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WO2008143322A1 - Cellulose derivative, cellulose derivative-polylactic acid graft copolymer and method for producing the same, and polylactic acid resin composition - Google Patents

Cellulose derivative, cellulose derivative-polylactic acid graft copolymer and method for producing the same, and polylactic acid resin composition Download PDF

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Publication number
WO2008143322A1
WO2008143322A1 PCT/JP2008/059469 JP2008059469W WO2008143322A1 WO 2008143322 A1 WO2008143322 A1 WO 2008143322A1 JP 2008059469 W JP2008059469 W JP 2008059469W WO 2008143322 A1 WO2008143322 A1 WO 2008143322A1
Authority
WO
WIPO (PCT)
Prior art keywords
cellulose derivative
polylactic acid
graft copolymer
resin composition
cellulose
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2008/059469
Other languages
French (fr)
Japanese (ja)
Inventor
Kenji Okada
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Okayama Prefecture Ind Promotion Foundation
Original Assignee
Okayama Prefecture Ind Promotion Foundation
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Okayama Prefecture Ind Promotion Foundation filed Critical Okayama Prefecture Ind Promotion Foundation
Priority to JP2009515274A priority Critical patent/JPWO2008143322A1/en
Publication of WO2008143322A1 publication Critical patent/WO2008143322A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66Polyesters containing oxygen in the form of ether groups
    • C08G63/664Polyesters containing oxygen in the form of ether groups derived from hydroxy carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08BPOLYSACCHARIDES; DERIVATIVES THEREOF
    • C08B15/00Preparation of other cellulose derivatives or modified cellulose, e.g. complexes
    • C08B15/05Derivatives containing elements other than carbon, hydrogen, oxygen, halogens or sulfur
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L1/00Compositions of cellulose, modified cellulose or cellulose derivatives
    • C08L1/08Cellulose derivatives
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/06Biodegradable

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Biochemistry (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Biological Depolymerization Polymers (AREA)
  • Polysaccharides And Polysaccharide Derivatives (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

Disclosed is a melt-moldable biodegradable resin material which is sufficiently satisfactory in thermal characteristics and mechanical characteristics after molding (as a molded article). Specifically disclosed is a cellulose derivative characterized by having an average polymerization degree of not less than 500. This cellulose derivative is preferably a cellulose silyl ether. Also specifically disclosed is a cellulose derivative-polylactic acid graft copolymer, wherein the main chain is composed of a cellulose derivative having an average polymerization degree of not less than 500 and a graft chain is composed of a polylactic acid. In this graft copolymer, the cellulose derivative of the main chain is preferably composed of a cellulose silyl ether. Further specifically disclosed is a polylactic acid resin composition obtained by blending 1-50 parts by weight of the graft copolymer in 100 parts by weight of a polylactic acid.
PCT/JP2008/059469 2007-05-23 2008-05-22 Cellulose derivative, cellulose derivative-polylactic acid graft copolymer and method for producing the same, and polylactic acid resin composition Ceased WO2008143322A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2009515274A JPWO2008143322A1 (en) 2007-05-23 2008-05-22 Cellulose derivative, cellulose derivative-polylactic acid graft copolymer, method for producing the same, and polylactic acid resin composition

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2007137203 2007-05-23
JP2007-137203 2007-05-23

Publications (1)

Publication Number Publication Date
WO2008143322A1 true WO2008143322A1 (en) 2008-11-27

Family

ID=40032015

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2008/059469 Ceased WO2008143322A1 (en) 2007-05-23 2008-05-22 Cellulose derivative, cellulose derivative-polylactic acid graft copolymer and method for producing the same, and polylactic acid resin composition

Country Status (2)

Country Link
JP (1) JPWO2008143322A1 (en)
WO (1) WO2008143322A1 (en)

