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WO2008010108A2 - Appareil d'électrolyse à deux tensions et procédé d'utilisation - Google Patents

Appareil d'électrolyse à deux tensions et procédé d'utilisation Download PDF

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Publication number
WO2008010108A2
WO2008010108A2 PCT/IB2007/051997 IB2007051997W WO2008010108A2 WO 2008010108 A2 WO2008010108 A2 WO 2008010108A2 IB 2007051997 W IB2007051997 W IB 2007051997W WO 2008010108 A2 WO2008010108 A2 WO 2008010108A2
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WO
WIPO (PCT)
Prior art keywords
high voltage
low voltage
pair
electrodes
electrolysis system
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/IB2007/051997
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English (en)
Other versions
WO2008010108A3 (fr
Inventor
Nehemia Davidson
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kuzo Holding Inc
Original Assignee
Kuzo Holding Inc
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Filing date
Publication date
Priority claimed from CA002579737A external-priority patent/CA2579737A1/fr
Application filed by Kuzo Holding Inc filed Critical Kuzo Holding Inc
Publication of WO2008010108A2 publication Critical patent/WO2008010108A2/fr
Publication of WO2008010108A3 publication Critical patent/WO2008010108A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B15/00—Operating or servicing cells
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B1/00—Electrolytic production of inorganic compounds or non-metals
    • C25B1/01—Products
    • C25B1/02—Hydrogen or oxygen
    • C25B1/04—Hydrogen or oxygen by electrolysis of water
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/17—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof
    • C25B9/19—Cells comprising dimensionally-stable non-movable electrodes; Assemblies of constructional parts thereof with diaphragms
    • C—CHEMISTRY; METALLURGY
    • C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
    • C25B—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR
    • C25B9/00—Cells or assemblies of cells; Constructional parts of cells; Assemblies of constructional parts, e.g. electrode-diaphragm assemblies; Process-related cell features
    • C25B9/70—Assemblies comprising two or more cells
    • C25B9/73—Assemblies comprising two or more cells of the filter-press type
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/36—Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Definitions

  • the present invention relates generally to electrolysis systems and, more particularly, to a high efficiency electrolysis system and methods of using same.
  • Fossil fuels in particular oil, coal and natural gas, represent the primary sources of energy in today's world.
  • fossil fuels are the largest single source of carbon dioxide emissions, a greenhouse gas, continued reliance on such fuels can be expected to lead to continued global warming. Accordingly it is imperative that alternative, clean and renewable energy sources be developed that can replace fossil fuels.
  • Hydrogen-based fuel is currently one of the leading contenders to replace fossil fuel.
  • Other, less developed hydrogen producing techniques include (i) biomass fermentation in which methane fermentation of high moisture content biomass creates fuel gas, a small portion of which is hydrogen; (ii) biological water splitting in which certain pho- tosynthetic microbes produce hydrogen from water during their metabolic activities; (iii) photoelectrochemical processes using either soluble metal complexes as a catalyst or semiconducting electrodes in a photochemical cell; (iv) thermochemical water splitting using chemicals such as bromine or iodine, assisted by heat, to split water molecules; (v) thermolysis in which concentrated solar energy is used to generate temperatures high enough to split methane into hydrogen and carbon; and (vi) electrolysis.
  • Electrolysis as a means of producing hydrogen has been known and used for over 80 years.
  • electrolysis of water uses two electrodes separated by an ion conducting electrolyte.
  • hydrogen is produced at the cathode and oxygen is produced at the anode, the two reaction areas separated by an ion conducting diaphragm.
  • Electricity is required to drive the process.
  • An alternative to conventional electrolysis is high temperature electrolysis, also known as steam electrolysis.
  • This process uses heat, for example produced by a solar concentrator, as a portion of the energy required to cause the needed reaction. Although lowering the electrical consumption of the process is desirable, this process has proven difficult to implement due to the tendency of the hydrogen and oxygen to recombine at the technique's high operating temperatures.
  • a high temperature heat source for example a geothermal source, can also be used as a replacement for fossil fuel.
