WO2002004356A1

WO2002004356A1 - Method for dewatering municipal waste-activated sludge using high electrical voltage

Info

Publication number: WO2002004356A1
Application number: PCT/US2001/011052
Authority: WO
Inventors: Jeffry Held; Satya P. Chauhan
Original assignee: D-H20 LLC
Current assignee: D-H20 LLC
Priority date: 2000-07-10
Filing date: 2001-04-05
Publication date: 2002-01-17
Anticipated expiration: 2003-01-10
Also published as: JP2004502541A; EP1315676A1; CA2382357A1; US6491820B2; US20020036175A1; US20020144957A1; US6395176B1; US6540919B2; EP1315676A4

Abstract

A system that allows the flexibility of primary and secondary treatment of municipal sludge, paper-pulp sludge, animal and plant waste, whereby the treatment thereof via electroporation may be used either as the primary dewatering treatment, secondary dewartering treatment, direct WAS-treatment, and combinations with other conventional dewatering techniques, in order to provide the municipal treatment platn, or the paper-pulp treatment plant, with the most cost-effective and efficient system as possible. The electroporated-treated sludge releases hitherto unreleased biosolids exiting from the PEF-electroporation system, which are returned to aeration tanks. The elelctroporation process causes the release of intracellular dissolved/organic matter, which is used as 'food' for the bacteria of the aeration tanks.

Description

METHOD FOR DEWATERING MUNICIPAL WASTE-ACTIVATED SLUDGE USING HIGH ELECTRICAL VOLTAGE

BACKGROUND OF THE INVENTION

In U.S. Patent No.6,030,538, issued in February 29, 2000 entitled "Method and pparatus for Dewatering Previously-Dewatered Municipal Waste- Water Sludges Using High Electrical Voltages, there is disclosed a system and method for dewatering and treating waste-activated sludge (WAS) emanating from municipal waste, or pulp-waste from a paper mill, as well as treating animal and plant waste. In that patent, the method for breaking down the WAS is to subject the WAS to electroporation, which incorporates nonarcing, cyclical high voltages in the range of between 15 KV and 100 KV, which break down inter-cellular and intracellular molecular bonds, to thus release inter-cellular and intracellular water, whereby the WAS is rendered inactive and greatly reduced in mass.

In the above-noted U.S. Patent, the apparatus and method disclosed therein, while capable in certain circumstances of being a primary municipal-sludge treatment, its intended and main objective was to use it as a secondary treatment to

previously-dewatered municipal waste sludge. It is the goal of the present invention to adapt the method and apparatus of U.S. Patent No. 6,030,538, issued in February 29, 2000 entitled "Method and Apparatus for Dewatering Previously-Dewatered Municipal Waste- Water Sludges Using High Electrical Voltages into a main, primary treatment of municipal waste sludge.

In a previous (Phase I) project, it has been demonstrated the laboratory feasibility of pulsed electric field (PEF) for disrupting the biomass in waste activated sludge (WAS) derived from municipal wastewater treatment. While there was no significant increase in the solids content of dewatered sludge, the quantity of WAS needing disposal was estimated to be significantly reduced.

Encouraged by the Phase I results, a pilot plant for testing at one or two wastewater treatment plants that generate WAS has been developed. It has been decided that a pulsed electric field (PEF) system that could handle 0.5 to 1.0 pgm WAS feed be designed. This requires an 8 kw power supply capable of generating 30 kV and pulse generator capable of handling 50 amp peak, current, bi-polar pulses, square wave, 10 μs pulse width, and 3000 pulses/second (pps).

SUMMARY OF THE INVENTION

It is the primary objective of the present invention to provide a method and apparatus for dewatering municipal waste sludge, paper-pulp waste sludge, animal and plant waste, using electroporation for the primary treatment of the sludge.

