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WO2009007061A1 - Procédé destiné à produire un mélange gazeux riche en méthane à partir de gaz de synthèse contenant du soufre provenant d'une gazéification - Google Patents

Procédé destiné à produire un mélange gazeux riche en méthane à partir de gaz de synthèse contenant du soufre provenant d'une gazéification Download PDF

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Publication number
WO2009007061A1
WO2009007061A1 PCT/EP2008/005464 EP2008005464W WO2009007061A1 WO 2009007061 A1 WO2009007061 A1 WO 2009007061A1 EP 2008005464 W EP2008005464 W EP 2008005464W WO 2009007061 A1 WO2009007061 A1 WO 2009007061A1
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WO
WIPO (PCT)
Prior art keywords
gas
hydrogen
product gas
methane
bringing
Prior art date
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Ceased
Application number
PCT/EP2008/005464
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English (en)
Inventor
Serge Biollaz
Tilman J. Schildhauer
Martin Seemann
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Scherrer Paul Institut
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Scherrer Paul Institut
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Filing date
Publication date
Application filed by Scherrer Paul Institut filed Critical Scherrer Paul Institut
Priority to CA2693459A priority Critical patent/CA2693459A1/fr
Priority to US12/668,577 priority patent/US20100205863A1/en
Priority to EP08773866A priority patent/EP2167617A1/fr
Priority to CN200880106240.2A priority patent/CN101802146A/zh
Publication of WO2009007061A1 publication Critical patent/WO2009007061A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C10G2/32—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts
    • C10G2/33—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen with the use of catalysts characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2/00—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
    • C10G2/30—Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon from carbon monoxide with hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/02—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
    • C10G45/04—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/32—Selective hydrogenation of the diolefin or acetylene compounds
    • C10G45/34—Selective hydrogenation of the diolefin or acetylene compounds characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G47/00—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions
    • C10G47/02—Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen- generating compounds, to obtain lower boiling fractions characterised by the catalyst used
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/06—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including a sorption process as the refining step in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G67/00—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only
    • C10G67/02—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only
    • C10G67/14—Treatment of hydrocarbon oils by at least one hydrotreatment process and at least one process for refining in the absence of hydrogen only plural serial stages only including at least two different refining steps in the absence of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00—Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/08—Production of synthetic natural gas
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS
    • C10L3/00—Gaseous fuels; Natural gas; Synthetic natural gas obtained by processes not covered by subclass C10G, C10K; Liquefied petroleum gas
    • C10L3/06—Natural gas; Synthetic natural gas obtained by processes not covered by C10G, C10K3/02 or C10K3/04
    • C10L3/10—Working-up natural gas or synthetic natural gas
    • C10L3/101—Removal of contaminants
    • C10L3/102—Removal of contaminants of acid contaminants
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/16—Integration of gasification processes with another plant or parts within the plant
    • C10J2300/164—Integration of gasification processes with another plant or parts within the plant with conversion of synthesis gas
    • C10J2300/1656—Conversion of synthesis gas to chemicals
    • C10J2300/1665—Conversion of synthesis gas to chemicals to alcohols, e.g. methanol or ethanol
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10J—PRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00—Details of gasification processes
    • C10J2300/18—Details of the gasification process, e.g. loops, autothermal operation
    • C10J2300/1807—Recycle loops, e.g. gas, solids, heating medium, water

