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WO2003040279A1 - Polymeres pour applications de blanchissage - Google Patents

Polymeres pour applications de blanchissage Download PDF

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Publication number
WO2003040279A1
WO2003040279A1 PCT/EP2002/010586 EP0210586W WO03040279A1 WO 2003040279 A1 WO2003040279 A1 WO 2003040279A1 EP 0210586 W EP0210586 W EP 0210586W WO 03040279 A1 WO03040279 A1 WO 03040279A1
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Prior art keywords
alkyl
group
groups
use according
polymer
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PCT/EP2002/010586
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English (en)
Inventor
Susanne Henning Rogers
Michael Stephen White
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hindustan Unilever Ltd
Unilever NV
Original Assignee
Hindustan Lever Ltd
Unilever NV
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Application filed by Hindustan Lever Ltd, Unilever NV filed Critical Hindustan Lever Ltd
Priority to BRPI0213709-7A priority Critical patent/BR0213709B1/pt
Priority to ES02774634.6T priority patent/ES2675289T3/es
Priority to EP02774634.6A priority patent/EP1442109B1/fr
Publication of WO2003040279A1 publication Critical patent/WO2003040279A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/226—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin esterified
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/0005—Other compounding ingredients characterised by their effect
    • C11D3/0036—Soil deposition preventing compositions; Antiredeposition agents
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/225—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin etherified, e.g. CMC
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/20—Organic compounds containing oxygen
    • C11D3/22—Carbohydrates or derivatives thereof
    • C11D3/222—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
    • C11D3/228—Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin with phosphorus- or sulfur-containing groups

