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WO2006034653A1 - Composite de fibre de carbone permettant de reparer et de renforcer les conduites presentant des defectuosites et procede d'application - Google Patents

Composite de fibre de carbone permettant de reparer et de renforcer les conduites presentant des defectuosites et procede d'application Download PDF

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Publication number
WO2006034653A1
WO2006034653A1 PCT/CN2005/001607 CN2005001607W WO2006034653A1 WO 2006034653 A1 WO2006034653 A1 WO 2006034653A1 CN 2005001607 W CN2005001607 W CN 2005001607W WO 2006034653 A1 WO2006034653 A1 WO 2006034653A1
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WIPO (PCT)
Prior art keywords
carbon fiber
repairing
reinforcing
weight
pipelines
Prior art date
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PCT/CN2005/001607
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English (en)
French (fr)
Inventor
Minxu Lu
Yufang Zhang
Shaohua Dong
Aitian Ge
Yingfeng Chen
Baorui Li
Guoan Zhang
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University of Science and Technology Beijing USTB
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University of Science and Technology Beijing USTB
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Publication of WO2006034653A1 publication Critical patent/WO2006034653A1/zh
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Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16LPIPES; JOINTS OR FITTINGS FOR PIPES; SUPPORTS FOR PIPES, CABLES OR PROTECTIVE TUBING; MEANS FOR THERMAL INSULATION IN GENERAL
    • F16L55/00Devices or appurtenances for use in, or in connection with, pipes or pipe systems
    • F16L55/16Devices for covering leaks in pipes or hoses, e.g. hose-menders
    • F16L55/168Devices for covering leaks in pipes or hoses, e.g. hose-menders from outside the pipe
    • F16L55/1683Devices for covering leaks in pipes or hoses, e.g. hose-menders from outside the pipe by means of a patch which is fixed on the wall of the pipe by means of an adhesive, a weld or the like

Definitions

  • the invention relates to a technology for repairing and reinforcing a defect-containing pipeline, in particular a metal pipeline, by using a resin-based carbon fiber composite material, and more particularly, the invention relates to a reinforcement for repairing and reinforcing a pipeline containing defects, in particular, a pipeline containing defects
  • the material is a resin-based carbon fiber composite material, a method for repairing and reinforcing pipeline defects by the material, and the application of the material and method in repairing and reinforcing defects of oil and gas transmission pipelines.
  • Oil and gas pipeline transportation is one of the five major transportation industries. At present, China's oil and gas long-distance pipelines have reached more than 30,000 kilometers. During long-term service, these pipelines are affected by formation pressure, soil corrosion, galvanic corrosion, external force damage, etc., causing accidents such as pipe bursts and leaks, which affect the normal transportation of pipelines. There are often oil and gas pipeline blasting and leakage accidents at home and abroad. For example, in 1989, there were 1024 casualties in the Ural gas pipeline of the former Soviet Union. In North America, a 13-kilometer accident occurred in the gas pipeline. A large number of on-site investigations have shown that more than 60% of the oil and gas pipelines in service in China have entered the accident-prone period.
  • the composite material reinforcement technology of American Clockspring Company is a composite sheet of isophthalic acid unsaturated polyester and E-glass fiber, which is wrapped on the surface of metal pipe by dry laying, between layers. Bonded with an epoxy adhesive.
  • This technology There are two disadvantages of this technology: First, during the construction process, there is no guarantee that the composite sheet and the tube body, the composite sheet layer and the layer are closely adhered; the other is the elastic modulus and strength of the glass fiber. Low, so the thickness of the reinforcing layer will be thicker, which will cause certain difficulties for subsequent corrosion protection, and the improvement of the bearing capacity of the substrate is also limited.
  • Carbon fiber is known for its high strength and high modulus of elasticity, and is most suitable for use as a reinforcing material.
  • Table 1 shows the performance comparison of carbon fiber cloth, carbon fiber resin composite material and X60 pipeline steel.
  • the elastic modulus of the resin-based carbon fiber composite is equal to or greater than 210Gpa, which is very close to the elastic modulus of steel 207GPa, which is very beneficial to the co-deformation of carbon fiber composite and steel, which is beneficial to the load between steel and carbon fiber composite. Evenly distributed, which is beneficial to achieve the reinforcing effect.
  • Resin-based carbon fiber composites have a sufficient amount of deformation greater than 1.4%. In general, the deformation of the pipe body is much smaller than the deformation of the carbon fiber composite material, and the reinforcement using the carbon fiber composite material is sufficiently safe from the viewpoint of the deformation of the pipe body.
  • the strength of carbon fiber reinforced materials is an order of magnitude greater than that of glass fibers, which allows thinner carbon fiber composites to achieve the reinforcement of thick glass fiber reinforced materials.
  • the object of the present invention is to develop a new technology for using carbon fiber for reinforcing pipelines, especially metal pipelines.
  • the specific strength and specific modulus of the reinforcing materials used are close to the metal pipe materials, and the construction process is simple, and Conducive to the tightness between the reinforcing material and the pipe body, between the reinforcing layer and the layer Tight fit, it can be integrated with the pipe to jointly carry the pressure inside the pipe, and the ultimate composite repair layer can meet the pressure capacity of the original pipe.
