70 to 0.92, preferably 0.72 to 0.90. By setting the Y / T ratio within this range, it is possible to increase the work hardening of the conductor itself at the time of crimping the terminal, and it is possible to obtain a wiring electric wire conductor with little reduction in strength of the crimped portion. Under the aging heat treatment conditions such that the Y / T ratio is less than 0.70, the strength decreases due to overaging, and it is not suitable for use as an electric wire. In addition, when the Y / T ratio exceeds 0.92, the strain is not sufficiently released, so that the conductor itself has a small work hardening at the time of crimping, and the component or manufacturing process reduces the strength after aging heat treatment. In such a case, even if the cross-sectional reduction rate of the crimp terminal is 40% or less, the strength reduction of the crimp portion becomes large.
The cross-sectional area reduction rate at the time of crimping is the ratio at which the cross-sectional area is reduced by caulking at the time of crimping, and the cross-sectional area of the entire conductor strand before crimping is A 0 (mm 2 ). When the area is A (mm 2 ), it is represented by (A 0 -A) / A 0 . If the cross-section reduction rate exceeds 40%, the decrease in absolute strength tends to be large regardless of the Y / T ratio. Therefore, the cross-section reduction rate of the crimp terminal is preferably 40% or less, more preferably 30% or less. . Also, if the cross-section reduction rate during crimping is less than 5%, the conductor portion is likely to come out from the crimped portion of the terminal, and the electrical connection that is the original purpose becomes insufficient. Is 5% or more, more preferably 10% or more.

 なお、本発明は、前記線材の材料を伸線加工後、撚線工程を経た後に時効熱処理を行っても良い。さらに、撚線工程後であって時効熱処理前に圧縮工程を追加しても良い。また、時効熱処理後に圧縮を行っても良いが、その場合は、圧着の断面減少率は圧縮における断面減少も加味して40%以下となるようにすることが好ましい。 In the present invention, the wire material may be subjected to an aging heat treatment after a wire drawing process and then a twisting process. Further, a compression process may be added after the stranded wire process and before the aging heat treatment. In addition, the compression may be performed after the aging heat treatment. In that case, it is preferable that the cross-section reduction rate of the crimping is 40% or less in consideration of the cross-section reduction in the compression.

 また、加工硬化指数(以下、n値と呼ぶ)は加工性を表す値であり、降伏点以上の塑性域における応力σとひずみεとの関係(曲線)をσ=Cε(Cは係数)で近似させた時の指数nのことである。このn値が大きい方が歪の分布が平均化されやすい。本発明では、鋭意検討の結果、本合金系においては、上記Y/T比が0.70~0.92の範囲を満たし、n値が0.04~0.17の時に優れた圧着強度が得られることを見出した。 The work hardening index (hereinafter referred to as n value) is a value representing workability, and the relationship (curve) between stress σ and strain ε in a plastic region above the yield point is σ = Cε n (C is a coefficient) Is the index n when approximated by. The larger the n value, the easier the strain distribution is averaged. In the present invention, as a result of intensive studies, in this alloy system, the Y / T ratio satisfies the range of 0.70 to 0.92, and excellent crimp strength is obtained when the n value is 0.04 to 0.17. It was found that it can be obtained.

 本発明において、前記線材の材料の製造方法に制約は無い。例えば、ビレットの熱間押出、鋳塊の熱間鍛造、あるいは連続鋳造などの製造方法のいずれでも本発明の配線用電線導体を構成する銅合金線材の材料を製造することが可能である。 In the present invention, there is no restriction on the method for producing the wire material. For example, the material of the copper alloy wire constituting the wire conductor for wiring of the present invention can be manufactured by any of manufacturing methods such as hot extrusion of billets, hot forging of ingots, or continuous casting.