Definitions

  • the present invention relates to substituted polysaccharides which are used in laundry cleaning products, for instance, for incorporation in products for dosing in the wash and/or rinse. These polymers are intended for, but not limited to, soil release benefits in such products.
  • soil release polymer is used in the art to cover polymeric materials which assist release of soil from fabrics, e.g. cotton or polyester based fabrics. For example, it is used in relation to polymers which assist release of soil direct from fibres. It is also used to refer to polymers which modify the fibres so that dirt adheres to the polymer-modified fibres rather than to the fibre material itself. Then, when the fabric is washed the next time, the dirt is more easily removed than if it was adhering the fibres. Although not wishing to be bound by any particular theory or explanation, the inventors believe that the soil release polymers utilised in the present invention probably exert their effect mainly by the latter mechanism. The compounds utilised by the present invention have been found, dependent upon the structure of the compound in question, to deliver a soil release, fabric care and/or other laundry cleaning benefit .
  • a benefit agent onto a substrate such as a fabric
  • a substrate such as a fabric
  • typical "benefit agents” include fabric softeners and conditioners, soil release polymers, sunscreens; and the like.
  • Deposition of a benefit agent is used, for example, in fabric treatment processes such as fabric softening to impart desirable properties to the fabric substrate.
  • the deposition of the benefit agent has had to rely upon the attractive forces between the oppositely charged substrate and the benefit agent.
  • this requires the addition of benefit agents during the rinsing step of a treatment process so as to avoid adverse effects from other charged chemical species present in the treatment compositions.
  • cationic fabric conditioners are incompatible with anionic surfactants in laundry washing compositions .
  • Such adverse charge considerations can place severe limitations upon the inclusion of benefit agents in compositions where an active component thereof is of an opposite charge to that of the benefit agent.
  • cotton is negatively charged and thus requires a positively charged benefit agent in order for the benefit agent to be substantive to the cotton, i.e. to have an affinity for the cotton so as to absorb onto it.
  • the substantivity of the benefit agent is reduced and/or the deposition rate of the material is reduced because of the presence of incompatible charged species in the compositions.
  • the compounds used by the present invention for soil-release and/or other benefits are substituted polysaccharide structures, especially substituted cellulosic structures.
  • S-A-4 235 735 discloses cellulose acetates with a defined degree of substitution as anti-redeposition agents in laundry products.
  • Cellulosic esters are also known for use in non-laundry applications, as described in O-A-91/16359 and GB-A-1 041 020.
  • cellulose based materials adhere to cotton fibres.
  • WO 00/18861 and WO 00/18862 disclose cellulosic compounds having a benefit agent attached, so that the benefit agent will be attached to the fibre. See also WO 99/14925.
  • polysaccharide, especially cellulose, based materials to adhere has not been fully investigated, and a need exists to find polysaccharide based materials that are of commercial significance.
  • a first aspect of the present invention provides use of a compound for promoting soil release during laundering of a textile fabric, the compound being a polymer having the general formula
  • each SU represents a sugar unit in a polysaccharide backbone
  • a represents the number of unsubstituted sugar units as a percentage of the total number of sugar units and is in the range from 0 to 99.9%, preferably 65 to 99%, more preferably 80 to 99%;
  • b represents the number of substituted sugar units as a percentage of the total number of sugar units and is in the range from 0.1 to 100%, preferably 1 to 35%, more preferably 1 to 20%;
  • n represents the degree of substitution per sugar unit and is from 1 to 3;
  • L represents an ester or ether linkage
  • R 1 represents a substituted alkyl group, preferably a hydroxyalkyl, carboxyalkyl or sulfoalkyl group or a salt thereof .
  • This aspect of the present invention may also be expressed as a method of promoting soil release during laundering of a textile fabric, the method comprising contacting the fabric with a polymer as defined above, preferably in the form of a laundry cleaning composition comprising said polymer, and most preferably in the form of an aqueous dispersion or solution of said composition, and subsequently washing the fabric after wear or use of the fabric.
  • this aspect may be expressed as use of a compound in the manufacture of a laundry cleaning composition for effecting soil release from a laundry item, the compound being a polymer as defined above.
  • a second aspect of the invention provides a polymer as defined above for deposition onto a fabric during a laundry cleaning process.
  • the second aspect of the invention may also be expressed as a method of depositing a benefit agent onto a fabric, the method comprising applying a polymer or a composition as defined above to the fabric .
  • cleaning or “laundering” mean “washing and/or rinsing” .
  • group -L-R 1 is a relatively small substituent of relatively low molecular weight compared to many of the groups which have been used as substituents for polysaccharides in the prior art .
  • alkyl refers to a branched or unbranched saturated hydrocarbon group which may contain from 1 to 12 carbon atoms, such as methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, t-butyl, octyl, decyl etc. More preferably, an alkyl group contains from 1 to 6, preferably 1 to 4 carbon atoms. "Substituted alkyl” refers to alkyl substituted with one or more substituent groups. Preferably, alkyl and substituted alkyl groups are unbranched.
  • alkenyl is a branched or unbranched unsaturated hydrocarbon containing 1 to 12, preferably 1 to 6 and especially 1 to 4 carbon atoms.
  • alkenyl and substituted alkenyl groups are unbranched.
  • a halogen atom may be a fluorine, chlorine, bromine or iodine atom and any group which contains a halo moiety, such as a haloalkyl group, may thus contain any one or more of these halogen atoms .
  • the term "degree of substitution” refers to substitution of the functional groups on the repeating sugar unit.
  • DS refers to substitution of the three hydroxyl groups on the repeating anhydroglucose unit .
  • the maximum degree of substitution is 3.
  • DS values do not generally relate to the uniformity of substitution of chemical groups along the polysaccharide molecule and are not related to the molecular weight of the polysaccharide backbone .
  • the average degree of substitution groups is preferably from 0.1 to 3 (eg. from 0.3 to 3), more preferably from 0.1 to 1 (eg. from 0.3 to 1) •
  • polysaccharides includes natural polysaccharides, synthetic polysaccharides, polysaccharide derivatives and modified polysaccharides.
  • Suitable polysaccharides for use in preparing the compounds of the present invention include, but are not limited to, gums, arabinans, galactans, seeds and mixtures thereof as well as cellulose and derivatives thereof.
  • Suitable polysaccharides that are useful in the present invention include polysaccharides with a degree of polymerisation (DP) over 40, preferably from about 50 to about 100,000, more preferably from about 500 to about 50,000.
  • DP degree of polymerisation
  • Constituent saccharides preferably include, but are not limited to, one or more of the following saccharides: isomaltose, isomaltotriose, isomaltotetraose, isomaltooligosaccharide, fructooligosaccharide, levooligosaccharides, galactooligosaccharide, xylooligosaccharide, gentiooligosaccharides, disaccharides, glucose, fructose, galactose, xylose, mannose, sorbose, arabinose, rhamnose, fucose, maltose, sucrose, lactose, maltulose, ribose, lyxose, allose, altrose, gulose, idose, talose, trehalose, nigerose, kojibiose, lactulose, oligosaccharides, maltooligosaccharides, trisaccharides,
  • the polysaccharides can be extracted from plants, produced by organisms, such as bacteria, fungi, prokaryotes, eukaryotes, extracted from animal and/or humans.
  • xanthan gum can be produced by Xanthomonas campestris, gellan by Sphingomonas paucimobilis, xyloglucan can be extracted from tamarind seed.
  • the polysaccharides can be linear, or branched in a variety of ways, such as 1-2, 1-3, 1-4, 1-6, 2-3 and mixtures thereof. Many naturally occurring polysaccharides have at least some degree of branching, or at any rate, at least some saccharide rings are in the form of pendant side groups on a main polysaccharide backbone. It is desirable that the polysaccharides of the present invention have a molecular weight in the range of from about 10,000 to about 10,000,000, more preferably from about 50,000 to about 1,000,000, most preferably from about 50,000 to about 500, 000.
  • the polysaccharide is selected from the group consisting of: tamarind gum (preferably consisting of xyloglucan polymers) , guar gum, locust bean gum (preferably consisting of galactomannan polymers) , and other industrial gums and polymers, which include, but are not limited to,
  • Polysaccharides can be used which have an a- or /?-linked backbone. However, more preferred polysaccharides have a ⁇ - linked backbone, preferably a / S-1,4 linked backbone. It is preferred that the ⁇ - 1 , 4-linked polysaccharide is cellulose; a cellulose derivative, particularly cellulose sulphate, cellulose acetate, sulphoethyl cellulose, cyanoethyl cellulose, methyl cellulose, ethyl cellulose, carboxymethylcellulose, hydroxyethylcellulose or hydroxypropylcellulose; a xyloglucan, particularly one derived from Tamarind seed gum; a glucomannan, particularly Konjac glucomannan; a galactomannan, particularly Locust Bean gum and Guar gum; a side chain branched galactomannan, particularly Xanthan gum; chitosan or a chitosan salt.
  • the natural polysaccharides can be modified with amines (primary , secondary, tertiary), amides, esters, ethers, urethanes, alcohols, carboxylic acids, tosylates, sulfonates, sulfates, nitrates, phosphates and mixtures thereof. Such a modification can take place in position 2, 3 and/or 6 of the saccharide unit.
  • modified or derivatised polysaccharides can be included in the compositions of the present invention in addition to the natural polysaccharides .
  • Nonlimiting examples of such modified polysaccharides include: carboxyl and hydroxymethyl substitutions (e.g. glucuronic acid instead of glucose) ; amino polysaccharides
  • polysaccharides containing silicone moieties are commercially available from Carbomer and include, but are not limited to, amino alginates, such as hexanediamine alginate, amine functionalised cellulose-like O-methyl- (N-l, 12- dodecanediamine) cellulose, biotin heparin, carboxymethylated dextran, guar polycarboxylic acid, carboxymethylated locust bean gum, carboxymethylated xanthan, chitosan phosphate, chitosan phosphate sulfate, diethylaminoethyl dextran, dodecylamide alginate, sialic acid, glucuronic acid, galacturonic acid, mannuronic acid, guluronic acid, N-acetylgluosamine, N-acetylgalactosamine, and mixtures thereof .
  • amino alginates such as hexanediamine alginate, amine functionalised cellulose-like O-methyl- (
  • Especially preferred polysaccharides include cellulose, ether, ester and urethane derivatives of cellulose, particularly cellulose monoacetate, xyloglucans and galactomannans, particularly Locust Bean gum.
  • the polysaccharide has a total number of sugar units from 10 to 7000, although this figure will be dependent on the type of polysaccharide chosen, at least to some extent.
  • the total number of sugar units is preferably from 50 to 1000, more preferably 50 to 750 and especially 200 to 300.
  • the preferred molecular weight of such polysaccharides is from 10 000 to 150 000.
  • the total number of sugar units is from 10 to 200, preferably 100 to 150.
  • the preferred molecular weight is from 10 000 to 20 000.
  • the total number of sugar units is preferably from 50 to 7000.
  • the preferred molecular weight is from 10 000 to 1000 000.
  • the total number of sugar units is preferably from 1000 to 3000.
  • the preferred molecular weight is from 250 000 to 600 000.
  • the polysaccharide can be linear, like in hydroxyalkyl cellulose, it can have an alternating repeat like in carrageenan, it can have an interrupted repeat like in pectin, it can be a block copolymer like in alginate, it can be branched like in dextran, or it can have a complex repeat like in xanthan. Descriptions of the polysaccharides are given in "An introduction to Polysaccharide Biotechnology", by M. Tombs and S. E. Harding, T.J. Press 1998.
  • the polymers utilised in the invention are polysaccharides in which at least one sugar unit of the polysaccharide has been substituted by a group of the general formula
  • each SU represents a sugar unit in a polysaccharide backbone
  • a represents the number of unsubstituted sugar units as a percentage of the total number of sugar units and is in the range from 0 to 99.9%, preferably 65 to 99%, more preferably 80 to 99% ;
  • b represents the number of substituted sugar units as a percentage of the total number of sugar units and is in the range from 0.1 to 100%, preferably 1 to 35%, more preferably 1 to 20%;
  • L represents an ester or ether linkage
  • R" represents a substituted alkyl group, preferably a hydroxyalkyl, carboxyalkyl or sulfoalkyl group or a salt thereof .
  • L represents a group -0-CO- or -0- .
  • R 1 is an alkyl group substituted by a group selected from -OH, -C0-OR 2 and -S0 3 -R 2 where R 2 represents a hydrogen atom or an alkali metal, preferably a sodium or potassium, atom.
  • R 2 represents a hydrogen atom or an alkali metal, preferably a sodium or potassium, atom.
  • the alkyl group is a C ⁇ - 6 alkyl, more preferably a C ⁇ _ 4 alkyl, group.
  • Ri represents a hydroxy C ⁇ _ 4 alkyl, preferably a hydroxymethyl group, a carboxy C ⁇ _ 6 alkyl, preferably a carboxy C ⁇ _ 4 alkyl, group or a sulfo C 2 _ 4 alkyl, preferably a sulfoethyl, group or a sodium salt thereof.
  • -L-R 1 represents a group selected from -0-CH 2 0H, -0-CH 2 CH 2 S0 3 H, -0-CH 2 -C0 2 H and -0-CO-CH 2 CH 2 C0 2 H and sodium salts thereof.
  • polysaccharide backbone in the polymers is ⁇ -linked, preferably ⁇ -1, -linked.
  • the polysaccharide backbone is selected from the group consisting of cellulose, cellulose derivatives (preferably cellulose sulphate, cellulose acetate, sulphoethyl cellulose, cyanoethyl cellulose, methyl cellulose, ethyl cellulose, carboxymethylcellulose, hydroxyethylcellulose or hydroxypropylcellulose) , xyloglucans (preferably those derived from Tamarind seed gum) , glucomannans (preferably Konjac glucomannan) , galactomannans (preferably Locust Bean gum, Guar gum and Xanthan gum), chitosan and chitosan salts. It is especially preferred that the polysaccharide backbone is Locust Bean gum or xyloglucan.
  • the polymers have the general formula :
  • L and R 1 are as defined above and at least one or more R groups are independently selected from groups of formulae : -
  • each R 8 is independently selected from C ⁇ _ 2 o
  • each R 9 is independently selected from hydrogen and groups R 8 as hereinbefore defined;
  • R is a bond or is selected from C ⁇ _ 4 alkylene, C 2 - 4 alkenylene and C 5 _ 7 arylene (e.g. phenylene) groups, the carbon atoms in any of these being optionally substituted by one or more substituents independently selected from C ⁇ - ⁇ 2 (preferably C ⁇ _ ) alkoxy, vinyl, hydroxyl , halo and amine
  • each R 11 is independently selected from hydrogen, counter cations such as alkali metal (preferably Na) or 2 Ca or 2 Mg, and groups R 8 as hereinbefore defined;
  • R is selected from C ⁇ _ 2 o (preferably C_. 6 ) alkyl, C 2 . 2 o (preferably C 2 - 6 ) alkenyl (e.g. vinyl) and C 5 - 7 aryl (e.g. phenyl) , any of which is optionally substituted by one or more substituents independently selected from C ⁇ _ 4 alkyl, C ⁇ _ ⁇ 2 (preferably C ⁇ _ 4 ) alkoxy, hydroxyl, carboxyl, cyano, sulfonato, vinyl and phenyl groups;
  • x is from 1 to 3;
  • any remaining R groups being selected from hydrogen and ether substituents.
  • R 12 is a methyl, ethyl, phenyl , hydroxyethyl , hydroxypropyl , carboxymethyl , sulphoethyl or cyanoethyl group.
  • R groups may optionally have one or more structures, for example as hereinbefore described.
  • one or more R groups may simply be hydrogen or an alkyl group .
  • Preferred groups may for example be independently selected from one or more of acetate, propanoate, trifluoroacetate, 2- (2-hydroxy-l-oxopropoxy) propanoate, lactate, glycolate, pyruvate, crotonate, isovalerate cinna ate, formate, salicylate, carbamate, methylcarbamate, benzoate, gluconate, methanesulphonate, toluene, sulphonate, groups and hemiester groups of fumaric, malonic, itaconic, oxalic, maleic, succinic, tartaric, aspartic, glutamic, and malic acids.
  • cellulose monoacetate refers to a molecule that has acetate esters in a degree of substitution of about 1.1 or less, preferably about 1.1 to about 0.5.
  • Cellulose triacetate refers to a molecule that has acetate esters in a degree of substitution of about 2.7 to 3.
  • Cellulose esters of hydroxyacids can be obtained using the acid anhydride in acetic acid solution at 20-30°C and in any case below 50°C. When the product has dissolved the liquid is poured into water. Tri-esters can be converted to secondary products as with the triacetate. Glycollic and lactic ester are most common. Cellulose glycollate may also be obtained from cellulose chloracetate (GB-A-320 842) by treating 100 parts with 32 parts of NaOH in alcohol added in small portions.
  • An alternative method of preparing cellulose esters consists in the partial displacement of the acid radical in a cellulose ester by treatment with another acid of higher ionisation constant (FR-A-702 116) .
  • the ester is heated at about 100°C with the acid which, preferably, should be a solvent for the ester.
  • the acid which, preferably, should be a solvent for the ester.
  • cellulose acetate- oxalate, tartrate, maleate, pyruvate, salicylate and phenylglycollate have been obtained, and from cellulose tribenzoate a cellulose benzoate-pyruvate .
  • a cellulose acetate-lactate or acetate-glycollate could be made in this way also.
  • cellulose acetate (10 g.) in dioxan (75 ml.) containing oxalic acid (10 g.) is heated at 100°C for 2 hours under reflux.
  • esters are prepared by variations of this process.
  • a simple ester of cellulose e.g. the acetate, is dissolved in a mixture of two (or three) organic acids, each of which has an ionisation constant greater than that of acetic acid
  • a cellulose acetate-lactate-pyruvate is prepared from cellulose acetate, 40 per cent, acetyl (100 g.), in a bath of 125 ml. pyruvic acid and 125 ml. of 85 per cent, lactic acid by heating at 100 °C for 18 hours. The product is soluble in water and is precipitated and washed with ether- acetone. M.p. 230-250°C.
  • m is from 1 to 2, preferably 1.
  • polymers used in the present invention may be synthesised by a variety of routes which are well known to those skilled in the art of polymer chemistry.
  • carboxyalkyl ether-linked polymers can be made by reacting a polysaccharide with a suitable haloalkanoic acid
  • carboxyalkyl ester-linked polymers can be made by reacting a polysaccharide with a suitable anhydride, such as succinic anhydride
  • sulfoalkyl ether-linked polymers can be made by reacting a polysaccharide with a suitable alkenyl sulphonic acid.
  • the substituted polysaccharide according to the first aspect of the present invention may be incorporated into compositions containing only a diluent (which may comprise solid and/or liquid) and/or also comprising an active ingredient.
  • the compound is typically included in said compositions at levels of from 0.01% to 25% by weight, preferably from 0.05% to 15%, more preferably from 0.1% to 10%, especially from 0.1% to 5% and most preferably from 0.5% to 3%.
  • the active ingredient in the compositions is preferably a surface active agent or a fabric conditioning agent. More than one active ingredient may be included. For some applications a mixture of active ingredients may be used.
  • compositions of the invention may be in any physical form e.g. a solid such as a powder or granules, a tablet, a solid bar, a paste, gel or liquid, especially, an aqueous based liquid.
  • a solid such as a powder or granules, a tablet, a solid bar, a paste, gel or liquid, especially, an aqueous based liquid.
  • the compositions may be used in laundry compositions, especially in liquid, powder or tablet laundry composition.
  • compositions of the present invention are preferably laundry compositions, especially main wash (fabric washing) compositions or rinse-added softening compositions.
  • the main wash compositions may include a fabric softening agent and rinse-added fabric softening compositions may include surface-active compounds, particularly non-ionic surface- active compounds, if appropriate.
  • the detergent compositions of the invention may contain a surface-active compound (surfactant) which may be chosen from soap and non-soap anionic, cationic, non-ionic, amphoteric and zwitterionic surface-active compounds and mixtures thereof.
  • surfactant may be chosen from soap and non-soap anionic, cationic, non-ionic, amphoteric and zwitterionic surface-active compounds and mixtures thereof.
  • surface-active compound surfactant
  • surfactant may be chosen from soap and non-soap anionic, cationic, non-ionic, amphoteric and zwitterionic surface-active compounds and mixtures thereof.
  • the preferred detergent-active compounds that can be used are soaps and synthetic non-soap anionic and non-ionic compounds.
  • compositions of the invention may contain linear alkylbenzene sulphonate, particularly linear alkylbenzene sulphonates having an alkyl chain length of C 8 -C ⁇ 5 . It is preferred if the level of linear alkylbenzene sulphonate is from 0 wt% to 30 wt%, more preferably 1 wt% to 25 wt%, most preferably from 2 wt% to 15 wt%.
  • compositions of the invention may contain other anionic surfactants in amounts additional to the percentages quoted above.
  • Suitable anionic surfactants are well-known to those skilled in the art. Examples include primary and secondary alkyl sulphates, particularly C 8 -C 15 primary alkyl sulphates; alkyl ether sulphates; olefin sulphonates; alkyl xylene sulphonates; dialkyl sulphosuccinates; and fatty acid ester sulphonates. Sodium salts are generally preferred.
  • the compositions of the invention may also contain non-ionic surfactant.
  • Nonionic surfactants that may be used include the primary and secondary alcohol ethoxylates, especially the C 8 -C 2 o aliphatic alcohols ethoxylated with an average of from 1 to 20 moles of ethylene oxide per mole of alcohol, and more especially the C ⁇ 0 -C ⁇ 5 primary and secondary aliphatic alcohols ethoxylated with an average of from 1 to 10 moles of ethylene oxide per mole of alcohol .
  • Non-ethoxylated nonionic surfactants include alkylpolyglycosides, glycerol monoethers, and polyhydroxyamides (glucamide) .
  • the level of non-ionic surfactant is from 0 wt% to 30 wt%, preferably from 1 wt% to 25 wt%, most preferably from 2 wt% to 15 wt%.
  • any conventional fabric conditioning agent may be used in the compositions of the present invention.
  • the conditioning agents may be cationic or non-ionic. If the fabric conditioning compound is to be employed in a main wash detergent composition the compound will typically be nonionic. For use in the rinse phase, typically they will be cationic. They may for example be used in amounts from 0.5% to 35%, preferably from 1% to 30% more preferably from 3% to 25% by weight of the composition.
