[go: up one dir, main page]

WO2001005600A1 - Matiere d'enregistrement a jet d'encre thermoretrecissable - Google Patents

Matiere d'enregistrement a jet d'encre thermoretrecissable Download PDF

Info

Publication number
WO2001005600A1
WO2001005600A1 PCT/US2000/018721 US0018721W WO0105600A1 WO 2001005600 A1 WO2001005600 A1 WO 2001005600A1 US 0018721 W US0018721 W US 0018721W WO 0105600 A1 WO0105600 A1 WO 0105600A1
Authority
WO
WIPO (PCT)
Prior art keywords
coating
shrinkable
article
substrate
ink jet
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US2000/018721
Other languages
English (en)
Inventor
Jodi A. Dalvey
Nabill F. Nasser
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
American Coating Technologies Inc
Original Assignee
American Coating Technologies Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by American Coating Technologies Inc filed Critical American Coating Technologies Inc
Priority to AU59241/00A priority Critical patent/AU5924100A/en
Publication of WO2001005600A1 publication Critical patent/WO2001005600A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M7/00—After-treatment of prints, e.g. heating, irradiating, setting of the ink, protection of the printed stock
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C61/00—Shaping by liberation of internal stresses; Making preforms having internal stresses; Apparatus therefor
    • B29C61/06—Making preforms having internal stresses, e.g. plastic memory
    • B29C61/0608—Making preforms having internal stresses, e.g. plastic memory characterised by the configuration or structure of the preforms
    • B29C61/0616—Making preforms having internal stresses, e.g. plastic memory characterised by the configuration or structure of the preforms layered or partially layered preforms, e.g. preforms with layers of adhesive or sealing compositions
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5263—Macromolecular coatings characterised by the use of polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
    • B41M5/5272—Polyesters; Polycarbonates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/502—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording characterised by structural details, e.g. multilayer materials
    • B41M5/504—Backcoats
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5245—Macromolecular coatings characterised by the use of polymers containing cationic or anionic groups, e.g. mordants
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
    • B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
    • B41M5/00—Duplicating or marking methods; Sheet materials for use therein
    • B41M5/50—Recording sheets characterised by the coating used to improve ink, dye or pigment receptivity, e.g. for ink-jet or thermal dye transfer recording
    • B41M5/52—Macromolecular coatings
    • B41M5/5254—Macromolecular coatings characterised by the use of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds, e.g. vinyl polymers