  • the heat source raises the temperature of water sufficiently to produce steam, the steam driving a turbine generator which, in turn, produces electricity.
  • the heat source can raise the temperature of a liquid that has a lower boiling temperature than water, such as isopentane, which can also be used to drive a turbine generator.
  • the heat source can be used as a fossil fuel replacement for non-electrical applications, such as heating buildings. Disclosure of Invention Technical Problem
  • the present invention provides an electrolysis system and method of using same.
  • the system includes at least one pair of low voltage electrodes comprised of a first material and at least one pair of high voltage electrodes comprised of the same, or different, material.
  • Each pair of electrodes includes a cathode and an anode with the separation distance between the cathode and anode of each pair of high voltage electrodes being greater than the separation distance between the cathode and anode of each pair of low voltage electrodes.
  • both low voltage electrodes of each pair of low voltage electrodes are located between the pair, or pairs, of high voltage electrodes.
  • the low voltage applied to the low voltage electrodes is pulsed as is the high voltage applied to the high voltage electrodes, the low voltage pulses and the high voltage pulses being timed to occur simultaneously.
  • the liquid within the tank is comprised of one or more of; water, deuterated water, tritiated water, semiheavy water, heavy oxygen water, and/or any other water containing an isotope of either hydrogen or oxygen.
  • the low and high voltage pulses occur at a frequency between 50 Hz and 7 kHz and with a pulse duration of between 0.1 and 75 percent of the time period defined by the frequency, and more preferably with a pulse duration of between 1 and 50 percent of the time period defined by the frequency.
  • the ratio of the high voltage to the low voltage is at least 5:1, more preferably within the range of 5: 1 to 100:1, still more preferably within the range of 5:1 to 33:1, and still more preferably within the range of 5:1 to 20:1.
  • the low voltage is between 3 and 1500 volts, more preferably between 12 and 750 volts.
  • the high voltage is between 50 volts and 50 kilovolts, more preferably between 100 volts and 5 kilovolts.
  • the low voltage electrodes and the high voltage electrodes are fabricated from any of a variety of materials, although preferably the electrode material is selected from the group consisting of steel, nickel, copper, iron, stainless steel, cobalt, manganese, zinc, titanium, platinum, palladium, and alloys thereof.
  • the low voltage electrodes and the high voltage electrodes can utilize any of a variety of surface shapes, with each pair of electrodes, i.e., the cathode and anode of each pair, being either positioned parallel to one another or not parallel to one another.
  • the concentration of electrolyte in the liquid is between 0.05 and 10 percent by weight. In at least one other embodiment of the invention, the concentration of electrolyte in the liquid is between 0.05 and 2.0 percent by weight. In yet at least one other embodiment of the invention, the concentration of electrolyte in the liquid is between 0.05 and 0.1 percent by weight.
  • FIG. 1 is an illustration of an exemplary embodiment of the invention
  • FIG. 2 is an illustration of an alternate exemplary embodiment utilizing multiple pairs of low voltage electrodes
  • FIG. 3 is an illustration of an alternate exemplary embodiment utilizing multiple pairs of high voltage electrodes
  • FIG. 4 is an illustration of an alternate exemplary embodiment utilizing multiple pairs of low voltage electrodes and multiple pairs of high voltage electrodes
  • FIG. 5 is an illustration of an alternate exemplary embodiment utilizing a vertical cylindrical tank
  • FIG. 6 is an illustration of an alternate exemplary embodiment utilizing a horizontal cylindrical tank
  • FIG. 7 is an illustration of an alternate exemplary embodiment utilizing a horizontal cylindrical tank and a separation membrane running lengthwise in the tank;
  • FIG. 8 is an illustration of one mode of operation
  • FIG. 9 is an illustration of an alternate mode of operation that includes initial process optimization steps
  • Fig. 10 is an illustration of an alternate, and preferred, mode of operation in which the process undergoes continuous optimization
  • FIG. 11 is a block diagram illustrating the preferred optimization control system.
  • Fig. 12 is a top, cross-sectional view of the embodiment shown in Fig. 1.
  • FIG. 1 is an illustration of an exemplary embodiment of the invention.
