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WO2002031905A3 - High performance lithium or lithium ion cell - Google Patents

High performance lithium or lithium ion cell Download PDF

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Publication number
WO2002031905A3
WO2002031905A3 PCT/US2001/030892 US0130892W WO0231905A3 WO 2002031905 A3 WO2002031905 A3 WO 2002031905A3 US 0130892 W US0130892 W US 0130892W WO 0231905 A3 WO0231905 A3 WO 0231905A3
Authority
WO
WIPO (PCT)
Prior art keywords
lithium
ion cell
high performance
lithium ion
micrometers
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2001/030892
Other languages
French (fr)
Other versions
WO2002031905A2 (en
Inventor
Dongli Dai
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
EIDP Inc
Original Assignee
EI Du Pont de Nemours and Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/684,206 external-priority patent/US6699623B1/en
Application filed by EI Du Pont de Nemours and Co filed Critical EI Du Pont de Nemours and Co
Priority to JP2002535189A priority Critical patent/JP2004511887A/en
Priority to KR10-2003-7004840A priority patent/KR20040005831A/en
Priority to AU2002211378A priority patent/AU2002211378A1/en
Priority to EP01979407A priority patent/EP1328996A2/en
Publication of WO2002031905A2 publication Critical patent/WO2002031905A2/en
Publication of WO2002031905A3 publication Critical patent/WO2002031905A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0567—Liquid materials characterised by the additives
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/663—Selection of materials containing carbon or carbonaceous materials as conductive part, e.g. graphite, carbon fibres
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/052—Li-accumulators
    • H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0565—Polymeric materials, e.g. gel-type or solid-type
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
    • H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
    • H01M10/0566—Liquid materials
    • H01M10/0568—Liquid materials characterised by the solutes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/05—Accumulators with non-aqueous electrolyte
    • H01M10/058—Construction or manufacture
    • H01M10/0585—Construction or manufacture of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/131—Electrodes based on mixed oxides or hydroxides, or on mixtures of oxides or hydroxides, e.g. LiCoOx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/13—Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
    • H01M4/133—Electrodes based on carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/64—Carriers or collectors
    • H01M4/66—Selection of materials
    • H01M4/665—Composites
    • H01M4/667—Composites in the form of layers, e.g. coatings
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0017—Non-aqueous electrolytes
    • H01M2300/0025—Organic electrolyte
    • H01M2300/0028—Organic electrolyte characterised by the solvent
    • H01M2300/0037—Mixture of solvents
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/50—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese
    • H01M4/505—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of manganese of mixed oxides or hydroxides containing manganese for inserting or intercalating light metals, e.g. LiMn2O4 or LiMn2OxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/48—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides
    • H01M4/52—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron
    • H01M4/525—Selection of substances as active materials, active masses, active liquids of inorganic oxides or hydroxides of nickel, cobalt or iron of mixed oxides or hydroxides containing iron, cobalt or nickel for inserting or intercalating light metals, e.g. LiNiO2, LiCoO2 or LiCoOxFy
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M4/00—Electrodes
    • H01M4/02—Electrodes composed of, or comprising, active material
    • H01M4/36—Selection of substances as active materials, active masses, active liquids
    • H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
    • H01M4/583—Carbonaceous material, e.g. graphite-intercalation compounds or CFx
    • H01M4/587—Carbonaceous material, e.g. graphite-intercalation compounds or CFx for inserting or intercalating light metals
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/14—Cells with non-aqueous electrolyte
    • H01M6/16—Cells with non-aqueous electrolyte with organic electrolyte
    • H01M6/162—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte
    • H01M6/166—Cells with non-aqueous electrolyte with organic electrolyte characterised by the electrolyte by the solute
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Electrochemistry (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Dispersion Chemistry (AREA)
  • Composite Materials (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)
  • Conductive Materials (AREA)
  • Cell Electrode Carriers And Collectors (AREA)
  • Cell Separators (AREA)

