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WO2009008929A9 - Commutateur bistable à l'échelle nanométrique - Google Patents

Commutateur bistable à l'échelle nanométrique Download PDF

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Publication number
WO2009008929A9
WO2009008929A9 PCT/US2008/004584 US2008004584W WO2009008929A9 WO 2009008929 A9 WO2009008929 A9 WO 2009008929A9 US 2008004584 W US2008004584 W US 2008004584W WO 2009008929 A9 WO2009008929 A9 WO 2009008929A9
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WO
WIPO (PCT)
Prior art keywords
terminals
voltage
swnt
nanoswitch
conductive
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2008/004584
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English (en)
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WO2009008929A8 (fr
WO2009008929A3 (fr
WO2009008929A2 (fr
Inventor
Sivasubramanian Somu
Ahmed Busnaina
Nicol Mcgruer
Peter Ryan
George G Adams
Xugang Xiong
Taehoon Kim
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Northeastern University China
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Northeastern University China
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Publication date
Application filed by Northeastern University China filed Critical Northeastern University China
Priority to US12/594,954 priority Critical patent/US8031514B2/en
Publication of WO2009008929A2 publication Critical patent/WO2009008929A2/fr
Publication of WO2009008929A3 publication Critical patent/WO2009008929A3/fr
Publication of WO2009008929A9 publication Critical patent/WO2009008929A9/fr
Anticipated expiration legal-status Critical
Publication of WO2009008929A8 publication Critical patent/WO2009008929A8/fr
Priority to US13/228,701 priority patent/US8211765B2/en
Priority to US13/534,105 priority patent/US8637356B2/en
Priority to US14/141,133 priority patent/US9117601B2/en
Ceased legal-status Critical Current

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Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01H—ELECTRIC SWITCHES; RELAYS; SELECTORS; EMERGENCY PROTECTIVE DEVICES
    • H01H11/00—Apparatus or processes specially adapted for the manufacture of electric switches
    • H01H11/04—Apparatus or processes specially adapted for the manufacture of electric switches of switch contacts
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y10/00—Nanotechnology for information processing, storage or transmission, e.g. quantum computing or single electron logic
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11C—STATIC STORES
    • G11C11/00—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor
    • G11C11/50—Digital stores characterised by the use of particular electric or magnetic storage elements; Storage elements therefor using actuation of electric contacts to store the information
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11C—STATIC STORES
    • G11C13/00—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00
    • G11C13/02—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using elements whose operation depends upon chemical change
    • G11C13/025—Digital stores characterised by the use of storage elements not covered by groups G11C11/00, G11C23/00, or G11C25/00 using elements whose operation depends upon chemical change using fullerenes, e.g. C60, or nanotubes, e.g. carbon or silicon nanotubes
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
    • H10K10/20—Organic diodes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y40/00—Manufacture or treatment of nanostructures
    • G—PHYSICS
    • G11—INFORMATION STORAGE
    • G11C—STATIC STORES
    • G11C2213/00—Indexing scheme relating to G11C13/00 for features not covered by this group
    • G11C2213/10—Resistive cells; Technology aspects
    • G11C2213/16—Memory cell being a nanotube, e.g. suspended nanotube
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K10/00—Organic devices specially adapted for rectifying, amplifying, oscillating or switching; Organic capacitors or resistors having potential barriers
    • H10K10/50—Bistable switching devices
    • H—ELECTRICITY
    • H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10K—ORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K85/00—Organic materials used in the body or electrodes of devices covered by this subclass
    • H10K85/20—Carbon compounds, e.g. carbon nanotubes or fullerenes
    • H10K85/221—Carbon nanotubes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/84—Manufacture, treatment, or detection of nanostructure
    • Y10S977/89—Deposition of materials, e.g. coating, cvd, or ald
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S977/00—Nanotechnology
    • Y10S977/902—Specified use of nanostructure
    • Y10S977/932—Specified use of nanostructure for electronic or optoelectronic application
    • Y10S977/943—Information storage or retrieval using nanostructure