It is also a primary objective of the present to provide such a system that will allow flexibility as to the primaiy and secondary treatment of municipal sludge, paper-pulp sludge, animal and plant waste, whereby the treatment thereof via electroporation may be used either as the primary dewatering treatment, secondary dewatering treatment, direct WAS -treatment, and combinations with other conventional dewatering techniques, in order to provide the municipal treatment plant, or the paper-pulp treatment plant, with the most cost-effective and efficient system as possible. BRIEF DESCRIPTION OF THE DRAWING

The invention will be more readily understood with reference to be accompanying drawings, wherein:

Figure 1 is a schematic showing the electroporation system as used as a secondary dewatering treatment;

Figure 2 is a schematic showing the electroporation system used in conjunction as a primary dewatering treatment in accordance with the present invention;

Figure 3 is a schematic showing the electroporation sub-system for use in

dewatering municipal, paper-pulp, animal and plant waste sludges; and

Figure 4 is a schematic diagram showing the overall apparatus of the present invention incorporating the electroporation sub-system for use as a primary or secondary dewatering treatment.

DETAILED DESCRIPTION OF THE INVENTION The original concept for the pulsed-electric filed (PEF) effect using electroporation was to dewater the previously-dewatered sludge. However, additional PEF data on a paper plant sludge has indicated that the big PEF effect from electroporation of WAS occurs at higher energy levels (e.g., 100 J/mL; or 400 k Wh/ton (DS) for feed at 6 percent solids), whereby cells are disrupted. The result is inactivation of cells, breakage of cells and release of some intracellular dissolved/organic matter and typically a worsening of flocculation and dewatering. Therefore, a more effective way of using this process is to recycle all of the PEF- treated sludge back to a aerobic bioreactor to utilize the sludge as food; that is, it has been discovered that the PEF-electroporation effect on disrupting the cellular units of the WAS has been to release intracellular dissolved/organic matter. This intracellular dissolved/organic matter is just the type of ideal "food" upon which the aerobic bioreactor flourishes. Thus, returning this released intracellular dissolved/organic matter back to the aerobic bioreactor will increase the BOD load on the bioreactor, and will thus reduce the quantity of WAS by up to about 50 percent. The flow sheet for this scenario is shown in Figure 2. Thus, it is now practical to employ the PEF-electroporation system as not only a secondary system for treating previously-dewatered sludge, but also to employ it as a primary system, as described hereinbelow.

Referring to Fig. 1, there is shown the schematic for using the PEF- electroporation system as a secondary treatment for previously-dewatered sludge, as disclosed in U.S. Patent No. 6,030,538, issued in February 29, 2000 entitled "Method and Apparatus for Dewatering Previously-Dewatered Municipal Waste- Water Sludges Using High Electrical Voltages. In Fig. 1, the wastewater is delivered to the primary treatment, aerobic-reactor tanks 10, and from there to a

secondary clarifier 12. From there, the WAS is delivered to the PEF-electroporation system 14 of the invention for deactivating the WAS to make it a Class "B" biomass for easier disposal. The biomass is then sent to a belt press 16 for further processing and disposal.

Referring now to Fig. 2, there is shown the flow chart of the present invention for employing the PEF-electroporation system as part of the primary treatment. In this system, the biosolids exiting from the PEF-electroporation system 14 are returned to the aeration tanks 10, since, as explained above, the PEF process causes the release of intracellular, dissolved organic matter, which is used as "food" for the bacteria of the aeration tanks. This "food" not only is further treated in the aeration tanks via aerobic digestion, but actually causes the aerobic digestion process in the aerobic tanlc itself to be accelerated for the same amount of oxygen supplied.

A practical problem with the system of Figure 2 is that the PEF throughput needs to be of the same order of magnitude as the WAS disposal rate in order to see a noticeable effect of PEF on WAS reduction. For this reason a 1.8 ton (DS)/day PEF system has been chosen as a pilot plant. With such a system, a WAS reduction of 0.9 ton/day on a dry basis or 7.5 tons/day on a filter press cake (at 12 percent solids) basis may be achieved. In terms of thickened sludge (at 2 percent solids) basis, this translate to elimination of 45 tons/day needing to be flocculated and dewatered. This will require PEF treatment of 15 gpm WAS at 2 percent solids.

