[go: up one dir, main page]

WO2003031380A1 - Procede de production de methanol et dispositif associe - Google Patents

Procede de production de methanol et dispositif associe Download PDF

Info

Publication number
WO2003031380A1
WO2003031380A1 PCT/RU2001/000421 RU0100421W WO03031380A1 WO 2003031380 A1 WO2003031380 A1 WO 2003031380A1 RU 0100421 W RU0100421 W RU 0100421W WO 03031380 A1 WO03031380 A1 WO 03031380A1
Authority
WO
WIPO (PCT)
Prior art keywords
gas
mixture
ρeaκtsiοnnοy
meτanοla
metal
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/RU2001/000421
Other languages
English (en)
Russian (ru)
Inventor
Vladimir Sergeevich Arutyunov
Valerii Mihailovich Rudakov
Valerii Ivanovich Savchenko
Evgenii Victorovich Sheverdenkin
Andrei Yurievich Zheltyakov
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Publication of WO2003031380A1 publication Critical patent/WO2003031380A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
    • C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/48—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups
    • C07C29/50—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by oxidation reactions with formation of hydroxy groups with molecular oxygen only
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals

Definitions

  • the inventive invention is not available in the area of urban chemistry, and the name is given to the technology of the use of methane gas directly from the use of gas (gas).
  • Natural gas for the most part, is the main hydrocarbon source for energy and chemical industry of the 21st century.
  • ⁇ dna ⁇ eg ⁇ is ⁇ lz ⁇ vanie vyzyvae ⁇ ⁇ yad se ⁇ ezny ⁇ ⁇ blem, svyazanny ⁇ with ⁇ ans- ⁇ i ⁇ v ⁇ y gaz ⁇ b ⁇ azn ⁇ g ⁇ sy ⁇ ya on g ⁇ madnye ⁇ ass ⁇ yaniya and ⁇ az ⁇ ab ⁇ y ⁇ en ⁇ abelny ⁇ ⁇ tsess ⁇ v ⁇ lucheniya of neg ⁇ zhid ⁇ i ⁇ m ⁇ ny ⁇ ⁇ liv and d ⁇ ugi ⁇ ⁇ imiches ⁇ i ⁇ ⁇ du ⁇ v.
  • Modern gas chemistry is not capable of seriously commercially operating with existing non-chemical processes. The formation of a highly efficient process of converting a gas into a metal would result in a higher concentration of harmful gases in the process of converting a non-reactive
  • a known method does not ensure the necessary speed of removal of the heat of reaction, which leads to the need to reduce the degree of loss of carbohydrate gas. Otherwise, even the use of an oxidizing agent as a fuel does not result in an efficient recycling of gas due to an increase in the consumption of gas. With this, a significant part of the supplied acid is consumed by the oxidation of C ⁇ in C0 2 , resulting in a further decrease in the degree of the use of carbon dioxide. In addition, an additional large amount of carbohydrate-containing gas is necessary to burn for the treatment of the process of re-energizing.
  • ⁇ aya s ⁇ de ⁇ zhi ⁇ is ⁇ chni ⁇ uglev ⁇ d ⁇ ds ⁇ de ⁇ zhascheg ⁇ gas ⁇ m ⁇ ess ⁇ and ⁇ d ⁇ g ⁇ eva ⁇ el for szha ⁇ iya and nag ⁇ eva gas is ⁇ chni ⁇ ⁇ i- sl ⁇ ds ⁇ de ⁇ zhascheg ⁇ gas ⁇ m ⁇ ess ⁇ m
  • P ⁇ s ⁇ avlennaya task ⁇ eshae ⁇ sya ⁇ em, ch ⁇ in s ⁇ s ⁇ be ⁇ izv ⁇ ds ⁇ va me ⁇ an ⁇ la, v ⁇ lyuchayuschem ⁇ azdelnuyu ⁇ dachu ⁇ sled ⁇ va ⁇ eln ⁇ szha ⁇ g ⁇ and nag ⁇ e ⁇ g ⁇ uglev ⁇ d ⁇ ds ⁇ de ⁇ zhascheg ⁇ szha ⁇ g ⁇ ⁇ isl ⁇ ds ⁇ de ⁇ zhascheg ⁇ gas and gas in smesi ⁇ elnye z ⁇ ny ⁇ sled ⁇ va ⁇ eln ⁇ ⁇ as ⁇ l ⁇ zhenny ⁇ ⁇ ea ⁇ v, ⁇ sleduyuschee gaz ⁇ azn ⁇ e ⁇ islenie uglev ⁇ d ⁇ ds ⁇ de ⁇ zhascheg ⁇ gas in ⁇ sled ⁇ va ⁇ eln ⁇ ⁇ as ⁇ l ⁇ zhenny ⁇
