WO2001078673A2 - Non-staining antiperspirant cosmetic composition - Google Patents
Non-staining antiperspirant cosmetic composition Download PDFInfo
- Publication number
- WO2001078673A2 WO2001078673A2 PCT/FR2001/001112 FR0101112W WO0178673A2 WO 2001078673 A2 WO2001078673 A2 WO 2001078673A2 FR 0101112 W FR0101112 W FR 0101112W WO 0178673 A2 WO0178673 A2 WO 0178673A2
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- salt
- aluminum
- composition
- manganese
- active material
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q15/00—Anti-perspirants or body deodorants
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/26—Aluminium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/19—Cosmetics or similar toiletry preparations characterised by the composition containing inorganic ingredients
- A61K8/28—Zirconium; Compounds thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/52—Stabilizers
Definitions
- the subject of the present invention is an antiperspirant cosmetic composition
- a cosmetically acceptable vehicle at least one salt or an aluminum complex and characterized in that it also comprises at least one water-soluble salt of divalent manganese as agent stain inhibitor.
- It also relates to a process for reducing or eliminating staining of clothing induced by an antiperspirant cosmetic composition based on salt or on aluminum complex.
- antiperspirant substances which have the effect of limiting the sweat flow. They generally consist of aluminum salts or aluminum and zirconium complexes.
- ZAG complexes usually have an Al / Zr quotient ranging from approximately 1.67 to 12.5 and a Metal / Cl quotient ranging from approximately 0.73 to 1.93.
- the preferred amino acid for preparing such ZAG complexes is glycine.
- Said antiperspirant substances currently used and approved by the FDA include aluminum chloride, aluminum hydrochloride, aluminum chlorohydrex, aluminum chlorohydrex PEG, aluminum chlorohydrex PG, aluminum dichlorohydrate , aluminum dichlorohydrex PEG, aluminum dichlorohydrex PG, aluminum sesquichlorohydrate, aluminum sesquichlorohydrex PEG, aluminum sesquichlorohydrex PG, aluminum sulfate, aluminum zirconium octachlorohydrate, aluminum zirconium octachlorohydrex GLY, aluminum zirconium pentachlorohydrate, aluminum zirconium pentachlorohydrex GLY, aluminum zirconium tetrachlorohydrate, aluminum zirconium trichlorohydrate, aluminum zirconium tetrachlorohydrate GLY, and aluminum zirconium trichlorohydrate-GLY.
- Said aluminum salts are generally present in the antiperspirant compositions at a concentration of between approximately
- this type of antiperspirant active agent has the significant disadvantage of sometimes staining clothing.
- the appearance of a yellow stain on the tissues has been observed, particularly when the latter have been impregnated with the constituents of the sweat secreted at the axillary level.
- this yellow stain is on the contrary accentuated by washing, and the heat (electric dryer, ironing or pressing) can further accentuate the intensity of the coloring.
- the present invention thus has for first object, an antiperspirant cosmetic composition comprising, in a cosmetically acceptable vehicle, at least one salt or an aluminum complex, and characterized in that it also comprises at least one water-soluble manganese salt divalent as a stain inhibitor. It also relates to a process for reducing or eliminating staining of clothing induced by an antiperspirant cosmetic composition comprising at least one aluminum salt or complex, by adding to said composition, from 0.1 to 15% of active material. by weight of a water-soluble salt of divalent manganese as a stain inhibitor.
- a water-soluble salt of divalent manganese as a stain-inhibiting agent in an antiperspirant cosmetic composition comprising at least one salt or an aluminum complex.
- the aluminum salts used in the antiperspirant cosmetic compositions and described above there may be mentioned more particularly the aluminum hydrochloride marketed by the company CLARIANT under the name LOCRON S, the aluminum hydroxychloride marketed by the company REHEIS under the name REACH 301 or by the company GUILINI CHEMIE under the name ALOXICOLL PF 40, the aluminum pentahydroxychloride / zirconium complex sold in aqueous solution at 40% of active material by the company REHEIS under the name REZAL 67 SOLUTION, the salt of aluminum and zirconium sold by the company REHEIS under the name REACH A2P-908-SUF.
- the aluminum hydrochloride marketed by the company CLARIANT under the name LOCRON S the aluminum hydroxychloride marketed by the company REHEIS under the name REACH 301 or by the company GUILINI CHEMIE under the name ALOXICOLL PF 40
- Said aluminum salts or complexes are present in the compositions according to the present invention in the concentrations indicated above, that is to say between approximately 1 and 40% by weight and preferably between 5 and 30% by weight of Active Matter by relative to the total weight of the composition.
- water-soluble manganese salts is understood to mean manganese salts of organic or mineral acids whose solubility in water, expressed as a percentage by weight of Mn ion, is greater than or equal to 0.3.
- Particularly preferred water-soluble manganese salts according to the present invention are manganese chloride, manganese acetate, manganese sulfate, manganese gluconate, manganese pidolate.
- manganese chloride MnCl2
- the divalent manganese salts according to the invention represent 0.1 to 15% of active material by weight approximately of the total weight of the antiperspirant cosmetic composition, preferably 0.25 to 10% by weight approximately of this weight, and preferably 0 , About 5 to 5% of this weight.
- the antiperspirant cosmetic composition according to the invention is conventionally formulated according to the form of presentation for which it is intended.
- a cosmetically acceptable vehicle which may in particular be essentially aqueous, or contain organic solvents and in particular C- ⁇ -C monoalcohols, preferably ethanol to accelerate the evaporation of the product, or propylene glycol, dipropylene glycol or their ethers.
- the antiperspirant cosmetic composition according to the invention can also be formulated as a water-in-oil, water-in-silicone, oil-in-water emulsion, or as a triple water-in-oil-in-water emulsion (such emulsions are known and described for example by C. FOX in "Cosmetics and Toiletries” - November 1986 - Vol 101 - pages 101-112).
- the antiperspirant cosmetic composition of the invention may also comprise cosmetic adjuvants chosen from fatty substances, gelling agents, emollients, softeners, antioxidants, opacifiers, stabilizers, anti-foaming agents, hydrating agents, vitamins, perfumes, preservatives, surfactants, fillers, sequestrants, polymers, propellants, basifying or acidifying agents, perfumes, dyes, pigments, thickening agents, or any other ingredient usually used in cosmetics for this type of application.
- cosmetic adjuvants chosen from fatty substances, gelling agents, emollients, softeners, antioxidants, opacifiers, stabilizers, anti-foaming agents, hydrating agents, vitamins, perfumes, preservatives, surfactants, fillers, sequestrants, polymers, propellants, basifying or acidifying agents, perfumes, dyes, pigments, thickening agents, or any other ingredient usually used in cosmetics for this type of application.
- the surfactants are preferably chosen from anionic, amphoteric or nonionic surfactants.