Definitions

  • the present invention relates to a method for converting coal or biomass to at least almost sulfur-free substitute natural gas. Further, the invention relates to a process to produce a methane rich gas mixture from gasification derived sulphur containing synthesis gases.
  • the present invention relates to a continuous production process of synthetic natural gas (SNG) from biomass, coal or naphta. More specifically, the present invention relates to the production of clean gaseous heating fuels from these less valuable sulphur containing hydrocarbonaceous materials.
  • SNG synthetic natural gas
  • SNG chemical vapor deposition
  • the production of SNG from biomass is the conversion of a "dirty/difficult" fuel into a clean burning well known commodity.
  • the costumer has the freedom to use the SNG for power generation, heating or mobility.
  • a big plus is the already existing infrastructure such as pipelines and compressed natural gas (NG) cars.
  • NG natural gas
  • the conversion of biomass to SNG is a complex process, which can be structured roughly into four main units; gasification, raw gas cleaning, fuel synthesis and gas sweetening.
  • a solid feed is thermally converted to a raw gas and subsequently cleaned of particles, tars and sulphur.
  • the raw gas is converted into raw SNG (a CH4/CO2 mixture) that is cleaned from CO 2 and optionally H 2 (gas sweetening) before injection into the natural gas grid.
  • H 2 S, COS or organic sulphur species depending on the temperature of the gasification.
  • Low temperature (LT) gasification promotes the formation of organic sulphur species such like thiophenes, mercaptanes and thio-ethers
  • HT high temperature
  • LT-gasification is advantageous (higher overall cold-gas efficiency) , as the raw gas contains already substantial amounts of CH 4 .
  • Drawbacks of this kind of raw gas are the high amount of poisonous components, such as alkenes, alkynes, H 2 S, COS, organic S-species, HCN, NH 3 , organic N-species.
  • FIG. 1a An example of a state of the art to produce synthesis gas for applications such as Fischer-Tropsch-Synthesis or production of Methanol, DME, and SNG is shown in figure Ia.
  • a scrubber at low temperatures is used to remove the tars and the organic S-species and N-species.
  • H 2 S, COS are absorbed on solid absorbers available for this duty (active carbon, ZnO or other metal oxides...) .
  • the gas cleaning is followed by a Water-Gas-Shift reactor, C0 2 -seperation and multiple methanation units. To increase the calorific value of the gas to the quality limits of the gas grid, CO 2 and H 2 is removed. The order of units 4-9 can be different.
  • the energetic effort in the gasification unit is higher for the production of pure H 2 , CO, CO 2 -mixtures;
  • the pure H 2 , CO, CO 2 -mixtures result in higher thermal losses in the synthesis due to the exothermic enthalpy of the methanation reaction.
  • a methane-rich stream can be produced from sulphur containing feedstocks containing 10 to 95 mol% of methane.
  • the first step following the Low-Temperature-gasification is a multifunctional process unit featuring hydrodesulphurization/denitrogenation, methanation, WGS, tar reforming and cracking and the hydrogenation/reforming of alkenes and alkynes simultaneously.
  • the H 2 S produced from the organic sulphur species by hydrolysis and the COS are removed by absorption on common absorber materials such like ZnO, CuO.
  • CO 2 can be removed before or after the 2 nd methanation step. For the adjustment of the calorific value excess H 2 is separated and may be recycled to unit 2.
  • the hydrodesulphurization unit is a common process step for the desulphurisation of feedstocks in the petrochemical industry or of natural gas before steam reforming.
  • the applied catalysts for these units tend to catalyse both methanation and watergas shift reaction which is unwanted as these exothermic reactions may lead to a thermal runaway of the reactor. In the subject process, however, the methanation and WGS-reactions are desired.
  • a fluidised bed reactor equipped with means for heat removal can be applied.
  • the catalyst fluidisation offers additionally the potential for internal regeneration of the catalyst from carbon deposits caused by compounds like ethylene or tars in the LT-gasifier producer gas.
  • Such an internal regeneration can be found for fluidised bed methanation and can be enhanced by staged addition of recycle H 2 and /or steam in the upper part of the fluidised bed.
  • the raw gas stream leaving the unit can be tailored to the requirements of a 2 nd methanation unit to minimise the total number of process units by the addition of steam, H 2 from the recycle and the proper choice of temperature and pressure. alkenes and alkynes simultaneously.
  • H 2 S produced from the organic sulphur species by hydrolysis and the COS are removed by absorption on common absorber materials such like ZnO, CuO.
  • CO 2 can be removed before or after the 2 nd methanation step. For the adjustment of the calorific value excess H 2 is separated and may be recycled to unit 2.
  • the hydrodesulphurization unit is a common process step for the desulphurisation of feedstocks in the petrochemical industry or of natural gas before steam reforming.
  • the applied catalysts for these units tend to catalyse both methanation and watergas shift reaction which is unwanted as these exothermic reactions may lead to a thermal runaway of the reactor. In the subject process, however, the methanation and WGS-reactions are desired.
  • a fluidised bed reactor equipped with means for heat removal can be applied.
  • the catalyst fluidisation offers additionally the potential for internal regeneration of the catalyst from carbon deposits caused by compounds like ethylene or tars in the LT-gasifier producer gas. Such an internal regeneration can be found for fluidised bed methanation and can be enhanced by staged addition of recycle H 2 and /or steam in the upper part of the fluidised bed.
  • the raw gas stream leaving the unit can be tailored to the requirements of a 2 nd methanation unit to minimise the total number of process units by the addition of steam, H 2 from the recycle and the proper choice of temperature and pressure.