  • Electrolysis system 100 includes a tank 101 comprised of a non-conductive material, the size of the tank depending primarily upon the desired output of the system as well as the dimensions of the electrodes contained within the tank.
  • tank 101 is shown as having a rectangular shape, it will be appreciated that the invention is not so limited and that tank 101 can utilize other shapes, for example cylindrical, square, irregularly- shaped, etc.
  • Tank 101 is substantially filled with liquid 103.
  • liquid 103 is comprised of water with an electrolyte, the electrolyte being either an acid electrolyte or a base electrolyte.
  • Exemplary electrolytes include potassium hydroxide and sodium hydroxide.
  • water' refers to water (H 2 O), deuterated water (deuterium oxide or D 2 O), tritiated water (tritium oxide or T 2 O), semiheavy water (HDO), heavy oxygen water (H 2 18 O or H 2 17 O) or any other water containing an isotope of either hydrogen or oxygen, either singly or in any combination thereof (for example, a combination of H 2 O and D 2 O).
  • a typical electrolysis system used to decompose water into hydrogen and oxygen gases utilizes relatively high concentrations of electrolyte.
  • the present invention has been found to work best with relatively low electrolyte concentrations, thereby maintaining a relatively high water resistivity (e.g., typically on the order of 1 to 2 megohms). Note that this resistivity is based on the initial resistance of the water since typically after the system has been operating for a while (for example, on the order of 5 to 6 hours), the resistivity of the water may drop.
  • the concentration of electrolyte is in the range of 0.05 percent to 10 percent by weight, more preferably the concentration of electrolyte is in the range of 0.05 percent to 2.0 percent by weight, and still more preferably the concentration of electrolyte is in the range of 0.1 percent to 0.2 percent by weight.
  • Membrane 105 permits ion/ electron exchange between the two regions of tank 101 while keeping separate the oxygen and hydrogen bubbles produced during electrolysis. Maintaining separate hydrogen and oxygen gas regions is important not only as a means of allowing the collection of pure hydrogen gas and pure oxygen gas, but also as a means of minimizing the risk of explosions due to the inadvertent recombination of the two gases.
  • Exemplary materials for membrane 105 include, but are not limited to, polypropylene, tetrafluoroethylene, asbestos, etc. In at least one preferred embodiment, membrane 105 is 25 microns thick and comprised of polypropylene. [25] As noted herein, the present system is capable of generating considerable heat.
  • system components such as tank 101 and membrane 105 that are expected to be subjected to the heat generated by the system must be fabricated from suitable materials and designed to indefinitely accommodate the intended operating temperatures as well as the internal tank pressure.
  • the system is designed to operate at a temperature of approximately 90° C at standard pressure.
  • the system is designed to operate at elevated temperatures (e.g., 100° C to 150° C) and at sufficient pressure to prevent boiling of liquid 103.
  • the system is designed to operate at even higher temperatures (e.g., 200° C to 250° C) and higher pressures (e.g., sufficient to prevent boiling).
  • the system utilizing system 100 also includes means for either storing the produced gases, e.g., hydrogen storage tanks, or means for delivering the produced gas to the point of consumption, e.g., pipes and valves, as well as flow gauges, pressure gauges, gas compressors, gas driers, gas purifiers, etc.
  • means for either storing the produced gases e.g., hydrogen storage tanks, or means for delivering the produced gas to the point of consumption, e.g., pipes and valves, as well as flow gauges, pressure gauges, gas compressors, gas driers, gas purifiers, etc.
  • the electrolysis system of the invention uses two types of electrodes, each type of electrode being comprised of one or more electrode pairs with each electrode pair including at least one cathode (i.e., a cathode coupled electrode) and at least one anode (i.e., an anode coupled electrode). All cathodes, regardless of the type, are kept in one region of tank 101 while all anodes, regardless of the type, are kept in the other tank region, the two tank regions separated by membrane 105. In the embodiment illustrated in Fig. 1, each type of electrode includes a single pair of electrodes.
  • the first pair of electrodes, electrodes 115/117, are coupled to a low voltage source
  • the second set of electrodes, electrodes 121/122, are coupled to a high voltage source 123.