- the fatty substances can consist of an oil or a wax or their mixture, petroleum jelly, paraffin, lanolin, hydrogenated lanolin, acetylated lanolin; they also include fatty acids, fatty alcohols such as lauric, cetyl, myristic, stearic, palmitic, oleic alcohol as well as 2-octyldodecanol, fatty acid esters such as glycerol monostearate, polyethylene glycol monostearate , isopropyl myristate, isopropyl adipate, isopropyl palmitate, octyl palmitate, C-12-C15 fatty alcohol benzoates (Finsolv TN from FINETEX), polyoxypropylenated myristic alcohol with 3 moles of propylene oxide (WITCONOL APM from WITCO), the triglycerides of fatty acids CQ-C ⁇ Q such as triglycerides of caprylic / capric acid.
- oils are chosen from animal, vegetable, mineral or synthetic oils and in particular hydrogenated palm oil, hydrogenated castor oil, petroleum jelly oil, paraffin oil, Purcellin oil (octanoate stearyl), silicone oils and isoparaffins.
- the waxes are chosen from animal, fossil, vegetable, mineral or synthetic waxes. Mention may in particular bees beeswax, Carnauba, Candelila, sugar cane, jojoba, Japanese wax, ozokerites, Montan wax, microcrystalline waxes, paraffins, waxes and silicone resins .
- the thickeners preferably nonionic, can be chosen from guar gums and modified or unmodified celluloses such as hydroxypropylated guar gum, cetylhydroxyethylcellulose, silicas such as, for example, Bentone Gel MiO sold by the company NL INDUSTRIES or Veegum Ultra, sold by the company POLYPLASTIC.
- the antiperspirant cosmetic composition may comprise emollients, which contribute to a soft, dry feeling, which is non-sticky when the composition is applied to the skin.
- emollients can be chosen from products of the volatile silicone type, non-volatile silicones and other non-volatile emollients.
- Volatile silicones are defined in a known manner as volatile compounds at room temperature. Among these compounds, mention may be made of cyclic and linear volatile silicones of the dimethylsiloxane type, the chains of which comprise from 3 to 9 silicone residues. Preferably, cyclomethicones D4 or D5 are chosen.
- Non-volatile silicones are defined in a known manner as compounds with low vapor pressure at room temperature.
- polyalkylsiloxanes in particular linear polyalkylsiloxanes such as, for example, linear polydimethylsiloxanes, or dimethicones, sold by the company Dow Corning under the name of "Dow Corning 200 Fluid”
- polyalkylarylsiloxanes such as, for example, polymethylphenylsiloxanes, sold by the company Dow Corning under the name of "Dow Corning 556 Fluid”
- polyether and siloxane copolymers such as, for example, dimethicone copolyols.
- non-volatile emollients which can be used in the present invention, there may be mentioned for example: hydrocarbon derivatives, mineral oils, fatty alcohols, alcohol esters of C3-C1 8 with C 3 -C ⁇ 8 acids, esters of benzoic acid with alcohols C ⁇ -C ⁇ s 2 and mixtures thereof, polyols, C 2 -C 6 preferably chosen from glycerol, propylene glycol or sorbitol, polyalkylene glycol polymers.
- the antiperspirant cosmetic composition according to the invention can thus be in the form of a lotion, cream or fluid gel distributed in aerosol spray, in pump bottle or in roll-on, in the form of thick cream distributed in tube and in stick form. or powder, and contain in this regard the ingredients and propellants generally used in this type of product and well known to those skilled in the art. Concrete, but in no way limiting, examples illustrating the invention will now be given.
- Natural sweat was taken from the armpits of 5 volunteers, the phenomenon of sweating having been induced by thermal stimulation (sauna at 80 ° C). The sweat samples were stored in crushed ice and then mixed before use.
- the cotton squares [A] [B] [C] [T2] and [T1] were then placed on a perforated metal plate covered with a non-woven towel, and on top of it, a micro plastic film -wave, in order to create a semi-occlusive medium mimicking the armpit.
- the metal plate was then placed in an oven thermostatically controlled at 37 ° C for 16 hours, simulating a day of wearing a garment.
- the cotton squares were separated from the gauze pads, machine washed at 40 ° C with 150 ml of SUPER BLUE CROSS gel, then machine dried.
- the intensity of the stain after washing was evaluated by colorimetric measurement
- the 3 parameters respectively designate the intensity (L *), the green / red color axis (a *), and the blue / yellow color axis (b *).
- Wax mixture microcrystalline wax / beeswax / 1.00 g polyethylene
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
Description
COMPOSITION COSMETIQUE ANTITRANSPIRANTE NE TACHANT PAS LES VETEMENTS ANTITRANSPIRANT COSMETIC COMPOSITION THAT DOES NOT STAIN CLOTHING
La présente invention a pour objet une composition cosmétique antitranspirante comprenant dans un véhicule cosmétiquement acceptable au moins un sel ou un complexe d'aluminium et caractérisée par le fait qu'elle comprend en outre au moins un sel hydrosoluble de manganèse divalent à titre d'agent inhibiteur de tachage.The subject of the present invention is an antiperspirant cosmetic composition comprising in a cosmetically acceptable vehicle at least one salt or an aluminum complex and characterized in that it also comprises at least one water-soluble salt of divalent manganese as agent stain inhibitor.
Elle concerne également un procédé pour réduire ou supprimer le tachage des vêtements induit par une composition cosmétique antitranspirante à base de sel ou de complexe d'aluminium.It also relates to a process for reducing or eliminating staining of clothing induced by an antiperspirant cosmetic composition based on salt or on aluminum complex.
Dans le domaine cosmétique, il est bien connu d'utiliser en application topique, des substances antitranspirantes qui ont pour effet de limiter le flux sudoral. Elles sont généralement constituées de sels d'aluminium ou de complexes d'aluminium et de zirconium.In the cosmetic field, it is well known to use in topical application, antiperspirant substances which have the effect of limiting the sweat flow. They generally consist of aluminum salts or aluminum and zirconium complexes.
Parmi les sels d'aluminium, on peut citer le chlorure d'aluminium et les hydroxyhalogénures d'aluminium. Dans le brevet USA N°. 3792068, on a décrit des complexes d'aluminum, de zirconium et d'amino-acides tels que la glycine. De tels complexes sont généralement connus sous l'appellation ZAG. Les complexes ZAG présentent d'ordinaire un quotient Al/Zr allant d'environ 1 ,67 à 12,5 et un quotient Métal/Cl allant d'environ 0,73 à 1 ,93. L'amino-acide préféré pour préparer de tels complexes ZAG est la glycine.Among the aluminum salts, mention may be made of aluminum chloride and aluminum hydroxyhalides. In USA patent no. 3792068, complexes of aluminum, zirconium and amino acids such as glycine have been described. Such complexes are generally known by the name ZAG. ZAG complexes usually have an Al / Zr quotient ranging from approximately 1.67 to 12.5 and a Metal / Cl quotient ranging from approximately 0.73 to 1.93. The preferred amino acid for preparing such ZAG complexes is glycine.