Definitions

  • the present invention relates to a shrinkable medium for receiving ink and to a method for printing the shrinkable medium.
  • Miniature works of art such as miniature pictures or miniature decorations on jewelry articles, date back to antiquity.
  • the art of making miniature items of decoration is no longer generally performed by actually drawing or painting a small image on a small article. Instead, the small image, such as a photograph or a printed image, is produced by optically reducing the photograph to a much smaller scale, through a medium such as a microfilm frame.
  • the kit includes a pattern sheet which has an outline of a figure imprinted thereon and a shrinkable plastic sheet.
  • the shrinkable plastic sheet is a biaxially-oriented polystyrene sheet with a thickness of about 0.01 millimeters.
  • the shrinkable sheet is sufficiently transparent so that a figure on a pattern sheet can be seen through the plastic sheet.
  • the outline and line details are then traced upon the upper surface of the plastic sheet with a suitable device such as permanent ink marker.
  • the sheet is then heated in an oven at a temperature of about 300°F for about thee minutes, whereupon the plastic softens and shrinks and the area of the plastic sheeting covered by the particulate material puffs or bulges outwardly.
  • the object is then removed from the oven while the plastic is soft, and the areas surrounding the puffed portions are flattened, if necessary, to exaggerate and accentuate the three dimensional appearance.
  • These shrinkable objects can be used to make play things such as humanoids or animal-like figures originating in a comic strip, a motion picture, or a television program.
  • the character whose contours are printed on the shrinkable plastic sheet may be colored by a child using colored pencils, or other coloring articles. The coloring is performed prior to treatment in the oven.
  • U.S. Patent No. 4,461,793 ('793) issuing July 24, 1984, describes a printable coating for use with a heat shrinkable object such as has been described.
  • the printable coating includes a saturated solvent-soluble polyester film forming resin, calcium carbonate, and a silicate compound.
  • An additional pigment to produce an opaque coating in a selected color may also be included.
  • the printable coating described in the '793 patent may receive inks that are generally used to print legends, and the coating can shrink up to 50% when applied to a plastic film without exhibiting wrinkling and without losing adhesion to the film.
  • the coating has an excellent abrasion resistance.
  • the heat shrinkable ink jet recording media comprises a heat shrinkable base substrate, and a heat shrinkable ink jet-receptive coating layer applied to a printable surface of the base substrate.
  • the base substrate and the ink jet-receptive coating layer are shrinkable in uniform proportions in all directions.
  • the base substrate is a polystyrene or biaxially-oriented polypropylene.
  • the ink jet ink-receptive coating layer comprises a flexible resin having a glass transition temperature which is lower than that of the substrate to which the coating is applied.
  • the water absorptivity of the coating is greater than 50% by weight.
  • the coating also includes an adhesion promoter that is a graft copolymer of hydroxy methylmethacrylate, or methylmethacrylate.
  • One embodiment of the present invention includes a method for making an ink jet printed, shrinkable article.
  • the method comprises providing a shrinkable substrate and providing a coating that comprises a film and a modified polyester resin.
  • the coating is applied to the shrinkable substrate. Indicia are imparted to the coating with an ink jet printer.
  • the coated substrate with the ink-based indicia is then shrunk without wrinkling.
  • the coated substrate is capable of receiving ink from an ink jet printer.
  • the miniature printed article comprises a shrinkable substrate and a shrinkable coating adhered to the substrate.
  • the coating is comprised of a film and a modified polyester resin.
  • the miniature also includes ink jet indicia on the coating.
  • the coating is smooth and unwrinkled when the article is shrunken.
  • One other embodiment of the present invention includes an ink j et printable coating that comprises a film and a modified polyester that overlays the film.
  • kits such as a kit for making jewelry or ornaments.
  • the kit comprises a container and shrinkable ink jet printed articles that are enclosed within the container.
  • a miniature printed article that comprises a hollow shrinkable substrate with internal and external surfaces and a shrinkable coating adhered to the substrate on all of the surfaces.
  • the coating is comprised of a film and a modified polyester resin.
  • the miniature includes ink jet indicia on the coating. The coating is smooth and unwrinkled on the internal and external surfaces when the article is shrunken.
  • FIG. 1 is a cross-sectional view of one embodiment of a shrinkable article of the present invention.
  • Figure 2 is a cross-sectional view of another embodiment of a shrinkable article of the present invention.
  • One embodiment of the present invention includes a method for making a miniature article with a surface comprised of a water soluble modified polyester, a film and ink printed indicia, the indicia having sharp definition and having adherence to an underlying heat shrinkable medium.
  • the method includes providing the heat shrinkable medium and applying a compatible, shrinkable, ink-receptive coating to the heat shrinkable medium.
  • the method includes optionally corona treating the surface of the heat shrinkable medium prior to application of the shrinkable coating.
  • the shrinkable coating comprises a modified water soluble polyester resin material comprised of about 7 to 55% of a modified-polyethylene resin or polyester resin, 90% of which is at a glass transition temperature of 100° Centigrade and 10% of which is greater than the glass transition temperature of 100° Centigrade and a film.
  • the shrinkable coating comprises an ink receptive coating.
  • the ink receptive coating comprisies a polyester polymer that is modified with polyvinyl alsohol and acrylic resin and cationic resinas a die fixing agent with a range of 0 to 70 percent by weight. One range embodiment is 0 to 40 percent.