  • voltage source 119 is referred to and labeled as a 'low' voltage source not because of the absolute voltage produced by the source, but because the output of voltage source 119 is maintained at a lower output voltage than the output of voltage source 123.
  • the individual electrodes of each pair of electrodes are parallel to one another; i.e., the face of electrode 115 is parallel to the face of electrode 117 and the face of electrode 121 is parallel to the face of electrode 122.
  • electrodes 115/117 and electrodes 121/122 are comprised of titanium.
  • electrodes 115/117 and electrodes 121/122 are comprised of stainless steel. It should be appreciated, however, that other materials can be used and that the same material does not have to be used for both the low and high voltage electrodes.
  • other exemplary materials that can be used for the low voltage and high voltage electrode pairs include, but are not limited to, copper, iron, cobalt, steel, manganese, zinc, nickel, platinum, palladium, and alloys of these materials.
  • the area of the face of electrode 115 covers a large percentage of the cross-sectional area of tank 101, typically on the order of at least 40 percent of the cross-sectional area of tank 101, and often between approximately 70 percent and 90 percent of the cross-sectional area of tank 101.
  • the separation distance between electrode pairs is dependent upon a variety of factors (e.g., tank size, voltage/current, etc.), in at least one preferred embodiment the separation of the low voltage electrodes (e.g., electrodes 115 and 117) is between 3 millimeters and 15 centimeters, and more preferably on the order of 10 to 12 centimeters.
  • Electrodes 121/122 are positioned outside of electrodes 115/117. In other words, the separation distance between electrodes 121 and 122 is greater than the separation distance between electrodes 115 and 117 and both low voltage electrodes are positioned between the high voltage electrodes.
  • the high voltage electrodes e.g., electrodes 121/122
  • the low voltage electrodes e.g., electrodes 115/117
  • typically the surface area of the high voltage electrodes is less than that of the low voltage electrodes, and more typically the surface area of the high voltage electrodes is much less than that of the low voltage electrodes.
  • the surface area of electrodes 121/122 is approximately 0.2 percent the surface area of electrodes 115/117 while in another exemplary preferred embodiment the surface area of electrodes 121/122 is approximately 2 percent the surface area of electrodes 115/117.
  • the voltage applied to high voltage electrode pair 121/122 is greater than that applied to low voltage electrodes 115/117.
  • the ratio of the high voltage to the low voltage is at least 5:1, more preferably the ratio is between 5:1 and 100:1, still more preferably the ratio is between 5:1 and 33:1, and even still more preferably the ratio is between 5:1 and 20:1.
  • the high voltage generated by source 123 is within the range of 50 volts to 50 kilovolts, and preferably within the range of 100 volts to 5 kilovolts.
  • the low voltage generated by source 119 is within the range of 3 volts to 1500 volts, and preferably within the range of 12 volts to 750 volts.
  • sources 119 and 123 are pulsed, preferably at a frequency of between 50 Hz and 7 kHz with a pulse width (i.e., pulse duration) of between 0.1 and 75 percent of the time period defined by the selected frequency, and more preferably with a pulse width of between 1 and 50 percent of the time period defined by the selected frequency.
  • pulse duration is preferably in the range of 6.7 microseconds to 5 milliseconds, and more preferably in the range of 67 microseconds to 3.3 milliseconds.
  • the pulse duration is preferably in the range of 1 microseconds to 0.75 milliseconds, and more preferably in the range of 10 microseconds to 0.5 milliseconds.
  • the frequency and/or pulse duration can be changed during system operation, thus allowing the system output efficiency to be continually optimized.
  • Voltage is simultaneously applied to electrodes 121/122 from source 123 and electrodes 115/117from source 119. In other words, the pulses applied to electrodes 121/122 coincide with the pulses applied to electrodes 115/117.
  • voltage sources 119 and 123 can include internal means for pulsing the respective outputs from each source, preferably an external pulse generator 125 controls a pair of switches, i.e., a low voltage switch 127 and a high voltage switch 129 which, in turn, control the output of voltage sources 119 and 123 as shown, and as described above.
