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WO2004111376A1 - Wooden fire door - Google Patents

Wooden fire door Download PDF

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Publication number
WO2004111376A1
WO2004111376A1 PCT/JP2004/008192 JP2004008192W WO2004111376A1 WO 2004111376 A1 WO2004111376 A1 WO 2004111376A1 JP 2004008192 W JP2004008192 W JP 2004008192W WO 2004111376 A1 WO2004111376 A1 WO 2004111376A1
Authority
WO
WIPO (PCT)
Prior art keywords
wooden
fire
fire door
combustion
wooden fire
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2004/008192
Other languages
French (fr)
Japanese (ja)
Inventor
Yoichiro Kuroiwa
Shinichi Sugawara
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KUROIWA MIE
Original Assignee
KUROIWA MIE
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KUROIWA MIE filed Critical KUROIWA MIE
Publication of WO2004111376A1 publication Critical patent/WO2004111376A1/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • EFIXED CONSTRUCTIONS
    • E06DOORS, WINDOWS, SHUTTERS, OR ROLLER BLINDS IN GENERAL; LADDERS
    • E06BFIXED OR MOVABLE CLOSURES FOR OPENINGS IN BUILDINGS, VEHICLES, FENCES OR LIKE ENCLOSURES IN GENERAL, e.g. DOORS, WINDOWS, BLINDS, GATES
    • E06B5/00Doors, windows, or like closures for special purposes; Border constructions therefor
    • E06B5/10Doors, windows, or like closures for special purposes; Border constructions therefor for protection against air-raid or other war-like action; for other protective purposes
    • E06B5/16Fireproof doors or similar closures; Adaptations of fixed constructions therefor
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62CFIRE-FIGHTING
    • A62C2/00Fire prevention or containment
    • A62C2/06Physical fire-barriers

