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WO2003014166A1 - Procede de fabrication de polymeres - Google Patents

Procede de fabrication de polymeres Download PDF

Info

Publication number
WO2003014166A1
WO2003014166A1 PCT/JP2002/008023 JP0208023W WO03014166A1 WO 2003014166 A1 WO2003014166 A1 WO 2003014166A1 JP 0208023 W JP0208023 W JP 0208023W WO 03014166 A1 WO03014166 A1 WO 03014166A1
Authority
WO
WIPO (PCT)
Prior art keywords
transition metal
catalytic activity
promoter
polymer
represented
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/JP2002/008023
Other languages
English (en)
French (fr)
Inventor
Toru Arai
Shingo Hanazato
Masataka Nakajima
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Denka Co Ltd
Original Assignee
Denki Kagaku Kogyo KK
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Denki Kagaku Kogyo KK filed Critical Denki Kagaku Kogyo KK
Priority to US10/486,242 priority Critical patent/US7214745B2/en
Priority to JP2003519115A priority patent/JP3964867B2/ja
Priority to EP02755857A priority patent/EP1428840A4/en
Publication of WO2003014166A1 publication Critical patent/WO2003014166A1/ja
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2420/00—Metallocene catalysts
    • C08F2420/08—Heteroatom bridge, i.e. Cp or analog where the bridging atom linking the two Cps or analogs is a heteroatom different from Si
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10S—TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10S526/00—Synthetic resins or natural rubbers -- part of the class 520 series
    • Y10S526/943—Polymerization with metallocene catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
PCT/JP2002/008023 2001-08-07 2002-08-06 Procede de fabrication de polymeres Ceased WO2003014166A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
US10/486,242 US7214745B2 (en) 2001-08-07 2002-08-06 Process for producing polymer
JP2003519115A JP3964867B2 (ja) 2001-08-07 2002-08-06 重合体の製造方法
EP02755857A EP1428840A4 (en) 2001-08-07 2002-08-06 POLYMER PRODUCTION PROCESS

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
JP2001-238803 2001-08-07
JP2001238803 2001-08-07
JP2002-78048 2002-03-20
JP2002078048 2002-03-20

Publications (1)

Publication Number Publication Date
WO2003014166A1 true WO2003014166A1 (fr) 2003-02-20

Family

ID=26620071

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/JP2002/008023 Ceased WO2003014166A1 (fr) 2001-08-07 2002-08-06 Procede de fabrication de polymeres

Country Status (4)

Country Link
US (1) US7214745B2 (ja)
EP (1) EP1428840A4 (ja)
JP (1) JP3964867B2 (ja)
WO (1) WO2003014166A1 (ja)