  • the fabric conditioning agent (s) have two long chain alkyl or alkenyl chains each having an average chain length greater than or equal to C 1S . Most preferably at least 50% of the long chain alkyl or alkenyl groups have a chain length of C ⁇ 8 or above. It is preferred if the long chain alkyl or alkenyl groups of the fabric conditioning agents are predominantly linear.
  • the fabric conditioning agents are preferably compounds that provide excellent softening, and are characterised by a chain melting L ⁇ to L ⁇ transition temperature greater than 25°C, preferably greater than 35°C, most preferably greater than 45°C.
  • This L ⁇ to L ⁇ transition can be measured by DSC as defined in " Handbook of Lipid Bilayers, D Marsh, CRC Press, Boca Raton, Florida, 1990 (pages 137 and 337) .
  • Substantially insoluble fabric conditioning compounds in the context of this invention are defined as fabric conditioning compounds having a solubility less than 1 x 10 "3 wt % in deminerailised water at 20°C.
  • the fabric softening compounds have a solubility less than 1 x 10 ⁇ 4 wt %, most preferably less than 1 x 10 "8 to 1 x 10 " ⁇ .
  • Preferred cationic fabric softening agents comprise a substantially water insoluble quaternary ammonium material comprising a single alkyl or alkenyl long chain having an average chain length greater than or equal to C 2 o or, more preferably, a compound comprising a polar head group and two alkyl or alkenyl chains having an average chain length greater than or equal to C 14 .
  • the cationic fabric softening agent is a quaternary ammonium material or a quaternary ammonium material containing at least one ester group.
  • the quaternary ammonium compounds containing at least one ester group are referred to herein as ester-linked quaternary ammonium compounds .
  • ester-linked quaternary ammonium compounds As used in the context of the quarternary ammonium cationic fabric softening agents, the term 'ester group', includes an ester group which is a linking group in the molecule.
  • ester-linked quaternary ammonium compounds it is preferred for the ester-linked quaternary ammonium compounds to contain two or more ester groups .
  • the ester group (s) is a linking group between the nitrogen atom and an alkyl group.
  • the ester groups (s) are preferably attached to the nitrogen atom via another hydrocarbyl group .
  • quaternary ammonium compounds containing at least one ester group, preferably two, wherein at least one higher molecular weight group containing at least one ester group and two or three lower molecular weight groups are linked to a common nitrogen atom to produce a cation and wherein the electrically balancing anion is a halide, acetate or lower alkosulphate ion, such as chloride or methosulphate .
  • the higher molecular weight substituent on the nitrogen is preferably a higher alkyl group, containing 12 to 28, preferably 12 to 22, e.g.
  • the lower molecular weight substituents are preferably lower alkyl of 1 to 4 carbon atoms, such as methyl or ethyl, or substituted lower alkyl.
  • One or more of the said lower molecular weight substituents may include an aryl moiety or may be replaced by an aryl, such as benzyl, phenyl or other suitable substituents.
  • the quaternary ammonium material is a compound having two C 12 -C 22 alkyl or alkenyl groups connected to a quaternary ammonium head group via at least one ester link, preferably two ester links or a compound comprising a single long chain with an average chain length equal to or greater than C 2 o ⁇
  • the quaternary ammonium material comprises a compound having two long chain alkyl or alkenyl chains with an average chain length equal to or greater than C i4 .
  • each chain has an average chain length equal to or greater than C 16 .
  • Most preferably at least 50% of each long chain alkyl or alkenyl group has a chain length of Cis . It is preferred if the long chain alkyl or alkenyl groups are predominantly linear.
  • ester-linked quaternary ammonium material that can be used in laundry rinse compositions according to the invention is represented by the formula (A) :
  • T is -O-C- or -C-O- ; each R 20 group is independently selected from C ⁇ _ 4 alkyl, hydroxyalkyl or C 2 - alkenyl groups; and wherein each R 21 group is independently selected from C 8 _ 28 alkyl or alkenyl groups;
  • Y " is any suitable counter-ion, i.e. a halide, acetate or lower alkosulphate ion, such as chloride or methosulphate;
  • w is an integer from 1-5 or is 0; and y is an integer from 1-5.
  • each R group is methyl and w is 1 or 2.
  • the quaternary ammonium material is biologically degradable.
  • Preferred materials of this class such as 1,2 bis [hardened tallowoyloxy] -3-trimethylammonium propane chloride and their method of preparation are, for example, described in US-A-4 137 180.
  • these materials comprise small amounts of the corresponding monoester as described in US-A-4 137 180 for example 1-hardened tallowoyloxy-2 -hydroxy-3- trimethylammonium propane chloride.
  • Another class of preferred ester-linked quaternary ammonium materials for use in laundry rinse compositions according to the invention can be represented by the formula:
  • T is -O-C- or -C-O- ;
  • R 20 , R 21 , w, and Y " are as defined above.
  • di- (tallowyloxyethyl) - dimethyl ammonium chloride available from Hoechst, is the most preferred.
  • Di- (hardened tallowyloxyethyl) dimethyl ammonium chloride, ex Hoechst and di- (tallowyloxyethyl) - methyl hydroxyethyl methosulphate are also preferred.
  • Another preferred class of quaternary ammonium cationic fabric softening agent is defined by formula (C) : -
  • R 20 , R 21 and Y " are as hereinbefore defined.
  • a preferred material of formula (C) is di-hardened tallow- diethyl ammonium chloride, sold under the Trademark Arquad 2HT.
  • the optionally ester-linked quaternary ammonium material may contain optional additional components, as known in the art, in particular, low molecular weight solvents, for instance isopropanol and/or ethanol, and co-actives such as nonionic softeners, for example fatty acid or sorbitan esters.
  • low molecular weight solvents for instance isopropanol and/or ethanol
  • co-actives such as nonionic softeners, for example fatty acid or sorbitan esters.
  • compositions of the invention when used as main wash fabric washing compositions, will generally also contain one or more detergency builders.
  • the total amount of detergency builder in the compositions will typically range from 5 to 80 wt%, preferably from 10 to 60 wt%.
  • Cationic surfactants which can be used in main-wash compositions for fabrics.
  • Cationic surfactants that may be used include quaternary ammonium salts of the general formula R ⁇ R 2 R 3 R 4 N + X " wherein the R groups are long or short hydrocarbon chains, typically alkyl, hydroxyalkyl or ethoxylated alkyl groups, and X is a counter-ion (for example, compounds in which R_ is a C 8 -C 2 2 alkyl group, preferably a C 8 -C ⁇ 0 or C ⁇ 2 -C ⁇ alkyl group, R 2 is a methyl group, and R 3 and R 4 , which may be the same or different, are methyl or hydroxyethyl groups) ; and cationic esters (for example, choline esters) .
  • surfactant surface-active compound
  • amount present will depend on the intended use of the detergent composition.
  • surfactant systems may be chosen, as is well known to the skilled formulator, for handwashing products and for products intended for use in different types of washing machine .
  • the total amount of surfactant present will also depend on the intended end use and may be as high as 60 wt%, for example, in a composition for washing fabrics by hand. In compositions for machine washing of fabrics, an amount of from 5 to 40 wt% is generally appropriate. Typically the compositions will comprise at least 2 wt% surfactant e.g. 2- 60%, preferably 15-40% most preferably 25-35%.
  • Detergent compositions suitable for use in most automatic fabric washing machines generally contain anionic non-soap surfactant, or non-ionic surfactant, or combinations of the two in any suitable ratio, optionally together with soap.
  • compositions of the invention when used as main wash fabric washing compositions, will generally also contain one or more detergency builders.
  • the total amount of detergency builder in the compositions will typically range from 5 to 80 wt%, preferably from 10 to 60 wt%.
  • Inorganic builders that may be present include sodium carbonate, if desired in combination with a crystallisation seed for calcium carbonate, as disclosed in GB 1 437 950 (Unilever) ; crystalline and amorphous aluminosilicates, for example, zeolites as disclosed in GB 1 473 201 (Henkel) , amorphous aluminosilicates as disclosed in GB 1 473 202
  • Inorganic phosphate builders for example, sodium orthophosphate, pyrophosphate and tripolyphosphate are also suitable for use with this invention.
  • compositions of the invention preferably contain an alkali metal, preferably sodium, aluminosilicate builder.
  • Sodium aluminosilicates may generally be incorporated in amounts of from 10 to 70% by weight (anhydrous basis) , preferably from 25 to 50 wt%.
  • the alkali metal aluminosilicate may be either crystalline or amorphous or mixtures thereof, having the general formula: 0.8-1.5 Na 2 0. A1 2 0 3 . 0.8-6 Si0 2
  • the preferred sodium aluminosilicates contain 1.5-3.5 Si0 2 units (in the formula above) . Both the amorphous and the crystalline materials can be prepared readily by reaction between sodium silicate and sodium aluminate, as amply described in the literature. Suitable crystalline sodium aluminosilicate ion-exchange detergency builders are described, for example, in GB 1 429 143 (Procter & Gamble) .
  • the preferred sodium aluminosilicates of this type are the well-known commercially available zeolites A and X, and mixtures thereof .
  • the zeolite may be the commercially available zeolite 4A now widely used in laundry detergent powders. However, according to a preferred embodiment of the invention, the zeolite 32 -
  • zeolite MAP maximum aluminium zeolite P as described and claimed in EP 384 070A (Unilever) .
  • Zeolite MAP is defined as an alkali metal aluminosilicate of the zeolite P type having a silicon to aluminium ratio not exceeding 1.33, preferably within the range of from 0.90 to 1.33, and more preferably within the range of from 0.90 to 1.20.
  • zeolite MAP having a silicon to aluminium ratio not exceeding 1.07, more preferably about 1.00.
  • the calcium binding capacity of zeolite MAP is generally at least 150 mg CaO per g of anhydrous material.
  • Organic builders that may be present include polycarboxylate polymers such as polyacrylates, acrylic/maleic copolymers, and acrylic phosphinates; monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono-, di and trisuccinates, carboxymethyloxy succinates, carboxymethyloxymalonates, dipicolinates, hydroxyethyliminodiacetates, alkyl- and alkenylmalonates and succinates; and sulphonated fatty acid salts. This list is not intended to be exhaustive.
  • polycarboxylate polymers such as polyacrylates, acrylic/maleic copolymers, and acrylic phosphinates
  • monomeric polycarboxylates such as citrates, gluconates, oxydisuccinates, glycerol mono-, di and trisuccinates, carboxymethyloxy succinates, carboxymethyloxymalonates, dipicolinates, hydroxyethy
  • Especially preferred organic builders are citrates, suitably used in amounts of from 5 to 30 wt%, preferably from 10 to 25 wt%; and acrylic polymers, more especially acrylic/maleic copolymers, suitably used in amounts of from 0.5 to 15 wt%, preferably from 1 to 10 wt%.
  • Builders both inorganic and organic, are preferably present in alkali metal salt, especially sodium salt, form. 33
  • compositions according to the invention may also suitably contain a bleach system.
  • Fabric washing compositions may desirably contain peroxy bleach compounds, for example, inorganic persalts or organic peroxyacids, capable of yielding hydrogen peroxide in aqueous solution.
  • Suitable peroxy bleach compounds include organic peroxides such as urea peroxide, and inorganic persalts such as the alkali metal perborates, percarbonates, perphosphates, persilicates and persulphates .
  • organic peroxides such as urea peroxide
  • inorganic persalts such as the alkali metal perborates, percarbonates, perphosphates, persilicates and persulphates .
  • Preferred inorganic persalts are sodium perborate monohydrate and tetrahydrate, and sodium percarbonate .
  • sodium percarbonate having a protective coating against destabilisation by moisture Especially preferred is sodium percarbonate having a protective coating against destabilisation by moisture.
  • Sodium percarbonate having a protective coating comprising sodium metaborate and sodium silicate is disclosed in GB 2 123 044B (Kao) .
  • the peroxy bleach compound is suitably present in an amount of from 0.1 to 35 wt%, preferably from 0.5 to 25 wt%.
  • the peroxy bleach compound may be used in conjunction with a bleach activator (bleach precursor) to improve bleaching action at low wash temperatures.
  • the bleach precursor is suitably present in an amount of from 0.1 to 8 wt%, preferably from 0.5 to 5 wt%.
  • Preferred bleach precursors are peroxycarboxylic acid precursors, more especially peracetic acid precursors and pernoanoic acid precursors. Especially preferred bleach 34
  • N,N,N' ,N' , -tetracetyl ethylenediamine (TAED) and sodium nonanoyloxybenzene sulphonate (SNOBS) are also of interest.
  • TAED N,N,N' ,N' , -tetracetyl ethylenediamine
  • SNOBS sodium nonanoyloxybenzene sulphonate
  • the bleach system can be either supplemented with or replaced by a peroxyacid.
  • peracids can be found in US 4 686 063 and US 5 397 501 (Unilever) .
  • a preferred example is the imido peroxycarboxylic class of peracids described in EP A 325 288, EP A 349 940, DE 382 3172 and EP 325 289.
  • a particularly preferred example is phthalimido peroxy caproic acid (PAP).
  • PAP phthalimido peroxy caproic acid
  • Such peracids are suitably present at 0.1 - 12%, preferably 0.5 - 10%.
  • a bleach stabiliser may also be present.
  • Suitable bleach stabilisers include ethylenediamine tetra-acetate (EDTA) , the polyphosphonates such as Dequest (Trade Mark) and non-phosphate stabilisers such as EDDS (ethylene diamine di-succinic acid) . These bleach stabilisers are also useful for stain removal especially in products containing low levels of bleaching species or no bleaching species.
  • An especially preferred bleach system comprises a peroxy bleach compound (preferably sodium percarbonate optionally together with a bleach activator) , and a transition metal bleach catalyst as described and claimed in EP 458 397A ,EP 458 398A and EP 509 787A (Unilever) . 35
  • a peroxy bleach compound preferably sodium percarbonate optionally together with a bleach activator
  • a transition metal bleach catalyst as described and claimed in EP 458 397A ,EP 458 398A and EP 509 787A (Unilever) .
  • compositions according to the invention may also contain one or more enzyme (s) .
  • Suitable enzymes include the proteases, amylases, cellulases, oxidases, peroxidases and lipases usable for incorporation in detergent compositions.
  • Preferred proteolytic enzymes are, catalytically active protein materials which degrade or alter protein types of stains when present as in fabric stains in a hydrolysis reaction. They may be of any suitable origin, such as vegetable, animal, bacterial or yeast origin.
  • proteolytic enzymes or proteases of various qualities and origins and having activity in various pH ranges of from 4-12 are available and can be used in the instant invention.
  • suitable proteolytic enzymes are the subtilins which are obtained from particular strains of B. Subtilis B. licheniformis , such as the commercially available subtilisins Maxatase (Trade Mark) , as supplied by Gist Brocades N.V. ,
  • protease obtained from a strain of Bacillus having maximum activity throughout the pH range of 8-12, being commercially available, e.g. from Novo Industri A/S under the registered trade-names Esperase (Trade Mark) and Savinase (Trade-Mark) .
  • Esperase Trade Mark
  • Savinase Trade-Mark
  • the preparation of these and analogous enzymes is described in GB 1 243 785.
  • Other commercial proteases are Kazusase (Trade Mark obtainable from
  • Detergency enzymes are commonly employed in granular form in amounts of from about 0.1 to about 3.0 wt%. However, any suitable physical form of enzyme may be used.
  • compositions of the invention may contain alkali metal, preferably sodium carbonate, in order to increase detergency and ease processing.
  • Sodium carbonate may suitably be present in amounts ranging from 1 to 60 wt%, preferably from 2 to 40 wt%.
  • compositions containing little or no sodium carbonate are also within the scope of the invention.
  • Powder flow may be improved by the incorporation of a small amount of a powder structurant, for example, a fatty acid (or fatty acid soap) , a sugar, an acrylate or acrylate/maleate copolymer, or sodium silicate.
  • a powder structurant for example, a fatty acid (or fatty acid soap) , a sugar, an acrylate or acrylate/maleate copolymer, or sodium silicate.
  • a powder structurant for example, a fatty acid (or fatty acid soap) , a sugar, an acrylate or acrylate/maleate copolymer, or sodium silicate.
  • fatty acid soap suitably present in an amount of from 1 to 5 wt%.
  • detergent compositions of the invention include sodium silicate; antiredeposition agents such as cellulosic polymers; soil release polymers; inorganic salts such as sodium sulphate; lather control agents or lather boosters as appropriate; proteolytic and lipolytic enzymes; dyes; coloured speckles; foam controllers and decoupling polymers.
  • Further additional ingredients include surfactants, detergency builders, bleaches, transition metal sequestrants, enzymes, fabric softening and/or conditioning agents, lubricants for inhibition of 37 -
  • UV absorbers such as fluorescers and photofading inhibitors, for example sunscreens/UV inhibitors and/or anti-oxidants, fungicides, insect repellents and/or insecticides, perfumes, dye fixatives, waterproofing agents, deposition aids, flocculants, anti-redeposition agents and soil release agents.
  • Particulate detergent compositions are suitably prepared by spray-drying a slurry of compatible heat-insensitive ingredients, and then spraying on or post-dosing those ingredients unsuitable for processing via the slurry.
  • the skilled detergent formulator will have no difficulty in deciding which ingredients should be included in the slurry and which should not .
  • Particulate detergent compositions of the invention preferably have a bulk density of at least 400 g/llitre, more preferably at least 500 g/litre. Especially preferred compositions have bulk densities of at least 650 g/litre, more preferably at least 700 g/litre. 38
  • Such powders may be prepared either by post-tower densification of spray-dried powder, or by wholly non-tower methods such as dry mixing and granulation; in both cases a high-speed mixer/granulator may advantageously be used. Processes using high-speed mixer/granulators are disclosed, for example, in EP 340 013A, EP 367 339A, EP 390 251A and EP 420 317A (Unilever) .
  • Liquid detergent compositions can be prepared by admixing the essential and optional ingredients thereof in any desired order to provide compositions containing components in the requisite concentrations.
  • Liquid compositions according to the present invention can also be in compact form which means it will contain a lower level of water compared to a conventional liquid detergent.
  • the substrate may be any substrate onto which it is desirable to deposit a polymer and which is subjected to treatment such as a washing or rinsing process.
  • the substrate may be a textile fabric, fabric, preferably of cotton.
  • the treatment of the substrate with the material of the invention can be made by any suitable method such as washing, soaking or rinsing of the substrate.
  • the treatment will involve a washing or rinsing method such as treatment in the main wash or rinse cycle of a washing machine and involves contacting the substrate with an aqueous medium comprising the material of the invention.
  • Locust Bean Gum (MUD 246B, ex Rhodia) (5g, 30.84 mmol of anhydrosugar units) was dispersed in a mixture of demineralised water (12 ml) and propan-2-ol (30 ml) with vigorous stirring in a 2-necked 100ml round bottom flask fitted with a mechanical stirrer. After heating the solution to 70 °C, sodium hydroxide (0.625g, 15.6 mmol) was added and the mixture stirred for 15 minutes at the reaction temperature. Sodium chloroacetate (1.8g, 15 mmol) was then added as a solution in demineralised water (2 ml) and the reaction mixture vigorously stirred for 15 minutes at 70 °C.
  • Locust Bean Gum (MUD 246B, ex Rhodia) (5g, 30.84 mmol of anhydrosugar units) was dispersed in a mixture of demineralised water (12 ml) and propan-2-ol (30 ml) with vigorous stirring in a 2 -necked 100ml round bottom flask fitted with a mechanical stirrer. After heating the solution to 70 °C, sodium hydroxide (0.625g, 15.6 mmol) was added as a solution in water (2 ml) and the mixture stirred for 15 minutes at the reaction temperature. Vinyl sulfonic acid (8 ml of a 25% aqueous solution, 15.6 mmol) was added and the - 41 -
  • reaction mixture vigorously stirred for 15 minutes at 70 °C.
  • the same protocol of adding both reagents was repeated three times and the reaction mixture stirred for 6 hours whilst maintaining the temperature at 70 °C.
  • the reaction mixture was then poured into methanol (200ml) and the resultant white precipitate collected on a sinter funnel .
  • the product was washed repeatedly with methanol and then re-dispersed into hot demineralised water. This was freeze dried resulting in 6.25g of creamy coloured material.
  • a 9% w/v solution of lithium chloride in anhydrous dimethylsulfoxide (DMSO) was prepared by heating 100 ml of the solvent to 150 °C in a 2 -necked round bottom flask fitted with a mechanical stirrer.
  • Locust Bean Gum (MUD 246B, ex Rhodia ) (5g, 30.84 mmol of anhydrosugar units) was added whilst maintaining the temperature until a highly viscous, homogeneous solution had formed.
  • succinic anhydride (4.5g, 45 mmol) was added as a solution in anhydrous dimethyl sulphoxide (DMSO) (10ml) followed by the addition of 4- (dimethylamino) pyridine (1.15g, 9.4 mmol), also as a solution in DMSO (10ml) .
  • DMSO dimethyl sulphoxide
  • 4- (dimethylamino) pyridine (1.15g, 9.4 mmol
  • the reaction mixture was then poured into methanol (300ml) and the resultant white precipitate collected on a sinter funnel After repeated - 42 -
  • Locust Bean Gum-succinate as prepared above (1.355g) was added to a conical flask, to which 25ml of 1M sodium hydroxide solution was added. This was repeated with a sample of the unmodified Locust Bean Gum (0.5g) as a blank. The flasks were stoppered and left at ambient temperature overnight. Each flask was then titrated with 1M hydrochloric acid solution using phenolphthalein as indicator. The amount of acid required for neutralisation allows the number of the succinic acid molecules present to be calculated. For this example, the Locust Bean Gum derivative was found to be 53% succinoylated.
  • Locust bean gum copolymer with a backbone of (1,4) -linked ⁇ -D-mannose units having side stubs of (1,6) -linked a-D- galactose groups in a ratio of mannose to galactose 4 :1
  • LAS linear alkylbenzene sulphonate
  • NaTPP Sodium tripolyphosphate Detergency used 0.5% w/w polymer
  • CM-XG carboxymethylated xyloglucan
  • CM-LBG carboxymethylated Locust Bean Gum
  • SU-XG succinoylated xyloglucan
  • SU-LBG succinoylated Locust Bean Gum
  • Su-Et XG sulfoethylated xyloglucan
  • Su-Et XG sulfoethylated Locust Bean Gum

