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WO2009075744A3 - Compositions durcissables à base de benzoxazines, leur procédé d'obtention et produits durcis issus de ces compositions - Google Patents

Compositions durcissables à base de benzoxazines, leur procédé d'obtention et produits durcis issus de ces compositions Download PDF

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Publication number
WO2009075744A3
WO2009075744A3 PCT/US2008/013291 US2008013291W WO2009075744A3 WO 2009075744 A3 WO2009075744 A3 WO 2009075744A3 US 2008013291 W US2008013291 W US 2008013291W WO 2009075744 A3 WO2009075744 A3 WO 2009075744A3
Authority
WO
WIPO (PCT)
Prior art keywords
preparation
based compositions
cured products
benzoxazine
curable benzoxazine
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2008/013291
Other languages
English (en)
Other versions
WO2009075744A2 (fr
Inventor
Stefan Kreiling
Rainer Schonfeld
Andreas Taden
Stanley L Lehmann
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Henkel AG and Co KGaA
Henkel Corp
Original Assignee
Henkel AG and Co KGaA
Henkel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Henkel AG and Co KGaA, Henkel Corp filed Critical Henkel AG and Co KGaA
Priority to BRPI0820012A priority Critical patent/BRPI0820012B1/pt
Priority to CA2708081A priority patent/CA2708081C/fr
Priority to ES08859554.1T priority patent/ES2556708T3/es
Priority to CN2008801191668A priority patent/CN101889048B/zh
Priority to EP08859554.1A priority patent/EP2217650B1/fr
Publication of WO2009075744A2 publication Critical patent/WO2009075744A2/fr
Publication of WO2009075744A3 publication Critical patent/WO2009075744A3/fr
Priority to US12/766,112 priority patent/US8759443B2/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/16—Nitrogen-containing compounds
    • C08K5/34—Heterocyclic compounds having nitrogen in the ring
    • C08K5/35—Heterocyclic compounds having nitrogen in the ring having also oxygen in the ring
    • C08K5/357—Six-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/52—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
    • C07D263/54—Benzoxazoles; Hydrogenated benzoxazoles
    • C07D263/56—Benzoxazoles; Hydrogenated benzoxazoles with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached in position 2
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D263/00—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings
    • C07D263/52—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems
    • C07D263/62—Heterocyclic compounds containing 1,3-oxazole or hydrogenated 1,3-oxazole rings condensed with carbocyclic rings or ring systems having two or more ring systems containing condensed 1,3-oxazole rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/10—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
    • C08G18/12—Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step using two or more compounds having active hydrogen in the first polymerisation step
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/65—Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
    • C08G18/66—Compounds of groups C08G18/42, C08G18/48, or C08G18/52
    • C08G18/6666—Compounds of group C08G18/48 or C08G18/52
    • C08G18/667—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38
    • C08G18/6674—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203
    • C08G18/6677—Compounds of group C08G18/48 or C08G18/52 with compounds of group C08G18/32 or polyamines of C08G18/38 with compounds of group C08G18/3203 having at least three hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G73/00—Macromolecular compounds obtained by reactions forming a linkage containing nitrogen with or without oxygen or carbon in the main chain of the macromolecule, not provided for in groups C08G12/00 - C08G71/00
    • C08G73/02—Polyamines
    • C08G73/0233—Polyamines derived from (poly)oxazolines, (poly)oxazines or having pendant acyl groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L79/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen or carbon only, not provided for in groups C08L61/00 - C08L77/00
    • C08L79/02—Polyamines

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Phenolic Resins Or Amino Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
  • Polyurethanes Or Polyureas (AREA)

