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WO2008018335A1 - gants et leur processus de fabrication - Google Patents

gants et leur processus de fabrication Download PDF

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Publication number
WO2008018335A1
WO2008018335A1 PCT/JP2007/065046 JP2007065046W WO2008018335A1 WO 2008018335 A1 WO2008018335 A1 WO 2008018335A1 JP 2007065046 W JP2007065046 W JP 2007065046W WO 2008018335 A1 WO2008018335 A1 WO 2008018335A1
Authority
WO
WIPO (PCT)
Prior art keywords
glove
gloves
hand
layer
resin layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2007/065046
Other languages
English (en)
Japanese (ja)
Inventor
Terukazu Fujihana
Ryohei Yamamoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Showa Glove Co
Original Assignee
Showa Glove Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Showa Glove Co filed Critical Showa Glove Co
Publication of WO2008018335A1 publication Critical patent/WO2008018335A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
    • D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
    • D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00—Gloves
    • A41D19/0006—Gloves made of several layers of material
    • A—HUMAN NECESSITIES
    • A41—WEARING APPAREL
    • A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
    • A41D19/00—Gloves
    • A41D19/015—Protective gloves
    • A41D19/01505—Protective gloves resistant to mechanical aggressions, e.g. cutting. piercing
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
    • D06M23/00—Treatment of fibres, threads, yarns, fabrics or fibrous goods made from such materials, characterised by the process
    • D06M23/04—Processes in which the treating agent is applied in the form of a foam
    • D—TEXTILES; PAPER
    • D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
    • D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
    • D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
    • D06N3/12—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins
    • D06N3/14—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes
    • D06N3/145—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. gelatine proteins with polyurethanes two or more layers of polyurethanes