Abstract

Graphite sheeting having a thickness of less than 250 micrometers and in-plane conductivity of at least 100 S/cm when employed as a cathode current collector in a lithium or lithium ion cell containing a fluorinated lithium imide or methide electrolyte salt imparts high thermal resistance, excellent electrochemical stability, and surprisingly high capacity retention at high rates of discharge.
PCT/US2001/030892 2000-10-06 2001-10-03 High performance lithium or lithium ion cell Ceased WO2002031905A2 (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
JP2002535189A JP2004511887A (en) 2000-10-06 2001-10-03 High performance lithium or lithium ion battery
KR10-2003-7004840A KR20040005831A (en) 2000-10-06 2001-10-03 High performance lithium or lithium ion cell
AU2002211378A AU2002211378A1 (en) 2000-10-06 2001-10-03 High performance lithium or lithium ion cell
EP01979407A EP1328996A2 (en) 2000-10-06 2001-10-03 High performance lithium or lithium ion cell

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US09/684,206 US6699623B1 (en) 2000-04-26 2000-10-06 High performance lithium or lithium ion cell
US09/684,206 2000-10-06

Publications (2)

Publication Number Publication Date
WO2002031905A2 WO2002031905A2 (en) 2002-04-18
WO2002031905A3 true WO2002031905A3 (en) 2002-10-03

Family

ID=24747096

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/030892 Ceased WO2002031905A2 (en) 2000-10-06 2001-10-03 High performance lithium or lithium ion cell

Country Status (7)

Country Link
EP (1) EP1328996A2 (en)
JP (2) JP2004511887A (en)
KR (1) KR20040005831A (en)
CN (1) CN1468455A (en)
AU (1) AU2002211378A1 (en)
TW (1) TW550847B (en)
WO (1) WO2002031905A2 (en)

Families Citing this family (32)