Lesdites substances antitranspirantes actuellement utilisées et approuvées par la F.D.A. (Food & Drug Administration) comprennent le chlorure d'aluminium, le chlorhydrate d'aluminium, l'aluminum chlorohydrex, l'aluminum chlorohydrex PEG, l'aluminum chlorohydrex PG, l'aluminum dichlorohydrate, l'aluminum dichlorohydrex PEG, l'aluminum dichlorohydrex PG, l'aluminum sesquichlorohydrate, l'aluminum sesquichlorohydrex PEG, l'aluminum sesquichlorohydrex PG, l'aluminum sulfate, l'aluminum zirconium octachlorohydrate, l'aluminum zirconium octachlorohydrex GLY, l'aluminum zirconium pentachlorohydrate, l'aluminum zirconium pentachlorohydrex GLY, l'aluminum zirconium tetrachlorohydrate, l'aluminum zirconium trichlorohydrate, l'aluminum zirconium tetrachlorohydrate GLY, et l'aluminum zirconium trichlorohydrate-GLY. Lesdits sels d'aluminium sont généralement présents dans les compositions antitranspirantes à une concentration comprise entre environ 1 et 40%, de préférence entre 5 et 30% et plus particulièrement entre 8 et 15% en poids par rapport au poids total des compositions.Said antiperspirant substances currently used and approved by the FDA (Food & Drug Administration) include aluminum chloride, aluminum hydrochloride, aluminum chlorohydrex, aluminum chlorohydrex PEG, aluminum chlorohydrex PG, aluminum dichlorohydrate , aluminum dichlorohydrex PEG, aluminum dichlorohydrex PG, aluminum sesquichlorohydrate, aluminum sesquichlorohydrex PEG, aluminum sesquichlorohydrex PG, aluminum sulfate, aluminum zirconium octachlorohydrate, aluminum zirconium octachlorohydrex GLY, aluminum zirconium pentachlorohydrate, aluminum zirconium pentachlorohydrex GLY, aluminum zirconium tetrachlorohydrate, aluminum zirconium trichlorohydrate, aluminum zirconium tetrachlorohydrate GLY, and aluminum zirconium trichlorohydrate-GLY. Said aluminum salts are generally present in the antiperspirant compositions at a concentration of between approximately 1 and 40%, preferably between 5 and 30% and more particularly between 8 and 15% by weight relative to the total weight of the compositions.
Ce type d'actif antitranspirant présente cependant l'inconvénient non négligeable de tacher parfois les vêtements. Ainsi, on a observé l'apparition d'un tachage jaune sur les tissus, particulièrement lorsque ceux-ci ont été imprégnés par les constituants de la sueur sécrétée au niveau axillaire. En outre, au lieu d'être éliminé par un cycle normal de lavage en machine, ce tachage jaune est au contraire accentué par le lavage, et la chaleur (séchoir électrique, repassage ou pressing) peut encore accentuer l'intensité de la coloration.However, this type of antiperspirant active agent has the significant disadvantage of sometimes staining clothing. Thus, the appearance of a yellow stain on the tissues has been observed, particularly when the latter have been impregnated with the constituents of the sweat secreted at the axillary level. In addition, instead of being eliminated by a normal machine wash cycle, this yellow stain is on the contrary accentuated by washing, and the heat (electric dryer, ironing or pressing) can further accentuate the intensity of the coloring.
En raison de leur caractère non facilement réversible, ces inconvénients apparaissent très gênants pour le consommateur.Because of their not easily reversible nature, these drawbacks appear to be very troublesome for the consumer.
Après de nombreuses recherches menées sur la question, la Demanderesse a maintenant découvert, de façon inattendue et surprenante, qu'en introduisant dans une composition cosmétique antitranspirante à base d'actif antitranspirant choisi parmi les sels ou les complexes d'aluminium, un sel hydrosoluble de manganèse divalent, on pouvait réduire efficacement l'intensité du tachage jaune des vêtements révélé notamment au cours de leur lavage.After numerous researches carried out on the question, the Applicant has now discovered, unexpectedly and surprisingly, that by introducing into an antiperspirant cosmetic composition based on antiperspirant active agent chosen from aluminum salts or complexes, a water-soluble salt of divalent manganese, it was possible to effectively reduce the intensity of the yellow stain on clothes revealed, especially during washing.
Cette découverte est à la base de la présente invention.This discovery is the basis of the present invention.
La présente invention a ainsi pour premier objet, une composition cosmétique antitranspirante comprenant, dans un véhicule cosmétiquement acceptable, au moins un sel ou un complexe d'aluminium, et caractérisée par le fait qu'elle comprend en outre au moins un sel hydrosoluble de manganèse divalent à titre d'agent inhibiteur de tachage. Elle a également pour objet, un procédé pour réduire ou supprimer le tachage des vêtements induit par une composition cosmétique antitranspirante comprenant au moins un sel ou un complexe d'aluminium, par adjonction à ladite composition, de 0,1 à 15 % de Matière Active en poids d'un sel hydrosoluble de manganèse divalent à titre d'inhibiteur de tachage.The present invention thus has for first object, an antiperspirant cosmetic composition comprising, in a cosmetically acceptable vehicle, at least one salt or an aluminum complex, and characterized in that it also comprises at least one water-soluble manganese salt divalent as a stain inhibitor. It also relates to a process for reducing or eliminating staining of clothing induced by an antiperspirant cosmetic composition comprising at least one aluminum salt or complex, by adding to said composition, from 0.1 to 15% of active material. by weight of a water-soluble salt of divalent manganese as a stain inhibitor.
Elle a aussi pour objet l'utilisation d'un sel hydrosoluble de manganèse divalent comme agent inhibiteur de tachage dans une composition cosmétique antitranspirante comprenant au moins un sel ou un complexe d'aluminium.It also relates to the use of a water-soluble salt of divalent manganese as a stain-inhibiting agent in an antiperspirant cosmetic composition comprising at least one salt or an aluminum complex.
Parmi les sels d'aluminium utilisés dans les compositions cosmétiques antitranspirantes et décrits ci-dessus, on peut citer plus particulièrement le chlorhydrate d'aluminium commercialisé par la société CLARIANT sous la dénomination LOCRON S, l'hydroxychlorure d'aluminium commercialisé par la société REHEIS sous la dénomination REACH 301 ou par la société GUILINI CHEMIE sous la dénomination ALOXICOLL PF 40, le complexe pentahydroxychlorure d'aluminium / zirconium vendu en solution aqueuse à 40% de matière active par la société REHEIS sous la dénomination REZAL 67 SOLUTION, le sel d'aluminium et de zirconium commercialisé par la société REHEIS sous la dénomination REACH A2P-908-SUF .Among the aluminum salts used in the antiperspirant cosmetic compositions and described above, there may be mentioned more particularly the aluminum hydrochloride marketed by the company CLARIANT under the name LOCRON S, the aluminum hydroxychloride marketed by the company REHEIS under the name REACH 301 or by the company GUILINI CHEMIE under the name ALOXICOLL PF 40, the aluminum pentahydroxychloride / zirconium complex sold in aqueous solution at 40% of active material by the company REHEIS under the name REZAL 67 SOLUTION, the salt of aluminum and zirconium sold by the company REHEIS under the name REACH A2P-908-SUF.