 本発明の配線用電線導体は、電線導体として適しているだけでなく、これに絶縁被覆が設けられた配線用電線としても好適なものとなる。絶縁被覆の材料としては、ポリエチレン、ポリプロピレン等のオレフィン系樹脂またはポリ塩化ビニル(PVC)樹脂等が好ましい。また、オレフィン系樹脂に関しては、これらに難燃剤や架橋剤等を添加して難燃性や機械強度等を高めたものとしてもよい。
 本発明の配線用電線においては、撚り合わされる導体素線としての銅合金線材の本数やその各素線の直径、また撚り線上に配される絶縁被覆層の層厚については特に制限はなく、配線用電線の用途に応じて適宜決めることができる。例えば、直径0.1~0.4mmの銅合金線材を7~100本撚り合わせ、厚さ0.1~1.0mmの絶縁被覆を設けることができる。
The wire conductor for wiring of the present invention is not only suitable as a wire conductor but also suitable as a wire for wiring provided with an insulating coating. As the material for the insulating coating, olefin resins such as polyethylene and polypropylene, or polyvinyl chloride (PVC) resins are preferable. In addition, regarding the olefin-based resin, a flame retardant, a cross-linking agent, or the like may be added to these to improve flame retardancy, mechanical strength, or the like.
In the electric wire for wiring of the present invention, there is no particular limitation on the number of copper alloy wires as conductor wires to be twisted and the diameter of each strand, and the layer thickness of the insulating coating layer disposed on the strands, It can be determined as appropriate according to the use of the wire for wiring. For example, 7 to 100 copper alloy wires having a diameter of 0.1 to 0.4 mm can be twisted to provide an insulation coating having a thickness of 0.1 to 1.0 mm.

 本発明の考え方は、本発明のCu-Ni-Si系以外の時効析出型合金にも適用できる。例えば、強度よりも導電性を重視する場合はCu-Fe系やCu-Cr系などの時効析出型合金を採用しても良い。 The concept of the present invention can be applied to an aging precipitation type alloy other than the Cu—Ni—Si system of the present invention. For example, when the electrical conductivity is more important than the strength, an aging precipitation type alloy such as Cu—Fe or Cu—Cr may be employed.

 以下に、本発明を実施例に基づきさらに詳細に説明するが、本発明はそれらに限定されるものではない。 Hereinafter, the present invention will be described in more detail based on examples, but the present invention is not limited thereto.

(実施例1)
 表1の合金成分で示される組成の合金を高周波溶解炉にて溶解し、各ビレットを鋳造した。次に、前記ビレットを900℃で熱間押出して、直ちに水中焼入れを行い、丸棒(直径16mm)を得た。次いで前記丸棒を冷間にて伸線し、直径0.14mmの断面円形状の銅合金線材を得た。丸棒から伸線への伸線加工度(η)は9.5であった(なお、以下の実施例2、比較例、参考例においても伸線加工度は同一であった。)。前記線材を7本撚り合わせ、さらに圧縮して断面積約0.1mmの撚線とした。前記撚線を430℃で2時間時効熱処理を行い、さらに絶縁体(ポリエチレン)で被覆し、長さ1kmの配線用電線を製造した。
Example 1
An alloy having the composition shown in Table 1 was melted in a high frequency melting furnace, and each billet was cast. Next, the billet was hot extruded at 900 ° C. and immediately quenched in water to obtain a round bar (diameter 16 mm). Next, the round bar was drawn cold to obtain a copper alloy wire having a circular cross section with a diameter of 0.14 mm. The drawing work degree (η) from the round bar to the drawing was 9.5 (note that the drawing work degree was the same in the following Example 2, Comparative Example, and Reference Example). Seven wires were twisted and further compressed to obtain a stranded wire having a cross-sectional area of about 0.1 mm 2 . The stranded wire was subjected to an aging heat treatment at 430 ° C. for 2 hours, and further covered with an insulator (polyethylene) to produce a wiring wire having a length of 1 km.