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Abstract

La présente invention se rapporte à l'utilisation d'un composé facilitant l'élimination des salissures lors du blanchissage d'une étoffe, ledit composé étant un polymère représenté par la formule générale (I) qui se caractérise en ce que chaque SU représente une unité glucidique dans un squelette de polysaccharide; a représente le nombre d'unités glucidiques non substituées, exprimé sous forme de pourcentage du nombre total d'unités glucidiques, et est compris entre 0 et 99,9 %, de préférence entre 65 et 99 %, et idéalement entre 80 et 99 %; b représente le nombre d'unités glucidiques substituées, exprimé sous forme de pourcentage du nombre total d'unités glucidiques, et est compris entre 0,1 à 100 %, de préférence entre 1 et 35 %, et idéalement entre 1 et 20 %; m représente le degré de substitution par unité glucidique et est compris entre 1 et 3; l représente un ester ou une liaison éther; R1 représente un groupe alkyle substitué, de préférence un groupe hydroxy alkyle, carboxy alkyle ou sulfoalkyle ou un sel de ceux-ci. L'invention se rapporte également à un procédé visant à faciliter l'élimination des salissures lors du blanchissage d'une étoffe ainsi qu'à l'utilisation de ces polymères pour la fabrication d'une composition de lavage du linge qui permet l'élimination des salissures d'un article textile.
PCT/EP2002/010586 2001-11-09 2002-09-20 Polymeres pour applications de blanchissage Ceased WO2003040279A1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
BRPI0213709-7A BR0213709B1 (pt) 2001-11-09 2002-09-20 Uso de um polímero para promover a liberação de sujeira durante a lavagem de roupa de um tecido têxtil
ES02774634.6T ES2675289T3 (es) 2001-11-09 2002-09-20 Polímeros para aplicaciones de lavado de ropa
EP02774634.6A EP1442109B1 (fr) 2001-11-09 2002-09-20 Polymeres pour applications de blanchissage

Applications Claiming Priority (2)

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GB0127036.2 2001-11-09
GB0127036A GB0127036D0 (en) 2001-11-09 2001-11-09 Polymers for laundry applications