Families Citing this family (24)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7541402B2 (en) 2002-10-15 2009-06-02 Exxonmobil Chemical Patents Inc. Blend functionalized polyolefin adhesive
US7700707B2 (en) 2002-10-15 2010-04-20 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US7550528B2 (en) 2002-10-15 2009-06-23 Exxonmobil Chemical Patents Inc. Functionalized olefin polymers
US7524910B2 (en) 2002-10-15 2009-04-28 Exxonmobil Chemical Patents Inc. Polyolefin adhesive compositions and articles made therefrom
US8722831B2 (en) * 2006-05-29 2014-05-13 Denki Kagaku Kogyo Kabushiki Kaisha Process for production of cross copolymers, cross copolymers obtained by the process, and use thereof
CN102007180A (zh) 2008-04-15 2011-04-06 电气化学工业株式会社 热塑性树脂组合物
US8664461B2 (en) * 2012-03-19 2014-03-04 Exxonmobil Chemical Patents Inc. Catalysts for producing polyalpha-olefins and processes related thereto
US10005858B2 (en) * 2014-09-10 2018-06-26 Sabic Global Technologies B.V. Boron-bridged 2-indenyl metallocene complexes for olefin polymerization
US9796795B2 (en) 2015-01-14 2017-10-24 Exxonmobil Chemical Patents Inc. Tetrahydroindacenyl catalyst composition, catalyst system, and processes for use thereof
WO2016171808A1 (en) 2015-04-20 2016-10-27 Exxonmobil Chemical Patents Inc. Catalyst composition comprising fluorided support and processes for use thereof
US10640583B2 (en) 2015-04-20 2020-05-05 Exxonmobil Chemical Patents, Inc. Catalyst composition comprising fluorided support and processes for use thereof
US9803037B1 (en) 2016-05-03 2017-10-31 Exxonmobil Chemical Patents Inc. Tetrahydro-as-indacenyl catalyst composition, catalyst system, and processes for use thereof
US10968290B2 (en) 2017-03-28 2021-04-06 Exxonmobil Chemical Patents Inc. Metallocene-catalyzed polyalpha-olefins
US10703838B2 (en) 2017-10-31 2020-07-07 Exxonmobil Chemical Patents Inc. Mixed catalyst systems with four metallocenes on a single support
US11021553B2 (en) 2018-02-12 2021-06-01 Exxonmobil Chemical Patents Inc. Metallocene dimer selective catalysts and processes to produce poly alpha-olefin dimers
US11084894B2 (en) 2018-02-12 2021-08-10 Exxonmobil Chemical Patents Inc. Catalyst systems and processes for poly alpha-olefin having high vinylidene content
US11078308B2 (en) 2018-02-12 2021-08-03 Exxonmobil Chemical Patents Inc. Processes to produce poly alpha-olefin trimers
EP3853191B1 (en) 2018-09-17 2025-10-15 ExxonMobil Chemical Patents Inc. Processes to produce poly alpha-olefin trimer and apparatus therefor
GB201820099D0 (en) * 2018-12-10 2019-01-23 Scg Chemicals Co Ltd Catalytic compounds
WO2021030045A1 (en) 2019-08-09 2021-02-18 Exxonmobil Chemical Patents Inc. Process to produce low viscosity polyalphaolefins using non-aromatic-hydrocarbon soluble activators
CN114845980A (zh) 2019-10-28 2022-08-02 埃克森美孚化学专利公司 二聚物选择性金属茂催化剂、非芳族烃可溶性活化剂和用其制备聚α-烯烃低聚物的方法
KR102710665B1 (ko) * 2019-12-12 2024-09-25 주식회사 엘지화학 폴리올레핀
EP4110834B1 (en) 2020-02-24 2024-04-03 ExxonMobil Chemical Patents Inc. Ansa-bis(inden-2-yl) catalysts for producing vinylidene-terminated polyalphaolefins
EP4143276A1 (en) 2020-04-29 2023-03-08 ExxonMobil Chemical Patents Inc. Poly alpha-olefin compositions and processes to produce poly alpha-olefins

Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0222307A (ja) * 1988-07-12 1990-01-25 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびオレフィンの重合方法
EP0381184A2 (en) * 1989-01-31 1990-08-08 AUSIMONT S.r.l. Catalysts for the polymerization of olefins
JPH0762012A (ja) * 1993-08-25 1995-03-07 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびこれを用いるオレフィンの重合方法
EP0676471A2 (en) * 1994-03-08 1995-10-11 American Home Products Corporation Effector proteins of rapamycin
JPH09176219A (ja) * 1995-12-27 1997-07-08 Sumitomo Chem Co Ltd オレフィン重合用触媒、及びオレフィン重合体の製造方法
US5962718A (en) * 1995-10-25 1999-10-05 Studiengesellschaft Kohle Mbh Zirconocenes and hafnocenes with boron-substituted cyclopentadienyl-ligands and the method of producing them
US5985784A (en) * 1992-01-27 1999-11-16 Targor Gmbh Catalyst and process for the polymerization and copolymerization of olefins

