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WO2006028265A1 - Cires organopolysiloxanes pour cosmétiques et produits cosmétiques les contenant - Google Patents

Cires organopolysiloxanes pour cosmétiques et produits cosmétiques les contenant Download PDF

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Publication number
WO2006028265A1
WO2006028265A1 PCT/JP2005/016980 JP2005016980W WO2006028265A1 WO 2006028265 A1 WO2006028265 A1 WO 2006028265A1 JP 2005016980 W JP2005016980 W JP 2005016980W WO 2006028265 A1 WO2006028265 A1 WO 2006028265A1
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WIPO (PCT)
Prior art keywords
group
acid
waxy
oil
organopolysiloxane
Prior art date
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Application number
PCT/JP2005/016980
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English (en)
Japanese (ja)
Inventor
Takatoshi Toyama
Takakazu Hino
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DuPont Toray Specialty Materials KK
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Dow Corning Toray Co Ltd
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Publication of WO2006028265A1 publication Critical patent/WO2006028265A1/fr
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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q19/00—Preparations for care of the skin
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G77/00—Macromolecular compounds obtained by reactions forming a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon in the main chain of the macromolecule
    • C08G77/04—Polysiloxanes
    • C08G77/38—Polysiloxanes modified by chemical after-treatment
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q1/00—Make-up preparations; Body powders; Preparations for removing make-up
    • A61Q1/02—Preparations containing skin colorants, e.g. pigments
    • A61Q1/04—Preparations containing skin colorants, e.g. pigments for lips
    • A61Q1/06—Lipsticks

Definitions

  • the present invention relates to an ivy-like organopolysiloxane for blending cosmetics, and a cosmetic comprising the same. More specifically, because it has good dispersibility in oily components and organic solvents, it can be easily blended into cosmetics, and cosmetics with good storage stability and feel are well known.
  • the present invention relates to a waxy organopolysiloxane for blending cosmetics that can be easily obtained, and a cosmetic that has good storage stability and feel because it is blended.
  • modified silicones in which a part of the methyl group of dimethylpolysiloxane is replaced with a long-chain alkyl group, etc.
  • siloxane Widely used as siloxane.
  • a wax-like modified silicone having specific endothermic properties can provide a cosmetic material that does not feel sticky and has good elongation (for example, Japanese Patent Application Laid-Open No. 2000-0 2 2 4 7 2 9).
  • ox-like organopolysiloxanes are poorly dispersible in oily components and organic solvents, which makes it difficult to produce cosmetics containing them, and adversely affects the storage stability and feel of cosmetics. There was a problem.
  • the present invention has been made based on the above situation.
  • the object of the present invention is good dispersibility in oily components and organic solvents, it can be easily blended into cosmetics, and cosmetics with good storage stability and feel can be easily obtained.
  • Another object of the present invention is to provide a cosmetic which is easy to produce and has good storage stability and feel.
  • the waxy organopolysiloxane for blending cosmetics of the present invention has a chemical structure represented by the following general formula (1), and has a melting point of 30 ° (up to 120 ° C). To do.
  • each R is independently
  • n is an integer of 0 to 1,200, and the number average of n is 50.0 to 1000.0.
  • R is the group (a) and (a
  • Group proportion is 70% by mass or less.
  • the cosmetic of the present invention is characterized by comprising (A) an oily component and Z or an organic solvent; and (B) the waxy organopolysiloxane of the present invention.
  • the boxy organopolysiloxane for blending cosmetics of the present invention is excellent in dispersibility in both oily components and organic solvents.
  • the waxy organopolysiloxane for blending cosmetics of the present invention can be easily blended into cosmetics.
  • a cosmetic having good storage stability and feel can be easily obtained.
  • the cosmetic of the present invention can be easily produced and has good storage stability and feel.
  • Figure 1 is a GPC chart measured for. (S i HI).
  • Figure 2 is a GPC chart measured for (S i H2).
  • Figure 3 is a GPC chart measured for (S i H3).
  • a long-chain alkyl group having 17 to 300 carbon atoms or a long-chain organic group containing a hetero atom may be linear or branched.
  • long-chain organic groups containing a long-chain alkyl group and a heteroatom may be collectively referred to simply as a “long-chain organic group”.
  • the number of carbon atoms present in the long-chain organic group is usually 17 to 300, preferably 20 to 90, more preferably 20 to 80, and particularly preferably 25 to 60. If the long chain organic group has less than 17 carbon atoms, it will be oily at room temperature and not waxy. On the other hand, if the number of carbons exceeds 300, the melting point becomes too high, the melt viscosity is too high, or the dispersibility in oily components or organic solvents becomes poor, so it should be applied to wax applications. I can't.
  • a linear alkyl group [CH 3 (CH 2 ) p , —] (p, is an integer of 16 to 299, preferably 19 to 89, more preferably 19 to 79, Particularly preferred are 24 to 59.) and branched alkyl groups can be mentioned, and a linear alkyl group is preferred.
  • Specific examples of strong long-chain alkyl groups include CH 3 (CH 2 ) 23 —oppi CH 3 (CH 2 ) 45 —.
  • the hetero atom may be any atom other than carbon. Also, it may be a mixture of various heteroatoms, and their position may be any.
  • the long-chain organic group containing a hetero atom is bonded to the organopolysiloxane via alkylene having 2 to 15 carbon atoms or alkylene 1 CO— having 2 to 15 carbon atoms.
  • the total number of heteroatoms in the long-chain organic group containing this heteroatom is 1 to 10, preferably 1 to 5, and more preferably 1 to 3.
  • the heteroatom is selected from an oxygen atom or a nitrogen atom.