  • an external pulse generator 125 controls a pair of switches, i.e., a low voltage switch 127 and a high voltage switch 129 which, in turn, control the output of voltage sources 119 and 123 as shown, and as described above.
  • the electrolysis process of the invention generates considerable heat. It will be appreciated that if the system is allowed to become too hot for a given pressure, the fluid within tank 101 will begin to boil. Additionally, various system components may be susceptible to heat damage. Although the system can be turned off and allowed to cool when the temperature exceeds a preset value, for example using a control system coupled to a thermocouple or other heat monitor which triggers the control system when the system (or tank fluid) exceeds the preset value, this is not a preferred approach due to the inherent inefficiency of stopping the process, allowing the system to cool, and then restarting the system. A more efficient, and preferred, approach uses means which actively cool the system to maintain the temperature within an acceptable range.
  • the cooling system does not allow the temperature to exceed 90° C.
  • tank 101 is surrounded by coolant conduit 131, portions of which are shown in Figs. 1-7.
  • coolant conduit 131 can either surround a portion of the electrolysis tank as shown, or be contained within the electrolysis tank, or be integrated within the walls of the electrolysis tank.
  • the coolant pump and refrigeration system is not shown in the figures as cooling systems are well known by those of skill in the art.
  • Figs. 2-7 illustrate a few alternate configurations, including the use of multiple pairs of low voltage electrodes (i.e., Fig. 2), multiple pairs of high voltage electrodes (i.e., Fig. 3), multiple pairs of low voltage and high voltage electrodes (e.g., Fig. 4), vertical cylindrical tanks (e.g., Fig. 5), and horizontal cylindrical tanks (e.g., Figs. 6 and 7).
  • FIG. 2 illustrates an alternate embodiment of the system shown in Fig. 1, the alternate configuration replacing low voltage electrode 115 with four low voltage electrodes 201-204 and replacing low voltage electrode 117 with four low voltage electrodes 205-208.
  • FIG. 3 illustrates an alternate embodiment of the system shown in Fig. 1, the alternate configuration replacing high voltage electrode 121 with three high voltage electrodes 301-303 and replacing high voltage electrode 122 with three high voltage electrodes 305-307.
  • FIG. 4 illustrates an alternate embodiment of the system shown in Fig. 1, the alternate configuration replacing low voltage electrode 115 with four low voltage electrodes 401-404, replacing low voltage electrode 117 with four low voltage electrodes 405-408, replacing high voltage electrode 121 with three high voltage electrodes 409-411 and replacing high voltage electrode 122 with three high voltage electrodes 413-415.
  • FIG. 5 illustrates an alternate embodiment of the system shown in Fig. 1, the alternate configuration replacing tank 101 with a vertically configured cylindrical tank 501.
  • FIG. 6 illustrates an alternate embodiment of the system shown in Fig. 1, the alternate configuration replacing tank 101 with a horizontally configured cylindrical tank 601, replacing membrane 105 with an appropriately shaped membrane 603, replacing low voltage electrodes 115/117 with shaped low voltage electrodes 605/606 and replacing high voltage electrodes 121/122 with shaped high voltage electrodes 607/608.
  • FIG. 7 illustrates an alternate embodiment of the system shown in Fig. 1, the alternate configuration replacing tank 101 with a horizontally configured cylindrical tank 701 which utilizes a lengthwise membrane 703. Additionally, low voltage electrodes 115/117 are replaced with low voltage electrodes 705/706 and high voltage electrodes 121/122 are replaced with high voltage electrodes 707/708.
  • the present electrolysis system can be used to generate hydrogen gas and oxygen gas.
  • the system can also be used to generate electricity, for example by placing a load across the low voltage electrodes.
  • the primary benefit of the present configuration is as a means of generating heat.
  • a cylindrical chamber configured as shown in Fig. 7 was used.
  • the tank was 125 centimeters long with an inside diameter of 44 centimeters and an outside diameter of 50 centimeters.
  • the tank contained 175 liters of water, the water including a potassium hydroxide (KOH) electrolyte at a concentration of 0.1 % by weight.