  • the technology of the invention can carry out the reinforcing operation without stopping the pipeline, does not require large mechanical lifting equipment during the construction process, does not need welding or cutting pipelines, has low construction space requirements, and has corrosion resistance, aging resistance, etc. advantage.
  • An object of the present invention is to provide a resin-based carbon fiber composite material for repairing and reinforcing a defective pipe, particularly a metal pipe, comprising a carbon fiber sheet and a special resin of the present invention.
  • Another object of the present invention is to provide a reinforcing material for repairing and repairing a defect-containing pipe, the material comprising a plurality of layers of the resin-based carbon fiber composite material, and one or more of the resin-based carbon fiber composite materials.
  • Extra-layer anti-corrosion material is added to provide a reinforcing material for repairing and repairing a defect-containing pipe, the material comprising a plurality of layers of the resin-based carbon fiber composite material, and one or more of the resin-based carbon fiber composite materials.
  • pipe refers to pipes made of various materials, particularly metal pipes, such as steel pipes.
  • carbon fiber sheet includes carbon fiber sheets made of various raw materials, such as carbon fiber cloth.
  • the carbon fiber sheet used in the present invention has a modulus of elasticity in the range of
  • resin-based carbon fiber composite material refers to a material in which a carbon fiber and a resin are composite-cured.
  • the material for repairing and reinforcing the defect-containing pipe of the present invention comprises a resin-based carbon fiber composite material and an outer anti-corrosion material.
  • the resin-based carbon fiber composite material includes a carbon fiber sheet and a special supporting resin.
  • the special accessory resin of the invention comprises two kinds of repair glue and adhesive glue.
  • the repairing glue is used for the filling and repairing of the damage defects outside the pipeline; the adhesive dipping is used for infiltrating the carbon fiber sheet, and the bonding between the carbon fiber and the pipe body and between the carbon fiber sheets.
  • Repair glue and adhesive dipped rubber can be divided into winter and summer. Winter and summer formulations are slightly different and can usually be achieved by adjusting the amount of curing accelerator. When the ambient temperature is lowered, the amount of the curing accelerator can be appropriately increased.
  • the repairing glue consists of two components, A and B.
  • the ratio of the two components is 2:1.
  • a component includes:
  • Part B includes:
  • the curing agent of (E) in the component B may be, for example, a modified aliphatic amine such as diethylenetriamine glyceryl n-butyl ether (e.g., commercial 593) or a phenolic modified polyamine (e.g., commercial T31).
  • a modified aliphatic amine such as diethylenetriamine glyceryl n-butyl ether (e.g., commercial 593) or a phenolic modified polyamine (e.g., commercial T31).
  • the repairing glue can be prepared by mixing and storing the components A and B of the matching resin separately. Weigh accurately according to the specified ratio before use, put it into the container, and mix it with a stirrer. The amount of glue applied should be used up within the available time.
  • the adhesive dipping consists of two components, A and B.
  • the ratio of the two components is preferably (3 ⁇ 4): 1.
  • a component includes:
  • Part B includes:
  • the epoxy resin of the component (A) may be a bisphenol A epoxy resin or a vinyl modified epoxy resin; the curing agent of the component B (E) may be a modified aliphatic amine such as diethylene. Triaminoglycerin n-butyl ether (e.g., commercial 593) or phenolic modified polyamine (e.g., commercial T31).
  • the adhesive dipping can be prepared as follows: the components A and B of the matching resin are separately mixed and stored, accurately weighed according to the prescribed ratio before use, and then placed in a container, and uniformly mixed with a stirrer. The amount of glue applied should be used up within the available time.
  • the resin-based carbon fiber composite material for repairing and reinforcing the defect-containing pipeline of the present invention comprises the following materials:
  • a multi-layer carbon fiber sheet in which a carbon fiber sheet is coated with a glue dipped, and the carbon fiber sheet layers are alternately laid at an angle as needed.
  • the present invention also provides a reinforcing material for repairing and repairing a defect-containing pipe, the material comprising a plurality of layers of the resin-based carbon fiber composite material, wherein each layer of the resin-based carbon fiber composite material is placed along a radial or circumferential direction of the pipe, Adjacent two layers of composite material may be laid in parallel, perpendicular or at an angle.
  • the reinforcing material also includes a multilayer outer anticorrosive material located outside of the resin-based carbon fiber composite.
  • the outer anticorrosive material is in principle the same as the original outer anticorrosive material that needs to be reinforced.
  • a commonly used external anti-corrosion material is a polyethylene cold-wound adhesive tape, and the thickness of the polyethylene adhesive tape is 0.7mn! ⁇ 2.0mm is suitable; tensile strength is better than ISMpa.
  • Another object of the present invention is to provide a method for repairing and reinforcing a defective pipe, particularly a defective metal pipe, using the material of the present invention, which has good construction safety and performance superiority.