 このようにして得られた各々の銅合金線材と配線用電線とについて、[1]引張強度、[2]0.2%耐力、[3]圧着強度、[4]n値を下記方法により調べた。各評価項目の測定方法は以下の通りである。
[1]引張強度
 JIS Z 2241に準じて、1種の銅合金線材ごとに供試材3本について測定し、その平均値を引張強度(MPa)とした。
[2]0.2%耐力
 JIS Z 2241に記載のオフセット法に準じ、0.2%の永久伸びが生じる時の応力を求めた。1種の銅合金線材ごとに供試材3本について測定し、その平均値を0.2%耐力(MPa)とした。
[3]端子圧着強度
 得られた配線用電線を常法により圧着端子に接続し、電線と端子とを掴んで引張試験を行い、破断が生じた時の強度を求めた。圧着の断面減少率は20%とした。なお、実用上、圧着強度が50N未満であると、配線時または配線後に断線が生じる可能性が高くなる。
[4]n値
 上記[3]の引張試験で得られた応力-歪線図を真応力-真歪線図に変換し、その傾きからn値を読み取った。
 結果を表1に示す。いずれも、Y/T比は0.70以上0.92以下で、n値は0.04以上0.17以下であり、圧着強度として実用上差し支えない50N以上が得られている。
For each copper alloy wire and wiring wire thus obtained, [1] Tensile strength, [2] 0.2% yield strength, [3] Crimp strength, and [4] n value were examined by the following methods. It was. The measurement method for each evaluation item is as follows.
[1] Tensile strength According to JIS Z 2241, three specimens were measured for each type of copper alloy wire, and the average value was taken as the tensile strength (MPa).
[2] 0.2% Yield Strength According to the offset method described in JIS Z 2241, the stress when permanent elongation of 0.2% occurs was determined. Three test materials were measured for each type of copper alloy wire, and the average value was defined as 0.2% proof stress (MPa).
[3] Terminal crimping strength The obtained wiring electric wire was connected to the crimping terminal by a conventional method, and the tensile test was conducted by grasping the electric wire and the terminal to determine the strength when the breakage occurred. The cross-sectional reduction rate of the crimping was 20%. In practice, if the pressure bonding strength is less than 50 N, there is a high possibility of disconnection during or after wiring.
[4] n Value The stress-strain diagram obtained in the tensile test of [3] above was converted into a true stress-true strain diagram, and the n value was read from the slope.
The results are shown in Table 1. In either case, the Y / T ratio is 0.70 or more and 0.92 or less, the n value is 0.04 or more and 0.17 or less, and the compression strength of 50 N or more which is practically acceptable is obtained.

Figure JPOXMLDOC01-appb-T000001
Figure JPOXMLDOC01-appb-T000001

(実施例2)
 表1の本発明例4および11について、圧着の断面減少率を10、20、30、40%とした時の圧着強度の結果を表2に示す。圧着の断面減少率が増加するにつれ、圧着強度の低下が見られるが、いずれも圧着強度として実用上差し支えない50N以上が得られている。
(Example 2)
Table 2 shows the results of the crimping strength when the cross-sectional reduction rate of crimping is 10, 20, 30, and 40% for inventive examples 4 and 11 in Table 1. As the cross-sectional reduction rate of crimping increases, the crimping strength decreases, but in both cases, a practically satisfactory 50N or more is obtained as the crimping strength.