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Cited By (213)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004111169A1 (fr) * 2003-06-16 2004-12-23 Unilever Plc Composition de traitement de blanchisserie
WO2006117056A1 (fr) * 2005-04-29 2006-11-09 Unilever Plc Polymeres pour la lessive
WO2006117071A1 (fr) * 2005-04-29 2006-11-09 Unilever Plc Polymeres pour applications de blanchisserie
WO2007049249A1 (fr) 2005-10-28 2007-05-03 The Procter & Gamble Company Compositions contenant du catechol modifie anioniquement et des polymeres qui favorisent la suspension des saletes
EP1867708A1 (fr) * 2006-06-16 2007-12-19 The Procter and Gamble Company Compositions de lavage
WO2010105943A1 (fr) 2009-03-20 2010-09-23 Henkel Ag & Co. Kgaa Utilisation de polymères à groupes carboxyle, en combinaison avec des cations bivalents pour la formation d'une couche protectrice
DE102009001803A1 (de) 2009-03-24 2010-09-30 Henkel Ag & Co. Kgaa Verwendung von Polymeren mit Carboxylgruppen in Kombination mit zweiwertigen Kationen zur Ausbildung einer Schutzschicht
WO2011080267A2 (fr) 2009-12-29 2011-07-07 Novozymes A/S Polypeptides amplifiant la detergence
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WO2012120304A1 (fr) 2011-03-09 2012-09-13 Reckitt Benckiser N.V. Composition de nettoyage de tapis
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WO2015001017A2 (fr) 2013-07-04 2015-01-08 Novozymes A/S Polypeptides présentant un effet anti-redéposition et polynucléotides codant pour ceux-ci
WO2015049370A1 (fr) 2013-10-03 2015-04-09 Novozymes A/S Composition détergente et utilisation de celle-ci
WO2015134737A1 (fr) 2014-03-05 2015-09-11 Novozymes A/S Compositions et procédés pour améliorer les propriétés de matières textiles cellulosiques avec une xyloglucane endotransglycosylase
WO2015134729A1 (fr) 2014-03-05 2015-09-11 Novozymes A/S Compositions et procédés destinés à améliorer les propriétés de matériaux textiles non-cellulosiques par l'utilisation d'endo-xyloglucane transférase
WO2015150457A1 (fr) 2014-04-01 2015-10-08 Novozymes A/S Polypeptides présentant une activité alpha-amylase
WO2015189371A1 (fr) 2014-06-12 2015-12-17 Novozymes A/S Variants d'alpha-amylase et polynucléotides codant pour ces derniers
WO2016001319A1 (fr) 2014-07-03 2016-01-07 Novozymes A/S Stabilisation améliorée d'enzyme autre que la protéase
WO2016079305A1 (fr) 2014-11-20 2016-05-26 Novozymes A/S Variants de alicyclobacillus et polynucléotides codant pour ceux-ci
WO2016096996A1 (fr) 2014-12-16 2016-06-23 Novozymes A/S Polypeptides ayant une activité n-acétylglucosamine oxydase
US9376648B2 (en) 2008-04-07 2016-06-28 The Procter & Gamble Company Foam manipulation compositions containing fine particles
WO2016135351A1 (fr) 2015-06-30 2016-09-01 Novozymes A/S Composition de détergent de lavage du linge, procédé de lavage et utilisation de la composition
WO2016162556A1 (fr) 2015-04-10 2016-10-13 Novozymes A/S Procédé de lavage de linge, utilisation d'adnase et composition détergente
EP3106508A1 (fr) 2015-06-18 2016-12-21 Henkel AG & Co. KGaA Composition détergente comprenant des variantes de subtilase
WO2017046260A1 (fr) 2015-09-17 2017-03-23 Novozymes A/S Polypeptides présentant une activité de dégradation de xylanase et polynucléotides codant pour ceux-ci
WO2017064253A1 (fr) 2015-10-14 2017-04-20 Novozymes A/S Polypeptides ayant une activité de protéase et polynucléotides codant pour ceux-ci
WO2017089366A1 (fr) 2015-11-24 2017-06-01 Novozymes A/S Polypeptides ayant une activité de protéase et polynucléotides codant pour ceux-ci
WO2017129754A1 (fr) 2016-01-29 2017-08-03 Novozymes A/S Variants de la bêta-glucanase et polynucléotides les codant
WO2017174769A2 (fr) 2016-04-08 2017-10-12 Novozymes A/S Compositions détergentes et utilisations de celles-ci
WO2017186943A1 (fr) 2016-04-29 2017-11-02 Novozymes A/S Compositions détergentes et leurs utilisations
WO2017207762A1 (fr) 2016-06-03 2017-12-07 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
WO2017210188A1 (fr) 2016-05-31 2017-12-07 Novozymes A/S Compositions stabilisées de peroxyde liquide
WO2018002261A1 (fr) 2016-07-01 2018-01-04 Novozymes A/S Compositions détergentes
WO2018001959A1 (fr) 2016-06-30 2018-01-04 Novozymes A/S Variants de lipase et compositions comprenant un tensioactif et un variant de lipase
WO2018007573A1 (fr) 2016-07-08 2018-01-11 Novozymes A/S Compositions détergentes contenant de la galactanase
WO2018007435A1 (fr) 2016-07-05 2018-01-11 Novozymes A/S Variants de pectate lyase et polynucléotides codant pour ces variants
WO2018011277A1 (fr) 2016-07-13 2018-01-18 Novozymes A/S Variants dnases de bacillus cibi
WO2018037062A1 (fr) 2016-08-24 2018-03-01 Novozymes A/S Variants d'endoglucanase gh9 et polynucléotides codant pour de tels variants
WO2018037065A1 (fr) 2016-08-24 2018-03-01 Henkel Ag & Co. Kgaa Composition détergente comprenant des variants i d'endoglucanase gh9
WO2018037064A1 (fr) 2016-08-24 2018-03-01 Henkel Ag & Co. Kgaa Compositions détergentes comprenant des variants de xanthane lyase i
WO2018037061A1 (fr) 2016-08-24 2018-03-01 Novozymes A/S Variants de lyase xanthan et polynucléotides codant pour ces variants
WO2018060475A1 (fr) 2016-09-29 2018-04-05 Novozymes A/S Granule contenant des spores
EP3309249A1 (fr) 2013-07-29 2018-04-18 Novozymes A/S Variants de protéases et polynuclétides les codant
WO2018077938A1 (fr) 2016-10-25 2018-05-03 Novozymes A/S Compositions détergentes
WO2018083093A1 (fr) 2016-11-01 2018-05-11 Novozymes A/S Granules à noyaux multiples
EP3321360A2 (fr) 2013-01-03 2018-05-16 Novozymes A/S Variants d'alpha-amylase et polynucléotides les codant
WO2018108865A1 (fr) 2016-12-12 2018-06-21 Novozymes A/S Utilisation de polypeptides
WO2018177203A1 (fr) 2017-03-31 2018-10-04 Novozymes A/S Polypeptides présentant une activité d'adnase
WO2018178061A1 (fr) 2017-03-31 2018-10-04 Novozymes A/S Polypeptides présentant une activité de rnase
WO2018177938A1 (fr) 2017-03-31 2018-10-04 Novozymes A/S Polypeptides présentant une activité dnase
WO2018177936A1 (fr) 2017-03-31 2018-10-04 Novozymes A/S Polypeptides ayant une activité dnase
EP3385362A1 (fr) 2017-04-05 2018-10-10 Henkel AG & Co. KGaA Compositions détergentes comprenant des mannanases fongiques
EP3385361A1 (fr) 2017-04-05 2018-10-10 Henkel AG & Co. KGaA Compositions détergentes comprenant des mannanases bactériennes
WO2018184816A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2018184817A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2018184818A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2018184873A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de détergent et leurs utilisations
WO2018185181A1 (fr) 2017-04-04 2018-10-11 Novozymes A/S Glycosyl hydrolases
WO2018185152A1 (fr) 2017-04-04 2018-10-11 Novozymes A/S Compositions de poypeptides et utilisations associées
WO2018185280A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2018185267A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2018185285A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et utilisations correspondantes
WO2018185150A1 (fr) 2017-04-04 2018-10-11 Novozymes A/S Polypeptides
WO2018185269A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et leurs utilisations
EP3401385A1 (fr) 2017-05-08 2018-11-14 Henkel AG & Co. KGaA Composition détergente comprenant un polypeptide comprenant un domaine de liaison aux glucides
WO2018206535A1 (fr) 2017-05-08 2018-11-15 Novozymes A/S Domaine de liaison aux glucides et polynucléotides codant pour celui-ci
WO2018224544A1 (fr) 2017-06-08 2018-12-13 Novozymes A/S Compositions comprenant des polypeptides ayant une activité cellulase et une activité amylase et leurs utilisations dans des compositions de nettoyage et détergentes
WO2019002356A1 (fr) 2017-06-30 2019-01-03 Novozymes A/S Composition de suspension enzymatique
WO2019038057A1 (fr) 2017-08-24 2019-02-28 Novozymes A/S Variants de la xanthane lyase et polynucléotides codant pour ceux-ci
WO2019038058A1 (fr) 2017-08-24 2019-02-28 Novozymes A/S Variants d'endoglucanase gh9 et polynucléotides codant pour de tels variants
WO2019038059A1 (fr) 2017-08-24 2019-02-28 Henkel Ag & Co. Kgaa Compositions détergentes comprenant des variants ii d'endoglucanase gh9
WO2019038060A1 (fr) 2017-08-24 2019-02-28 Henkel Ag & Co. Kgaa Composition détergente comprenant des variants de xanthane lyase ii
EP3453757A1 (fr) 2013-12-20 2019-03-13 Novozymes A/S Polypeptides a activite de protease et polynucleotides les codant
WO2019057902A1 (fr) 2017-09-22 2019-03-28 Novozymes A/S Nouveaux polypeptides
EP3461881A1 (fr) 2013-05-03 2019-04-03 Novozymes A/S Microencapsulation d'enzymes détergentes
WO2019067390A1 (fr) 2017-09-27 2019-04-04 The Procter & Gamble Company Compositions de détergent contenant des lipases
WO2019068713A1 (fr) 2017-10-02 2019-04-11 Novozymes A/S Polypeptides présentant une activité mannanase et polynucléotides codant pour ces polypeptides
WO2019068715A1 (fr) 2017-10-02 2019-04-11 Novozymes A/S Polypeptides présentant une activité mannanase et polynucléotides codant pour ces polypeptides
WO2019076834A1 (fr) 2017-10-16 2019-04-25 Novozymes A/S Granulés à faible teneur en poussière
WO2019076833A1 (fr) 2017-10-16 2019-04-25 Novozymes A/S Granules libérant une faible quantité poussière
WO2019076800A1 (fr) 2017-10-16 2019-04-25 Novozymes A/S Compositions de nettoyage et leurs utilisations
DE102017125558A1 (de) 2017-11-01 2019-05-02 Henkel Ag & Co. Kgaa Reinigungszusammensetzungen, die dispersine i enthalten
WO2019081724A1 (fr) 2017-10-27 2019-05-02 Novozymes A/S Variants de dnase
WO2019081515A1 (fr) 2017-10-24 2019-05-02 Novozymes A/S Compositions comprenant des polypeptides présentant une activité mannanase
WO2019084350A1 (fr) 2017-10-27 2019-05-02 The Procter & Gamble Company Compositions détergentes comportant des variants polypeptidiques
DE102017125559A1 (de) 2017-11-01 2019-05-02 Henkel Ag & Co. Kgaa Reinigungszusammensetzungen, die dispersine ii enthalten
DE102017125560A1 (de) 2017-11-01 2019-05-02 Henkel Ag & Co. Kgaa Reinigungszusammensetzungen, die dispersine iii enthalten
WO2019086528A1 (fr) 2017-11-01 2019-05-09 Novozymes A/S Polypeptides et compositions comprenant de tels polypeptides
WO2019086530A1 (fr) 2017-11-01 2019-05-09 Novozymes A/S Polypeptides et compositions comprenant de tels polypeptides
WO2019086532A1 (fr) 2017-11-01 2019-05-09 Novozymes A/S Procédés de nettoyage de dispositifs médicaux
WO2019162000A1 (fr) 2018-02-23 2019-08-29 Henkel Ag & Co. Kgaa Composition détergente comprenant des variants d'endoglucanase et de lyase de xanthane
WO2019175240A1 (fr) 2018-03-13 2019-09-19 Novozymes A/S Microencapsulation utilisant des oligomères de sucres aminés
WO2019180111A1 (fr) 2018-03-23 2019-09-26 Novozymes A/S Variants de subtilase et compositions les comprenant
WO2019201783A1 (fr) 2018-04-19 2019-10-24 Novozymes A/S Variants de cellulase stablisés
WO2019201785A1 (fr) 2018-04-19 2019-10-24 Novozymes A/S Variants améliorés de cellulase
WO2019201793A1 (fr) 2018-04-17 2019-10-24 Novozymes A/S Polypeptides ayant une activité de liaison des hydrates de carbone dans des compositions détergentes et leur utilisation pour réduire les plis de textiles ou de tissus
WO2020002255A1 (fr) 2018-06-29 2020-01-02 Novozymes A/S Variants de subtilase et compositions les comprenant
WO2020002604A1 (fr) 2018-06-28 2020-01-02 Novozymes A/S Compositions détergentes et leurs utilisations
WO2020002608A1 (fr) 2018-06-29 2020-01-02 Novozymes A/S Compositions détergentes et leurs utilisations
WO2020007875A1 (fr) 2018-07-03 2020-01-09 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2020007863A1 (fr) 2018-07-02 2020-01-09 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2020008024A1 (fr) 2018-07-06 2020-01-09 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2020008043A1 (fr) 2018-07-06 2020-01-09 Novozymes A/S Compositions de nettoyage et leurs utilisations
EP3608403A2 (fr) 2014-12-15 2020-02-12 Henkel AG & Co. KGaA Composition détergente comprenant des variantes de subtilase
EP3611260A1 (fr) 2013-07-29 2020-02-19 Novozymes A/S Variants de protéase et polynucléotides les codants
WO2020070063A2 (fr) 2018-10-01 2020-04-09 Novozymes A/S Compositions détergentes et leurs utilisations
WO2020070249A1 (fr) 2018-10-03 2020-04-09 Novozymes A/S Compositions de nettoyage
WO2020070011A1 (fr) 2018-10-02 2020-04-09 Novozymes A/S Composition de nettoyage
WO2020070209A1 (fr) 2018-10-02 2020-04-09 Novozymes A/S Composition de nettoyage
WO2020070199A1 (fr) 2018-10-03 2020-04-09 Novozymes A/S Polypeptides ayant une activité de dégradation de l'alpha-mannane et polynucléotides codant pour ceux-ci
WO2020070014A1 (fr) 2018-10-02 2020-04-09 Novozymes A/S Composition de nettoyage comprenant un tensioactif anionique et un polypeptide ayant une activité rnase
WO2020074499A1 (fr) 2018-10-09 2020-04-16 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2020074498A1 (fr) 2018-10-09 2020-04-16 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2020074545A1 (fr) 2018-10-11 2020-04-16 Novozymes A/S Compositions de nettoyage et leurs utilisations
EP3647398A1 (fr) 2018-10-31 2020-05-06 Henkel AG & Co. KGaA Compositions de nettoyage contenant des dispersines v
EP3647397A1 (fr) 2018-10-31 2020-05-06 Henkel AG & Co. KGaA Compositions de nettoyage contenant des dispersions iv
WO2020114965A1 (fr) 2018-12-03 2020-06-11 Novozymes A/S Composition détergente en poudre de faible ph
WO2020114968A1 (fr) 2018-12-03 2020-06-11 Novozymes A/S Composition de détergent en poudre
WO2020127796A2 (fr) 2018-12-21 2020-06-25 Novozymes A/S Polypeptides ayant une activité de dégradation de peptidoglycane et polynucléotides codant pour ceux-ci
WO2020127775A1 (fr) 2018-12-21 2020-06-25 Novozymes A/S Sachet de détergent comprenant des métalloprotéases
EP3690037A1 (fr) 2014-12-04 2020-08-05 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
EP3702452A1 (fr) 2019-03-01 2020-09-02 Novozymes A/S Compositions détergentes comprenant deux protéases
EP3708660A2 (fr) 2015-10-07 2020-09-16 Novozymes A/S Polypeptides
WO2020188095A1 (fr) 2019-03-21 2020-09-24 Novozymes A/S Variants d'alpha-amylase et polynucléotides codant pour ceux-ci
EP3715442A1 (fr) 2016-03-23 2020-09-30 Novozymes A/S Utilisation d'un polypeptide ayant une activité dnase pour le traitement de tissus
WO2020201403A1 (fr) 2019-04-03 2020-10-08 Novozymes A/S Polypeptides ayant une activité bêta-glucanase, polynucléotides codant pour celles-ci et leur utilisation dans des compositions nettoyantes et détergentes
EP3722406A1 (fr) 2014-04-11 2020-10-14 Novozymes A/S Composition de détergent
WO2020208056A1 (fr) 2019-04-12 2020-10-15 Novozymes A/S Variants stabilisés d'un glycoside hydrolase
WO2020207944A1 (fr) 2019-04-10 2020-10-15 Novozymes A/S Variants polypeptidiques
EP3739029A1 (fr) 2014-07-04 2020-11-18 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
EP3741848A2 (fr) 2014-12-19 2020-11-25 Novozymes A/S Variantes de protéases et polynucléotides les codant
EP3741849A2 (fr) 2014-12-19 2020-11-25 Novozymes A/S Variantes de protéases et polynucléotides les codant
WO2021009067A1 (fr) 2019-07-12 2021-01-21 Novozymes A/S Émulsions enzymatiques pour détergents
EP3786269A1 (fr) 2013-06-06 2021-03-03 Novozymes A/S Variants d'alpha-amylase et polynucléotides les codant
WO2021037895A1 (fr) 2019-08-27 2021-03-04 Novozymes A/S Composition détergente
WO2021053127A1 (fr) 2019-09-19 2021-03-25 Novozymes A/S Composition détergente
WO2021064068A1 (fr) 2019-10-03 2021-04-08 Novozymes A/S Polypeptides comprenant au moins deux domaines de liaison aux hydrates de carbone
WO2021122117A1 (fr) 2019-12-20 2021-06-24 Henkel Ag & Co. Kgaa Composition de nettoyage comprenant une dispersine et une carbohydrase
WO2021122120A2 (fr) 2019-12-20 2021-06-24 Henkel Ag & Co. Kgaa Compositions de nettoyage comprenant des dispersines viii
WO2021123307A2 (fr) 2019-12-20 2021-06-24 Novozymes A/S Polypeptides présentant une activité protéolytique et leur utilisation
WO2021121394A1 (fr) 2019-12-20 2021-06-24 Novozymes A/S Compositions enzymatiques liquides stabilisées exemptes de bore
WO2021122118A1 (fr) 2019-12-20 2021-06-24 Henkel Ag & Co. Kgaa Compositions de nettoyage comprenant des dispersines vi
WO2021122121A1 (fr) 2019-12-20 2021-06-24 Henkel Ag & Co. Kgaa Compositions de nettoyage comprenant des dispersines ix
WO2021130167A1 (fr) 2019-12-23 2021-07-01 Novozymes A/S Compositions enzymatiques et utilisations associées
WO2021148364A1 (fr) 2020-01-23 2021-07-29 Novozymes A/S Compositions enzymatiques et leurs utilisations
WO2021152120A1 (fr) 2020-01-31 2021-08-05 Novozymes A/S Variants de mannanase et polynucléotides codant pour ceux-ci
DE102020201317A1 (de) 2020-02-04 2021-08-05 Henkel Ag & Co. Kgaa Chitosanderivate als schmutzablösevermögende Wirkstoffe
WO2021152123A1 (fr) 2020-01-31 2021-08-05 Novozymes A/S Variants de mannanase et polynucléotides codant pour ceux-ci
EP3872175A1 (fr) 2015-06-18 2021-09-01 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
EP3878960A1 (fr) 2014-07-04 2021-09-15 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
EP3892708A1 (fr) 2020-04-06 2021-10-13 Henkel AG & Co. KGaA Compositions de nettoyage comprenant des variantes de dispersine
WO2021204838A1 (fr) 2020-04-08 2021-10-14 Novozymes A/S Variants de module de liaison d'hydrate de carbone
WO2021214059A1 (fr) 2020-04-21 2021-10-28 Novozymes A/S Compositions de nettoyage comprenant des polypeptides ayant une activité de dégradation de fructane
WO2021239818A1 (fr) 2020-05-26 2021-12-02 Novozymes A/S Variants de subtilase et compositions les comprenant
EP3936593A1 (fr) 2020-07-08 2022-01-12 Henkel AG & Co. KGaA Compositions de nettoyage et leurs utilisations
EP3957711A2 (fr) 2015-10-28 2022-02-23 Novozymes A/S Composition de détergent comprenant des variants de protéase et d'amylase
WO2022043563A1 (fr) 2020-08-28 2022-03-03 Novozymes A/S Variants de protéase dégradant le polyester
WO2022043321A2 (fr) 2020-08-25 2022-03-03 Novozymes A/S Variants de xyloglucanase de la famille 44
WO2022074037A2 (fr) 2020-10-07 2022-04-14 Novozymes A/S Variants d'alpha-amylase
WO2022084303A2 (fr) 2020-10-20 2022-04-28 Novozymes A/S Utilisation de polypeptides ayant une activité de dnase
EP4032966A1 (fr) 2021-01-22 2022-07-27 Novozymes A/S Composition enzymatique liquide avec piégeur de sulfite
EP4039806A1 (fr) 2021-02-04 2022-08-10 Henkel AG & Co. KGaA Composition détergente comprenant des variants de xanthane lyase et d'endoglucanase à stabilité améliorée
WO2022171872A1 (fr) 2021-02-12 2022-08-18 Novozymes A/S Détergents biologiques stabilisés
WO2022171780A2 (fr) 2021-02-12 2022-08-18 Novozymes A/S Variants d'alpha-amylase
US11441140B2 (en) 2015-12-07 2022-09-13 Henkel Ag & Co. Kgaa Dishwashing compositions comprising polypeptides having beta-glucanase activity and uses thereof
WO2022189521A1 (fr) 2021-03-12 2022-09-15 Novozymes A/S Variants polypeptidiques
EP4060036A1 (fr) 2021-03-15 2022-09-21 Novozymes A/S Variantes de polypeptides
WO2022194673A1 (fr) 2021-03-15 2022-09-22 Novozymes A/S Variants de la dnase
WO2022268885A1 (fr) 2021-06-23 2022-12-29 Novozymes A/S Polypeptides d'alpha-amylase
WO2023061928A1 (fr) 2021-10-12 2023-04-20 Novozymes A/S Endoglucanase à stabilité améliorée
EP4206309A1 (fr) 2021-12-30 2023-07-05 Novozymes A/S Particules de protéines à blancheur améliorée
WO2023165950A1 (fr) 2022-03-04 2023-09-07 Novozymes A/S Variants de dnase et compositions
WO2023194204A1 (fr) 2022-04-08 2023-10-12 Novozymes A/S Variants et compositions d'hexosaminidase
WO2023247348A1 (fr) 2022-06-21 2023-12-28 Novozymes A/S Variants de mannanase et polynucléotides codant pour ceux-ci
EP4324919A2 (fr) 2015-10-14 2024-02-21 Novozymes A/S Variants polypeptidiques
EP4339282A2 (fr) 2014-12-04 2024-03-20 Novozymes A/S Compositions de nettoyage liquides comprenant des variants de protéase
WO2024083819A1 (fr) 2022-10-20 2024-04-25 Novozymes A/S Agents d'élimination de lipides pour détergents
WO2024110541A1 (fr) 2022-11-22 2024-05-30 Novozymes A/S Granulés colorés ayant une stabilité de colorant améliorée
WO2024121070A1 (fr) 2022-12-05 2024-06-13 Novozymes A/S Variants de protéase et polynucléotides codant pour ceux-ci
WO2024131880A2 (fr) 2022-12-23 2024-06-27 Novozymes A/S Composition détergente comprenant une catalase et une amylase
WO2024213513A1 (fr) 2023-04-12 2024-10-17 Novozymes A/S Compositions comprenant des polypeptides ayant une activité de phosphatase alcaline
EP4461796A1 (fr) 2023-05-10 2024-11-13 Novozymes A/S Composition detergente comprenant une laccase
EP4461795A1 (fr) 2023-05-10 2024-11-13 Novozymes A/S Composition detergente comprenant une laccase
WO2025011933A1 (fr) 2023-07-07 2025-01-16 Novozymes A/S Procédé de lavage pour éliminer des taches protéiques
WO2025153046A1 (fr) 2024-01-19 2025-07-24 Novozymes A/S Compositions détergentes et leurs utilisations
WO2025257254A1 (fr) 2024-06-12 2025-12-18 Novozymes A/S Lipases et variants de lipase et leur utilisation

Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB846217A (en) * 1957-11-22 1960-08-31 Mo Och Domsjoe Ab Detergent compositions
US3756966A (en) * 1971-09-28 1973-09-04 Lever Brothers Ltd Compositions sulfosuccinate derivatives of carbohydrates as builders for detergent
US4020015A (en) * 1971-10-12 1977-04-26 Lever Brothers Company Detergent compositions
GB1537287A (en) * 1975-04-02 1978-12-29 Procter & Gamble Detergent composition
US4235735A (en) * 1979-07-30 1980-11-25 Milliken Research Corporation Laundry detergent containing cellulose acetate anti-redeposition agent
EP0054325A1 (fr) * 1980-12-17 1982-06-23 Unilever N.V. Composition détergente ayant des propriétés empêchant le redépôt
EP0213729A1 (fr) * 1985-07-29 1987-03-11 Unilever Plc Compositions détergentes
WO1999014245A1 (fr) * 1997-09-15 1999-03-25 The Procter & Gamble Company Compositions de detergent a lessive comportant des polymeres cellulosiques qui conferent un aspect et une integrite avantageux aux tissus laves a l'aide de celles-ci
WO2000018861A1 (fr) * 1998-09-30 2000-04-06 Unilever Plc Traitement pour substrats
WO2000040684A1 (fr) * 1999-01-05 2000-07-13 Unilever Plc Traitement pour textiles
WO2000042144A1 (fr) * 1999-01-13 2000-07-20 The Procter & Gamble Company Compositions detergentes contenant un polymere de cellulose
WO2000065015A2 (fr) * 1999-04-27 2000-11-02 The Procter & Gamble Company Compositions traitante pour surfaces et procede associe

Family Cites Families (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB320842A (en) 1928-04-18 1929-10-18 Henry Dreyfus The manufacture and treatment of cellulose derivatives
FR702116A (fr) 1929-08-02 1931-03-30 Kodak Pathe Soc Procédé de fabrication d'esters mixtes de cellulose
US3303051A (en) 1963-04-05 1967-02-07 United Merchants & Mfg Process of conditioning cellulose acetate with hydroxyethylcellulose
GB1243785A (en) 1967-10-12 1971-08-25 De La Rue Instr Improvements in sheet counting apparatus
GB1437950A (en) 1972-08-22 1976-06-03 Unilever Ltd Detergent compositions
AT330930B (de) 1973-04-13 1976-07-26 Henkel & Cie Gmbh Verfahren zur herstellung von festen, schuttfahigen wasch- oder reinigungsmitteln mit einem gehalt an calcium bindenden substanzen
US4605509A (en) 1973-05-11 1986-08-12 The Procter & Gamble Company Detergent compositions containing sodium aluminosilicate builders
DE2433485A1 (de) 1973-07-16 1975-02-06 Procter & Gamble Zur verwendung in waschmitteln geeignete aluminosilikat-ionenaustauscher
GB1567947A (en) 1976-07-02 1980-05-21 Unilever Ltd Esters of quaternised amino-alcohols for treating fabrics
ES523135A0 (es) 1982-06-10 1985-03-01 Kao Corp Un procedimiento para la preparacion de percarborato sodico recubierto con un borato.
DE3413571A1 (de) 1984-04-11 1985-10-24 Hoechst Ag, 6230 Frankfurt Verwendung von kristallinen schichtfoermigen natriumsilikaten zur wasserenthaertung und verfahren zur wasserenthaertung
US4686063A (en) 1986-09-12 1987-08-11 The Procter & Gamble Company Fatty peroxyacids or salts thereof having amide moieties in the fatty chain and low levels of exotherm control agents
US4818426A (en) 1987-03-17 1989-04-04 Lever Brothers Company Quaternary ammonium or phosphonium substituted peroxy carbonic acid precursors and their use in detergent bleach compositions
US4751015A (en) 1987-03-17 1988-06-14 Lever Brothers Company Quaternary ammonium or phosphonium substituted peroxy carbonic acid precursors and their use in detergent bleach compositions
US4933103A (en) 1987-03-23 1990-06-12 Kao Corporation Bleaching composition
US4915863A (en) 1987-08-14 1990-04-10 Kao Corporation Bleaching composition
IT1215739B (it) 1988-01-20 1990-02-22 Ausimont Spa Perossiacidi immido aromatici come agenti sbiancanti.
IT1233846B (it) 1988-01-20 1992-04-21 Ausimont Spa Perossiacidi immido aromatici
GB8810193D0 (en) 1988-04-29 1988-06-02 Unilever Plc Detergent compositions & process for preparing them
DE3823172C2 (de) 1988-07-08 1998-01-22 Hoechst Ag omega-Phthalimidoperoxihexansäure, Verfahren zu dessen Herstellung und dessen Verwendung
DE68925938T2 (de) 1988-11-02 1996-08-08 Unilever Nv Verfahren zur Herstellung einer körnigen Reinigungsmittelzusammensetzung mit hoher Schüttdichte
CA2001927C (fr) 1988-11-03 1999-12-21 Graham Thomas Brown Aluminosilicates et detergents
GB8907187D0 (en) 1989-03-30 1989-05-10 Unilever Plc Detergent compositions and process for preparing them
US4988451A (en) 1989-06-14 1991-01-29 Lever Brothers Company, Division Of Conopco, Inc. Stabilization of particles containing quaternary ammonium bleach precursors
GB8922018D0 (en) 1989-09-29 1989-11-15 Unilever Plc Detergent compositions and process for preparing them
US5142034A (en) 1990-04-16 1992-08-25 Eastman Kodak Company Cellulose ester compositions and process for the preparation thereof
EP0458397B1 (fr) 1990-05-21 1997-03-26 Unilever N.V. Activation du blanchiment
GB9108136D0 (en) 1991-04-17 1991-06-05 Unilever Plc Concentrated detergent powder compositions
US5397501A (en) 1993-07-26 1995-03-14 Lever Brothers Company, Division Of Conopco, Inc. Amido peroxycarboxylic acids for bleaching
US6004923A (en) * 1995-10-27 1999-12-21 Basf Aktiengesellschaft Fatty acid derivatives and their use as surfactants in detergents and cleaners
ES2203830T3 (es) 1996-12-26 2004-04-16 THE PROCTER & GAMBLE COMPANY Composiciones de detergentes para colada con polimeros celulosicos para impartir mejoras en la apariencia e integridad a tejidos lavados con las mismas.
DE19740558C2 (de) 1997-09-15 2003-01-09 Siemens Ag Verfahren zum Übertragen von "MWI-Dienst"-spezifischen Nachrichten in Telekommunikationsnetzen, insbesondere in hybriden DECT/ISDN-spezifischen Telekommunikationsnetzen
GB9821218D0 (en) 1998-09-30 1998-11-25 Unilever Plc Treatment for fabrics
GB9900151D0 (en) 1999-01-05 1999-02-24 Unilever Plc Treatment for fabrics
GB0117768D0 (en) * 2001-07-20 2001-09-12 Unilever Plc Use of polymers in fabrics cleaning