  • Another object of the present invention is to provide a repairing and reinforcing material and method for damage defects outside the oil and gas pipeline, that is, a technique for repairing and reinforcing the damage of the oil and gas pipeline by using the materials and methods described above.
  • the method for repairing and repairing a pipeline, such as an external damage defect of an oil and gas metal pipeline, using the material of the present invention includes the following steps:
  • the carbon fiber cloth is pasted according to a certain size and number of layers, and the resin-based carbon fiber composite material layers are placed along the radial or circumferential direction of the pipe as needed, so that the adjacent two layers of the composite material are parallel, perpendicular or at an angle. Staggered laying. Wherein the carbon fiber cloth is brushed or impregnated with the adhesive of the present invention;
  • the surface of the bonded carbon fiber composite material is entangled with a polyethylene cold wrap tape.
  • the pipe Before implementing the method, the pipe must be surface-cleaned first, and the surface of the pipe, such as honeycomb, pockmark, small hole, near the weld, etc., should be repaired with a repairing glue, that is, the repaired putty is smoothed and smoothed, and the surface is smoothed to the surface. If there are still irregularities, it should be smoothed with sandpaper.
  • a repairing glue that is, the repaired putty is smoothed and smoothed, and the surface is smoothed to the surface. If there are still irregularities, it should be smoothed with sandpaper.
  • the carbon fiber cloth is pasted by wet bonding, that is, the carbon fiber cloth is first brushed or impregnated with the epoxy resin adhesive of the present invention, and then entangled and reinforced.
  • the longitudinal and transverse overlap of the carbon fiber sheets should be kept to a certain length.
  • the anti-corrosion repair of the work area should be carried out after the adhesive surface of each adhesive surface in the reinforcing work area is dried.
  • the overlapping width of the wound layer and the original anti-corrosion layer should be kept a certain length. When wrapped around 3 ⁇ 4, the edges of the tape should be parallel and should not be twisted.
  • Fig. 1 is a schematic diagram of a pipe and a defect for a blasting test, in which a defect is a part for repairing and reinforcing, and a defect is a part for comparison without repairing and reinforcing.
  • Figure 2 is a pressure-time diagram of the hydraulic burst test.
  • Figure 3 is a photograph of the shape of the reinforcing part in the burst test. It can be seen from the photograph that the pipe on both sides of the reinforcing part under pressure is bulged, and there is no change in the reinforcing part.
  • Fig. 4 is a photograph showing the appearance of the mechanical scratch of the pipe of the embodiment 2.
  • Fig. 5 is a photograph showing the appearance of the defect of the external force of the pipe of the embodiment 2.
  • Figure 6 is a photograph of the appearance of the pipe after repairing in Example 2.
  • Example 1 Evaluation of the technical solution of the present invention by a water blasting test method
  • the ⁇ 660 gas pipeline is taken as an example to simulate the defect size that may exist in the gas pipeline, and the technology is evaluated by the water pressure burst test method.
  • the test tubes and defects are shown in Figure 1. The test process is as follows:
  • a defect of 50 mm X 30 mm X 4 mm (defect 1) was made at the portion where the anti-corrosion layer was peeled off, and the defect was repaired and reinforced by the technique of the present invention (see Example 2).
  • a defect of 50 mm X 30 mm X 2.0 mm (defect 2) was made in another part of the test tube, and this defect was not reinforced.
  • the test tube is filled with water and vented, and when the test sample is filled with water and does not leak, the pressure is gradually increased until the sample is broken.
  • the pressurization process is shown in Figure 2.
  • the results of the blasting test show that: the damage is generated at the small defect (defect 2) which is not repaired and reinforced, and the damage is typical tear-type damage; the test tube has obvious expansion phenomenon, and the repaired and reinforced defect There is no obvious change at the place. Under the pressure, the test tube on both sides of the reinforcing part is bulged, resulting in obvious expansion (see Figure 3).
  • the blasting pressure of the reinforced tube is 16.4Mpa, which is much higher than the design work of the sample.
  • the pressure (6.4 Mpa) indicates that the technology has reached the goal of reinforcement.
  • Example 2 Repair and reinforcement of natural gas pipeline defects 01607
  • the field embodiment of the present invention is an example of defect reinforcement applied to the Shaanxi-Beijing gas pipeline.
  • the defect is reinforced by the reinforcing material and the repair and reinforcement method according to the present invention.
  • the specific implementation process is as follows:
  • the defect of reinforcement construction is located somewhere in Shaanxi section of Shaanxi-Beijing pipeline. It is located at the edge of the desert. It is a sandy soil structure. The surface water layer is shallow. The depth of the pipeline is about 1300mm, and the surface temperature of the tube is about 40°C. There are three mechanical damages in the pipe body. One is an obvious mechanical scratch, 150mm long, 3.5mm deep, 20mm deepest at the deepest point (see Figure 4); the other two are bumps, 1.5mm deep and 20mm long (see Figure 5).
  • the surface cleaning of the pipeline for example, the result of surface treatment should be such that the quality of the pretreatment of the base layer reaches the St3 level specified in the national standard GB/T8923-1988.