Definitions

  • the present invention relates to a wooden fire door which is used, for example, as a door of a house or a company and has a fire prevention performance of trapping fire or heat when a fire occurs.
  • the specific fire prevention equipment 60 is made of steel and its power is not recognized. Therefore, the fire door is generally made of steel. Steel fire doors have the drawbacks of being strong, warping with heavy heat, and having high radiant heat (5-8 times the size of wood).
  • Japanese Patent Application Laid-Open No. 7-208033 discloses a paulownia laminated plate obtained by laminating a paulownia glulam
  • Japanese Patent Application Laid-Open No. 7-259445 discloses a paulownia glue laminated lumber and a thermosetting resin.
  • a laminated resin laminate is disclosed.
  • Japanese Unexamined Patent Publication No. 7-293127 discloses a combination of paulownia wood and non-combustible paper
  • Japanese Unexamined Patent Publication No. 7-324561 discloses a combination of a paulownia wood and phenol foam. Have been. Further, Japanese Unexamined Patent Publication No.
  • Japanese Unexamined Patent Publication No. 2000-179245 discloses a combination of a paulownia wood and a volcanic glass fiber plate. Is disclosed. Further, Japanese Patent Application Laid-Open No. 2000-310090 discloses a structure for preventing the warp of the paulownia wood, and Japanese Patent Application Laid-Open No. 2001-17560 discloses a structure for facilitating escape at the time of disaster.
  • the conventional wooden fire doors have a problem in terms of, for example, deterioration in fire prevention performance due to aging, manufacturing costs, or fire prevention performance in the event of fire, and can be sufficiently satisfied. No product has been obtained. In other words, fire performance cannot be obtained for 60 minutes in an average combustion test at approximately 900 ° C based on ISO standards, and it cannot be approved by the Minister of Land, Infrastructure, Transport and Tourism as “specified fire prevention equipment”. [0006] Furthermore, as described above, since the use of phenol form or a volcanic glass fiber plate or the like to enhance the fire protection performance of a wooden fire door, the manufacturing cost increases, and ultimately, it increases. However, there is a problem that the product cost increases.
  • an object of the present invention is to provide a wooden fire door capable of exhibiting extremely excellent fire prevention performance with a structure as simple as possible and capable of greatly reducing costs.
  • a first aspect of the present invention for achieving the above object is a wooden fire door having a wooden core and a decorative plate provided on a surface thereof, wherein a wooden fireproof door is provided between the core and the decorative plate.
  • a wooden fire door characterized in that at least one sheet-like combustion delay member having a fire-resistant adhesive layer on both sides is provided.
  • a second aspect of the present invention is characterized in that, in the first aspect, two or more Japanese papers and the fire-resistant adhesive layer provided between and on both sides of the Japanese paper are provided. Wooden fire door.
  • a third aspect of the present invention is the wooden fire door according to the first or second aspect, wherein the combustion delay member is press-bonded between plate members joined to both surfaces thereof. It is in
  • the combustion delay member is provided between the core material and a non-combustible material obtained by impregnating wood with a combustion retardant, Further, the wooden fire door is characterized in that the decorative board is joined to a surface of the non-combustible material opposite to the core material side.
  • a fifth aspect of the present invention is the wooden fire door according to the fourth aspect, wherein the combustion delay member is also provided between the incombustible material and the decorative board. .
  • the refractory adhesive layer contains at least an inorganic material comprising a siloxane and a silanol salt. It is on the characteristic wooden fire door.
  • the flame retardant contains a flame retardant containing at least one of ammonium polyphosphate and boric acid. There is a wooden fire door.
  • the combustion retardant contains an inorganic material that becomes a molten state during combustion to fix a carbonized residue. Located on a wooden fire door.
  • the inorganic material comprises at least one selected from a silicate, a borosilicate, a borate and silica. Located on wooden fire doors.
  • a tenth aspect of the present invention is the wooden fire door according to any one of the first to ninth aspects, wherein the decorative board is a wooden plywood impregnated with the combustion retardant. .
  • An eleventh aspect of the present invention is the wooden fire door according to any one of the eleventh to tenth aspects, wherein the core material is mainly made of paulownia material.
  • a twelfth aspect of the present invention is the wooden fire door according to any one of the eleventh to eleventh aspects, wherein the core material is a laminate of paulownia laminated wood.
  • a thirteenth aspect of the present invention is the wooden fire door according to the twelfth aspect, wherein the core material is a three-layer cross-clad laminate of the paulownia laminated wood.
  • a fourteenth aspect of the present invention is characterized in that, in any one of the eleventh to thirteenth aspects, a graphite foam material is provided in the vicinity of an end face of the door in a longitudinal direction thereof. It is on the wooden fire door.
  • FIG. 1 is a schematic perspective view of a wooden fire door according to Embodiment 1 of the present invention.
  • FIG. 2 is a sectional view of a wooden fire door according to Embodiment 1 of the present invention, where (a) is a longitudinal sectional view. Yes, (b) is a cross-sectional view.
  • FIG. 3 is an enlarged sectional view of a main part of a wooden fire door according to Embodiment 1 of the present invention.
  • FIG. 4 is an enlarged sectional view of a main part for explaining a combustion delay member and a method for manufacturing the same according to Embodiment 1 of the present invention.
  • FIG. 5 is an enlarged sectional view of a main part showing one manufacturing process of the wooden fire door according to Embodiment 1 of the present invention.
  • FIG. 6 is an enlarged sectional view of a main part of a wooden fire door according to Embodiment 2 of the present invention.
  • FIG. 7 is an enlarged sectional view of a main part of a wooden fire door according to Embodiment 3 of the present invention.
  • FIG. 8 is an enlarged sectional view of a main part of a wooden fire door according to Embodiment 4 of the present invention.
  • the wooden fire door of the present invention by providing at least one sheet-like combustion delay member having a fire-resistant adhesive layer on both surfaces between the core material and the decorative board, a fire can be prevented when a fire occurs.
  • this combustion delay member traps fire and heat for a long period of time, and exhibits extremely excellent fire protection performance. That is, the wooden fire door of the present invention has a combustion delay between the core material and the decorative board. Despite its relatively simple structure with intervening members, it can achieve a fire protection performance of more than 60 minutes in a combustion test at an average of about 900 ° C based on ISO standards.
  • at least a wooden door having a core material is defined as a wooden fire door.
  • combustion delay members for example, in terms of both fire prevention performance and cost, for example,
  • the refractory adhesive forming the refractory adhesive layer preferably contains at least an inorganic material composed of a siloxane and a silanol salt.
  • a refractory adhesive is formed by reacting metal silicon (purity 99%) with sodium hydroxide in an aqueous solvent in the presence of a boric acid compound or an inorganic acid such as fluoride. It preferably contains an inorganic material composed of a siloxane and a silanol salt.
  • Such an inorganic material is a low-viscosity material having a composition ratio of SiZNa of 2 or more, an amorphous pH of 12 or less, and a hardness of 500 cP or less.
  • a fire-resistant adhesive for forming such a fire-resistant adhesive layer is commercially available from, for example, Comics as an aqueous film-forming inorganic compound “Liquid ceramics (LC) silica-based”.
  • Such a fire-resistant adhesive contains, for example, an inorganic material composed of a siloxane / silanol salt, and when heated at a relatively high temperature in the event of a fire, becomes an inorganic foam and has excellent heat insulation.
  • a refractory adhesive layer made of such a refractory adhesive is formed on both sides of at least one sheet of paper, and this is interposed as a combustion delay member between the core material and the decorative plate. In the event of a fire, the fire-resistant adhesive layer becomes an inorganic foam, trapping fire and heat over a long period of time, significantly reducing the effect on the core material and providing excellent fire protection performance. A fire door can be realized.
  • the fire-resistant adhesive layer on the decorative plate side of the combustion delay member is heated to form an inorganic foam. It becomes a body, and this inorganic foam blocks fire and heat for a long time. Also, even when the heat insulating effect of the inorganic foam is reduced, the refractory adhesive layer on the core material side of the combustion retarding member is still inorganic. Since it is a foam, the paper and the inorganic foam can further block fire and heat, thereby effectively preventing the core material from burning over a long period of time. As described above, in the present invention, in particular, by laminating two or more papers, a plurality of such fire-resistant adhesive layers can be provided, which is very effective in enhancing fire prevention performance.
  • this fire-resistant adhesive layer serves as a waterproof sheet, and warps due to diffusion of moisture of the core material. Can be effectively prevented. Therefore, warpage of the core material and the like is effectively prevented, and there is no problem of performance degradation over time.
  • the paper used for the combustion delay member is not particularly limited, and conventionally known papers can be used. Examples thereof include paper such as Japanese paper and Western paper, and Japanese paper is particularly preferred. Les ,.
  • the thickness of such paper is not particularly limited, but is preferably, for example, about 0.1 to 0.6 mm.
  • the combustion delay member is preferably press-bonded between plate members bonded to both surfaces thereof.
  • a combustion delay member is interposed between a core material and a decorative plate, and a predetermined load is applied to the core material and the decorative plate so as to sandwich the combustion delay member. It is compressed between the material and the decorative board, and is bonded to each of the core material and the decorative board via the refractory adhesive layer. That is, for example, when the combustion delay member is composed of a plurality of sheets of paper, it is preferable to laminate on one of the plate members, and overlap and press-bond the other plate member.
  • the paper when the flame retarding member is compressed in the thickness direction by press bonding, the paper is impregnated with the refractory adhesive forming the refractory adhesive layer, and the two are integrated. At this time, the fire-resistant adhesive layer is uniformly and stably formed between the two plate materials with a plurality of papers interposed therebetween, and the paper becomes a buffer material compared with the case where no paper is interposed. It is possible to form a refractory adhesive layer having a desired thickness with less outflow of the agent. Thereby, the fire prevention performance of the wooden fire door can be dramatically improved. That is, in the present invention, paper, particularly Japanese paper, functions so as to stably form the refractory adhesive layer between the plate materials.
  • a combustion delay member is formed by laminating two or more sheets of paper with a fire-resistant adhesive layer, and this combustion delay member is press-bonded to each of the core material and the decorative board, the fire protection of the wooden fire door can be prevented. Performance can be further enhanced.
  • a combustion delay member is a wooden protection member. It may be provided only on one side of the fire door to which the fire protection performance is to be provided.
  • such a combustion delay member is preferably provided, for example, between a core material and a dummy material in order to enhance fire prevention performance. Then, it is preferable that the dummy material and the decorative board are bonded by a fire-resistant adhesive layer. As a result, the number of fire-resistant adhesive layers is increased, and when a fire occurs, each of the fire-resistant adhesive layers becomes an inorganic foam, so that the fire prevention performance of the wooden fire door can be enhanced. More preferably, such a dummy material is impregnated with a combustion retardant to make it a noncombustible material. As a result, when a fire occurs, this non-combustible material can trap fire and heat for a long period of time.
  • the present invention is not limited to this, and at least one of such a dummy material and a non-combustible material may be provided between the core material and the combustion delay member. It may be provided. In any case, by providing at least one of such a dummy material or a non-combustible material between the core material and the decorative plate, the fire prevention performance of the wooden fire door can be enhanced.
  • the wooden plywood in addition to the dummy material, for example, when a wooden plywood is used as a decorative board, the wooden plywood may be impregnated with a combustion retardant. That is, instead of the dummy material, a wooden plywood may be impregnated with a combustion retardant, or each of the dummy material and the wooden plywood may be impregnated with a combustion retardant.
  • the core material may be impregnated or coated with a flame retardant, if necessary, to secure the desired fire protection performance.
  • the combustion delay member, the non-combustible material, the core material, and the decorative plate may be press-bonded at the same time. It may be sandwiched between the boards and adhered to each other, or may be sandwiched between the core material and the decorative board and then further press-bonded.
  • the wood used as such a non-combustible material is not particularly limited as long as it is impregnated with a flame retardant, and conventionally known natural wood can be used. , Cedar, karamatsu, and ryou, or a laminated material or a laminated material thereof. Of course, in addition to wood, a resin or the like may be impregnated with a flame retardant to make it a non-combustible material.
  • the thickness of such a noncombustible material is not particularly limited, but is preferably, for example, about 3 to 6 mm.
  • a flame retardant for impregnating wood or the like it is preferable to use a phosphoric acid type, a boric acid type, a non-halogen type water-soluble type, etc., which are non-toxic and odorless and volatile. Using organic compounds (VOC), etc.
  • a flame retardant containing at least a flame retardant is not particularly limited as long as it contains at least one of ammonium polyphosphate and boric acid as a component and impregnates wood.
  • Boric acid and the like contained in such a flame retardant react with OH groups contained in wood tissue (cellulose, hemicellulose, lignin, etc.) during the burning of the core material or non-combustible material. It generates an inflammable carbonized layer and water, and exerts the action of preventing the generation of flammable substances (dehydration carbonizing action). For this reason, it is effective to include a large amount of boric acid or the like in the combustion retardant.
  • a flame retardant containing a high-concentration boric acid compound obtained by mixing a boric acid compound so as to have a solubility equal to or higher than 100 g of 5 g Z water at normal temperature is preferable.
  • a boric acid compound for example, a phosphoric acid, a silanol salt, a polymer material, or the like may be contained in the combustion retardant, if necessary.
  • a high-concentration boric acid compound comprising one or more of a metal ion sequestering agent or a wet-permeable surfactant and a phosphoric acid compound / silanol salt.
  • examples of such a flameproofing agent include a flameproofing agent mainly containing ammonium polyphosphate and ammonium sulfate, and further containing other components as necessary.
  • a flameproofing agent containing boric acid as a main component and further containing other components as necessary may be mentioned.
  • a flame retardant obtained by mixing these flame retardants may be used. It should be noted that such a boric acid-based compound such as boric acid can also be expected to have an antiseptic / antibiotic effect.
  • the flame retardant may contain an inorganic material for fixing a carbonized residue obtained by burning wood or the like, together with the flame retardant.
  • the inorganic material acts to fix the carbonized residue that melts under high-temperature heating to become a glass state and is difficult to burn, prevents the carbonized residue from dropping, and has the ability to generate water. Therefore, the surface temperature is reduced, and the fire prevention performance is further improved.
  • inorganic salts having water of crystallization release or decompose the water of crystallization during combustion to exhibit an endothermic effect.
  • an inorganic material for immobilizing such a carbonized residue there is citric acid.
  • At least one selected from salts, borates, borates, and silica include water, which is an alkali silicate obtained by melting silicon dioxide and an alkali. Glass. However, if normal water glass is used, the alkali component is too strong. It is preferable to use one with a reduced / o.
  • the borate include sodium borate (borax). It should be noted that such a borate can be expected to have an antiseptic and anti-termite effect similarly to the above-mentioned boric acid.
  • the dehydration carbonizing action and the endothermic action act in a combined manner, and further excellent fire prevention performance can be obtained. it can.
  • the amount of such a flame retardant impregnated is not particularly limited as long as it is appropriately adjusted according to the type and dimensions of the wood to be impregnated so as to obtain a desired fire prevention performance.
  • the standard is about 50 150 g in a liquid state, and particularly preferably about 90 g.
  • the method for impregnating the wood with the combustion retardant is not particularly limited. For example, after a sufficient amount of the combustion retardant is put in a container, the temperature is raised to about 80 ° C. And a method in which wood is immersed therein at a predetermined temperature for a certain period of time for impregnation. After impregnation with the flame retardant, the non-combustible material impregnated with a certain amount of the active ingredient is produced by natural drying within 1 to 12 hours or drying by heating.
  • impregnating the wood with the combustion retardant in the present invention is not limited to so-called diving, in which the wood is immersed in a container storing the combustion retardant, and impregnation by pressure may be used.
  • the method for manufacturing the above-described combustion retardation member is not particularly limited.
  • a fire-resistant adhesive layer is applied to the entire surface of one side of the paper at about 200 g / m2 using a roll coater or the like. It is manufactured by applying 2 pieces and then attaching another paper or non-combustible material. At this time, the paper and the non-combustible material may be press-bonded.
  • a wooden fire door is manufactured by joining a combustion delay member to both surfaces of the core material on the door surface side, and then joining decorative panels on the surfaces of the combustion delay member. You.
  • a heat-resistant material generally used is used.
  • an adhesive may be used, it is particularly preferable to use the above-described fire-resistant adhesive from the viewpoint of enhancing fire prevention performance. As a result, a wooden fire door having very excellent fire protection performance can be realized.
  • the core material used for the wooden fire door of the present invention it is preferable to use a paulownia material from the viewpoint of fire protection performance and weight reduction, but if there is no problem in fire protection performance, other wood may be used. It can be used as a core material. In other words, the paulownia wood used as the core material itself exhibits fire protection performance. In addition to such paulownia wood, the impregnation amount of the combustion retardant, cost, door weight, or door strength In consideration of the above, for example, wood such as cedar, Karamatsu, and Ryou can be used.
  • cedar and karamatsu in order to increase the strength of the door, it is preferable to use cedar and karamatsu, etc., and in terms of cost, it is preferable to use thinned cedar and matsu.
  • paulownia wood from the viewpoint of reducing the weight of the door. If the door is lightened in this way, it is possible to reduce the transportation cost and to improve the workability at the time of installation.
  • the core is made of paulownia wood, it is preferable to use a paulownia wood of a quality that is unlikely to warp.
  • the core material may be any one of a paulownia wood cut from natural paulownia wood and a paulownia laminated wood, and may be a single material or a laminated material. When laminating, it is preferable to use an odd number. In any case, the type of wood forming the core material may be appropriately determined in consideration of required fire prevention performance, cost, and the like.
  • a reinforcing member made of wood that is harder to warp than paulownia wood.
  • reinforcing members include artificial plywood, which is preferably a natural wood laminated wood having a specific gravity of 0.5 or more, and frame materials such as LVL (natural grain parallel plywood laminated wood).
  • the reinforcing member is in contact with the laminated material or the like via the above-described fire-resistant adhesive in terms of enhancing fire protection performance. It is preferable to combine them.
  • the strength can be secured, and this may be used as a reinforcing member.
  • a three-layer cloth of natural wood laminated wood may be used as the reinforcing member.
  • the fire protection performance can be further improved by joining the natural wood laminated timber with a fire-resistant adhesive.
  • the laminated material and the reinforcing member may be joined by a structure in which they are fitted to each other via the uneven portion. preferable.
  • such a reinforcing member is included in a laminated material and is referred to as a core material.
  • a decorative plate is provided on the outermost surface of the wooden fire door of the present invention.
  • the decorative board include a laminated wood and a laminate formed using natural wood, a chemical board such as a wooden plywood or a calcium silicate board.
  • a wooden board is used as the decorative board, the decorative board does not need to be impregnated with the above-described combustion retardant, but may be impregnated if necessary.
  • a chemical plate has a certain degree of fire prevention performance, a wooden fire door using a chemical plate as a decorative plate is different from a wooden fire door using a wooden plate material impregnated with a flame retardant as a decorative plate. In comparison, fire prevention performance hardly decreases.
  • the wooden fire door of the present invention is provided with a combustion delay member made of at least one sheet of paper having a fire-resistant adhesive layer on both sides, between the core material and the lig board.
  • a combustion delay member made of at least one sheet of paper having a fire-resistant adhesive layer on both sides, between the core material and the lig board.
  • the wooden fire door according to the present invention has a relatively simple structure without using a fire-resistant sheet or the like, and exhibits excellent fire prevention performance.
  • the product can be provided at low cost.
  • the entire body when impregnating the core with the reinforcing member attached thereto with the combustion retardant, the entire body may be impregnated with the combustion retardant as it is, but only the paulownia wood is impregnated with the combustion retardant.
  • a reinforcing member may be attached.
  • the fire retarding performance can be further enhanced by impregnating and applying the combustion retarder to the reinforcing member.
  • a core material When a core material is formed using a laminated material, it is preferable to adhere a laminated material or the like with a fire-resistant adhesive in order to enhance fire prevention performance.
  • a fire-resistant adhesive in order to enhance fire prevention performance.
  • the laminated material may be joined via a fire-resistant adhesive to form a core material.
  • the structure of the wooden fire door is not particularly limited except that a combustion delay member made of at least one sheet of paper having a fire-resistant adhesive layer on both sides is provided between the core material and the decorative plate.
  • a well-known fire prevention structure may be employed according to the required fire prevention performance.
  • a paulownia laminate and a thermosetting resin laminate are laminated (the structure disclosed in JP-A-7-259445), and a paulownia wood and non-combustible paper are combined (JP-A-7-259445).
  • No. 293127 a combination of paulownia wood and phenolic foam (structure disclosed in JP-A-7-324561), and a combination of paulownia glue laminated with a refractory sheet
  • Japanese Unexamined Patent Publication No. The structure disclosed in Japanese Patent No. 256746), a combination of paulownia wood and a volcanic glass fiber plate (the structure disclosed in Japanese Patent Application Laid-Open No. 2000-179245) and the like can be used.
  • a structure using only paulownia laminates laminated with materials may be used. May be applied.
  • FIG. 1 is a schematic perspective view of a wooden fire door according to Embodiment 1 of the present invention.
  • 2 is a cross-sectional view of the wooden fire door according to Embodiment 1 of the present invention, in which (a) is a longitudinal sectional view and (b) is a transverse sectional view.
  • FIG. 3 is an enlarged sectional view of a main part of the wooden fire door.
  • the wooden fire door 10 of the present embodiment includes a paulownia laminate 24 in which a plurality of paulownia members 21-23 are laminated, and reinforcing members 25 provided on four sides thereof. And a decorative plate 30 made of a wooden plywood joined to the surface of the core material 20.
  • the paulownia laminate 24 is positioned between the paulownia members 21 and 22 whose grain direction (fiber direction) matches the longitudinal direction. Furthermore, the paulownia members 21 and 22 have a three-layer cross-clad structure in which a paulownia member 23 that is a direction orthogonal to the grain direction is sandwiched and laminated.
  • the paulownia members 21 to 23 constituting the paulownia laminate 24 may be formed in a predetermined size, and may be formed by joining a plurality of short pieces and dimensions. It may be something.
  • the paulownia laminate 24 formed by cross-tensioning the paulownia members 21-23 so that the grain direction is substantially orthogonal to the paulownia members 21-23 can effectively prevent warpage.
  • a reinforcing member 25 for example, in this embodiment, a paulownia laminated wood is used.
  • the thickness of the reinforcing member 25 (dimension in the surface direction of the door) needs to be about 150 mm in order to satisfy a fire test of 60 minutes, which depends on the fire protection performance of the wooden fire door.
  • a foam material 40 is provided on the surface on the door end face side of the reinforcing member 25 so as to be embedded in the longitudinal direction.
  • a decorative material 50 which is a large material or a side material is provided on the surface of the reinforcing member 25 on the door end surface side so as to cover the reinforcing member 25.
  • the foam material 40 for example, a graphite foam material that expands about 10 times in the thickness direction at about 230 ° C. may be used, thereby completely closing the gap with the frontage. It can prevent the flow of smoke and the spread of fire.
  • the foam material 40 is provided on four sides of the fire door, but may be provided on at least three end faces.
  • the cosmetic material 50 can be omitted as necessary depending on the place.
  • the decorative board 30 is bonded to the surface of the core material 20, and in this embodiment, a wooden plywood having a thickness of 4 mm was used.
  • a combustion retarding member made of at least a profile paper having a fire-resistant adhesive layer made of a fire-resistant adhesive on both surfaces.
  • the combustion delay member 100 is formed by bonding three Japanese papers 101 with a fire-resistant adhesive layer 102 made of a fire-resistant adhesive.
  • the flame retardant member 100 is made of a core material 20 and a decorative board 30 and a fire-resistant adhesive layer. Joined by 102.
  • FIG. 4 is an enlarged sectional view of an essential part for explaining a combustion delay member and a method for manufacturing the same according to Embodiment 1 of the present invention.
  • the combustion delay member 100 is manufactured as follows. Specifically, first, three pieces of Japanese paper 101 having a thickness of 0.1 to 0.6 mm as shown in FIG. 4A are prepared. Thereafter, as shown in Figure. 4 (b), in the on one surface of the core member 20, for example, using a roll coater, a refractory adhesive about 20 Og / m 2 applied to a refractory adhesive layer 102 formed I do.
  • the combustion delay member 100 is brought into contact with each of the core material 20 and the decorative plate 30 via the fire-resistant adhesive layer 102. Press bonding was performed under a predetermined load. At this time, each Japanese paper 101 is impregnated with the effective component of the fire-resistant adhesive layer 102 and both are integrated. As a result, the fire prevention performance of the wooden fire door can be dramatically improved.
  • the combustion delay member 100 is formed using a plurality of Japanese papers 101 as in the present embodiment, for example, the Japanese paper 101 is laminated on the decorative board 30 via the fire-resistant adhesive layer 102, The core material 20 may be press-bonded thereon.
  • the refractory adhesive forming the refractory adhesive layer 102 preferably contains at least an inorganic material composed of a siloxane and a silanol salt.
  • the refractory adhesive is formed by reacting metal silicon (purity 99%) with sodium hydroxide in an aqueous solvent in the presence of an inorganic acid such as a boric acid compound or a fluoride.
  • An inorganic material consisting of the siloxane and the silanol salt was contained.
  • such an inorganic material is a material having an Si / Na component ratio of 2 or more, an amorphous material having a pH of 12 or less and a hardness of 500 cP or less and having low viscosity.
  • an aqueous film-forming inorganic compound “Liquid Ceramics (LC) silica-based” (trade name: manufactured by Comix Corporation) was used as such a refractory adhesive.
  • the refractory adhesive layer 102 is made of a siloxane / silanol salt.
  • a siloxane / silanol salt When heated at a relatively high temperature in the event of a fire, it becomes an inorganic foam and exhibits excellent heat insulation and waterproof properties.
  • the wooden fire door 10 of the present embodiment becomes an inorganic foam from the decorative plate 30 side of the combustion delay member 100, which blocks fire and heat for a long time. Even if the heat insulating effect of the inorganic foam is reduced, the fire-resistant adhesive layer 102 sandwiched between the Japanese paper and the Japanese paper is also made of the inorganic foam. 20 can be effectively blocked from burning.
  • a fire-resistant adhesive layer 102 has a waterproof effect and functions as a waterproof sheet, it is possible to effectively prevent the warpage due to the diffusion of moisture from the core material 20. . Therefore, the wooden fire door 10 of the present embodiment can prevent fire and heat for a long period of time and also prevent the occurrence of warpage, so that extremely excellent fire prevention performance can be obtained.
  • the wooden fire door 10 of the present embodiment has the fire-resistant adhesive layer 102 between the core material 20 and the decorative board 30 and between both sides and each of the three sheets of Japanese paper 101. Since the combustion delay member 100 is provided, extremely excellent fire prevention performance can be obtained in the event of a fire despite the relatively simple structure.
  • the wooden fire door 10 can effectively prevent warpage of the core member 20 and the like by the waterproof effect of the fire-resistant adhesive layer 102 of the combustion delay member 100, and can reduce performance and cost due to aging. No problem.
  • the combustion delay member 100 may be provided only on one side to which fire protection performance is to be provided.
  • FIG. 6 is an enlarged sectional view of a main part of a wooden fire door according to Embodiment 2 of the present invention. Note that, in the present embodiment, the same portions as those described with reference to FIGS. 1 to 4 are denoted by the same reference numerals, and redundant description will be omitted.
  • the wooden fire door 10A of the present embodiment is the same as the above except that the combustion delay member 100 is provided between the non-combustible material 103 in which a dummy material is impregnated with a combustion retardant and the core material 20. This is the same as in the first embodiment.
  • the wooden fire door 10A of the present embodiment is configured such that each of the three pieces of Japanese paper 101 and the non-combustible material 103 are bonded with a fire-resistant adhesive layer 102, and the core material 20 and the decorative board 30 are bonded together. Each It has a structure further bonded by a refractory adhesive layer 102.
  • a combustion delay member 100A made of one piece of Japanese paper 101 having a fire-resistant adhesive 102 on both surfaces is provided between the non-combustible material 103 and the decorative board 30, a combustion delay member 100A made of one piece of Japanese paper 101 having a fire-resistant adhesive 102 on both surfaces is provided.
  • the flame retardant impregnated in the dummy material contains a flame retardant containing at least one of ammonium polyphosphate and boric acid as a component.
  • a flame retardant containing boric acid was used.
  • boric acid reacts with the ⁇ H group contained in the wood tissue during combustion of the noncombustible material 103 to generate a hardly combustible carbonized layer and water, thereby preventing the generation of flammable substances ( (Dehydration carbonization).
  • the dummy material is impregnated with a flame retardant containing an inorganic material that becomes a molten state and fixes a carbonized residue when burned together with such a flame retardant.
  • a flame retardant containing an inorganic material that becomes a molten state and fixes a carbonized residue when burned together with such a flame retardant.
  • Such an inorganic material melts when a fire occurs or the like, and becomes, for example, a glassy state, and acts to mutually fix carbonized residues generated by carbonizing the noncombustible material 103. Therefore, if the inorganic material is impregnated into the wood together with the flame retardant, the carbonized residues are fixed to each other by the inorganic material, and the carbonized residues can be prevented from collapsing.
  • Examples of such an inorganic material include those in which the alkalinity of water glass is reduced by 70% to 80%. It is needless to say that such an inorganic material may be added as appropriate according to the required fire
  • the dummy material is impregnated with the combustion retardant.
  • the present invention is not limited to this.
  • the decorative plate may be impregnated with the combustion retardant instead of the dummy material. May be impregnated.
  • FIG. 7 is an enlarged sectional view of a main part of a wooden fire door according to Embodiment 3 of the present invention. Note that, in the present embodiment, the same portions as those described with reference to FIGS. 1 to 4 are denoted by the same reference numerals, and redundant description will be omitted.
  • the combustion delay member 100 is provided between the non-combustible material 103 in which the combustion retardant is impregnated in the dummy material and the decorative board 30.
  • burning Embodiment 2 is the same as Embodiment 2 except that the delay member 100A is provided between the core member 20 and the non-combustible member 103.
  • each of the combustion delay members 100, 100A, and the non-combustible material 103 traps fire and heat for a long time, and thus is similar to the first embodiment described above. Demonstrate very good fire protection performance.
  • FIG. 8 is an enlarged sectional view of a main part of a wooden fire door according to Embodiment 4 of the present invention. Note that, in the present embodiment, the same portions as those described with reference to FIGS. 1 to 4 are denoted by the same reference numerals, and redundant description will be omitted.
  • a core member composed of a reinforcing member 25C in which three layers of natural wood laminated timber 60 are cross-bonded and a paulownia laminated material 24C in which three layers of each paulownia member 21-23 are cross-stretched. It is the same as Embodiment 1 described above, except that a wooden fire door 10C using 20C is used. Further, the paulownia laminate 24C and the reinforcing member 25C are fitted to each other via a concave-convex portion 70 provided at a joint portion between the two. Thereby, sufficient joining strength is obtained and door strength can be increased.
  • a wooden fire door 10D using a reinforcing member 25D having a structure in which each natural wood laminated wood 60 is bonded by a fire-resistant adhesive layer 102 may be used. Further, in the wooden fire door 10D, the reinforcing member 25D and the paulownia laminated material 24D are further adhered to each other by the refractory adhesive layer 102, and the respective paulownia members 21-23 constituting the core material 20D are mutually bonded with the refractory adhesive. Adhered by layer 102. Thereby, very excellent fire prevention performance can be obtained.
  • Embodiments 1 and 2 described above may be adopted for the door structure of the wooden fire doors IOC, 10D of the present embodiment.
  • a reinforcing member made of synthetic plywood was joined to the upper, lower, left and right end surfaces of a paulownia laminated material in which three layers of paulownia laminated wood were cross-bonded to form a core material having a thickness of 35 mm and 900 mm ⁇ 2200 mm.
  • LC Liquid Ceramic
  • a fire-resistant adhesive layer was formed on each of the non-combustible materials on both sides, respectively.
  • a Japanese paper was attached on the fire-resistant adhesive layer, and a further fire-resistant adhesive layer was further formed on the Japanese paper.
  • a decorative plate having a thickness of 2.7 mm and a size of 900 mm x 2200 mm was bonded thereon, and then the core material, the decorative plate, the non-combustible material, and the combustion delay member were press-bonded to each other. Wooden fire door.
  • the wooden fire door of Example 1 was burned with a flame of about 900 ° C. on average from one side, and a combustion test was performed for 60 minutes to evaluate the fire protection performance of the wooden fire door.
  • the combustion test is a certification test by the Minister of Land, Infrastructure, Transport and Tourism based on “specified fire prevention equipment” based on ISO standards.
  • Example 1 It was found that by interposing a combustion delay member between the core material and the decorative plate, extremely excellent fire protection performance was obtained. In addition, the wooden fire door of Example 1 achieved a fire protection performance of 60 minutes in an average 900 ° C combustion test based on ISO standards. Was able to pass.