  • the shrinkable coating is applied to the shrinkable medium.
  • the method further includes printing the applied shrinkable coating with an ink such as ink from an ink jet process.
  • the method additionally includes heating the heat shrinkable medium and the shrinkable coating for about 2 to 10 minutes at a temperature within a range of about 300 +/- 10° F or subjecting to baking condisions to shrink the heat shrinkable medium and the shrinkable coating to a degree that is about 50 percent of their original size or less.
  • Another embodiment of the present invention includes a miniature article with an outer surface comprised of a substantially smooth, modified water soluble polyester.
  • Miniature ink-printed indicia with a sharp definition are on the smooth outer surface.
  • the ink-printed indicia include ink jet printed indicia.
  • One cross-sectional view of the miniature article, illustrated at 10 in Fig. 1 comprises a heat shrinkable substrate 12, and a coating that comprises a film 14 that overlays the substrate 12 and a modified polyester overlay 16 that overlays the film 14.
  • the coating and heat shrinkable medium shrink together so that the outer coated surface is smooth and not wrinkled and remains adhered to the substrate.
  • the ink jet printed indicia on the coating have sharp definition both before and after shrinkage. The ink jet printed indicia are believed to be bound to the coating.
  • the shrinkable substrate 12 is, in one embodiment, in a form of a sheet of a shrinkable material such as polystyrene or biaxially-oriented polypropylene.
  • the substrate is shrinkable in an "X" dimensional direction in an amount of up to about 61% and is shrinkable in a "Y" dimensional direction in an amount of up to about 41% after heating the base substrate at about 120 to 170° C typically and, for some embodiments, 300°C, for about five minutes.
  • the "X" dimensional direction and the "Y” dimensional direction are perpendicular to each other and are in a plane formed by the substrate.
  • the shrinkable substrate 12 is corona treated. Corona treatment may, for some embodiments, improve adherence of the coating to the substrate.
  • One embodiment of the method of the present invention includes applying a coating to the substrate that can receive an ink jet print, that is shrinkable, and that comprises a water-based polyester material.
  • the polyester resin coating overlay 16 employed is designated, NS- 244LX, or NS-282 or WAC-10 and is manufactured by Takamatsu Oil and Fat Company, Ltd., of Osaka, Japan.
  • This material includes an n-propanol concentration of about 1.8% by weight, a modified polyester resin concentration of about 15% by weight, and a water concentration of about 83.2% by weight.
  • This coating material has a boiling point of 100° C and a specific gravity of 1.032 at 20° C. The material is a white emulsion that has a slightly alcoholic odor.
  • a coating which includes a polyester resin and a urethane resin and is known as WAC-15, also manufactured by Takamatsu Oil & Fat Co., Ltd.
  • WAC-15 is free of organic solvent.
  • the viscosity of the coating is about 500 cps and is adjustable with care.
  • Another modified polyester resin overlay material that may be employed in the method of the present invention include a modified polyester resin designated NS-282LX, manufactured by Takamatsu Oil and Fat Company, Ltd., of Osaka, Japan.
  • This coating material has a modified polyester concentration that forms a clear layer after drying and that has good jet ink absorption.
  • the modified polyester has a good adhesion to polyester and polyvinyl chloride films.
  • the coating is applied to a thickness of about 8 to 12 microns.
  • the 282 LX modified polyester resin has an appearance of a white emulsion and a modified polyester concentration of 15% +/-1 percent by weight.
  • the viscosity of the modified polyester resin is less than 1000 centipoise at 25 °C.
  • the resin pH at 25 °C is 4-6.
  • the 282 LX resin is nonionic and may, for some embodiments, include n-propyl alcohol in a concentration of 2.0% by weight. At low temperatures, the viscosity increases dramatically. The viscosity is reduced by heating at 40°C.
  • Another coating embodiment utilizes a modified polyester resin known as NS-244LX, also manufactured by Takamatsu Oil and Fat Company, Ltd., of Osaka, Japan.
  • This material has an n-propanol concentration of about 1.8% by weight, a modified polyester resin concentration of about 15% by weight, and water in a concentration of about 83.2% by weight.
  • the specific gravity of this material is 1.032.
  • the vapor density of the material is 5 +1- 1.
  • the modified polyester resin material is soluble in water. All of the resins utilized in the present invention are water soluble and water based.
  • Another coating embodiment utilizes an emulsion resin that includes a linear polyester of high molecular weight, known as NS-246LX.
  • the NS-246LX is also manufactures by Takamatsu Oil & Fat, Ltd. Of Osaka, Japan.
  • the NS-246LX coating has good ink absorption and good ink fixation.
  • the coating also includes polyvinylalcohol and resin, NS-246LX.
  • This coating has a non-volatile content of about 15% by weight, a viscosity of 1000 cps at 25 degrees Centigrade, a color of milky white, a pH of 4 to 6.
  • the coating is a nonionic coating and includes about 2% n-propyl alcohol. The coating is dried in a still environment at about 110 degrees Centigrade.
  • Another coating embodiment utilizes a linear polyester of high molecular weight, polyvinylalcohol and acrylic resin which is known as NS- 286LX and is manufactured by Takamatsu Oil & Fat Co., Ltd., of Kyutaro- machi Chuoh-ku, Osaka, Japan.
  • the NS-286LX coating has good ink absorption and good ink fixation, especially for direct and acid dyes.
  • the coating has a good adhesion to films such as polyester and does not bronze.
  • the coating has a good water resistance, is resistant to curl after coating and has a lustrous surface.
  • the coating is applicable as a thin layer, 4 to 12 microns.
  • the coating has a non- volatile content of about 15% by weight; a viscosity of 1000 cps at 25 degrees Centigrade; a pH of 4-6 and contains about 2% normal propyl alcohol. This coating is dried at a temperature of about 110 degrees Centigrade, in still air.
