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WO2006015149A1 - Bar soap compositions with enhanced lather properties - Google Patents

Bar soap compositions with enhanced lather properties Download PDF

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Publication number
WO2006015149A1
WO2006015149A1 PCT/US2005/026845 US2005026845W WO2006015149A1 WO 2006015149 A1 WO2006015149 A1 WO 2006015149A1 US 2005026845 W US2005026845 W US 2005026845W WO 2006015149 A1 WO2006015149 A1 WO 2006015149A1
Authority
WO
WIPO (PCT)
Prior art keywords
weight
soap
peg
molecular weight
polyol
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2005/026845
Other languages
French (fr)
Inventor
Robert Demson
James Dalton
Jayesh Patel
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dial Corp
Original Assignee
Dial Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dial Corp filed Critical Dial Corp
Publication of WO2006015149A1 publication Critical patent/WO2006015149A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D10/00Compositions of detergents, not provided for by one single preceding group
    • C11D10/04Compositions of detergents, not provided for by one single preceding group based on mixtures of surface-active non-soap compounds and soap
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D17/00Detergent materials or soaps characterised by their shape or physical properties
    • C11D17/0047Detergents in the form of bars or tablets
    • C11D17/006Detergents in the form of bars or tablets containing mainly surfactants, but no builders, e.g. syndet bar
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16Organic compounds
    • C11D3/37Polymers
    • C11D3/3703Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • C11D3/3707Polyethers, e.g. polyalkyleneoxides
    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D1/00Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
    • C11D1/88Ampholytes; Electroneutral compounds
    • C11D1/92Sulfobetaines ; Sulfitobetaines

Definitions

  • Soap commonly defined as the salt of a fatty acid
  • aqueous caustic soda with fats and oils from natural sources to form a surfactant molecule.
  • sodium soap i.e. basic soap
  • the formulation chemist is challenged to find a skillful combination of additives within the hundreds of synthetic detergents and innumerable plasticizers, binders, moisturizers and fillers available that will fulfill consumer expectations beyond the manufacture of just an effective cleansing agent.
  • the incorporation of an additive, or combination of additives, to produce an acceptable end product, while maintaining both manufacturing capabilities and processing efficiencies must be considered within formulation development.
  • This invention relates to solid soap compositions which have greatly improved lather creaminess (lotion like feel) and bar slip in use. These improvements are achieved through a synergistic combination of high and low molecular weight polyols along with a co-surfactant.
  • a vegetable based fatty acid solid soap when combined with about 0.10 to 5.00% by weight of cocoamidopropyl hydroxy sultaine (amphoteric co- surfactant) and about 0.10 to about 4.00% by weight of PEG-12 (low molecular weight polyol) and about 0.01% to about 1.00% by weight of PEG-90M (high molecular weight polyol) results in a solid soap composition with greatly improved lather creaminess and slip in use.
  • these additions are used at relatively low levels and allows for a cost effective way to deliver these enhanced properties to a basic soap formula, which does not offer these properties.
  • a “low molecular weight” polyol we mean a polyol having a molecular weight below about 3000.
  • a “high molecular weight polyol is one having a molecular weight of about 20,000 or more.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Cosmetics (AREA)
  • Detergent Compositions (AREA)

Abstract

This invention relates to solid soap compositions which have greatly improved lather creaminess (lotion like feel) and bar slip in use. These improvements are achieved through a synergistic combination of high and low molecular weight polyols along with a co-surfactant. More specifically, it ha been found that a vegetable based fatty acid soap when combined with about 0.10 to 5.00% by weight of cocoamidopropyl hydroxy sultaine (amphoteric co-surfactant) and about 0.10 to about 4.00% by weight of PEG-12 (low molecular weight polyol) and about 0.01% to about 1.00% by weight of PEG-90M (high molecular weight polyol) results in a soap composition with greatly improved lather creaminess and slip in use.

Description

Title: BAR SOAP COMPOSITIONS WITH ENHANCED LATHER
PROPERTIES
Inventors: Robert Demson, James Dalton, Jayesh Patel
Background of Invention
[0001] Soap, commonly defined as the salt of a fatty acid, is the reaction product of aqueous caustic soda with fats and oils from natural sources to form a surfactant molecule. In this respect sodium soap (i.e. basic soap) alone, although having both adequate cleansing and foaming characteristics, without additives does not exhibit the more desirable lather attributes generally associated with detergent, or synthetic surfactant systems as found in more costly combination or synthetic bar soap formulas. To enhance the foaming and/or lather attributes of basic soap the formulation chemist is challenged to find a skillful combination of additives within the hundreds of synthetic detergents and innumerable plasticizers, binders, moisturizers and fillers available that will fulfill consumer expectations beyond the manufacture of just an effective cleansing agent. Furthermore, the incorporation of an additive, or combination of additives, to produce an acceptable end product, while maintaining both manufacturing capabilities and processing efficiencies must be considered within formulation development.
[0002] Given this large array of materials, finding a unique combination yielding enhanced lather attributes in a basic soap while maintaining manufacturing and processing efficiencies is accomplished in the present invention. Detailed Description
[0003] This invention relates to solid soap compositions which have greatly improved lather creaminess (lotion like feel) and bar slip in use. These improvements are achieved through a synergistic combination of high and low molecular weight polyols along with a co-surfactant. More specifically, we have found that a vegetable based fatty acid solid soap when combined with about 0.10 to 5.00% by weight of cocoamidopropyl hydroxy sultaine (amphoteric co- surfactant) and about 0.10 to about 4.00% by weight of PEG-12 (low molecular weight polyol) and about 0.01% to about 1.00% by weight of PEG-90M (high molecular weight polyol) results in a solid soap composition with greatly improved lather creaminess and slip in use. As shown below, these additions are used at relatively low levels and allows for a cost effective way to deliver these enhanced properties to a basic soap formula, which does not offer these properties.
Figure imgf000003_0001
[0004] By a "low molecular weight" polyol we mean a polyol having a molecular weight below about 3000. A "high molecular weight polyol is one having a molecular weight of about 20,000 or more. Example(s): [0005] To test the effectiveness of this invention, a series of soap bars were prepared. The soap employed in these bars was a vegetable based soap having an 80:20 ratio of palm oil fatty acids to coco fatty acids.
[0006] A panel of people were assembled to wash their hands with the soap bars shown in the following table. Each panelist was asked to rate the lather creaminess and bar slip as "poor", "average" or "excellent". PEG-12 was used at a level of 2.5% by weight; cocoamidopropyl hydroxysultaine at a level of 1.5% by weight; and PEG-90M at a level of 0.06% by weight.
Figure imgf000004_0001
[0007] From the above chart, it is clear that both the plain bar soap and bar soap with PEG-
12 were rated as "poor". The bars which included the amphoteric (hydroxysultaine); the PEG-90M and the combination of PEG-12 and PEG-90M all were judged as "average". However, the bars which contained the hydroxysultaine, PEG-12 and PEG-90M were rated as "excellent" in lather creaminess and bar slip.

