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WO2003016415A1 - Procede de transformation de matieres brutes hydrocarbonees - Google Patents

Procede de transformation de matieres brutes hydrocarbonees Download PDF

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Publication number
WO2003016415A1
WO2003016415A1 PCT/RU2002/000129 RU0200129W WO03016415A1 WO 2003016415 A1 WO2003016415 A1 WO 2003016415A1 RU 0200129 W RU0200129 W RU 0200129W WO 03016415 A1 WO03016415 A1 WO 03016415A1
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WIPO (PCT)
Prior art keywords
chτο
ποτοκ
ποdayuτ
πiροliza
προduκτοv
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Ceased
Application number
PCT/RU2002/000129
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English (en)
Russian (ru)
Inventor
Boris Tikhonovich Plachenov
Viktor Nikolaevich Lebedev
Vladimir Afanasievich Pinchuk
Anatoly Anatolievich Barunin
Toomas Ernstovich Kekhva
Valerian Vigdorovich Krasnik
Valery Timofeevich Shevchuk
Kirill Nikolaevich Akhapkin
Yuri Nikolaevich Filimonov
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Individual
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Publication of WO2003016415A1 publication Critical patent/WO2003016415A1/fr
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Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G9/00—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils
    • C10G9/28—Thermal non-catalytic cracking, in the absence of hydrogen, of hydrocarbon oils with preheated moving solid material