  • Gaseous oxidation of carbohydrate-containing gas is a viable means of continuous use due to the fact that it is not subject to continuous degree of ⁇ - settling of the reaction mixture; regulate the parameters of the selected steam;
  • the reactive mixture is pre-separated by separation to separate the pressure of the gas network of the exhaust gas user; Oxidation of carbohydrates burning gas at an initial temperature of 380-480 ° C, a pressure of 3 - 8 ⁇ Pa and oxygen concentration in the processing zones of 1, 5 - 6%; from ⁇ exhaust gases give off ⁇ and / or ⁇ 2 and purified exhaust gases go to the source hydrocarbon-supporting gas, and separated ⁇ and / or ⁇ 2 are used for treating the products.
  • P ⁇ s ⁇ avlennaya task ⁇ eshae ⁇ sya ⁇ a ⁇ zhe ⁇ em, ch ⁇ in us ⁇ an ⁇ v ⁇ e for ⁇ - izv ⁇ ds ⁇ va me ⁇ an ⁇ la, s ⁇ de ⁇ zhaschey is ⁇ chni ⁇ uglev ⁇ d ⁇ ds ⁇ de ⁇ zhascheg ⁇ gas ⁇ m ⁇ ess ⁇ m for eg ⁇ szha ⁇ iya, is ⁇ chni ⁇ gas ⁇ isl ⁇ ds ⁇ de ⁇ zhascheg ⁇ with ⁇ m ⁇ ess ⁇ m for eg ⁇ szha ⁇ iya, ⁇ sled ⁇ va ⁇ eln ⁇ us ⁇ an ⁇ vlennye ⁇ ea ⁇ y, ⁇ azhdy of ⁇ y ⁇ s ⁇ de ⁇ zhi ⁇ ⁇ sled ⁇ va ⁇ eln ⁇ che ⁇ eduyuschiesya smesi ⁇ el- nye and ⁇ ea ⁇
  • the internal transfer of the pipe to the reactive zone is made up of a material that is inert to the external mixture of the reaction mixture; us ⁇ an ⁇ v ⁇ a m ⁇ zhe ⁇ s ⁇ de ⁇ zha ⁇ d ⁇ v ⁇ smi ⁇ - sled ⁇ va ⁇ eln ⁇ ⁇ as ⁇ l ⁇ zhenny ⁇ ⁇ ea ⁇ tsi ⁇ nny ⁇ z ⁇ n ⁇ barter ⁇ ⁇ ey me ⁇ e in ⁇ d- n ⁇ m ⁇ ea ⁇ e with ⁇ ub ⁇ v ⁇ dami for ⁇ dachi ⁇ du ⁇ v ⁇ ea ⁇ tsii of ⁇ edy- duscheg ⁇ ⁇ ea ⁇ a in ⁇ e ⁇ vuyu smesi ⁇ elnuyu z ⁇ nu ⁇ sleduyuscheg ⁇ ⁇ ea ⁇ a.
  • the installation may also contain devices for regulating the parameters of the steam; and before using the appliance, it may be possible to install a satisfactory cooling device for a complete cooling of the reactive mixtures pre-separation and separation from it of liquid products. Consequently, the unit can be equipped with a separation unit for ⁇ and / or ⁇ 2 , a connected outlet for the gas of the gas supply of the unit P ⁇ edl ⁇ zhenny s ⁇ s ⁇ b and us ⁇ an ⁇ v ⁇ a s ⁇ sem ⁇ m ⁇ e ⁇ la che ⁇ ez s ⁇ en ⁇ u v ⁇ dyanym ⁇ ndensa ⁇ m ne ⁇ s ⁇ eds ⁇ venn ⁇ in ⁇ ea ⁇ tsi ⁇ nn ⁇ y z ⁇ ne with ⁇ b ⁇ az ⁇ vani- it ⁇ a ⁇ a pressure above 6 a ⁇ m ⁇ bes ⁇ echivayu ⁇ ⁇ vedenie s ⁇ adiyn ⁇ g ⁇ ⁇ tsessa ⁇ isleniya ⁇ a ⁇ i
  • P ⁇ mim ⁇ ne ⁇ b ⁇ dim ⁇ s ⁇ i increase ⁇ as ⁇ d ⁇ v on ⁇ izv ⁇ ds ⁇ v ⁇ d ⁇ g ⁇ s ⁇ yascheg ⁇ ⁇ i- sl ⁇ da, e ⁇ ⁇ iv ⁇ di ⁇ ⁇ bezv ⁇ zv ⁇ a ⁇ n ⁇ y ⁇ e ⁇ e is ⁇ dn ⁇ g ⁇ uglev ⁇ d ⁇ dn ⁇ g ⁇ sy ⁇ ya and d ⁇ lni ⁇ eln ⁇ mu ⁇ az ⁇ g ⁇ evu ⁇ ea ⁇ tsi ⁇ nn ⁇ y mixture ch ⁇ usl ⁇ zhnyae ⁇ ⁇ blemu detachably ⁇ e ⁇ la.
  • P ⁇ edlagae maya us ⁇ an ⁇ v ⁇ a with ⁇ eguli ⁇ uemym sem ⁇ m ⁇ e ⁇ la v ⁇ dyanym ⁇ ndensa ⁇ m ne ⁇ s ⁇ eds ⁇ venn ⁇ in ⁇ de ⁇ ea ⁇ tsii ⁇ bes ⁇ echivae ⁇ v ⁇ zm ⁇ zhn ⁇ s ⁇ ⁇ n ⁇ li ⁇ uem ⁇ g ⁇ ⁇ vaziiz ⁇ e ⁇ miches ⁇ g ⁇ ⁇ vedeniya ⁇ tsessa ⁇ isleniya in nes ⁇ l ⁇ i ⁇ ⁇ sled ⁇ va ⁇ eln ⁇ ⁇ as ⁇ l ⁇ zhenny ⁇ ⁇ ea ⁇ tsi ⁇ nny ⁇ z ⁇ na ⁇ without ⁇ - mezhu ⁇ chn ⁇ g ⁇ ⁇ ln ⁇ g ⁇ ⁇ lazhdeniya ⁇ ea ⁇ tsi ⁇ nn ⁇ y mixture and isolating zhid ⁇ i ⁇ ⁇ du