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Abstract

A wooden fire door that is capable of exhibiting excellent fire protection characteristics with a structure that is made as simple as possible and whose production cost can be remarkably reduced. In a wooden fire door (10) having a wooden core member (20) and a decorative plate (30) provided on a surface of the door, a burn delay member (100) is installed between the core member (20) and the decorative plate (30). The burn delay member (100) is constructed from at least a sheet of paper (101) having fire resistant adhesive layers (102) on both surfaces. Excellent fire protection characteristics can be obtained with the structure above, and also the product can be provided at low cost because production costs can be remarkably reduced.

Description

明 細 書  Specification

木製防火扉  Wooden fire door

技術分野  Technical field

[0001] 本発明は、例えば、住宅や会社等の扉として用いられ、火災発生時に火や熱をトラ ップするという防火性能を有する木製防火扉に関する。  The present invention relates to a wooden fire door which is used, for example, as a door of a house or a company and has a fire prevention performance of trapping fire or heat when a fire occurs.

背景技術  Background art

[0002] 従来、特定防火設備 60としてはスチール製し力認められなかったので、防火扉は 一般的にはスチール製である。スチール製の防火扉は頑丈である力 重ぐ高熱で 反ってしまい、また、輻射熱が大きい(木の 5— 8倍)などの欠点を有する。  [0002] Conventionally, the specific fire prevention equipment 60 is made of steel and its power is not recognized. Therefore, the fire door is generally made of steel. Steel fire doors have the drawbacks of being strong, warping with heavy heat, and having high radiant heat (5-8 times the size of wood).

[0003] そこで、平成 2年に甲種防火扉及び乙種防火扉の試験方法が改正され、一定条件 を満たせば木製戸であっても特定防火設備 60若しくは特定防火設備 20として認可 されるようになつたことを契機として桐材を用いた木製防火扉が開発されている。  [0003] Therefore, the test methods for Class A fire doors and Class B fire doors were revised in 1990, and even if wooden doors were to meet certain conditions, they would be approved as the specified fire protection equipment 60 or the specified fire protection equipment 20. As a result, wooden fire doors made of paulownia wood have been developed.

[0004] そして、特開平 7-208033号公報には、桐の集成材を積層した桐積層板を用いた ものが開示され、特開平 7-259445号公報には、桐集成材と熱硬化性樹脂積層板 とを積層したものが開示されている。また、特開平 7—293127号公報には、桐材と不 燃紙とを組み合わせたものが開示され、特開平 7—324561号公報には、桐材とフエ ノールフォームとを組み合わせたものが開示されている。さらに、特開平 9—256746 号公報には、桐集成材に耐火シートを組み合わせたものが開示され、特開 2000—1 79245号公報には、桐材と火山性ガラス繊維板とを組み合わせたものが開示されて いる。また、特開 2000-310090号公報には、桐材の反りを防止する構造が開示さ れ、特開 2001-17560号公報には、災害時の脱出を容易にする構造が開示されて いる。  [0004] Japanese Patent Application Laid-Open No. 7-208033 discloses a paulownia laminated plate obtained by laminating a paulownia glulam, and Japanese Patent Application Laid-Open No. 7-259445 discloses a paulownia glue laminated lumber and a thermosetting resin. A laminated resin laminate is disclosed. Japanese Unexamined Patent Publication No. 7-293127 discloses a combination of paulownia wood and non-combustible paper, and Japanese Unexamined Patent Publication No. 7-324561 discloses a combination of a paulownia wood and phenol foam. Have been. Further, Japanese Unexamined Patent Publication No. 9-256746 discloses a combination of a paulownia laminated wood and a refractory sheet, and Japanese Unexamined Patent Publication No. 2000-179245 discloses a combination of a paulownia wood and a volcanic glass fiber plate. Is disclosed. Further, Japanese Patent Application Laid-Open No. 2000-310090 discloses a structure for preventing the warp of the paulownia wood, and Japanese Patent Application Laid-Open No. 2001-17560 discloses a structure for facilitating escape at the time of disaster.

[0005] し力、しながら、従来の木製防火扉は、例えば、経年変化の中での防火性能低下や 製造コスト、或いは、火災発生時の防火性能の点で問題があり、十分に満足できる製 品は得られていない。すなわち、 ISO基準に基づく平均約 900°Cの燃焼試験におい て 60分の防火性能を得ることができず、「特定防火設備」の国土交通大臣認定を受 けることができない。 [0006] また、木製防火扉の防火性能を高めるためには、上述したように、フエノールフォー ムゃ火山性ガラス繊維板等を用いるため、製造コストが増大してしまレ、、最終的には 、製品コストが高くなるという問題がある。 [0005] However, the conventional wooden fire doors have a problem in terms of, for example, deterioration in fire prevention performance due to aging, manufacturing costs, or fire prevention performance in the event of fire, and can be sufficiently satisfied. No product has been obtained. In other words, fire performance cannot be obtained for 60 minutes in an average combustion test at approximately 900 ° C based on ISO standards, and it cannot be approved by the Minister of Land, Infrastructure, Transport and Tourism as “specified fire prevention equipment”. [0006] Furthermore, as described above, since the use of phenol form or a volcanic glass fiber plate or the like to enhance the fire protection performance of a wooden fire door, the manufacturing cost increases, and ultimately, it increases. However, there is a problem that the product cost increases.

発明の開示  Disclosure of the invention

発明が解決しょうとする課題  Problems the invention is trying to solve

[0007] 本発明はこのような事情に鑑み、できるだけ簡単な構造で非常に優れた防火性能 を発揮できると共にコストを大幅に低減できる木製防火扉を提供することを目的とす る。 [0007] In view of such circumstances, an object of the present invention is to provide a wooden fire door capable of exhibiting extremely excellent fire prevention performance with a structure as simple as possible and capable of greatly reducing costs.

課題を解決するための手段  Means for solving the problem

[0008] 上記目的を達成する本発明の第 1の態様は、木製の芯材と、表面に設けられた化 粧板とを有する木製防火扉において、前記芯材と前記化粧板との間には、両面に耐 火接着剤層を有する少なくとも 1枚の紙力 なる燃焼遅延部材が設けられていること を特徴とする木製防火扉にある。 [0008] A first aspect of the present invention for achieving the above object is a wooden fire door having a wooden core and a decorative plate provided on a surface thereof, wherein a wooden fireproof door is provided between the core and the decorative plate. Is a wooden fire door characterized in that at least one sheet-like combustion delay member having a fire-resistant adhesive layer on both sides is provided.

[0009] 本発明の第 2の態様は、第 1の態様において、 2枚以上の和紙と当該和紙のそれぞ れの間及び両面に設けられた前記耐火接着剤層とからなることを特徴とする木製防 火扉にある。  [0009] A second aspect of the present invention is characterized in that, in the first aspect, two or more Japanese papers and the fire-resistant adhesive layer provided between and on both sides of the Japanese paper are provided. Wooden fire door.

[0010] 本発明の第 3の態様は、第 1又は 2の態様において、前記燃焼遅延部材は、その両 面に接合される板材の間にプレス接着されていることを特徴とする木製防火扉にある  [0010] A third aspect of the present invention is the wooden fire door according to the first or second aspect, wherein the combustion delay member is press-bonded between plate members joined to both surfaces thereof. It is in

[0011] 本発明の第 4の態様は、第 1一 3の何れかの態様において、前記燃焼遅延部材は 、前記芯材と木材に燃焼遅延剤を含浸した不燃材との間に設けられ、且つ前記不燃 材の前記芯材側とは反対側の面上には前記化粧板が接合されていることを特徴とす る木製防火扉にある。 [0011] In a fourth aspect of the present invention, in any one of the thirteenth to thirteenth aspects, the combustion delay member is provided between the core material and a non-combustible material obtained by impregnating wood with a combustion retardant, Further, the wooden fire door is characterized in that the decorative board is joined to a surface of the non-combustible material opposite to the core material side.

[0012] 本発明の第 5の態様は、第 4の態様において、前記燃焼遅延部材は、前記不燃材 と前記化粧板との間にも設けられていることを特徴とする木製防火扉にある。  [0012] A fifth aspect of the present invention is the wooden fire door according to the fourth aspect, wherein the combustion delay member is also provided between the incombustible material and the decorative board. .

[0013] 本発明の第 6の態様は、第 1一 5の何れかの態様において、前記耐火接着剤層に は、少なくともシロキサンとシラノール塩とからなる無機材料が含有されてレ、ることを特 徴とする木製防火扉にある。 [0014] 本発明の第 7の態様は、第 4の態様において、前記燃焼遅延剤には、ポリリン酸ァ ンモニゥム及びホウ酸の少なくとも何れか一方を含む防炎薬剤が含有されていること を特徴とする木製防火扉にある。 [0013] In a sixth aspect of the present invention, in any one of the first to fifth aspects, the refractory adhesive layer contains at least an inorganic material comprising a siloxane and a silanol salt. It is on the characteristic wooden fire door. [0014] In a seventh aspect of the present invention, in the fourth aspect, the flame retardant contains a flame retardant containing at least one of ammonium polyphosphate and boric acid. There is a wooden fire door.

[0015] 本発明の第 8の態様は、第 7の態様において、前記燃焼遅延剤には、燃焼時に溶 融状態となって炭化残渣を固定する無機材料が含有されていることを特徴とする木 製防火扉にある。 [0015] In an eighth aspect of the present invention, in the seventh aspect, the combustion retardant contains an inorganic material that becomes a molten state during combustion to fix a carbonized residue. Located on a wooden fire door.

[0016] 本発明の第 9の態様は、第 8の態様において、前記無機材料が、ケィ酸塩、ホウケ ィ酸塩、ホウ酸塩及びシリカから選択される少なくとも一種からなることを特徴とする 木製防火扉にある。  In a ninth aspect of the present invention, in the eighth aspect, the inorganic material comprises at least one selected from a silicate, a borosilicate, a borate and silica. Located on wooden fire doors.

[0017] 本発明の第 10の態様は、第 1一 9の何れかの態様において、前記化粧板が、前記 燃焼遅延剤が含浸された木製合板であることを特徴とする木製防火扉にある。  [0017] A tenth aspect of the present invention is the wooden fire door according to any one of the first to ninth aspects, wherein the decorative board is a wooden plywood impregnated with the combustion retardant. .

[0018] 本発明の第 11の態様は、第 1一 10の何れかの態様において、前記芯材が、桐材 を主体とするものであることを特徴とする木製防火扉にある。 [0018] An eleventh aspect of the present invention is the wooden fire door according to any one of the eleventh to tenth aspects, wherein the core material is mainly made of paulownia material.

[0019] 本発明の第 12の態様は、第 1一 11の何れかの態様において、前記芯材が、桐集 成材の積層板であることを特徴とする木製防火扉にある。 [0019] A twelfth aspect of the present invention is the wooden fire door according to any one of the eleventh to eleventh aspects, wherein the core material is a laminate of paulownia laminated wood.

[0020] 本発明の第 13の態様は、第 12の態様において、前記芯材が、前記桐集成材の 3 層クロス張りの積層板であることを特徴とする木製防火扉にある。 [0020] A thirteenth aspect of the present invention is the wooden fire door according to the twelfth aspect, wherein the core material is a three-layer cross-clad laminate of the paulownia laminated wood.

[0021] 本発明の第 14の態様は、第 1一 13の何れかの態様において、前記扉の端面近傍 には、グラフアイト系発泡材がその長手方向に亘つて設けられていることを特徴とする 木製防火扉にある。  A fourteenth aspect of the present invention is characterized in that, in any one of the eleventh to thirteenth aspects, a graphite foam material is provided in the vicinity of an end face of the door in a longitudinal direction thereof. It is on the wooden fire door.

発明の効果  The invention's effect

[0022] 本発明によれば、両面に耐火接着剤層を有する少なくとも 夂の紙からなる燃焼遅 延部材を芯材と化粧板との間に設けた比較的簡単な構造にも関わらず、非常に優れ た防火性能を発揮できると共にコストを大幅に低減できる木製防火扉を低コストで提 供することができるという効果を奏する。  [0022] According to the present invention, despite a relatively simple structure in which a combustion delay member made of at least a paper having a refractory adhesive layer on both surfaces is provided between the core material and the decorative plate, an extremely long time is required. This has the effect of providing a low cost wooden fire door that can exhibit excellent fire protection performance and greatly reduce costs.