Patent Citations (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB846217A (en) * 1957-11-22 1960-08-31 Mo Och Domsjoe Ab Detergent compositions
US3756966A (en) * 1971-09-28 1973-09-04 Lever Brothers Ltd Compositions sulfosuccinate derivatives of carbohydrates as builders for detergent
US4020015A (en) * 1971-10-12 1977-04-26 Lever Brothers Company Detergent compositions
GB1537287A (en) * 1975-04-02 1978-12-29 Procter & Gamble Detergent composition
US4235735A (en) * 1979-07-30 1980-11-25 Milliken Research Corporation Laundry detergent containing cellulose acetate anti-redeposition agent
EP0054325A1 (fr) * 1980-12-17 1982-06-23 Unilever N.V. Composition détergente ayant des propriétés empêchant le redépôt
EP0213729A1 (fr) * 1985-07-29 1987-03-11 Unilever Plc Compositions détergentes
WO1999014245A1 (fr) * 1997-09-15 1999-03-25 The Procter & Gamble Company Compositions de detergent a lessive comportant des polymeres cellulosiques qui conferent un aspect et une integrite avantageux aux tissus laves a l'aide de celles-ci
WO2000018861A1 (fr) * 1998-09-30 2000-04-06 Unilever Plc Traitement pour substrats
WO2000040684A1 (fr) * 1999-01-05 2000-07-13 Unilever Plc Traitement pour textiles
WO2000042144A1 (fr) * 1999-01-13 2000-07-20 The Procter & Gamble Company Compositions detergentes contenant un polymere de cellulose
WO2000065015A2 (fr) * 1999-04-27 2000-11-02 The Procter & Gamble Company Compositions traitante pour surfaces et procede associe