  • Best va ⁇ ian ⁇ ⁇ susches ⁇ vleniya iz ⁇ b ⁇ e ⁇ eniya Us ⁇ an ⁇ v ⁇ a s ⁇ de ⁇ zhi ⁇ is ⁇ chni ⁇ 1 ( ⁇ ig.1) uglev ⁇ d ⁇ ds ⁇ de ⁇ zhascheg ⁇ gas ⁇ m ⁇ ess ⁇ m 2, 3 is ⁇ chni ⁇ ⁇ isl ⁇ ds ⁇ de ⁇ zhascheg ⁇ gas ⁇ m ⁇ ess ⁇ m 4 d ⁇ v ⁇ smi ⁇ sled ⁇ va ⁇ eln ⁇ ⁇ as ⁇ l ⁇ zhenny ⁇ ⁇ ea ⁇ v 5 ⁇ - Aug.
  • main zone 1 and also pipe 16 for the supply of a gas-liquid reactive mixture in a refrigeration condenser 17.
  • ⁇ l ⁇ dny su ⁇ y ⁇ i ⁇ dny gas (s ⁇ de ⁇ zhanie me ⁇ ana 98%) of 1 is ⁇ ch- ni ⁇ a ⁇ as ⁇ d ⁇ m 49049 ⁇ g / h szhimayu ⁇ in ⁇ m ⁇ ess ⁇ e 2 d ⁇ 5.8 ⁇ a, ⁇ dayu ⁇ che ⁇ ez ⁇ e ⁇ u ⁇ e ⁇ a ⁇ ivny ⁇ e ⁇ l ⁇ bmenni ⁇ ⁇ ⁇ ub ⁇ v ⁇ dam 14 15 6 mixtures- ⁇ elnuyu z ⁇ nu 7 ⁇ ⁇ e ⁇ v ⁇ g ⁇ ⁇ ea ⁇ a 5 ⁇ , at the same time, the outlet 8 releases air from the compressor 4 with a discharge of 8777 kg / h and a pressure of 6 ⁇ a.
  • the reaction zone 9 ⁇ of the reaction 5 ⁇ is produced by a gas-different oxidation of natural gas at an initial temperature of 450 ° C, a pressure of 5.8 ° C, at a pressure of 5.8 bar.
  • the reactive mixture is discharged into the mixing zone 7 2 of the following process 5 2 , when the process 8 is in the same way as the process is discharged.
  • Liquid products from the appliance 18 are supplied to the unit 20 and are discharged to the unit 21 and further to the recycling unit 22 and the metal and the food are disposed of 23. At the same time, there is a separation of an aqueous solution of maldehyde in the presence of 24 for further processing in the minerals.
  • the flue gases from the separating unit 18 are supplied to the user 26 for burning to the consumer (EC).
  • EXAMPLE 2 Solid dry gas (methane content 98%) from source 1 with a consumption of 4775 kg / h mixed with a cleaned, non-combustible thirteen
  • Resistive heat exchanger 14 for pipes 15, 6 in the mixing zone 7 ⁇ of the transformer 5 ⁇ is supplied with acid from the compressor 4 with a discharge of 2483 kg / h and an outlet pressure of 8 ⁇ .
  • Liquid products from the unit 18 are supplied to the unit 20 and are discharged to the unit 21 and further to the recycling department at the 22nd part with the separation of the metal and the food product. At the same time, there is a separation of an aqueous process of the preparation of maldehyde of 24 for further processing in the process of cooking.
  • the flue gases from the 18th unit are supplied with 26 exhaust gas to unit 25 of the copper-ammonia purifier, where the discharge of C ⁇ and C ⁇ 2 is carried out, which leads to the discharge of water.
  • ⁇ chischenny uglev ⁇ d ⁇ ds ⁇ de ⁇ - containing gas ⁇ ⁇ ub ⁇ v ⁇ du 27 v ⁇ zv ⁇ aschayu ⁇ in is ⁇ chni ⁇ P ⁇ ime ⁇ 1. 3.
  • the reactive mixture is discharged to the next mixing zone 7 2 , the same as the reaction, when it is 8, in the same way there is no acid.
  • Gid ⁇ i ⁇ vanie vydelenn ⁇ g ⁇ ⁇ sida ugle ⁇ da, sele ⁇ ivn ⁇ s ⁇ ⁇ b ⁇ az ⁇ vaniya ⁇ g ⁇ ⁇ is ⁇ dn ⁇ mu ugle ⁇ du d ⁇ s ⁇ igae ⁇ 50%, from ⁇ b ⁇ az ⁇ vaniem d ⁇ lni- ⁇ eln ⁇ g ⁇ ⁇ liches ⁇ va me ⁇ an ⁇ la ⁇ zv ⁇ lyae ⁇ ⁇ ch ⁇ i vdv ⁇ e ⁇ vysi ⁇ vy ⁇ d me ⁇ an ⁇ la in ⁇ asche ⁇ e on iz ⁇ as ⁇ d ⁇ vann ⁇ e uglev ⁇ d ⁇ dn ⁇ e sy ⁇ e.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Furnace Details (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