  • the adhesive preparation and the repairing glue are prepared according to the preparation method described above and the formulation described in Table 3, and then the epoxy resin adhesive is applied to the carbon fiber cloth (the amount of the adhesive is shown in Table 3), and the same is used. Wound reinforcement.
  • the number and direction of winding of the carbon fiber cloth are two layers in the circumferential direction, one in the axial direction, two in the circumferential direction, one in the axial direction, and two in the circumferential direction, and a total of eight layers.
  • the anti-corrosion repair should be carried out after the adhesive surface of each adhesive surface in the reinforcing work area is dried.
  • the outer anticorrosive material used is a polyethylene adhesive tape wrapped around one layer.
  • the overlapping width of the wound layer and the original anti-corrosion layer should be not less than 100 mm.
  • the length of the adhesive tape at the beginning and end of the adhesive tape shall be not less than 1/4 of the pipe circumference and not less than 100 mm. When entangled, the edges of the adhesive tape should be parallel and the wrinkles should not be twisted.
  • the pipe segment described in this embodiment has been below the design working pressure due to the existence of the defect.
  • N2005/001607 operation which invisibly increases the running cost of the pipeline; after the repair and reinforcement, the operating pressure can be increased to the design level.
  • the present invention is a new matching technology suitable for pipeline repair and reinforcement, and is suitable for damage of damaged pipelines caused by corrosion, mechanical or other reasons for different pipe diameters.
  • the construction process does not require pipeline shutdown, and the reinforcing material can be tightly wrapped around the pipeline, which has little effect on the increase of the pipeline's own weight. It can be integrated with the pipe to jointly carry the pressure inside the pipe and make the pressure capacity of the repaired pipe reach and exceed the pressure capacity of the original pipe.

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  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