Lesdits sels ou complexes d'aluminium sont présents dans les compositions selon la présente invention dans les concentrations indiquées ci-avant c'est à dire entre environ 1 et 40% en poids et de préférence entre 5 et 30% en poids de Matière Active par rapport au poids total de la composition.Said aluminum salts or complexes are present in the compositions according to the present invention in the concentrations indicated above, that is to say between approximately 1 and 40% by weight and preferably between 5 and 30% by weight of Active Matter by relative to the total weight of the composition.
Au sens de la présente invention, on entend par sels hydrosolubles de manganèse des sels de manganèse d'acides organiques ou minéraux dont la solubilité dans l'eau, exprimée en pourcentage pondéral d'ion Mn, est supérieure ou égale à 0,3 . Des sels hydrosolubles de manganèse particulièrement préférés selon la présente invention sont le chlorure de manganèse, l'acétate de manganèse, le sulfate de manganèse, le gluconate de manganèse, le pidolate de manganèse. Parmi les sels mentionnés ci-avant, on préfère encore plus particulièrement utiliser, selon la présente invention, le chlorure de manganèse (MnCl2).For the purposes of the present invention, the term water-soluble manganese salts is understood to mean manganese salts of organic or mineral acids whose solubility in water, expressed as a percentage by weight of Mn ion, is greater than or equal to 0.3. Particularly preferred water-soluble manganese salts according to the present invention are manganese chloride, manganese acetate, manganese sulfate, manganese gluconate, manganese pidolate. Among the salts mentioned above, it is even more particularly preferred to use, according to the present invention, manganese chloride (MnCl2).
Les sels de manganèse divalent selon l'invention représentent 0,1 à 15 % de Matière Active en poids environ du poids total de la composition cosmétique antitranspirante, de préférence 0,25 à 10 % en poids environ de ce poids, et de préférence 0,5 à 5 % environ de ce poids.The divalent manganese salts according to the invention represent 0.1 to 15% of active material by weight approximately of the total weight of the antiperspirant cosmetic composition, preferably 0.25 to 10% by weight approximately of this weight, and preferably 0 , About 5 to 5% of this weight.
La composition cosmétique antitranspirante selon l'invention est formulée classiquement selon la forme de présentation à laquelle elle est destinée.The antiperspirant cosmetic composition according to the invention is conventionally formulated according to the form of presentation for which it is intended.
Elle est plus particulièrement formulée dans un véhicule cosmétiquement acceptable qui peut être notamment essentiellement aqueux, ou contenir des solvants organiques et notamment des monoalcools en C-ι-C , de préférence de l'éthanol pour accélérer l'évaporation du produit, ou du propylène glycol, du dipropylène glycol ou leurs éthers.It is more particularly formulated in a cosmetically acceptable vehicle which may in particular be essentially aqueous, or contain organic solvents and in particular C-ι-C monoalcohols, preferably ethanol to accelerate the evaporation of the product, or propylene glycol, dipropylene glycol or their ethers.
La composition cosmétique antitranspirante selon l'invention peut également être formulée en émulsion eau-dans-huile, eau-dans-silicone, huile-dans-eau, ou en émulsion triple eau-dans-huile-dans-eau, (de telles émulsions sont connues et décrites par exemple par C. FOX dans « Cosmetics and Toiletries » - november 1986 - Vol 101 - pages 101-112).The antiperspirant cosmetic composition according to the invention can also be formulated as a water-in-oil, water-in-silicone, oil-in-water emulsion, or as a triple water-in-oil-in-water emulsion (such emulsions are known and described for example by C. FOX in "Cosmetics and Toiletries" - November 1986 - Vol 101 - pages 101-112).
La composition cosmétique antitranspirante de l'invention peut comprendre en outre des adjuvants cosmétiques choisis parmi les corps gras, les gélifiants, les émollients, les adoucissants, les antioxydants, les opacifiants, les stabilisants, les agents anti-mousse, les agents hydratants, les vitamines, les parfums, les conservateurs, les tensioactifs, les charges, les séquestrants, les polymères, les propulseurs, les agents alcalinisants ou acidifiants, les parfums, les colorants, les pigments, les agents épaississants, ou tout autre ingrédient habituellement utilisé en cosmétique pour ce type d'application. Bien entendu, l'homme de métier veillera à choisir ce ou ces éventuels composés complémentaires de manière telle que les propriétés avantageuses attachées intrinsèquement à la composition cosmétique antitranspirante conforme à l'invention ne soient pas, ou substantiellement pas, altérées par la ou les adjonctions envisagées.The antiperspirant cosmetic composition of the invention may also comprise cosmetic adjuvants chosen from fatty substances, gelling agents, emollients, softeners, antioxidants, opacifiers, stabilizers, anti-foaming agents, hydrating agents, vitamins, perfumes, preservatives, surfactants, fillers, sequestrants, polymers, propellants, basifying or acidifying agents, perfumes, dyes, pigments, thickening agents, or any other ingredient usually used in cosmetics for this type of application. Of course, the person skilled in the art will take care to choose this or these optional additional compounds in such a way that the advantageous properties intrinsically attached to the antiperspirant cosmetic composition in accordance with the invention is not, or is not substantially, altered by the proposed addition (s).
Les tensio-actifs sont choisis de préférence parmi les tensio-actifs anioniques, amphotères ou non-ioniques.The surfactants are preferably chosen from anionic, amphoteric or nonionic surfactants.
Les corps gras peuvent être constitués par une huile ou une cire ou leur mélange, la vaseline, la paraffine, la lanoline, la lanoline hydrogénée, la lanoline acétylée ; ils comprennent également les acides gras, les alcools gras tels que l'alcool laurique, cétylique, myristique, stéarique, palmitique, oléique ainsi que le 2- octyldodécanol, les esters d'acides gras tels que le monostéarate de glycerol, le monostéarate de polyéthylèneglycol, le myristate d'isopropyle, l'adipate d'isopropyle, le palmitate d'isopropyle, le palmitate d'octyle, les benzoates d'alcools gras en C-12-C15 (Finsolv TN de FINETEX), l'alcool myristique polyoxypropyléné à 3 moles d'oxyde de propylène (WITCONOL APM de WITCO), les triglycérides d'acides gras en CQ-C^ Q tels que les triglycérides d'acide caprylique/caprique.The fatty substances can consist of an oil or a wax or their mixture, petroleum jelly, paraffin, lanolin, hydrogenated lanolin, acetylated lanolin; they also include fatty acids, fatty alcohols such as lauric, cetyl, myristic, stearic, palmitic, oleic alcohol as well as 2-octyldodecanol, fatty acid esters such as glycerol monostearate, polyethylene glycol monostearate , isopropyl myristate, isopropyl adipate, isopropyl palmitate, octyl palmitate, C-12-C15 fatty alcohol benzoates (Finsolv TN from FINETEX), polyoxypropylenated myristic alcohol with 3 moles of propylene oxide (WITCONOL APM from WITCO), the triglycerides of fatty acids CQ-C ^ Q such as triglycerides of caprylic / capric acid.