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012073089A (en) * 2010-09-28 2012-04-12 Gunze Ltd Method for measuring degree of polymerization of cellulose
WO2017061548A1 (en) * 2015-10-06 2017-04-13 株式会社カネカ Polymer material, film, circular polarizing plate, image display apparatus, and manufacturing method for film
JP2018172580A (en) * 2017-03-31 2018-11-08 株式会社カネカ Method for producing cellulose derivative
JP2018177892A (en) * 2017-04-06 2018-11-15 株式会社カネカ Method for producing cellulose derivative
WO2018207848A1 (en) * 2017-05-12 2018-11-15 地方独立行政法人大阪産業技術研究所 Poly(lactic acid)-grafted cellulose nanofiber and production method therefor
CN109456487A (en) * 2018-10-16 2019-03-12 湖北省冠成生物降解塑料制品有限公司 A kind of preparation method and application of cellulose derivative grafted polylactic acid
CN112280104A (en) * 2020-10-30 2021-01-29 界首市天路包装材料有限公司 Processing technology of environmentally friendly degradable packaging shell
CN114479139A (en) * 2022-01-14 2022-05-13 江西冠德新材科技股份有限公司 Fiber-based degradable film and preparation method thereof
JP2023012765A (en) * 2021-07-14 2023-01-26 国立大学法人九州工業大学 Cellulose ester composition
WO2023145958A1 (en) * 2022-01-31 2023-08-03 冨士色素株式会社 Thermoplastic composition
EP4223836A4 (en) * 2020-09-30 2024-10-09 Daio Paper Corporation POLYLACTIC ACID COMPOSITE RESIN
EP4223835A4 (en) * 2020-09-30 2024-10-09 Daio Paper Corporation CELLULOSE COMPOSITE RESIN

Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63221101A (en) * 1987-03-09 1988-09-14 Natoko Paint Kk Modified cellulose derivative
JPH0616833A (en) * 1992-03-25 1994-01-25 Basf Ag Production of recycled polyglucan thin film
JPH06182934A (en) * 1992-08-19 1994-07-05 Hoechst Ag Laminar element and its application
JPH08283302A (en) * 1995-04-11 1996-10-29 Shin Etsu Chem Co Ltd Siloxane-containing cellulose derivative and method for producing the same
JPH11124468A (en) * 1997-10-21 1999-05-11 Daicel Chem Ind Ltd Regenerated cellulose formed product having selective reflecting property and its production
JP2000319401A (en) * 1999-05-11 2000-11-21 Daicel Chem Ind Ltd Method for decolorizing grafted cellulose derivative
JP2001019702A (en) * 1999-07-05 2001-01-23 Daicel Chem Ind Ltd Method for producing cyclic ester-modified cellulose derivative
JP2001278901A (en) * 2000-02-15 2001-10-10 Clariant Gmbh Hydrophobized and modified cellulose ethers, their production and use
JP2001521072A (en) * 1997-10-27 2001-11-06 ロディア アセトウ Method for producing regenerated cellulose fiber or yarn
JP2004359840A (en) * 2003-04-10 2004-12-24 Toray Ind Inc Resin composition, its molded product and disperse aid
WO2005108471A1 (en) * 2004-05-05 2005-11-17 Firmenich Sa Biodegradable grafted copolymers
WO2006048946A1 (en) * 2004-11-08 2006-05-11 Agri Future Joetsu Co., Ltd. Biodegradable graft polymer and process for producing the same
JP2007254707A (en) * 2006-02-24 2007-10-04 Daicel Chem Ind Ltd Optically modified glucan derivative and optically molded product
JP2007254708A (en) * 2006-02-24 2007-10-04 Daicel Chem Ind Ltd Modified cellulose acylate and molded article for optical use
WO2007129722A1 (en) * 2006-05-09 2007-11-15 Daicel Chemical Industries, Ltd. Hydroxy acid-modified glucan derivative and molded body thereof