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  • Pipe Accessories (AREA)
  • Lining Or Joining Of Plastics Or The Like (AREA)

Description

含缺陷管道修复补强的碳纤维复合材料和方法 发明领域
本发明涉及用树脂基碳纤维复合材料对含缺陷管道, 特别是金属管道 进行修复补强的技术, 更具体地, 本发明涉及用于含缺陷管道, 特别是含 缺陷金属管道修复补强的补强材料, 该材料为树脂基碳纤维复合材料, 用 所述材料对管道缺陷进行修复补强的方法, 以及所述材料和方法在油气输 送管道缺陷的修复补强中的应用。
背景技术
油气管道运输是五大运输产业之一, 仅目前我国油气长输管道就达 3 万余公里。 这些管道在长期服役过程中, 由于受到地层压力、 土壤腐蚀、 电偶腐蚀、 外力损伤等作用, 造成管道爆裂、 泄漏等事故发生, 影响管道 的正常输送作业。,国内外常有油气管道爆破和泄漏事故发生, 如 1989年, 前苏联乌拉尔输气管道爆破一次伤亡 1024人;北美也曾发生输气管道一次 爆破开裂 13公里的大事故。大量的现场调查表明, 我国在役油气管线 60% 以上已进入事故多发期。 通常, 有缺陷的油气输送管道在运行作业时, 往 往釆取降压输送的做法, 这样不仅影响了正常的生产作业, 而且大大增加 了运行成本。 因此开发一种效果好、 便于实施的补强材料和方法是本领域 追求的目标。 在现有的油气管道外缺陷修复补强技术中, 主要有传统的焊 接补疤和复合材料补强等方法。 由于悍接补疤过程中有可能发生焊穿和产 生氢脆的危险, 特别对于不停输的输气管线, 一般建议不釆用此方法。 而 树脂基复合材料由于具有轻质高强、 抗腐蚀、 耐久性好、 施工简便、 不影 响结构的外观等优异特性, 已被国外的油公司用于管道补强。 如美国 Clockspring公司的复合材料补强技术, 它是釆用间苯二甲酸型不饱和聚酯 与 E-玻璃纤维复合成片材, 采用干铺法包裹于金属管道表面, 在层与层之 间用环氧粘结剂粘结。 这种技术的缺点有两个: 一是施工过程中, 无法保 证复合片材与管体、 复合片材层与层之间的紧密贴合; 另一是玻璃纤维的 弹性模量及强度均较低, 所以补强层的厚度会较厚, 对后续防腐造成一定 困难, 对基体承载能力的提高程度也很有限。
近年来有一些关于使用碳纤维进行金属管道外损伤缺陷补强的报道, 但没有公开具体的实施方案。
碳纤维以其强度高、 弹性模量大而著称, 最适合于作为补强材料所用。 表 1示出碳纤维布、 碳纤维树脂复合材料和 X60管线钢的性能比较。
表 1碳纤维、 碳纤维复合材料与 X60管线钢的性能比较
Figure imgf000004_0001
由表 1可以看出, 用碳纤维作为补强材料有如下优点:
1. 树脂基碳纤维复合材料的弹性模量等于或大于 210Gpa, 和钢的弹性模量 207GPa十分接近, 非常有利于碳纤维复合材料与钢的协同变形, 有利于载 荷在钢和碳纤维复合材料之间的均匀分布, 从而有利于达到补强效果。 . 树脂基碳纤维复合材料具有足够的变形量, 大于 1.4%。 一般情况下, 管体 变形远小于碳纤维复合材料的变形量, 使用碳纤维复合材料进行补强从管 体变形的角度来说也是足够保险的。
. 碳纤维补强材料的强度比玻璃纤维大一个数量级, 这使得较薄的碳纤维复 合材料便可以达到很厚的玻璃纤维补强材料才能具有的补强效果。
本发明目的在于研制一种将碳纤维用于含缺陷管道, 特别是金属管道 补强的新型技术, 所使用的补强材料的比强度、 比模量与金属管体材料接 近, 施工过程简便, 并有利于补强材料和管体之间、 补强层与层之间的紧 密贴合, 它可与管道形成一体, 共同承载管内压力, 并使最终构成的复合 修复层承压能力达到并超过原始管道的承压能力。 本发明的技术可在管线 不停输的情况下进行补强作业, 施工过程中不需要大型的机械吊装设备, 不需要焊接或切割管道, 施工空间要求很低, 并且有抗腐蚀、 耐老化等优 点。
发明内容
本发明的目的是提供一种用于含缺陷管道, 特别是金属管道修复补强 的树脂基碳纤维复合材料, 所述的树脂基碳纤维复合材料包括碳纤维片材 和本发明的专用树脂。
本发明的另一目的是提供了一种用于含缺陷管道修复补强的补强材 料, 该材料包括多层所述的树脂基碳纤维复合材料, 和位于树脂基碳纤维 复合材料外的一或多层外防腐材料。
本文所用的术语 "管道" 是指用各种材料制成的管道, 特别是金属管 道, 例如钢管。
本文所用的术语 "碳纤维片材" 包括以各种原料制作的碳纤维片材, 例如碳纤维布。 优选的, 本发明所使用的碳纤维片材其弹性模量范围为
( 1.0-3.0 ) X 105MPa, 抗拉强度范围为 2500〜3500Mpa, 延伸率 δ范围为 0. 2-3. 0%, 单位面积重量范围为 200〜300g/m2
本文所用的术语 "树脂基碳纤维复合材料" 是指碳纤维与树脂复合固 化后的材料。
本发明用于含缺陷管道修复补强的材料包括树脂基碳纤维复合材料 和外防腐材料。 所述树脂基碳纤维复合材料包括碳纤维片材和专用配套树 脂。