L'invention concerne un procédé de production de méthanol consistant à acheminer séparément un gaz successivement comprimé et réchauffé contenant des hydrocarbures et un gaz comprimé contenant de l'oxygène vers des zones de mélange (71-78) de réacteurs (51-58) disposés à la suite; à soumettre le gaz contenant des hydrocarbures à une oxydation en phase gazeuse dans les zones de réaction (91-98) des réacteurs (51-58) disposées à la suite, à une température initiale allant jusqu'à 500 °C, à une pression allant jusqu'à 10 MPa et à une teneur en oxygène inférieure à 8 % en volume dans les zones de réaction (91-98) ; à refroidir le mélange de réaction à travers la paroi de la zone de réaction précédente (91-97), avant de l'acheminer vers les zones de réaction suivantes (92-98), au moyen d'un condensat aqueux et par la production de vapeur; puis à refroidir ce mélange de réaction après la dernière zone de réaction (98) du dernier réacteur (58), avant la séparation, dans un échangeur thermique de récupération (14) et dans un condenseur réfrigérant à air (17). Le procédé selon l'invention consiste enfin à réaliser la séparation du mélange liquide-gaz de réaction refroidi en gaz d'échappement et en produits liquides; à rectifier ces produits liquides par extraction de méthanol pendant l'acheminement de la vapeur obtenue par le refroidissement des produits de réaction; et à acheminer les gaz d'échappement vers le gaz de départ contenant des hydrocarbures ou vers la combustion.
PCT/RU2001/000421 2001-10-10 2001-10-17 Procede de production de methanol et dispositif associe Ceased WO2003031380A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2001127294/04A RU2200731C1 (ru) 2001-10-10 2001-10-10 Способ производства метанола и установка для его осуществления
RU2001127294 2001-10-10