  • Examples of the long-chain organic group containing a hetero atom include an alkoxy carboalkyl group [CH 3 (CH 2 ) p O (CO) (CH 2 ) q —]; an alkylaminocarbonylalkyl group [CH 3 (CH 2 )] p NHCO (CH 2 ) q —]; Alkylcarbo-alkyloxy group [CH 3 (CH 2 ) p COO (CH 2 ) q —]; Alkoxyalkyl group [CH 3 (CH 2 ) p O (CH 2 ) q ⁇ ]; Alkylcarboxoxy (2-hydroxy) propyloxyalkyl group [CH 3 (CH 2 ) p COOCH 2 CH (OH) CH 2 O (CH 2 ) q —]; Alkylcarbonylaminoalkyl group [CH 3 (CH 2 ) p C 0 NH (CH 2 ) q —]; Anolequinolamino canolebonin
  • p is an integer having 17 to 300 carbon atoms in the long-chain organic group
  • q is an integer of 1 to 15, preferably 2 to 13
  • the wax-like organopolysiloxane of the present invention has one or more groups (a) in the molecule and thus exhibits a wax-like property.
  • the number ratio of the group (a) is usually 5 to 60%, preferably 5 to 45%.
  • the group (b) constituting a part of R is a hydrogen atom, an alkyl group having 2 to 16 carbon atoms, an aryl group having 6 to 10 carbon atoms, an aralkyl group having 7 to 14 carbon atoms, or an alkyl group having 1 to 8 carbon atoms.
  • alkyl group having 2 to 16 carbon atoms examples include an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group, and a hexyl group.
  • the aryl group having 6 to 10 carbon atoms includes a phenyl group and a naphthyl group, and among these, a phenyl group is particularly preferable.
  • Aralkyl groups having 7 to 14 carbon atoms include benzyl and phenethyl groups.
  • the group (b) includes a group that is by-produced when a long-chain organic group is introduced into the organopolysiloxane, and the “organic group having 2 to 16 carbon atoms including heteroatoms” includes chain elongation. Included are reactive groups such as hydrosilyl groups, hydroxy groups and epoxy groups, including intermediate reactive groups formed during long reactions, and groups resulting from blocking or inactivating these reactive groups.
  • Such groups include hydroxyalkyl groups [HO (CH 2 ) q —]; alkoxyalkyl groups [CH 3 (CH 2 ) s O (CH 2 ) q —]; epoxypropyloxyalkyl groups [CH 2 (0) CHCH 2 0 (CH 2 ) n —]; Ananoloxy (2-hydroxy) propylalkyl group [CH 3 (CH 2 ) s OCH 2 CH (OH) CH 2 0 (CH 2 ) q ⁇ ]; Alkoxy Carbonylalkyl group [CH 3 (CH 2 ) s O (CO) (CH 2 ) q —]; Alkyl carbonyl alkyl group [CH 3 (CH 2 ) s COO (CH 2 ) q —] It is.
  • s is an integer of 0 to 13, preferably 0 to 2, and q is as defined above. However, the total carbon number of these groups is 2-16.
  • the number ratio of the group (b) is usually 0 to 50%, preferably 0 to 20%, more preferably 0 to 5%.
  • the total mass ratio of the group (a) and the mass ratio of the group (b) is as follows. Usually, it is 80% or less, preferably 65% or less, more preferably 50% or less.
  • the group (c) constituting a part of R is a methyl group.
  • the number ratio of (c) methyl groups is usually 40 to 95%, preferably 55 to 95%.
  • the wrinkles, spread and good feel that are characteristic of silicone wax cannot be obtained.
  • the applied cosmetics are solidified, and such cosmetics cannot sufficiently prevent makeup collapse.
  • n is an integer of 0 to 1200, preferably 5 to 800.
  • the number average of n is 50.0-; L000.0, Preferably, it is 50.0-500.0.
  • Oganopolysiloxanes whose n number average is less than 50.0 do not provide the good wrinkle, spread and good feel of silicone wax.
  • ⁇ exceeds 1200 and the number average exceeds 1000.0, the organopolysiloxane has an excessively high viscosity at the time of melting, and the cosmetic feel such as elongation becomes worse, and it is difficult to add to cosmetics. It becomes.
  • numerator is 70 mass% or less, Preferably it is 10-50 mass%.
  • the proportion of the group (a) is more than 70% by mass, the dispersibility in the oil component and the organic solvent becomes poor and the object of the present invention cannot be achieved.
  • a preferred chemical structure is as follows: In the above general formula (1), 5 to 45% by number of R is (a) a long chain alkyl group having 25 to 60 carbon atoms, and 0 to 20% by number of R is (b) An alkoxy group having 1 to 8 carbon atoms, 55 to 95% by number of R is (c) a methyl group; n is 5 to 800.
  • the specific structure of the modified organopolysiloxane represented by the above general formula (1) includes the following general formula (1 A) in which a part of R is composed of (a) a long-chain organic group is a long-chain alkyl group.
  • the long-chain organic group has the formula: Formula: CH 3 (CH 2 ) p O (CH 2 ) n —
  • An organopolysiloxane represented by the following general formula (1D), which is a group represented by q— can be mentioned
  • the waxy organopolysiloxane for blending cosmetics of the present invention is represented by the above general formula (1), and it is necessary that the melting point is 30 ° C. to 120 ° C. If it is less than 30 ° C, it will become liquid at room temperature such as in summer, so it will dissolve during storage, and the product (cosmetics) containing this will become too soft, so that it will become a waxy organopolysiloxane. Don't make use of On the other hand, if the melting point is higher than 120 ° C., a large amount of heat is required for dissolution, which is not practical.
  • the melting point is preferably 35 to 100 ° C, preferably 40 to 80. C is particularly preferred.