図面の簡単な説明  BRIEF DESCRIPTION OF THE FIGURES

[0023] [図 1]本発明の実施形態 1に係る木製防火扉の概略斜視図である。  FIG. 1 is a schematic perspective view of a wooden fire door according to Embodiment 1 of the present invention.

[図 2]本発明の実施形態 1に係る木製防火扉の断面図であって、(a)は縦断面図で あり、(b)は横断面図である。 FIG. 2 is a sectional view of a wooden fire door according to Embodiment 1 of the present invention, where (a) is a longitudinal sectional view. Yes, (b) is a cross-sectional view.

[図 3]本発明の実施形態 1に係る木製防火扉の要部拡大断面図である。  FIG. 3 is an enlarged sectional view of a main part of a wooden fire door according to Embodiment 1 of the present invention.

[図 4]本発明の実施形態 1に係る燃焼遅延部材及びその製造方法を説明する要部 拡大断面図である。  FIG. 4 is an enlarged sectional view of a main part for explaining a combustion delay member and a method for manufacturing the same according to Embodiment 1 of the present invention.

[図 5]本発明の実施形態 1に係る木製防火扉の一製造工程を示す要部拡大断面図 である。  FIG. 5 is an enlarged sectional view of a main part showing one manufacturing process of the wooden fire door according to Embodiment 1 of the present invention.

[図 6]本発明の実施形態 2に係る木製防火扉の要部拡大断面図である。  FIG. 6 is an enlarged sectional view of a main part of a wooden fire door according to Embodiment 2 of the present invention.

[図 7]本発明の実施形態 3に係る木製防火扉の要部拡大断面図である。  FIG. 7 is an enlarged sectional view of a main part of a wooden fire door according to Embodiment 3 of the present invention.

[図 8]本発明の実施形態 4に係る木製防火扉の要部拡大断面図である。  FIG. 8 is an enlarged sectional view of a main part of a wooden fire door according to Embodiment 4 of the present invention.

符号の説明  Explanation of reference numerals

[0024] 10 木製防火扉 [0024] 10 wooden fire doors

20 芯材  20 core material

21、 22、 23 桐部材  21, 22, 23 Paulownia members

24 桐積層板  24 Paulownia laminate

25 補強部材  25 Reinforcement members

30 化粧合板  30 decorative plywood

40 発泡材  40 foam

50 化粧材  50 Cosmetic materials

60 天然木集成材  60 Natural wood glued lumber

100 燃焼遅延部材  100 Combustion delay member

101 和紙  101 Japanese paper

102 耐火接着剤  102 fire resistant adhesive

103 不燃材  103 noncombustible material

発明を実施するための最良の形態  BEST MODE FOR CARRYING OUT THE INVENTION

[0025] 本発明に係る木製防火扉によると、芯材と化粧板との間に、両面に耐火接着剤層 を有する少なくとも 1枚の紙力 なる燃焼遅延部材を設けることにより、火災発生時に は、この燃焼遅延部材が火や熱を長期間に亘つてトラップし、非常に優れた防火性 能を発揮する。すなわち、本発明の木製防火扉は、芯材と化粧板との間に燃焼遅延 部材を介在させた比較的簡単な構造にも関わらず、 ISO基準に基づく平均約 900°C の燃焼試験において 60分以上の防火性能を得ることができるものである。なお、本 発明において、少なくとも芯材が木製の扉のことを木製防火扉と定義する。 [0025] According to the wooden fire door of the present invention, by providing at least one sheet-like combustion delay member having a fire-resistant adhesive layer on both surfaces between the core material and the decorative board, a fire can be prevented when a fire occurs. However, this combustion delay member traps fire and heat for a long period of time, and exhibits extremely excellent fire protection performance. That is, the wooden fire door of the present invention has a combustion delay between the core material and the decorative board. Despite its relatively simple structure with intervening members, it can achieve a fire protection performance of more than 60 minutes in a combustion test at an average of about 900 ° C based on ISO standards. In the present invention, at least a wooden door having a core material is defined as a wooden fire door.

[0026] また、このような燃焼遅延部材は、防火性能及びコストの両面で、複数枚、例えば、  [0026] Further, a plurality of such combustion delay members, for example, in terms of both fire prevention performance and cost, for example,

2枚以上の紙と、これら各紙の間のそれぞれに設けられた耐火接着剤層とを有する 積層構造とするのが好ましい。これにより、耐火接着剤層が複数設けられるので、木 製防火扉の防火性能をさらに高めることができる。  It is preferable to adopt a laminated structure including two or more sheets of paper and a refractory adhesive layer provided between the respective sheets of paper. Thereby, since a plurality of fireproof adhesive layers are provided, the fire protection performance of the wooden fire door can be further enhanced.

[0027] ここで、耐火接着剤層を形成する耐火接着剤は、少なくともシロキサンとシラノール 塩とからなる無機材料を含有しているのが好ましい。具体的には、耐火接着剤は、ホ ゥ酸化合物やフッ化物等の無機酸の存在下で、金属ケィ素(純度 99%)と水酸化ナ トリウムとを水溶媒中で反応させることで生成したシロキサンとシラノール塩とからなる 無機材料を含有しているのが好ましい。そして、このような無機材料は、 SiZNaの成 分比が 2以上であり、アモルファス状で pHが 12以下、硬度 500cP以下の低粘性を 有する材料である。このような耐火接着剤層を形成する耐火接着剤は、例えば、コー ミックス社から、水性造膜性無機化合物「リキッドセラミックス (LC)シリカ系」などとして 市販されている。  Here, the refractory adhesive forming the refractory adhesive layer preferably contains at least an inorganic material composed of a siloxane and a silanol salt. Specifically, a refractory adhesive is formed by reacting metal silicon (purity 99%) with sodium hydroxide in an aqueous solvent in the presence of a boric acid compound or an inorganic acid such as fluoride. It preferably contains an inorganic material composed of a siloxane and a silanol salt. Such an inorganic material is a low-viscosity material having a composition ratio of SiZNa of 2 or more, an amorphous pH of 12 or less, and a hardness of 500 cP or less. A fire-resistant adhesive for forming such a fire-resistant adhesive layer is commercially available from, for example, Comics as an aqueous film-forming inorganic compound “Liquid ceramics (LC) silica-based”.

[0028] このような耐火接着剤は、例えば、シロキサンゃシラノール塩とからなる無機材料を 含有させることにより、火災発生時に比較的高い温度で加熱されると、無機発泡体と なり、優れた断熱性能を有すると共に、優れた防水性能を有する材料となる。そして、 本発明では、このような耐火接着剤からなる耐火接着剤層を少なくとも 1枚の紙の両 面に形成し、これを燃焼遅延部材として芯材と化粧板との間に介在させることで、火 災発生時には、耐火接着剤層が無機発泡体となって火や熱を長期間に亘つてトラッ プし、芯材に対する影響が大幅に低減され、非常に優れた防火性能を有する木製防 火扉を実現できる。  [0028] Such a fire-resistant adhesive contains, for example, an inorganic material composed of a siloxane / silanol salt, and when heated at a relatively high temperature in the event of a fire, becomes an inorganic foam and has excellent heat insulation. A material that has both high performance and excellent waterproof performance. In the present invention, a refractory adhesive layer made of such a refractory adhesive is formed on both sides of at least one sheet of paper, and this is interposed as a combustion delay member between the core material and the decorative plate. In the event of a fire, the fire-resistant adhesive layer becomes an inorganic foam, trapping fire and heat over a long period of time, significantly reducing the effect on the core material and providing excellent fire protection performance. A fire door can be realized.

[0029] 例えば、両面及び間に耐火接着剤層を有する 2枚の紙からなる燃焼遅延部材を用 いた木製防火扉では、燃焼遅延部材の化粧板側の耐火接着剤層が加熱されて無機 発泡体となり、この無機発泡体が火や熱を長時間遮断する。また、この無機発泡体に よる断熱効果が低減した場合でも、燃焼遅延部材の芯材側の耐火接着剤層が無機 発泡体となるので、紙と無機発泡体とで火や熱をさらに遮断でき、これにより芯材が 燃焼してしまうのを長期に亘つて有効に防止することができる。このように、本発明で は、特に、紙を 2枚以上積層することで、このような耐火接着剤層を複数設けることが できるため、防火性能を高めるのに非常に有効である。 [0029] For example, in a wooden fire door using a combustion delay member made of two sheets of paper having a fire-resistant adhesive layer on both sides and between them, the fire-resistant adhesive layer on the decorative plate side of the combustion delay member is heated to form an inorganic foam. It becomes a body, and this inorganic foam blocks fire and heat for a long time. Also, even when the heat insulating effect of the inorganic foam is reduced, the refractory adhesive layer on the core material side of the combustion retarding member is still inorganic. Since it is a foam, the paper and the inorganic foam can further block fire and heat, thereby effectively preventing the core material from burning over a long period of time. As described above, in the present invention, in particular, by laminating two or more papers, a plurality of such fire-resistant adhesive layers can be provided, which is very effective in enhancing fire prevention performance.

[0030] また、このような耐火接着剤層は、上述したように、防水効果が期待できるので、こ の耐火接着剤層が防水シートとしての役割を果たし、芯材カ の水分の発散による 反りの発生を効果的に防止することができる。したがって、芯材等の反りが有効に防 止され、経年変化の中での性能低下の問題はない。 [0030] In addition, since such a fire-resistant adhesive layer can be expected to have a waterproof effect as described above, this fire-resistant adhesive layer serves as a waterproof sheet, and warps due to diffusion of moisture of the core material. Can be effectively prevented. Therefore, warpage of the core material and the like is effectively prevented, and there is no problem of performance degradation over time.

[0031] なお、燃焼遅延部材に用いられる紙としては、特に限定されず、従来公知のものを 使用できるが、その一例を挙げれば、和紙や洋紙等の紙があり、特に、和紙が好まし レ、。なお、このような紙の厚さは、特に限定されないが、例えば、約 0. 1 -0. 6mmの ものがよい。 [0031] The paper used for the combustion delay member is not particularly limited, and conventionally known papers can be used. Examples thereof include paper such as Japanese paper and Western paper, and Japanese paper is particularly preferred. Les ,. The thickness of such paper is not particularly limited, but is preferably, for example, about 0.1 to 0.6 mm.

[0032] また、本発明では、燃焼遅延部材は、その両面に接合される板材の間にプレス接 着されているのが好ましい。例えば、芯材と化粧板との間に燃焼遅延部材を介在さ せ、この燃焼遅延部材を挟み込むように芯材及び化粧板に対して所定の荷重を加え ることにより、燃焼遅延部材は、芯材と化粧板との間で圧縮され、且つ芯材と化粧板 とのそれぞれに耐火接着剤層を介して接着される。すなわち、例えば、燃焼遅延部 材が複数枚の紙からなる場合には、一方の板材上に積層して他方の板材を重ねて プレス接着するのが好ましい。このように、プレス接着して燃焼遅延部材をその厚さ 方向に圧縮すると、紙に耐火接着剤層を形成する耐火接着剤が含浸されると共に両 者が一体化する。この際、 2枚の板材間に複数枚の紙を介して耐火接着剤層が均一 に安定して形成され、且つ紙が介在しない場合と比較して、紙が緩衝材となるため耐 火接着剤の流れ出しが少なぐ所望の厚さの耐火接着剤層を形成できる。これにより 、木製防火扉の防火性能を飛躍的に向上できる。すなわち、本発明では、紙、特に 和紙が耐火接着剤層を板材間に安定して形成するように機能する。したがって、本 発明では、特に 2枚以上の紙を耐火接着剤層によって積層した燃焼遅延部材とし、 且つこの燃焼遅延部材を芯材と化粧板とのそれぞれにプレス接着すれば、木製防火 扉の防火性能をさらに高めることができる。なお、このような燃焼遅延部材は、木製防 火扉の防火性能を付与すべき一方側のみに設けてもよい。 [0032] Further, in the present invention, the combustion delay member is preferably press-bonded between plate members bonded to both surfaces thereof. For example, a combustion delay member is interposed between a core material and a decorative plate, and a predetermined load is applied to the core material and the decorative plate so as to sandwich the combustion delay member. It is compressed between the material and the decorative board, and is bonded to each of the core material and the decorative board via the refractory adhesive layer. That is, for example, when the combustion delay member is composed of a plurality of sheets of paper, it is preferable to laminate on one of the plate members, and overlap and press-bond the other plate member. As described above, when the flame retarding member is compressed in the thickness direction by press bonding, the paper is impregnated with the refractory adhesive forming the refractory adhesive layer, and the two are integrated. At this time, the fire-resistant adhesive layer is uniformly and stably formed between the two plate materials with a plurality of papers interposed therebetween, and the paper becomes a buffer material compared with the case where no paper is interposed. It is possible to form a refractory adhesive layer having a desired thickness with less outflow of the agent. Thereby, the fire prevention performance of the wooden fire door can be dramatically improved. That is, in the present invention, paper, particularly Japanese paper, functions so as to stably form the refractory adhesive layer between the plate materials. Therefore, in the present invention, in particular, if a combustion delay member is formed by laminating two or more sheets of paper with a fire-resistant adhesive layer, and this combustion delay member is press-bonded to each of the core material and the decorative board, the fire protection of the wooden fire door can be prevented. Performance can be further enhanced. It should be noted that such a combustion delay member is a wooden protection member. It may be provided only on one side of the fire door to which the fire protection performance is to be provided.

[0033] さらに、本発明では、このような燃焼遅延部材は、防火性能を高める点で、例えば、 芯材とダミー材との間に設けるのが好ましい。そして、このダミー材と化粧板とは耐火 接着剤層によって接着するのが好ましい。これにより、耐火接着剤層の層の数が増え 、火災発生時には、これら各耐火接着剤層が無機発泡体となり、木製防火扉の防火 性能を高めることができる。また、このようなダミー材には燃焼遅延剤を含浸させて不 燃材とするのがさらに好ましい。これにより、火災発生時には、この不燃材が火や熱を 長期間に亘つてトラップできる。勿論、本発明はこれに限定されず、このようなダミー 材及び不燃材の少なくとも何れか一方を芯材と燃焼遅延部材との間に設けるようにし てもよいし、ダミー材及び不燃材を複数枚設けてもよい。何れにしても、このようなダミ ー材又は不燃材の少なくとも何れか一方を芯材と化粧板との間に少なくとも 1枚設け ることにより、木製防火扉の防火性能を高めることができる。  Further, in the present invention, such a combustion delay member is preferably provided, for example, between a core material and a dummy material in order to enhance fire prevention performance. Then, it is preferable that the dummy material and the decorative board are bonded by a fire-resistant adhesive layer. As a result, the number of fire-resistant adhesive layers is increased, and when a fire occurs, each of the fire-resistant adhesive layers becomes an inorganic foam, so that the fire prevention performance of the wooden fire door can be enhanced. More preferably, such a dummy material is impregnated with a combustion retardant to make it a noncombustible material. As a result, when a fire occurs, this non-combustible material can trap fire and heat for a long period of time. Of course, the present invention is not limited to this, and at least one of such a dummy material and a non-combustible material may be provided between the core material and the combustion delay member. It may be provided. In any case, by providing at least one of such a dummy material or a non-combustible material between the core material and the decorative plate, the fire prevention performance of the wooden fire door can be enhanced.

[0034] また、本発明の木製防火扉では、ダミー材の他、例えば、化粧板として木製合板を 用いる場合には、その木製合板に燃焼遅延剤を含浸させてもよい。すなわち、ダミー 材の代わりに、木製合板に燃焼遅延剤を含浸してもよいし、ダミー材及び木製合板 のそれぞれに燃焼遅延剤を含浸してもよい。勿論、所望の防火性能を確保するため に、必要に応じて、芯材に燃焼遅延剤を含浸又は塗布してもよい。  [0034] In the wooden fire door of the present invention, in addition to the dummy material, for example, when a wooden plywood is used as a decorative board, the wooden plywood may be impregnated with a combustion retardant. That is, instead of the dummy material, a wooden plywood may be impregnated with a combustion retardant, or each of the dummy material and the wooden plywood may be impregnated with a combustion retardant. Of course, the core material may be impregnated or coated with a flame retardant, if necessary, to secure the desired fire protection performance.