Publications (1)

Publication Number Publication Date
WO2003031380A1 true WO2003031380A1 (fr) 2003-04-17

Family

ID=20253624

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/RU2001/000421 Ceased WO2003031380A1 (fr) 2001-10-10 2001-10-17 Procede de production de methanol et dispositif associe

Country Status (2)

Country Link
RU (1) RU2200731C1 (fr)
WO (1) WO2003031380A1 (fr)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7161048B2 (en) 2005-05-20 2007-01-09 Rinnovi, L.L.C. Method for deriving methanol from waste generated methane and structured product formulated therefrom
US7456327B2 (en) 2004-07-29 2008-11-25 Gas Technologies, Llc Method for direct-oxygenation of alkane gases
US7578981B2 (en) 2004-07-29 2009-08-25 Gas Technologies Llc System for direct-oxygenation of alkane gases
US7642293B2 (en) 2004-07-29 2010-01-05 Gas Technologies Llc Method and apparatus for producing methanol with hydrocarbon recycling
US8193254B2 (en) 2005-12-27 2012-06-05 Gas Technologies Llc Method and system for methanol production
US8524175B2 (en) 2005-12-27 2013-09-03 Gas Technologies Llc Tandem reactor system having an injectively-mixed backmixing reaction chamber, tubular-reactor, and axially movable interface
US9180426B2 (en) 2004-07-29 2015-11-10 Gas Technologies, Llc Scrubber for methanol production system

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US8202916B2 (en) 2004-07-29 2012-06-19 Gas Technologies Llc Method of and apparatus for producing methanol
US8293186B2 (en) 2004-07-29 2012-10-23 Gas Technologies Llc Method and apparatus for producing methanol
US7179843B2 (en) 2004-07-29 2007-02-20 Gas Technologies Llc Method of and apparatus for producing methanol
RU2282612C1 (ru) * 2005-06-23 2006-08-27 Общество с ограниченной ответственностью "Метанол технолоджи" Способ получения жидких оксигенатов путем конверсии природного газа и установка для его осуществления
US7687669B2 (en) 2005-12-27 2010-03-30 Gas Technologies Llc Method for direct-oxygenation of alkane gases
RU2433863C1 (ru) * 2010-04-14 2011-11-20 Андрей Юрьевич Беляев Реактор для осуществления газофазных каталитических процессов
SG11201504353UA (en) 2012-12-22 2015-07-30 Gas Tech Llc Method and apparatus for providing oxygenated hydrocarbons
RU2568113C1 (ru) * 2015-02-09 2015-11-10 Алексей Михайлович Шкода Способ производства метанола и установка для его осуществления

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2006757A (en) * 1977-09-24 1979-05-10 Huels Chemische Werke Ag Process for the manufacture of formaldehyde and methanol by partial oxidation of methane
US4618732A (en) * 1985-05-20 1986-10-21 Gesser Hyman D Direct conversion of natural gas to methanol by controlled oxidation
US4982023A (en) * 1989-10-16 1991-01-01 Mobil Oil Corporation Oxidation of methane to methanol
RU2162460C1 (ru) * 2000-06-06 2001-01-27 Арутюнов Владимир Сергеевич Способ производства метанола и установка для производства метанола

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2006757A (en) * 1977-09-24 1979-05-10 Huels Chemische Werke Ag Process for the manufacture of formaldehyde and methanol by partial oxidation of methane
US4618732A (en) * 1985-05-20 1986-10-21 Gesser Hyman D Direct conversion of natural gas to methanol by controlled oxidation
US4982023A (en) * 1989-10-16 1991-01-01 Mobil Oil Corporation Oxidation of methane to methanol
RU2162460C1 (ru) * 2000-06-06 2001-01-27 Арутюнов Владимир Сергеевич Способ производства метанола и установка для производства метанола

