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WO2008149950A1 - Ｏｈ型陰イオン交換性炭化水素系エラストマー、その用途およびその製造方法 - Google Patents

Ｏｈ型陰イオン交換性炭化水素系エラストマー、その用途およびその製造方法 Download PDF

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Publication number
WO2008149950A1
WO2008149950A1 PCT/JP2008/060392 JP2008060392W WO2008149950A1 WO 2008149950 A1 WO2008149950 A1 WO 2008149950A1 JP 2008060392 W JP2008060392 W JP 2008060392W WO 2008149950 A1 WO2008149950 A1 WO 2008149950A1
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WIPO (PCT)
Prior art keywords
producing
hydrocarbon elastomer
elastomer
anion exchange
ionic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/060392
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English (en)
French (fr)
Inventor
Hitoshi Matsuoka
Kenji Fukuta
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Tokuyama Corp
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Tokuyama Corp
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Filing date
Publication date
Application filed by Tokuyama Corp filed Critical Tokuyama Corp
Priority to JP2009517899A priority Critical patent/JP4999123B2/ja
Priority to AT08765205T priority patent/ATE550359T1/de
Priority to US12/663,148 priority patent/US8242042B2/en
Priority to EP08765205A priority patent/EP2157105B1/en
Publication of WO2008149950A1 publication Critical patent/WO2008149950A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1067—Polymeric electrolyte materials characterised by their physical properties, e.g. porosity, ionic conductivity or thickness
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/04—Reduction, e.g. hydrogenation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/18—Introducing halogen atoms or halogen-containing groups
    • C08F8/24—Haloalkylation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
    • C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/44—Preparation of metal salts or ammonium salts
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/86—Inert electrodes with catalytic activity, e.g. for fuel cells
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1016—Fuel cells with solid electrolytes characterised by the electrolyte material
    • H01M8/1018—Polymeric electrolyte materials
    • H01M8/1069—Polymeric electrolyte materials characterised by the manufacturing processes
    • H01M8/1072—Polymeric electrolyte materials characterised by the manufacturing processes by chemical reactions, e.g. in situ polymerisation or in situ crosslinking
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0065—Solid electrolytes
    • H01M2300/0082—Organic polymers
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00—Fuel cells; Manufacture thereof
    • H01M8/10—Fuel cells with solid electrolytes
    • H01M8/1009—Fuel cells with solid electrolytes with one of the reactants being liquid, solid or liquid-charged
    • H01M8/1011—Direct alcohol fuel cells [DAFC], e.g. direct methanol fuel cells [DMFC]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/50—Fuel cells
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Engineering & Computer Science (AREA)
  • Electrochemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Sustainable Development (AREA)
  • Sustainable Energy (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Fuel Cell (AREA)
  • Inert Electrodes (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Graft Or Block Polymers (AREA)
  • Conductive Materials (AREA)

Abstract

　本発明は、固体高分子型燃料電池の触媒電極層製造時に用いられるＯＨ型陰イオン交換性炭化水素系エラストマーについて、安定性、耐久性および柔軟性のバランスを考慮し、最適の構成および製法を提供することを目的としている。また、本発明は、ＯＨ型陰イオン交換性炭化水素系エラストマーを含むイオン伝導性付与剤において、濃度が高い場合であっても、該エラストマーが均一に溶解ないしは分散し、適度な粘度を有するイオン伝導性付与剤を提供することを目的としている。 　本発明の陰イオン交換性炭化水素系エラストマーは、ヨウ素価が３～２５であり、ＯＨ－、ＣＯ３ ２－および／またはＨＣＯ３ －が対イオンである陰イオン交換基を分子内に有し、水に難溶であることを特徴としている。かかる炭化水素系エラストマーは、有機溶媒と混合して、触媒電極層形成用イオン伝導性付与剤として好ましく用いられる。
PCT/JP2008/060392 2007-06-05 2008-06-05 Ｏｈ型陰イオン交換性炭化水素系エラストマー、その用途およびその製造方法 Ceased WO2008149950A1 (ja)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2009517899A JP4999123B2 (ja) 2007-06-05 2008-06-05 Ｏｈ型陰イオン交換性炭化水素系エラストマー、その用途およびその製造方法
AT08765205T ATE550359T1 (de) 2007-06-05 2008-06-05 Ionenleitfähigkeitsvermittler umfassend kohlenwasserstoffelastomer, das zum austausch von anionen vom oh-typ befähigt ist, und herstellungsverfahren dafür
US12/663,148 US8242042B2 (en) 2007-06-05 2008-06-05 OH-type anion-exchange hydrocarbon-based elastomer, use and production method thereof
EP08765205A EP2157105B1 (en) 2007-06-05 2008-06-05 Ion-conductivity imparting agent comprising hydrocarbon elastomer capable of oh type anion exchange, use thereof, and process for producing the same

