[go: up one dir, main page]

WO2008003729A3 - Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres - Google Patents

Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres Download PDF

Info

Publication number
WO2008003729A3
WO2008003729A3 PCT/EP2007/056779 EP2007056779W WO2008003729A3 WO 2008003729 A3 WO2008003729 A3 WO 2008003729A3 EP 2007056779 W EP2007056779 W EP 2007056779W WO 2008003729 A3 WO2008003729 A3 WO 2008003729A3
Authority
WO
WIPO (PCT)
Prior art keywords
derivatives
free
preparation
aqueous dispersion
radical polymerization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/EP2007/056779
Other languages
English (en)
Other versions
WO2008003729A2 (fr
Inventor
Patrick Lacroix-Desmazes
Jeff Tonnar
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ecole Nationale Superieure de Chimie de Montpellier ENSCM
Original Assignee
Ecole Nationale Superieure de Chimie de Montpellier ENSCM
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ecole Nationale Superieure de Chimie de Montpellier ENSCM filed Critical Ecole Nationale Superieure de Chimie de Montpellier ENSCM
Priority to EP07787075A priority Critical patent/EP2049573A2/fr
Priority to MX2008016485A priority patent/MX2008016485A/es
Priority to US12/308,977 priority patent/US20090306302A1/en
Publication of WO2008003729A2 publication Critical patent/WO2008003729A2/fr
Publication of WO2008003729A3 publication Critical patent/WO2008003729A3/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/18—Suspension polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/38—Polymerisation using regulators, e.g. chain terminating agents, e.g. telomerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F214/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen
    • C08F214/02—Monomers containing chlorine
    • C08F214/04—Monomers containing two carbon atoms
    • C08F214/06—Vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/04—Azo-compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/40—Redox systems
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Graft Or Block Polymers (AREA)
  • Polymerisation Methods In General (AREA)

Abstract

Procédé de polymérisation radicalaire en dispersion aqueuse pour la préparation de polymères mettant en oeuvre (A) au moins un monomère éthyléniquement insaturé dont l'un d'entre eux est mis en oeuvre à titre de monomère principal et est choisi parmi le styrène et ses dérivés, l'acide acrylique et ses dérivés, l'acide méthacrylique et ses dérivés, les diéniques, les esters vinyliques, les éthers vinyliques, les dérivés vinyliques de la pyridine, l'acide vinylsulphonique et ses dérivés, l'acide vinylphosphonique et ses dérivés et les monomères N-vinyliques, (B) au moins un agent générateur de radicaux choisis parmi les diazocomposés, les peroxydes et les dialkyldiphénylalcanes, (C) de l'iode moléculaire, et (D) au moins un oxydant dont la solubilité dans l'eau est d'au moins 10 g/l dont au moins un peut être l'un de (B); qui comprend les étapes selon lesquelles (1) on introduit dans un réacteur au moins une fraction de chacun des composés (A), (B), (C) et (D); et (2) on fait réagir le contenu du réacteur, tout en y introduisant le solde éventuel de chacun des composés (A), (B), (C) et (D). Procédé de polymérisation radicalaire en dispersion aqueuse pour la préparation de copolymères à blocs au départ de polymères préparés par le procédé susmentionné.
PCT/EP2007/056779 2006-07-04 2007-07-04 Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres Ceased WO2008003729A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
EP07787075A EP2049573A2 (fr) 2006-07-04 2007-07-04 Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres
MX2008016485A MX2008016485A (es) 2006-07-04 2007-07-04 Procedimiento de polimerización por radicales libres en dispersión acuosa para la preparación de polímeros.
US12/308,977 US20090306302A1 (en) 2006-07-04 2007-07-04 Process of free-radical polymerization in aqueous disperasion for the preparation of polymers

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
FR0606079A FR2903409A1 (fr) 2006-07-04 2006-07-04 Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres
FR0606079 2006-07-04
US81827606P 2006-07-05 2006-07-05
US60/818,276 2006-07-05

Publications (2)

Publication Number Publication Date
WO2008003729A2 WO2008003729A2 (fr) 2008-01-10
WO2008003729A3 true WO2008003729A3 (fr) 2008-05-08

Family

ID=37719193

Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/EP2007/056778 Ceased WO2008003728A1 (fr) 2006-07-04 2007-07-04 Procédé de polymérisation radicalaire dans une dispersion aqueuse permettant la préparation d'un copolymère séquencé comprenant au moins une séquence de polymère halogéné
PCT/EP2007/056779 Ceased WO2008003729A2 (fr) 2006-07-04 2007-07-04 Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres

Family Applications Before (1)

Application Number Title Priority Date Filing Date
PCT/EP2007/056778 Ceased WO2008003728A1 (fr) 2006-07-04 2007-07-04 Procédé de polymérisation radicalaire dans une dispersion aqueuse permettant la préparation d'un copolymère séquencé comprenant au moins une séquence de polymère halogéné