  • the melting point of the waxy organopolysiloxane is mainly influenced by the long chain group of the organopolysiloxane, that is, the group (a) in the above general formula (1). That is, it is almost the same as the compound corresponding to the group (a) (for example, 1-icosene in the case of icosyl group).
  • the melting point is increased by increasing the proportion of the (a) group in the group bonded to silicon or by lengthening the polysiloxane chain.
  • the ivy-like onoreganopolysiloxane of the present invention can be produced by an ordinary method for producing modified dimethylpolysiloxane.
  • it can be obtained by subjecting dimethylpolysiloxane in which a part of the methyl group is substituted with a hydrogen atom group and ⁇ -olefin to a hydrosilylation reaction.
  • the waxy organopolysiloxane of the present invention having the specific chemical structure and physical property values (melting point) as described above can be suitably used as a wax to be blended in cosmetics.
  • the cosmetic of the present invention comprises (i) an oily component and / or an organic solvent (hereinafter also referred to as “component (ii)”); (ii) the waxy organopolysiloxane (hereinafter “ Ingredient (also referred to as ⁇ )).
  • the oily component constituting one of the components (A) of the cosmetic of the present invention may be solid, semi-solid, or liquid as long as it is used in ordinary cosmetics. Examples include natural animal and vegetable oils, semi-synthetic oils and fats, hydrocarbon oils, higher alcohols, ester oils, fluorine oils, and silicone oils.
  • Natural animal and plant oils and fats” and “semi-synthetic oils and fats” used as oil components include Apogado oil, Amani oil, Almond oil, Ibotaro, Eno oil, Olive oil, Cacao fat, Kapok wax, Kaya oil, Carnaupa wax, Liver oil Candelilla wax, Beef tallow, Beef leg fat, Beef bone fat hardened beef tallow, Kiyonin oil, Whale wax, Hardened oil, Wheat germ oil, Sesame oil, Rice germ oil, Rice bran oil, Sugar cane wax, Southern power oil, Saflower oil , Shea butter, cinnamon oil, cinnamon oil, jojo valou, shellac wax, turtle oil, soybean oil, tea seed oil, camellia oil, evening primrose oil, corn oil, lard, rapeseed oil, Japanese kiri oil, nukarou, germ oil, horse fat Persic oil, palm oil, palm kernel oil, castor oil, hydrogenated castor oil, castor oil fatty acid
  • “Hydrocarbon oils” used as oil components include ozokerite, squalane, squalene, ceresin, paraffin, paraffin wax, liquid paraffin, liquid isoparaffin, pristane, polyisoptylene, microcrystalline wax, petrolatum, etc .; Lauric acid, myristic acid, palmitic acid, stearic acid, behejuic acid, undecylenic acid, oleic acid, linoleic acid, linolenic acid, arachidonic acid, eicosapentaenoic acid (EPA) ', docosahexaenoic acid (D HA ), Isostearic acid and erucic acid.
  • “Higher alcohol” used as an oil component includes lauryl alcohol
  • “Ester oil” used as an oil component includes isodecyl isononanoate, isotridecyl isononanoate, isononyl isononanoate, diisobutyl adipate, 2-hexyldecyl didipate, di-2-heptylundecyl adipate, monoisostearic acid n-alkyl glycol, isocetyl isostearate, trimethylolpropane triisostearate, ethylene glycol -2-ethyl hexylate, cetyl 2-ethylhexanoate, trimethylolpropane tri-1-ethylhexanoate, tetra-2- Ethylhexanoate pentaerythritol, cetyl octanoate, octyldodecyl gum ester, oleyl oleate, octyldodecy
  • fluorinated oil agent used as the oil component include perfluoropolyether, perfluorodecalin, perfluorooctane and the like.
  • the cosmetic of the present invention it is preferable to contain a silicone oil as the oil component because the dispersibility of the coconut-like organopolysiloxane is particularly excellent.
  • siloxane oil for example, dimethylpolysiloxane having a degree of polymerization (the number of keys in the siloxane chain) of 10 or more and a liquid to gum-like one in which a part of its methyl group is substituted are used.
  • the siloxane chain may have a branched chain or may be partially crosslinked.
  • substituents examples include a linear or branched alkyl group having 2 to 16 carbon atoms, an aryl group (for example, a phenyl group, a 2-phenylethyl group), an amino-substituted alkyl group (for example, one C 3 H 6 NH 2 , -C 3 H 6 NH C 2 H 4 NH 2 ), sugar derivative groups, glyceryl groups, polyglyceryl groups and the like. Particularly preferred is dimethylpolysiloxane having a degree of polymerization of 10 to 400.
  • the organic solvent constituting one of the components (A) of the cosmetic of the present invention may be any organic solvent used in ordinary cosmetics, such as lower alcohols such as ethanol and isopropanol, tetrachlorodifluoro Tan, C2-C9 polysiloxane (e.g., C2-C9 linear dimethylpolysiloxane, C4-C5 cyclic dimethyl polysiloxane, part of these methyl groups as a phenol group) For example). Particularly preferred is cyclic dimethylpolysiloxane having 4 to 5 carbon atoms.
  • lower alcohols such as ethanol and isopropanol
  • tetrachlorodifluoro Tan tetrachlorodifluoro Tan
  • C2-C9 polysiloxane e.g., C2-C9 linear dimethylpolysiloxane, C4-C5 cyclic dimethyl polysiloxane, part of these methyl groups as a
  • the component (A) is preferably blended in the cosmetic composition of the present invention in a proportion of 0.01 to 99.0% by mass, more preferably 0.1 to 95.0% by mass.