  • the coating is applicable by die coating, roller coating knife coating, blade coating, and kiss roll coating.
  • Other modified polyester resin coating formulations that may be employed in the method and coating of the present invention include NS-63W, manufactured by Takamatsu Oil and Fat Company, as well as PES-513E, also manufactured by Takamatsu Oil and Fat Company. These modified polyester materials make a clear layer after drying on a substrate.
  • Coatings prepared with the modified polyester resin materials have good ink absorption, including good absorption of ink used in ink jet printing.
  • the coating embodiments prepared with these resins have good adhesion to films such as polyester and polyvinyl chloride.
  • Coatings have good water resistance and may be layered to a relatively thin thickness, such as about eight to twelve microns.
  • One other coating usable in the method of the present invention is a color changeable coaitng that is activated by temperatures , thermochromic, or UV light, photochromic, with and without ink jet receptive coating. Inks are obtained from Matsui in coatings activiated thermochromically. Photopia inks from Matsui are used in coatings activated photochromically.
  • Other method embodiments include a phosphorescent pigment that is coated without an ink receiving layer; a product with an ink jet coating on one side that incorporates the phosphorescent pigments; and a product with ink jet coating on one side and the phosphorescent pigments incorporated in a polymer matrix on the other side.
  • Phosphorescent pigments usable in the present invention include doped zinc sulfide pigments and strontium sulfide pigments. Manufacturers include Allied Signal, UMC, USR, Matsui and WC Manufacturing.
  • a film 14 such as polyester or polyvinyl chloride is overlayed on the shrinkable substrate 12.
  • the modified polyester 16 is applied over the film.
  • the film aids in adhering the modified polyester to the shrinkable medium.
  • the modified polyester permits the shrinkable article to be ink jet printed.
  • the viscosity of the modified polyester resin coating material is less than 1,000 cps at 25°C. Viscosity modifiers may be added for some embodiments. Particular coating methods require viscosities that range from about 25 cps to as great as about 20,000 cps.
  • the pH of the modified polyester resin-based coating ranges from about 4 to 6 for the NS244LX and NS282LX coating formulations, which are nonionic resins.
  • the pH for the NS122L modified polyester resin-based coating, which comprises an anionic polyester resin is about 7.
  • the anionic polyester resins may be altered by addition of a surfactant such as n-propanol in a concentration of about 2.0% by weight.
  • the nonionic resins do not include an n-propanol composition. Coatings made with the modified polyester resins dry at about 110° C in about three minutes.
  • the modified polyester resin coating formulations may optionally be altered with an addition of a surfactant or a pigment or a plasticizer for special colors or effects.
  • a surfactant may be used in order to enhance wetting properties and adhesive properties of the coating.
  • the coating may be shrunk to a maximum of about 50% of its application area in an X-Y plane.
  • the modified polyester resin coating is compatibly shrinkable to the shrinkable substrate.
  • the substrate 12a is coated as shown at 16a and 16b.
  • the coating 16a and 16b overlays film 14 a and 14b.
  • the coating 16a is an internal coating.
  • the coating 16b is an external coating.
  • the coating may be uniform or different coatings may be used on different sides. Coating on both sides provides improved shrinkage balance over the entire substrate 12a.
  • Inkjet printing uses jets of colored ink, similar in appearance and consistency to fountain pen ink.
  • the ink is ejected through a nozzle under pressure and is transformed into uniform droplets by vibration of a piezoelectric crystal.
  • the droplets are charged electrostatically and are deflected by a computer or other digital image-generating device.
  • Any type of ink jet printing may be used in the method of the present invention.
  • Methods include a computer activated single nozzle, a bank of nozzles, bubblejet and phase-change technology.
  • Indicia printed on the shrinkable coated surface include letters as well as color or luminescent images.
  • Ink for the color images includes dyes that have different spectral and reflective characteristics from pigments. Images also include holographic images and images that glow in the dark.
  • Inkjet printing typically requires a surface that has a capacity to dry the impinging drops of ink by absorption without wicking or spreading of the ink for maximum printing density and sharpness. It has surprisingly been found that the coating used in the process and article of the present invention receives ink jet print and does not require a material such as silica or calcium carbonate to impart clarity and sharpness of the indicia.
  • Ink jet printing may be used to make indicia such as letters, symbols, or dots used to make an image such as a face or an animal or other image.
  • Print from the ink jet printing may have a variety of colors.
  • Print may be used to make holograms. Print, for some embodiments, glows in the dark.
  • a magnetic substrate is laminated to the back of the film.
  • a magnetic coating is applied to the back of the film.
  • Articles made with the method of the present invention include but are not limited to articles such as toys, figures, two-dimensional images, and other articles that may be miniaturized. Other articles include kits such as jewelry kits and ornaments and ornament kits such as Christmas tree ornament kits.
  • a jewelry kit and ornament kit comprises a shrinkable article of the present invention, a container for the shrinkable article and, optionally coloring agents such as crayons or paint, fastening devices, and other kit components, such as components that attach one shrinkable article to another.
  • One other embodiment is made by laminating a magnetic substrate to the back of a film or coating or applying a magnetic coating to the back of a film or coating.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Ink Jet Recording Methods And Recording Media Thereof (AREA)

