[go: up one dir, main page]

WO2002014443A3 - Urethane-based stain-release coatings - Google Patents

Urethane-based stain-release coatings Download PDF

Info

Publication number
WO2002014443A3
WO2002014443A3 PCT/US2001/022059 US0122059W WO0214443A3 WO 2002014443 A3 WO2002014443 A3 WO 2002014443A3 US 0122059 W US0122059 W US 0122059W WO 0214443 A3 WO0214443 A3 WO 0214443A3
Authority
WO
WIPO (PCT)
Prior art keywords
monoalcohols
group
urethane oligomers
coatings
urethane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2001/022059
Other languages
French (fr)
Other versions
WO2002014443A2 (en
Inventor
Wayne W Fan
Steven J Martin
Zai-Ming Qiu
Michael S Terrazas
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
3M Innovative Properties Co
Original Assignee
3M Innovative Properties Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 3M Innovative Properties Co filed Critical 3M Innovative Properties Co
Priority to AU2001273428A priority Critical patent/AU2001273428A1/en
Publication of WO2002014443A2 publication Critical patent/WO2002014443A2/en
Publication of WO2002014443A3 publication Critical patent/WO2002014443A3/en
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00—After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/46—Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with organic materials
    • C04B41/48—Macromolecular compounds
    • C04B41/488—Other macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
    • C04B41/4884—Polyurethanes; Polyisocyanates
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/285—Nitrogen containing compounds
    • C08G18/2855—Lactams
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/2805—Compounds having only one group containing active hydrogen
    • C08G18/288—Compounds containing at least one heteroatom other than oxygen or nitrogen
    • C08G18/289—Compounds containing at least one heteroatom other than oxygen or nitrogen containing silicon
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/341—Dicarboxylic acids, esters of polycarboxylic acids containing two carboxylic acid groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/34—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C08G18/348—Hydroxycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3802—Low-molecular-weight compounds having heteroatoms other than oxygen having halogens
    • C08G18/3804—Polyhydroxy compounds
    • C08G18/3812—Polyhydroxy compounds having fluorine atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3819—Low-molecular-weight compounds having heteroatoms other than oxygen having nitrogen
    • C08G18/3821—Carboxylic acids; Esters thereof with monohydroxyl compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/38—Low-molecular-weight compounds having heteroatoms other than oxygen
    • C08G18/3855—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur
    • C08G18/3876—Low-molecular-weight compounds having heteroatoms other than oxygen having sulfur containing mercapto groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
    • C08G18/72—Polyisocyanates or polyisothiocyanates
    • C08G18/77—Polyisocyanates or polyisothiocyanates having heteroatoms in addition to the isocyanate or isothiocyanate nitrogen and oxygen or sulfur
    • C08G18/78—Nitrogen
    • C08G18/79—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates
    • C08G18/791—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups
    • C08G18/792—Nitrogen characterised by the polyisocyanates used, these having groups formed by oligomerisation of isocyanates or isothiocyanates containing isocyanurate groups formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C—CHEMISTRY; METALLURGY
    • C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/20—Resistance against chemical, physical or biological attack

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Structural Engineering (AREA)
  • Paints Or Removers (AREA)

Abstract

This invention relates to chemical compositions comprising one or more urethaneoligomers of at least two repeating units selected from the group consisting of fluorine-containing urethane oligomers and long-chain hydrocarbon-containing urethane oligomers. These urethane oligomers comprise the reaction product of (a) one or more polyfunctional isocyanate compounds; (b) one or more polyols; (c) one or more monoalcohols selected from the group consisting of fluorochemical monoalcohols, optionally substituted long-chain hydrocarbon monoalcohols, and mixtures thereof; (d) one or more silanes; and optionally (e) one or more water-solubilizing compounds comprising one or more water-solubilizing groups and at least one isocyanate-reactive hydrogen containing group. The chemical compositions of the present invention can be applied as coatings and these coatings can impart stain-release characteristics and resist being worn-off due to wear and abrasion.
PCT/US2001/022059 2000-08-14 2001-07-12 Urethane-based stain-release coatings Ceased WO2002014443A2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU2001273428A AU2001273428A1 (en) 2000-08-14 2001-07-12 Urethane-based stain-release coatings

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US22506100P 2000-08-14 2000-08-14
US60/225,061 2000-08-14
US22604900P 2000-08-16 2000-08-16
US60/226,049 2000-08-16
US80444701A 2001-03-12 2001-03-12
US09/804,447 2001-03-12

Publications (2)

Publication Number Publication Date
WO2002014443A2 WO2002014443A2 (en) 2002-02-21
WO2002014443A3 true WO2002014443A3 (en) 2002-08-29

Family

ID=27397434

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2001/022059 Ceased WO2002014443A2 (en) 2000-08-14 2001-07-12 Urethane-based stain-release coatings

Country Status (2)