Definitions

  • the invention relates to nanotechnology. More specifically, the invention relates to a non-volatile bistable nanoswitch for an electrical circuit.
  • Switching devices used in electronic components preferably provide high density, non-volatile storage at high speed, low power consumption, and low cost.
  • the use of nanotechnology has promised improvements in all of these areas.
  • WO 01/03208 describes the use of single-walled carbon nanotubes (SWNT) in crossbar junctions as memory devices.
  • SWNT single-walled carbon nanotubes
  • a nanowire such as a SWNT is suspended over other nanowires at a junction.
  • An electrical current in one or both nanowires causes either attraction or repulsion of the wires, resulting in the stable closing or opening of an electrical circuit.
  • the invention provides a non-volatile bistable nano-electromechanical switch employing one or more nanotubes such as SWNT as the actuation element.
  • the actuation of each of two different states can be achieved at about the same voltage, and at a relatively low voltage, compared to other SWNT electromechanical devices.
  • the nanoswitch device of the current invention can be applied in the fabrication of latches, flip-flops, registers, and other components used, for example, in microprocessor chips for computers and other applications.
  • a nanoswitch device according to the invention can also be incorporated with existing CMOS processes to fabricate nonvolatile memory devices, and modifications to the bistable nanoswitch can result in sensor devices such as radiation detectors, chemical sensors, thermal sensors, and biological sensors.
  • One aspect of the invention is a non-volatile, bistable nanoswitch device.
  • the device includes as the actuation element a single-walled carbon nanotube spanning a gap between first and second electrical terminals or contacts exposed on a surface of an insulating nanosubstrate. The gap between the terminals contains first and second nanoscale channels.
  • the device further contains a third electrical terminal exposed on the surface of the nanosubstrate. The third terminal is electrically connected to a first conductive layer situated within the first channel.
  • the device still further contains a fourth electrical terminal exposed on the surface of the nanosubstrate. The fourth terminal is electrically connected to a conductive layer situated within the second channel.
  • the nanotube moves within the first channel and forms an electrical contact with the conductive layer in the first channel.
  • application of a second voltage between the second and fourth terminals causes the nanotube to form an electrical contact with the conductive layer in the second channel.
  • the design of the nanoswitch is such that activation of state 1 is accompanied by inactivation of state 2, and the activation of state 2 is accompanied by inactivation of state 1.
  • Another aspect of the invention is an electrical component that includes one or more nanoswitch devices as described above.
  • the electrical component is a latch, a flip-flop, a register, or a relay.
  • the invention provides a method of actuating a nanoswitch device as described above.
  • the method includes the steps of: providing the nanoswitch device in state 1, having a non-volatile electrical connection between the first and third terminals; applying a voltage between the second and fourth terminals; and removing the voltage between the second and fourth terminals.
  • the method establishes a non-volatile electrical connection between the second and fourth terminals, and abolishes the electrical connection between the first and third terminals.
  • Still another aspect of the invention is a method of actuating a nanoswitch device as described above.
  • the method includes the steps of: providing the nanoswitch device in state 2, having a non-volatile electrical connection between the second and fourth terminals; applying a voltage between the first and third terminals; and removing the voltage between the first and third terminals.
  • the method establishes a non-volatile electrical connection between the first and third terminals, and abolishes the electrical connection between the second and fourth terminals.
  • Yet another aspect of the invention is a method of making a non-volatile, bistable nanoswitch device.
  • the method includes the steps of applying an insulating layer onto a substrate surface; applying a metal mask layer onto the insulating layer; applying a photoresist layer onto the metal mask layer; using lithography to fabricate in the photoresist, metal mask, and insulating layers first, second, third, and fourth nanoscale terminal areas and first and second nanoscale channels; applying a conductive layer onto the terminal areas, the channels, and the metal mask layer, whereby conductive terminals are formed in the terminal areas and conductive channels within the channels; removing the metal mask layer, leaving conductive layer inside the terminal areas and channels; and applying one or more actuation nanoelement across the insulating area and the first and second channels.
  • the nanoelement provides electrical contact between the conductive layer of the first and second terminals.