  • the above wax-like organopolysiloxane used in the cosmetic of the present invention (the wax-like organopolysiloxane of the present invention) is excellent in dispersibility in these oil components and organic solvents, so that Compared with cosmetics containing organopolysiloxane, the cosmetics of the present invention can be easily manufactured, and have storage stability and feel. It will be excellent.
  • the component (B) composed of the waxy organopolysiloxane of the present invention is added in an amount of 0.1 to 0.1 parts by mass of the oily component and / or the component (A) composed of an organic solvent.
  • the content is preferably 30 parts by mass, more preferably 0.2 to 50 parts by mass.
  • the cosmetics of the present invention can contain various components constituting normal cosmetics as optional components depending on the purpose.
  • optional components include surfactants.
  • surfactants have anionic, cationic, nonionic and amphoteric properties.
  • the surfactant is not particularly limited, and any surfactant can be used. Any of these can be used.
  • anionic surfactants include: fatty acid soaps such as sodium stearate triethanolamine, alkyl ether carboxylic acids and salts thereof, condensates of amino acids and fatty acids, alkane sulphones Acid salt, alkene sulfonate, fatty acid ester sulfonate, fatty acid amide sulfonate, formalin condensation sulfonate, alkyl sulfate ester salt, secondary higher alcohol sulfate ester, alkyl and aryl ether sulfate ester Salts, sulfate esters of fatty acid esters, sulfate esters of fatty acid alkylol amides, sulfate esters such as funnel oil, alkyl phosphates, ether phosphates, alkyl aryl ether phosphates, amide phosphates, N-acyl amino acid system Such as sex agents.
  • fatty acid soaps such as sodium stea
  • Suitable fatty acid surfactants include fatty acid soaps, hyacyl sulfonates, alkyl sulfonates, alkyl sulfonates, alkyl naphthalene sulfonates, alkyl sulfates, polyoxyethylene alkyls.
  • Examples include ether sulfates, alkyl amide sulfates, alkyl phosphates, alkyl amide phosphates, alkylalkyl taurine salts, N-long chain acyl amino acid salts, polyoxyethylene alkyl ether phosphates, and the like.
  • Cationic surfactants include alkylamine salts, polyamines and amino Examples include amine salts such as alcohol fatty acid derivatives, alkyl quaternary ammonium salts, aromatic quaternary ammonium salts, pyridinium salts, and imidazolium salts.
  • cetyl trimethyl ammonium chloride cetyl trimethyl ammonium chloride, stearyl trimethyl ammonium chloride, benenyl trimethyl ammonium chloride, and benzyldimethyl hydroxyethyl ammonium chloride
  • Stearyl chloride dimethylbenzil dimethylammonium, distearyldimethylammonium chloride, lauryltrimethylammonium chloride, myristyldimethylbenzylammonium chloride, lanolin fatty acid aminopropylethyl dimethylammonium sulfate and cetyl
  • quaternary ammonium salts such as triethylammomethylsulfate.
  • Nonionic surfactants include sorbitan fatty acid ester, glycerin fatty acid ester, polyglycerin fatty acid ester, propylene glycolic acid ester, polyethylene glycolic acid ester, sucrose acid ester, polyoxyethylene alkyl ether, polyoxypropylene alkyl ether, Polyoxyethylene alkyl phenyl ether, polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyoxyethylene propylene dallicol fatty acid ester, polyoxyethylene castor oil, polyoxy Ethylene hydrogenated castor oil, Polyoxyethylene phytostanolate enore, Polyoxyethylene phytosterol / lei Le, polyoxyethylene Kore Star Roh one Noreetenore, polyoxyethylene cholesteryl Rirueteru, Al force Noruami de, sugar ethers, such as sugar Ami de like.
  • Polyoxyethylene alkyl ether, alkylaryl polyoxyethylene ether, alkylol amide, alkylglycerin ether type polyoxyethylene ether, and polypropylene glycol ester are used as suitable nonionic surfactants.
  • amphoteric surfactants examples include betaine type (carboxybetaine 'sulfobetaine), amide betaine type, aminocarboxylate type, and imidazoline derivative type.
  • powders and colorants can be used depending on the purpose. If such powders and colorants are used in normal cosmetics, their shape (spherical, needle-like, plate-like, etc.), particle size (smoke-like, fine particles, pigment grade, etc.), particles Regardless of the structure (porous, nonporous, etc.), any can be used. Examples include powders such as inorganic powders, organic powders, and surfactant metal salt powders, and colorants such as colored pigments, pearl pigments, tar dyes, metal powder pigments, and natural dyes. .
  • inorganic powders include titanium oxide, zirconium oxide, zinc oxide, cerium oxide, magnesium oxide, barium sulfate, calcium sulfate, magnesium sulfate, calcium carbonate, magnesium carbonate, talc, my power, kaolin, sericite , Muscovite, synthetic mica, phlogopite, saucite, biotite, lithia mica, silicate, anhydrous silicate, aluminum silicate, magnesium silicate, aluminum silicate magnesium, calcium silicate magnesium, calcium silicate, barium silicate , Strontium karate, metal tandasteate, hydroxy patite, vermiculite, hydrite, bentonite, montmorillonite, hectorite, zeolite, ceramic powder, dicalcium phosphate, alumina, aluminum hydroxide, Boron, and silica.