Abstract

L'invention concerne une composition durcissable comprenant: au moins une benzoxazine et au moins un additif durcisseur pouvant se lier à au moins une benzoxazine pendant le durcissement, caractérisée en ce que l'additif durcisseur est réparti dans la composition durcie sous forme de domaines séparés, et que au moins 50% de ces domaines séparés par rapport à leur quantité totale ont, dans quelque direction spatiale que ce soit, une longueur maximale comprise entre 10 nm et 500 nm, comme déterminé par microscopie électronique à transmission (MET).
PCT/US2008/013291 2007-12-06 2008-12-02 Compositions durcissables à base de benzoxazines, leur procédé d'obtention et produits durcis issus de ces compositions Ceased WO2009075744A2 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BRPI0820012A BRPI0820012B1 (pt) 2007-12-06 2008-12-02 composições baseadas em benzoxazina curáveis, sua preparação e produtos curados a partir das mesmas
CA2708081A CA2708081C (fr) 2007-12-06 2008-12-02 Compositions durcissables a base de benzoxazines, leur procede d'obtention et produits durcis issus de ces compositions
ES08859554.1T ES2556708T3 (es) 2007-12-06 2008-12-02 Composiciones curables a base de benzoxazinas, su preparación y productos curados de las mismas
CN2008801191668A CN101889048B (zh) 2007-12-06 2008-12-02 基于苯并噁嗪的可固化组合物、它们的制备及其固化产物
EP08859554.1A EP2217650B1 (fr) 2007-12-06 2008-12-02 Compositions durcissables à base de benzoxazines, leur procédé d'obtention et produits durcis issus de ces compositions
US12/766,112 US8759443B2 (en) 2007-12-06 2010-04-23 Curable benzoxazine-based compositions, their preparation and cured products thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US99291707P 2007-12-06 2007-12-06
US60/992,917 2007-12-06

Related Child Applications (1)

Application Number Title Priority Date Filing Date
US12/766,112 Continuation US8759443B2 (en) 2007-12-06 2010-04-23 Curable benzoxazine-based compositions, their preparation and cured products thereof

Publications (2)

Publication Number Publication Date
WO2009075744A2 WO2009075744A2 (fr) 2009-06-18
WO2009075744A3 true WO2009075744A3 (fr) 2009-08-20

Family

ID=40756023

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2008/013291 Ceased WO2009075744A2 (fr) 2007-12-06 2008-12-02 Compositions durcissables à base de benzoxazines, leur procédé d'obtention et produits durcis issus de ces compositions

Country Status (7)

Country Link
US (1) US8759443B2 (fr)
EP (1) EP2217650B1 (fr)
CN (1) CN101889048B (fr)
BR (1) BRPI0820012B1 (fr)
CA (1) CA2708081C (fr)
ES (1) ES2556708T3 (fr)
WO (1) WO2009075744A2 (fr)

Families Citing this family (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ES2435547T3 (es) * 2007-12-06 2013-12-20 Henkel Ag & Co. Kgaa Composiciones curables que contienen endurecedores basados en isocianato
ES2736175T3 (es) * 2007-12-06 2019-12-26 Henkel Ag & Co Kgaa Macromonómeros de benzoxazina curables, su preparación y productos curados de los mismos
CA2737833C (fr) * 2008-09-19 2016-08-09 Henkel Ag & Co. Kgaa Compositions a base de benzoxazine contenant des durcisseurs a base d'isocyanate
US8389758B2 (en) 2009-06-05 2013-03-05 3M Innovative Properties Company Benzoxazine-thiol adducts
US8383706B2 (en) * 2009-06-05 2013-02-26 3M Innovative Properties Company Benzoxazine-thiol adducts
GB201101302D0 (en) * 2011-01-25 2011-03-09 Cytec Tech Corp Benzoxazine resins
ES2623013T3 (es) * 2011-08-11 2017-07-10 Huntsman Advanced Materials Americas Llc Método para producir compuestos de benzoxazina
US8410202B1 (en) * 2011-10-24 2013-04-02 Xerox Corporation Coating compositions
CN107995916B (zh) 2015-07-23 2021-08-10 亨斯迈先进材料美国有限责任公司 可固化的苯并噁嗪组合物
JP7204907B2 (ja) * 2018-11-09 2023-01-16 ハンツマン・インターナショナル・エルエルシー ベンゾオキサジンベースのポリウレタン樹脂組成物
US11421080B2 (en) * 2018-12-20 2022-08-23 The Boeing Company Fluoropolymer adhesives and methods thereof
CN117247654B (zh) * 2023-11-17 2024-02-09 西南石油大学 一种水溶性苯并噁嗪和无机纤维复合气凝胶及其制备方法