Country Link
AU (1) AU2001273428A1 (en)
WO (1) WO2002014443A2 (en)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6646088B2 (en) * 2000-08-16 2003-11-11 3M Innovative Properties Company Urethane-based stain-release coatings
US6890360B2 (en) 2001-12-17 2005-05-10 3M Innovative Properties Company Fluorochemical urethane composition for treatment of fibrous substrates
BR0311207A (en) 2002-05-24 2005-03-15 3M Innovative Properies Compan Fluorochemical composition, coating composition, method of treating a fibrous substrate, and article
US7425279B2 (en) 2002-05-24 2008-09-16 3M Innovative Properties Company Fluorochemical composition for treatment of a fibrous substrate
US7094829B2 (en) 2002-05-24 2006-08-22 3M Innovative Properties Company Fluorochemical composition comprising a fluorinated polymer and treatment of a fibrous substrate therewith
US20040147188A1 (en) * 2003-01-28 2004-07-29 3M Innovative Properties Company Fluorochemical urethane composition for treatment of fibrous substrates
US7258925B2 (en) 2003-07-11 2007-08-21 E.I. Du Pont De Nemours And Company Fluorochemical finishes for paint applicators
CN1297399C (en) * 2003-07-24 2007-01-31 上海交通大学 Method for preparing inorganic ceramic classified structure/organic compound material
US7094743B2 (en) 2003-07-29 2006-08-22 3M Innovative Properties Company Composition, wipe and method for cleaning, protecting and imparting gloss to a substrate
CA2541757A1 (en) 2003-10-06 2005-04-28 3M Innovative Properties Company Stain resistant polyurethane coatings
US20060047032A1 (en) 2004-09-01 2006-03-02 Miller Chandra T Anionic/cationic masonry sealing systems
EP1632464B1 (en) 2004-09-02 2011-04-13 3M Innovative Properties Company Method for treating porous stone using a fluorochemical composition
US20070197401A1 (en) * 2006-02-21 2007-08-23 Arco Manuel J Sandstone having a modified wettability and a method for modifying the surface energy of sandstone
BRPI0719929A2 (en) 2006-12-07 2014-03-11 3M Innovative Properties Co PARTICULARS UNDERSTANDING FLUORATED SILOXANE AND METHODS FOR PREPARING AND USING THEM
US20110232530A1 (en) * 2008-11-25 2011-09-29 Dams Rudolf J Fluorinated ether urethanes and methods of using the same
ITTO20130425A1 (en) 2013-05-28 2014-11-29 S E Special Engines S R L SELF-EXTINGUISHING MOSAIC CARDS

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4853418A (en) * 1987-08-10 1989-08-01 Dainichiseika Color & Chemicals Mfg. Co., Ltd. Polyurethane emulsion, sheet-like porous material making use of the emulsion and production process of the material
FR2749309A1 (en) * 1996-05-29 1997-12-05 Atochem Elf Sa Fluorinated urethane oligomers
WO1998051723A1 (en) * 1997-05-14 1998-11-19 Minnesota Mining And Manufacturing Company Fluorochemical composition comprising a polyurethane having a fluorochemical oligomer and a hydrophilic segment to impart stain release properties to a substrate

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4853418A (en) * 1987-08-10 1989-08-01 Dainichiseika Color & Chemicals Mfg. Co., Ltd. Polyurethane emulsion, sheet-like porous material making use of the emulsion and production process of the material
FR2749309A1 (en) * 1996-05-29 1997-12-05 Atochem Elf Sa Fluorinated urethane oligomers
WO1998051723A1 (en) * 1997-05-14 1998-11-19 Minnesota Mining And Manufacturing Company Fluorochemical composition comprising a polyurethane having a fluorochemical oligomer and a hydrophilic segment to impart stain release properties to a substrate

Also Published As

Publication number Publication date
AU2001273428A1 (en) 2002-02-25
WO2002014443A2 (en) 2002-02-21

Similar Documents

Publication Publication Date Title
WO2002014443A3 (en) Urethane-based stain-release coatings
WO2005037884A8 (en) Stain resistant polyurethane coatings
CA2125237A1 (en) Polyisocyanates containing allophanate and isocyanurate groups, a process for their production from cyclic diisocyanates and their use in two-component coating compositions
RU2003105834A (en) METHOD FOR PRODUCING POLYURETHANE MATERIAL
AR029831A1 (en) PROCESS TO PREPARE AN ELASTOMERO
CA2136371A1 (en) Aliphatic rim elastomers
ID26835A (en) POLYURETHANE AND MAKING THAT CONTAIN POLYURETHANTS
CA2234280A1 (en) Colloidal metal oxides having blocked isocyanate groups
CA2093884A1 (en) Polyisocyanates containing allophanate and isocyanurate groups, a process for their production from a mixture of diisocyanates and their use in two-component coating compositions
KR960034250A (en) Polyurethane coatings with very low volatile organic content
WO2002081071A3 (en) Novel polymer dispersants having hyperbranched structures
CA2328156A1 (en) A flexible polyurethane material
DE2966876D1 (en) Modified diisocyanate compositions and polyurethanes thereof
HUP0402516A2 (en) High impact poly(urethane urea)polysulfides
CA2205252A1 (en) High modulus, high impact polyurethane/polyurea rim
KR950008574A (en) Bis (N-alkylaminocyclohexyl) methane as a curing agent for polyurethanes and polyureas
JPS57185313A (en) Polyurethane and its preparation
BR0112898A (en) Process for the preparation of a polyurethane material and,
MY131129A (en) Foams containing silicon
HU0105266D0 (en) Polyisocyanate compositions and a process for the production of low-density flexible foams with low humid aged compression sets from these polyisocyanate compositions
MX9502638A (en) Linear hdi urethane prepolymers for rim application.
WO2004033514A3 (en) Spandex fiber using ethylene diamene/1,2-diaminopropane as chain extender and process for making same.
KR930021673A (en) Process for producing flexible polyurethane foam
CA2174305A1 (en) Method of producing gaskets from polyurethane/urea compositions and gaskets produced therefrom
ES2105264T3 (en) FLEXIBLE POLYURETHANE FOAMS MODIFIED AGAINST COMBUSTION.

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A2

Designated state(s): AE AG AL AM AT AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ CZ DE DE DK DK DM DZ EC EE EE ES FI FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SK SL TJ TM TR TT TZ UA UG UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A2

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

WA Withdrawal of international application