Abstract

La présente invention concerne un procédé de production d'un articule miniature présentant une surface comprenant un polyester hydrosoluble et des marques imprimées à l'encre, les marques ayant une définition nette et ayant une adhérence sur la surface. Le procédé consiste à utiliser un support thermorétrécissable et à appliquer un revêtement compatible rétrécissable et recevant l'encre sur le support thermorétrécissable.
PCT/US2000/018721 1999-07-16 2000-07-10 Matiere d'enregistrement a jet d'encre thermoretrecissable Ceased WO2001005600A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU59241/00A AU5924100A (en) 1999-07-16 2000-07-10 Heat-shrinkable ink-jet recording material

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/354,827 1999-07-16
US41635699A 1999-10-12 1999-10-12
US09/416,356 1999-10-12

Publications (1)

Publication Number Publication Date
WO2001005600A1 true WO2001005600A1 (fr) 2001-01-25

Family

ID=23649634

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US2000/018721 Ceased WO2001005600A1 (fr) 1999-07-16 2000-07-10 Matiere d'enregistrement a jet d'encre thermoretrecissable

Country Status (1)

Country Link
WO (1) WO2001005600A1 (fr)

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7022385B1 (en) * 2001-10-04 2006-04-04 Nucoat, Inc. Laminated imaged recording media
WO2008115374A1 (fr) * 2007-03-16 2008-09-25 Asutosh Nigam Support d'impression jet d'encre pour images métalliques ou semi-métalliques avec surface réceptive à l'encre plus une couche de dessus ou de fond adhésive, et éventuellement une couche de protection amovible, la surface de la couche adhésive pouvant s'appliquer sur des articles tex
WO2009085134A1 (fr) * 2007-12-21 2009-07-09 Eastman Kodak Company Procédé permettant d'utiliser un support de réception aux propriétés adaptables
WO2011117574A1 (fr) 2010-03-26 2011-09-29 Cambridge Display Technology Limited Dispositif électroluminescent organique
JP2014211395A (ja) * 2013-04-19 2014-11-13 国立大学法人島根大学 塗料乾燥に伴う溶剤の密度推定法
EP3106316A2 (fr) 2015-06-15 2016-12-21 Sihl GmbH Film rétrécissable multicouche imprimable par jet d'encre
CN112068410A (zh) * 2020-09-24 2020-12-11 江苏兴广包装科技有限公司 一种直写式全息微缩加密方法
CN115923366A (zh) * 2021-08-27 2023-04-07 精工爱普生株式会社 喷墨记录方法及被包装体的包装方法

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4102456A (en) * 1977-01-21 1978-07-25 K & B Innovations, Inc. Kit for three-dimensional plastic objects
US4461793A (en) * 1983-02-07 1984-07-24 W. H. Brady Co. Printable coating for heatshrinkable materials
EP0899121A1 (fr) * 1997-08-26 1999-03-03 Arkwright Inc. Matériau thermorétractable pour l'impression par jet d'encre