One way to reduce the cost of the pilot plant, which is driven by the PEF power supply and pulser cost, is to pre-thicken the WAS. Therefore, a 15 gpm rental centrifuge 18 is used for pilot testing. It is estimated that this will produce a 5 gpm feed for the PEF reactor at a solids content of 6 percent, Such a feed can be handled by a Moyno pump. The feed streams to the centrifuge and the PEF units are

represented as Stream Nos. 10 and 11, respectively in Figure 2. However, in practical application such as centrifuge may not be necessary.

PEF POWER SUPPLY AND PULSER DESIGN The conceptual design of the power supply and the pulse generator (pulser) for the system of Fig. 2 is shown in Figure 3. This figure shows four chambers 20 in series, although two chambers also can be used if the pulse rate is increased. The specifications for the two-chamber design are shown in Table 1. The design requires a 35 kW input power supply 22 (32 kW continuous output) delivering 30 kV. The pulse generator 24 is 200 amp maximum current and a pulse rate of 4,000 hz. (maximum).

Table 1. Pilot Plant PEF Power Supply, Reactor, and Pulser

The actual sludge handling system and the associated instrumentation is shown in Figure 4. A detailed list of specifications is provided in Table 2. Tank TI holds up to 100 gallons of untreated feed material, delivered through valve VI from the centrifuge 18. A mixer is provided for blending infeed material. A bottom drain allows disposal to sewer at the end of a test run. Valve V4 is provided for withdrawing a sample for analysis. Material leaves TI through V2 and a strainer to a variable-speed progressing cavity pump, which can flow from 0.5 to 5.0 gallons per minute. The tank, pump mixer and associated valves are mounted to one 42- inch square skid for transport purposes. The feed leaving PI passes through quick- connect fittings to a reinforced hose to the reactor.

The PEF-electroporation reactor subsystem includes a power supply, pulse generator and pairs of treatment chambers as described above with reference to Fig. 3. These would be mounted to a skid , along with associated valves V5, 6 and 7. Quick-connect fittings and hose convey the treated material to valves on the outlet tanlc skid. Valves V12 and 13 permit the treated material to be recycled back to TI. Valve V8 permits the treated material to enter tanlc T2, of 100-gallon capacity. As with TI, a mixer, a sample port and a bottom drain are provided. Tanlc T2, pump P2, mixer M2 and associated valves are mounted to another skid. Treated material leaving through VI 0 leads to transfer pump P2. Valve VI 8 is a globe style for adjusting the flow rate through V14 to tanlc T3. Valve VI 3 allows treated material from T2 to return to TI, assisted by P2, to increase treatment time.

The P2 pump is used to return the treated sludge to the biotreatment plant, aerobic tanks 10, when the PEF-electroporation system is used as a primary system, or optionally to filter press 16, if desired, when the PEF-electroporation system is used as a secondary treatment.

Safety logic has been incorporated as follows. Level control LI will close VI to prevent overfilling TI, with subsequent spillage. Level control L2 will shut down PI and the power supply when the liquid level becomes too low. Level control L3 and T2 will shut down PI and the power supply when tank T3 becomes full, to prevent spillage.

