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WO2007087099A3 - Method of removing scale and acidic composition used thereof - Google Patents

Method of removing scale and acidic composition used thereof Download PDF

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Publication number
WO2007087099A3
WO2007087099A3 PCT/US2006/062023 US2006062023W WO2007087099A3 WO 2007087099 A3 WO2007087099 A3 WO 2007087099A3 US 2006062023 W US2006062023 W US 2006062023W WO 2007087099 A3 WO2007087099 A3 WO 2007087099A3
Authority
WO
WIPO (PCT)
Prior art keywords
composition used
acidic composition
removing scale
addition
urea
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2006/062023
Other languages
French (fr)
Other versions
WO2007087099A2 (en
Inventor
James C Emerson
Lyle H Steimel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Diversey Inc
Original Assignee
JohnsonDiversey Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JohnsonDiversey Inc filed Critical JohnsonDiversey Inc
Priority to MX2008009193A priority Critical patent/MX2008009193A/en
Priority to CA002637314A priority patent/CA2637314A1/en
Publication of WO2007087099A2 publication Critical patent/WO2007087099A2/en
Publication of WO2007087099A3 publication Critical patent/WO2007087099A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F14/00—Inhibiting incrustation in apparatus for heating liquids for physical or chemical purposes
    • C23F14/02—Inhibiting incrustation in apparatus for heating liquids for physical or chemical purposes by chemical means
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/086—Condensed phosphates
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F5/00—Softening water; Preventing scale; Adding scale preventatives or scale removers to water, e.g. adding sequestering agents
    • C02F5/08—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents
    • C02F5/10—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances
    • C02F5/12—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen
    • C02F5/125—Treatment of water with complexing chemicals or other solubilising agents for softening, scale prevention or scale removal, e.g. adding sequestering agents using organic substances containing nitrogen combined with inorganic substances
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/14—Nitrogen-containing compounds
    • C23F11/141—Amines; Quaternary ammonium compounds
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/14—Nitrogen-containing compounds
    • C23F11/145—Amides; N-substituted amides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F11/00—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent
    • C23F11/08—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids
    • C23F11/10—Inhibiting corrosion of metallic material by applying inhibitors to the surface in danger of corrosion or adding them to the corrosive agent in other liquids using organic inhibitors
    • C23F11/14—Nitrogen-containing compounds
    • C23F11/149—Heterocyclic compounds containing nitrogen as hetero atom
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/04—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors
    • C23G1/06—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors
    • C23G1/061—Cleaning or pickling metallic material with solutions or molten salts with acid solutions using inhibitors organic inhibitors nitrogen-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
    • C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
    • C23G1/02—Cleaning or pickling metallic material with solutions or molten salts with acid solutions
    • C23G1/10—Other heavy metals
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00—Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/02—Non-contaminated water, e.g. for industrial water supply
    • C02F2103/023—Water in cooling circuits
    • C—CHEMISTRY; METALLURGY
    • C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00—Specific treatment goals
    • C02F2303/08—Corrosion inhibition

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Inorganic Chemistry (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
  • Detergent Compositions (AREA)

Abstract

The corrosion inhibiting activity of quaternary ammonium compounds is enhanced by the addition of a carbamide, specifically urea, in particular, the aryfquinoiinium halide corrosion inhibitor's activity with respect to a galvanized surface is significantly enhanced by the addition of the urea.
PCT/US2006/062023 2006-01-17 2006-12-13 Method of removing scale and acidic composition used thereof Ceased WO2007087099A2 (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
MX2008009193A MX2008009193A (en) 2006-01-17 2006-12-13 Method of removing scale and acidic composition used thereof.
CA002637314A CA2637314A1 (en) 2006-01-17 2006-12-13 Method of removing scale and acidic composition used thereof

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US11/333,155 2006-01-17
US11/333,155 US20070164258A1 (en) 2006-01-17 2006-01-17 Enhanced galvanized corrosion inhibitor

Publications (2)

Publication Number Publication Date
WO2007087099A2 WO2007087099A2 (en) 2007-08-02
WO2007087099A3 true WO2007087099A3 (en) 2008-02-21

Family

ID=37831842

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2006/062023 Ceased WO2007087099A2 (en) 2006-01-17 2006-12-13 Method of removing scale and acidic composition used thereof

Country Status (4)

Country Link
US (1) US20070164258A1 (en)
CA (1) CA2637314A1 (en)
MX (1) MX2008009193A (en)
WO (1) WO2007087099A2 (en)