Definitions

  • the present invention relates to a hand bag suitable for work in a clean room and work equivalent thereto, and a method for manufacturing the hand bag.
  • gloves composed of only resin or rubber are easy to tear due to excessive pulling at the time of attachment and detachment, and are damaged from places where stress forces such as fingertips are easily applied even after use. It was difficult to use.
  • these gloves made of chlorinated bur resin, NBR rubber or natural rubber have a problem that it is hard to be used continuously for a long time.
  • Patent Document 1 Japanese Patent Laid-Open No. 11-12823
  • Patent Document 2 JP-A-6-33303
  • the present invention intends to solve the problem by reducing the thickness of the glove while providing strength that does not easily break by using a thin fiber fabric as a base.
  • the original softness and strength of the fabric is applied, and it fits in the hand and has good workability. Even if it is used for a long time that the coating layer does not easily peel or break due to excessive tension or external force, and can be reused many times for washing and washing.
  • the point is to provide a glove that does not stuffy and can be finely worked, such as a touch panel in a clean room, and a manufacturing method thereof.
  • the present invention comprises a glove-like hand from a fiber fabric having a longitudinal tensile elongation of 170% or more and a thickness of 500 in or less.
  • a glove having a hand impregnated with a foamed urethane resin layer was constructed.
  • the tensile elongation refers to the elongation when a point between two points on the fabric is approximately 5 mm wide and 2.5 kg. For example, when the original distance lcm becomes 2 cm by pulling (original distance) 200%), the tensile elongation is 200%.
  • the vertical direction is a direction along the length direction of the finger.
  • the thickness of the fiber fabric is the thickness measured according to JIS L 1096.
  • a non-porous moisture-permeable and waterproof polyurethane resin layer is further coated on the foam layer.
  • the fiber fabric may be made of wooly polyester or wooly nylon.
  • a fabric made by combining these and urethane elastic yarn is preferable.
  • the thickness of the glove including the film-formed foam layer and the polyurethane resin layer is 500 am or less. preferable.
  • the thickness of the glove refers to the thickness measured according to JIS K 6250.
  • the present invention comprises a glove-like hand made from a fiber fabric having a longitudinal tensile elongation of 170% or more and a thickness of 500 m or less, and urethane foam is foamed on the hand. Also provided is a method of manufacturing a glove characterized in that the layer is impregnated. Here again, preferably, a nonporous moisture-permeable waterproof polyurethane resin layer is further deposited on the foamed layer.
  • the impregnated layer is foamed, a soft glove having excellent overall elongation can be constructed without impairing the original elongation characteristics of the fabric having a tensile elongation of 170% or more. Therefore, it is possible to provide gloves that fit well in the hand, have good workability, and are comfortable to fit, both for those with slightly larger hands. In addition, it is possible to construct a glove that can maintain an excellent fit feeling to the steam compared to conventional film gloves.
  • the degree of adhesion is higher than that of a conventional method in which the coating layer is directly coated only on the cloth due to the presence of the impregnation layer. Is further improved. Accordingly, the coating layer itself can be thinned, and a glove having a thin and soft fit as a whole can be provided. Specifically, it has been confirmed that the coating layer of the present invention can provide a glove having a good workability that is soft and fits in the hand with a thinness of about 10 to 30 m and sufficient adhesion and strength.
  • the coating layer since the adhesion strength of the coating layer is improved by the presence of the impregnation layer, the coating layer does not easily peel off even when a glove is pulled or an external force is applied, and the fused portion is peeled off. Since there is no separation, the durability is improved, and it can be reused many times by washing and washing. Since the impregnated layer is foamed and the coating layer is thin with a non-porous moisture-permeable waterproof resin with hydrophilic groups, the entire glove can be given moisture permeability and waterproofness, making it more sultry than conventional film gloves. ⁇ Can maintain excellent fit.
  • FIG. 1 is an enlarged photograph of the glove surface after the test with the number of friction of “100”, (a) is Example 1, (b) is Comparative Example 3, (c) is Comparative Example 4, ( d) Photo of Comparative Example 5.
  • FIG. 2 An enlarged photograph of the surface of the glove after the test with the number of friction of “400 times” for Example 1, (a) is 25 magnifications, and (b) is 100 magnifications.
  • the glove according to the present invention comprises a glove-like hand made of a fiber fabric having a longitudinal tensile elongation along the finger length direction of 170% or more and a thickness of 500 m or less.
  • the raw hand is impregnated with a foam layer of urethane resin.
  • the foam layer is a urethane film wet film-forming foam layer.
  • a non-porous moisture-permeable and waterproof polyurethane resin layer is further deposited on the foam layer.
  • a force-separate hand that explains an example using a sewing hand can also be used.
  • the fiber fabric constituting the hand is preferably a fabric made of woolly polyester or woolly nylon, or a fabric made by combining these with urethane elastic yarn.
  • the tensile elongation in the longitudinal direction of the raw cloth is less than 170%, the elongation of the finger part of the glove is particularly bad, and the flexibility of the finger part is poor and the fitting comfort is lowered. More preferably, it is set to 200% or more. In addition, if the thickness of the fabric is thicker than 500 m, the flexibility of the finger part is lowered, and the fit feeling is lowered with the feeling of stickiness and workability is also lowered. More preferably set to 400 in or less
  • the thickness of the glove including the film-formed foam layer and the polyurethane resin layer is 500 m or less, more preferably 400 Hm or less.
  • each of the textile fabrics shown in Table 1 is composed of a glove-like hand, and a urethane resin foam layer is impregnated and adhered to the hand. Further, a non-porous moisture-permeable and waterproof polyurethane resin layer is further applied.
  • Fabrics that have been punched into a glove shape are sewn to produce a fiber glove, and then the scouring process is performed on the produced sewing hand. Scouring is performed at 85 ° C to 95 ° C for 15 minutes using lg / L of a scouring agent (“SSK-15” manufactured by Matsumoto Yushi Seiyaku Co., Ltd.) in 30 times the weight of the original hand. Done.