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007-148850 2007-06-05
JP2007148850 2007-06-05

Publications (1)

Publication Number Publication Date
WO2008149950A1 true WO2008149950A1 (ja) 2008-12-11

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ID=40093760

Family Applications (1)

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PCT/JP2008/060392 Ceased WO2008149950A1 (ja) 2007-06-05 2008-06-05 Ｏｈ型陰イオン交換性炭化水素系エラストマー、その用途およびその製造方法

Country Status (6)

Country Link
US (1) US8242042B2 (ja)
EP (1) EP2157105B1 (ja)
JP (1) JP4999123B2 (ja)
KR (1) KR101475098B1 (ja)
AT (1) ATE550359T1 (ja)
WO (1) WO2008149950A1 (ja)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009148051A1 (ja) * 2008-06-05 2009-12-10 株式会社トクヤマ 陰イオン交換膜型燃料電池における触媒電極層用イオン伝導性付与剤の製造方法
WO2014013879A1 (ja) * 2012-07-20 2014-01-23 株式会社トクヤマ 陰イオン交換膜型燃料電池用の触媒層及び膜－電極接合体並びにこれらを用いる陰イオン交換膜型燃料電池及びその運転方法

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP2629304A4 (en) * 2010-10-13 2015-11-11 Sumitomo Riko Co Ltd FLEXIBLE CONDUCTOR MATERIAL AND TRANSDUCER, SOFT PRINTED CIRCUIT BOARD, AND ELECTROMAGNETIC PROTECTION USING THE SOFT CONDUCTOR MATERIAL
CN104081569A (zh) * 2012-02-29 2014-10-01 株式会社德山 催化电极层及其制造方法
JP6336483B2 (ja) * 2013-01-14 2018-06-06 クレイトン・ポリマーズ・ユー・エス・エル・エル・シー アニオン交換ブロックコポリマー、これらの製造およびこれらの使用
CZ201456A3 (cs) 2014-01-24 2015-05-13 Ústav makromolekulární chemie AV ČR, v.v.i. Způsob přípravy rozpustného blokového kopolymeru styrenu a olefinů a jeho použití
US20190060842A1 (en) 2017-08-22 2019-02-28 Daniel M. Knauss Functionalized poly(diallylpiperidinium) and its copolymers for use in ion conducting applications
US10836874B2 (en) * 2017-10-02 2020-11-17 Colorado School Of Mines High performance cross-linked triblock cationic functionalized polymer for electrochemical applications, methods of making and methods of using
CZ2022238A3 (cs) 2022-06-03 2023-10-04 Ústav makromolekulární chemie AV ČR, v. v. i. Anion-výměnný materiál na bázi blokového polymeru styrenu a olefinů