Les huiles sont choisies parmi les huiles animales, végétales, minérales ou de synthèse et notamment l'huile de palme hydrogénée, l'huile de ricin hydrogénée, l'huile de vaseline, l'huile de paraffine, l'huile de Purcellin (octanoate de stéaryle), les huiles de silicone et les isoparaffines.The oils are chosen from animal, vegetable, mineral or synthetic oils and in particular hydrogenated palm oil, hydrogenated castor oil, petroleum jelly oil, paraffin oil, Purcellin oil (octanoate stearyl), silicone oils and isoparaffins.
Les cires sont choisies parmi les cires animales, fossiles, végétales, minérales ou de synthèse. On peut citer notamment les cires d'abeille, les cires de Carnauba, de Candelila, de canne à sucre, de jojoba, du Japon, les ozokérites, la cire de Montan, les cires microcristallines, les paraffines, les cires et résines de silicone. Les épaississants, de préférence non ioniques, peuvent être choisis parmi les gommes de guar et celluloses modifiées ou non modifiées telles que la gomme de guar hydroxypropylée, la cétylhydroxyéthylcellulose, les silices comme par exemple la Bentone Gel MiO vendue par la société NL INDUSTRIES ou la Veegum Ultra, vendue par la société POLYPLASTIC.The waxes are chosen from animal, fossil, vegetable, mineral or synthetic waxes. Mention may in particular bees beeswax, Carnauba, Candelila, sugar cane, jojoba, Japanese wax, ozokerites, Montan wax, microcrystalline waxes, paraffins, waxes and silicone resins . The thickeners, preferably nonionic, can be chosen from guar gums and modified or unmodified celluloses such as hydroxypropylated guar gum, cetylhydroxyethylcellulose, silicas such as, for example, Bentone Gel MiO sold by the company NL INDUSTRIES or Veegum Ultra, sold by the company POLYPLASTIC.
La composition cosmétique antitranspirante peut comprendre des émollients, qui contribuent à une sensation douce, sèche, non-collante à l'application de la composition sur la peau. Ces émollients peuvent être choisis parmi des produits du type silicone volatile, des silicones non-volatiles et d'autres émollients non- volatils.The antiperspirant cosmetic composition may comprise emollients, which contribute to a soft, dry feeling, which is non-sticky when the composition is applied to the skin. These emollients can be chosen from products of the volatile silicone type, non-volatile silicones and other non-volatile emollients.
Les silicones volatiles sont définies de façon connue comme des composés volatils à température ambiante. On peut citer parmi ces composés les silicones volatiles cycliques et linéaires du type diméthylsiloxane dont les chaînes comprennent de 3 à 9 résidus silicones. De préférence on choisit les cyclométhicones D4 ou D5.Volatile silicones are defined in a known manner as volatile compounds at room temperature. Among these compounds, mention may be made of cyclic and linear volatile silicones of the dimethylsiloxane type, the chains of which comprise from 3 to 9 silicone residues. Preferably, cyclomethicones D4 or D5 are chosen.
Les silicones non-volatiles sont définies de façon connue comme des composés de pression de vapeur faible à température ambiante. Parmi ces composés sont inclus : les polyalkylsiloxanes, en particulier les polyalkylsiloxanes linéaires comme par exemple les polydiméthylsiloxanes, ou diméthicones, linéaires, commercialisés par la société Dow Corning sous le nom de « Dow Corning 200 Fluid » ; les polyalkylarylsiloxanes comme par exemple les polyméthylphénylsiloxanes, commercialisés par la société Dow Corning sous le nom de « Dow Corning 556 Fluid » ; les copolymères polyéther et siloxane, comme par exemple les diméthicone copolyols.Non-volatile silicones are defined in a known manner as compounds with low vapor pressure at room temperature. Among these compounds are included: polyalkylsiloxanes, in particular linear polyalkylsiloxanes such as, for example, linear polydimethylsiloxanes, or dimethicones, sold by the company Dow Corning under the name of "Dow Corning 200 Fluid"; polyalkylarylsiloxanes such as, for example, polymethylphenylsiloxanes, sold by the company Dow Corning under the name of "Dow Corning 556 Fluid"; polyether and siloxane copolymers, such as, for example, dimethicone copolyols.
Parmi les émollients non-volatils utilisables dans la présente invention, on peut citer par exemple : les dérivés hydrocarbonés, les huiles minérales, les alcools gras, les esters d'alcools en C3-C18 avec des acides en C3-Cι8, les esters de l'acide benzoïque avec des alcools en Cι2-Cιs et leurs mélanges, des polyols en C2-C6 choisis de préférence parmi le glycerol, le propylèneglycol ou le sorbitol, les polymères de polalkylène glycol.Among the non-volatile emollients which can be used in the present invention, there may be mentioned for example: hydrocarbon derivatives, mineral oils, fatty alcohols, alcohol esters of C3-C1 8 with C 3 -Cι 8 acids, esters of benzoic acid with alcohols Cι -Cιs 2 and mixtures thereof, polyols, C 2 -C 6 preferably chosen from glycerol, propylene glycol or sorbitol, polyalkylene glycol polymers.
Les quantités de ces différents constituants pouvant être présents dans la composition cosmétique antitranspirante selon l'invention sont celles classiquement utilisées pour les formes de présentation considérées.The amounts of these various constituents which may be present in the antiperspirant cosmetic composition according to the invention are those conventionally used for the forms of presentation considered.
La composition cosmétique antitranspirante selon l'invention peut ainsi se présenter sous forme de lotion, de crème ou de gel fluide distribué en spray aérosol, en flacon pompe ou en roll-on, sous forme de crème épaisse distribuée en tube et sous forme de stick ou de poudre, et contenir à cet égard les ingrédients et propulseurs généralement utilisés dans ce type de produits et bien connus de l'homme de l'art. Des exemples concrets, mais nullement limitatifs, illustrant l'invention vont maintenant être donnés.The antiperspirant cosmetic composition according to the invention can thus be in the form of a lotion, cream or fluid gel distributed in aerosol spray, in pump bottle or in roll-on, in the form of thick cream distributed in tube and in stick form. or powder, and contain in this regard the ingredients and propellants generally used in this type of product and well known to those skilled in the art. Concrete, but in no way limiting, examples illustrating the invention will now be given.
EXEMPLE 1 :EXAMPLE 1:
Nous avons évalué la capacité du chlorure de manganèse à réduire le tachage jaune induit par le chlorhydrate d'aluminium sur les tissus en présence de sueur naturelle.We evaluated the ability of manganese chloride to reduce yellow staining induced by aluminum hydrochloride on tissues in the presence of natural sweat.