  • organic powders include: 'polyamide powder, polyester powder, polyethylene powder, polypropylene powder, polystyrene powder, polyuretan, benzoguanamine powder, polymethylenobenzoguanamine powder, tetrafluoroethylene powder, polymethylol methacrylate Powder, Cellulose, Synolec powder, Nylon powder, 1 2 Nylon, 6 Nylon, Silicone powder, Styrene 'acrylic acid copolymer, Dibulebenzene / Styrene copolymer Examples thereof include coalescence, vinyl resin, urea resin, phenol resin, fluororesin, carbon resin, acrylic resin, melamine resin, epoxy resin, polycarbonate resin, microcrystalline fiber powder, starch powder, lauroyl lysine and the like. Furthermore, an organic powder mainly composed of one [S i one o—] n — skeleton is also preferable. In this case, a part of the molecule may have one S i (CH 2 ) m -
  • surfactant metal salt powder examples include zinc stearate, aluminum stearate, calcium stearate, magnesium stearate, zinc myristate, magnesium myristate, zinc cetyl phosphate, calcium cetyl phosphate. And zinc sodium cetyl phosphate.
  • colored pigments include inorganic red pigments such as iron oxide, iron hydroxide and iron titanate, inorganic brown pigments such as ⁇ / iron monoxide, inorganic yellow pigments such as yellow iron oxide and ocher, black acidification Inorganic black pigments such as iron and carbon black, inorganic purple pigments such as manganese violet and cobalt violet, inorganic green pigments such as hydroxide hydride, acid chrome, acid cobalt and cobalt titanate, inorganic blue pigments such as bitumen and ultramarine blue Examples include pigments, tar dyes raked, natural dyes raked, and synthetic resin powders obtained by combining these powders.
  • inorganic red pigments such as iron oxide, iron hydroxide and iron titanate
  • inorganic brown pigments such as ⁇ / iron monoxide
  • inorganic yellow pigments such as yellow iron oxide and ocher
  • black acidification Inorganic black pigments such as iron and carbon black
  • inorganic purple pigments such as manganes
  • pearl pigments include: Titanium oxide-coated my strength, oxysalt-bismuth, titanium oxide-coated bismuth oxychloride, titanium oxide-coated talc, fish scale foil, titanium oxide-coated colored mica; Examples include powder, kappa powder, and stainless steel powder.
  • the tar dyes are Red No. 3, Red No. 10 4, Red No. 10 6, Red No. 201, Red No. 20, Red No. 2, No. 04, Red No. 20, No. 5, Red No. 20 , Red 2 2 6, Red 2 2 7, Red 2 2 8, Red 2 3 0, Red 4 0 1, Red 5 0 5, Yellow 4, Yellow 5, Yellow 2 0 2 No., Yellow 2 0 3, Yellow 2 0 4, Yellow 4 0 1, Blue 1, Blue 2, Blue 2 0 1, Blue 4 0 4, Green 3, Green 2 0 1, Green No. 2, No. 4, Green No. 2, No. 5, Orange No. 2, No. 1, Orange No. 2, No. 3, Orange No. 2, No. 4, Orange No. 2, No. 6, No. 2, No.
  • the cosmetic composition of the present invention includes a thickening agent, a suspension agent, or a milk emulsion stabilizing stabilizer.
  • a thickening agent water-soluble in water 55 High molecular weight molecules can be included.
  • water-soluble high molecular weight molecules are Aara Rabibia Ago gum, Toragara Gaka Kantoto, Gaga Rakutan Tan, Kikiyarolobbugagammu, Guguaga Gamumu, Kakara Rajagagammu, Kakaragagiginanan, Pepe Kukuchintin, Agar, Quincy Sustained ((Mamarumume Mouth)), Dendungpun ((Kokomeme, Tomoromoro Cocoro) Shishi, Nono, Reiko, Kokomugigi)), Aaruru Gekkokororoidodo, Totrarunto Togagammu, Loroca Casto Stobien Ngagammu, etc.
  • Starch polymers such as methethylyl dihydrododroxy sip mouth pirulu dedenpump, methyl cellulose, ethyl cellulose, methyl hydroxypropenoresenorelose, carboxymethylenocellulose, hydroxymethinoresose, hydroxypropinole Senorelose, Nitrosenorelose, Senorelose sulfate
  • Acrylic polymers such as lithium, polyethyl acrylate, polyacrylamide, other synthetic water-soluble polymers such as polyethyleneimine and cationic polymers, bentonite, magnesium aluminum silicate, montmorillonite, beidellite, nontronite Inorganic water-soluble polymers such as saponite, hectorite, and anhydrous carboxylic acid.
  • Anionic water-soluble polymers include gum arabic, carrageenan, pectin, xanthan gum, sodium alginate, carboxybier polymer, dermatan sulfate, keratan sulfate, heparan sulfate and their salts. Is mentioned.
  • cationic water-soluble polymers include cationic modified cellulose ether derivatives (polymer JR (UCC), etc.), cationic starch, cationized guar gum derivatives, diarreno-resin methinoream monum chloride.
  • amphoteric water-soluble polymer a copolymer of a monomer having an anionic group such as a carboxyl group or a sulfonic acid group and a monomer having a basic nitrogen, a polymer or copolymer of a carboxybetaine type monomer
  • examples thereof include a copolymer of a monomer having an anionic group and a monomer having a basic nitrogen-containing group.
  • amphoteric water-soluble polymer commercially available ones can be used, and examples thereof include a Zaralyl acrylate quaternary ammonium salt / acrylamide copolymer such as Marquat Plus 3330 (manufactured by Calgon).
  • a Zaralyl acrylate quaternary ammonium salt / acrylamide copolymer such as Marquat Plus 3330 (manufactured by Calgon).
  • nonionic water-soluble polymers examples include galactan, methyl cellulose, methyl hydroxypropyl cellulose, hydroxypropyl cellulose, hydroxyxetyl cellulose, and dextrin.
  • the cosmetic of the present invention can also contain a film-forming agent such as polyvinyl alcohol or polybulurpyrrolidone, which are also water-soluble polymers.
  • a film-forming agent such as polyvinyl alcohol or polybulurpyrrolidone, which are also water-soluble polymers.