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6207786B1 (en) * 1998-11-10 2001-03-27 Edison Polymer Innovation Corporation Ternary systems of benzoxazine, epoxy, and phenolic resins
US6743852B2 (en) * 2001-11-13 2004-06-01 Henkel Corporation Benzoxazines, thermosetting resins comprised thereof, and methods for use thereof
US20050070634A1 (en) * 2003-07-07 2005-03-31 Andreas Lutz Process for applying a streamable epoxy adhesive
WO2007064801A1 (fr) * 2005-12-02 2007-06-07 Henkel Corporation Compositions durcissables

Family Cites Families (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3433851C2 (de) 1984-09-14 1987-01-08 Gurit-Essex Ag, Freienbach Chemisch härtbare Harze aus 1-Oxa-3-aza-tetralin-Gruppen enthaltenden Verbindungen und cycloaliphatischen Epoxid-harzen, Verfahren zu deren Herstellung sowie Verwendung solcher Harze
EP0356379B1 (fr) 1988-07-18 1996-03-20 Gurit-Essex AG Résines durcissables en vue d'obtenir des matières plastiques difficilement inflammables et résistantes à haute température et leur procédé de préparation
US5443911A (en) 1990-05-21 1995-08-22 Gurit-Essex Ag Curable resins comprising halogenated epoxy resins and 1-oxa-3-aza tetraline compounds, method for preparing and use of resins
EP0493310A1 (fr) 1990-12-21 1992-07-01 Gurit-Essex AG Résines durcissables ayant des propriétés ignifuges à l'état durci et leur utilisation
US5543516A (en) 1994-05-18 1996-08-06 Edison Polymer Innovation Corporation Process for preparation of benzoxazine compounds in solventless systems
US7666938B2 (en) * 2004-12-03 2010-02-23 Henkel Corporation Nanoparticle silica filled benzoxazine compositions
JP2007106800A (ja) 2005-10-11 2007-04-26 Sekisui Chem Co Ltd 熱硬化性樹脂、及びそれを含む熱硬化性組成物、並びにそれから得られる成形体
JP2007146070A (ja) 2005-11-30 2007-06-14 Sekisui Chem Co Ltd 熱硬化性樹脂、その製造方法及び該樹脂を含む熱硬化性組成物、並びにそれから得られる成形体及び該成形体を含む電子機器
JP2007154018A (ja) 2005-12-05 2007-06-21 Sekisui Chem Co Ltd 熱硬化性樹脂、その製造方法及び該樹脂を含む熱硬化性組成物、並びにそれから得られる成形体及び該成形体を含む電子機器

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6207786B1 (en) * 1998-11-10 2001-03-27 Edison Polymer Innovation Corporation Ternary systems of benzoxazine, epoxy, and phenolic resins
US6743852B2 (en) * 2001-11-13 2004-06-01 Henkel Corporation Benzoxazines, thermosetting resins comprised thereof, and methods for use thereof
US20050070634A1 (en) * 2003-07-07 2005-03-31 Andreas Lutz Process for applying a streamable epoxy adhesive
WO2007064801A1 (fr) * 2005-12-02 2007-06-07 Henkel Corporation Compositions durcissables

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
RIMDUSIT, S. ET AL.: "Toughening of polybenzoxazine by alloying with urethane prepolymer and flexible epoxy: a comparative study", POLYM. ENG. SCI., 2005, pages 288 - 296, XP001227910 *

Also Published As

Publication number Publication date
CN101889048B (zh) 2012-09-05
BRPI0820012A2 (pt) 2015-05-19
CN101889048A (zh) 2010-11-17
WO2009075744A2 (fr) 2009-06-18
BRPI0820012B1 (pt) 2019-09-03
US8759443B2 (en) 2014-06-24
ES2556708T3 (es) 2016-01-19
CA2708081A1 (fr) 2009-06-18
EP2217650B1 (fr) 2015-10-21
CA2708081C (fr) 2016-06-14
EP2217650A4 (fr) 2012-05-02
EP2217650A2 (fr) 2010-08-18
US20100204385A1 (en) 2010-08-12

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