  • the terminals are situated around an insulating area containing the channels.
  • the first and second terminals are generally situated opposite each other, and the third and fourth terminals are generally situated opposite each other.
  • the third terminal is connected to the first channel and the fourth terminal is connected to the second channel.
  • the nanoelement actuator lies over the channels, and is capable of movement that establishes electrical contact between the nanoelement and the conductive layer in the channel when voltage is applied between the conductive layer of a channel and a terminal not connected to the channel.
  • Still another aspect of the invention is a method of integrating a single nanowire, such as a SWNT, into a nanocircuit.
  • the method includes the steps of: providing a nanosubstrate, a surface of which contains two conductive terminals separated by an insulating area; adding a liquid suspension of nanotubes, such as SWNT, to the surface of the nanosubstrate to cover the conductive terminals; performing dielectrophoresis by applying a voltage between the two conductive terminals; and removing excess SWNT using a stream of gas, such that only one SWNT remains in electrical contact with both conductive terminals.
  • Figure 1 shows schematic representations of a prior art nanoswitch device (Fig. IA) and an embodiment of the present invention (Fig. IB).
  • Figure 2 shows a perspective view of a nanoswitch device embodiment in which a single nanotube serves as the actuation element.
  • Figure 3 illustrates the non-volatility of two states (Fig. 3A, State 1 ; and Fig. 3B, State 2) in an embodiment of the nanoswitch device of the present invention, shown in cross section.
  • Figure 4 shows an example of a process for making a nanoswitch device of the present invention.
  • the insulating layer and metal mask layer have been etched to prepare conductive terminals and channels.
  • a conductive layer has been added in Fig. 4B.
  • the unwanted portions of the conductive layer have been removed together with the metal mask layer in Fig. 4C.
  • the actuation element a single-walled carbon nanotube, has been added in Fig. 4D.
  • Figure 5 shows an example of a process for making a nanoswitch device of the invention by adding sequential layers to a substrate, performing lithography, and etching.
  • Figure 6 illustrates the steps of a process for adding a single-walled nanotube as actuation element to a nanoswitch device.
  • Figure 7 shows a series of blunt (Fig. 7A), intermediate (Fig. 7B), and fine-tipped (Fig. 7C) electrodes for use in the dielectrophoretic assembly of a SWNT actuation element.
  • Figure 8 shows the effect of performing dielectrophoretic assembly of SWNT actuatiors using an AC voltage without (Fig. 8A) or with (Fig. 8B) a phase shifter.
  • Figure 9A shows a method for fabricating a bistable nanoswitch device having only one SWNT as actuator.
  • Figure 9B is an enlargement of the micrograph of Fig. 9A.
  • Figure 1OA shows a theoretical phase diagram of the volatility of the bridge structure as a function of the gap between the electrode and the carbon nanotube and the width of the electrode.
  • Figure 1OB shows the calculated upper limit of the actuation voltage as a function of the width and gap of the channel.
  • the inventors have developed a bistable nanoscale switching device capable of switching between two non-volatile states.
  • the device utilizes a nanoelement such as a single SWNT as the actuator.
  • a method for fabricating the nanoswitch has been developed in which one SWNT is attached by dielectrophoresis in a crossbar junction configuration that allows electromechanical forces to stably and repeatedly switch between two alternative electrical connections.
  • the nanoswitch can be incorporated into circuits such as flip-flops, latches, registers, and relays, and will find application as an element of electrical components such as memory devices and microprocessors.
  • FIG. 1 A comparison between a prior art nanoscale switch device and a device according to the present invention is shown in Fig. 1.
  • the earlier device design shown in Fig. IA requires a restoring electrode, whose fabrication requires additional steps.
  • the configuration of a device according to the present invention (Fig. 1 B) is simpler, resulting in lower production costs.
  • Furthe r instead of the patterned sheets of nanoelements used in many previous devices, the nanoswitch of the present invention can use SWNT bundles or even a single SWNT as the actuation element. The result is that less power is consumed in response to the same voltage applied for switching between two alternative states.
  • the configuration of the present invention allows the same low voltage to be used to set either of two states, allowing a 5-fold reduction in voltage compared to prior devices.
  • the dimensions of the device are in the nanometer range, and hence result in increased storage density compared to larger microscale devices.
  • Nanoswitch device 5 contains four metallic or conductive terminals A, B, C and D fabricated on a surface of an insulating substrate by well established nanofabrication and microfabrication methods. These terminals are also referred to herein as first terminal 80, second terminal 85, third terminal 90, and fourth terminal 95. The four terminals surround an insulating area on the surface of the substrate.