  • SSK-15 a scouring agent manufactured by Matsumoto Yushi Seiyaku Co., Ltd.
  • waste water treatment is performed, and then a rinsing treatment is performed. Rinsing is performed at room temperature for 3 minutes using 30 times the weight of the hand. After rinsing, it is drained and then dehydrated and dried at 110 degrees for 10 minutes.
  • a wet film-formable urethane resin (Dainippon Ink Chemical Co., Ltd. “Crisbon 8006HVLD”) 10wt% with the above-mentioned hand over an aluminum hand mold and the hand mold with the master hand dissolved in a mixed solvent of DMF and toluene Immerse it in a solution (resin 10wt%, DMF85wt%, toluene 5wt%) at 4mm / sec, pull it up at 4mm / sec, soak it in warm water at 50 ° C for 60 minutes, and replace the solvent DMF in the resin solution with water. Then, pull up from the water, dry at 110 ° C for 10 minutes, and cool to a hand mold temperature of around 50 ° C with a fan.
  • Example 1 As can be seen from the results in Table 2, in Examples 1 and 2, in Example 1, the stretch in the longitudinal direction of the fabric is larger, and the elongation of the glove fingers is also larger as 175. It became a comfortable glove. Compared to this, Example 2 is sufficient for use in a clean room with a little dissatisfaction. In Comparative Example 1, since the tensile elongation in the longitudinal direction of the fabric is small, the elongation of the finger part of the glove is deteriorated, and therefore, the flexibility of the finger part is poor and the fitting comfort is considered to be affected. In Comparative Example 2, although the elongation is sufficient, the fabric thickness is as large as 680 m, and the volume of the impregnated layer that penetrates further increases. Seems to have gone bad.
  • Table 4 below shows the results of the tensile test, tear test, and dust resistance test performed on the gloves of Example 1 and Comparative Examples 3 to 5.
  • the gloves of Comparative Examples 3 to 5 are those described in Patent Document 2 described above, which are finished in a glove shape by heat fusion so that the films face each other from a sheet obtained by laminating a thin film on a thin fiber fabric. It is the conventional fusion glove for clean rooms illustrated.
  • Comparative Example 3 the trade name of "Prof eS io n on seam glovesj (Co., Ltd.
  • test piece (1. Ocm x 10cm) including a sewn or fused part of each glove, perpendicular to the sewn or fused part at a pulling speed of 15cm / min and a distance between chucks of 6cm. The sample was pulled in the direction, and the resistance until the specimen started to tear was measured.
  • the tear test involves preparing a test piece (5. Ocm x 10 cm) that includes a sewn or fused part of each glove, making a tear along the sewn or fused part, and then both ends at the boundary of the tear. The part was supported, pulled at a pulling rate of 15 cm / min, and a distance between chucks of 6 cm. Also, in the dust resistance test, 20 gloves were prepared in accordance with JIS B 9923, and the number of dusts of 0.3 am or more in the first and third washing was measured.
  • Example 1 has a durability about 3 to 4 times that of the fused gloves of Comparative Examples 3 to 5, both in terms of tension and tear.
  • Comparative Examples 3 to 5 were actually torn along the fused part, whereas Example 1 was torn apart from the sewn part.
  • the sewing part has higher durability than the other parts, and the sewing part of Example 1 has a durability far exceeding the above 3 to 4 times compared to Comparative Examples 3 to 5. It has the power S component power.
  • the glove according to the present invention is provided with an impregnation layer and a coating layer on the original hand sewn in the shape of a glove having a heat fusion part as in Comparative Examples 3 to 5, so that the original hand
  • the sewing part of the resin is impregnated with resin!
  • Example 1 the results of the dust generation resistance test are also considerably smaller in Example 1 than in the gloves of Comparative Examples 3 to 5, which is very excellent in dust generation resistance and a clean room with a cleanness of 100 is sufficient. It can be seen that it is a glove that can be used. As a result, the sewing part in which the glove of the present invention is sewn with the sewing machine is also fixed by impregnation with the resin! /, Thus preventing dust generation! / And sewing. It can be seen that the wet hand film-forming foam layer of urethane resin is impregnated in the hand and the generation of fabric scraps from the inside of the gloves is also prevented.
  • FIGS. 1 and 2 show the results of the abrasion resistance test performed on the gloves of Example 1 and Comparative Examples 3 to 5.
  • the abrasion resistance test method is the CE test EN388, using the test equipment “Nu_ MartindaleJ (manufactured by James H. Heal & Co. td.), And the abrasive paper is water resistant paper (3M sandpaper (dry & wet)). ) # 2000)
  • Figure 1 is an enlarged photograph (100 magnifications) of the glove surface after the test with 100 times of friction, (a) in Example 1 and (b) in comparison. Examples 3 and (c) are Comparative Example 4 and (d) is Comparative Example 5.
  • FIG. 2 shows Example 1 This is an enlarged photograph of the surface of the glove after the test with the number of frictions “400”, (a) is 25 times magnification and (b) is 100 magnifications. In Comparative Examples 3 to 5, since the damaged part occurred at the number of wear “100 times”, it was not continued and the number of wear was not made “400 times”.
  • the glove of Example 1 showed no damage to the surface coating even when the number of friction was "400".
  • the gloves of Comparative Examples 3 to 5 as shown in FIG.
  • the glove according to the present invention has a coating layer that adheres to the impregnation layer impregnated into the fiber fabric and can be coated even when a force is applied from the outside, compared to a fusion glove that is directly applied only to the fabric. It can be seen that the layer does not peel easily, the durability is improved, and it can be reused many times by washing and washing, which has been particularly demanded in recent years.
  • Table 5 shows the results of the air leak test for the gloves of Example 1 and Comparative Examples 3 to 5.
  • the air leak test was conducted with 10 gloves each in accordance with CE test EN374-2.
  • the glove of Example 1 has sufficient water resistance, and the glove of the present invention is impregnated on the original hand sewn into a glove shape having a heat-sealed portion as in Comparative Examples 3 to 5. Since each coating layer is provided, the joints (sewing parts) that are likely to cause air leaks are also impregnated with resin and have high resistance, strength and water resistance! A force.

