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WO2008138534A3 - Impact strength modified polycarbonate compositions - Google Patents

Impact strength modified polycarbonate compositions Download PDF

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Publication number
WO2008138534A3
WO2008138534A3 PCT/EP2008/003680 EP2008003680W WO2008138534A3 WO 2008138534 A3 WO2008138534 A3 WO 2008138534A3 EP 2008003680 W EP2008003680 W EP 2008003680W WO 2008138534 A3 WO2008138534 A3 WO 2008138534A3
Authority
WO
WIPO (PCT)
Prior art keywords
weight percent
compositions
graft
sum
polycarbonate compositions
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2008/003680
Other languages
German (de)
French (fr)
Other versions
WO2008138534A2 (en
Inventor
Andreas Seidel
Evgueni Avtomonov
Eckhard Wenz
Thomas Eckel
Herbert Eichenauer
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Covestro Deutschland AG
Original Assignee
Bayer MaterialScience AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Bayer MaterialScience AG filed Critical Bayer MaterialScience AG
Priority to BRPI0811878-7A2A priority Critical patent/BRPI0811878A2/en
Priority to JP2010507828A priority patent/JP2010526922A/en
Priority to CA002687362A priority patent/CA2687362A1/en
Priority to EP08758407A priority patent/EP2148902A2/en
Priority to CN200880016160A priority patent/CN101679736A/en
Priority to MX2009011440A priority patent/MX2009011440A/en
Publication of WO2008138534A2 publication Critical patent/WO2008138534A2/en
Publication of WO2008138534A3 publication Critical patent/WO2008138534A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C08F2/24—Emulsion polymerisation with the aid of emulsifying agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F253/00—Macromolecular compounds obtained by polymerising monomers on to natural rubbers or derivatives thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F279/00—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00
    • C08F279/02—Macromolecular compounds obtained by polymerising monomers on to polymers of monomers having two or more carbon-to-carbon double bonds as defined in group C08F36/00 on to polymers of conjugated dienes
    • C08F279/04—Vinyl aromatic monomers and nitriles as the only monomers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/003—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
    • C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C08L67/03—Polyesters derived from dicarboxylic acids and dihydroxy compounds the dicarboxylic acids and dihydroxy compounds having the carboxyl- and the hydroxy groups directly linked to aromatic rings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C08L69/005—Polyester-carbonates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/0008—Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005—Stabilisers against oxidation, heat, light, ozone
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/101—Esters; Ether-esters of monocarboxylic acids
    • C08K5/103—Esters; Ether-esters of monocarboxylic acids with polyalcohols
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/04—Oxygen-containing compounds
    • C08K5/10—Esters; Ether-esters
    • C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/36—Sulfur-, selenium-, or tellurium-containing compounds
    • C08K5/41—Compounds containing sulfur bound to oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/49—Phosphorus-containing compounds
    • C08K5/51—Phosphorus bound to oxygen
    • C08K5/52—Phosphorus bound to oxygen only
    • C08K5/521—Esters of phosphoric acids, e.g. of H3PO4
    • C08K5/523—Esters of phosphoric acids, e.g. of H3PO4 with hydroxyaryl compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention relates to compositions comprising: A) 10 - 99 weight percent aromatic polycarbonate and/or aromatic polyester carbonate, B) 1 - 35 weight percent rubberized graft copolymer of B.1 5 to 95 of at least one vinyl monomer and B.2 95 to 5 of one or more graft foundations having a glass transition temperature of < 10° C, C) 0 - 40 weight percent vinyl(co)polymer and/or polyalkylene terephthalate, excepting a copolymer made of α-methyl-styrene and acrylnitrile, D) 0 - 50 weight percent phosphorous flame retardant, relative to the sum of components A+B+C, E) 0 - 50 weight percent of additives, relative to the sum of components A+B+C, characterized in that component B can be obtained by reacting component B.1 and the graft foundation B.2 by means of emulsion polymerization, wherein an emulsifier according to formula (I) is used, said compositions being characterized by a high resistance to hydrolysis. The invention further relates to the use of polycarbonate compositions for producing molds and molded parts.
PCT/EP2008/003680 2007-05-16 2008-05-08 Impact strength modified polycarbonate compositions Ceased WO2008138534A2 (en)

Priority Applications (6)