  • the substrate contains base layer 10 for mechanical support beneath insulating layer 20. The exact positions of each of the terminals is not critical and can be determined according to the situation or user preference.
  • first and second terminals are generally positioned opposite each other, and the third and fourth terminals are generally situated opposite each other.
  • the first and second terminals are positioned about 180 degrees from each other, and the third and fourth terminals are similarly positioned about 180 degrees from each other.
  • a line connecting the first and second terminals is approximately perpendicular to (at 90 degrees to) a line connecting the third and fourth terminals.
  • Third terminal 90 and fourth terminal 95 are extended to form trenches or channels in the insulating area between first terminal 80 and second terminal 85. More specifically, third terminal 90 is connected to first channel 40, and fourth terminal 95 is connected to second channel 42.
  • first and second terminals (80 and 85) may also be referred to as "electrodes” while the first and second channels (40 and 42) may also be referred to as "extension electrodes".
  • the two channels do not intersect, and do not connect with either first terminal 80 or second terminal 85.
  • the four terminals and the two channels are lined with a layer of conductive material 30.
  • the conductive layer of the terminals as well as the channels is preferably below the level of the insulator.
  • SWNT 50 electrically connects first terminal 80 with second terminal 85, but in the open state does not have electrical contact with the conductive layer in either channel 40 or channel 42.
  • the completely fabricated substrate 100 containing terminals 80, 85, 90, and 95 as well as channels 40 and 42 can be connected to a circuit, such as circuit 60 or circuit 70 as shown in Fig. IB, to form functional nanoswitch device 5.
  • the geometry described above is easily scalable, such that many more pairs of electrodes (similar to 80 and 85) and trenches (similar to 40 and 42) can be fabricated, thereby increasing the number of switches.
  • a critical voltage V cr also referred to herein as the "first threshold voltage”
  • the SWNT adheres to the extension electrode of terminal B and electrical continuity is established between terminals B and C.
  • state 1 a cross-sectional view of the state is shown in Fig. 3 A.
  • This critical voltage V cr is a function of the gap between the SWNT and the extension electrode, the width of the extension electrode, and the diameter of the SWNT.
  • a potential is applied between terminals D and A above the critical voltage V cr (also referred to herein as the "second threshold voltage”), the SWNT adheres to the extension electrode of terminal D, and electrical continuity is established between terminals D and A.
  • the axial tension of the SWNT increases enormously, and the SWNT overcomes the intermolecular forces responsible for SWNT attachment to the extension electrode of terminal B, thereby interrupting electrical continuity between terminals B and C.
  • state 2 a cross sectional view of this state is shown in Fig. 3B.
  • the critical voltage V cr is a function of the gap between the SWNT and the extension electrode, the width of the extension electrode, and the diameter of the SWNT.
  • a standard E-Beam lithography process (or a similar lithography process suitable for the nanometer scale, such as UV, immersion or EUV lithography) can be employed to expose the desired patterns onto a positive photoresist spun onto a metal deposited on an insulating substrate.
  • an anisotropic etching of the insulator is carried out, resulting in the structure depicted in Fig. 4A.
  • wet etching of the insulator is performed, e.g., by dipping the substrate in an etching solution. This ensures that an undercut is developed in the insulating trenches, so as to prevent metal deposition on the side walls.
  • Metal deposition is carried out, resulting in the structure shown in Fig. 4B. Metal deposition is immediately followed by a lift off process to yield a structure as shown in Fig. 4C, which is now ready for the assembly of SWNTs, resulting in the completed nanoswitch shown in Fig. 4D.
  • Fig. 5 depicts a sample layering, lithography, and etching process used to build the etched substrate of a nanoswitch device according to the invention.
  • Substrate layer 10 can be any material that provides mechanical support for the device and can be fabricated with standard techniques.
  • the substrate is preferably a non-conducting (insulating) or semiconducting material such as silicon, silicon dioxide, or silicon nitride. If the substrate itself is not sufficiently insulating, then insulating layer 20 can be added to the substrate, e.g., by thermal oxidation of silicon to form silicon dioxide.
  • the insulating layer is at least 80 nm in thickness.