Landscapes

  • Engineering & Computer Science (AREA)
  • Textile Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Dispersion Chemistry (AREA)
  • Gloves (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)

Abstract

L'invention entend proposer des gants fabriqués en utilisant un fin textile comme matériau de base et présentant ainsi une grande solidité, une faible épaisseur, et une douceur inhérente au textile ; que l'on obtient par la formation stérique d'enduction de gants bruts par application à des modèles de mains ce qui offre l'avantage d'une grande maniabilité du fait de leur excellente adaptation à la main, avec une perméabilité à l'humidité et une étanchéité à l'eau empêchant la sueur comme la pénétration de l'eau de l'extérieur, sans souffrir de l'arrachement ou de la rupture des couches de revêtement suite à une tension immodérée ou une force externe excessive, de sorte qu'on peut les utiliser de façon répétée en les nettoyant ou les lavant ; sans provoquer de sueur même en cas d'usage prolongé et en permettant des opérations précises comme l'utilisation d'un panneau tactile dans une salle propre, et leur processus de fabrication. L'invention concerne alors des gants produits en utilisant un gant brut d'un textile présentant une résistance à la traction supérieure ou égale à 170% dans le sens de la chaîne et une épaisseur inférieure ou égale à 500μm, en recouvrant le gant brut d'une couche de résine d'uréthane moussée selon un procédé de formation de film humide par imprégnation, avant de constituer une couche de résine de polyuréthane non poreuse, perméable à l'humidité et étanche à l'eau sur la couche de résine d'uréthane moussée.
PCT/JP2007/065046 2006-08-09 2007-08-01 gants et leur processus de fabrication Ceased WO2008018335A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006216456A JP2008038303A (ja) 2006-08-09 2006-08-09 手袋及びその製造方法
JP2006-216456 2006-08-09

Publications (1)

Publication Number Publication Date
WO2008018335A1 true WO2008018335A1 (fr) 2008-02-14