Claims

Claims
1. A solid soap composition having enhanced lather properties comprising from about 75 to 90% by weight of an alkali metal salt of a fatty acid, from about 0.10 to about 5.0% by weight of an amphoteric surfactant, about 0.10 to about 4.0% by weight of a low molecular weight polyol, and about 0.10% to about 1.0% by weight of a high molecular weight polyol.
2. The soap composition of claim 1 wherein said amphoteric surfactant is cocoamidopropyl hydroxy sultaine.
3. The soap composition of claim 2 wherein said low molecular weight polyol is PEG- 12.
4. The soap composition of claim 3 wherein said high molecular weight polyol is PEG- 9OM.
5. The soap composition of claim 4 wherein said soap is a vegetable based soap having an 80/20 ratio of palm oil fatty acids to coco fatty acids.
6. A solid soap composition having enhanced lather properties comprising from about 75 to about 90% of an alkali metal salt of fatty acids, about 1.5% by weight of an amphoteric surfactant, about 2.5% by weight of PEG-12, and about 0.06% by weight of PEG-90M.
PCT/US2005/026845 2004-07-29 2005-07-28 Bar soap compositions with enhanced lather properties Ceased WO2006015149A1 (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US59202604P 2004-07-29 2004-07-29
US60/592,026 2004-07-29

Publications (1)

Publication Number Publication Date
WO2006015149A1 true WO2006015149A1 (en) 2006-02-09

Family

ID=35787455

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2005/026845 Ceased WO2006015149A1 (en) 2004-07-29 2005-07-28 Bar soap compositions with enhanced lather properties

Country Status (1)

Country Link
WO (1) WO2006015149A1 (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110135586A1 (en) * 2008-08-20 2011-06-09 Kpss - Kao Professional Salon Services Gmbh Solid anhydrous composition for keratin fibers
WO2011073906A1 (en) * 2009-12-18 2011-06-23 Koninklijke Philips Electronics N.V. Polyethylene glycol containing composition for shaving
WO2015075086A1 (en) * 2013-11-25 2015-05-28 Unilever Plc Soap bar formulations with improved skin softness comprising nonionic polymer structuring system

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040058831A1 (en) * 2002-07-18 2004-03-25 Unilever Home And Personal Care Usa, Division Of Conopco, Inc. Exfoliating and moisturizing toilet bar
US20050227887A1 (en) * 2004-04-13 2005-10-13 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Combination toilet bar composition

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20040058831A1 (en) * 2002-07-18 2004-03-25 Unilever Home And Personal Care Usa, Division Of Conopco, Inc. Exfoliating and moisturizing toilet bar
US20050227887A1 (en) * 2004-04-13 2005-10-13 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Combination toilet bar composition

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20110135586A1 (en) * 2008-08-20 2011-06-09 Kpss - Kao Professional Salon Services Gmbh Solid anhydrous composition for keratin fibers
US20170196785A1 (en) * 2008-08-20 2017-07-13 Kao Germany Gmbh Solid anhydrous composition for keratin fibers
US10849837B2 (en) 2008-08-20 2020-12-01 Kao Germany Gmbh Solid anhydrous composition for keratin fibers
WO2011073906A1 (en) * 2009-12-18 2011-06-23 Koninklijke Philips Electronics N.V. Polyethylene glycol containing composition for shaving
CN102655884A (en) * 2009-12-18 2012-09-05 皇家飞利浦电子股份有限公司 Compositions containing polyethylene glycol for shaving
WO2015075086A1 (en) * 2013-11-25 2015-05-28 Unilever Plc Soap bar formulations with improved skin softness comprising nonionic polymer structuring system
CN105765048A (en) * 2013-11-25 2016-07-13 荷兰联合利华有限公司 Soap bar formulations comprising a nonionic polymer structuring system with improved skin softness
US9861571B2 (en) 2013-11-25 2018-01-09 Conopco, Inc. Soap bar formulations with improved skin softness comprising nonionic polymer structuring system
EA030328B1 (en) * 2013-11-25 2018-07-31 Юнилевер Н.В. Soap bar formulations with improved skin softness comprising nonionic polymer structuring system
CN105765048B (en) * 2013-11-25 2019-03-12 荷兰联合利华有限公司 Soap bar formulations containing nonionic polymer structuring systems with improved skin softness
EP3074498B1 (en) 2013-11-25 2019-04-17 Unilever Plc. Soap bar formulations with improved skin softness comprising nonionic polymer structuring system

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