  • the thickness of the insulating layer can be adjusted depending, for example, on the purity of the substrate material or the pattern of the trenches. The increased presence of impurities in, e.g., silicon used as the substrate base may be compensated by using a thicker insulating layer. The preferred thickness of the insulating layer also increases as the width of the trenches (first and second channels) increases. Suitable trench dimensions that maintain the non-volatile nature of the nanoswitch states can be determined, for example, by reference to Fig. 1OA.
  • Metal mask layer 22 is applied onto the insulating layer.
  • the metal mask layer can be a 20 nm thick layer of tungsten.
  • photoresist layer 24 is applied (e.g., spun on) to the mask layer.
  • the photoresist can be a 150 nm thick layer of polymethylmethacrylate (PMMA).
  • PMMA polymethylmethacrylate
  • the photoresist is exposed to provide the pattern of conducting material required to form the conductive terminals (electrodes) and channels (extension electrodes) of the device.
  • exposure can be by standard electron beam lithography.
  • the metal mask layer is etched.
  • a tungsten mask layer can be etched using SF 6 .
  • the insulating layer is then etched.
  • CHF 3 can be used to etch a silicon dioxide insulating layer to a depth of about -70 nm.
  • An additional wet etching step (e.g., using a 1 :50 dilution of 30% HF) is preferred, so as to undercut the channel regions, which will inhibit metal deposition on the side walls; such metal deposition could defeat the actuation mechanism.
  • the preferred etch rate is about 4 nm/min.
  • the conductive layer is applied, and subsequently the mask is lifted off. Any metallic conductor can be used for the conductive layer. For example, gold, silver, chromium, or any combination thereof can be used.
  • a preferred conducting layer is a 60 nm layer of Cr/Au.
  • the conductive layer remains slightly below the surface of the adjacent insulating layer at the terminals (electrodes), and well below the insulating layer surface adjacent to the channels (troughs).
  • assembly of one or more nanoelements such as SWNTs between the electrodes, for use as the actuator of the nanoswitch is performed using dielectrophoresis.
  • DEP dielectrophoresis
  • ⁇ ⁇ is the real permittivity of the suspending medium
  • E rms is the root mean square (rms) of the electric field
  • K( ⁇ ) is the Clausius-Mosotti factor
  • ⁇ * and ⁇ are the complex permittivity of the rod-like particle and the suspending medium, respectively
  • ⁇ * ⁇ — i( ⁇ /oo)
  • i ⁇ is the real permittivity
  • ⁇ is the conductivity of the material.
  • E is a material property and can be written as a product of the relative permittivity of the material and permittivity of free space ⁇ o-
  • an AC voltage source with a frequency in the range from about 100 kHz to about 10 MHz is preferred. A frequency of about 1 MHz is more preferred.
  • the amplitude of the AC voltage can be in the range from about 1 to about 5 volts.
  • a phase shifter is used to provide voltage gradients of opposite direction at the two electrodes during dielectrophoresis.
  • the nanoelement or nanoelements used as the actuation mechanism for the nanoswitch are preferably either SWNT or multi-walled carbon nanotubes.
  • the nanotube or nanotubes can be configured either as a bundle containing a small number of nanotubes, e.g., 1 or more, or about 1-10, 2-10, 3-10, or 5-10 nanotubes, or as a single nanotube spanning the first and second terminals of the nanoswitch device. Single nanotubes are most preferred as the actuator.
  • SWNT can be obtained from commercial sources as an aqueous suspension. For the studies described in the Examples, SWNT were obtained either from Nantero, Inc. (Woburn, MA) or from Brewer Science, Inc. (Rolla, MO).
  • the SWNT suspensions generally had a pH value in the range of 6-7 and a conductivity in the range from about 10 to about 40 ⁇ S/cm, or about 30 ⁇ S/cm. While individual nanotubes are preferred as the actuator, if a greater number of nanotubes is desired, then either the concentration of the nanotube suspension can be increased, or the time of dielectrophoresis can be increased.
  • the method of integrating a single nanowire, such as a SWNT or a multi-walled carbon nanotube, into the nanoswitch device of the present invention also can be used to integrate such a nanowire into a nanocircuit, for example, a circuit or device that does not function as a switch but performs another function.
  • a nanosubstrate for incorporation of the nanowire has a surface that contains at least two exposed conductive terminals separated by an insulating area.
  • a liquid suspension of nanotubes, such as SWNT is added to the surface of the nanosubstrate to cover the conductive terminals and a portion or all of the insulating area between them.
  • Dielectrophoresis is then performed by applying a voltage between the two terminals, for example, by using the terminals as electrodes for dielectrophoresis.
  • Conditions for dielectrophoresis are similar to or the same as those for assembling a SWNT in the nanoswitch of the present invention.
  • excess SWNT suspension can be removed using a stream of gas (e.g., nitrogen), such that only one SWNT remains in electrical contact with both conductive terminals.