Table 2. Sludge Handling System Specifications

Description Qty

Supplier Inlet Tank TI 100-Gal carbon steel j acketed mixing tank 1

Buckeye Fab. 2-inch PVC, Schedule 80 90-Deg. elbow, 806-020 (bypass in) 1

Harrington Mixer, C-Clamp mount direct drive, % HP, 400-250-DD-ED 1

Harrington Union ball valve, 2-inch socket, 1001020 2

Harrington Strainer, 2-inch clear PVC, RVAT 108 1

Harrington Replacement screen, PVC 1

Harrington 2-inch PVC, Schedule 80 pipe, 800-020, 20 feet length 1

Harrington 2-mch PVC, Schedule 80 90-Deg elbow, 806-020 2

Harrington Quick disconnect, Part F, 2-inch, polypro., FPP-020 2

Harrington Quick disconnect, Part C, 2-inch, polypro., CPP-020 2

Harrington Hose, PVC standard duty, 2-inch, 11 OP-020 100 ft

Harrington Hose clamps, 3-inch, H-44SS 10/paclc

Harrington Bulkhead fitting, V^-inch PVC BF10050SXT 1

Harrington Ball valve, !/₂-inch socket, 107005

Harrington Elbow, 90-degree, ^-inch Sch 80 PVC, 806-005

Harrington Level control, high to shut feed valve, LV751

Omega Level control, low to shut off pump PI and Powr supply, LV751

Omega Solid state relay for feed valve, SSR240AC10

Omega Solid state relay for pump and power supply, SSR240AC25

Omega

Feed Valve VI

Quick disconnect, Part F, 2-inch, polypro., FPP-020

Harrington Quick disconnect, Part C, 2-inch, polypro., CPP-020

Harrington Union ball valve, 2-inch, 1001020

Harrington Electric actuator, 2085020

Harrington

Process Pump PI

Pump, 5.0 down to 0.5 GPM, 35 psi, Moyno

Buckeye Pump Direct Current control for pump, NEMA 4 enclosure

Buckeye Pump Hose nipples, polypro., 2-inch, HNPP-020 2

Harrington 2-inch PVC, Schedule 80 tee, 801-020 2

Harrington 2-inch PVC, Schedule 80 pipe, 800-020, 20 feet length 1

Harrington 2-inch PVC, Schedule 80 90-Deg elbow, 806-020 2

Harrington

Reactor Connections

Quick disconnect, Part F, 2-inch, polypro., FPP-020 2

Harrington Quick disconnect, Part C, 2-inch, polypro., CPP-020 2

Harrington Union ball valve, 2-inch socket, 1001020 1

Harrington 2-inch PVC, Schedule 80 socket tee, 801-020 2

Harrington Table 2. Sludge Handling System Specifications (Continued)

Description Qty

Supplier Reducing bushing, 2-inch by i^-inch thread, 838-247 2

Harrington Vi-inch by 1-1/2-inch long PVC Schedule 80 nipple, 882-015 2

Harrington Union ball valve, Ainch threaded, 1001005 2

Harrington -inch PVC Schedule 80 threaded tee, 805-005 1

Harrington Reducing bushing V^-inch to Vi-inch threaded, 839-072 2

Harrington Pressure gauge with guard, 0-60 psig, GGME060-PP 1

Harrington Tube adapter, Vi-inch MPT to -inch tube, 4MSC4N-B 2

Parker

Outlet Tanlc T2

100-Gal jacketed carbon steel tanlc with legs, 2-in outlet 1

Buckeye Fab. 2-inch PVC, Schedule 80 90-Deg elbow, 806-020 (inlet) 1

Harrington Union ball valve, 2-inch socket 1001020 5

Harrington Quick disconnect, Part F, 2-inch, polypro., FPP-020 3

Harrington Quick discom ect, Part C, 2-inch, polypro., CPP-020 3

Harrington 2-inch PVC, Schedule 80 90-Deg elbow, 806-020 4

Harrington 2-inch PVC, Schedule 80 socket tee, 801-020 2

Harrington 2-inch PVC, Schedule 80 threaded tee, 805-020 3

Harrington 2-inch by 6-inch PVC, Schedule 80 nipple 2

Harrington Mixer, C-Clamp mount direct drive, ^lA HP, 400-250-DD-ED 1

Harrington ^-inch by 2-inch PVC, Schedule 80 1

Harrington Ball valve, Y₂ inch socket, 107005 1

Harrington Elbow 90-degree, ^l/₂- c Sch 80 PVC, 806-005 1

Harrington Level control, low to shut off pump PI and Powr supply, LV751 1

Omega Solid state relay for pump and power supply, SSR240AC25 1

Omega

Outlet Tank Pump

Pump, 5 GPM 20 feet of head, centrifugal 1

Buckeye Pump Motor starter, NEMA 4 with thermal unit 1

C.E.D. Hose nipples, polypro., 2-inch, HNPP-020 4

Harrington Glove valve, threaded, PVC, 2-inch, 1261020 1

Harrington

Product Pump P2

Pump, 5 GPM 20 feet of head, centrifugal 1

Buckeye Pump Motor starter, NEMA 4 with thermal unit 1

C.E.D. Sealtite, a-inch lot

C.E.D. Wires, cords lot

C.E.D.