Definitions

  • the process of processing hydrocarbon raw materials is known, in particular, fuel oil, heavy fuel oil and other fractions of heavy hydrocarbon raw materials.
  • the process runs with a frequency of 500-1500 cycles per minute.
  • fuel oil As a raw material used, fuel oil is used, with a sulfur content of 2.0–4.0%, with a density of 970 kg / m and a temperature of start of incubation of 330 ° ⁇ .
  • the benefit of the indicated net- work results in the output at the output of the following products (%): ethylene - 34; ⁇ ylene - 13; butadiene - 4; ⁇ i ⁇ ndensat - 8; heavy tar - 22.
  • the method of obtaining olefins is also known by means of a high rate of conversion of hydrocarbons to the US Patent ⁇ ° 4 256 565, class. On 10/9/36, 03/17/1981, taken as a result of the closest analogue (simple) we declare the method. According to this analogue, olefins with a high yield are obtained from hydrocarbon raw materials, especially from heavy non-ferrous fractions.
  • the angle of the gas supply from the front of the reaction zone and the supply of hydrocarbons to the rear is 45 ° C.
  • the high-temperature carrier generates a gas generator and transmits a high-temperature vapor to the hydrocarbon
  • hot fuels are used in the use of fuel gases.
  • an oxidizing agent is used in the quality of the oxidizer.
  • the process of utilization is carried out in the range of pressures from 0.3 to 5.0 ⁇ Pa to change the composition of the generator, as well as to regulate the supply of the product.
  • the aftertreatment is introduced into the after-tem- perature components and the mixture is cooled to a temperature of 500–100. 5
  • the exhaust chamber in the reactor has an additional flow of water to increase the yield of exhaust gases and hydrogen emissions.
  • ⁇ ⁇ i ⁇ lizn ⁇ y ⁇ ame ⁇ e in ⁇ ea ⁇ tsi ⁇ nny ⁇ d ⁇ lni ⁇ eln ⁇ m ⁇ gu ⁇ ⁇ - dava ⁇ v ⁇ dyan ⁇ y ⁇ a ⁇ to change ⁇ a ⁇ tsialn ⁇ g ⁇ uglev ⁇ d ⁇ d ⁇ v pressure for gene ⁇ atsii v ⁇ d ⁇ da and ⁇ vysheniya vy ⁇ da ⁇ le ⁇ in ⁇ v and ⁇ a ⁇ zhe for ⁇ eguli- ⁇ vaniya s ⁇ s ⁇ ava ⁇ du ⁇ v ⁇ i ⁇ liza.
  • ⁇ ⁇ i ⁇ lizn ⁇ y ⁇ ame ⁇ e in ⁇ ea ⁇ tsi ⁇ nny ⁇ d ⁇ lni ⁇ eln ⁇ m ⁇ gu ⁇ ⁇ - dava ⁇ ⁇ sid ugle ⁇ da to pressure changes ⁇ a ⁇ tsialn ⁇ g ⁇ uglev ⁇ d ⁇ d ⁇ v, gene ⁇ atsii v ⁇ d ⁇ da in ⁇ ea ⁇ tsii ⁇ a ⁇ v ⁇ y ⁇ nve ⁇ sii and ⁇ a ⁇ zhe for ⁇ eguli ⁇ va- Nia s ⁇ s ⁇ ava ⁇ du ⁇ v ⁇ i ⁇ liza.
  • ⁇ ⁇ i ⁇ lizn ⁇ y ⁇ ame ⁇ e in ⁇ ea ⁇ tsi ⁇ nny ⁇ d ⁇ lni ⁇ eln ⁇ m ⁇ gu ⁇ ⁇ - dava ⁇ di ⁇ sid ugle ⁇ da to pressure changes ⁇ a ⁇ tsialn ⁇ g ⁇ uglev ⁇ d ⁇ - d ⁇ v, gene ⁇ atsii v ⁇ d ⁇ da and ⁇ sida ugle ⁇ da in ⁇ ea ⁇ tsii ugle ⁇ isl ⁇ n ⁇ y ⁇ nve ⁇ - these and ⁇ a ⁇ zhe for ⁇ eguli ⁇ vaniya s ⁇ s ⁇ ava ⁇ du ⁇ v ⁇ i ⁇ liza.
  • the water can be supplied.
  • Pi ⁇ liznaya ⁇ ame ⁇ a 3 s ⁇ s ⁇ i ⁇ of dvu ⁇ ⁇ ea ⁇ tsi ⁇ nny ⁇ z ⁇ n: ⁇ e ⁇ v ⁇ y z ⁇ ny ⁇ ea ⁇ tsy (Z ⁇ - 1) 7 and the second reaction zone (W-2) 8, ne ⁇ - s ⁇ eds ⁇ venn ⁇ ⁇ imy ⁇ ayu ⁇ d ⁇ ug ⁇ d ⁇ ugu and ⁇ azdeleny ⁇ yasami 9, 10 for introducing v ⁇ ys ⁇ a za ⁇ al ⁇ chny ⁇ , che ⁇ ez ⁇ yas 9 v ⁇ ys ⁇ a and d ⁇ lni ⁇ elny ⁇ , che ⁇ ez ⁇ yas 10 v ⁇ ys ⁇ a ⁇ m ⁇ nen ⁇ v.
  • Sending a reactive feed is quicker, equal to 10 5 -10 6 deg / s.
  • a change in the primary process and the regulation of the structure of the target products are carried out by the addition of additional components after the 10th knot.
  • Original processed raw materials optional and hardened ⁇ m ⁇ nen ⁇ y ⁇ dg ⁇ avlivayu ⁇ in bl ⁇ e 15 ⁇ dg ⁇ v ⁇ i (BP) and in ⁇ dayu ⁇ ⁇ i ⁇ - liznu ⁇ ame ⁇ u 3 che ⁇ ez ⁇ yasa 11,10 and 12, 9 and 13 v ⁇ ys ⁇ a, s ⁇ ve ⁇ s ⁇ venn ⁇ , ⁇ - ⁇ ye ⁇ eds ⁇ avlyayu ⁇ s ⁇ b ⁇ y ⁇ yad ⁇ sun ⁇ (on s ⁇ eme not ⁇ azany) ⁇ as ⁇ l ⁇ - zhenny ⁇ ⁇ ⁇ e ⁇ ime ⁇ u P ⁇ 3.
  • BP 15 ⁇ izv ⁇ dya ⁇ ⁇ edva ⁇ i ⁇ elny nag ⁇ ev is ⁇ dn ⁇ g ⁇ uglev ⁇ d ⁇ dn ⁇ g ⁇ sy ⁇ ya above ⁇ ch ⁇ i ⁇ lavleniya, n ⁇ below ⁇ em ⁇ e ⁇ a- ⁇ u ⁇ y ⁇ s ⁇ - or sm ⁇ l ⁇ b ⁇ az ⁇ vaniya and ⁇ a ⁇ zhe ⁇ bes ⁇ echivayu ⁇ d ⁇ zi ⁇ vannuyu ⁇ - giving sy ⁇ ya, and d ⁇ lni ⁇ elny ⁇ za ⁇ al ⁇ chny ⁇ ⁇ m ⁇ nen ⁇ v, che ⁇ ez s ⁇ ve ⁇ s ⁇ - vuyuschie ⁇ yasa v ⁇ ys ⁇ a.
  • Table 1 Physicochemicals and, in fact, historical sources of raw materials.
  • ⁇ gas generator 2 produces fuels burning in an oxidizer with a co-oxidizing agent excess of 0.95-0.7 and a gas by-product of 2000 ° C.
