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WO2007011981A1 - Composition de perfluoropolymere additionnee d'une charge comprenant un additif fluoropolymere a point de fusion bas - Google Patents

Composition de perfluoropolymere additionnee d'une charge comprenant un additif fluoropolymere a point de fusion bas Download PDF

Info

Publication number
WO2007011981A1
WO2007011981A1 PCT/US2006/027965 US2006027965W WO2007011981A1 WO 2007011981 A1 WO2007011981 A1 WO 2007011981A1 US 2006027965 W US2006027965 W US 2006027965W WO 2007011981 A1 WO2007011981 A1 WO 2007011981A1
Authority
WO
WIPO (PCT)
Prior art keywords
composition
agent
melt
perfluoropolymer
char
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2006/027965
Other languages
English (en)
Inventor
Yevgeniy I. Globus
Mark A. Jozokos
Sundar Kilnagar Venkataraman
Heidi Elizabeth Burch
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
AlphaGary Corp
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
AlphaGary Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by EI Du Pont de Nemours and Co, AlphaGary Corp filed Critical EI Du Pont de Nemours and Co
Priority to EP06787806A priority Critical patent/EP1904563B1/fr
Priority to CA002614607A priority patent/CA2614607A1/fr
Priority to JP2008522914A priority patent/JP2009501839A/ja
Priority to DE602006012679T priority patent/DE602006012679D1/de
Priority to CN2006800264126A priority patent/CN101248125B/zh
Publication of WO2007011981A1 publication Critical patent/WO2007011981A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/12—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
    • C08L27/18—Homopolymers or copolymers or tetrafluoroethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/16—Solid spheres
    • C08K7/18—Solid spheres inorganic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group

Definitions

  • the ability of the composition of the present invention to pass the NFPA-255 burn test is demonstrated by melt- fabricating an article from the composition and subjecting that article to the burn test.
  • the composition of the present invention is especially useful as cable jacket for plenum cable, the jacket being formed by extrusion over and onto the core of the cable.
  • the jacket composition of the present invention can be considered to pass the NFPA-255 burn test when the entire cable is subjected to the test and passes the test. This is confirmed by substituting a jacket such as a polyvinyl chloride composition over the same cable core, and the cable fails the burn test because the jacket does not pass this test.
  • the jacket of the composition of the present invention when responsible for the cable passing the test, the jacket itself can be considered to pass the burn test.
  • the volume resistivity of a composition which incorporates a low melting fluoropolymer additive is higher, actually much higher, than with a hydrocarbon polymer additive present.
  • the composition of the present invention therefore also exhibits improved electrical performance, notably reduced conductivity as cable jacket, as compared to the perfluoropolymer/char forming agent composition wherein hydrocarbon polymer is present to improve physical properties of the bicomponent composition. This improvement is especially useful in a cable jacket wherein the cable is coaxial cable.
  • the char-forming agent contributes to formation of a char structure that prevents the total composition from dripping, which would lead to objectionable smoke formation and failure of the burn test. It is unexpected that char-forming agent would have any utility when used with non-flammable perfluoropolymer. Although the perfluoropolymer does not burn, it appears that the char-forming agent interacts with the perfluoropolymer during the burn test to prevent the high MFR perfluoropolymer from dripping, whereby the creation of smoke is suppressed. Although the combination of the perfluoropolymer and char- forming agent is melt flowable (extrudable), which suggests that the composition would drip when subjected to burning, the composition does not drip.
  • the fluoropolymer additive is used in the composition of the present invention in an amount that is effective to provide the physical properties desired.
  • the fluoropolymer additive itself does not provide the improved physical properties. Instead, the fluoropolymer additive interacts with the char-forming agent and perfluoropolymer to limit the reduction in tensile properties that the agent if used by itself would have on the perfluoropolymer composition. Without the presence of the fluoropolymer additive, the melt blend of the perfluoropolymer/char-forming agent tends to be cheesy in appearance, i.e. to lack integrity, e.g. showing cracks and containing loose, unincorporated agent.
  • Additional support for the cables is provided by steel poultry netting (chicken wire), the poultry netting laying on the metal rods and the cable laying on the poultry netting, as set forth in Appendix B-7.2.
  • a large number of cables, each 25 ft (7.6 m) long, are laid side-by-side on the poultry netting as described above.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