[0035] さらに、本発明では、防火性能を高める点で、このようなダミー材又は不燃材と燃焼 遅延部材、芯材及び化粧板とをプレス接着するのが好ましい。例えば、燃焼遅延部 材、不燃材、芯材及び化粧板のそれぞれを同時にプレス接着してもよいが、燃焼遅 延部材と不燃材とを予めプレス接着した後、これを芯材とィヒ粧板との間に挟んで相互 に接着してもよいし、芯材と化粧板との間に挟んだ後、さらにプレス接着してもよレ、。  Further, in the present invention, from the viewpoint of enhancing fire prevention performance, it is preferable to press-bond such a dummy material or non-combustible material to the combustion delay member, the core material, and the decorative board. For example, the combustion delay member, the non-combustible material, the core material, and the decorative plate may be press-bonded at the same time. It may be sandwiched between the boards and adhered to each other, or may be sandwiched between the core material and the decorative board and then further press-bonded.

[0036] なお、このような不燃材として用いる木材は、燃焼遅延剤を含浸するものであれば 特に限定されず、従来公知の天然木材を使用できるが、その一例を挙げれば、例え ば、桐、杉、唐松、及び椋など、あるいは、これらの集成材、若しくは、積層材などが 挙げられる。勿論、木材のほか、樹脂等に燃焼遅延剤を含浸させて不燃材としてもよ レ、。なお、このような不燃材の厚さは、特に限定されないが、例えば、約 3— 6mmのも のがよい。 [0037] このような木材等に含浸させる燃焼遅延剤としては、リン酸系タイプ、ホウ酸系タイ プ、ノンハロゲン系の水溶性タイプ等を使用するのが好ましぐ無毒無臭であり、且つ 揮発性有機化合物 (VOC)等を一切使用してレ、なレ、ものが好ましレ、。 [0036] The wood used as such a non-combustible material is not particularly limited as long as it is impregnated with a flame retardant, and conventionally known natural wood can be used. , Cedar, karamatsu, and ryou, or a laminated material or a laminated material thereof. Of course, in addition to wood, a resin or the like may be impregnated with a flame retardant to make it a non-combustible material. The thickness of such a noncombustible material is not particularly limited, but is preferably, for example, about 3 to 6 mm. As such a flame retardant for impregnating wood or the like, it is preferable to use a phosphoric acid type, a boric acid type, a non-halogen type water-soluble type, etc., which are non-toxic and odorless and volatile. Using organic compounds (VOC), etc.

[0038] 特に、本発明では、少なくとも防炎薬剤を含有する燃焼遅延剤を用いるのが好まし レ、。このような防炎薬剤としては、少なくともポリリン酸アンモニゥム及びホウ酸の少な くとも一方を成分として含み、木材に含浸するものであれば特に限定されない。このよ うな燃焼遅延剤に含まれるホウ酸等は、芯材、あるいは不燃材等の燃焼時に、木材 の組織体(セルロース、へミセルロース、リグニン等)に含まれる OH基と反応すること で、燃えにくい炭化層と水とを発生し、可燃性物質の生成を防止する作用(脱水炭化 作用)を発揮するものである。このため、燃焼遅延剤にはホウ酸等を多く含有させると 効果的である。例えば、ホウ酸化合物を常温で 5gZ水 100gに相当する溶解度以上 となるように混合した高濃度ホウ酸化合物を含有した燃焼遅延剤であるのが好ましい 。勿論、燃焼遅延剤には、このようなホウ酸化合物の他に、必要に応じて、例えば、リ ン酸、シラノール塩、及び高分子材料等を含有させてもよい。特に好ましくは、金属ィ オン封鎖剤や湿潤浸透性の界面活性剤の一種以上とリン酸化合物ゃシラノール塩 等からなる高濃度ホウ酸化合物を含有してレ、るのがよレ、。  In particular, in the present invention, it is preferable to use a flame retardant containing at least a flame retardant. Such a flameproofing agent is not particularly limited as long as it contains at least one of ammonium polyphosphate and boric acid as a component and impregnates wood. Boric acid and the like contained in such a flame retardant react with OH groups contained in wood tissue (cellulose, hemicellulose, lignin, etc.) during the burning of the core material or non-combustible material. It generates an inflammable carbonized layer and water, and exerts the action of preventing the generation of flammable substances (dehydration carbonizing action). For this reason, it is effective to include a large amount of boric acid or the like in the combustion retardant. For example, a flame retardant containing a high-concentration boric acid compound obtained by mixing a boric acid compound so as to have a solubility equal to or higher than 100 g of 5 g Z water at normal temperature is preferable. Of course, in addition to such a boric acid compound, for example, a phosphoric acid, a silanol salt, a polymer material, or the like may be contained in the combustion retardant, if necessary. It is particularly preferable to include a high-concentration boric acid compound comprising one or more of a metal ion sequestering agent or a wet-permeable surfactant and a phosphoric acid compound / silanol salt.

[0039] ここで、このような防炎薬剤としては、例えば、ポリリン酸アンモニゥム及び硫酸アン モニゥムを主成分とし、必要に応じて、さらに他の成分を含有する防炎薬剤が挙げら れる。または、ホウ酸を主成分とし、必要に応じてさらに他の成分を含有する防炎薬 剤が挙げられる。勿論、これら各防炎薬剤を混合した防炎薬剤を用いてもよい。なお 、このようなホウ酸等のホウ酸系の化合物は、防腐防蟻効果も期待できる。  [0039] Here, examples of such a flameproofing agent include a flameproofing agent mainly containing ammonium polyphosphate and ammonium sulfate, and further containing other components as necessary. Alternatively, a flameproofing agent containing boric acid as a main component and further containing other components as necessary may be mentioned. Of course, a flame retardant obtained by mixing these flame retardants may be used. It should be noted that such a boric acid-based compound such as boric acid can also be expected to have an antiseptic / antibiotic effect.

[0040] また、本発明では、燃焼遅延剤には、上述した防炎薬剤と共に木材等が燃焼して 炭化した炭化残渣を固定するための無機材料を含有させることができる。すなわち、 無機材料は、高温加熱下で溶融してガラス状態となって燃えにくい炭化残渣を固定 化するように作用し、炭化残渣が落下するのを防止し、さらに水を発生する性能があ るので、表面温度を低下させるものであり、これにより防火性能がさらに向上する。よ り詳細には、結晶水を持つ無機塩類が、燃焼時に、その結晶水を放出又は分解して 、吸熱効果を発揮する。このような炭化残渣を固定化する無機材料としては、ケィ酸 塩、ホウケィ酸塩、ホウ酸塩、およびシリカから選択される少なくとも一種が挙げられ、 ケィ酸塩としては、例えば、二酸化ケイ素とアルカリとを融解して得られたケィ酸アル カリ塩である水ガラスが挙げられる。但し、通常の水ガラスを使用するとアルカリ成分 が強すぎるので、アルカリ性を 70— 80。/o低減したものを用いることが好ましい。また、 ホウ酸塩としては、例えば、ホウ酸ナトリウム(ホウ砂)が挙げられる。なお、このような ホウ酸塩についても、上述したホウ酸と同様に、防腐防蟻効果が期待できる。 [0040] Further, in the present invention, the flame retardant may contain an inorganic material for fixing a carbonized residue obtained by burning wood or the like, together with the flame retardant. In other words, the inorganic material acts to fix the carbonized residue that melts under high-temperature heating to become a glass state and is difficult to burn, prevents the carbonized residue from dropping, and has the ability to generate water. Therefore, the surface temperature is reduced, and the fire prevention performance is further improved. More specifically, inorganic salts having water of crystallization release or decompose the water of crystallization during combustion to exhibit an endothermic effect. As an inorganic material for immobilizing such a carbonized residue, there is citric acid. At least one selected from salts, borates, borates, and silica. Examples of the silicates include water, which is an alkali silicate obtained by melting silicon dioxide and an alkali. Glass. However, if normal water glass is used, the alkali component is too strong. It is preferable to use one with a reduced / o. Examples of the borate include sodium borate (borax). It should be noted that such a borate can be expected to have an antiseptic and anti-termite effect similarly to the above-mentioned boric acid.

[0041] このように、本発明では、上述した燃焼遅延剤に特定の無機材料を含有させること で、脱水炭化作用と吸熱作用とが複合的に作用し、さらに優れた防火性能を得ること ができる。 [0041] As described above, in the present invention, by including a specific inorganic material in the above-described combustion retardant, the dehydration carbonizing action and the endothermic action act in a combined manner, and further excellent fire prevention performance can be obtained. it can.

[0042] このような燃焼遅延剤の含浸量は、含浸させる木材の種類や寸法に応じて、所望 の防火性能が得られるように適宜調整すればよぐ特に限定されるものではないが、 例えば、厚さ 3 6mmの木材の場合には、液体状態で 50 150g程度が目安となり 、特に、 90g程度が好ましい。また、木材には、燃焼遅延剤を塗布するだけでもよい ので、その場合には、約 200g/m2程度の塗布量とするのが好ましい。 [0042] The amount of such a flame retardant impregnated is not particularly limited as long as it is appropriately adjusted according to the type and dimensions of the wood to be impregnated so as to obtain a desired fire prevention performance. In the case of wood having a thickness of 36 mm, the standard is about 50 150 g in a liquid state, and particularly preferably about 90 g. In addition, since it is sufficient to apply only a flame retardant to wood, in such a case, it is preferable to apply about 200 g / m 2 .

[0043] ここで、木材に燃焼遅延剤を含浸させる方法としては、特に限定されるものではな いが、例えば、容器に十分な量の燃焼遅延剤を入れた後、約 80°Cに温度を上げ、そ の中に木材を所定温度下で一定時間浸漬して含浸させる方法等が挙げられる。なお 、燃焼遅延剤の含浸後は、 1一 2時間以内の自然乾燥、又は加熱により乾燥すること で、一定量の有効成分を含浸させた不燃材が製造される。ここで、本発明でいう木材 に燃焼遅延剤を含浸させるとは、燃焼遅延剤を溜めた容器内に木材を漬ける、いわ ゆるディッビングに限定されず、加圧による含浸であってもよい。  Here, the method for impregnating the wood with the combustion retardant is not particularly limited. For example, after a sufficient amount of the combustion retardant is put in a container, the temperature is raised to about 80 ° C. And a method in which wood is immersed therein at a predetermined temperature for a certain period of time for impregnation. After impregnation with the flame retardant, the non-combustible material impregnated with a certain amount of the active ingredient is produced by natural drying within 1 to 12 hours or drying by heating. Here, impregnating the wood with the combustion retardant in the present invention is not limited to so-called diving, in which the wood is immersed in a container storing the combustion retardant, and impregnation by pressure may be used.

[0044] なお、上述した燃焼遅延部材の製造方法は、特に限定されなるものではないが、例 えば、ロールコータ等を用いて、紙の一方面の全面に耐火接着剤層を約 200g/m2 塗布し、その上から別の紙又は不燃材等を張り合わせることで製造される。なお、こ の張り合わせの際、紙と不燃材とをプレス接着してもよい。そして、本発明の木製防 火扉は、芯材の扉表面側の両面に燃焼遅延部材を接合した後、その燃焼遅延部材 の面上に化粧板をそれぞれ接合することで木製防火扉が製造される。このように、芯 材、化粧板、燃焼遅延部材を相互に接合する際には、一般的に用いられる耐熱性の 接着剤を用いてもよいが、防火性能を高める点では、上述した耐火接着剤を用いる のが特に好ましい。これにより、非常に優れた防火性能を有する木製防火扉が実現 できる。 [0044] The method for manufacturing the above-described combustion retardation member is not particularly limited. For example, a fire-resistant adhesive layer is applied to the entire surface of one side of the paper at about 200 g / m2 using a roll coater or the like. It is manufactured by applying 2 pieces and then attaching another paper or non-combustible material. At this time, the paper and the non-combustible material may be press-bonded. In the wooden fire door of the present invention, a wooden fire door is manufactured by joining a combustion delay member to both surfaces of the core material on the door surface side, and then joining decorative panels on the surfaces of the combustion delay member. You. As described above, when the core material, the decorative board, and the combustion delay member are joined to each other, a heat-resistant material generally used is used. Although an adhesive may be used, it is particularly preferable to use the above-described fire-resistant adhesive from the viewpoint of enhancing fire prevention performance. As a result, a wooden fire door having very excellent fire protection performance can be realized.

[0045] 以上説明した本発明のように燃焼遅延部材を用いた木製防火扉は従来存在せず 、これを用いることにより、従来の耐火性板や耐火シートなどを用いるよりも、非常に 高い防火性能を有する木製防火扉を低コストで提供できる。  [0045] As described above, there is no conventional wooden fire door using a combustion delay member as in the present invention. By using such a fire door, a very high fire protection can be obtained as compared with a conventional fire-resistant plate or fire-resistant sheet. A high performance wooden fire door can be provided at low cost.

[0046] ここで、本発明の木製防火扉に用いる芯材は、防火性能や軽量化の点で、桐材を 用いるのが好ましいが、防火性能の点で問題がなければ、他の木材を芯材としてもよ レ、。すなわち、芯材に用いる桐材は、それ自体で防火性能を発揮するものであるが、 このような桐材の他に、上述した燃焼遅延剤の含浸量、コスト、扉重量、あるいは扉の 強度等を考慮して、例えば、杉、唐松、及び椋等の木材を用いることができる。特に、 扉の強度を高める点では、杉材及び唐松等を用いるのが好ましぐコスト的には、杉 及び唐松等の間伐材を用いるのが好ましい。また、扉重量の軽量化を図る点では桐 材を用いるのが好ましい。このように扉の軽量ィ匕を図れば、運搬費を低く抑えることが でき、取り付け時の作業性を向上できるという効果もある。さらに、このように芯材を桐 材とする場合には、桐材として反りが出難いとされている品質の材料を用いるのが好 ましレ、。また、芯材は、天然の桐から切り出した桐材又は桐の集成材の何れを用いて もよぐ 1枚物でも積層材でもよいが、積層する場合には奇数枚用いるのが好ましい。 何れにしても、要求される防火性能や、コスト等を考慮して、芯材を形成する木種を 適宜決定すればよい。  Here, as the core material used for the wooden fire door of the present invention, it is preferable to use a paulownia material from the viewpoint of fire protection performance and weight reduction, but if there is no problem in fire protection performance, other wood may be used. It can be used as a core material. In other words, the paulownia wood used as the core material itself exhibits fire protection performance. In addition to such paulownia wood, the impregnation amount of the combustion retardant, cost, door weight, or door strength In consideration of the above, for example, wood such as cedar, Karamatsu, and Ryou can be used. In particular, in order to increase the strength of the door, it is preferable to use cedar and karamatsu, etc., and in terms of cost, it is preferable to use thinned cedar and matsu. Also, it is preferable to use paulownia wood from the viewpoint of reducing the weight of the door. If the door is lightened in this way, it is possible to reduce the transportation cost and to improve the workability at the time of installation. Furthermore, when the core is made of paulownia wood, it is preferable to use a paulownia wood of a quality that is unlikely to warp. The core material may be any one of a paulownia wood cut from natural paulownia wood and a paulownia laminated wood, and may be a single material or a laminated material. When laminating, it is preferable to use an odd number. In any case, the type of wood forming the core material may be appropriately determined in consideration of required fire prevention performance, cost, and the like.

