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WO2008081898A1 - Method for regeneration of strongly basic anion exchange resin - Google Patents

Method for regeneration of strongly basic anion exchange resin Download PDF

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Publication number
WO2008081898A1
WO2008081898A1 PCT/JP2007/075191 JP2007075191W WO2008081898A1 WO 2008081898 A1 WO2008081898 A1 WO 2008081898A1 JP 2007075191 W JP2007075191 W JP 2007075191W WO 2008081898 A1 WO2008081898 A1 WO 2008081898A1
Authority
WO
WIPO (PCT)
Prior art keywords
anion exchange
exchange resin
strongly basic
basic anion
resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2007/075191
Other languages
French (fr)
Japanese (ja)
Inventor
Toshikuni Yonemoto
Naomi Kitagawa
Hiroaki Takayanagi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Tohoku Techno Arch Co Ltd
Original Assignee
Mitsubishi Chemical Corp
Tohoku Techno Arch Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corp, Tohoku Techno Arch Co Ltd filed Critical Mitsubishi Chemical Corp
Publication of WO2008081898A1 publication Critical patent/WO2008081898A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C67/00—Preparation of carboxylic acid esters
    • C07C67/03—Preparation of carboxylic acid esters by reacting an ester group with a hydroxy group
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/06—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing polymers
    • B01J31/08—Ion-exchange resins
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11C—FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM
    • C11C3/00—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom
    • C11C3/003—Fats, oils, or fatty acids by chemical modification of fats, oils, or fatty acids obtained therefrom by esterification of fatty acids with alcohols
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00—Technologies for the production of fuel of non-fossil origin
    • Y02E50/10—Biofuels, e.g. bio-diesel

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Catalysts (AREA)
  • Fats And Perfumes (AREA)

Abstract

Disclosed is a method for regenerating the catalytic activity of a given strongly basic anion exchange resin to a satisfactory level after the resin is used in the production of a fatty acid ester for a biodiesel fuel. When the strongly basic anion exchange resin has a tertiary amine having a pKa value of 9.8 or less bound chemically to an insoluble carrier, the resin which has been used in the production of a fatty acid ester for a biodiesel fuel is washed with a weakly acidic solution, subjected to the replacement of a counter ion with an aqueous alkaline solution, and swelled with a solvent.
PCT/JP2007/075191 2006-12-28 2007-12-27 Method for regeneration of strongly basic anion exchange resin Ceased WO2008081898A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2006-355941 2006-12-28
JP2006355941 2006-12-28

Publications (1)

Publication Number Publication Date
WO2008081898A1 true WO2008081898A1 (en) 2008-07-10

Family

ID=39588580

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2007/075191 Ceased WO2008081898A1 (en) 2006-12-28 2007-12-27 Method for regeneration of strongly basic anion exchange resin

Country Status (2)

Country Link
JP (1) JP2008178871A (en)
WO (1) WO2008081898A1 (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102816645A (en) * 2012-09-14 2012-12-12 天津工业大学 Continuous preparation method of biodiesel
JP2016059833A (en) * 2014-09-16 2016-04-25 国立大学法人東北大学 Regeneration treatment of anion exchange resin catalyst for continuous production of fatty acid ester
CN111229192A (en) * 2020-03-27 2020-06-05 江苏中有信科技有限公司 Macroporous resin cleaning and recycling process and device
CN119638878A (en) * 2025-02-13 2025-03-18 富海(东营)技术服务有限公司 Alcoholysis method of EVA

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2009191205A (en) * 2008-02-15 2009-08-27 Tohoku Techno Arch Co Ltd Fatty acid ester production method and fatty acid ester production apparatus
JP6109475B2 (en) * 2008-11-28 2017-04-05 テラヴィア ホールディングス， インコーポレイテッド Production of oil according to use in heterotrophic microorganisms
SG185781A1 (en) 2010-05-28 2013-01-30 Solazyme Inc Food compositions comprising tailored oils
SG10201509035WA (en) 2010-11-03 2015-12-30 Solazyme Inc Microbial Oils With Lowered Pour Points, Dielectric Fluids Produced Therefrom, And Related Methods
CN103827307A (en) 2011-02-02 2014-05-28 索拉兹米公司 Custom oils produced from recombinant oleaginous microorganisms
EP3550025A1 (en) 2012-04-18 2019-10-09 Corbion Biotech, Inc. Tailored oils
SG10201802834YA (en) 2013-10-04 2018-05-30 Terravia Holdings Inc Tailored oils
ES2764273T3 (en) 2014-07-10 2020-06-02 Corbion Biotech Inc Novel Ketoacyl ACP Synthase Genes and Their Use

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS57187042A (en) * 1981-05-15 1982-11-17 Nippon Petrochem Co Ltd Regeneration method for ion exchange resin
JPS62215549A (en) * 1986-03-14 1987-09-22 Nisshin Oil Mills Ltd:The Production of fatty acid ester
JPH066718B2 (en) * 1986-03-19 1994-01-26 日清製油株式会社 Method for producing fatty acid ester
JP4502096B2 (en) * 2000-09-29 2010-07-14 三菱瓦斯化学株式会社 Regeneration method of strongly basic anion exchange resin
ES2432042T3 (en) * 2004-07-02 2013-11-29 Mitsui Chemicals, Inc. Modified ion exchange resin and procedure to produce bisphenols

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
"12996 no Kagaku Shohin", CHEMICAL INDUSTRIAL DAILY REPORT CORPORATION EDITION, THE CHEMICAL DAILY CO., LTD., 24 January 1996 (1996-01-24), pages 927 - 930, XP003018062 *
SHIBASAKI-KITAKAWA ET AL.: "Biodiesel production using anionic ion-exchange resin as heterogeneous catalyst", BIORESOURCE TECHNOLOGY, vol. 98, no. 2, 1 January 2007 (2007-01-01), pages 416 - 421, XP005645234 *
THE SOCIETY OF POLYMER SCIENCE, JAPAN: "Kobunshi Shin Sozai Binran, 2nd print", 10 March 1995, MARUZEN CO., LTD., pages: 206 - 212 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102816645A (en) * 2012-09-14 2012-12-12 天津工业大学 Continuous preparation method of biodiesel
JP2016059833A (en) * 2014-09-16 2016-04-25 国立大学法人東北大学 Regeneration treatment of anion exchange resin catalyst for continuous production of fatty acid ester
CN111229192A (en) * 2020-03-27 2020-06-05 江苏中有信科技有限公司 Macroporous resin cleaning and recycling process and device
CN119638878A (en) * 2025-02-13 2025-03-18 富海(东营)技术服务有限公司 Alcoholysis method of EVA

Also Published As

Publication number Publication date
JP2008178871A (en) 2008-08-07

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