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Industrial Gases (AREA)

Abstract

La présente invention concerne un procédé destiné à transformer un gaz brut en un gaz riche en méthane et/ou en un gaz riche en hydrogène, comprenant les étapes consistant à : a) fournir le gaz brut provenant d'un procédé de gazéification de charbon et/ou de biomasse, le gaz brut contenant ainsi, outre sa teneur en méthane et en hydrogène, du monoxyde de carbone, du dioxyde de carbone, des alcanes, des alcènes, des alcynes, du goudron, en particulier du benzol et du naphtalène, du COS, du sulfure d'hydrogène et des composés de soufre organique, en particulier des thiophènes ; ainsi, le rapport hydrogène sur monoxyde de carbone va de 0,3 à 4 ; b) mettre ce gaz brut en contact avec un catalyseur agencé sous la forme d'un réacteur à lit fluidisé à des températures supérieures à 200 °C et à des pressions supérieures ou égales à 1 bar afin de transformer le gaz brut en un premier gaz de gazogène et, ainsi, de simultanément transformer les composants de soufre organique en sulfure d'hydrogène, reformer les goudrons, générer une réaction de conversion à la vapeur d'eau et générer du méthane à partir de la teneur en hydrogène/monoxyde de carbone ; c) soumettre le premier gaz de gazogène à un procédé d'absorption de soufre afin de générer un deuxième gaz de gazogène, réduisant ainsi la teneur en sulfure d'hydrogène et en COS, comprise entre 100 et 1000 ppm, jusqu'à 1000 ppM ou moins ; d) éventuellement soumettre le deuxième gaz de gazogène à un procédé d'élimination du dioxyde de carbone afin de générer un troisième gaz de gazogène au moins quasiment exempt de dioxyde de carbone ; e) soumettre le troisième gaz de gazogène à un deuxième procédé de méthanisation afin de générer un quatrième gaz de gazogène présentant une teneur en méthane supérieure à 5 % en volume ; f) ) éventuellement soumettre le quatrième gaz de gazogène à un procédé d'élimination du dioxyde de carbone afin de générer un cinquième gaz de gazogène au moins quasiment exempt de dioxyde de carbone ; g) soumettre le cinquième gaz de gazogène à un procédé de séparation d'hydrogène afin de séparer un gaz riche en hydrogène d'un gaz riche en méthane restant, appelé gaz naturel de substitution.
PCT/EP2008/005464 2007-07-10 2008-07-03 Procédé destiné à produire un mélange gazeux riche en méthane à partir de gaz de synthèse contenant du soufre provenant d'une gazéification Ceased WO2009007061A1 (fr)

Priority Applications (4)