Country Status (6)

Country Link
US (2) US8541524B2 (fr)
EP (2) EP2049573A2 (fr)
JP (1) JP5201419B2 (fr)
FR (1) FR2903409A1 (fr)
MX (1) MX2008016485A (fr)
WO (2) WO2008003728A1 (fr)

Families Citing this family (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7741524B2 (en) 2003-04-22 2010-06-22 Solvay (Societe Anonyme) Iodinated organic substances of low molecular mass and process for preparing them
FR2903409A1 (fr) * 2006-07-04 2008-01-11 Solvay Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres
DE102008054482A1 (de) * 2008-12-10 2010-06-17 Wacker Chemie Ag Pfropfcopolymere und deren Verwendung als Low-Profile-Additive
JP2013018953A (ja) * 2011-06-15 2013-01-31 Canon Inc 高分子粒子の製造方法
KR101507999B1 (ko) 2011-08-03 2015-04-07 인하대학교 산학협력단 Ｒｉｔｐ 중합법과 용액 재결정법을 이용한 안정화된 단분산 구형 고분자 입자의 제조 방법
EP2794695B1 (fr) * 2011-12-21 2016-03-16 Solvay Sa Procédé de préparation d'un polymère de chlorure de vinylidène
US9394394B2 (en) * 2013-09-30 2016-07-19 Honeywell International Inc. Synthesis of chlorotrifluoroethylene-based block copolymers by iodine transfer polymerization
FR3053970A1 (fr) 2016-07-13 2018-01-19 Centre National De La Recherche Scientifique (Cnrs) Procede de synthese d'une polyolefine par romp en presence d'un catalyseur a base de ruthenium
US11180665B2 (en) 2020-02-21 2021-11-23 Swimc Llc Stain-blocking polymers, primers, kits, and methods
CN117715885A (zh) 2021-07-30 2024-03-15 巴斯夫欧洲公司 组合物及其在受控活性水基乳液聚合中的应用
CN119463072B (zh) * 2024-11-11 2025-12-09 苏州大学 一种基于光控原位溴-碘转换可逆-失活自由基聚合法制备星形嵌段共聚物的方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040054108A1 (en) * 2002-07-23 2004-03-18 Mestach Dirk Emiel Paula Method for polymerizing ethylenically unsaturated monomers by degenerative iodine transfer
FR2858319A1 (fr) * 2003-08-01 2005-02-04 Solvay Procede de preparation de substances organiques iodees de faible masse moleculaire et substances organiques iodees de faible masse moleculaire
WO2007085623A1 (fr) * 2006-01-26 2007-08-02 Rhodia Operations Procede de preparation par polymerisation par transfert d'iode d'un copolymere a architecture controlee de type telomere ou de copolymere a bloc issu de monomeres vinyl phosphonate

Family Cites Families (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3467636A (en) 1967-02-24 1969-09-16 Du Pont Redox catalyst system for preparing vinylidene fluoride interpolymers
LU73211A1 (fr) 1975-08-18 1977-04-15
JPS5386787A (en) * 1977-09-30 1978-07-31 Daikin Ind Ltd Polymer having fluorine-containing segment and its production
JPS63260914A (ja) * 1987-04-17 1988-10-27 Nippon Mektron Ltd ブロツク共重合体の製造方法
BE1007648A3 (fr) 1993-10-21 1995-09-05 Solvay Procede pour la polymerisation radicalaire du chlorure de vinyle a ph acide en dispersion aqueuse.
EP1026152B1 (fr) * 1997-03-31 2006-07-26 Daikin Industries, Limited Procede de production de derives d'acide ethersulfonique de perfluorovinyle
EP0947527A1 (fr) 1998-04-03 1999-10-06 The B.F. Goodrich Company Copolymères à blocs au milieu aqueux et un procédé pour leur production
US6911515B2 (en) 2001-03-23 2005-06-28 University Of Pennsylvania Aqueous room temperature living radical polymerization of vinyl halides
FR2826658B1 (fr) * 2001-06-29 2003-09-05 Rhodia Chimie Sa Synthese de polymeres par voie radicalaire controlee en miniemulsion
FR2839724B1 (fr) * 2002-05-17 2005-08-05 Solvay Procedes de polymerisation radicalaire pour preparer des polymeres halogenes et polymeres halogenes
FR2839725A1 (fr) * 2002-05-17 2003-11-21 Solvay Polymeres alpha-fluoroacryliques a faible indice de polydispersite, procede pour les synthetiser et procede de fabrication d'articles les mettant en oeuvre
US7741524B2 (en) 2003-04-22 2010-06-22 Solvay (Societe Anonyme) Iodinated organic substances of low molecular mass and process for preparing them
JP2006524215A (ja) * 2003-04-22 2006-10-26 ソルヴェイ 低分子量のヨウ素化有機物質及びその調製方法
FR2903409A1 (fr) * 2006-07-04 2008-01-11 Solvay Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres
EP2158237B1 (fr) * 2007-06-21 2012-10-24 DSM IP Assets B.V. Procédé permettant d'obtenir de faibles niveaux de monomères libres dans une émulsion de copolymère séquencé préparée par polymérisation par transfert d'iode (inverse)