Patent Citations (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS63221101A (en) * 1987-03-09 1988-09-14 Natoko Paint Kk Modified cellulose derivative
JPH0616833A (en) * 1992-03-25 1994-01-25 Basf Ag Production of recycled polyglucan thin film
JPH06182934A (en) * 1992-08-19 1994-07-05 Hoechst Ag Laminar element and its application
JPH08283302A (en) * 1995-04-11 1996-10-29 Shin Etsu Chem Co Ltd Siloxane-containing cellulose derivative and method for producing the same
JPH11124468A (en) * 1997-10-21 1999-05-11 Daicel Chem Ind Ltd Regenerated cellulose formed product having selective reflecting property and its production
JP2001521072A (en) * 1997-10-27 2001-11-06 ロディア アセトウ Method for producing regenerated cellulose fiber or yarn
JP2000319401A (en) * 1999-05-11 2000-11-21 Daicel Chem Ind Ltd Method for decolorizing grafted cellulose derivative
JP2001019702A (en) * 1999-07-05 2001-01-23 Daicel Chem Ind Ltd Method for producing cyclic ester-modified cellulose derivative
JP2001278901A (en) * 2000-02-15 2001-10-10 Clariant Gmbh Hydrophobized and modified cellulose ethers, their production and use
JP2004359840A (en) * 2003-04-10 2004-12-24 Toray Ind Inc Resin composition, its molded product and disperse aid
WO2005108471A1 (en) * 2004-05-05 2005-11-17 Firmenich Sa Biodegradable grafted copolymers
WO2006048946A1 (en) * 2004-11-08 2006-05-11 Agri Future Joetsu Co., Ltd. Biodegradable graft polymer and process for producing the same
JP2007254707A (en) * 2006-02-24 2007-10-04 Daicel Chem Ind Ltd Optically modified glucan derivative and optically molded product
JP2007254708A (en) * 2006-02-24 2007-10-04 Daicel Chem Ind Ltd Modified cellulose acylate and molded article for optical use
WO2007129722A1 (en) * 2006-05-09 2007-11-15 Daicel Chemical Industries, Ltd. Hydroxy acid-modified glucan derivative and molded body thereof

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2012073089A (en) * 2010-09-28 2012-04-12 Gunze Ltd Method for measuring degree of polymerization of cellulose
WO2017061548A1 (en) * 2015-10-06 2017-04-13 株式会社カネカ Polymer material, film, circular polarizing plate, image display apparatus, and manufacturing method for film
CN108137712A (en) * 2015-10-06 2018-06-08 株式会社钟化 Polymer material, film, circular polarizer, image display device, and method for producing film
US10851180B2 (en) 2015-10-06 2020-12-01 Kaneka Corporation Polymer material, film, circular polarizing plate, image display apparatus, and manufacturing method for film
JP2018172580A (en) * 2017-03-31 2018-11-08 株式会社カネカ Method for producing cellulose derivative
JP2018177892A (en) * 2017-04-06 2018-11-15 株式会社カネカ Method for producing cellulose derivative
WO2018207848A1 (en) * 2017-05-12 2018-11-15 地方独立行政法人大阪産業技術研究所 Poly(lactic acid)-grafted cellulose nanofiber and production method therefor
US11046787B2 (en) 2017-05-12 2021-06-29 Osaka Research Institute Of Industrial Science And Technology Polylactide-grafted cellulose nanofiber and production method thereof
CN109456487A (en) * 2018-10-16 2019-03-12 湖北省冠成生物降解塑料制品有限公司 A kind of preparation method and application of cellulose derivative grafted polylactic acid
EP4223836A4 (en) * 2020-09-30 2024-10-09 Daio Paper Corporation POLYLACTIC ACID COMPOSITE RESIN
EP4223835A4 (en) * 2020-09-30 2024-10-09 Daio Paper Corporation CELLULOSE COMPOSITE RESIN
CN112280104A (en) * 2020-10-30 2021-01-29 界首市天路包装材料有限公司 Processing technology of environmentally friendly degradable packaging shell
JP2023012765A (en) * 2021-07-14 2023-01-26 国立大学法人九州工業大学 Cellulose ester composition
JP7754407B2 (en) 2021-07-14 2025-10-15 国立大学法人九州工業大学 Cellulose ester composition
CN114479139B (en) * 2022-01-14 2023-08-25 江西冠德新材科技股份有限公司 Fiber-based degradable film and preparation method thereof
CN114479139A (en) * 2022-01-14 2022-05-13 江西冠德新材科技股份有限公司 Fiber-based degradable film and preparation method thereof
WO2023145958A1 (en) * 2022-01-31 2023-08-03 冨士色素株式会社 Thermoplastic composition

Also Published As

Publication number Publication date
JPWO2008143322A1 (en) 2010-08-12

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