Families Citing this family (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2939146B1 (en) 2008-11-28 2012-11-16 Arkema France USE OF ALKANE SULFONIC ACID FOR RUST REMOVAL
ES2708173T3 (en) 2009-06-25 2019-04-09 Henkel Ag & Co Kgaa Formulation of metal loss inhibitor and processes
SI2348142T1 (en) * 2010-01-25 2019-03-29 Westinghouse Electric Company Llc Method and composition for removing scale deposits formed on a metal surface within a steam generating system
CA2788177C (en) 2010-01-26 2020-04-28 Dominion Engineering, Inc. Method and composition for removing deposits
CN101892489B (en) * 2010-07-23 2012-11-07 广州唯普电力科技有限公司 Cleaning agent for flue dust scale on surface of gas heat exchanger of gas desulfurization system and preparation method thereof
FR3004460B1 (en) * 2013-04-16 2015-04-17 Cba World S A Rl PRODUCT FOR THE REMOVAL OF RESIDUES FROM INSOLUBLE CALCIUM SALTS.
US20150034315A1 (en) * 2013-07-31 2015-02-05 Schlumberger Technology Corporation Viscosified acid fluid and method for use thereof
CA2866658A1 (en) * 2014-10-02 2016-04-02 Fluid Energy Group Ltd. Synthetic acid compositions alternatives to conventional acids in the oil and gas industry
CN104761065A (en) * 2015-04-24 2015-07-08 张萍 Descaling agent
CA2892877A1 (en) * 2015-05-28 2016-11-28 Fluid Energy Group Ltd. Using non-regulated synthetic acid compositions as alternatives to conventional acids in the oil and gas industry
CA2892895A1 (en) 2015-05-28 2016-11-28 Fluid Energy Group Ltd. Novel organic acid compositions for use in the oil and gas industry
US10683576B2 (en) * 2017-03-27 2020-06-16 Baker Hughes, A Ge Company, Llc Corrosion inhibitors for passivation of galvanized coatings and carbon steel
FR3079528A1 (en) 2018-03-29 2019-10-04 Suez Groupe PROCESS FOR PREVENTING THE FORMATION OF WHITE RUST ON A ZINC-COATED STEEL SURFACE
CN109183048A (en) * 2018-11-13 2019-01-11 中化化工科学技术研究总院有限公司 A kind of hydrochloric acid high temperature corrosion-retarding fog inhibitor and its application method

Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1039187A (en) * 1963-06-26 1966-08-17 Dow Chemical Co A method for removing scale from metallic surfaces
US3345296A (en) * 1964-02-28 1967-10-03 Fmc Corp Corrosion inhibition
US3356526A (en) * 1964-05-13 1967-12-05 Armour & Co Method of preparing water-dispersible softener compositions and products produced thereby
US3634270A (en) * 1969-06-20 1972-01-11 Dow Chemical Co Inhibitor
US3985671A (en) * 1974-09-26 1976-10-12 Universal Oil Products Company Scale control agents
EP0408297A1 (en) * 1989-07-11 1991-01-16 Warwick International Group Limited Scale inhibition
GB2279347A (en) * 1993-06-22 1995-01-04 Roger Liddle Jefferson Urea derivatives and their use in treating water
WO2002008127A1 (en) * 2000-07-20 2002-01-31 Rhodia Consumer Specialties Limited Treatment of iron sulphide deposits
US6866797B1 (en) * 2000-08-03 2005-03-15 Bj Services Company Corrosion inhibitors and methods of use

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3335085A (en) * 1964-04-08 1967-08-08 Calgon Corp Inhibiting corrosion by acids
NL155315B (en) * 1964-06-09 1977-12-15 Ver Kunstmestfabriekn Mekog Al PROCEDURE FOR CLEANING IRONS OR STEEL, INTERNAL SURFACES OF INDUSTRIAL EQUIPMENT
US3332871A (en) * 1966-06-27 1967-07-25 Myron L Robinson Water treatment
US3779935A (en) * 1971-07-12 1973-12-18 Exxon Research Engineering Co Inhibition of corrosion
US4025359A (en) * 1974-04-01 1977-05-24 Connelly Jr George F Inhibited acid composition for cleaning water systems
US4138276A (en) * 1976-03-01 1979-02-06 J. M. Eltzroth & Associates, Inc. Coating compositions
WO1990001478A1 (en) * 1988-07-29 1990-02-22 Sri International Synergistic corrosion inhibitors based on substituted pyridinium compounds
US5697443A (en) * 1996-02-09 1997-12-16 Halliburton Energy Services, Inc. Method and composition for acidizing subterranean formations utilizing corrosion inhibitor intensifiers

Patent Citations (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1039187A (en) * 1963-06-26 1966-08-17 Dow Chemical Co A method for removing scale from metallic surfaces
US3345296A (en) * 1964-02-28 1967-10-03 Fmc Corp Corrosion inhibition
US3356526A (en) * 1964-05-13 1967-12-05 Armour & Co Method of preparing water-dispersible softener compositions and products produced thereby
US3634270A (en) * 1969-06-20 1972-01-11 Dow Chemical Co Inhibitor
US3985671A (en) * 1974-09-26 1976-10-12 Universal Oil Products Company Scale control agents
EP0408297A1 (en) * 1989-07-11 1991-01-16 Warwick International Group Limited Scale inhibition
GB2279347A (en) * 1993-06-22 1995-01-04 Roger Liddle Jefferson Urea derivatives and their use in treating water
WO2002008127A1 (en) * 2000-07-20 2002-01-31 Rhodia Consumer Specialties Limited Treatment of iron sulphide deposits
US6866797B1 (en) * 2000-08-03 2005-03-15 Bj Services Company Corrosion inhibitors and methods of use

Also Published As

Publication number Publication date
WO2007087099A2 (en) 2007-08-02
US20070164258A1 (en) 2007-07-19
MX2008009193A (en) 2008-09-10
CA2637314A1 (en) 2007-08-02

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