[0047] 一般的には、桐の集成材を用いて複数枚積層して用いるのが好ましぐさらに、木 目(繊維方向)を略直交するようにクロスさせて 3層構造とした積層材が特に好ましレ、  [0047] In general, it is preferable to laminate a plurality of plies using a paulownia laminated wood, and furthermore, a laminated material having a three-layer structure in which the grain (fiber direction) is crossed so as to be substantially orthogonal. Is particularly preferred,

[0048] また、桐材は熱による反りが生じやすいので、面方向の四方、すなわち、扉の四辺 を、桐材より堅ぐ反りにくい木材からなる補強部材 (框材)で覆うようにする必要があ る。このような補強部材としては、比重 0. 5以上の天然木集成材であるのが好ましぐ 人工合板、 L. V. L (天然目平行合板集成材)などの框材を挙げることができる。また 、補強部材は、防火性能を高める点で、上述した耐火接着剤を介して積層材等に接 合するのが好ましい。勿論、桐材であっても、その桐材を用いて桐集成材とすれば、 強度は確保できるので、これを補強部材として用いてもよい。また、本発明では、補 強部材として天然木集成材を 3層クロス張りしたものを用いてもよい。この場合には、 各天然木集成材を耐火接着剤により接合することで、防火性能をさらに高めることが できる。そして、積層材と補強部材とは、凹凸部を介して相互に嵌合する構造により 接合してもよぐこのような場合にも、耐火接着剤を介して接合するのが防火性能の 点で好ましい。なお、本発明では、このような補強部材を積層材に含めて芯材という。 [0048] In addition, since paulownia wood is likely to be warped by heat, it is necessary to cover the four sides of the surface, that is, the four sides of the door, with a reinforcing member (frame material) made of wood that is harder to warp than paulownia wood. There is. Examples of such reinforcing members include artificial plywood, which is preferably a natural wood laminated wood having a specific gravity of 0.5 or more, and frame materials such as LVL (natural grain parallel plywood laminated wood). In addition, the reinforcing member is in contact with the laminated material or the like via the above-described fire-resistant adhesive in terms of enhancing fire protection performance. It is preferable to combine them. Of course, even if it is a paulownia wood, if the paulownia wood is used as a paulownia laminated wood, the strength can be secured, and this may be used as a reinforcing member. Further, in the present invention, a three-layer cloth of natural wood laminated wood may be used as the reinforcing member. In this case, the fire protection performance can be further improved by joining the natural wood laminated timber with a fire-resistant adhesive. In such a case, the laminated material and the reinforcing member may be joined by a structure in which they are fitted to each other via the uneven portion. preferable. In the present invention, such a reinforcing member is included in a laminated material and is referred to as a core material.

[0049] さらに、本発明の木製防火扉の最外表面には、化粧板が設けられている。化粧板と しては、例えば、天然の木材を用いて形成した集成材、積層材や、木製合板、あるい は珪酸カルシウム板等のケミカル板等が挙げられる。なお、化粧板として木製の板材 を用いる場合には、化粧板に上述した燃焼遅延剤を含浸させなくてもよいが、勿論、 必要に応じて含浸させてもよい。また、ケミカル板は、ある程度の防火性能を有するこ とから、化粧板としてケミカル板を用いた木製防火扉は、燃焼遅延剤を含浸させた木 製の板材を化粧板として用いた木製防火扉と比べて、防火性能が低下することは殆 どない。 [0049] Further, a decorative plate is provided on the outermost surface of the wooden fire door of the present invention. Examples of the decorative board include a laminated wood and a laminate formed using natural wood, a chemical board such as a wooden plywood or a calcium silicate board. When a wooden board is used as the decorative board, the decorative board does not need to be impregnated with the above-described combustion retardant, but may be impregnated if necessary. In addition, since a chemical plate has a certain degree of fire prevention performance, a wooden fire door using a chemical plate as a decorative plate is different from a wooden fire door using a wooden plate material impregnated with a flame retardant as a decorative plate. In comparison, fire prevention performance hardly decreases.

[0050] 以上説明したように、本発明の木製防火扉は、両面に耐火接着剤層を有する少な くとも 1枚の紙からなる燃焼遅延部材を芯材とィヒ粧板との間に設けた比較的簡単な構 造にも関わらず、 ISO基準に基づく平均約 900°Cの燃焼試験において 60分以上の 防火性能が得られるものである。  [0050] As described above, the wooden fire door of the present invention is provided with a combustion delay member made of at least one sheet of paper having a fire-resistant adhesive layer on both sides, between the core material and the lig board. Despite its relatively simple structure, fire protection performance of more than 60 minutes can be obtained in a combustion test at an average of about 900 ° C based on ISO standards.

[0051] また、本発明に係る木製防火扉は、耐火シート等を用いなくても、比較的簡単な構 造で、優れた防火性能を発揮するため、従来品と比べて、製造コストが大幅に低減 でき、製品を低コストで提供することができる。  Further, the wooden fire door according to the present invention has a relatively simple structure without using a fire-resistant sheet or the like, and exhibits excellent fire prevention performance. The product can be provided at low cost.

[0052] ここで、本発明では、上述したように、芯材と化粧板との間に燃焼遅延部材を介在さ せることで、非常に優れた防火性能が得られるため、これ以外に扉に対して防火対 策を施さなくてもよいが、必要に応じて、芯材、化粧板等に燃焼遅延剤を含浸、又は 塗布することで、防火性能をさらに高めることができる。  Here, in the present invention, as described above, by interposing a combustion delay member between the core material and the decorative plate, extremely excellent fire prevention performance can be obtained. It is not necessary to take fire-prevention measures, but if necessary, impregnating or applying a flame retardant to the core material, decorative panel, etc. can further enhance the fire-prevention performance.

[0053] 例えば、補強部材を取り付けた芯材に燃焼遅延剤を含浸させる場合には、そのま ま全体に燃焼遅延剤を含浸させてもよいが、桐材のみに燃焼遅延剤を含浸させた後 、補強部材を取り付けてもよい。勿論、このように補強部材を後付する場合、補強部 材にも燃焼遅延剤を含浸、塗布することで、防火性能をさらに高めることができる。 For example, when impregnating the core with the reinforcing member attached thereto with the combustion retardant, the entire body may be impregnated with the combustion retardant as it is, but only the paulownia wood is impregnated with the combustion retardant. rear , A reinforcing member may be attached. Of course, when the reinforcing member is retrofitted in this manner, the fire retarding performance can be further enhanced by impregnating and applying the combustion retarder to the reinforcing member.

[0054] また、積層材を用いて芯材を構成する場合には、防火性能を高めるため集成材等 を耐火接着剤により接着するのが好ましいが、本発明では、燃焼遅延部材を用いる ことで優れた防火性能が得られるので、集成材等を耐火接着剤により接着しなくても よい。勿論、要求される防火性能に応じて、耐火接着剤を介して積層材を接合して芯 材としてもよい。  When a core material is formed using a laminated material, it is preferable to adhere a laminated material or the like with a fire-resistant adhesive in order to enhance fire prevention performance. However, in the present invention, by using a combustion delay member, Since excellent fire protection performance can be obtained, it is not necessary to glue the laminated wood with a fire-resistant adhesive. Of course, according to the required fire protection performance, the laminated material may be joined via a fire-resistant adhesive to form a core material.

[0055] なお、本発明では、両面に耐火接着剤層を有する少なくとも 1枚の紙からなる燃焼 遅延部材を芯材と化粧板との間に設けた以外は、木製防火扉の構造は特に限定さ れず、要求される防火性能に応じて、従来力もの公知の防火構造を採用してもよい。  In the present invention, the structure of the wooden fire door is not particularly limited except that a combustion delay member made of at least one sheet of paper having a fire-resistant adhesive layer on both sides is provided between the core material and the decorative plate. Instead, a well-known fire prevention structure may be employed according to the required fire prevention performance.

[0056] 例えば、桐集成材と熱硬化性樹脂積層板とを積層したもの(特開平 7—259445号 公報に開示された構造)、桐材と不燃紙とを組み合わせたもの(特開平 7— 293127 号公報に開示された構造)、桐材とフエノールフォームとを組み合わせたもの(特開平 7-324561号公報に開示された構造)、桐集成材に耐火シートを組み合わせたもの (特開平 9一 256746号公報に開示された構造)、桐材と火山性ガラス繊維板とを組 み合わせたもの(特開 2000— 179245号公報に開示された構造)等を用いることが できるが、桐の集成材を積層した桐積層板のみを用いたもの(特開平 7-208033号 公報に開示された構造)でもよぐさらに、桐材の反りを防止する構造 (特開 2000-3 10090号公報に開示された構造)を適用してもよい。  [0056] For example, a paulownia laminate and a thermosetting resin laminate are laminated (the structure disclosed in JP-A-7-259445), and a paulownia wood and non-combustible paper are combined (JP-A-7-259445). No. 293127), a combination of paulownia wood and phenolic foam (structure disclosed in JP-A-7-324561), and a combination of paulownia glue laminated with a refractory sheet (Japanese Unexamined Patent Publication No. The structure disclosed in Japanese Patent No. 256746), a combination of paulownia wood and a volcanic glass fiber plate (the structure disclosed in Japanese Patent Application Laid-Open No. 2000-179245) and the like can be used. A structure using only paulownia laminates laminated with materials (the structure disclosed in Japanese Patent Application Laid-Open No. 7-208033) may be used. May be applied.

[0057] 以下、本発明を実施するための最良の形態について説明する。  Hereinafter, the best mode for carrying out the present invention will be described.

[0058] (実施形態 1)  (Embodiment 1)

図 1は、本発明の実施形態 1に係る木製防火扉の概略斜視図である。また、図 2は 、本発明の実施形態 1に係る木製防火扉の断面図であって、(a)は縦断面図であり、 (b)は横断面図である。さらに、図 3は、木製防火扉の要部拡大断面図である。  FIG. 1 is a schematic perspective view of a wooden fire door according to Embodiment 1 of the present invention. 2 is a cross-sectional view of the wooden fire door according to Embodiment 1 of the present invention, in which (a) is a longitudinal sectional view and (b) is a transverse sectional view. FIG. 3 is an enlarged sectional view of a main part of the wooden fire door.

[0059] 図 1及び図 2に示すように、本実施形態の木製防火扉 10は、複数の桐部材 21— 2 3を積層した桐積層板 24と、その四方に設けられた補強部材 25とからなる芯材 20と 、芯材 20の表面に接合された木製合板からなる化粧板 30とを具備する。  As shown in FIG. 1 and FIG. 2, the wooden fire door 10 of the present embodiment includes a paulownia laminate 24 in which a plurality of paulownia members 21-23 are laminated, and reinforcing members 25 provided on four sides thereof. And a decorative plate 30 made of a wooden plywood joined to the surface of the core material 20.

[0060] 桐積層板 24は、木目方向(繊維方向)が長手方向に一致した桐部材 21、 22との間 に、桐部材 21、 22の木目方向と直交する方向である桐部材 23を挟持して積層した 3 層クロス張り構造である。なお、この桐積層板 24を構成する桐部材 21— 23は、それ ぞれ所定の大きさに形成されたものであってもょレ、し、短レ、寸法のものを複数枚継ぎ 合わせたものであってもよレ、。このように桐部材 21— 23の木目方向が略直交するよう にクロス張りすることによって形成された桐積層板 24は効果的に反りの発生を防止す ること力 Sできる。 [0060] The paulownia laminate 24 is positioned between the paulownia members 21 and 22 whose grain direction (fiber direction) matches the longitudinal direction. Furthermore, the paulownia members 21 and 22 have a three-layer cross-clad structure in which a paulownia member 23 that is a direction orthogonal to the grain direction is sandwiched and laminated. The paulownia members 21 to 23 constituting the paulownia laminate 24 may be formed in a predetermined size, and may be formed by joining a plurality of short pieces and dimensions. It may be something. The paulownia laminate 24 formed by cross-tensioning the paulownia members 21-23 so that the grain direction is substantially orthogonal to the paulownia members 21-23 can effectively prevent warpage.

[0061] また、桐積層板 24の上下左右の端面には、桐材より堅い木材、本実施形態では合 成合板からなる補強部材 25が設けられている。このような補強部材 25は、例えば、 本実施形態では、桐集成材を用いた。このように、桐積層板 24の四方を補強部材 25 で囲って芯材 20としたので、反りをより確実に防止することができる。なお、補強部材 25の厚さ(扉の面方向の寸法)は、木製防火扉の防火性能によって異なる力 60分 防火試験を満足するためには、 150mm厚程度のものが必要となる。  [0061] Further, reinforcing members 25 made of wood harder than paulownia wood, in this embodiment, a composite plywood, are provided on the upper, lower, left, and right end surfaces of the paulownia laminated board 24. For such a reinforcing member 25, for example, in this embodiment, a paulownia laminated wood is used. Thus, since the core material 20 is formed by surrounding the four sides of the paulownia laminate 24 with the reinforcing members 25, warpage can be more reliably prevented. The thickness of the reinforcing member 25 (dimension in the surface direction of the door) needs to be about 150 mm in order to satisfy a fire test of 60 minutes, which depends on the fire protection performance of the wooden fire door.

[0062] さらに、本実施形態の木製防火扉 10においては、補強部材 25の扉端面側の表面 には、発泡材 40が長手方向に亘つて埋め込まれるように設けられており、発泡材 40 を覆うように補強部材 25の扉端面側表面には大手材又は横手材となる化粧材 50が 設けられている。  Further, in the wooden fire door 10 of the present embodiment, a foam material 40 is provided on the surface on the door end face side of the reinforcing member 25 so as to be embedded in the longitudinal direction. A decorative material 50 which is a large material or a side material is provided on the surface of the reinforcing member 25 on the door end surface side so as to cover the reinforcing member 25.

[0063] ここで、発泡材 40としては、例えば、 230°C程度で厚さ方向に 10倍程度に膨張す るグラフアイト系発泡材を用いればよぐこれにより間口との隙間を完全に塞ぐことが でき、煙の流れを防止すると共に延焼を防止することができる。この発泡材 40は本実 施形態では、防火扉の四方に設けたが、少なくとも三方の端面に設ければよい。また 、化粧材 50は、場所によっては必要に応じて省略できるものである。  Here, as the foam material 40, for example, a graphite foam material that expands about 10 times in the thickness direction at about 230 ° C. may be used, thereby completely closing the gap with the frontage. It can prevent the flow of smoke and the spread of fire. In this embodiment, the foam material 40 is provided on four sides of the fire door, but may be provided on at least three end faces. Further, the cosmetic material 50 can be omitted as necessary depending on the place.

[0064] また、化粧板 30は、芯材 20の表面に接合されており、本実施形態では、厚さ 4mm の木製合板を用いた。  [0064] Further, the decorative board 30 is bonded to the surface of the core material 20, and in this embodiment, a wooden plywood having a thickness of 4 mm was used.

[0065] このような芯材 20と化粧板 30との間には、本発明では、両面に耐火接着剤からな る耐火接着剤層を有する少なくとも 夂の紙からなる燃焼遅延部材が設けられている 。例えば、本実施形態では、図 3に示すように、燃焼遅延部材 100は、 3枚の和紙 10 1を耐火接着剤からなる耐火接着剤層 102によってそれぞれ接着したものとした。そ して、この燃焼遅延部材 100は、芯材 20及び化粧板 30のそれぞれと耐火接着剤層 102によって接合されている。 [0065] Between the core material 20 and the decorative board 30, in the present invention, there is provided a combustion retarding member made of at least a profile paper having a fire-resistant adhesive layer made of a fire-resistant adhesive on both surfaces. There. For example, in the present embodiment, as shown in FIG. 3, the combustion delay member 100 is formed by bonding three Japanese papers 101 with a fire-resistant adhesive layer 102 made of a fire-resistant adhesive. The flame retardant member 100 is made of a core material 20 and a decorative board 30 and a fire-resistant adhesive layer. Joined by 102.