Application Number Priority Date Filing Date Title
BRPI0811878-7A2A BRPI0811878A2 (en) 2007-05-16 2008-05-08 POLYCARBONATE COMPOSITIONS MODIFIED FOR IMPACT
JP2010507828A JP2010526922A (en) 2007-05-16 2008-05-08 Impact-resistant polycarbonate composition
CA002687362A CA2687362A1 (en) 2007-05-16 2008-05-08 Impact strength modified polycarbonate compositions
EP08758407A EP2148902A2 (en) 2007-05-16 2008-05-08 Impact strength modified polycarbonate compositions
CN200880016160A CN101679736A (en) 2007-05-16 2008-05-08 Impact toughness modified polycarbonate composition
MX2009011440A MX2009011440A (en) 2007-05-16 2008-05-08 Impact strength modified polycarbonate compositions.

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
DE102007023097.6 2007-05-16
DE102007023097 2007-05-16
DE102008015124.6 2008-03-20
DE102008015124A DE102008015124A1 (en) 2007-05-16 2008-03-20 Impact modified polycarbonate compositions

Publications (2)

Publication Number Publication Date
WO2008138534A2 WO2008138534A2 (en) 2008-11-20
WO2008138534A3 true WO2008138534A3 (en) 2009-05-07

Family

ID=39868965

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/EP2008/003680 Ceased WO2008138534A2 (en) 2007-05-16 2008-05-08 Impact strength modified polycarbonate compositions

Country Status (10)

Country Link
EP (1) EP2148902A2 (en)
JP (1) JP2010526922A (en)
KR (1) KR20100016530A (en)
CN (1) CN101679736A (en)
BR (1) BRPI0811878A2 (en)
CA (1) CA2687362A1 (en)
DE (1) DE102008015124A1 (en)
MX (1) MX2009011440A (en)
RU (1) RU2009146338A (en)
WO (1) WO2008138534A2 (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009118114A1 (en) * 2008-03-22 2009-10-01 Bayer Materialscience Ag Impact-resistant modified polycarbonate compositions with a good combination of raw talc, hydrolysis- and melt stability
EP2657259A1 (en) * 2012-04-23 2013-10-30 Bayer MaterialScience AG ABS compounds with improved surface after hot-wet storage
CN107868430A (en) * 2017-12-08 2018-04-03 福建麦凯智造婴童文化股份有限公司 A kind of engineering plastics applied to toy for children and preparation method thereof
CN113563710B (en) * 2021-09-22 2021-12-21 北京能之光科技有限公司 Method for preparing polycarbonate with reduced internal stress
CN115678237B (en) * 2022-10-21 2024-07-12 金发科技股份有限公司 Slow-combustion polycarbonate composite material and preparation method and application thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4732935A (en) * 1983-06-14 1988-03-22 Kureha Kagaku Kogyo Kabushiki Kaisha Thermoplastic resin composition
EP0390081A2 (en) * 1989-03-28 1990-10-03 Mitsubishi Rayon Co., Ltd. Thermoplastic resin composition

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DE1495626B1 (en) 1960-03-30 1971-06-09 Bayer Ag METHOD OF MANUFACTURING POLYESTERS
US3419634A (en) 1966-01-03 1968-12-31 Gen Electric Organopolysiloxane polycarbonate block copolymers
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DE2232877B2 (en) 1972-07-05 1980-04-10 Werner & Pfleiderer, 7000 Stuttgart Process for the production of polyesters
JPS5039599B2 (en) 1973-03-30 1975-12-18
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JPS5292295A (en) 1976-01-29 1977-08-03 Sumitomo Chem Co Ltd Preparation of aromatic polyester
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Patent Citations (2)

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Publication number Priority date Publication date Assignee Title
US4732935A (en) * 1983-06-14 1988-03-22 Kureha Kagaku Kogyo Kabushiki Kaisha Thermoplastic resin composition
EP0390081A2 (en) * 1989-03-28 1990-10-03 Mitsubishi Rayon Co., Ltd. Thermoplastic resin composition

Also Published As

Publication number Publication date
CA2687362A1 (en) 2008-11-20
JP2010526922A (en) 2010-08-05
DE102008015124A1 (en) 2008-11-20
WO2008138534A2 (en) 2008-11-20
EP2148902A2 (en) 2010-02-03
CN101679736A (en) 2010-03-24
RU2009146338A (en) 2011-06-27
BRPI0811878A2 (en) 2014-11-18
MX2009011440A (en) 2009-11-10
KR20100016530A (en) 2010-02-12

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