  • a nanoswitch device is preferably non-volatile and bistable, i.e., existing in one of two stable switching states for a long period of time (e.g., for at least an hour, a day, a week, a month, a year, or longer) until a signal is sent to the deivce to switch it into the other state.
  • each state is characterized by possessing a conductance pathway between certain conductive terminals, but leaving an open circuit between others.
  • a method of switching from state 1 to state 2 can include the steps of: (1) providing a bistable, non- volatile nanoswitch device in state 1 , having a non-volatile electrical connection between first and third terminals; (2) applying a voltage between second and fourth terminals; and (3) removing the voltage between the second and fourth terminals. The method establishes a non-volatile electrical connection between the second and fourth terminals, and abolishes the electrical connection between the first and third terminals.
  • a related method of switching from state 2 to state 1 can include the steps of: (1) providing a bistable, non-volatile nanoswitch device in state 2, having a non-volatile electrical connection between second and fourth terminals; (2) applying a voltage between first and third terminals; and (3) removing the voltage between the first and third terminals.
  • the method establishes a non-volatile electrical connection between the first and third terminals, and abolishes the electrical connection between the second and fourth terminals.
  • An advantage of the present nanoswitch is that approximately the same low voltage will suffice to both switch the device from state 2 to state 1 (first voltage) and to switch it from state 1 to state 2 (second voltage).
  • the required voltage will depend on the particular design, but a switching voltage in the range of about 3 volts is preferred. Any voltage above the threshold required for switching can be used, but excessive voltage that could damage the device should be avoided.
  • aqueous suspension of commercially available highly purified SWNTs was used in the experiment.
  • the aqueous suspension was diluted to 10 ⁇ 5 g/ml using deionized water, and 1 ⁇ L of SWNT suspension 1 10 was deposited onto the surface of etched, metal-coated substrate 100 so as to bridge and cover the insulating area between the first and second electrodes and containing the extension electrodes.
  • the substrate was configured for dielectrophoresis as shown in Fig. 6 (120) by attaching leads to the first and second electrodes, and attaching the electrodes to AC voltage source 130. Assembly was conducted at a frequency of 1 MHz with the AC voltage between two electrodes in the range from 1 to 5 Vpp. After 1 min of assembly, the solution was dried using a stream of nitrogen gas.
  • Example I the resulting nanotubes were difficult to align appropriately and reproducibly by varying process parameters including pH, SWNT concentration, conductivity of the solution, AC voltage, and frequency of the applied field. Therefore, the dielectrophoretic process was modified to achieve better assembly. Specifically, modifications were directed to the electric field gradient, represented as VE rmE , in dielectrophoresis equations. It was discovered that a change of the electrode configuration was necessary to get the desired electrical field gradient. Dielectrophoresis was carried out using the same conditions as in Example I. In the case of flat electrodes, shown in Fig. 7A, a number of SWNTs were assembled over a large area between the two electrodes, because flat electrodes provide a uniform electric field over a large area.
  • VE rmE electric field gradient
  • Electrodes with a triangular shape at their tips also were fabricated (Fig. 7B), and again used to assemble SWNT using the same conditions as before. However, there were too many SWNTs assembled between two edge points as well as SWNT assembled at the angular point. Finally, very sharp electrodes were designed as shown in Fig. 7C and used to carry out the assembly of SWNTs using the same conditions. Using the sharp electrodes, the nanotubes assembled only between the tips, and did not form between two edge points, because the strength of electric field was reduced by the long distance between the edges.
  • a phase shifter was introduced to produce a field gradient at the ground electrode with opposite phase to that of the phase electrode. This is depicted schematically in Fig. 8, where the phase electrode is represented as electrode-A and the ground electrode as electrode-B.
  • Fig. 8 also presents scanning electron microscopy (SEM) images of SWNTs assembled without (Fig. 8A) or with (Fig. 8B) the use of phase shifting. The use of the phase shifter led to uniform SWNT assembly at both electrodes.
  • a non-linear model was employed to determine the mechanical and electrical limits for various device dimensions. Using the model, a phase diagram of the volatility of the bridge structure as a function of the gap between the electrode and the carbon nanotube and the width of the electrode was produced. The phase diagram is shown in Fig. 1 OA. The upper limit of the actuation voltage is shown in Fig. 1OB as a function of the width and gap of the trench. Slippage of the SWNT at the SWNT-electrode interface was not considered.