  • natural or discharged gas, process gases, processed raw materials may be used.
  • the process of processing in a near-chamber 3 is controlled at a pressure of 0.5-1 ⁇ Pa.
  • the resulting gas and steam supply is supplied to ⁇ -2 8, where it is mixed with additional processable raw materials supplied after 10 times.
  • the temperature is maintained equal to 1000–900 ° ⁇ , and in the end of ⁇ -2 8, 700–600 ° ⁇ .
  • the resulting reacted mixture is quenched after siphon 13 of the processed raw material and is supplied to the siphon 14.
  • ⁇ gas generator 2 produces combustion of fuels in an oxidizer with a ko-coefficient of excess of an oxidizing agent of 1.05-0.95 with a gas treatment of 2500 bypasses.
  • natural or discharged gas, process gases, processed raw materials may be used.
  • the process of processing in a practical chamber 3 is at a pressure of 0.3-1.0 ⁇ Pa.
  • the gases produced in the gas generator 2 are supplied through a quick blower 6 in Z ⁇ -1 7, where they are mixed with vapors supplied to the gas inlet for 11 minutes.
  • ⁇ of the starting part of ⁇ -1 7 temperature support is equal eleven
  • Received gas and gas supply are supplied to ⁇ -2 8, where they are mixed with additional processed materials and supplied to them.
  • the temperature is maintained equal to 600 ° ⁇ , and in the end of ⁇ -2 8 - 200 ° ⁇ .
  • the resulting reactive mixture is delivered to block 14 of the separation.
  • Original raw materials, optional and hardened components are supplied in unit 15.
  • ⁇ gas generator 2 produces combustion of fuels in an oxidizer with a ko- coefficient of excess of an oxidizer of 1.05-1.20 with a gas treatment of a gas outlet of 2300 ° C. 12
  • either natural or discharged gas, recirculation gases or processed raw materials may be used.
  • the process of processing in an ideal chamber 3 is at a pressure of about 5.0 psi. A good working pressure is caused by pressure that is not necessary for the further processing of the resulting synthesis gas.
  • the gases produced in the gas generator 2 are supplied through a critical burner 6 to W-1 7, where they are mixed with the raw materials supplied to the same zone through the 11-12 discharge zone. In the initial part of ⁇ -1, the temperature is maintained at 2000–1800 ° ⁇ , and in the end, it is 1400–1500 ° ⁇ .
  • the resulting gas and gas stream is fed into Z-2 8, where it is mixed with the water supplied through belt 9.
  • the temperature is maintained equal to 800 ° ⁇ , and in the end of ⁇ -2, 8,200 ° ⁇ .
  • the gas-fired gas boiler which contains soot and carbon dioxide, is delivered in block 14 of the separation.
  • Original raw materials, optional and hardened components are supplied in unit 15.
  • ⁇ gas generator 2 produces fuels burning in an oxidizer with a co-oxidizing agent excess of 0.95-0.7 and a gas by-product of 2000 ° C.
  • natural or discharged gas, process gases, processed raw materials may be used.
  • the process of processing in a near-chamber 3 is subjected to pressure up to 5.0 PSa in order to increase the yield of liquid hydrocarbons.
  • Received gases are supplied through a critical unit 6 in Z ⁇ -1 7, 14 where i ⁇ smeshivayu ⁇ with ⁇ a ⁇ m, ⁇ davaemym in ⁇ u same z ⁇ nu che ⁇ ez ⁇ yas 12 v ⁇ ys ⁇ a and ⁇ e ⁇ e ⁇ aba ⁇ yvaemym sy ⁇ em ⁇ davaemym che ⁇ ez ⁇ yas 11 v ⁇ ys ⁇ a, ⁇ i e ⁇ m ⁇ v ⁇ dya ⁇ ⁇ a ⁇ -ugle ⁇ isl ⁇ nuyu ⁇ nve ⁇ siyu sy ⁇ ya with ⁇ b ⁇ az ⁇ vaniem v ⁇ d ⁇ da and ⁇ sida ugle ⁇ da and ⁇ lazhdayu ⁇ d ⁇ ⁇ em ⁇ e ⁇ a ⁇ u ⁇ y ⁇ avn ⁇ y 1150-1200 ° C .
  • the resulting gas and gas stream is sent to W-2 8, where it is mixed with the processed raw materials supplied through the course of 10 times.
  • the temperature is maintained equal to 1000–800 ° ⁇ , and in the end of ⁇ -2 8, 700–600 ° ⁇ .
  • the obtained products are charged with water that is supplied through the belt 13 and sent to unit 14 for the separation of fuel carbohydrates.
  • Original raw materials, optional and custom-made components are prepared in block 15 of the preparation.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Electric Connection Of Electric Components To Printed Circuits (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)