Les essais de tachage ont été réalisés sur tissu de coton blanc. Des carrés de 10 cm de côté ont été découpés dans des tee-shirts neufs, préalablement décatis par un lavage en machine à 90°C, avec une dose de 150 ml de lessive « SUPER CROIX BLEU ». 3 solutions aqueuses ont été testées comparativement à 2 témoins : -solutions aqueuses :The staining tests were carried out on white cotton fabric. Squares with a side of 10 cm were cut from new T-shirts, previously decatified by machine washing at 90 ° C, with a dose of 150 ml of "SUPER CROIX BLEU" detergent. 3 aqueous solutions were tested compared to 2 controls: -aqueous solutions:
- [A] → MnCi2 (3 %)- [A] → MnCi2 (3%)
- [B] → Hydroxychlorure d'aluminium (15 %)- [B] → Aluminum hydroxychloride (15%)
- [C] → Association:- [C] → Association:
MnCl2 (3 %) + hydroxychlorure d'aluminium (15 %)MnCl2 (3%) + aluminum hydroxychloride (15%)
-témoins :- witnesses:
- [T1] carré de coton non traité par l'une des solutions aqueuses , sans contact avec la sueur naturelle,- [T1] cotton square not treated with one of the aqueous solutions, without contact with natural sweat,
- [T2] carré de coton non traité par l'une des solutions aqueuses, mais mis en contact avec la sueur naturelle.- [T2] cotton square not treated with one of the aqueous solutions, but brought into contact with natural sweat.
De la sueur naturelle a été prélevée au niveau des aisselles sur 5 volontaires, le phénomène de transpiration ayant été induit par stimulation thermique (sauna à 80°C). Les prélèvements de sueur ont été conservés dans de la glace pilée, puis mélangés avant utilisation.Natural sweat was taken from the armpits of 5 volunteers, the phenomenon of sweating having been induced by thermal stimulation (sauna at 80 ° C). The sweat samples were stored in crushed ice and then mixed before use.
0,4 ml de chacune des 3 solutions aqueuses [A], [B], [C] ont été appliqués au centre de 3 carrés de coton. Puis une compresse de gaze de 5x7 cm imbibée de 4 ml de sueur naturelle a été déposée sur les carrés de coton imprégnés des solutions [A] [B] [C] et sur le tissu0.4 ml of each of the 3 aqueous solutions [A], [B], [C] were applied to the center of 3 cotton squares. Then a 5x7 cm gauze pad soaked in 4 ml of natural sweat was placed on the cotton squares impregnated with the solutions [A] [B] [C] and on the fabric
[T2].[T2].
Les carrés de coton [A] [B] [C] [T2] ont été ensuite plies en deux, la compresse de gaze imbibée de sueur à l'intérieur.The cotton squares [A] [B] [C] [T2] were then folded in half, the gauze pad soaked in sweat inside.
Les carrés de coton [A] [B] [C] [T2] et [T1] ont ensuite été disposés sur une plaque métallique perforée recouverte d'une serviette en non-tissé, et par dessus, d'un film plastique type micro-onde, afin de créer un milieu semi-occlusif mimant l'aisselle. La plaque métallique a été ensuite placée dans une étuve thermostatée à 37°C, pendant 16 heures, simulant une journée de port d'un vêtement.The cotton squares [A] [B] [C] [T2] and [T1] were then placed on a perforated metal plate covered with a non-woven towel, and on top of it, a micro plastic film -wave, in order to create a semi-occlusive medium mimicking the armpit. The metal plate was then placed in an oven thermostatically controlled at 37 ° C for 16 hours, simulating a day of wearing a garment.
Après traitement, les carrés de coton ont été séparés des compresses de gaze, lavés en machine à 40°C avec 150 ml de gel SUPER CROIX BLEU, puis séchés en machine.After treatment, the cotton squares were separated from the gauze pads, machine washed at 40 ° C with 150 ml of SUPER BLUE CROSS gel, then machine dried.
L'intensité du tachage après lavage a été évalué par mesure colorimétriqueThe intensity of the stain after washing was evaluated by colorimetric measurement
[au colorimètre MINOLTA CM2002 dans le système L* a* b* ].[with the MINOLTA CM2002 colorimeter in the L * a * b * system].
Une triple mesure a été réalisée en des endroits différents du carré de coton.A triple measurement was carried out in different places of the cotton square.
Dans le système L* a* b* les 3 paramètres désignent respectivement l'intensité (L* ), l'axe de couleur vert/rouge (a* ), et l'axe de couleur bleu/jaune (b* ).In the L * a * b * system the 3 parameters respectively designate the intensity (L *), the green / red color axis (a *), and the blue / yellow color axis (b *).
La variation de la coloration (du tachage) DE par rapport au carré de coton témoin [T1] est calculée en appliquant l'équation suivante :The variation in the coloration (of the stain) DE with respect to the square of control cotton [T1] is calculated by applying the following equation:
Les résultats sont réunis dans le graphique I ci-après.The results are collated in Graph I below.
Ces mesures démontrent que le tachage a nettement diminué dans le cas où le chlorure de manganèse est présent dans la composition antitranspirante à base de chlorhydrate d'aluminium [C]. EXEMPLE 2 : Spray antitranspirant hvdroalcoolique (flacon-pompe)These measurements demonstrate that the stain has clearly decreased in the case where manganese chloride is present in the antiperspirant composition based on aluminum hydrochloride [C]. EXAMPLE 2 Antiperspirant spray hydroalcoholic (pump bottle)
MnCI2, 4H2O 3.50 gMnCI 2 , 4H 2 O 3.50 g
Chlorhydrate d'aluminium 25.00 gAluminum hydrochloride 25.00 g
Alcool éthylique 95 % vol. dénaturé 40.00 gEthyl alcohol 95% vol. denatured 40.00 g
Parfum q.sPerfume q.s
Eau déminéralisée qsp 100.00 gDemineralized water qs 100.00 g
EXEMPLE 3 : Roll-on hvdroalcoolique antitranspirant transparentEXAMPLE 3 Transparent anti-perspirant hvdroalcoholic roll-on
Alcool cétylique oxyéthyléné (20 OE) et oxypropyléné 2.00 gOxyethylenated (20 EO) and oxypropylenated cetyl alcohol 2.00 g
(5 OP)(5 OP)
Hydroxyéthylcellulose 0.75 gHydroxyethylcellulose 0.75 g