Cited By (255)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1770157A1 (fr) * 2003-06-16 2007-04-04 Unilever Plc Compositions pour la traitement de lavage
WO2004111169A1 (fr) * 2003-06-16 2004-12-23 Unilever Plc Composition de traitement de blanchisserie
CN100390257C (zh) * 2003-06-16 2008-05-28 荷兰联合利华有限公司 洗衣处理组合物
US7528101B2 (en) 2003-06-16 2009-05-05 Conopco, Inc. Laundry treatment compositions
US7967871B2 (en) 2005-04-29 2011-06-28 The Sun Products Corporation Polymers for laundry applications
WO2006117056A1 (fr) * 2005-04-29 2006-11-09 Unilever Plc Polymeres pour la lessive
WO2006117071A1 (fr) * 2005-04-29 2006-11-09 Unilever Plc Polymeres pour applications de blanchisserie
EP1937403A4 (fr) * 2005-08-31 2013-05-15 Ge Healthcare Bio Sciences Ab Fabrication de matrices pour chromatographie
US8858800B2 (en) 2005-08-31 2014-10-14 Ge Healthcare Bio-Sciences Ab Manufacture of chromatography matrices
WO2007049249A1 (fr) 2005-10-28 2007-05-03 The Procter & Gamble Company Compositions contenant du catechol modifie anioniquement et des polymeres qui favorisent la suspension des saletes
WO2007144855A1 (fr) * 2006-06-16 2007-12-21 The Procter & Gamble Company Compositions de détergent
EP1867708A1 (fr) * 2006-06-16 2007-12-19 The Procter and Gamble Company Compositions de lavage
US9376648B2 (en) 2008-04-07 2016-06-28 The Procter & Gamble Company Foam manipulation compositions containing fine particles
WO2010105943A1 (fr) 2009-03-20 2010-09-23 Henkel Ag & Co. Kgaa Utilisation de polymères à groupes carboxyle, en combinaison avec des cations bivalents pour la formation d'une couche protectrice
US8206462B2 (en) 2009-03-20 2012-06-26 Henkel Ag & Co. Kgaa Use of polymers comprising carboxyl groups in combination with bivalent cations for creating a protective layer
DE102009001803A1 (de) 2009-03-24 2010-09-30 Henkel Ag & Co. Kgaa Verwendung von Polymeren mit Carboxylgruppen in Kombination mit zweiwertigen Kationen zur Ausbildung einer Schutzschicht
WO2011080267A2 (fr) 2009-12-29 2011-07-07 Novozymes A/S Polypeptides amplifiant la detergence
WO2011104339A1 (fr) 2010-02-25 2011-09-01 Novozymes A/S Variants d'un lysozyme et polynucléotides pour les coder
WO2012035103A1 (fr) 2010-09-16 2012-03-22 Novozymes A/S Lysozymes
WO2012110562A2 (fr) 2011-02-16 2012-08-23 Novozymes A/S Compositions détergentes comprenant des métalloprotéases
WO2012110563A1 (fr) 2011-02-16 2012-08-23 Novozymes A/S Compositions détersives contenant des métalloprotéases
WO2012110564A1 (fr) 2011-02-16 2012-08-23 Novozymes A/S Composition de détergent comprenant des métalloprotéases m7 ou m35
WO2012120304A1 (fr) 2011-03-09 2012-09-13 Reckitt Benckiser N.V. Composition de nettoyage de tapis
WO2012175708A2 (fr) 2011-06-24 2012-12-27 Novozymes A/S Polypeptides ayant une activité de protéase et polynucléotides les codant
EP3543333A2 (fr) 2011-06-30 2019-09-25 Novozymes A/S Procédé de criblage d'alpha-amylases
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WO2013131964A1 (fr) 2012-03-07 2013-09-12 Novozymes A/S Composition détergente et substitution d'azurants optiques dans des compositions détergentes
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WO2014090940A1 (fr) 2012-12-14 2014-06-19 Novozymes A/S Élimination de souillures issues de la peau
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WO2014152674A1 (fr) 2013-03-14 2014-09-25 Novozymes A/S Films solubles dans l'eau contenant des enzymes et des inhibiteurs
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WO2016079305A1 (fr) 2014-11-20 2016-05-26 Novozymes A/S Variants de alicyclobacillus et polynucléotides codant pour ceux-ci
EP3690037A1 (fr) 2014-12-04 2020-08-05 Novozymes A/S Variants de subtilase et polynucléotides codant pour ceux-ci
EP4339282A2 (fr) 2014-12-04 2024-03-20 Novozymes A/S Compositions de nettoyage liquides comprenant des variants de protéase
EP4541886A2 (fr) 2014-12-04 2025-04-23 Novozymes A/S Compositions de nettoyage liquides comprenant des variants de protéase
US10760036B2 (en) 2014-12-15 2020-09-01 Henkel Ag & Co. Kgaa Detergent composition comprising subtilase variants
EP3608403A2 (fr) 2014-12-15 2020-02-12 Henkel AG & Co. KGaA Composition détergente comprenant des variantes de subtilase
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WO2016162556A1 (fr) 2015-04-10 2016-10-13 Novozymes A/S Procédé de lavage de linge, utilisation d'adnase et composition détergente
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WO2016135351A1 (fr) 2015-06-30 2016-09-01 Novozymes A/S Composition de détergent de lavage du linge, procédé de lavage et utilisation de la composition
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US11441140B2 (en) 2015-12-07 2022-09-13 Henkel Ag & Co. Kgaa Dishwashing compositions comprising polypeptides having beta-glucanase activity and uses thereof
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EP3950941A2 (fr) 2016-07-13 2022-02-09 Novozymes A/S Variants polypeptidiques de la dnase
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WO2018037061A1 (fr) 2016-08-24 2018-03-01 Novozymes A/S Variants de lyase xanthan et polynucléotides codant pour ces variants
WO2018060475A1 (fr) 2016-09-29 2018-04-05 Novozymes A/S Granule contenant des spores
WO2018077938A1 (fr) 2016-10-25 2018-05-03 Novozymes A/S Compositions détergentes
WO2018083093A1 (fr) 2016-11-01 2018-05-11 Novozymes A/S Granules à noyaux multiples
WO2018108865A1 (fr) 2016-12-12 2018-06-21 Novozymes A/S Utilisation de polypeptides
WO2018177936A1 (fr) 2017-03-31 2018-10-04 Novozymes A/S Polypeptides ayant une activité dnase
WO2018177203A1 (fr) 2017-03-31 2018-10-04 Novozymes A/S Polypeptides présentant une activité d'adnase
WO2018178061A1 (fr) 2017-03-31 2018-10-04 Novozymes A/S Polypeptides présentant une activité de rnase
WO2018177938A1 (fr) 2017-03-31 2018-10-04 Novozymes A/S Polypeptides présentant une activité dnase
WO2018185152A1 (fr) 2017-04-04 2018-10-11 Novozymes A/S Compositions de poypeptides et utilisations associées
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WO2018184767A1 (fr) 2017-04-05 2018-10-11 Henkel Ag & Co. Kgaa Compositions détergentes comprenant des mannanases bactériennes
WO2018185267A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et leurs utilisations
EP3626809A1 (fr) 2017-04-06 2020-03-25 Novozymes A/S Compositions détergentes et leurs utilisations
WO2018185285A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et utilisations correspondantes
WO2018185280A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2018185269A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2018184873A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de détergent et leurs utilisations
EP3967756A1 (fr) 2017-04-06 2022-03-16 Novozymes A/S Compositions détergentes et leurs utilisations
WO2018184818A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2018184817A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2018184816A1 (fr) 2017-04-06 2018-10-11 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2018206535A1 (fr) 2017-05-08 2018-11-15 Novozymes A/S Domaine de liaison aux glucides et polynucléotides codant pour celui-ci
WO2018206178A1 (fr) 2017-05-08 2018-11-15 Henkel Ag & Co. Kgaa Composition détergente qui contient un polypeptide comprenant un domaine de liaison aux hydrates de carbone
EP3401385A1 (fr) 2017-05-08 2018-11-14 Henkel AG & Co. KGaA Composition détergente comprenant un polypeptide comprenant un domaine de liaison aux glucides
WO2018224544A1 (fr) 2017-06-08 2018-12-13 Novozymes A/S Compositions comprenant des polypeptides ayant une activité cellulase et une activité amylase et leurs utilisations dans des compositions de nettoyage et détergentes
WO2019002356A1 (fr) 2017-06-30 2019-01-03 Novozymes A/S Composition de suspension enzymatique
WO2019038057A1 (fr) 2017-08-24 2019-02-28 Novozymes A/S Variants de la xanthane lyase et polynucléotides codant pour ceux-ci
WO2019038058A1 (fr) 2017-08-24 2019-02-28 Novozymes A/S Variants d'endoglucanase gh9 et polynucléotides codant pour de tels variants
WO2019038059A1 (fr) 2017-08-24 2019-02-28 Henkel Ag & Co. Kgaa Compositions détergentes comprenant des variants ii d'endoglucanase gh9
WO2019038060A1 (fr) 2017-08-24 2019-02-28 Henkel Ag & Co. Kgaa Composition détergente comprenant des variants de xanthane lyase ii
WO2019057902A1 (fr) 2017-09-22 2019-03-28 Novozymes A/S Nouveaux polypeptides
WO2019067390A1 (fr) 2017-09-27 2019-04-04 The Procter & Gamble Company Compositions de détergent contenant des lipases
WO2019068713A1 (fr) 2017-10-02 2019-04-11 Novozymes A/S Polypeptides présentant une activité mannanase et polynucléotides codant pour ces polypeptides
WO2019068715A1 (fr) 2017-10-02 2019-04-11 Novozymes A/S Polypeptides présentant une activité mannanase et polynucléotides codant pour ces polypeptides
WO2019076833A1 (fr) 2017-10-16 2019-04-25 Novozymes A/S Granules libérant une faible quantité poussière
WO2019076800A1 (fr) 2017-10-16 2019-04-25 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2019076834A1 (fr) 2017-10-16 2019-04-25 Novozymes A/S Granulés à faible teneur en poussière
WO2019081515A1 (fr) 2017-10-24 2019-05-02 Novozymes A/S Compositions comprenant des polypeptides présentant une activité mannanase
WO2019084349A1 (fr) 2017-10-27 2019-05-02 The Procter & Gamble Company Compositions détergentes comprenant des variants polypeptidiques
WO2019081724A1 (fr) 2017-10-27 2019-05-02 Novozymes A/S Variants de dnase
WO2019081721A1 (fr) 2017-10-27 2019-05-02 Novozymes A/S Variants de la dnase
WO2019084350A1 (fr) 2017-10-27 2019-05-02 The Procter & Gamble Company Compositions détergentes comportant des variants polypeptidiques
WO2019086521A1 (fr) 2017-11-01 2019-05-09 Henkel Ag & Co. Kgaa Compositions de nettoyage contenant des dispersines ii
EP4379029A1 (fr) 2017-11-01 2024-06-05 Novozymes A/S Polypeptides et compositions comprenant de tels polypeptides
DE102017125558A1 (de) 2017-11-01 2019-05-02 Henkel Ag & Co. Kgaa Reinigungszusammensetzungen, die dispersine i enthalten
DE102017125559A1 (de) 2017-11-01 2019-05-02 Henkel Ag & Co. Kgaa Reinigungszusammensetzungen, die dispersine ii enthalten
DE102017125560A1 (de) 2017-11-01 2019-05-02 Henkel Ag & Co. Kgaa Reinigungszusammensetzungen, die dispersine iii enthalten
WO2019086532A1 (fr) 2017-11-01 2019-05-09 Novozymes A/S Procédés de nettoyage de dispositifs médicaux
US12291696B2 (en) 2017-11-01 2025-05-06 Henkel Ag & Co. Kgaa Cleaning compositions containing Dispersins III
WO2019086530A1 (fr) 2017-11-01 2019-05-09 Novozymes A/S Polypeptides et compositions comprenant de tels polypeptides
WO2019086528A1 (fr) 2017-11-01 2019-05-09 Novozymes A/S Polypeptides et compositions comprenant de tels polypeptides
WO2019086520A1 (fr) 2017-11-01 2019-05-09 Henkel Ag & Co. Kgaa Compositions de nettoyage contenant des dispersines i
WO2019086526A1 (fr) 2017-11-01 2019-05-09 Henkel Ag & Co. Kgaa Compositions de nettoyage contenant des dispersines iii
WO2019162000A1 (fr) 2018-02-23 2019-08-29 Henkel Ag & Co. Kgaa Composition détergente comprenant des variants d'endoglucanase et de lyase de xanthane
WO2019175240A1 (fr) 2018-03-13 2019-09-19 Novozymes A/S Microencapsulation utilisant des oligomères de sucres aminés
WO2019180111A1 (fr) 2018-03-23 2019-09-26 Novozymes A/S Variants de subtilase et compositions les comprenant
WO2019201793A1 (fr) 2018-04-17 2019-10-24 Novozymes A/S Polypeptides ayant une activité de liaison des hydrates de carbone dans des compositions détergentes et leur utilisation pour réduire les plis de textiles ou de tissus
WO2019201785A1 (fr) 2018-04-19 2019-10-24 Novozymes A/S Variants améliorés de cellulase
WO2019201783A1 (fr) 2018-04-19 2019-10-24 Novozymes A/S Variants de cellulase stablisés
WO2020002604A1 (fr) 2018-06-28 2020-01-02 Novozymes A/S Compositions détergentes et leurs utilisations
WO2020002255A1 (fr) 2018-06-29 2020-01-02 Novozymes A/S Variants de subtilase et compositions les comprenant
WO2020002608A1 (fr) 2018-06-29 2020-01-02 Novozymes A/S Compositions détergentes et leurs utilisations
WO2020007863A1 (fr) 2018-07-02 2020-01-09 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2020007875A1 (fr) 2018-07-03 2020-01-09 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2020008024A1 (fr) 2018-07-06 2020-01-09 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2020008043A1 (fr) 2018-07-06 2020-01-09 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2020070063A2 (fr) 2018-10-01 2020-04-09 Novozymes A/S Compositions détergentes et leurs utilisations
WO2020070011A1 (fr) 2018-10-02 2020-04-09 Novozymes A/S Composition de nettoyage
WO2020070209A1 (fr) 2018-10-02 2020-04-09 Novozymes A/S Composition de nettoyage
WO2020070014A1 (fr) 2018-10-02 2020-04-09 Novozymes A/S Composition de nettoyage comprenant un tensioactif anionique et un polypeptide ayant une activité rnase
WO2020070199A1 (fr) 2018-10-03 2020-04-09 Novozymes A/S Polypeptides ayant une activité de dégradation de l'alpha-mannane et polynucléotides codant pour ceux-ci
WO2020070249A1 (fr) 2018-10-03 2020-04-09 Novozymes A/S Compositions de nettoyage
WO2020074499A1 (fr) 2018-10-09 2020-04-16 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2020074498A1 (fr) 2018-10-09 2020-04-16 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2020074545A1 (fr) 2018-10-11 2020-04-16 Novozymes A/S Compositions de nettoyage et leurs utilisations
WO2020088958A1 (fr) 2018-10-31 2020-05-07 Henkel Ag & Co. Kgaa Compositions de nettoyage contenant des dispersines v
EP3647398A1 (fr) 2018-10-31 2020-05-06 Henkel AG & Co. KGaA Compositions de nettoyage contenant des dispersines v
EP3647397A1 (fr) 2018-10-31 2020-05-06 Henkel AG & Co. KGaA Compositions de nettoyage contenant des dispersions iv
WO2020088957A1 (fr) 2018-10-31 2020-05-07 Henkel Ag & Co. Kgaa Compositions de nettoyage contenant des dispersines iv
WO2020114968A1 (fr) 2018-12-03 2020-06-11 Novozymes A/S Composition de détergent en poudre
WO2020114965A1 (fr) 2018-12-03 2020-06-11 Novozymes A/S Composition détergente en poudre de faible ph
WO2020127796A2 (fr) 2018-12-21 2020-06-25 Novozymes A/S Polypeptides ayant une activité de dégradation de peptidoglycane et polynucléotides codant pour ceux-ci
WO2020127775A1 (fr) 2018-12-21 2020-06-25 Novozymes A/S Sachet de détergent comprenant des métalloprotéases
EP3702452A1 (fr) 2019-03-01 2020-09-02 Novozymes A/S Compositions détergentes comprenant deux protéases
WO2020178102A1 (fr) 2019-03-01 2020-09-10 Novozymes A/S Compositions détergentes comprenant deux protéases
EP4524225A2 (fr) 2019-03-01 2025-03-19 Novozymes A/S Variants de protéase et compositions détergentes les comprenant
WO2020188095A1 (fr) 2019-03-21 2020-09-24 Novozymes A/S Variants d'alpha-amylase et polynucléotides codant pour ceux-ci
WO2020201403A1 (fr) 2019-04-03 2020-10-08 Novozymes A/S Polypeptides ayant une activité bêta-glucanase, polynucléotides codant pour celles-ci et leur utilisation dans des compositions nettoyantes et détergentes
WO2020207944A1 (fr) 2019-04-10 2020-10-15 Novozymes A/S Variants polypeptidiques
WO2020208056A1 (fr) 2019-04-12 2020-10-15 Novozymes A/S Variants stabilisés d'un glycoside hydrolase
WO2021009067A1 (fr) 2019-07-12 2021-01-21 Novozymes A/S Émulsions enzymatiques pour détergents
WO2021037895A1 (fr) 2019-08-27 2021-03-04 Novozymes A/S Composition détergente
WO2021053127A1 (fr) 2019-09-19 2021-03-25 Novozymes A/S Composition détergente
WO2021064068A1 (fr) 2019-10-03 2021-04-08 Novozymes A/S Polypeptides comprenant au moins deux domaines de liaison aux hydrates de carbone
WO2021123307A2 (fr) 2019-12-20 2021-06-24 Novozymes A/S Polypeptides présentant une activité protéolytique et leur utilisation
WO2021122117A1 (fr) 2019-12-20 2021-06-24 Henkel Ag & Co. Kgaa Composition de nettoyage comprenant une dispersine et une carbohydrase
WO2021122120A2 (fr) 2019-12-20 2021-06-24 Henkel Ag & Co. Kgaa Compositions de nettoyage comprenant des dispersines viii
WO2021122121A1 (fr) 2019-12-20 2021-06-24 Henkel Ag & Co. Kgaa Compositions de nettoyage comprenant des dispersines ix
WO2021122118A1 (fr) 2019-12-20 2021-06-24 Henkel Ag & Co. Kgaa Compositions de nettoyage comprenant des dispersines vi
WO2021121394A1 (fr) 2019-12-20 2021-06-24 Novozymes A/S Compositions enzymatiques liquides stabilisées exemptes de bore
WO2021130167A1 (fr) 2019-12-23 2021-07-01 Novozymes A/S Compositions enzymatiques et utilisations associées
WO2021148364A1 (fr) 2020-01-23 2021-07-29 Novozymes A/S Compositions enzymatiques et leurs utilisations
WO2021152123A1 (fr) 2020-01-31 2021-08-05 Novozymes A/S Variants de mannanase et polynucléotides codant pour ceux-ci
WO2021152120A1 (fr) 2020-01-31 2021-08-05 Novozymes A/S Variants de mannanase et polynucléotides codant pour ceux-ci
DE102020201317A1 (de) 2020-02-04 2021-08-05 Henkel Ag & Co. Kgaa Chitosanderivate als schmutzablösevermögende Wirkstoffe
EP3892708A1 (fr) 2020-04-06 2021-10-13 Henkel AG & Co. KGaA Compositions de nettoyage comprenant des variantes de dispersine
WO2021204838A1 (fr) 2020-04-08 2021-10-14 Novozymes A/S Variants de module de liaison d'hydrate de carbone
WO2021214059A1 (fr) 2020-04-21 2021-10-28 Novozymes A/S Compositions de nettoyage comprenant des polypeptides ayant une activité de dégradation de fructane
WO2021239818A1 (fr) 2020-05-26 2021-12-02 Novozymes A/S Variants de subtilase et compositions les comprenant
EP3936593A1 (fr) 2020-07-08 2022-01-12 Henkel AG & Co. KGaA Compositions de nettoyage et leurs utilisations
WO2022008387A1 (fr) 2020-07-08 2022-01-13 Henkel Ag & Co. Kgaa Compositions de nettoyage et leurs utilisations
EP4656720A2 (fr) 2020-08-25 2025-12-03 Novozymes A/S Variants de xyloglucanase de la famille 44
WO2022043321A2 (fr) 2020-08-25 2022-03-03 Novozymes A/S Variants de xyloglucanase de la famille 44
WO2022043563A1 (fr) 2020-08-28 2022-03-03 Novozymes A/S Variants de protéase dégradant le polyester
WO2022043547A1 (fr) 2020-08-28 2022-03-03 Novozymes A/S Variants de protéase à solubilité améliorée
WO2022074037A2 (fr) 2020-10-07 2022-04-14 Novozymes A/S Variants d'alpha-amylase
WO2022084303A2 (fr) 2020-10-20 2022-04-28 Novozymes A/S Utilisation de polypeptides ayant une activité de dnase
EP4032966A1 (fr) 2021-01-22 2022-07-27 Novozymes A/S Composition enzymatique liquide avec piégeur de sulfite
WO2022157311A1 (fr) 2021-01-22 2022-07-28 Novozymes A/S Composition d'enzyme liquide avec piégeur de sulfite
EP4039806A1 (fr) 2021-02-04 2022-08-10 Henkel AG & Co. KGaA Composition détergente comprenant des variants de xanthane lyase et d'endoglucanase à stabilité améliorée
WO2022167251A1 (fr) 2021-02-04 2022-08-11 Henkel Ag & Co. Kgaa Composition détergente comprenant des variants de xanthane lyase et d'endoglucanase ayant une stabilité améliorée
WO2022171872A1 (fr) 2021-02-12 2022-08-18 Novozymes A/S Détergents biologiques stabilisés
WO2022171780A2 (fr) 2021-02-12 2022-08-18 Novozymes A/S Variants d'alpha-amylase
WO2022189521A1 (fr) 2021-03-12 2022-09-15 Novozymes A/S Variants polypeptidiques
WO2022194673A1 (fr) 2021-03-15 2022-09-22 Novozymes A/S Variants de la dnase
WO2022194668A1 (fr) 2021-03-15 2022-09-22 Novozymes A/S Variants polypeptidiques
EP4060036A1 (fr) 2021-03-15 2022-09-21 Novozymes A/S Variantes de polypeptides
WO2022268885A1 (fr) 2021-06-23 2022-12-29 Novozymes A/S Polypeptides d'alpha-amylase
WO2023061928A1 (fr) 2021-10-12 2023-04-20 Novozymes A/S Endoglucanase à stabilité améliorée
WO2023126254A1 (fr) 2021-12-30 2023-07-06 Novozymes A/S Particules de protéine présentant une blancheur améliorée
EP4206309A1 (fr) 2021-12-30 2023-07-05 Novozymes A/S Particules de protéines à blancheur améliorée
WO2023165950A1 (fr) 2022-03-04 2023-09-07 Novozymes A/S Variants de dnase et compositions
WO2023194204A1 (fr) 2022-04-08 2023-10-12 Novozymes A/S Variants et compositions d'hexosaminidase
WO2023247348A1 (fr) 2022-06-21 2023-12-28 Novozymes A/S Variants de mannanase et polynucléotides codant pour ceux-ci
WO2024083819A1 (fr) 2022-10-20 2024-04-25 Novozymes A/S Agents d'élimination de lipides pour détergents
WO2024110541A1 (fr) 2022-11-22 2024-05-30 Novozymes A/S Granulés colorés ayant une stabilité de colorant améliorée
WO2024121070A1 (fr) 2022-12-05 2024-06-13 Novozymes A/S Variants de protéase et polynucléotides codant pour ceux-ci
WO2024131880A2 (fr) 2022-12-23 2024-06-27 Novozymes A/S Composition détergente comprenant une catalase et une amylase
WO2024213513A1 (fr) 2023-04-12 2024-10-17 Novozymes A/S Compositions comprenant des polypeptides ayant une activité de phosphatase alcaline
EP4461795A1 (fr) 2023-05-10 2024-11-13 Novozymes A/S Composition detergente comprenant une laccase
EP4461796A1 (fr) 2023-05-10 2024-11-13 Novozymes A/S Composition detergente comprenant une laccase
WO2025011933A1 (fr) 2023-07-07 2025-01-16 Novozymes A/S Procédé de lavage pour éliminer des taches protéiques
WO2025153046A1 (fr) 2024-01-19 2025-07-24 Novozymes A/S Compositions détergentes et leurs utilisations
WO2025257254A1 (fr) 2024-06-12 2025-12-18 Novozymes A/S Lipases et variants de lipase et leur utilisation

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EP2330178A3 (fr) 2014-05-14
EP2330178A2 (fr) 2011-06-08
EP1442109A1 (fr) 2004-08-04
GB0127036D0 (en) 2002-01-02
BR0213709A (pt) 2004-10-26
EP1442109B1 (fr) 2018-04-25
ES2675289T3 (es) 2018-07-10

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