La présente invention concerne des câbles pour vide technique gainés au moyen d'une composition comprenant un perfluoropolymère, un agent inorganique formant un produit de carbonisation et un additif fluoropolymère, cette composition passant l'essai de combustion NFPA-255.
PCT/US2006/027965 2005-07-18 2006-07-18 Composition de perfluoropolymere additionnee d'une charge comprenant un additif fluoropolymere a point de fusion bas Ceased WO2007011981A1 (fr)

Priority Applications (5)

Application Number Priority Date Filing Date Title
EP06787806A EP1904563B1 (fr) 2005-07-18 2006-07-18 Composition de perfluoropolymere additionnee d'une charge comprenant un additif fluoropolymere a point de fusion bas
CA002614607A CA2614607A1 (fr) 2005-07-18 2006-07-18 Composition de perfluoropolymere additionnee d'une charge comprenant un additif fluoropolymere a point de fusion bas
JP2008522914A JP2009501839A (ja) 2005-07-18 2006-07-18 低融点フルオロポリマー添加剤を含む充填パーフルオロポリマー組成物
DE602006012679T DE602006012679D1 (de) 2005-07-18 2006-07-18 Gefüllte perfluorpolymerzusammensetzung mit niedrigschmelzendem fluorpolymerzusatz
CN2006800264126A CN101248125B (zh) 2005-07-18 2006-07-18 包含低熔点含氟聚合物添加剂的填充全氟聚合物组合物

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US70016705P 2005-07-18 2005-07-18
US60/700,167 2005-07-18

Publications (1)

Publication Number Publication Date
WO2007011981A1 true WO2007011981A1 (fr) 2007-01-25

Family

ID=37310768

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/027965 Ceased WO2007011981A1 (fr) 2005-07-18 2006-07-18 Composition de perfluoropolymere additionnee d'une charge comprenant un additif fluoropolymere a point de fusion bas

Country Status (7)

Country Link
US (1) US7683130B2 (fr)
EP (1) EP1904563B1 (fr)
JP (1) JP2009501839A (fr)
CN (1) CN101248125B (fr)
CA (1) CA2614607A1 (fr)
DE (1) DE602006012679D1 (fr)
WO (1) WO2007011981A1 (fr)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20070015875A1 (en) * 2005-07-18 2007-01-18 Globus Yevgeniy I Foamed article comprising filled perfluoropolymer composition
US7625974B2 (en) * 2005-09-30 2009-12-01 Alphagary Corporation Highly filled unsaturated fluoropolymer compositions for cables
JP5131202B2 (ja) * 2007-02-16 2013-01-30 ダイキン工業株式会社 フッ素樹脂組成物、フッ素樹脂成形品及びその製造方法
US20120030122A1 (en) * 2010-07-27 2012-02-02 Sap Ag Agile workflow modeling and execution based on document
US8835765B2 (en) 2010-07-30 2014-09-16 Nexans FEP modification using titanium dioxide to reduce skew in data communications cables
BR112016004218B1 (pt) * 2013-08-30 2021-01-19 Arkema Inc. combinação compósita fluoropolimérica, processo para formar a referida combinação e artigo compreendendo a mesma
CN103740012A (zh) * 2014-01-10 2014-04-23 长园电子（集团）有限公司 一种耐低温氟橡胶热收缩套管及其制备方法
KR102357451B1 (ko) * 2016-04-28 2022-01-28 에이지씨 가부시키가이샤 피복 전선
CN116836497A (zh) * 2023-07-12 2023-10-03 广东祥利特种材料科技有限公司 一种充电桩用热塑性弹性体电缆料

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997036954A1 (fr) * 1996-03-30 1997-10-09 W.L. Gore & Associates (Uk) Ltd. Dispersions en polytetrafluoroethylene de type granulaire et articles fondus produits a partir de celles-ci
WO1999011706A2 (fr) * 1997-09-05 1999-03-11 Chemfab Corporation Composition polymere fluoree perfectionnee
WO2000008346A1 (fr) * 1998-08-07 2000-02-17 Dana Corporation Materiau pour coussinets
WO2005073984A1 (fr) * 2004-01-23 2005-08-11 E.I. Dupont De Nemours And Company Perfluoropolymeres garnis
EP1591469A1 (fr) * 2004-03-30 2005-11-02 Carl Freudenberg KG Compositions élastomériques à base de mélanges de polymères fluorés