[0066] ここで、図 4を参照して、燃焼遅延部材 100を説明する。なお、図 4は、本発明の実 施形態 1に係る燃焼遅延部材及びその製造方法を説明する要部拡大断面図である 。燃焼遅延部材 100は、以下のようにして製造される。具体的には、まず、図 4 (a)に 示すような厚さ 0. 1-0. 6mmの和紙 101を 3枚用意する。その後、図 4 (b)に示すよ うに、芯材 20の一方面上に、例えば、ロールコータ等を用いて、耐火接着剤を約 20 Og/m2塗布して耐火接着剤層 102を形成する。その後、この耐火接着剤層 102の 上から和紙 101を張り合わせ、同様の作業を 2回繰り返すことにより、図 4 (c)に示す ように、 3枚の和紙 101を耐火接着剤層 102によって接着する。次に、図 4 (d)に示す ように、この和紙 101の上に耐火接着剤層 102を形成した後、化粧板 30を貼ることに より、芯材 20と化粧板 30との間に燃焼遅延部材 100が形成される。 Here, the combustion delay member 100 will be described with reference to FIG. FIG. 4 is an enlarged sectional view of an essential part for explaining a combustion delay member and a method for manufacturing the same according to Embodiment 1 of the present invention. The combustion delay member 100 is manufactured as follows. Specifically, first, three pieces of Japanese paper 101 having a thickness of 0.1 to 0.6 mm as shown in FIG. 4A are prepared. Thereafter, as shown in Figure. 4 (b), in the on one surface of the core member 20, for example, using a roll coater, a refractory adhesive about 20 Og / m 2 applied to a refractory adhesive layer 102 formed I do. Thereafter, the Japanese paper 101 is stuck on the fire-resistant adhesive layer 102, and the same operation is repeated twice, so that the three sheets of Japanese paper 101 are bonded by the fire-resistant adhesive layer 102 as shown in FIG. 4 (c). . Next, as shown in FIG. 4 (d), after forming a refractory adhesive layer 102 on the washi paper 101, a decorative board 30 is attached, so that the burning between the core material 20 and the decorative board 30 is performed. A delay member 100 is formed.

[0067] そして、このような燃焼遅延部材 100は、本実施形態では、図 5に示すように、芯材 20と化粧板 30とのそれぞれに耐火接着剤層 102を介して当接させた後、所定の荷 重でプレス接着するようにした。このとき、各和紙 101に耐火接着剤層 102の有効成 分が含浸され且つ両者が一体化する。これにより、木製防火扉の防火性能を飛躍的 に高めることができる。勿論、本実施形態のように、複数枚の和紙 101を用いて燃焼 遅延部材 100を形成する際には、例えば、化粧板 30上に和紙 101を耐火接着剤層 102を介して積層して、その上に芯材 20をプレス接着するようにしてもよい。  In the present embodiment, as shown in FIG. 5, the combustion delay member 100 is brought into contact with each of the core material 20 and the decorative plate 30 via the fire-resistant adhesive layer 102. Press bonding was performed under a predetermined load. At this time, each Japanese paper 101 is impregnated with the effective component of the fire-resistant adhesive layer 102 and both are integrated. As a result, the fire prevention performance of the wooden fire door can be dramatically improved. Of course, when the combustion delay member 100 is formed using a plurality of Japanese papers 101 as in the present embodiment, for example, the Japanese paper 101 is laminated on the decorative board 30 via the fire-resistant adhesive layer 102, The core material 20 may be press-bonded thereon.

[0068] ここで、耐火接着剤層 102を形成する耐火接着剤としては、少なくともシロキサンと シラノール塩とからなる無機材料を含有しているのが好ましい。例えば、本実施形態 では、耐火接着剤は、ホウ酸化合物やフッ化物等の無機酸の存在下で、金属ケィ素 (純度 99%)と水酸化ナトリウムとを水溶媒中で反応させることで生成したシロキサン とシラノール塩とからなる無機材料を含有させた。また、このような無機材料は、 Si/ Naの成分比が 2以上であり、アモルファス状で pHが 12以下、硬度 500cP以下の低 粘性を有する材料である。例えば、本実施形態では、このような耐火接着剤として、 水性造膜性無機化合物「リキッドセラミックス (LC)シリカ系」(商品名:コーミックス (株 )製)を用いた。  Here, the refractory adhesive forming the refractory adhesive layer 102 preferably contains at least an inorganic material composed of a siloxane and a silanol salt. For example, in this embodiment, the refractory adhesive is formed by reacting metal silicon (purity 99%) with sodium hydroxide in an aqueous solvent in the presence of an inorganic acid such as a boric acid compound or a fluoride. An inorganic material consisting of the siloxane and the silanol salt was contained. Further, such an inorganic material is a material having an Si / Na component ratio of 2 or more, an amorphous material having a pH of 12 or less and a hardness of 500 cP or less and having low viscosity. For example, in the present embodiment, an aqueous film-forming inorganic compound “Liquid Ceramics (LC) silica-based” (trade name: manufactured by Comix Corporation) was used as such a refractory adhesive.

[0069] そして、本実施形態では、耐火接着剤層 102がシロキサンゃシラノール塩とからな る無機材料を含有しているので、火災発生時に比較的高い温度で加熱されると、無 機発泡体となり、優れた断熱性能及び防水性能を発揮する。このため、本実施形態 の木製防火扉 10は、火災発生時には、燃焼遅延部材 100の化粧板 30側から無機 発泡体となり、これが火や熱を長時間に亘つて遮断する。そして、この無機発泡体に よる断熱効果が低減しても、和紙と和紙とに挟まれた各耐火接着剤層 102も同様に 無機発泡体となるので、火や熱をさらにトラップし、芯材 20が燃焼してしまうのを有効 に遮断できる。 [0069] In the present embodiment, the refractory adhesive layer 102 is made of a siloxane / silanol salt. When heated at a relatively high temperature in the event of a fire, it becomes an inorganic foam and exhibits excellent heat insulation and waterproof properties. For this reason, when a fire occurs, the wooden fire door 10 of the present embodiment becomes an inorganic foam from the decorative plate 30 side of the combustion delay member 100, which blocks fire and heat for a long time. Even if the heat insulating effect of the inorganic foam is reduced, the fire-resistant adhesive layer 102 sandwiched between the Japanese paper and the Japanese paper is also made of the inorganic foam. 20 can be effectively blocked from burning.

[0070] また、このような耐火接着剤層 102は、防水効果があり、防水シートとしての役割を 果たすため、芯材 20からの水分の発散による反りの発生を効果的に防止することが できる。したがって、本実施形態の木製防火扉 10は、火や熱を長時間遮断すると共 に反りの発生を防止できるので、非常に優れた防火性能を得ることができる。  [0070] Further, since such a fire-resistant adhesive layer 102 has a waterproof effect and functions as a waterproof sheet, it is possible to effectively prevent the warpage due to the diffusion of moisture from the core material 20. . Therefore, the wooden fire door 10 of the present embodiment can prevent fire and heat for a long period of time and also prevent the occurrence of warpage, so that extremely excellent fire prevention performance can be obtained.

[0071] 以上説明したように、本実施形態の木製防火扉 10は、芯材 20と化粧板 30との間 に、両面及び 3枚の和紙 101のそれぞれの間に耐火接着剤層 102を有する燃焼遅 延部材 100を設けるようにしたので、火災発生時には、比較的簡単な構造にも関わら ず、非常に優れた防火性能を得ることができる。  As described above, the wooden fire door 10 of the present embodiment has the fire-resistant adhesive layer 102 between the core material 20 and the decorative board 30 and between both sides and each of the three sheets of Japanese paper 101. Since the combustion delay member 100 is provided, extremely excellent fire prevention performance can be obtained in the event of a fire despite the relatively simple structure.

[0072] また、木製防火扉 10は、燃焼遅延部材 100の耐火接着剤層 102の防水効果により 、芯材 20等の反りが有効に防止され、経年変化の中での性能低下やコスト等の問題 もない。  Further, the wooden fire door 10 can effectively prevent warpage of the core member 20 and the like by the waterproof effect of the fire-resistant adhesive layer 102 of the combustion delay member 100, and can reduce performance and cost due to aging. No problem.

[0073] なお、燃焼遅延部材 100は、防火性能を付与すべき一方側のみに設けてもよい。  [0073] The combustion delay member 100 may be provided only on one side to which fire protection performance is to be provided.

[0074] (実施形態 2) (Embodiment 2)

図 6は、本発明の実施形態 2に係る木製防火扉の要部拡大断面図である。なお、 本実施形態では、上述した図 1一図 4で説明した同一部分には同一符号を付して重 複する説明は省略する。  FIG. 6 is an enlarged sectional view of a main part of a wooden fire door according to Embodiment 2 of the present invention. Note that, in the present embodiment, the same portions as those described with reference to FIGS. 1 to 4 are denoted by the same reference numerals, and redundant description will be omitted.

[0075] 図 6に示すように、本実施形態の木製防火扉 10Aは、燃焼遅延部材 100をダミー 材に燃焼遅延剤を含浸した不燃材 103と芯材 20との間に設けた以外は上述した実 施形態 1と同様である。 As shown in FIG. 6, the wooden fire door 10A of the present embodiment is the same as the above except that the combustion delay member 100 is provided between the non-combustible material 103 in which a dummy material is impregnated with a combustion retardant and the core material 20. This is the same as in the first embodiment.

[0076] 具体的には、本実施形態の木製防火扉 10Aは、 3枚の和紙 101のそれぞれと不燃 材 103とを耐火接着剤層 102によって接着し、これを芯材 20と化粧板 30とのそれぞ れに耐火接着剤層 102によって更に接着した構造を有している。そして、本実施形 態では、不燃材 103と化粧板 30との間に、両面に耐火接着剤 102を有する 1枚の和 紙 101からなる燃焼遅延部材 100Aが設けられている。 Specifically, the wooden fire door 10A of the present embodiment is configured such that each of the three pieces of Japanese paper 101 and the non-combustible material 103 are bonded with a fire-resistant adhesive layer 102, and the core material 20 and the decorative board 30 are bonded together. Each It has a structure further bonded by a refractory adhesive layer 102. In the present embodiment, between the non-combustible material 103 and the decorative board 30, a combustion delay member 100A made of one piece of Japanese paper 101 having a fire-resistant adhesive 102 on both surfaces is provided.

[0077] ここで、ダミー材に含浸した燃焼遅延剤は、少なくともポリリン酸アンモニゥム及びホ ゥ酸の少なくとも一方を成分として含む防炎薬剤を含有している。例えば、本実施形 態では、ホウ酸を含む防炎薬剤を用いた。このようなホウ酸を含有する防炎薬剤は、 ダミー材に含浸させると、火災発生時には、木材の組織に対する酸素供給を実質的 に止める作用がある。すなわち、ホウ酸は、不燃材 103の燃焼時に、木材の組織体 に含まれる〇H基と反応することで、燃えにくい炭化層と水とを発生し、可燃性物質の 生成を防止する作用(脱水炭化作用)を発揮するものである。  Here, the flame retardant impregnated in the dummy material contains a flame retardant containing at least one of ammonium polyphosphate and boric acid as a component. For example, in the present embodiment, a flame retardant containing boric acid was used. When such a flame retardant containing boric acid is impregnated into a dummy material, it has an effect of substantially stopping the supply of oxygen to the wood tissue in the event of a fire. In other words, boric acid reacts with the 〇H group contained in the wood tissue during combustion of the noncombustible material 103 to generate a hardly combustible carbonized layer and water, thereby preventing the generation of flammable substances ( (Dehydration carbonization).

[0078] また、本実施形態では、ダミー材に、このような防炎薬剤と共に燃焼時に溶融状態 となって炭化残渣を固定する無機材料を含有する燃焼遅延剤を含浸するのが好まし レ、。このような無機材料は、火災発生時等に溶融して、例えば、ガラス状態となり、不 燃材 103が炭化して生成した炭化残渣を相互に固定するように作用する。このため、 無機材料を防炎薬剤と共に木材に含浸させれば、無機材料により炭化残渣が相互 に固定され、炭化残渣が崩れ落ちるのを防止できる。このような無機材料としては、 例えば、水ガラスのアルカリ性を 70%— 80%低減させたもの等が挙げられる。なお、 このような無機材料は、必要な防火性能に応じて適宜加えればよぐ勿論、添加しな くてもよいことはいうまでもない。  [0078] In the present embodiment, it is preferable that the dummy material is impregnated with a flame retardant containing an inorganic material that becomes a molten state and fixes a carbonized residue when burned together with such a flame retardant. . Such an inorganic material melts when a fire occurs or the like, and becomes, for example, a glassy state, and acts to mutually fix carbonized residues generated by carbonizing the noncombustible material 103. Therefore, if the inorganic material is impregnated into the wood together with the flame retardant, the carbonized residues are fixed to each other by the inorganic material, and the carbonized residues can be prevented from collapsing. Examples of such an inorganic material include those in which the alkalinity of water glass is reduced by 70% to 80%. It is needless to say that such an inorganic material may be added as appropriate according to the required fire prevention performance, and need not be added.

[0079] また、本実施形態では、ダミー材に燃焼遅延剤を含浸したが、これに限定されず、 例えば、ダミー材の代わりに化粧板に燃焼遅延剤を含浸してもよぐ勿論、両方に含 浸させてもよい。  Further, in this embodiment, the dummy material is impregnated with the combustion retardant. However, the present invention is not limited to this. For example, the decorative plate may be impregnated with the combustion retardant instead of the dummy material. May be impregnated.

[0080] (実施形態 3)  (Embodiment 3)

図 7は、本発明の実施形態 3に係る木製防火扉の要部拡大断面図である。なお、 本実施形態では、上述した図 1一図 4で説明した同一部分には同一符号を付して重 複する説明は省略する。  FIG. 7 is an enlarged sectional view of a main part of a wooden fire door according to Embodiment 3 of the present invention. Note that, in the present embodiment, the same portions as those described with reference to FIGS. 1 to 4 are denoted by the same reference numerals, and redundant description will be omitted.

[0081] 図 7に示すように、本実施形態の各木製防火扉 10Bは、燃焼遅延部材 100をダミ ー材に燃焼遅延剤を含浸した不燃材 103と化粧板 30との間に設けた。そして、燃焼 遅延部材 100Aを芯材 20と不燃材 103との間に設けた以外は上述した実施形態 2と 同様である。 As shown in FIG. 7, in each of the wooden fire doors 10 B of the present embodiment, the combustion delay member 100 is provided between the non-combustible material 103 in which the combustion retardant is impregnated in the dummy material and the decorative board 30. And burning Embodiment 2 is the same as Embodiment 2 except that the delay member 100A is provided between the core member 20 and the non-combustible member 103.

[0082] このような構成の木製防火扉 10Bとしても、燃焼遅延部材 100、 100A、及び不燃 材 103のそれぞれが火や熱を長時間に亘つてトラップするので、上述した実施形態 1 と同様に、非常に優れた防火性能を発揮する。  [0082] Also in the wooden fire door 10B having such a configuration, each of the combustion delay members 100, 100A, and the non-combustible material 103 traps fire and heat for a long time, and thus is similar to the first embodiment described above. Demonstrate very good fire protection performance.

[0083] (実施形態 4)  (Embodiment 4)

図 8は、本発明の実施形態 4に係る木製防火扉の要部拡大断面図である。なお、 本実施形態では、上述した図 1一図 4で説明した同一部分には同一符号を付して重 複する説明は省略する。  FIG. 8 is an enlarged sectional view of a main part of a wooden fire door according to Embodiment 4 of the present invention. Note that, in the present embodiment, the same portions as those described with reference to FIGS. 1 to 4 are denoted by the same reference numerals, and redundant description will be omitted.