本发明的专用配套树脂包括修补胶和粘浸胶两种。 修补胶用于管道外 损伤缺陷的填平修补; 粘浸胶用于渗浸碳纤维片材, 以及碳纤维与管体之 间、 碳纤维片材之间的粘结。 修补胶和粘浸胶分别可分为冬用与夏用两种。 冬用和夏用配方略有不同, 通常可通过调整固化促进剂的用量来实现。 当 使用环境温度降低时, 可适当加大固化促进剂的用量。 本领域普通技术人 员根据本领域的常识, 或通过简单试验即可知道在某一使用温度下应该如 7 修补胶
修补胶由甲、 乙两组分组成, 甲乙两组分的配比为 2: 1。
甲组分包括:
(A) : 30%〜50% (重量) 的液态双酚 A型环氧树脂,
(B) : 10%〜20% (重量) 的液态酚醛型环氧树脂
(C) : 5%〜10% (重量) 的气相二氧化硅, 和
(D: 35%〜40% (重量) 的硅灰石或氧化铝填料;
乙组分包括:
(E) : 60%〜80% (重量) 的改性胺类环氧固化剂, 和
(F) : 20%〜40% (重量) 的促进剂 2, 4, 6 -三 (二甲氨基) -甲基苯 酚;
所述乙组分中 (E) 的固化剂例如可以是改性脂肪族胺, 例如二乙烯 三胺基甘油正丁基醚(例如商品 593) 或酚醛改性多元胺 (例如商品 T31)。
构成缺陷填平修补胶的甲、 乙两组分混合固化后的性能如表 1。
表 2修补胶的规格性能
Figure imgf000006_0001
修补胶可按下述方法制备:将配套树脂的甲、乙组分分别混合和储存, 使用前按规定比例准确称量后放入容器内, 用搅拌器拌合均勾。 一次配胶 量应以在可使用时间内用完为宜。
粘浸胶
粘浸胶由甲、 乙两组分组成, 甲乙两组分的配比以 (3~4): 1为宜。 甲组分包括:
(A) : 68%〜84% (重量) 的液态环氧树脂,
(B) : 10%〜15% (重量) 的丙烯酸酯液体橡胶,
(C) : 5%〜15% (重量) 的气相二氧化硅, 和
(D) : 1%〜2% (重量寸) 的颜料;
乙组分包括:
(E) : 70%〜90% (重量) 的改性胺类环氧固化剂, 和
(F) : 10%〜30% (重量) 的环氧固化促进剂 2, 4, 6-三 (二甲氨基) -甲基苯酚;
所述甲组分 (A) 的环氧树脂可以是双酚 A 型环氧树脂或乙烯基改性 环氧树脂; 乙组分 (E) 的固化剂可以是改性脂肪族胺, 例如二乙烯三胺基 甘油正丁基醚 (例如商品 593) 或酚醛改性多元胺 (例如商品 T31)。
构成粘浸胶的甲、 乙两组分混合固化后的性能如表 2。
表 3 粘浸胶的规格性能
项目 粘浸胶
LZ300W (冬用) LZ300S (夏用)
甲乙组分的配比 (3-4): 1
适用温度' C 5-15 15-35
可使用时间 (min) 40-170 60-180
指触干燥时间 (hr) 4.0-12.0 3.0-10.0
形状 乳脂状
性能指标 拉 伸 强度 弯曲强度 压缩强度 钢钢剪切强 弹性模量
(Mpa) (Mpa) (Mpa) 度 (Mpa) (Mpa)
30 40 50 ^10 ^2X103 主要用途 涂刷钢管表面、 渗透粘贴碳纤维片 粘浸胶可按下述方法制备:将配套树脂的甲、 乙组分分别混合和储存, 使用前按规定比例准确称量后放入容器内, 用搅拌器拌合均匀。 一次配胶 量应以在可使用时间内用完为宜。 具体的, 本发明用于含缺陷管道修复补强的树脂基碳纤维复合材料包 括以下材料:
1、 用于将管道表面缺陷填平修补的修补胶层;
2、 多层碳纤维片材, 其中的碳纤维片材涂刷了粘浸胶, 且根据需要 使各碳纤维片材层以一定角度交错铺设。
本发明还提供了用于含缺陷管道修复补强的补强材料, 该材料包括多 层所述的树脂基碳纤维复合材料, 其中各层树脂基碳纤维复合材料沿管道 的径向或环向放置, 相邻的两层复合材料可以平行的、 垂直的或以一定角 度交错铺设。
该补强材料还包括位于树脂基碳纤维复合材料外的多层外防腐材料。 所述外防腐材料原则上与需要补强管道的原始外防腐材料相同。 常用的外 防腐材料是聚乙烯冷缠胶粘带,所述的聚乙烯胶粘带厚度以 0.7mn!〜 2.0mm为宜; 抗拉强度大于 ISMpa为宜。
在实际应用时, 根据管道缺陷的具体情况, 本专业技术人员可按照通 常的缺陷补强参数设计方法确定补强层的厚度、 宽度和补强材料用量。 本发明的另一目的是提供一种用本发明的材料对含缺陷管道, 特别是 含缺陷金属管道进行修复补强的方法, 该方法具有良好的施工安全性和性 能优越性。
本发明的另一目的是提供一种油气管道外损伤缺陷的修复补强材料 和方法, 即采用以上所述的材料和方法对油气管道外损伤缺陷进行修复补 强的技术。
用本发明的材料对管道, 例如对油气金属管道的外损伤缺陷进行修复 补强的方法包括以下步骤:
1.对管道进行表面清理;
2.对管道表面的缺陷进行修补 将管道表面凹陷部位, 例如蜂窝、 麻面、 小孔、 焊缝附近等用修补胶 填平, 修复至表面平整;
3. 湿法粘贴碳纤维布
按一定的尺寸及层数粘贴碳纤维布, 且根据需要将各树脂基碳纤维复合 材料层沿管道的径向或环向放置, 使相邻的两层复合材料之间是以平行、垂直 或一定角度交错铺设。 其中所述的碳纤维布涂刷或浸渍了本发明的粘浸胶;
4. 对作业区进行防腐修复