Family Cites Families (22)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS495446A (fr) * 1972-05-08 1974-01-18
JPS6023702B2 (ja) * 1976-02-17 1985-06-08 ダイキン工業株式会社 成形性の改良されたフツ素樹脂組成物
US4520170A (en) * 1982-09-20 1985-05-28 E. I. Du Pont De Nemours And Company Method for reinforcing perfluoroelastomer compositions
JPS59193947A (ja) * 1983-04-19 1984-11-02 Ishikawajima Harima Heavy Ind Co Ltd 酸素中における難燃性樹脂
US4624990A (en) * 1983-10-07 1986-11-25 Raychem Corporation Melt-shapeable fluoropolymer compositions
US4963609A (en) * 1989-11-01 1990-10-16 E. I. Du Pont De Nemours And Company Low smoke and flame-resistant composition
US5547761A (en) * 1992-08-28 1996-08-20 E. I. Du Pont De Nemours And Company Low melting tetrafluoroethylene copolymer and its uses
US5543217A (en) * 1995-02-06 1996-08-06 E. I. Du Pont De Nemours And Company Amorphous copolymers of tetrafluoroethylene and hexafluoropropylene
US5677404A (en) * 1996-02-23 1997-10-14 E. I. Du Pont De Nemours And Company Tetrafluoroethylene terpolymer
US5919878A (en) * 1996-09-13 1999-07-06 E. I. Du Pont De Nemours And Company Amorphous fluoropolymer containing perfluoro(ethyl vinyl ether)
EP0897410A4 (fr) * 1997-02-28 2000-07-12 Atochem North America Elf Copolymeres de fluorure de vinylidene et d'hexafluoropropylene presentant une teneur en constituants extractibles reduite et une transparence de solution amelioree
EP0891997A1 (fr) * 1997-07-15 1999-01-20 E.I. Du Pont De Nemours And Company Compositions de polymères fluorés et procédé de fabrication
US5888424A (en) * 1997-07-24 1999-03-30 E. I. Du Pont De Nemours And Company Fluorescent fluoroplastics
US6197904B1 (en) * 1998-02-26 2001-03-06 E. I. Du Pont De Nemours And Company Low-melting tetrafluoroethylene copolymer
EP1209176A4 (fr) * 1999-06-30 2002-09-18 Daikin Ind Ltd Materiau compose fluore souple, resistant a la chaleur et non collant
ATE313598T1 (de) * 1999-09-30 2006-01-15 Daikin Ind Ltd Transparente elastomerzusammensetzung
DE10033514A1 (de) * 2000-07-11 2002-02-07 Dyneon Gmbh FEP mit erhöhter Wechselbiegefestigkeit und geringen Düsenablagerungen
US6468280B1 (en) * 2000-07-24 2002-10-22 Sulzer Orthopedics Inc. Unicompartmental replacement instrument and method
JP4458658B2 (ja) * 2000-12-06 2010-04-28 三井・デュポンフロロケミカル株式会社 熱溶融性フッ素樹脂組成物
JP5268255B2 (ja) * 2003-11-21 2013-08-21 エイエヌピー テクノロジーズ， インコーポレイテッド 非対称分岐ポリマー抱合体およびマイクロアレイアッセイ
JP2006096968A (ja) * 2004-09-03 2006-04-13 Daikin Ind Ltd 電線ジャケット用材料及び電線ジャケット
US20070015875A1 (en) * 2005-07-18 2007-01-18 Globus Yevgeniy I Foamed article comprising filled perfluoropolymer composition

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997036954A1 (fr) * 1996-03-30 1997-10-09 W.L. Gore & Associates (Uk) Ltd. Dispersions en polytetrafluoroethylene de type granulaire et articles fondus produits a partir de celles-ci
WO1999011706A2 (fr) * 1997-09-05 1999-03-11 Chemfab Corporation Composition polymere fluoree perfectionnee
WO2000008346A1 (fr) * 1998-08-07 2000-02-17 Dana Corporation Materiau pour coussinets
WO2005073984A1 (fr) * 2004-01-23 2005-08-11 E.I. Dupont De Nemours And Company Perfluoropolymeres garnis
EP1591469A1 (fr) * 2004-03-30 2005-11-02 Carl Freudenberg KG Compositions élastomériques à base de mélanges de polymères fluorés

Also Published As

Publication number Publication date
CN101248125B (zh) 2011-07-27
JP2009501839A (ja) 2009-01-22
US20070015874A1 (en) 2007-01-18
CA2614607A1 (fr) 2007-01-25
EP1904563B1 (fr) 2010-03-03
US7683130B2 (en) 2010-03-23
EP1904563A1 (fr) 2008-04-02
CN101248125A (zh) 2008-08-20
DE602006012679D1 (de) 2010-04-15

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