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JP4798951B2 (en) * 2004-03-04 2011-10-19 三洋電機株式会社 Non-aqueous electrolyte battery positive electrode and battery using this positive electrode
EP2025023B1 (en) * 2006-04-18 2020-07-15 Commonwealth Scientific And Industrial Research Organisation Flexible energy storage devices
FR2916577B1 (en) * 2007-05-25 2009-11-27 Commissariat Energie Atomique ELECTROLYTIC ORGANIC GLASS, METHOD FOR MANUFACTURING THE SAME, AND DEVICE COMPRISING SAME.
JP2011523765A (en) * 2008-05-29 2011-08-18 ライデン エナジー インコーポレイテッド Electrochemical cell containing ionic liquid electrolyte
US8541117B2 (en) * 2009-11-11 2013-09-24 Blackberry Limited Low noise battery with a magnetic compensation structure for wireless mobile communication device
JP5601474B2 (en) * 2011-02-28 2014-10-08 株式会社Ｇｓユアサ Negative electrode plate for lead acid battery and lead acid battery
CN105761941B (en) * 2011-03-09 2018-07-13 亚奎尼能源公司 Metal-free aqueous electrolyte energy storage device
US8298701B2 (en) 2011-03-09 2012-10-30 Aquion Energy Inc. Aqueous electrolyte energy storage device
JP5303057B2 (en) * 2011-10-27 2013-10-02 株式会社神戸製鋼所 Current collector, electrode and secondary battery
FR2988225B1 (en) * 2012-03-13 2014-03-28 Hutchinson ANODE FOR LITHIUM-ION BATTERY CELL, METHOD FOR MANUFACTURING SAME, AND BATTERY INCORPORATING SAME
JP6517787B2 (en) * 2013-06-05 2019-05-22 ジョンソン、マッセイ、パブリック、リミテッド、カンパニーＪｏｈｎｓｏｎ Ｍａｔｔｈｅｙ Ｐｕｂｌｉｃ Ｌｉｍｉｔｅｄ Ｃｏｍｐａｎｙ Method of preparing lithium titanium spinel and use thereof
DE112014004442T5 (en) 2013-09-25 2016-06-23 The University Of Tokyo Non-aqueous electrolyte secondary battery
JP5817007B1 (en) * 2013-09-25 2015-11-18 国立大学法人 東京大学 Non-aqueous secondary battery
JP5816998B2 (en) * 2013-09-25 2015-11-18 国立大学法人 東京大学 Electrolytic solution containing a salt having alkali metal, alkaline earth metal or aluminum as a cation and an organic solvent having a hetero element
JP5817005B2 (en) * 2013-09-25 2015-11-18 国立大学法人 東京大学 Non-aqueous secondary battery
WO2015045389A1 (en) * 2013-09-25 2015-04-02 国立大学法人東京大学 Electrolyte solution for electricity storage devices such as batteries and capacitors containing salt, wherein alkali metal, alkaline earth metal or aluminum serves as cations, and organic solvent having hetero element, method for producing same, and capacitor provided with said electrolyte solution
EP3051620A4 (en) * 2013-09-25 2017-04-05 The University of Tokyo Electrolyte solution for electricity storage devices such as batteries and capacitors containing salt, wherein alkali metal, alkaline earth metal or aluminum serves as cations, and organic solvent having hetero element, method for producing same, and capacitor provided with said electrolyte solution
JP5816999B2 (en) * 2013-09-25 2015-11-18 国立大学法人 東京大学 Method for producing electrolytic solution comprising salt having alkali metal, alkaline earth metal or aluminum as cation and organic solvent having hetero element
JP5817008B1 (en) * 2013-09-25 2015-11-18 国立大学法人 東京大学 Non-aqueous secondary battery
JP5817009B1 (en) * 2013-09-25 2015-11-18 国立大学法人 東京大学 Non-aqueous secondary battery
JP5817001B2 (en) * 2013-09-25 2015-11-18 国立大学法人 東京大学 Non-aqueous secondary battery
JP5817006B1 (en) * 2013-09-25 2015-11-18 国立大学法人 東京大学 Non-aqueous secondary battery
JP5817000B2 (en) * 2013-09-25 2015-11-18 国立大学法人 東京大学 Electrolyte group containing salt having alkali metal, alkaline earth metal or aluminum as cation and organic solvent having hetero element
JP5965445B2 (en) 2013-09-25 2016-08-03 国立大学法人 東京大学 Nonaqueous electrolyte secondary battery
JP5816997B2 (en) * 2013-09-25 2015-11-18 国立大学法人 東京大学 High-viscosity electrolytic solution containing a salt having alkali metal, alkaline earth metal or aluminum as a cation and an organic solvent having a hetero element
JP5817002B2 (en) * 2013-09-25 2015-11-18 国立大学法人 東京大学 Non-aqueous secondary battery
US9263762B2 (en) * 2013-11-22 2016-02-16 Lanyang Energy Technology Co., Ltd. Lithium ion batteries
CN110710049B (en) * 2017-06-07 2023-06-20 罗伯特·博世有限公司 Batteries with low counter-ion permeability layers
US12002963B2 (en) 2018-05-31 2024-06-04 Robert Bosch Gmbh Electrode configuration with a protrusion inhibiting separator
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US5494762A (en) * 1992-01-16 1996-02-27 Nippondenso Co., Ltd. Non-aqueous electrolyte lithium secondary cell
EP0731518A1 (en) * 1995-03-06 1996-09-11 Minnesota Mining And Manufacturing Company Perfluoroalkylsulfonates, sulfonimides, and sulfonyl methides, and electrolytes containing them
EP0807985A1 (en) * 1996-05-17 1997-11-19 Nisshinbo Industries, Inc. Current collector for molten salt battery, process for producing material for said current collector, and molten salt battery using current collector
WO1999030381A1 (en) * 1997-12-10 1999-06-17 Minnesota Mining And Manufacturing Company Bis(perfluoroalkylsulfonyl)imide surfactant salts in electrochemical systems
WO2000011742A1 (en) * 1998-08-25 2000-03-02 3M Innovative Properties Company Cyano-substituted methide and amide salts
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Title
PATENT ABSTRACTS OF JAPAN vol. 2000, no. 19 5 June 2001 (2001-06-05) *

Also Published As

Publication number Publication date
JP2004511887A (en) 2004-04-15
AU2002211378A1 (en) 2002-04-22
CN1468455A (en) 2004-01-14
JP2009043737A (en) 2009-02-26
EP1328996A2 (en) 2003-07-23
TW550847B (en) 2003-09-01
WO2002031905A2 (en) 2002-04-18
KR20040005831A (en) 2004-01-16

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