MnCI2, 4H2O 4.00 gMnCI 2 , 4H 2 O 4.00 g
Complexe pentahydroxychlorure d'aluminium / zirconium 45.00 g en solution aqueuse à 40 %Aluminum pentahydroxychloride / zirconium complex 45.00 g in 40% aqueous solution
Alcool éthylique 95 % vol. dénaturé 45.00 gEthyl alcohol 95% vol. denatured 45.00 g
Parfum q.sPerfume q.s
Eau déminéralisée qsp 100.00 gDemineralized water qs 100.00 g
EXEMPLE 4 : Emulsion antitranspirante eau-dans-siliconeEXAMPLE 4 Antiperspirant water-in-silicone emulsion
Silicone DC 245 Fluid (DOW CORNING) 6.60 gSilicone DC 245 Fluid (DOW CORNING) 6.60 g
Silicone DC 5225 C (DOW CORNING) 9.40 gSilicone DC 5225 C (DOW CORNING) 9.40 g
Alcool éthylique 15.00 gEthyl alcohol 15.00 g
Propylène glycol 17.00 g Complexe pentahydroxychlorure d'aluminium / zirconium en solution aqueuse à 40 % 48.00 gPropylene glycol 17.00 g Aluminum pentahydroxychloride / zirconium complex in 40% aqueous solution 48.00 g
MnCI2, 4H2O 4.50 gMnCI 2 , 4H 2 O 4.50 g
Parfum, conservateurs q.sPerfume, preservatives q.s
Eau déminéralisée qsp 100.00 gDemineralized water qs 100.00 g
EXEMPLE 5 : Emulsion antitranspirante Huile-dans-eauEXAMPLE 5 Oil-in-water antiperspirant emulsion
Mélange mono/distéarate de glycéryle / stéarate de polyethylène glycol (100 OE) 8.00 gMixture of mono / glyceryl distearate / polyethylene glycol stearate (100 EO) 8.00 g
Alcool cétylique 2.50 gCetyl alcohol 2.50 g
Mélange de cires : cire microcristalline / cire d'abeille / 1.00 g polyethylèneWax mixture: microcrystalline wax / beeswax / 1.00 g polyethylene
Cire liquide de jojoba 6.00 gLiquid jojoba wax 6.00 g
Myristate de myristyle oxyéthyléné (3 OE) 2.00 gOxyethylenated myristyl myristate (3 EO) 2.00 g
Chlorhydrate d'aluminium 20.00 gAluminum hydrochloride 20.00 g
MnCI2, 4H2O 3.50 gMnCI 2 , 4H 2 O 3.50 g
Parfums, conservateurs q.sPerfumes, preservatives q.s
Eau déminéralisée qsp 100.00 g Demineralized water qs 100.00 g
Claims
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU2001250485A AU2001250485A1 (en) | 2000-04-18 | 2001-04-11 | Non-staining antiperspirant cosmetic composition |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR0004995A FR2807655B1 (en) | 2000-04-18 | 2000-04-18 | USE OF DIVALENT MANGANESE SALTS AS DEODORANT ASSETS IN COSMETIC COMPOSITIONS |
| FR00/04995 | 2000-04-18 | ||
| FR0010595A FR2807656B1 (en) | 2000-04-18 | 2000-08-11 | ANTITRANSPIRANT COSMETIC COMPOSITION THAT DOES NOT STAIN CLOTHING |
| FR00/10595 | 2000-08-11 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| WO2001078673A2 true WO2001078673A2 (en) | 2001-10-25 |
| WO2001078673A3 WO2001078673A3 (en) | 2002-05-23 |
Family
ID=26212348
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/FR2001/001112 Ceased WO2001078673A2 (en) | 2000-04-18 | 2001-04-11 | Non-staining antiperspirant cosmetic composition |
Country Status (3)
| Country | Link |
|---|---|
| AU (1) | AU2001250485A1 (en) |
| FR (1) | FR2807656B1 (en) |
| WO (1) | WO2001078673A2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7105691B2 (en) | 2003-06-26 | 2006-09-12 | Colgate-Palmolive Company | Aluminum / zirconium / glycine antiperspirant actives stabilized with Betaine |
| FR2926978A1 (en) * | 2008-02-06 | 2009-08-07 | Oreal | DEODORANT AND / OR ANTI-TRANSPIRANT COMPOSITION BASED ON INTERFERENTIAL MICRIOPARTICLES; METHOD OF MAKE-UP AND TREATMENT OF PERSPIRATION AND / OR BODILY ODORS IN PARTICULAR AXILLAR |
| FR2995914A1 (en) * | 2012-09-27 | 2014-03-28 | Oreal | METHOD FOR PROTECTING THE COLOR OF A TEXTILE MATERIAL WITH OIL-IN-WATER EMULSION CONTAINING A MIXTURE OF ALKYLPOLYGLYCOSIDE AND ALCOHOL FATTY AND AN ASSOCIATIVE NON-IONIC POLYETHANE POLYETHER |
| WO2014095686A3 (en) * | 2012-12-21 | 2014-11-06 | Henkel Ag & Co. Kgaa | Textile-sparing, non-aerosol antiperspirants with hydroxycarboxylic acids |
| WO2014095689A3 (en) * | 2012-12-21 | 2014-11-06 | Henkel Ag & Co. Kgaa | Textile-sparing antiperspirant sprays with hydroxycarboxylic acids |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1514216A (en) * | 1974-07-18 | 1978-06-14 | Nelson Res & Dev | Microbiocidal composition |
| JP2824460B2 (en) * | 1988-03-11 | 1998-11-11 | 株式会社ビーエムジー | Adhesive PVA hydrogel composition |
| JPH0773597B2 (en) * | 1988-05-16 | 1995-08-09 | 俶将 猪狩 | Deodorant composition |
| CA2208500A1 (en) * | 1994-12-21 | 1996-06-27 | Cosmederm Technologies | Formulations and methods for reducing skin irritation |
| JPH08208493A (en) * | 1995-02-07 | 1996-08-13 | Koutaku Hayashi | Hair tonic |
| CA2211361A1 (en) * | 1995-03-20 | 1996-09-26 | Unilever Plc | Liquid cleansing formulations |
| FR2740333B1 (en) * | 1995-10-26 | 1997-12-05 | Oreal | USE OF A SUBSTANCE P ANTAGONIST IN A TOPICAL COMPOSITION AS AN ANTITRANSPIRANT AGENT |
| FR2743813B1 (en) * | 1996-01-23 | 1998-02-20 | Oreal | STABLE GEL COMPOSITION WITH HIGH ELECTROLYTE CONTENT |
| JPH09202721A (en) * | 1996-01-25 | 1997-08-05 | Ichimaru Pharcos Co Ltd | Deodorant |
| JP3677894B2 (en) * | 1996-09-12 | 2005-08-03 | ポーラ化成工業株式会社 | Intercalation metal inclusion compound |
-
2000
- 2000-08-11 FR FR0010595A patent/FR2807656B1/en not_active Expired - Fee Related
-
2001
- 2001-04-11 AU AU2001250485A patent/AU2001250485A1/en not_active Abandoned
- 2001-04-11 WO PCT/FR2001/001112 patent/WO2001078673A2/en not_active Ceased
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7105691B2 (en) | 2003-06-26 | 2006-09-12 | Colgate-Palmolive Company | Aluminum / zirconium / glycine antiperspirant actives stabilized with Betaine |
| FR2926978A1 (en) * | 2008-02-06 | 2009-08-07 | Oreal | DEODORANT AND / OR ANTI-TRANSPIRANT COMPOSITION BASED ON INTERFERENTIAL MICRIOPARTICLES; METHOD OF MAKE-UP AND TREATMENT OF PERSPIRATION AND / OR BODILY ODORS IN PARTICULAR AXILLAR |
| EP2090284A1 (en) * | 2008-02-06 | 2009-08-19 | L'Oréal | Deodorant and/or antiperspirant composition based on interference microparticles; makeup method and method for treating perspiration and/or body odours, in particular axillary odours |