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08302037A (ja) * 1995-05-09 1996-11-19 Tokuyama Corp イオン交換膜の製造方法
JPH11135137A (ja) 1997-10-31 1999-05-21 Asahi Glass Co Ltd 固体高分子電解質型メタノール燃料電池
JPH11273695A (ja) 1998-03-19 1999-10-08 Asahi Glass Co Ltd 固体高分子電解質型メタノール燃料電池
JP2000331693A (ja) 1999-05-19 2000-11-30 Asahi Glass Co Ltd 固体高分子型燃料電池
JP2002367626A (ja) 2001-06-12 2002-12-20 Tokuyama Corp ガス拡散電極用イオン伝導性付与剤
WO2006068279A1 (ja) * 2004-12-20 2006-06-29 Kuraray Co., Ltd. イオン伝導性バインダー、膜−電極接合体及び燃料電池
JP2007042573A (ja) 2005-06-29 2007-02-15 Kuraray Co Ltd 固体高分子型燃料電池用高分子電解質膜、膜−電極接合体及び燃料電池

Family Cites Families (4)

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US6294257B1 (en) * 1997-03-11 2001-09-25 Zeon Corporation Conductive elastomer film, method for production thereof, and conductive elastomer composition
CA2353378C (en) * 2000-07-24 2008-09-23 Asahi Glass Company, Limited Anion exchange membrane, process for its production and solution treating apparatus
JP2006202737A (ja) 2004-12-20 2006-08-03 Kuraray Co Ltd イオン伝導性バインダー、膜−電極接合体及び燃料電池
WO2006070929A1 (ja) 2004-12-27 2006-07-06 Kuraray Co., Ltd. 固体高分子型燃料電池用高分子電解質膜、膜－電極接合体及び燃料電池

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH08302037A (ja) * 1995-05-09 1996-11-19 Tokuyama Corp イオン交換膜の製造方法
JPH11135137A (ja) 1997-10-31 1999-05-21 Asahi Glass Co Ltd 固体高分子電解質型メタノール燃料電池
JPH11273695A (ja) 1998-03-19 1999-10-08 Asahi Glass Co Ltd 固体高分子電解質型メタノール燃料電池
JP2000331693A (ja) 1999-05-19 2000-11-30 Asahi Glass Co Ltd 固体高分子型燃料電池
JP2002367626A (ja) 2001-06-12 2002-12-20 Tokuyama Corp ガス拡散電極用イオン伝導性付与剤
WO2006068279A1 (ja) * 2004-12-20 2006-06-29 Kuraray Co., Ltd. イオン伝導性バインダー、膜−電極接合体及び燃料電池
JP2007042573A (ja) 2005-06-29 2007-02-15 Kuraray Co Ltd 固体高分子型燃料電池用高分子電解質膜、膜−電極接合体及び燃料電池

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2009148051A1 (ja) * 2008-06-05 2009-12-10 株式会社トクヤマ 陰イオン交換膜型燃料電池における触媒電極層用イオン伝導性付与剤の製造方法
JP5386486B2 (ja) * 2008-06-05 2014-01-15 株式会社トクヤマ 陰イオン交換膜型燃料電池における触媒電極層用イオン伝導性付与剤の製造方法
WO2014013879A1 (ja) * 2012-07-20 2014-01-23 株式会社トクヤマ 陰イオン交換膜型燃料電池用の触媒層及び膜－電極接合体並びにこれらを用いる陰イオン交換膜型燃料電池及びその運転方法
JP2014022249A (ja) * 2012-07-20 2014-02-03 Tokuyama Corp イオン伝導性付与剤並びにカソード触媒層並びに該触媒層を用いて形成する膜−電極接合体並びに陰イオン交換膜型燃料電池及びその運転方法

Also Published As

Publication number Publication date
EP2157105B1 (en) 2012-03-21
KR20100018527A (ko) 2010-02-17
JPWO2008149950A1 (ja) 2010-08-26
EP2157105A1 (en) 2010-02-24
JP4999123B2 (ja) 2012-08-15
KR101475098B1 (ko) 2014-12-22
ATE550359T1 (de) 2012-04-15
US8242042B2 (en) 2012-08-14
EP2157105A4 (en) 2010-09-29
US20100222208A1 (en) 2010-09-02

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