Family Cites Families (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3808268A1 (de) 1988-03-12 1989-09-21 Hoechst Ag Verfahren zur herstellung eines 1-olefinpolymers
US5932669A (en) * 1991-11-30 1999-08-03 Targor Gmbh Metallocenes having benzo-fused indenyl derivatives as ligands, processes for their preparation and their use as catalysts
US5910464A (en) * 1992-06-18 1999-06-08 Montell Technology Company Bv Catalysts for the polymerization of olefins
DE69426043T3 (de) * 1993-06-07 2015-06-18 Mitsui Chemicals, Inc. Polypropylen
DE69534784T2 (de) 1994-04-07 2006-08-03 Innovene Europe Ltd., Staines Polymerisationsverfahren und so erhaltene Polyolefine
IT1269837B (it) * 1994-05-26 1997-04-15 Spherilene Srl Componenti e catalizzatori per la polimerizzazione delle olefine
IT1273661B (it) 1994-07-20 1997-07-09 Spherilene Srl Catalizzatori per la polimerizzazione delle olefine
CA2183650C (en) * 1994-12-20 2006-01-03 Toshiyuki Tsutsui Process for preparing ethylene polymer and ethylene polymer
DE69617371T2 (de) * 1995-06-08 2002-08-08 Showa Denko K.K., Tokio/Tokyo Ionische Verbindungen und Katalysator für die Olefinpolymerisation, der die Verbindungen verwendet
DE19711339B4 (de) 1996-03-19 2008-09-11 Denki Kagaku Kogyo K.K. Copolymer aus Ethylen und aromatischer Vinylverbindung, Verfahren zu dessen Herstellung, Formkörper daraus sowie Zusammensetzung umfassend das Copolymer
JP3181920B2 (ja) * 1996-04-22 2001-07-03 日本ポリオレフィン株式会社 ポリオレフィン製造用触媒及びポリオレフィンの製造方法
DE19622207A1 (de) * 1996-06-03 1997-12-04 Hoechst Ag Chemische Verbindung
US6329479B1 (en) 1997-04-17 2001-12-11 Denki Kagaku Kogyo Kabushiki Kaisha Transition metal compound as catalyst component for polymerization, aromatic vinyl compound-olefin copolymer having stereoregularity and method for its preparation by means of the transition metal compound as catalyst component
US6235855B1 (en) 1997-04-17 2001-05-22 Denki Kagaku Kogyo Kabushiki Kaisha Transition metal compound as catalyst component in method for producing aromatic vinyl compound polymer or aromatic vinyl compound-olefin copolymer having stereoregularity
US6489424B2 (en) 1997-04-17 2002-12-03 Denki Kagaku Kogyo Kabushiki Kaisha Transition metal catalyst component for polymerization, aromatic vinyl compound polymer having stereoregularity and method for its preparation by means of the catalyst component
DE69839662D1 (de) 1997-10-01 2008-08-14 Denki Kagaku Kogyo Kk Folie und Folie zum Spannverpacken
AU1688199A (en) * 1997-12-25 1999-07-19 Denki Kagaku Kogyo Kabushiki Kaisha Polymerization catalyst and process for producing olefin polymer or copolymer with the same
EP1062957A4 (en) 1998-03-09 2009-04-29 Denki Kagaku Kogyo Kk MEDICAL MATERIAL AND NEED FOR MEDICAL USE
US6410649B1 (en) 1998-03-23 2002-06-25 Denki Kagaku Kogyo Kabushiki Kaisha Resin composition
ATE248849T1 (de) * 1998-10-08 2003-09-15 Dow Chemical Co Verbrückte metallkomplexe
US6410673B1 (en) 1998-10-19 2002-06-25 Denki Kagaku Kogyo Kabushiki Kaisha Ethylene/aromatic vinyl copolymer and molded product thereof
CN1331706A (zh) 1998-12-22 2002-01-16 电气化学工业株式会社 交联共聚合化的烯烃/苯乙烯/二烯共聚物、其制备方法及其用途
JP4726371B2 (ja) 1999-09-13 2011-07-20 電気化学工業株式会社 クロス共重合化オレフィン−芳香族ビニル化合物−ジエン共重合体の製造方法
US6891004B2 (en) * 2000-03-14 2005-05-10 Denki Kagaku Kogyo Kabushiki Kaisha Transition metal catalyst component for polymerization, and method for producing a polymer by means thereof
WO2001068719A1 (en) 2000-03-14 2001-09-20 Denki Kagaku Kogyo Kabushiki Kaisha Transition metal catalyst component for polymerization and process for producing polymer with the same

Patent Citations (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0222307A (ja) * 1988-07-12 1990-01-25 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびオレフィンの重合方法
EP0381184A2 (en) * 1989-01-31 1990-08-08 AUSIMONT S.r.l. Catalysts for the polymerization of olefins
US5985784A (en) * 1992-01-27 1999-11-16 Targor Gmbh Catalyst and process for the polymerization and copolymerization of olefins
JPH0762012A (ja) * 1993-08-25 1995-03-07 Mitsui Petrochem Ind Ltd オレフィン重合用触媒およびこれを用いるオレフィンの重合方法
EP0676471A2 (en) * 1994-03-08 1995-10-11 American Home Products Corporation Effector proteins of rapamycin
US5962718A (en) * 1995-10-25 1999-10-05 Studiengesellschaft Kohle Mbh Zirconocenes and hafnocenes with boron-substituted cyclopentadienyl-ligands and the method of producing them
JPH09176219A (ja) * 1995-12-27 1997-07-08 Sumitomo Chem Co Ltd オレフィン重合用触媒、及びオレフィン重合体の製造方法

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See also references of EP1428840A4 *

Also Published As

Publication number Publication date
US7214745B2 (en) 2007-05-08
EP1428840A4 (en) 2005-04-06
EP1428840A1 (en) 2004-06-16
JP3964867B2 (ja) 2007-08-22
US20050176901A1 (en) 2005-08-11
JPWO2003014166A1 (ja) 2004-11-25

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