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  • Chemical & Material Sciences (AREA)
  • Nanotechnology (AREA)
  • Computer Hardware Design (AREA)
  • Physics & Mathematics (AREA)
  • Mathematical Physics (AREA)
  • Theoretical Computer Science (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Micromachines (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Semiconductor Memories (AREA)

Abstract

L'invention concerne un commutateur électromécanique, bistable, non volatile, à l'échelle nanométrique destiné à être utilisé dans des composants de mémoires et des microprocesseurs. Le commutateur utilise des nanotubes de carbone comme éléments d'actionnement. On a développé un procédé pour fabriquer des commutateurs et l'échelle nanométrique comportant un nanotube de carbone à simple paroi comme actionneur. L'actionnement de deux états différents peut être obtenu en utilisant la même basse tension pour chaque état.
PCT/US2008/004584 2007-04-09 2008-04-09 Commutateur bistable à l'échelle nanométrique Ceased WO2009008929A2 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
US12/594,954 US8031514B2 (en) 2007-04-09 2008-04-09 Bistable nanoswitch
US13/228,701 US8211765B2 (en) 2007-04-09 2011-09-09 Bistable nanoswitch
US13/534,105 US8637356B2 (en) 2007-04-09 2012-06-27 Method of integrating a single nanowire into a nanocircuit
US14/141,133 US9117601B2 (en) 2007-04-09 2013-12-26 System and method for integrating a single nanowire into a nanocircuit

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US92246807P 2007-04-09 2007-04-09
US60/922,468 2007-04-09

Related Child Applications (2)

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US12/594,954 A-371-Of-International US8031514B2 (en) 2007-04-09 2008-04-09 Bistable nanoswitch
US13/228,701 Division US8211765B2 (en) 2007-04-09 2011-09-09 Bistable nanoswitch

Publications (4)

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WO2009008929A2 WO2009008929A2 (fr) 2009-01-15
WO2009008929A3 WO2009008929A3 (fr) 2009-03-19
WO2009008929A9 true WO2009008929A9 (fr) 2009-04-30
WO2009008929A8 WO2009008929A8 (fr) 2010-08-05

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WO (1) WO2009008929A2 (fr)

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US8877636B1 (en) * 2010-02-26 2014-11-04 The United States Of America As Represented By The Adminstrator Of National Aeronautics And Space Administration Processing of nanostructured devices using microfabrication techniques
EP2363870A1 (fr) * 2010-03-04 2011-09-07 Thomson Licensing Commutateur électromécanique, dispositif de stockage comprenant un tel commutateur électromécanique et son procédé de fonctionnement
WO2012075006A2 (fr) * 2010-11-29 2012-06-07 Northeastern University Assemblage, à haute densité et commandé par champ électrique, de nanoéléments sur une surface isolée
TWI550267B (zh) * 2014-12-08 2016-09-21 國立清華大學 感測吹管的製作方法
RU2599461C1 (ru) * 2015-06-11 2016-10-10 федеральное государственное бюджетное образовательное учреждение высшего образования "Ульяновский государственный университет" Нанопереключатель
WO2020120133A1 (fr) * 2018-12-10 2020-06-18 Ludwig-Maximilians-Universität München Dispositif nanoélectrique et son procédé de production
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Also Published As

Publication number Publication date
US8211765B2 (en) 2012-07-03
WO2009008929A8 (fr) 2010-08-05
US20120052649A1 (en) 2012-03-01
US9117601B2 (en) 2015-08-25
WO2009008929A3 (fr) 2009-03-19
US20140202860A1 (en) 2014-07-24
US8637356B2 (en) 2014-01-28
US20100116631A1 (en) 2010-05-13
WO2009008929A2 (fr) 2009-01-15
US20120267223A1 (en) 2012-10-25
US8031514B2 (en) 2011-10-04

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