Figure JPOXMLDOC01-appb-T000002
Figure JPOXMLDOC01-appb-T000002

(比較例、参考例)
 表3は、表1の本発明例4および11について、撚線加工後の時効熱処理条件を以下のようにそれぞれ変えて、Y/T比を0.93および0.69で、かつ、n値をそれぞれ0.03、0.18と、いずれも本発明の範囲外とした比較例と、並びに圧着の断面減少率を50%、60%にしたときの参考例を、それぞれ試験結果とともに示すものである。前記時効熱処理条件は、比較例1~4では390℃で2時間であり、比較例5~8では500℃で2時間であった。
 Y/T比が0.93の例(比較例1~4)では、圧着の断面減少率が10~30%までは本発明例と変わらない圧着強度が得られているが、40%では断面積低下による絶対強度の低下が大きくなり50Nを下回っている。また、Y/T比が0.69の例(比較例5~8)では、圧着の断面減少率が10、20%までは圧着強度は50N以上が得られているが、30、40%では50Nを下回っている。
 なお、圧着の断面減少率が50%、60%である参考例1~4を併せて示すが、これらはいずれも圧着強度が50Nを下回っている。
(Comparative example, reference example)
Table 3 shows examples 4 and 11 of the present invention in Table 1, with the aging heat treatment conditions after twisting being changed as follows, with Y / T ratios of 0.93 and 0.69, and n value 0.03 and 0.18 respectively, and comparative examples in which both are outside the scope of the present invention, and reference examples when the cross-section reduction rate of crimping is 50% and 60% are shown together with the test results, respectively. It is. The aging heat treatment conditions were 390 ° C. for 2 hours in Comparative Examples 1 to 4, and 500 ° C. for 2 hours in Comparative Examples 5 to 8.
In the case where the Y / T ratio is 0.93 (Comparative Examples 1 to 4), the crimping strength that is the same as that of the present invention is obtained when the cross-section reduction rate of the crimping is 10 to 30%. The decrease in absolute strength due to the decrease in area is greater than 50N. In addition, in the examples where the Y / T ratio is 0.69 (Comparative Examples 5 to 8), the crimping strength is 50 N or more until the cross-section reduction rate of crimping is 10 or 20%, but in the case of 30 or 40%. Below 50N.
Reference examples 1 to 4 in which the cross-section reduction rate of the crimping is 50% and 60% are also shown, but these all have a crimping strength of less than 50N.

Figure JPOXMLDOC01-appb-T000003
Figure JPOXMLDOC01-appb-T000003

(従来例)
 表4に従来例をそれぞれ試験結果とともに示す。
 従来例は以下の工程で製造した。すなわち、従来例1、2は軟銅(タフピッチ銅)を、従来例3、4は表4の合金成分で示される組成の合金について、特許文献1の段落0032に記載された方法により連続鋳造圧延装置にて荒引き線を製造し、次いで冷間にて伸線し、直径0.14mmの素線を得た。前記素線を7本撚り合わせ、さらに圧縮して断面積約0.1mmの撚線を得て、さらに絶縁体(ポリエチレン)で被覆して配線用電線とした。前記撚線を通電加熱装置で焼鈍を行ったものを従来例1および3、焼鈍を行っていないものを従来例2および4とした。
 各特性の測定は、前述の[1]~[4]と同じ方法とした。従来例では、いずれも圧着強度は50N未満であり、実用的ではない。
(Conventional example)
Table 4 shows conventional examples together with test results.
The conventional example was manufactured by the following steps. That is, the conventional examples 1 and 2 are for soft copper (tough pitch copper), and the conventional examples 3 and 4 are for alloys having the compositions shown in Table 4 by the method described in paragraph 0032 of Patent Document 1 by a continuous casting and rolling apparatus. A rough-drawn wire was manufactured at, and then drawn in the cold to obtain a strand having a diameter of 0.14 mm. Seven strands were twisted and further compressed to obtain a stranded wire having a cross-sectional area of about 0.1 mm 2 , and further covered with an insulator (polyethylene) to obtain a wiring electric wire. Conventional examples 1 and 3 were obtained by annealing the stranded wire with an electric heating device, and conventional examples 2 and 4 were obtained by performing no annealing.
Each characteristic was measured by the same method as [1] to [4] described above. In the conventional examples, the pressure bonding strength is less than 50N, which is not practical.