  • the components used in ordinary cosmetics within the range that does not hinder the effects of the present invention such as water, film-forming agent, oil-soluble gelling agent, organically modified viscosity Soil minerals, resins, UV absorbers, UV scattering agents, moisturizers, antiseptics, antibacterial agents, fragrances, chemicals, salts, antioxidants, pH adjusters, chelating agents, refreshing agents, anti-inflammatory agents, skin care ingredients ( Whitening agents, cell activators, rough skin improving agents, blood circulation promoters, skin astringents, antiseborrheic agents, etc.), vitamins, amino acids, nucleic acids, hormones, inclusion compounds, proteins or proteins This is where you can add white and white decomposition products. .
  • oil-soluble soluble gellizing agents examples include: Aarluminiminumum stetea alleleate, Magnum nemus mustetea alleleate, Any metal metal genus, such as tartto, NN——Laurauroloyroo LL LL—Gogururutataminic acid, baboon, ⁇ ——jiji ⁇ —Buticyllumamimin Any amino acid-induced conductor, such as dedextostriline papal, 55 estesteryl mimititinate, estesteryl, dedextritrinsate stea allyl phosphate, 22 ——Hetexyl Hexasanate Paparrimimitate Acid Desquist Phosphoglycol fatty acid estesterol, sucrose sugar Paparrumimititinate estesterol, sucrose sugar stetea allyl phosphate estesterol, etc. Benzylidylidene Desulene Induced Conductor, Didimethytilyl Benbenzil Lilde Dodecisyl
  • Mouth-necked clay clay organic mutated clay clay, such as dimethimechininoreresio geo-octata de decile Gegerulich pills that can be selected from mineral minerals are listed. .
  • any benzoic acid-based purple ultraviolet external absorption / absorption absorber such as paparala aminominobenzoic acid can be used.
  • Any anantral bisulphinic acid-based purple ultraviolet external absorption absorber such as methacrylic acid, anantral bisulphilic acid, etc.
  • any salicylicylic acid-based violet ultraviolet ray such as methacrylic acid salicylicylic acid, etc.
  • Shishikey cinnamate 22--Ethylyl hexylyl such as any key cinnamate-based violet UV-absorbing absorber, 22, 24, 44-jijihihi dodrolo Kishishibenbenzozofuenonon Any of the Benzozofuenonone-based UV-absorption absorbers, such as urocarcaninic acid ethyryl, etc. 44, 11 tt 1 1 1 1 Petittille 1 44, 1 1 1 1 Examples include ultraviolet external radiation absorbing and absorbing agents. .
  • moisturizing moisturizers examples include guglirice sericin, sosol rubbito tolu, ethic lentil glico cocool, propylopirelle 2200 Pupiropipirenren Gurico Kono Norere, 11, 33, 3 buchichichirenrenguririkokoruru, gugururu coco sous, Kikisiriri Tono Norere, Mama Nore Rechito Tono Norere, Poporirieje Titreleng Glicoco nonorele,, Hyaiaruoru oral oxalic acid, Condordroiititin sulphuric acid, Pipirolo Lido Doncarca borbonic acid salt, Poporilio Oxyxie citylene Methicyl Rudadar Lucoco Sicido, Poporily
  • Preservatives and antibacterial agents include paraoxybenzoic acid alkyl ester, benzoic acid, 25 sodium benzoate, sorbic acid, potassium sorbate, phenoxyethanol, etc.
  • Antibacterial agents include benzoic acid, salicylic acid, coalic acid, sorbic acid, Parabenzoic acid anolequinole estenole, ⁇ Lacronore Metacresol Monole, Hexaclo oral Fen, Benzalkonium Chloride, Chlorhexidine Chloride, Trichlorocarbanilide, Sensation Photoelements, phenoxyethanol, ethylparaben, butylparaben, etc.
  • Antioxidants include tocopherol, butyl hydroxyaesole, dibutylhydroxytoluene, phytic acid, etc.
  • pH adjusters include lactic acid, citrate, glycolic acid, succinic acid, tartaric acid, dl-malic acid, Potassium carbonate, sodium bicarbonate, ammonium bicarbonate, etc.
  • chelating agents alanine, edetic acid sodium salt, sodium polyphosphate, sodium metaphosphate, phosphoric acid, etc.
  • L-menthol As a cooling agent, L-menthol, examples of anti-inflammatory agents such as forceful include alantoin, glycyrrhizic acid opium salt, glycyrrhetinic acid and stearyl glycyrrhetinate, tranexamic acid, and azulene.
  • Skin beautifying ingredients include placenta extract, whitening agent such as arbutin, dartathione, yukinoshita extract, royal jelly, photosensitizer, cholesterol derivative, cell activator such as calf blood extract, rough skin improver, nonylate salmonylylami Nicotinic acid benzyl ester, nicotinic acid ⁇ -butoxy chinole ester, capsaicin, gingerone, cantalis tincture, ictamonore, caffeine, tannic acid, hibo noreneo 1 nicotinic acid tocopheronole, inositolole hexicotinate, Circulatory agents such as cyclandrate, cinnarizine, tolazoline, acetylcholine, verapamil, cephalanthin, ⁇ -oryzanol and sodium dextran sulfate, skin astringents such as zinc oxide and tannic acid, iow and titan
  • Vitamins such as vitamin coconut oil, retinol, retinol acetate, retinol palmitate, vitamin A such as riboflavin, riboflavin butyrate, flavin adenine nucleotides, pyridoxine hydrochloride, pyridoxine syndio Vitamin B 6 such as octanoate, pyridoxine tripalmitate, vitamin B 12 and its derivatives, vitamin B 15 such as vitamin B 15 and its derivatives, L-ascorbic acid, L-ascorbic acid dipalmitate Vitamin C such as ester, L-ascorbic acid 1-sodium sulfate, L-ascorbic acid phosphate dieste rudikarium, vitamin D such as ergocalciferol, cholecalcifue mouth, etc., ⁇ -tocopherol, j3-tocophero Nore, ⁇ -Toco Hue Mouth, Acetic Acid dl— “—Tocophere Mouth,
  • Estra examples include diol and ethenyl estradiol.