Abstract

L'invention concerne un procédé de transformation de matières brutes hydrocarbonées, notamment de résidus pétroliers lourds, contenant des fractions dont le point d'ébullition est supérieur à 350°C. Le procédé selon l'invention consiste à produire un fluide caloporteur haute température par la combustion d'un combustible dans de l'oxygène; à chauffer préalablement les matières brutes hydrocarbonées à une température supérieure au point de fusion mais inférieure à la température de cokéfaction ou de résinification; à acheminer simultanément le fluide caloporteur haute température et les matières brutes hydrocarbonées préalablement chauffées dans la zone de réaction d'une chambre à pyrolyse, puis à effectuer un traitement par trempe des produits de réaction, le chauffage des matières brutes hydrocarbonées à une température comprise entre 700 et 2500 °C dans la zone de réaction s'effectuant à une vitesse égale à (4-5) x 105 degrés/seconde. La présente invention trouve des applications dans l'industrie de la transformation des produits pétroliers. Le procédé selon l'invention permet d'augmenter les possibilités de transformation des matières brutes et d'élargir le champ des produits ciblés obtenus, tels que les gaz de synthèse, les hydrocarbures légers utilisés comme combustibles, le coke, la suie, et d'augmenter le rendement de ces produits.
PCT/RU2002/000129 2001-08-13 2002-03-28 Procede de transformation de matieres brutes hydrocarbonees Ceased WO2003016415A1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
RU2001123175 2001-08-13
RU2001123175A RU2188846C1 (ru) 2001-08-13 2001-08-13 Способ переработки углеводородного сырья

Publications (1)

Publication Number Publication Date
WO2003016415A1 true WO2003016415A1 (fr) 2003-02-27

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PCT/RU2002/000129 Ceased WO2003016415A1 (fr) 2001-08-13 2002-03-28 Procede de transformation de matieres brutes hydrocarbonees

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WO (1) WO2003016415A1 (fr)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005073346A1 (fr) * 2004-02-02 2005-08-11 Boris Nikolaevich Ulko Procede et installation destines a un traitement haute temperature de residus de petrole lourd
US8871173B2 (en) 2010-02-19 2014-10-28 Cabot Corporation Method for carbon black production using preheated feedstock and apparatus for same

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2325426C2 (ru) * 2006-02-01 2008-05-27 ООО "Компания по освоению новых технологий в топливно-энергетическом комплексе "КОНТТЭК" Способ переработки углеводородного сырья
RU2330058C1 (ru) * 2006-12-06 2008-07-27 Михаил Сергеевич Неупокоев Способ переработки попутных нефтяных газов
RU2347801C1 (ru) * 2007-10-22 2009-02-27 Талгат Магсумович Магсумов Установка для пиролиза углеводородного сырья
SE534818C2 (sv) * 2010-05-06 2012-01-10 Cortus Ab Förfarande och anordning för införande av pulverformigt material i en förgasningsreaktor, varvid anordningen innefattar en lavaldysa
RU2545378C1 (ru) * 2013-11-12 2015-03-27 ОБЩЕСТВО С ОГРАНИЧЕННОЙ ОТВЕТСТВЕННОСТЬЮ "Научно-производственная компания Кедр-89" Устройство для осуществления термодеструктивных процессов переработки тяжелых нефтяных остатков
RU2731213C1 (ru) * 2019-11-26 2020-08-31 Общество с ограниченной ответственностью "ЭНЕРДЖИ ЭНД ИНЖИНИРИНГ" Способ переработки попутных нефтяных газов в жидкие продукты

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4142963A (en) * 1977-06-07 1979-03-06 Union Carbide Corporation Penetration enhanced fluid mixing method for thermal hydrocarbon cracking
US4256565A (en) * 1979-11-13 1981-03-17 Rockwell International Corporation Method of producing olefins from hydrocarbons
SU1320221A1 (ru) * 1985-01-29 1987-06-30 Ярославское научно-производственное объединение "Техуглерод" Способ получени ароматических углеводородов

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2743046A1 (de) * 1977-09-24 1979-04-05 Gewerk Eisenhuette Westfalia Vortriebsschild fuer das auffahren von tunnels, stollen o.dgl.
JPS6011584A (ja) * 1983-06-30 1985-01-21 Mitsubishi Heavy Ind Ltd 炭化水素から石油化学製品を選択的に製造するための熱分解法
RU2145626C1 (ru) * 1999-04-26 2000-02-20 Зао "Тк Сибур Нн" Способ переработки углеводородного сырья

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4142963A (en) * 1977-06-07 1979-03-06 Union Carbide Corporation Penetration enhanced fluid mixing method for thermal hydrocarbon cracking
US4256565A (en) * 1979-11-13 1981-03-17 Rockwell International Corporation Method of producing olefins from hydrocarbons
SU1320221A1 (ru) * 1985-01-29 1987-06-30 Ярославское научно-производственное объединение "Техуглерод" Способ получени ароматических углеводородов

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2005073346A1 (fr) * 2004-02-02 2005-08-11 Boris Nikolaevich Ulko Procede et installation destines a un traitement haute temperature de residus de petrole lourd
US8871173B2 (en) 2010-02-19 2014-10-28 Cabot Corporation Method for carbon black production using preheated feedstock and apparatus for same
US9574087B2 (en) 2010-02-19 2017-02-21 Cabot Corporation Method for carbon black production using preheated feedstock and apparatus for same

Also Published As

Publication number Publication date
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