Figure JPOXMLDOC01-appb-T000004
Figure JPOXMLDOC01-appb-T000004

 本発明をその実施態様とともに説明したが、我々は特に指定しない限り我々の発明を説明のどの細部においても限定しようとするものではなく、添付の請求の範囲に示した発明の精神と範囲に反することなく幅広く解釈されるべきであると考える。 While this invention has been described in conjunction with its embodiments, we do not intend to limit our invention in any detail of the description unless otherwise specified and are contrary to the spirit and scope of the invention as set forth in the appended claims. I think it should be interpreted widely.

 本願は、2008年6月17日に日本国で特許出願された特願2008-157599に基づく優先権を主張するものであり、これはここに参照してその内容を本明細書の記載の一部として取り込む。 This application claims priority based on Japanese Patent Application No. 2008-157599 filed in Japan on June 17, 2008, which is incorporated herein by reference. Capture as part.

Claims (8)

 Niを1.0~4.5質量%、Siを0.2~1.1質量%含有し、残部がCuと不可避不純物からなる組成を有する銅合金線材を複数本撚り合わせてなる配線用電線導体であって、前記銅合金線材の0.2%耐力と引張強さの比が0.70以上0.92以下であり、かつ加工硬化指数が0.04以上0.17以下であることを特徴とする配線用電線導体。 An electric wire for wiring formed by twisting a plurality of copper alloy wires containing 1.0 to 4.5% by mass of Ni, 0.2 to 1.1% by mass of Si, and the balance of Cu and inevitable impurities A ratio of 0.2% proof stress and tensile strength of the copper alloy wire is 0.70 or more and 0.92 or less, and a work hardening index is 0.04 or more and 0.17 or less. Characteristic wire conductor for wiring.  Niを1.0~4.5質量%、Siを0.2~1.1質量%含有し、さらにSnを0.005~1.0質量%、Feを0.005~0.2質量%、Crを0.005~0.2質量%、Coを0.05~2質量%、Pを0.005~0.1質量%、Agを0.005~0.3質量%からなる群から選ばれる少なくとも1種を含有し、残部がCuと不可避不純物からなる組成を有する銅合金線材を複数本撚り合わせてなる配線用電線導体であって、前記銅合金線材の0.2%耐力と引張強さの比が0.70以上0.92以下であり、加工硬化指数が0.04以上0.17以下であることを特徴とする配線用電線導体。 Containing 1.0 to 4.5% by mass of Ni, 0.2 to 1.1% by mass of Si, 0.005 to 1.0% by mass of Sn, and 0.005 to 0.2% by mass of Fe From the group consisting of 0.005 to 0.2% by mass of Cr, 0.05 to 2% by mass of Co, 0.005 to 0.1% by mass of P, and 0.005 to 0.3% by mass of Ag. A wire conductor for wiring formed by twisting a plurality of copper alloy wires having a composition composed of Cu and inevitable impurities, the balance being 0.2% proof stress and tensile strength of the copper alloy wires. A wire conductor for wiring, wherein the strength ratio is 0.70 or more and 0.92 or less, and the work hardening index is 0.04 or more and 0.17 or less.  前記銅合金線材の組成が、Mnを0.01~0.5質量%、Mgを0.05~0.5質量%からなる群から選ばれる少なくとも1種をさらに含有することを特徴とする、請求項1又は請求項2に記載の配線用電線導体。 The composition of the copper alloy wire further contains at least one selected from the group consisting of 0.01 to 0.5% by mass of Mn and 0.05 to 0.5% by mass of Mg. The wire conductor for wiring according to claim 1 or 2.  前記銅合金線材の組成が、さらにZnを0.1~1.5質量%含有することを特徴とする、請求項1~3のいずれか1項に記載の配線用電線導体。 The wire conductor for wiring according to any one of claims 1 to 3, wherein the composition of the copper alloy wire further contains 0.1 to 1.5 mass% of Zn.  断面積が0.03~0.13mmであることを特徴とする、請求項1~4のいずれか1項に記載の配線用電線導体。 The electric wire conductor for wiring according to any one of claims 1 to 4, wherein the cross-sectional area is 0.03 to 0.13 mm 2 .  