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
ARTJUNOV V.S. ET AL.: "Proizvodstvo toplivnykh spirtovykh smesei i motornykh topliv iz uglevodorodnykh gazov", KHIMICHESKAYA PROMYSHLENNOST, no. 11, 1993, pages 543 - 546 *

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7456327B2 (en) 2004-07-29 2008-11-25 Gas Technologies, Llc Method for direct-oxygenation of alkane gases
US7578981B2 (en) 2004-07-29 2009-08-25 Gas Technologies Llc System for direct-oxygenation of alkane gases
US7642293B2 (en) 2004-07-29 2010-01-05 Gas Technologies Llc Method and apparatus for producing methanol with hydrocarbon recycling
US9180426B2 (en) 2004-07-29 2015-11-10 Gas Technologies, Llc Scrubber for methanol production system
US7161048B2 (en) 2005-05-20 2007-01-09 Rinnovi, L.L.C. Method for deriving methanol from waste generated methane and structured product formulated therefrom
US8193254B2 (en) 2005-12-27 2012-06-05 Gas Technologies Llc Method and system for methanol production
US8524175B2 (en) 2005-12-27 2013-09-03 Gas Technologies Llc Tandem reactor system having an injectively-mixed backmixing reaction chamber, tubular-reactor, and axially movable interface
US10287224B2 (en) 2005-12-27 2019-05-14 Gas Technologies Llc Method and apparatus for producing methanol with hydrocarbon recycling

Also Published As

Publication number Publication date
RU2200731C1 (ru) 2003-03-20

Similar Documents

Publication Publication Date Title
WO2003031380A1 (fr) Procede de production de methanol et dispositif associe
US2660032A (en) Gas turbine cycle employing secondary fuel as a coolant
RU2162460C1 (ru) Способ производства метанола и установка для производства метанола
PL144284B1 (en) Method of and apparatus for manufacture of ammonia
CN85101024B (zh) 氨合成气的生产方法和装置
JP2020532540A (ja) 二酸化炭素を使用するエタンの酸化脱水素
RU2203261C1 (ru) Способ получения метанола и установка для его осуществления
CN112209351A (zh) 一种焦化脱硫废液制硫酸的方法
US7179843B2 (en) Method of and apparatus for producing methanol
US8202916B2 (en) Method of and apparatus for producing methanol
US4235800A (en) Synthesis gas
US11772971B2 (en) Nitric acid production process and plant with oxygen supply unit
JP7715797B2 (ja) 反応炉アセンブリ、硫黄含有廃棄物処理システム、硫黄含有廃棄物の燃焼方法、及び硫黄含有廃棄物再生による硫酸製造方法
JPS61219702A (ja) メタノ−ルのリホ−ミング法及びその装置
WO1988000580A1 (fr) Procede d'obtention de methanol
US4081511A (en) Process for removing nitric oxides from processing exhaust gases
RU2539656C1 (ru) Способ получения жидких углеводородов из углеводородного газа и установка для его осуществления
CN115920784B (zh) 一种dmo生产系统和开停车方法
RU2415703C2 (ru) Способ термического окисления шахтного метана и установка для его осуществления
RU2434841C2 (ru) Способ обработки и извлечения энергии отработанного газа реакции окисления
RU2022927C1 (ru) Способ производства аммиака
CN214087722U (zh) 一种焦化脱硫废液制硫酸的系统
RU97111823A (ru) Способ прямого восстановления содержащего оксид железа материала в форме частиц и установка для осуществления этого способа
RU2134147C1 (ru) Способ переработки природного газа с получением пара и метанола
RU2282612C1 (ru) Способ получения жидких оксигенатов путем конверсии природного газа и установка для его осуществления

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BY BZ CA CH CN CO CR CU CZ DE DM DZ EE ES FI GB GD GE GH GM HU ID IL IN IS JP KE KG KP KR KZ LK LR LS LT LU LV MA MD MG MK MW MX MZ NO NZ PL PT RO RU SD SG SI SK SL TJ TM TR TT TZ UA UG UZ VN YU ZA

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW MZ SD SL SZ UG ZW AM AZ BY KG KZ MD TJ TM AT BE CH CY DE DK ES FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GQ GW MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: JP