  • the low voltage electrodes i.e., electrodes 705/706 in Fig. 7, were 75 centimeters by 30 centimeters by 0.5 centimeters and had a separation distance of approximately 10 centimeters.
  • the pulse frequency was maintained at 150 Hz and the pulse duration was initially set to 260 microseconds and gradually lowered to 180 microseconds during the course of a 4 hour run.
  • the low voltage supply was set to 50 volts, drawing a current of between 5.5 and 7.65 amps, and the high voltage supply was set to 910 volts, drawing a current of between 2.15 and 2.48 amps.
  • the initial temperature was 28° C and monitored continuously with a pair of thermocouples, one in each side of the tank. After conclusion of the 4 hour run, the temperature of the tank fluid had increased to 67° C.
  • the inventor has found a direct correlation between the efficiency of the electrolysis apparatus of the invention and electrode size, the power supplied to the electrodes, and the pulse frequency/duration.
  • another test was performed similar to the above test, but replacing the high voltage electrodes with larger electrodes, the larger electrodes measuring 9.5 centimeters by 5 centimeters by 0.5 centimeters.
  • the new high voltage electrodes provided approximately 6.3 times the surface area of the previous high voltage electrodes.
  • the larger electrodes still operating at a voltage of 910 volts, drew a current of between 1.73 and 1.9 amps.
  • the low voltage supply was again set at 50 volts, in this run the low voltage electrodes drawing between 0.6 and 1.25 amps.
  • Fig. 8 illustrates one method of operation requiring minimal optimization.
  • the electrolysis tank is filled with water (step 801).
  • the level of water in the tank preferably just covers the top of the electrodes although the process can also be run with even more water filling the tank.
  • the electrolyte can either be mixed into the water prior to filling the tank or after the tank is filled.
  • the frequency of the pulse generator is then set (step 803) as well as the pulse duration (step 805), the pulse generator controlling the output pulse frequency/ duration for both the high voltage supply and the low voltage supply.
  • the initial voltage settings for the low voltage power supply (e.g., source 119) and the high voltage power supply (e.g., source 123) are also set (step 807), although it will be appreciated that the order of set-up is clearly not critical to the electrolysis process.
  • electrolysis is initiated (step 809) and continues (step 811) until process termination is desired (step 813).
  • Exemplary system configuration parameters that affect the optimal electrolysis settings include tank size, quantity of water, electrolyte composition, electrolyte concentration, pressure, electrode size, electrode composition, electrode shape, electrode separation, low voltage setting, high voltage setting, pulse frequency and pulse duration.
  • Fig. 9 illustrates an alternate procedure appropriate, for example, for use with new, untested system configurations, the approach providing optimization steps.
  • the tank is filled (step 901) and initial settings for pulse frequency (step 903), pulse duration (step 905), high voltage supply output (step 907) and low voltage supply output (step 909) are made.
  • the initial settings are based on previous settings that have been optimized for a similarly configured system. For example, assuming that the new configuration was the same as a previous configuration except for the composition of the electrodes, a reasonable initial set-up would be the optimized set-up from the previous configuration.
  • step 911 electrolysis is initiated (step 911) and the output of the system is monitored (step 913).
  • the rate of temperature increase would be monitored in step 913.
  • System optimization can begin immediately or the system can be allowed to run for an initial period of time (step 915) prior to optimization.
  • step 915 is optional, it is shown in phantom.
  • the initial period of operation can be based on achieving a predetermined temperature or a different criteria can be used. Alternately the initial period of time can simply be a predetermined time period, for example 30 minutes.
  • the system output is monitored (step 917) while optimizing one or more of the operational parameters.
  • the first parameter to be optimized is pulse duration (step 919) followed by the optimization of the pulse frequency (step 920).
  • the voltage of the high voltage supply is optimized (step 921) followed by the optimization of the output voltage of the low voltage supply (step 922).
  • the electrolysis process is allowed to continue (step 923) without further optimization until the process is halted, step 925.
  • optimization steps 919-922 are performed continuously throughout the electrolysis process until electrolysis is suspended. Alternately a subset of steps 919-922 can be performed continuously throughout the electrolysis process.