| CN101548937B (en) * | 2008-02-06 | 2016-06-29 | 莱雅公司 | Deodorizer and/or Antipers pirant compositions；Cosmetic method and the method for processing perspiration and/or body odor |
| FR2995914A1 (en) * | 2012-09-27 | 2014-03-28 | Oreal | METHOD FOR PROTECTING THE COLOR OF A TEXTILE MATERIAL WITH OIL-IN-WATER EMULSION CONTAINING A MIXTURE OF ALKYLPOLYGLYCOSIDE AND ALCOHOL FATTY AND AN ASSOCIATIVE NON-IONIC POLYETHANE POLYETHER |
| WO2014048647A1 (en) * | 2012-09-27 | 2014-04-03 | L'oreal | Process for protecting the colour of a textile material with an oil-in-water emulsion containing a mixture of alkylpolyglycoside and fatty alcohol and an associative nonionic polyurethane polyether |
| RU2692849C2 (en) * | 2012-09-27 | 2019-06-28 | Л'Ореаль | Method of protecting colouring of textile material using an oil-in-water emulsion containing a mixture of alkyl polyglycoside and fatty alcohol and associative non-ionic polyether-polyurethane |
| WO2014095686A3 (en) * | 2012-12-21 | 2014-11-06 | Henkel Ag & Co. Kgaa | Textile-sparing, non-aerosol antiperspirants with hydroxycarboxylic acids |
| WO2014095689A3 (en) * | 2012-12-21 | 2014-11-06 | Henkel Ag & Co. Kgaa | Textile-sparing antiperspirant sprays with hydroxycarboxylic acids |
| US9095520B2 (en) | 2012-12-21 | 2015-08-04 | Henkel Ag & Co. Kgaa | Textile friendly non-aerosol antiperspirants with a hydroxy acid |
Also Published As
| Publication number | Publication date |
|---|---|
| AU2001250485A1 (en) | 2001-10-30 |
| WO2001078673A3 (en) | 2002-05-23 |
| FR2807656A1 (en) | 2001-10-19 |
| FR2807656B1 (en) | 2002-05-24 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2090284B1 (en) | Antiperspirant composition based on interference microparticles; makeup method and method for treating perspiration and/or body odours , in particular axillary odours | |
| FR2953716A1 (en) | KIT FOR FORMULATING A COSMETIC PRODUCT | |
| FR2863490A1 (en) | OIL-IN-WATER EMULSION DEORING COMPOSITION CONTAINING A MIXTURE OF ALKYLPOLYGLYCOSIDE AND FATTY ALCOHOL AND AN ASSOCIATIVE NON-IONIC POLYETHANE POLYETHER | |
| FR2952531A1 (en) | AQUEOUS SCENSE COMPOSITION COMPRISING AT LEAST ONE VOLATILE LINEAR ALKANE; PERFUMING PROCESS | |
| CZ421398A3 (en) | Cosmetic preparation | |
| EP1902754B1 (en) | Hydro-alcoholic deodorant composition containing a water-soluble salt of zinc and salicylic acid | |
| JPS62292710A (en) | Skin cosmetic | |
| EP1925291B1 (en) | Cosmetic composition comprising at least one volatile ester | |
| EP1486199B1 (en) | Alcoholic aerosol deodorant composition containing zinc salicylate | |
| WO2001078673A2 (en) | Non-staining antiperspirant cosmetic composition | |
| FR2990850A1 (en) | COSMETIC COMPOSITION COMPRISING THE ASSOCIATION OF A LIPOPHILIC DERIVATIVE OF SALICYLIC ACID, AN ANTI-TRANSPIRANT ALUMINUM SALT OR COMPLEX, AND AN ACETIC N, DIACIDAL AMINO ACID SALT | |
| FR3012960A1 (en) | USE AS A DEODORANT AGENT OF A SALICYLIC ACID SALICY DERIVATIVE, ALONE OR IN MIXING | |
| FR2863488A1 (en) | COSMETIC DEODORANT COMPOSITION COMPRISING THE ASSOCIATION OF ZINC GLUCONATE AND A SINGLE ANTI-TRANSPIRANT ALUMINUM SALT | |
| FR2954136A1 (en) | DEODORANT COMPOSITION BASED ON ANTIMICROBIAL PEPTIDES AND METHOD FOR TREATING BODY ODORS | |
| CA2353721A1 (en) | Deodorant cosmetic composition | |
| EP1541122B1 (en) | Cosmetic deodorant composition comprising an association of zinc pidolate with an anti-perspirant aluminium salt | |
| JP5291365B2 (en) | Keratin condition improving agent | |
| EP1584330A1 (en) | Oil in water emulsion-type antiperspirant composition containing wax microparticles | |
| WO2003002081A1 (en) | Composition comprising a hydroxydiphenyl ether derivative inhibiting the development of body odours | |
| NL2039433B1 (en) | Color cosmetics formulation | |
| FR2815856A1 (en) | USE OF 1,3-DIPHENYLPROPANE DERIVATIVES AS ACTIVE INGREDIENTS INHIBITING THE DEVELOPMENT OF BODY ODORS IN COSMETIC COMPOSITIONS | |
| FR2996756A1 (en) | COSMETIC USE OF A MONO-UNSATURATED FATTY ACID OR ONE OF ITS SALTS AND / OR ITS ESTERS AS DEODORANT ACTIVE | |
| FR2894134A1 (en) | USE AS ANTI-TRANSPARENT AGENT OF A DISPERSION OF CATIONIC SILICA COLLOIDAL PARTICLES; ANTI-TRANSPARENT COMPOSITIONS; COSMETIC PROCESS FOR TREATING TRANSPIRATION | |
| WO2003002072A1 (en) | Compositions containing a hydroxydiphenyl ether derivative inhibiting body odours | |
| FR3120191A1 (en) | antiperspirant cosmetic compositions, use of the antiperspirant cosmetic composition, and process for manufacturing a cosmetic composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| AK | Designated states |
Kind code of ref document: A2 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW |
|
| AL | Designated countries for regional patents |
Kind code of ref document: A2 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG |
|
| 121 | Ep: the epo has been informed by wipo that ep was designated in this application | ||
| DFPE | Request for preliminary examination filed prior to expiration of 19th month from priority date (pct application filed before 20040101) | ||
| AK | Designated states |
Kind code of ref document: A3 Designated state(s): AE AG AL AM AT AU AZ BA BB BG BR BY BZ CA CH CN CO CR CU CZ DE DK DM DZ EE ES FI GB GD GE GH GM HR HU ID IL IN IS JP KE KG KP KR KZ LC LK LR LS LT LU LV MA MD MG MK MN MW MX MZ NO NZ PL PT RO RU SD SE SG SI SK SL TJ TM TR TT TZ UA UG US UZ VN YU ZA ZW |
|
| AL | Designated countries for regional patents |
Kind code of ref document: A3 Designated state(s): GH GM KE LS MW MZ SD SL SZ TZ UG ZW AM AZ BY KG KZ MD RU TJ TM AT BE CH CY DE DK ES FI FR GB GR IE IT LU MC NL PT SE TR BF BJ CF CG CI CM GA GN GW ML MR NE SN TD TG |
|
| 122 | Ep: pct application non-entry in european phase | ||
| NENP | Non-entry into the national phase |
Ref country code: JP |