Family

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Family Applications (1)

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PCT/JP2007/065046 Ceased WO2008018335A1 (fr) 2006-08-09 2007-08-01 gants et leur processus de fabrication

Country Status (2)

Country Link
JP (1) JP2008038303A (fr)
WO (1) WO2008018335A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110099689A1 (en) * 2009-11-02 2011-05-05 Atg Ceylon (Private) Limited Protective garments and materials therefor
CN103857304A (zh) * 2011-10-14 2014-06-11 住友橡胶工业株式会社 手套
CN114705620A (zh) * 2022-04-12 2022-07-05 赛立特(南通)安全用品有限公司 一种评价手套热粘合型防撞击块粘结牢度的测试方法
EP4230790A4 (fr) * 2021-12-27 2024-11-27 Zhangjiagang Siqi Science and Technology, Co., Ltd Gants entièrement enduits par trempage présentant des fonctions d'absorption d'humidité et d'évacuation de la transpiration

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2016121412A (ja) * 2014-12-24 2016-07-07 株式会社東和コーポレーション 手袋

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0219503A (ja) * 1988-07-07 1990-01-23 Dai Ichi Kogyo Seiyaku Co Ltd 作業用手袋の製造法
JPH09324311A (ja) * 1996-06-04 1997-12-16 North Kasei Kogyo Kk 作業用手袋及びその製造方法
JP2001131814A (ja) * 1999-11-01 2001-05-15 Dia Gomme Kk 作業用手袋及びその製造方法
JP2001509554A (ja) * 1997-07-11 2001-07-24 パトリック・ボレアニ 繊維担体から形成された操作・保護用手袋形態の衣料製品

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60224804A (ja) * 1984-04-20 1985-11-09 東和グロ−ブ株式会社 手袋
JPH0318486Y2 (fr) * 1985-03-26 1991-04-18
JPS6269808A (ja) * 1985-09-20 1987-03-31 東和グロ−ブ株式会社 手袋及びその製造方法
JPS6356212U (fr) * 1986-09-29 1988-04-15
JPH11217709A (ja) * 1998-01-29 1999-08-10 Masaru Obayashi 薄シート状手袋
JP2001073211A (ja) * 1999-09-01 2001-03-21 Kawanishi Kogyo Kk 作業用手袋およびその製造方法
JP2001070009A (ja) * 1999-09-02 2001-03-21 Daiyu Shoji:Kk カイロ装着用インソール

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0219503A (ja) * 1988-07-07 1990-01-23 Dai Ichi Kogyo Seiyaku Co Ltd 作業用手袋の製造法
JPH09324311A (ja) * 1996-06-04 1997-12-16 North Kasei Kogyo Kk 作業用手袋及びその製造方法
JP2001509554A (ja) * 1997-07-11 2001-07-24 パトリック・ボレアニ 繊維担体から形成された操作・保護用手袋形態の衣料製品
JP2001131814A (ja) * 1999-11-01 2001-05-15 Dia Gomme Kk 作業用手袋及びその製造方法

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110099689A1 (en) * 2009-11-02 2011-05-05 Atg Ceylon (Private) Limited Protective garments and materials therefor
US9061453B2 (en) * 2009-11-02 2015-06-23 Atg Ceylon (Private) Limited Protective garments and materials therefor
CN103857304A (zh) * 2011-10-14 2014-06-11 住友橡胶工业株式会社 手套
CN103857304B (zh) * 2011-10-14 2015-11-25 住友橡胶工业株式会社 手套
EP4230790A4 (fr) * 2021-12-27 2024-11-27 Zhangjiagang Siqi Science and Technology, Co., Ltd Gants entièrement enduits par trempage présentant des fonctions d'absorption d'humidité et d'évacuation de la transpiration
CN114705620A (zh) * 2022-04-12 2022-07-05 赛立特(南通)安全用品有限公司 一种评价手套热粘合型防撞击块粘结牢度的测试方法

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