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WO2009057463A1 - 気相接触酸化反応方法 - Google Patents

気相接触酸化反応方法 Download PDF

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Publication number
WO2009057463A1
WO2009057463A1 PCT/JP2008/068845 JP2008068845W WO2009057463A1 WO 2009057463 A1 WO2009057463 A1 WO 2009057463A1 JP 2008068845 W JP2008068845 W JP 2008068845W WO 2009057463 A1 WO2009057463 A1 WO 2009057463A1
Authority
WO
WIPO (PCT)
Prior art keywords
reaction
catalyst
layer
oxidation reaction
catalytic oxidation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/068845
Other languages
English (en)
French (fr)
Inventor
Toshitake Kojima
Yoshimasa Seo
Hiroyuki Onoue
Hideki Sugi
Kazuo Shiraishi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Kayaku Co Ltd
Original Assignee
Nippon Kayaku Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nippon Kayaku Co Ltd filed Critical Nippon Kayaku Co Ltd
Priority to CN200880113893A priority Critical patent/CN101842341A/zh
Priority to JP2009539007A priority patent/JPWO2009057463A1/ja
Publication of WO2009057463A1 publication Critical patent/WO2009057463A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/888—Tungsten
    • B01J23/8885—Tungsten containing also molybdenum
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/002—Mixed oxides other than spinels, e.g. perovskite
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
    • B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/85—Chromium, molybdenum or tungsten
    • B01J23/88—Molybdenum
    • B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
    • B01J23/8876—Arsenic, antimony or bismuth
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0219—Coating the coating containing organic compounds
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B01J37/0223—Coating of particles by rotation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J8/00—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
    • B01J8/02—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds
    • B01J8/06—Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes with stationary particles, e.g. in fixed beds in tube reactors; the solid particles being arranged in tubes
    • B01J8/067—Heating or cooling the reactor
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
    • C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
    • C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
    • C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Devices And Processes Conducted In The Presence Of Fluids And Solid Particles (AREA)

Abstract

【課題】固定床管型反応器を用いる気相接触酸化反応方法において、ホットスポットを抑制し、かつ目的反応生成物を高収率で製造する方法を提供する。 【解決手段】触媒を充填した管型反応管を原料ガス入口側から出口側に向かって、部分反応層と全反応層に分け、該部分反応層に、原料ガスの一部が触媒と接触しない無反応帯と原料ガスの残部が触媒と接触する触媒層を設け、該全反応層において、該無反応帯を通過した原料ガスと該部分反応層の触媒層を通過したガスを酸化反応させることを特徴とする気相接触酸化反応方法。
PCT/JP2008/068845 2007-11-02 2008-10-17 気相接触酸化反応方法 Ceased WO2009057463A1 (ja)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN200880113893A CN101842341A (zh) 2007-11-02 2008-10-17 气相催化氧化反应方法
JP2009539007A JPWO2009057463A1 (ja) 2007-11-02 2008-10-17 気相接触酸化反応方法

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-286099 2007-11-02
JP2007286099 2007-11-02

Publications (1)

Publication Number Publication Date
WO2009057463A1 true WO2009057463A1 (ja) 2009-05-07

Family

ID=40590855

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/068845 Ceased WO2009057463A1 (ja) 2007-11-02 2008-10-17 気相接触酸化反応方法

Country Status (3)

Country Link
JP (1) JPWO2009057463A1 (ja)
CN (1) CN101842341A (ja)
WO (1) WO2009057463A1 (ja)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012105304A1 (ja) * 2011-02-02 2012-08-09 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
WO2014181839A1 (ja) * 2013-05-09 2014-11-13 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸製造用触媒、その製造方法及び不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
WO2015068640A1 (ja) 2013-11-07 2015-05-14 株式会社日本触媒 反応管用充填物、反応管、およびそれを用いた反応方法
JP2018111720A (ja) * 2013-10-10 2018-07-19 日本化薬株式会社 不飽和カルボン酸の製造方法、及び担持触媒

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP3321247B1 (en) * 2015-07-10 2019-11-20 Nippon Kayaku Kabushiki Kaisha Method for producing unsaturated aldehyde and/or unsaturated carboxylic acid

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04217932A (ja) * 1990-04-03 1992-08-07 Nippon Shokubai Co Ltd 不飽和アルデヒドおよび不飽和酸の製造方法
JPH1180052A (ja) * 1997-09-04 1999-03-23 Toagosei Co Ltd 気相接触酸化反応方法及び反応器

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04217932A (ja) * 1990-04-03 1992-08-07 Nippon Shokubai Co Ltd 不飽和アルデヒドおよび不飽和酸の製造方法
JPH1180052A (ja) * 1997-09-04 1999-03-23 Toagosei Co Ltd 気相接触酸化反応方法及び反応器

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2012105304A1 (ja) * 2011-02-02 2012-08-09 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
US8969618B2 (en) 2011-02-02 2015-03-03 Nipponkayaku Kabushiki Kaisha Process for producing unsaturated aldehyde and/or unsaturated carboxylic acid
WO2014181839A1 (ja) * 2013-05-09 2014-11-13 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸製造用触媒、その製造方法及び不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
JP5951121B2 (ja) * 2013-05-09 2016-07-13 日本化薬株式会社 不飽和アルデヒドおよび／または不飽和カルボン酸製造用触媒、その製造方法及び不飽和アルデヒドおよび／または不飽和カルボン酸の製造方法
US9656248B2 (en) 2013-05-09 2017-05-23 Nippon Kayaku Kabushiki Kaisha Catalyst for producing unsaturated aldehyde and/or unsaturated carboxylic acid, method for producing same, and method for producing unsaturated aldehyde and/or unsaturated carboxylic acid
JP2018111720A (ja) * 2013-10-10 2018-07-19 日本化薬株式会社 不飽和カルボン酸の製造方法、及び担持触媒
WO2015068640A1 (ja) 2013-11-07 2015-05-14 株式会社日本触媒 反応管用充填物、反応管、およびそれを用いた反応方法
US10099189B2 (en) 2013-11-07 2018-10-16 Nippon Shokubai Co., Ltd. Packing for reaction tube, reaction tube, and reaction method using same

Also Published As

Publication number Publication date
CN101842341A (zh) 2010-09-22
JPWO2009057463A1 (ja) 2011-03-10

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