  • Figs. 9 and 10 The optimization process described relative to Figs. 9 and 10 can be performed manually. In the preferred embodiment, however, the system and the optimization of the system are controlled via computer as illustrated in the block diagram of Fig. 11.
  • computer 1101 receives system performance data from monitor 1103.
  • monitor 1103 can monitor the temperature of the fluid within the tank, thus allowing absolute temperature and the rate of temperature change to be monitored and/ or determined.
  • computer 1101 varies the output of high voltage source 1105, the output of low voltage source 1107 and the frequency and pulse duration generated by pulse generator 1109 in order to optimize the output of the system as previously described.
  • the electrodes are flat and arranged such that the flat electrodes faces are parallel to one another.
  • Fig. 12 is a top, cross-sectional view of the electrode configuration of the system illustrated in Fig. 1. It should be appreciated that such a configuration is not a requirement of the invention.
  • some or all of the electrodes can utilize curved surfaces and/or be arranged in a non-parallel geometry.

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  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
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  • Inorganic Chemistry (AREA)
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Abstract

L'invention concerne un système d'électrolyse (100) et un procédé pour l'utiliser. Outre une cuve électrolytique (101) et une membrane (105) divisant la cuve en deux régions, le système comprend au moins une paire d'électrodes basse tension (115/117) constituées d'un premier matériau et au moins une paire d'électrodes haute tension (121/122) constituées du même premier matériau ou d'un matériau différent. La distance séparant la cathode et l'anode dans chaque paire d'électrodes haute tension est supérieure à la distance séparant la cathode et l'anode dans chaque paire d'électrodes basse tension, lesdites électrodes basse tension de chaque paire étant placées entre la ou les paires d'électrodes haute tension. La basse tension appliquée aux électrodes basse tension et la haute tension appliquée aux électrodes haute tension sont impulsées de manière à ce que les impulsions soient simultanées.
PCT/IB2007/051997 2006-06-09 2007-05-27 Appareil d'électrolyse à deux tensions et procédé d'utilisation Ceased WO2008010108A2 (fr)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US45004206A 2006-06-09 2006-06-09
US11/450,042 2006-06-09
CA002579737A CA2579737A1 (fr) 2006-06-09 2007-02-27 Electrolyseur bi-tension et methode d'utilisation
CA2,579,737 2007-02-27

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WO2008010108A2 true WO2008010108A2 (fr) 2008-01-24
WO2008010108A3 WO2008010108A3 (fr) 2008-05-22

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008146187A1 (fr) * 2007-05-30 2008-12-04 Kuzo Holding Inc. Appareil d'électrolyse pulsée et son procédé d'utilisation
WO2008146188A3 (fr) * 2007-05-30 2009-05-07 Kuzo Holding Inc Contrôleur de vitesse de réaction pour système d'électrolyse et son procédé d'utilisation
WO2010053844A1 (fr) * 2008-11-05 2010-05-14 Pepsico Inc. Champ électrique pulsé haute tension pour un traitement antimicrobien

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FR2570087B1 (fr) * 1984-09-13 1986-11-21 Rhone Poulenc Spec Chim Procede d'oxydation electrolytique et ensemble d'electrolyse pour sa mise en oeuvre
US6638413B1 (en) * 1989-10-10 2003-10-28 Lectro Press, Inc. Methods and apparatus for electrolysis of water
JP2737643B2 (ja) * 1994-03-25 1998-04-08 日本電気株式会社 電解活性水の生成方法および生成装置

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2008146187A1 (fr) * 2007-05-30 2008-12-04 Kuzo Holding Inc. Appareil d'électrolyse pulsée et son procédé d'utilisation
WO2008146188A3 (fr) * 2007-05-30 2009-05-07 Kuzo Holding Inc Contrôleur de vitesse de réaction pour système d'électrolyse et son procédé d'utilisation
WO2010053844A1 (fr) * 2008-11-05 2010-05-14 Pepsico Inc. Champ électrique pulsé haute tension pour un traitement antimicrobien

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