Application Number Priority Date Filing Date Title
CA2693459A CA2693459A1 (fr) 2007-07-10 2008-07-03 Procede destine a produire un melange gazeux riche en methane a partir de gaz de synthese contenant du soufre provenant d'une gazeification
US12/668,577 US20100205863A1 (en) 2007-07-10 2008-07-03 Process to Produce a Methane Rich Gas Mixture From Gasification Derived Sulphur Containing Synthesis Gases
EP08773866A EP2167617A1 (fr) 2007-07-10 2008-07-03 Procédé destiné à produire un mélange gazeux riche en méthane à partir de gaz de synthèse contenant du soufre provenant d'une gazéification
CN200880106240.2A CN101802146A (zh) 2007-07-10 2008-07-03 由气化得到的含硫合成气制造富甲烷气体混合物的方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07013482.0 2007-07-10
EP07013482 2007-07-10

Publications (1)

Publication Number Publication Date
WO2009007061A1 true WO2009007061A1 (fr) 2009-01-15

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PCT/EP2008/005464 Ceased WO2009007061A1 (fr) 2007-07-10 2008-07-03 Procédé destiné à produire un mélange gazeux riche en méthane à partir de gaz de synthèse contenant du soufre provenant d'une gazéification

Country Status (5)

Country Link
US (1) US20100205863A1 (fr)
EP (1) EP2167617A1 (fr)
CN (1) CN101802146A (fr)
CA (1) CA2693459A1 (fr)
WO (1) WO2009007061A1 (fr)

Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL2002756C2 (nl) * 2009-04-16 2010-10-19 Stichting Energie Werkwijze en systeem voor het vervaardigen van een brandbaar gas uit een brandstof.
WO2011060539A1 (fr) * 2009-11-18 2011-05-26 G4 Insights Inc. Procédé et système d'hydrogazéification de la biomasse
WO2011076315A3 (fr) * 2009-12-23 2011-09-15 Solar Fuel Gmbh Procédé de production d'un gaz de produit riche en méthane, et système de réacteur utilisable à cet effet
CN102250658A (zh) * 2010-05-19 2011-11-23 上海标氢气体技术有限公司 焦炉煤气和高炉煤气原料转化制液化天然气的方法
WO2012024112A1 (fr) * 2010-08-19 2012-02-23 Fina Technology, Inc. Matériaux plastiques « écologiques » et méthodes de fabrication de ceux-ci
WO2013076051A1 (fr) 2011-11-21 2013-05-30 Gdf Suez Procede de production de biomethane
DE102012013000A1 (de) 2012-06-28 2014-01-02 Linde Aktiengesellschaft Prozess zur kombinierten Herstellung von Wasserstoff und Ethylen
WO2014057004A1 (fr) * 2012-10-11 2014-04-17 Zentrum für Sonnenenergie- und Wasserstoff-Forschung Baden-Württemberg Procédé et dispositif de production d'un substitut de gaz naturel contenant du méthane et système d'alimentation en énergie correspondant
US8715616B2 (en) 2011-02-11 2014-05-06 Phillips 66 Company Soak and coke
CN104232194A (zh) * 2013-06-07 2014-12-24 中国海洋石油总公司 一种由炭质材料生产甲烷联产液体燃料的方法
WO2015011503A1 (fr) * 2013-07-26 2015-01-29 Advanced Plasma Power Limited Procédé de production d'un substitut du gaz naturel
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WO2015011503A1 (fr) * 2013-07-26 2015-01-29 Advanced Plasma Power Limited Procédé de production d'un substitut du gaz naturel
WO2017178769A1 (fr) 2016-04-15 2017-10-19 Engie Dispositif et procede de cogeneration de methanol et de methane de synthese
WO2022013239A1 (fr) 2020-07-14 2022-01-20 Engie Dispositif et procédé de production hybride de dihydrogène de synthèse et/ou de méthane de synthèse

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