在粘贴的碳纤维复合材料表面用聚乙烯冷缠胶粘带对其进行缠绕防 护。
在实施该方法之前, 必须首先对管道进行表面清理, 对管道表面的缺 陷例如蜂窝、 麻面、 小孔、 焊缝附近等用修补胶, 即修补腻子涂刮填平, 修复至表面平整, 表面仍存在凹凸糙纹的, 应该用砂纸打磨平整。
碳纤维布的粘贴采用湿法粘贴的方法, 即首先将碳纤维布涂刷或浸渍 本发明的环氧树脂粘浸胶, 然后用其进行缠绕补强。 为确保施工质量, 碳 纤维片的纵横向搭接应保持一定长度。
作业区的防腐修复, 应该在补强作业区域内各粘贴面的胶粘剂表干后进 行。 缠绕层与原防腐层的搭接宽度应保持一定长度。 缠 ¾时胶粘带边缝应平 行, 不得扭曲皱折。
为保证施工质量, 在需要进行开挖和回填时, 应该按照规定的施工要 求进行。 例如对现场检测已确定的缺陷位置, 必须在现场监护人员的监护 下实施人工开挖。 开挖过程中注意测量埋深, 防止铁器损坏防腐层及钢管。 在补强施工完成, 并确认开挖管段无漏点后, 采用细沙或素土进行分层夯 实回填, 并对现场进行清理和恢复地形原貌, 保证管线的埋深达到设计要 求。
下面通过对本发明具体实施方式的描述, 结合附图对本发明的材料及 方法予以详尽的说明。
附图说明
图 1为爆破试验用管道及缺陷示意图, 其中, 缺陷一是进行修复补强 的部位, 缺陷二是用于进行对比而不进行修复补强的部位。
图 2水压爆破试验的压力-时间关系图。 01607 图 3是爆破试验中补强部位形貌的照片。 由照片可以看出在压力下补 强部位两侧管道发生隆起, 而补强部位没有任何变化。
图 4是实施例 2管道机械划痕缺陷形貌的照片。
图 5是实施例 2管道外力致伤缺陷形貌的照片。
图 6是实施例 2修复补强后管道形貌的照片。
具体实施方式
为了进一步阐述本技术所涉材料及施工工艺, 给出了下述实施例。 但 是, 这些实施例不以任何方式限制本发明的范围。
实施例 1 : 用水压爆破试验方法对本发明的技术方案进行评价
为了检验本技术的实施效果, 以 Φ660输气钢管为例, 模拟输气管道可 能存在的缺陷尺寸, 釆用水压爆破试验方法对该技术进行了评价。 试验用 管及缺陷示意见图 1, 试验过程如下:
截取与某输气管线主干线用管相同尺寸、 材质的管子 5.45m (该管子 为 X60螺旋焊管,管径为 660mm,壁厚为 8.7mm,设计工作压力为 6.4Mpa), 两端用留有排气孔、 进水孔的封头封堵 (见图 2 )。
对需要补强的管体部位进行清理, 以去除管子外表面的防腐层、 环氧 涂层及污物, 并使其表面处理质量达到 GB/T8923-1988中规定的 St3级。
在被剥除防腐层的部位制作 50 mm X 30mm X 4 mm的缺陷 (缺陷一), 采用本发明的技术 (参见实施例 2 ) 对该缺陷进行修复补强。 为便于试验 对比,在该试验管的另一部位又制作了 50 mm X 30mm X 2.0mm的一个缺陷 (缺陷二), 这一缺陷不进行补强。
对试验用管进行注水排气, 在检查试样注满水并不漏气的情况下, 进 行逐级加压, 直至试样破坏。 加压过程见图 2。 该爆破试验结果显示: 破 坏是在未经修复补强的小缺陷 (缺陷二) 处产生的, 破坏为典型的撕裂型 破坏; 试验管有明显的膨胀现象, 而经修复、 补强的缺陷处并无明显变化, 在压力下补强部位两侧试验管发生隆起, 产生明显的膨胀现象 (见图 3 ); 补强后的管体爆破压力为 16.4Mpa,远高于试样的设计工作压力(6.4 Mpa), 表明该技术已经达到了补强的目的。 实施例 2: 天然气管道缺陷的修复补强 01607 本发明技术的现场实施例为应用于陕京输气管线的缺陷补强实例。 利 用本发明所述的补强材料和修复补强方法对该处的缺陷进行补强。 具体实 施过程如下:
1、 开挖和对管道进行表面清理
补强施工的缺陷点位于陕京管线陕西某段某处。 该处位于沙漠的边沿, 属沙土结构, 地表水水层较浅, 管道埋深 1300mm左右, 管体外表面温度 约 40°C。 管体有三处机械损伤。 一处为明显的机械划痕, 长 150mm, 深 3.5mm,最深处宽度为 20mm (见图 4 ) ;另两处为碰伤,深 1.5 mm,长 20mm (见图 5 )。
对管道进行表面清理, 例如表面处理的结果应该使基层预处理质量达 到国家标准 GB/T8923-1988中规定的 St3级。
2、 对管道进行修补
对钢管表面缺陷例如蜂窝、 麻面、 小孔、 焊缝附近等用修补胶, 即修 补腻子涂刮填平, 修复至表面平整, 表面仍存在凹凸糙纹的, 应该用砂纸 打磨平整。 其中所述修补胶的配方和用量见表 4。
3、 采用湿法粘贴碳纤维布
首先按上文所述制备方法和表 3所述配方制备粘浸胶和修补胶, 然后将 碳纤维布涂刷所述的环氧树脂粘浸胶 (粘浸胶的用量见表 3 ), 并用其进行 缠绕补强。
7 表 3 补强材料及用量
Figure imgf000012_0001
所述碳纤维布缠绕的层数和方向是环向二层、 轴向一层、 环向二层、 轴向一层和环向二层, 共计八层。
4、 对作业区进行防腐修复
防腐修复应该在补强作业区域内各粘贴面的胶粘剂表干后进行。 所使 用的外防腐材料为聚乙烯胶粘带, 缠绕一层。 缠绕层与原防腐层的搭接宽 度应不少于 100mm。 胶粘带始端与末端搭接长度应不少于 1/4管子周长, 且不少于 100mm。 缠绕时胶粘带边缝应平行, 不得扭曲皱折。