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040054108A1 (en) * 2002-07-23 2004-03-18 Mestach Dirk Emiel Paula Method for polymerizing ethylenically unsaturated monomers by degenerative iodine transfer
FR2858319A1 (fr) * 2003-08-01 2005-02-04 Solvay Procede de preparation de substances organiques iodees de faible masse moleculaire et substances organiques iodees de faible masse moleculaire
WO2007085623A1 (fr) * 2006-01-26 2007-08-02 Rhodia Operations Procede de preparation par polymerisation par transfert d'iode d'un copolymere a architecture controlee de type telomere ou de copolymere a bloc issu de monomeres vinyl phosphonate

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP2049573A2 *

Also Published As

Publication number Publication date
WO2008003728A1 (fr) 2008-01-10
US20090292071A1 (en) 2009-11-26
MX2008016485A (es) 2009-02-25
FR2903409A1 (fr) 2008-01-11
EP2041185B1 (fr) 2019-01-09
EP2049573A2 (fr) 2009-04-22
JP5201419B2 (ja) 2013-06-05
EP2041185A1 (fr) 2009-04-01
JP2009541567A (ja) 2009-11-26
WO2008003729A2 (fr) 2008-01-10
US8541524B2 (en) 2013-09-24
US20090306302A1 (en) 2009-12-10

Similar Documents

Publication Publication Date Title
WO2008003729A3 (fr) Procede de polymerisation radicalaire en dispersion aqueuse pour la preparation de polymeres
AU749553B2 (en) Solubilized hydrophobically-modified alkali-soluble emulsion polymers
WO2008071649A3 (fr) Microcapsules
MX2007014024A (es) Uso de mezclas polimericas para la produccion de formulaciones farmaceuticas recubiertas y formulacion farmaceutica con recubrimiento polimerico mezclado.
EP3599258B1 (fr) Procédé de fabrication d'aérogels polymériques sans couleur, à haute porosité et transparents
WO2008078055A3 (fr) Copolymeres a base d'unites methacrylates, leur procede de preparation et leurs utilisations
US5399621A (en) Process for the preparation of a graft copolymer latex of core/shell dispersion particles having improved phase binding between core and shell
MY146025A (en) Polymerisation process and polymer product
WO2007078819A3 (fr) Procedes de fabrication d’un copolymere sequence a faible energie de surface et applications
US6696519B2 (en) Redox process for preparing emulsion polymer having low residual monomer content
JP2011523944A5 (fr)
DE50015884D1 (de) Verfahren zur Herstellung von Vinylester-(Meth)acrylsäureester-Mischpolymerisaten
EP2045277A3 (fr) Procédé de polymérisation radicalaire pour préparer des copolymères à blocs et copolymères à blocs
CA2395914C (fr) Latex ayant un haut extrait sec, une faible viscosite et presentant une distribution bimodale
PL2074183T3 (pl) Wodne kompozycje dodatku zawierające krzemian warstwowy
JP2009300719A5 (fr)
CN102167754A (zh) 双硫杂蒽二醇及其衍生物为引发剂的活性自由基聚合方法
JP2002265504A5 (fr)
JPH0684409B2 (ja) 耐熱性熱可塑性樹脂の製造方法
WO2009041693A1 (fr) Copolymère pour polyglutarimide et procédé pour le produire
JPS60206810A (ja) 共重合体の製法
JP5198263B2 (ja) 高比粘度の無水マレイン酸及びアルキルビニルエーテルの共重合体を製造する方法
DE602006020718D1 (de) Polymerdispersion in einem reaktiven organischen medium, verfahren zu ihrer herstellung sowie verwendungen
JPH07278212A (ja) 水性エマルジョンの製造方法
JP5042520B2 (ja) ポリビニルアルコール系重合体およびその製造方法

Legal Events

Date Code Title Description
121 Ep: the epo has been informed by wipo that ep was designated in this application

Ref document number: 07787075

Country of ref document: EP

Kind code of ref document: A2

WWE Wipo information: entry into national phase

Ref document number: MX/A/2008/016485

Country of ref document: MX

WWE Wipo information: entry into national phase

Ref document number: 12308977

Country of ref document: US

NENP Non-entry into the national phase

Ref country code: DE

WWE Wipo information: entry into national phase

Ref document number: 2007787075

Country of ref document: EP

NENP Non-entry into the national phase

Ref country code: RU