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4102456A (en) * 1977-01-21 1978-07-25 K & B Innovations, Inc. Kit for three-dimensional plastic objects
US4461793A (en) * 1983-02-07 1984-07-24 W. H. Brady Co. Printable coating for heatshrinkable materials
EP0899121A1 (fr) * 1997-08-26 1999-03-03 Arkwright Inc. Matériau thermorétractable pour l'impression par jet d'encre

Cited By (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7022385B1 (en) * 2001-10-04 2006-04-04 Nucoat, Inc. Laminated imaged recording media
WO2008115374A1 (fr) * 2007-03-16 2008-09-25 Asutosh Nigam Support d'impression jet d'encre pour images métalliques ou semi-métalliques avec surface réceptive à l'encre plus une couche de dessus ou de fond adhésive, et éventuellement une couche de protection amovible, la surface de la couche adhésive pouvant s'appliquer sur des articles tex
WO2009085134A1 (fr) * 2007-12-21 2009-07-09 Eastman Kodak Company Procédé permettant d'utiliser un support de réception aux propriétés adaptables
WO2011117574A1 (fr) 2010-03-26 2011-09-29 Cambridge Display Technology Limited Dispositif électroluminescent organique
DE112011101062T5 (de) 2010-03-26 2013-01-03 Cambridge Display Technology Limited Organische elektrolumineszierende Vorrichtung
JP2014211395A (ja) * 2013-04-19 2014-11-13 国立大学法人島根大学 塗料乾燥に伴う溶剤の密度推定法
EP3106316A2 (fr) 2015-06-15 2016-12-21 Sihl GmbH Film rétrécissable multicouche imprimable par jet d'encre
US10442232B2 (en) 2015-06-15 2019-10-15 Sihl Gmbh Inkjet printable multi-layer shrink film
CN112068410A (zh) * 2020-09-24 2020-12-11 江苏兴广包装科技有限公司 一种直写式全息微缩加密方法
CN112068410B (zh) * 2020-09-24 2021-04-20 江苏兴广包装科技有限公司 一种直写式全息微缩加密方法
CN115923366A (zh) * 2021-08-27 2023-04-07 精工爱普生株式会社 喷墨记录方法及被包装体的包装方法
CN115923366B (zh) * 2021-08-27 2025-08-01 精工爱普生株式会社 喷墨记录方法及被包装体的包装方法

Similar Documents

Publication Publication Date Title
US6299967B1 (en) Ink jet recording media for use in making temporary tattoos and processes thereof
KR101479286B1 (ko) 수압 전사 방법, 수압 전사용 전사 필름 및 수압 전사품
US6716504B2 (en) Decorative sticker sheet
JPH11314498A (ja) プラッシュ模様付きの多色フロック転写
US8114485B1 (en) Water resistant shrinkable medium for receiving ink
US20240359425A1 (en) Method for producing discoloring body
US5951057A (en) Greeting card having removable decal section
WO2001005600A1 (fr) Matiere d'enregistrement a jet d'encre thermoretrecissable
KR100473741B1 (ko) 실크스크린 반사 전사품 및 그 제조방법
US3589955A (en) Oil painting simulation and the like
US7699458B2 (en) Provision of images on surfaces
US7056121B2 (en) Kit for decorating a holographic image bearing panel
US4046936A (en) Imprinted compressible foam article and method of manufacture
JPS60224595A (ja) ライテイングボ−ドの製造方法
Parraman Colour printing techniques and new developments in colour printing
JP2000308516A5 (fr)
JP2000308516A (ja) 付け爪の製造方法
JPS6238160B2 (fr)
JP2918971B2 (ja) 凹凸模様付与用熱転写シート
KR20000047031A (ko) 신규의인쇄용전사조성물,이를이용한인쇄방법및장치
JPH106700A (ja) 絵画風に仕上げたインクジェット画像及びその制作方法
JPH1143869A (ja) シート状印刷物の製造方法
JPH08276651A (ja) 立体印刷されたシールおよびその製造方法
JP3753344B2 (ja) 隠しメッセージの作成方法
JP7341739B2 (ja) 変色体、変色体セット

Legal Events

Date Code Title Description
AK Designated states

Kind code of ref document: A1

Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW

AL Designated countries for regional patents

Kind code of ref document: A1

Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG

121 Ep: the epo has been informed by wipo that ep was designated in this application
DFPE Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101)
REG Reference to national code

Ref country code: DE

Ref legal event code: 8642

122 Ep: pct application non-entry in european phase
NENP Non-entry into the national phase

Ref country code: JP