  • protein or protein degradation product examples include soy protein, silk fiproin, and elastin in addition to the gelatin and collagen described above.
  • the cosmetics of the present invention include emulsions such as water-in-oil emulsions and oil-in-water emulsions, and oily, creamy, mousse, gel, waxes are used according to the purpose of use. It can have various forms such as a stick or stick.
  • the cosmetic of the present invention is not limited by the production method, and can be produced by a normal production method.
  • it can be produced by mixing each component.
  • a method is preferred in which a roux-like organopolysiloxane, an oil component and ⁇ or an organic solvent are mixed and then mixed with other components.
  • GPC measurement conditions are as follows.
  • RI detector Refractive index (RI) detector “RI-504R” (GL Science Co., Ltd.) • Calibration curve: Measured using 10 kinds of standard polystyrene (molecular weight 1.2 X 10 3 to 2.75 X 10 6 ) manufactured by Showa Denko KK
  • the number of repetitions in the formula is an average value.
  • a long-chain alkyl group derived from a long-chain ⁇ -olefin is used as the group (a) constituting R in the general formula (1).
  • waxy silicone (1) the number ratio of (a) group, (b) group, (c) group (methyl group) is about 10: 1.5: 88.5, The proportion of group (a) is approximately 40% by mass.
  • a long-chain alkyl group derived from a long-chain ⁇ -olefin is used as the group (a) constituting R in the general formula (1).
  • waxy silicone (2) the number ratio of (a) group, (b) group, (c) group (methyl group) is about 18: 2: 80, and (a) The proportion of groups is approximately 50% by weight.
  • Wax-like silicone (3) consists of alkoxycarbonylalkyl groups (long chain organic groups containing heteroatoms) introduced by hydrosilylation and esterification reactions. ) As a group of (a) constituting R of the general formula (1).
  • waxy silicone (3) the number ratio of (a) group, (b) group, (c) group (methyl group) is approximately 25: 2: 73, and (a) the proportion of radicals is almost 65 weight 0/0.
  • the obtained waxy organopolysiloxane differs from that of the present invention in that the ratio of the group (a) to the whole molecule is 75% by mass and exceeds 70% by mass. This is called waxy silicone (C1).
  • Measurement was performed using a differential scanning calorimeter “DSC-6200” (manufactured by Seiko Denshi Kogyo Co., Ltd.) using 5 mg of the sample.
  • DSC-6200 differential scanning calorimeter
  • the temperature was raised to 180 ° C under the condition of 10 ° C / min (the first temperature rise process), then at 180 ° C
  • let stand for 5 minutes at 30 ° C, then 170 ° C under the condition of 10 ° CZmin (Second heating process).
  • the temperature (Tm) at the maximum peak of the endothermic curve in the second temperature rising process was taken as the melting point.
  • a water-in-oil solid cream (a cosmetic of the present invention) was produced as follows.
  • Wax-like silicone (1) 30 parts by mass
  • a water-in-oil solid cream was prepared in the same manner as in Example 4 except that waxy silicone (2) 30 parts by mass was used instead of waxy silicone (1) 30 parts by mass.
  • Example 6 Preparation example of water-in-oil solid cream
  • Waxy silicone (1) A water-in-oil solid cream was prepared in the same manner as in Example 4 except that 30 parts by weight of waxy silicone (3) was used instead of 30 parts by weight.
  • Example 7 Example of preparation of lipstick
  • a lipstick (the cosmetic of the present invention) was produced as follows.
  • Wax silicone (1) 30 parts by mass
  • Wax-like silicone (1) A solid stick-like lipstick was prepared in the same manner as in Example 7 except that 30 parts by mass of wax-like silicone (2) was used.
  • Waxy silicone (1) Wax silicone instead of 30 parts by mass (3) A solid stick-like lipstick was prepared in the same manner as in Example 7 except that 30 parts by mass was used.
  • a foundation (a cosmetic of the present invention) was produced as follows.
  • Wax silicone (1) 15 parts by mass
  • Waxy silicone (1) An emulsion foundation was prepared in the same manner as in Example 10 except that 15 parts by weight of waxy silicone (2) was used.
  • Waxy silicone (1) Prepare an emulsion foundation in the same manner as in Example 10 except that 15 parts by weight of waxy silicone (3) was used. did.
  • an eyebrow ink (a cosmetic of the present invention) was produced as follows.
  • Wax-like silicone (1) 1 8 parts by mass
  • Waxy silicone (1) 1 An emulsion eyeliner was prepared in the same manner as in Example 13 except that 8 parts by weight of waxy silicone (2) 1 was used.
  • Waxy silicone (1) 1 An emulsion eyeliner was prepared in the same manner as in Example 13 except that 8 parts by weight of waxy silicone (3) 1 was used instead of 8 parts by weight. Industrial applicability
  • the roux-like organopolysiloxane of the present invention has good dispersibility in an oily component and an organic solvent, and thus can be suitably used as a cosmetic ingredient.