請求項1~5のいずれか1項に記載の配線用電線導体が、その周囲に絶縁被覆を有してなることを特徴とする配線用電線。 A wiring electric wire according to any one of claims 1 to 5, wherein the wiring electric wire conductor has an insulating coating around it.  Niを1.0~4.5質量%、Siを0.2~1.1質量%含有し、残部がCuと不可避不純物からなる組成を有する銅合金を鋳造し、得られた鋳塊又はそれから得た丸棒に溶体化処理を施し、これを所定の線径に伸線加工して銅合金線材を得て、該銅合金線材を複数本撚り合わせ、さらに圧縮した後、350~550℃で、1分~5時間時効焼鈍を行う各工程を含んでなることを特徴とする配線用電線導体の製造方法。 An ingot obtained by casting a copper alloy containing 1.0 to 4.5% by mass of Ni, 0.2 to 1.1% by mass of Si, and the balance of Cu and inevitable impurities. The obtained round bar is subjected to a solution treatment, and this is drawn into a predetermined wire diameter to obtain a copper alloy wire, and a plurality of the copper alloy wires are twisted and further compressed, and then at 350 to 550 ° C. A method for producing a wire conductor for wiring, comprising the steps of aging annealing for 1 minute to 5 hours.  Niを1.0~4.5質量%、Siを0.2~1.1質量%含有し、さらにSnを0.005~1.0質量%、Feを0.005~0.2質量%、Crを0.005~0.2質量%、Coを0.05~2質量%、Pを0.005~0.1質量%、Agを0.005~0.3質量%からなる群から選ばれる少なくとも1種を含有し、残部がCuと不可避不純物からなる組成を有する銅合金を鋳造し、得られた鋳塊又はそれから得た丸棒に溶体化処理を施し、これを所定の線径に伸線加工して銅合金線材を得て、該銅合金線材を複数本撚り合わせ、さらに圧縮した後、350~550℃で、1分~5時間時効焼鈍を行う各工程を含んでなることを特徴とする配線用電線導体の製造方法。 Containing 1.0 to 4.5% by mass of Ni, 0.2 to 1.1% by mass of Si, 0.005 to 1.0% by mass of Sn, and 0.005 to 0.2% by mass of Fe From the group consisting of 0.005 to 0.2% by mass of Cr, 0.05 to 2% by mass of Co, 0.005 to 0.1% by mass of P, and 0.005 to 0.3% by mass of Ag. A copper alloy containing at least one selected and having the balance consisting of Cu and inevitable impurities is cast, and the obtained ingot or a round bar obtained therefrom is subjected to a solution treatment, and this is treated with a predetermined wire diameter. To obtain a copper alloy wire by wire drawing, twisting a plurality of the copper alloy wires, further compressing, and thereafter performing aging annealing at 350 to 550 ° C. for 1 minute to 5 hours A method for producing a wire conductor for wiring.
PCT/JP2009/061049 2008-06-17 2009-06-17 Electric wire conductor for wiring, electric wire for wiring, and method for manufacturing electric wire conductor for wiring Ceased WO2009154239A1 (en)

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JP2012028057A (en) * 2010-07-21 2012-02-09 Yazaki Corp Electric wire and electric wire with terminal
US9263165B2 (en) 2010-07-21 2016-02-16 Yazaki Corporation Electrical wire and electrical wire with terminal
US9786403B2 (en) 2010-07-21 2017-10-10 Yazaki Corporation Electrical wire and electrical wire with terminal
DE112011102402B4 (en) 2010-07-21 2020-07-30 Yazaki Corporation Wire with connector
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CN107532238A (en) * 2015-04-21 2018-01-02 株式会社自动网络技术研究所 Copper alloy wire, copper-alloy stranded conductor, covered electric cable and wire harness

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