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WO2009060642A1 - Flue gas desulfurizer - Google Patents

Flue gas desulfurizer Download PDF

Info

Publication number
WO2009060642A1
WO2009060642A1 PCT/JP2008/062575 JP2008062575W WO2009060642A1 WO 2009060642 A1 WO2009060642 A1 WO 2009060642A1 JP 2008062575 W JP2008062575 W JP 2008062575W WO 2009060642 A1 WO2009060642 A1 WO 2009060642A1
Authority
WO
WIPO (PCT)
Prior art keywords
liquid
column
desulfurization
flue gas
liquid column
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/062575
Other languages
French (fr)
Japanese (ja)
Inventor
Keisuke Sonoda
Shozo Nagao
Yoshihiko Tsuchiyama
Tomoo Akiyama
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Heavy Industries Ltd
Original Assignee
Mitsubishi Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Heavy Industries Ltd filed Critical Mitsubishi Heavy Industries Ltd
Priority to IN6945DEN2014 priority Critical patent/IN2014DN06945A/en
Publication of WO2009060642A1 publication Critical patent/WO2009060642A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/14Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by absorption
    • B01D53/18Absorbing units; Liquid distributors therefor
    • B01D53/185Liquid distributors
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/48Sulfur compounds
    • B01D53/50Sulfur oxides
    • B01D53/501Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound
    • B01D53/504Sulfur oxides by treating the gases with a solution or a suspension of an alkali or earth-alkali or ammonium compound characterised by a specific device
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/77Liquid phase processes
    • B01D53/79Injecting reactants
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/40Alkaline earth metal or magnesium compounds
    • B01D2251/404Alkaline earth metal or magnesium compounds of calcium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/604Hydroxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/30Sulfur compounds
    • B01D2257/302Sulfur oxides

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Analytical Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Treating Waste Gases (AREA)
  • Gas Separation By Absorption (AREA)
  • Nozzles (AREA)

Abstract

A liquid-column flue gas desulfurizer capable of flexibly coping with the change of conditions such as desulfurization performance, field adjustment, and so on, by which the increase of cost and construction time can be minimized. In the liquid-column flue gas desulfurizer for performing desulfurization by bringing absorbing liquid which is jetted upward from a liquid column nozzle (20) and falls in a desulfurization tower and combustion exhaust gas which rises from the bottom of the desulfurization tower into gas-liquid contact with each other, an outlet chip (30) having a different jet flow rate or jet pattern of the absorbing liquid is removably attached to the tip of the liquid column nozzle (20). By attaching a liquid column dispersing mechanism to the tip of the liquid column nozzle, the dispersion of a liquid column can be accelerated and the area of the absorbing liquid brought into contact with the combustion exhaust gas can be increased. Consequently, the desulfurization efficiency can be improved and the size of the desulfurization tower can be reduced, which is very effective in reducing the installation space and cost of the device.
PCT/JP2008/062575 2007-11-09 2008-07-11 Flue gas desulfurizer Ceased WO2009060642A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
IN6945DEN2014 IN2014DN06945A (en) 2007-11-09 2008-07-11

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007292389A JP5254597B2 (en) 2007-11-09 2007-11-09 Flue gas desulfurization equipment
JP2007-292389 2007-11-09

Publications (1)

Publication Number Publication Date
WO2009060642A1 true WO2009060642A1 (en) 2009-05-14

Family

ID=40625547

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/062575 Ceased WO2009060642A1 (en) 2007-11-09 2008-07-11 Flue gas desulfurizer

Country Status (6)

Country Link
JP (1) JP5254597B2 (en)
IN (1) IN2014DN06945A (en)
MY (1) MY154532A (en)
SA (2) SA08290471B1 (en)
TW (2) TWI430832B (en)
WO (1) WO2009060642A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3006100A4 (en) * 2014-01-31 2016-06-08 Mitsubishi Heavy Ind Ltd GAS-LIQUID CONTACTOR AND CO2 RECOVERING APPARATUS EQUIPPED WITH SAME
WO2016089821A1 (en) * 2014-12-04 2016-06-09 Exxonmobil Research And Engineering Company Fluid injection nozzle for fluid bed reactors
CN107983545A (en) * 2018-01-04 2018-05-04 中国华电集团科学技术研究总院有限公司 A kind of anti-blocking throttle type nozzle for SCR denitration system ammonia-spraying grid

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR101793983B1 (en) * 2017-06-27 2017-12-01 한국발전기술(주) Equipment for automatically removing impurities of absorber in flue gas desulferization system and driving method thereof
JP2021065850A (en) * 2019-10-25 2021-04-30 株式会社徳重 Injection port formation member and sprayer using the same

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07241429A (en) * 1994-03-04 1995-09-19 Mitsubishi Heavy Ind Ltd Gas-liquid contacting device
JPH09117635A (en) * 1995-10-26 1997-05-06 Ishikawajima Harima Heavy Ind Co Ltd Circulation spray pipe structure in the tower

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5953828U (en) * 1982-09-28 1984-04-09 三菱重工業株式会社 Gas-liquid contact device

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH07241429A (en) * 1994-03-04 1995-09-19 Mitsubishi Heavy Ind Ltd Gas-liquid contacting device
JPH09117635A (en) * 1995-10-26 1997-05-06 Ishikawajima Harima Heavy Ind Co Ltd Circulation spray pipe structure in the tower

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3006100A4 (en) * 2014-01-31 2016-06-08 Mitsubishi Heavy Ind Ltd GAS-LIQUID CONTACTOR AND CO2 RECOVERING APPARATUS EQUIPPED WITH SAME
US10065149B2 (en) 2014-01-31 2018-09-04 Mitsubishi Heavy Industries Engineering Ltd. Gas-liquid contactor and CO2-recovering apparatus provided therewith
WO2016089821A1 (en) * 2014-12-04 2016-06-09 Exxonmobil Research And Engineering Company Fluid injection nozzle for fluid bed reactors
CN106999889A (en) * 2014-12-04 2017-08-01 埃克森美孚研究工程公司 Fluid injection nozzle for fluidized-bed reactor
US9889420B2 (en) 2014-12-04 2018-02-13 Exxonmobil Research And Engineering Company Fluid injection nozzle for fluid bed reactors
RU2693143C2 (en) * 2014-12-04 2019-07-01 ЭкссонМобил Рисерч энд Энджиниринг Компани Fluid injector nozzle for fluid bed reactor
CN107983545A (en) * 2018-01-04 2018-05-04 中国华电集团科学技术研究总院有限公司 A kind of anti-blocking throttle type nozzle for SCR denitration system ammonia-spraying grid

Also Published As

Publication number Publication date
IN2014DN06945A (en) 2015-04-10
TWI347213B (en) 2011-08-21
JP5254597B2 (en) 2013-08-07
MY154532A (en) 2015-06-30
TW201125633A (en) 2011-08-01
SA08290471B1 (en) 2011-10-03
TWI430832B (en) 2014-03-21
TW200920469A (en) 2009-05-16
JP2009113016A (en) 2009-05-28
SA111320375B1 (en) 2014-11-30

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