修复补强后管道的形貌见图 6
本实施例所述的管段由于该缺陷的存在, 一直在低于设计工作压力下 N2005/001607 运行, 无形中提高了管道的运行成本; 经过此次修复补强后, 运行工作压 力可提高到设计水平。
总之, 本发明是一种适合管道修复补强的全新配套技术, 适合于不同 管径的, 由于腐蚀、 机械或其它原因所造成的损伤管道补强。 其施工过程 无需管线停产作业, 且补强材料可以紧紧的缠绕着管道, 对管道自重的增 加影响很少。 它可与管道形成一体, 共同承载管内压力, 并使修复后管道 的承压能力达到并超过原始管道的承压能力。
以上已详细描述了本发明的实施方案, 对本领域技术人员来说很显然 可以做很多改进和变化而不会背离本发明的基本精神。 所有这些变化和改 进都在本发明的保护范围之内。

Claims

权利要求
1. 用于含缺陷管道修复补强的树脂基碳纤维复合材料,其中包括用粘 浸胶涂刷或浸渍的碳纤维片材, 所述粘浸胶由甲乙两组分组成, 其中
甲组分包括:
(A) : 68%〜84% (重量) 的液态环氧树脂,
( B ) : 10%〜15% (重量) 的丙烯酸酯液体橡胶,
( C ) : 5%〜15% (重量) 的气相二氧化硅, 和
( D) : 1%〜2% (重量) 的颜料;
乙组分包括:
( E) : 70%〜90% (重量) 的改性胺类环氧固化剂, 和
( F ) : 10%〜30% (重量) 的环氧固化促进剂 2, 4, 6-三 (二甲氨基) -甲基苯酚;
其中甲组分 (A) 的环氧树脂可以是双酚 A型环氧树脂或乙烯基改性 环氧树脂; 乙组分 (E) 的固化剂可以是改性脂肪族胺;
甲、 乙两组分在使用前以 (3〜4): 1的比例用搅拌器均匀混合。
2. 权利要求 1的树脂基碳纤维复合材料,其中所述材料还包括用于将 管道外缺陷填平修补的修补胶, 所述修补胶由甲、 乙两组分组成, 其中 甲组分包括:
( A) : 30%〜50% (重量) 的液态双酚 A型环氧树脂,
( B ) : 10%〜20% (重量) 的液态酚醛型环氧树脂
( C) : 5%〜10% (重量) 的气相二氧化硅, 和
( D ) : 35%〜40% (重量) 的硅灰石或氧化铝填料;
乙组分包括:
(E) : 60%〜80% (重量) 的改性胺类环氧固化剂, 和
( F) : 20%〜40% (重量) 的促进剂 2, 4, 6-三 (二甲氨基) -甲基苯 酚;
其中乙组分中 (E) 的固化剂可以是改性脂肪族胺;
甲、 乙两组分在使用前以 2: 1比例用搅拌器均匀混合。
3. 权利要求 1或 2的树脂基碳纤维复合材料,其中所述碳纤维片材的 弹性模量 E的范围为 (0.5— 20.0) x l05MPa, 拉伸强度 Sb的范围为 (0.5— 20.0 ) X 103MPa, 延伸率 δ的范围为 0.1-5.0%。
4. 权利要求 3的树脂基碳纤维复合材料,其中所述的改性脂肪族胺是 二乙烯三胺基甘油正丁基醚或酚醛改性多元胺。
5. 用于含缺陷管道修复补强的补强材料, 该材料包括多层权利要求 1-4任意一项所述的树脂基碳纤维复合材料,其中各层树脂基碳纤维复合材 料沿管道的径向或环向放置, 相邻的两层复合材料可以是平行的、 垂直的 或以一定角度交错铺设的。
6. 权利要求 5所述的补强材料,其中所述的补强材料还包括位于树脂 基碳纤维复合材料外的一或多层外防腐材料。
7. 权利要求 6的补强材料, 其中所述的外防腐材料是聚乙烯胶粘带。
8. 用权利要求 1-7 任意一项的材料对含缺陷管道进行修复补强的方 法, 该方法包括以下步骤:
( 1 ) 用权利要求 2 所述的修补胶对管道表面的缺陷进行修补, 将其 修复至表面平整;
( 2 ) 湿法粘贴碳纤维片材
按一定的尺寸及层数粘贴碳纤维片材, 所述碳纤维片材涂刷了权利要 求 1所述粘浸胶, 或用所述的粘浸胶浸渍, 且根据需要使各碳纤维片材层 沿管道的径向或环向放置, 相邻的两层碳纤维片材可以是平行的、 垂直的 或以一定角度交错铺设的。
9. 按照权利要求 8的方法,该方法还包括对作业区进行防腐处理的步 骤, 该步骤包括在粘贴了所述碳纤维片材后的外表面按一定的尺寸和层数 用聚乙烯冷缠胶粘带对其进行缠绕防护。
10. 按照权利要求 8或 9的方法,该方法还包括在对管道进行修补之前 需要对损伤部位进行表面清理。
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CN112431992A (zh) * 2020-11-19 2021-03-02 西安热工研究院有限公司 一种油气管道凹坑缺陷修复方法
CN113821854A (zh) * 2021-09-16 2021-12-21 中国建筑第八工程局有限公司 既有工业厂房生产设备的修复方法
CN114479579A (zh) * 2022-03-08 2022-05-13 石狮华宝新材料工程有限公司 一种重防腐管道修补用光固化复合片材及管道修补工艺

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