Skids

42-inch square, metal, fork lift entry four sides

Table 2. Sludge Handling System Specifications (Continued)

Description Qty

Supplier Instrumentation Oscilloscope, storage, two inputs, 100 MHz, printer interface

Tektronix Current sensor, 0.01 Volt/ Ampere, 100 Amp. max.

Pearson Electr. Clamp-on flowmeter, 2 to 12-inch pipe, 4 - 20 ma output

Controlotron Voltage sensor, 60 Kilovolt, lOOOv/lV, Type PVM-1

North Star Resch Printer, Epsom jet Model 740, Part No. C257001 parallel port

ADS Systems Centronics-type paraller printer port cost, Epsom F2E020-06 1

ADS Systems Type K thermocouple readout, Omega DP45KF + SB45 1 ea.

Omega Type K thermocouple, 304SS sheath, 1/8-in. dia., KQSS-18G-12 2

Omega Conductivity and pH meter, 0-200 μS, 0-14pH, P-19651-20 1

Cole-Parmer Conductivity and pH flow-through cell, P-l 9502-42 2

Cole-Parmer

Alternative clamp-on flow meter, Omron FD-303 + FD-5 sensor for %-in. to %-in. pipe + FD-5000 sensor for ³/₄-in. to 12-in. pipes.

While a specific embodiment of the invention has been shown and described, it is to be understood that numerous changes and modifications may be made therein without departing from the scope and spirit of the invention as set forth in the appended claims.

Claims

WHAT WE CLAIM IS:

CLAIM 1. A method of dewatering paper-pulp sludge, municipal waste sludge, animal waste sludge containing intra-cellular water molecules contained in molecular cellular units of the waste sludge, or plant and animal waste sludge, comprising:

(a) pumping the waste sludge into a dewatering apparatus;

(b) destroying in the dewatering apparatus at least most of the individual cellular units of the waste sludge in order to release the intracellular water molecules contained therein; and said step (b) causing massive disruption of the cellular matter, allowing for the release of bound as well as intra-cellular liquids and intracellular dissolved/organic matter, which may be used as food for the bacteria of aeration tanks;

(c) directing the released intracellular dissolved/organic matter to an aeration tank for supplying food to bacteria of said aeration tank.

CLAIM 2. The method according to claim 1, wherein said step (b) comprises electroporating said sludge.

CLAIM 3. The method according to claim 2, wherein said electroporation is performed with voltages between 15 KV. and 100,00 KV.

CLAIM 4. A method of treating sludge, such as paper-pulp sludge, municipal sludge, plant and animal waste, in which the sludge is treated in an aeration tank for performing aerobic digestion, comprising:

(a) treating the sludge to a dewatering process that releases intracellular dissolved/organic matter;

(b) directing the sludge treated in said step (a) to an aeration tank for performing aerobic digestion thereon

whereby the intracellular, dissolved organic matter is used as food for the bacteria of the aeration tanks, whereby the aerobic digestion process is accelerated thereby for the same amount of supplied oxygen.

CLAIM 5. The method according to claim 4, wherein said step (a) comprises electroporating the sludge.

CLAIM 6. The method according to claim 4, further comprising alternatively directing the sludge directly to a further dewatering process.

CLAIM 7. A method of treating sludge, such as paper-pulp sludge, municipal sludge, plant and animal waste,

(a) treating the sludge to a dewatering process that releases intracellular, dissolved organic matter;

(b) directing the sludge treated in said step (a) to one of: an aeration tank for performing aerobic digestion thereon, or to a different, dewatering process.

CLAIM 8. The method according to claim 7, wherein said step (b) comprises alternatively directing the sludge to further dewatering process consisting of a filter press.

CLAIM 9. The method according to claim 7, wherein said (b) comprises directing the sludge to an aeration tanlc, where said intracellular, dissolved organic matter is used as food for the bacteria of the aeration tanks, whereby the aerobic digestion process is accelerated thereby for the same amount of supplied oxygen.