[0084] 図 8 (a)に示すように、天然木集成材 60を 3層クロス張りした補強部材 25Cと各桐部 材 21— 23を 3層クロス張りした桐積層材 24Cとからなる芯材 20Cを用いた木製防火 扉 10Cとした以外は上述した実施形態 1と同様である。また、桐積層板 24Cと補強部 材 25Cとは、両者の接合部分に設けられた凹凸部 70を介して相互に嵌合している。 これにより、十分な接合強度が得られ、扉強度を高めることができる。  [0084] As shown in Fig. 8 (a), a core member composed of a reinforcing member 25C in which three layers of natural wood laminated timber 60 are cross-bonded and a paulownia laminated material 24C in which three layers of each paulownia member 21-23 are cross-stretched. It is the same as Embodiment 1 described above, except that a wooden fire door 10C using 20C is used. Further, the paulownia laminate 24C and the reinforcing member 25C are fitted to each other via a concave-convex portion 70 provided at a joint portion between the two. Thereby, sufficient joining strength is obtained and door strength can be increased.

[0085] さらに、図 8 (b)に示すように、各天然木集成材 60を耐火接着剤層 102によって接 着した構造の補強部材 25Dを用いた木製防火扉 10Dとしてもよい。また、この木製 防火扉 10Dでは、さらに、補強部材 25Dと桐積層材 24Dとを耐火接着剤層 102によ つて接着し、芯材 20Dを構成する各桐部材 21— 23を相互に耐火接着剤層 102によ つて接着している。これにより、非常に優れた防火性能を得ることができる。  [0085] Further, as shown in Fig. 8 (b), a wooden fire door 10D using a reinforcing member 25D having a structure in which each natural wood laminated wood 60 is bonded by a fire-resistant adhesive layer 102 may be used. Further, in the wooden fire door 10D, the reinforcing member 25D and the paulownia laminated material 24D are further adhered to each other by the refractory adhesive layer 102, and the respective paulownia members 21-23 constituting the core material 20D are mutually bonded with the refractory adhesive. Adhered by layer 102. Thereby, very excellent fire prevention performance can be obtained.

[0086] 勿論、本実施形態の木製防火扉 IOC, 10Dの扉構造に、上述した実施形態 1及び 2の構造を採用してもよいことは言うまでもない。  [0086] Of course, it goes without saying that the structure of Embodiments 1 and 2 described above may be adopted for the door structure of the wooden fire doors IOC, 10D of the present embodiment.

[0087] ここで、本発明に係る木製防火扉の防火性能に関して、以下の実施例を例に挙げ て、さらに詳細に説明する。  [0087] Here, the fire prevention performance of the wooden fire door according to the present invention will be described in more detail with reference to the following examples.

実施例 1  Example 1

[0088] まず、桐集成材を 3層クロス張りした桐積層材の上下左右の端面に、合成合板から なる補強部材を接合し、厚さ 35mm、 900mm X 2200mmの芯材とした。  First, a reinforcing member made of synthetic plywood was joined to the upper, lower, left and right end surfaces of a paulownia laminated material in which three layers of paulownia laminated wood were cross-bonded to form a core material having a thickness of 35 mm and 900 mm × 2200 mm.

[0089] 次に、厚さ 0. 13mmの和紙を 3枚用意し、芯材の一方面上にシロキサンとシラノー ノレ塩とからなる無機材料を含有する耐火接着剤を約 200g/m2塗布して耐火接着剤 層を形成し、その上から和紙を貼った後、同様の作業を二回繰り返すことにより、 3枚 の和紙のそれぞれを耐火接着剤層によって接着した。次に、この上に厚さ 5. 0— 5. 5mmの杉材にホウ酸を含む燃焼遅延剤の有効成分を 5g/水 100gを含浸させた不 燃材を耐火接着剤を介して接着した。そして、同様に、芯材の反対側にも、 3枚の和 紙を耐火接着剤層によって接着し、この上力 不燃材を耐火接着剤層によって接着 した後、全体をプレス接着した。なお、耐火接着剤としては、水性造膜性無機化合物 「リキッドセラミック(LC)シリカ系」(商品名;コーミックス (株)製)を用いた。 Next, three pieces of Japanese paper having a thickness of 0.13 mm were prepared, and about 200 g / m 2 of a fire-resistant adhesive containing an inorganic material composed of siloxane and silanol salt was applied to one surface of the core material. Refractory adhesive After a layer was formed and Japanese paper was pasted thereon, the same operation was repeated twice, so that each of the three Japanese papers was bonded with the fire-resistant adhesive layer. Next, a non-combustible material obtained by impregnating a 5.0-5.5 mm thick cedar wood with an effective component of a fire retardant containing boric acid at 5 g / 100 g of water was bonded thereto through a fire-resistant adhesive. . Similarly, on the opposite side of the core material, three pieces of Japanese paper were bonded with a fire-resistant adhesive layer, and the non-combustible material was bonded with a fire-resistant adhesive layer, and then the whole was press-bonded. As the refractory adhesive, an aqueous film-forming inorganic compound “Liquid Ceramic (LC) silica-based” (trade name; manufactured by Comix Corp.) was used.

[0090] 次いで、両面側の各不燃材上に耐火接着剤層をそれぞれ形成した後、この耐火接 着剤層上に 夂の和紙をそれぞれ貼り、この和紙の上にさらに耐火接着剤層をそれ ぞれ形成した。その後、この上に、厚さ 2. 7mm、 900mm X 2200mmの化粧板を接 合した後、これら芯材、化粧板、不燃材、及び燃焼遅延部材を相互にプレス接着し、 これを実施例 1の木製防火扉とした。  [0090] Next, after a fire-resistant adhesive layer was formed on each of the non-combustible materials on both sides, respectively, a Japanese paper was attached on the fire-resistant adhesive layer, and a further fire-resistant adhesive layer was further formed on the Japanese paper. Each formed. Thereafter, a decorative plate having a thickness of 2.7 mm and a size of 900 mm x 2200 mm was bonded thereon, and then the core material, the decorative plate, the non-combustible material, and the combustion delay member were press-bonded to each other. Wooden fire door.

[0091] (試験例)  [0091] (Test example)

実施例 1の木製防火扉の一方面側から平均約 900°Cの炎で炙って、 60分の燃焼 試験を行い、木製防火扉の防火性能を評価した。なお、燃焼試験は、 ISO基準に基 づく「特定防火設備」の国土交通大臣認定試験である。  The wooden fire door of Example 1 was burned with a flame of about 900 ° C. on average from one side, and a combustion test was performed for 60 minutes to evaluate the fire protection performance of the wooden fire door. The combustion test is a certification test by the Minister of Land, Infrastructure, Transport and Tourism based on “specified fire prevention equipment” based on ISO standards.

[0092] その結果、実施例 1の木製防火扉は、扉の一方面側から約 900°Cの炎で 60分間 炙っても、燃焼深度は約 15mm、すなわち、芯材は 3/4以上残っており、非常に優 れた防火性能が得られることが分かった。また、扉の炎で炙った面側からその反対面 に伝わる輻射熱の温度は、約 40°C程度であった。これは、燃焼遅延剤が不燃材の 炭化残渣を固定するように作用すると共に、耐火接着剤層が無機発泡体となり、火 や熱を長時間遮断できたためと考えられる。  [0092] As a result, even if the wooden fire door of Example 1 was burned from one side of the door with a flame of about 900 ° C for 60 minutes, the burning depth was about 15 mm, that is, 3/4 or more of the core remained. It was found that excellent fire protection performance was obtained. The temperature of the radiant heat transmitted from the side of the door flamed to the opposite side was about 40 ° C. This is probably because the flame retardant acts to fix the carbonized residue of the non-combustible material, and the refractory adhesive layer becomes an inorganic foam, which can block fire and heat for a long time.

[0093] このこと力、ら、芯材と化粧板との間に燃焼遅延部材を介在させることで、非常に優れ た防火性能が得られることが分かった。そして、実施例 1の木製防火扉は、 ISO基準 に基づく平均約 900°Cの燃焼試験において 60分の防火性能が得られ、実際に、「特 定防火設備」の国土交通大臣認定取得のテストに合格することができた。  [0093] It was found that by interposing a combustion delay member between the core material and the decorative plate, extremely excellent fire protection performance was obtained. In addition, the wooden fire door of Example 1 achieved a fire protection performance of 60 minutes in an average 900 ° C combustion test based on ISO standards. Was able to pass.

[0094] また、実施例 1の木製防火扉は、 900°C/60分の燃焼試験において、芯材はその まま残っていたことから、 60分以上の防火性能が得られているのは明らかである。 なお、不燃材とィ匕粧板との間の燃焼遅延部材を除いても、または不燃材を設けず に化粧板を燃焼遅延部材上に直接プレス接着したとしても、同様に、 900°C/60分 の防火性能が得られることは明らかである。また、燃焼遅延部材を防火性能を付与す べき一方側のみに設けて木製防火扉としても、同様に、 900°C/60分の防火性能が 得られることは言うまでもない。 [0094] Further, in the wooden fire door of Example 1, the core material remained as it was in the combustion test at 900 ° C / 60 minutes, so that it is clear that the fire protection performance of 60 minutes or more was obtained. It is. In addition, even if the burn retarding member between the incombustible material and the decorative board is removed, or even if the decorative board is directly press-bonded onto the burn retarding member without providing the incombustible material, similarly, 900 ° C / It is clear that a fire protection performance of 60 minutes can be obtained. Also, it is needless to say that the fire retarding performance of 900 ° C / 60 minutes can be similarly obtained by providing the fire retarding member only on one side to which the fire preventing performance is to be provided as a wooden fire door.

Claims

請求の範囲 The scope of the claims [1] 木製の芯材と、表面に設けられた化粧板とを有する木製防火扉において、  [1] In a wooden fire door having a wooden core and a decorative plate provided on the surface, 前記芯材と前記化粧板との間には、両面に耐火接着剤層を有する少なくとも 1枚の 紙力 なる燃焼遅延部材が設けられていることを特徴とする木製防火扉。  A wooden fire door, wherein at least one sheet-like combustion delay member having a fire-resistant adhesive layer on both surfaces is provided between the core material and the decorative board. [2] 請求の範囲 1において、前記燃焼遅延部材は、 2枚以上の和紙と当該和紙のそれ ぞれの間及び両面に設けられた前記耐火接着剤層とからなることを特徴とする木製 防火扉。  [2] The wooden fire prevention device according to claim 1, wherein the combustion delay member comprises two or more Japanese papers and the refractory adhesive layers provided between and on both sides of the Japanese paper. door. [3] 請求の範囲 1又は 2において、前記燃焼遅延部材は、その両面に接合される板材 の間にプレス接着されていることを特徴とする木製防火扉。  [3] The wooden fire door according to claim 1 or 2, wherein the combustion delay member is press-bonded between plate members joined to both surfaces thereof. [4] 請求の範囲 1一 3の何れかにおいて、前記燃焼遅延部材は、前記芯材と木材に燃 焼遅延剤を含浸した不燃材との間に設けられ、且つ前記不燃材の前記芯材側とは 反対側の面上には前記化粧板が接合されていることを特徴とする木製防火扉。 [4] In any one of claims 1-3, the combustion retarding member is provided between the core material and a non-combustible material obtained by impregnating a wood with a flame retardant, and the core material of the non-combustible material is provided. A wooden fire door, wherein the decorative panel is joined to a surface on a side opposite to the side. [5] 請求の範囲 4において、前記燃焼遅延部材は、前記不燃材と前記化粧板との間に も設けられていることを特徴とする木製防火扉。 [5] The wooden fire door according to claim 4, wherein the combustion delay member is also provided between the incombustible material and the decorative board. [6] 請求の範囲 4において、前記燃焼遅延部材は、前記不燃材と前記化粧板との間に も設けられていることを特徴とする木製防火扉。 6. The wooden fire door according to claim 4, wherein the combustion delay member is also provided between the incombustible material and the decorative board. [7] 請求の範囲 4において、前記燃焼遅延剤には、ポリリン酸アンモニゥム及びホウ酸 の少なくとも何れか一方を含む防炎薬剤が含有されていることを特徴とする木製防火 扉。 7. The wooden fire door according to claim 4, wherein the flame retardant contains a flame retardant containing at least one of ammonium polyphosphate and boric acid. [8] 請求の範囲 7において、前記燃焼遅延剤には、燃焼時に溶融状態となって炭化残 渣を固定する無機材料が含有されていることを特徴とする木製防火扉。  [8] The wooden fire door according to claim 7, wherein the combustion retardant contains an inorganic material which is in a molten state during combustion to fix a carbonized residue. [9] 請求の範囲 8において、前記無機材料が、ケィ酸塩、ホウケィ酸塩、ホウ酸塩及び シリカから選択される少なくとも一種からなることを特徴とする木製防火扉。 9. The wooden fire door according to claim 8, wherein the inorganic material is made of at least one selected from the group consisting of a silicate, a borosilicate, a borate, and silica. [10] 請求の範囲 1一 9の何れかにおいて、前記化粧板が、木製前記燃焼遅延剤が含浸 された木製合板であることを特徴とする木製防火扉。  [10] The wooden fire door according to any one of items [11] to [9], wherein the decorative board is a wooden plywood impregnated with a wooden flame retardant. [11] 請求の範囲 1一 10の何れかにおいて、前記芯材が、桐材を主体とするものであるこ とを特徴とする木製防火扉。  [11] The wooden fire door according to any one of claims 110, wherein the core material is mainly made of paulownia material. [12] 請求の範囲 1一 11の何れかにおいて、前記芯材が、桐集成材の積層板であること を特徴とする木製防火扉。 [12] In any one of claims 1-11, the core material is a laminated board of paulownia laminated wood A wooden fire door characterized by the following. [13] 請求の範囲 12において、前記芯材が、前記桐集成材の 3層クロス張りの積層板で あることを特徴とする木製防火扉。  13. The wooden fire door according to claim 12, wherein the core material is a three-layer cloth-clad laminate of the paulownia laminated wood. [14] 請求の範囲 1一 13の何れかにおいて、前記扉の端面近傍には、グラフアイト系発泡 材がその長手方向に亘つて設けられていることを特徴とする木製防火扉。 [14] The wooden fire door according to any one of claims 113, wherein a graphite foam material is provided in the vicinity of an end face of the door in a longitudinal direction thereof.
PCT/JP2004/008192 2003-06-11 2004-06-11 Wooden fire door Ceased WO2004111376A1 (en)

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JP2006233681A (en) * 2005-02-28 2006-09-07 Itochu Kenzai Corp Core material, wooden fire door, and manufacturing method of the door
JP2009041199A (en) * 2007-08-06 2009-02-26 Ookuma:Kk Refractory building materials, manufacturing methods thereof, and refractory doors
JP5290024B2 (en) * 2009-03-31 2013-09-18 清水建設株式会社 Wooden parts
KR101311828B1 (en) 2012-07-10 2013-09-25 (주)다마텍 엔지니어링 Fire wall

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JPH0353901A (en) * 1989-07-24 1991-03-07 Shizuoka Pref Gov Mokuzai Kyodo Kumiai Rengokai Manufacture of wooden fireproofing door
JPH07259445A (en) * 1994-03-25 1995-10-09 Aica Kogyo Co Ltd Wooden fire door
JPH07293127A (en) * 1994-04-20 1995-11-07 Tateshina Seisakusho:Kk Wooden fire door
JP2958740B2 (en) * 1994-05-31 1999-10-06 株式会社ノナカ Fire door
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JP2001294645A (en) * 2000-02-22 2001-10-23 Hilti Ag Binary in-situ foaming system and method for using the same for closing opening with foam for flameproofing

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