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Abstract

La présente invention décrit des cires organopolysiloxanes pour cosmétiques dont les structures chimiques correspondent à la formule générale (1) et dont les points de fusion sont compris entre 30 et 120 °C. Lesdites cires présentent d’excellentes propriétés de dispersion dans les milieux huileux et les solvants organiques, et s’incorporent aisément à des produits cosmétiques. Elles permettent en outre la fabrication aisée de produits cosmétiques dont les propriétés de stabilité lors du stockage et de douceurau toucher sont excellentes : (1) [où au moins un groupement R est un groupement organique à longue chaîne (a) comprenant soit une longue chaîne en C17-C300, soit un hétéroatome, à la condition que le groupement (a) représente au maximum 70 % en masse de la masse totale de la molécule ; et la moyenne numérique de n est égale à un nombre compris entre 50,0 et 1 000,0]. La présente invention a également pour objet des produits cosmétiques obtenus en mélangeant (A) un milieu huileux et/ou un solvant organiqueavec (B) une cire organopolysiloxane telle que décrite ci-dessus ; lesdits produits sont de fabrication aisée et présentent d’excellentes propriétés de stabilité lors du stockage et de douceur au toucher.
PCT/JP2005/016980 2004-09-06 2005-09-06 Cires organopolysiloxanes pour cosmétiques et produits cosmétiques les contenant Ceased WO2006028265A1 (fr)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013190703A1 (fr) * 2012-06-21 2013-12-27 L'oreal Composition cosmétique solide comprenant une huile d'hydrocarbure non volatile, des cires et une teneur élevée en huile de silicone phénylée non volatile

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP4965145B2 (ja) * 2006-03-30 2012-07-04 株式会社コーセー 水中油型睫用化粧料
JP5079317B2 (ja) * 2006-12-12 2012-11-21 モメンティブ・パフォーマンス・マテリアルズ・ジャパン合同会社 毛髪化粧料組成物
JP6127699B2 (ja) * 2013-05-13 2017-05-17 日油株式会社 化粧料用組成物

Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4844826A (en) * 1987-10-09 1989-07-04 Th. Goldschmidt Ag Use of organosilicon compounds to thicken oils
JPH0264115A (ja) * 1988-08-30 1990-03-05 Nippon Unicar Co Ltd ポリジアルキルシロキサン−オレフィンブロック共重合体、その製造法、該共重合体を含を組成物及び該組成物からつくられた成形品
JPH05262616A (ja) * 1992-03-19 1993-10-12 Toshiba Silicone Co Ltd 化粧料
JPH069367A (ja) * 1992-03-09 1994-01-18 Dow Corning Corp 乾燥皮膚の処置方法
JPH0873744A (ja) * 1994-07-01 1996-03-19 Kao Corp シリコーン油固化剤及びそれを含有する化粧料
GB2299024A (en) * 1995-03-24 1996-09-25 Unilever Plc Antiperspirant containing an alkyl ester siloxane
JPH10500431A (ja) * 1995-04-18 1998-01-13 ローヌ−プーラン シミ エステル官能基を含有するシリコーンワックスの油状媒体を増粘させるための用途
JP2002029918A (ja) * 2000-07-12 2002-01-29 Shin Etsu Chem Co Ltd 固形化粧料
WO2002077071A1 (fr) * 2001-03-15 2002-10-03 Nippon Unicar Company Limited Organopolysiloxane cireux et composition de toner le contenant
JP2004224729A (ja) * 2003-01-23 2004-08-12 Nippon Unicar Co Ltd ワックス状オルガノポリシロキサンを含んでなる化粧料

Patent Citations (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4844826A (en) * 1987-10-09 1989-07-04 Th. Goldschmidt Ag Use of organosilicon compounds to thicken oils
JPH0264115A (ja) * 1988-08-30 1990-03-05 Nippon Unicar Co Ltd ポリジアルキルシロキサン−オレフィンブロック共重合体、その製造法、該共重合体を含を組成物及び該組成物からつくられた成形品
JPH069367A (ja) * 1992-03-09 1994-01-18 Dow Corning Corp 乾燥皮膚の処置方法
JPH05262616A (ja) * 1992-03-19 1993-10-12 Toshiba Silicone Co Ltd 化粧料
JPH0873744A (ja) * 1994-07-01 1996-03-19 Kao Corp シリコーン油固化剤及びそれを含有する化粧料
GB2299024A (en) * 1995-03-24 1996-09-25 Unilever Plc Antiperspirant containing an alkyl ester siloxane
JPH10500431A (ja) * 1995-04-18 1998-01-13 ローヌ−プーラン シミ エステル官能基を含有するシリコーンワックスの油状媒体を増粘させるための用途
JP2002029918A (ja) * 2000-07-12 2002-01-29 Shin Etsu Chem Co Ltd 固形化粧料
WO2002077071A1 (fr) * 2001-03-15 2002-10-03 Nippon Unicar Company Limited Organopolysiloxane cireux et composition de toner le contenant
JP2004224729A (ja) * 2003-01-23 2004-08-12 Nippon Unicar Co Ltd ワックス状オルガノポリシロキサンを含んでなる化粧料

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2013190703A1 (fr) * 2012-06-21 2013-12-27 L'oreal Composition cosmétique solide comprenant une huile d'hydrocarbure non volatile, des cires et une teneur élevée en huile de silicone phénylée non volatile
WO2013191300A1 (fr) * 2012-06-21 2013-12-27 L'oreal Composition cosmétique solide comprenant une huile hydrocarbonée non volatile, des cires et une teneur élevée en huile de silicone phénylée non volatile
CN104321109A (zh) * 2012-06-21 2015-01-28 莱雅公司 包含非挥发性烃化油、蜡和高含量非挥发性苯代硅油的化妆品固体组合物
US11389381B2 (en) 2012-06-21 2022-07-19 L'oreal Cosmetic solid composition comprising a non volatile hydrocarbonated oil, waxes and a high content from non volatile phenylated silicone oil

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