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WO2000030197A1 - Pile electrochimique et procede de montage de ladite pile - Google Patents

Pile electrochimique et procede de montage de ladite pile Download PDF

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Publication number
WO2000030197A1
WO2000030197A1 PCT/US1998/024742 US9824742W WO0030197A1 WO 2000030197 A1 WO2000030197 A1 WO 2000030197A1 US 9824742 W US9824742 W US 9824742W WO 0030197 A1 WO0030197 A1 WO 0030197A1
Authority
WO
WIPO (PCT)
Prior art keywords
separator
electrode
container
cavity
anode
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1998/024742
Other languages
English (en)
Inventor
Lewis F. Urry
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Edgewell Personal Care Brands LLC
Original Assignee
Eveready Battery Co Inc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eveready Battery Co Inc filed Critical Eveready Battery Co Inc
Priority to CA002318073A priority Critical patent/CA2318073A1/fr
Priority to CN98813871A priority patent/CN1286813A/zh
Priority to PCT/US1998/024742 priority patent/WO2000030197A1/fr
Priority to EP98958093A priority patent/EP1048092A1/fr
Priority to AU14202/99A priority patent/AU1420299A/en
Priority to JP2000583106A priority patent/JP2002530814A/ja
Publication of WO2000030197A1 publication Critical patent/WO2000030197A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Classifications

    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/04—Construction or manufacture in general
    • H01M10/0413—Large-sized flat cells or batteries for motive or stationary systems with plate-like electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
    • H01M50/463—Separators, membranes or diaphragms characterised by their shape
    • H01M50/469—Separators, membranes or diaphragms characterised by their shape tubular or cylindrical
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/04—Construction or manufacture in general
    • H01M10/0459—Cells or batteries with folded separator between plate-like electrodes
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00—Secondary cells; Manufacture thereof
    • H01M10/24—Alkaline accumulators
    • H01M10/28—Construction or manufacture
    • H01M10/283—Cells or batteries with two cup-shaped or cylindrical collectors
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M6/00—Primary cells; Manufacture thereof
    • H01M6/04—Cells with aqueous electrolyte
    • H01M6/06—Dry cells, i.e. cells wherein the electrolyte is rendered non-fluid
    • H—ELECTRICITY
    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2300/00—Electrolytes
    • H01M2300/0002—Aqueous electrolytes
    • H01M2300/0014—Alkaline electrolytes
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10—Energy storage using batteries
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50—Manufacturing or production processes characterised by the final manufactured product

Definitions

  • the present invention generally relates to an electrochemical cell and, more particularly, to an electrochemical cell and method of assembling a cell having increased anode-to-cathode interface area.
  • Electrochemical cells are commonly employed to supply voltage for electrically operated devices, particularly for portable electrically operated devices.
  • alkaline cells of the generally cylindrical shape are commercially available in industry- recognized, standard sizes, including D-, C-, AA-, AAA-, and AAAA-size cells, as well as other sizes and configurations.
  • Alkaline cells such as the aforementioned type commonly provide a predetermined open circuit voltage supply with limited service performance.
  • Conventional cylindrical alkaline cells generally have a cylindrically shaped steel can provided with a positive cover at one end and a negative cover at the opposite end.
  • the cylindrical cell has a positive electrode, commonly referred to as the cathode, which is often formed of a mixture of manganese dioxide, graphite, potassium hydroxide solution, deionized water, and TEFLON ® solution formed about the interior side surface of the cylindrical steel can.
  • a cup-shaped separator is centrally disposed within an inner cylindrical volume of the can about the interior surface of the cathode.
  • a negative electrode, commonly referred to as the anode is typically formed of zinc powder, a gelling agent, and other additives, and is disposed with an electrolyte solution within the separator.
  • Conventional cells of the cylindrical type typically have a single anode and a single cathode assembled within the steel can with the separator interfaced therebetween.
  • the cathode is typically disposed against the interior surface of the can, generally within an outer peripheral portion of the can, with a cylindrical cavity centrally formed in the cathode.
  • a cup-shaped separator configured to an approximate size and shape of the cavity within the cathode is then inserted in the cavity.
  • the separator generally has an anode-to-cathode interface generally defined by the shape and size of the anode and cathode, which is approximately equal to the surface area of the outer periphery of the cylindrical anode.
  • the anode is generally shaped as a cylinder with a uniformly curved outer surface parallel to the container wall such that the cathode is not easily susceptible to breakage which can lead to ionic and electric discontinuity in the cell.
  • a primary goal in designing alkaline cells is to increase the service performance, which is the length of time for the cell to discharge under a given load to a specific voltage at which the cell is no longer useful for its intended purpose.
  • Commercially available alkaline cells commonly have an external size that is defined by industry standards, thereby limiting the ability to increase the amount of active materials within the cell. Yet, the need to find new ways to increase service performance remains the goal of the cell designers.
  • the present invention enhances the performance of an electrochemical cell by providing the cell with an increased anode-to-cathode interface area to realize enhanced service performance.
  • the present invention provides an electrochemical cell and method of assembling an electrochemical cell with increased anode-to-cathode interface area.
  • a container is provided having a closed bottom end and aii open top end.
  • a first electrode is provided in the container and has a cavity formed therein.
  • a tubular separator is disposed within the cavity such that the tubular separator is bent to form first and second compartments within the separator.
  • a conductive plate preferably coated with active first electrode material, such as manganese dioxide, is inserted with the separator into the cavity such that the conductive sheet is disposed between the first and second compartments.
  • a second electrode is dispensed within the first compartment, while a third electrode is dispensed within the second compartment.
  • a current collector is assembled in contact with the second and third electrodes, and a cover and seal assembly is assembled to the open top end of the container.
  • the first electrode comprises a cathode
  • the second and third electrodes each comprises an anode.
  • FIG. 1 is an exploded view of an electrochemical cell illustrating assembly of a tubular separator and conductive plate within a cavity in an electrode of the cell can;
  • FIG. 2 is a side view of the cell can further illustrating assembly of the tubular separator and conductive plate during assembly of the cell;
  • FIG. 3 is an elevational, cross-sectional view of the electrochemical cell of the present invention taken on a plane through the longitudinal axis thereof;
  • FIG. 4 is a cross-sectional view of the electrochemical cell of FIG. 3 taken on plane IV-IV;
  • FIG. 5 is an elevational, cross-sectional view of an electrochemical cell according to another embodiment of the present invention and taken on a plane through the longitudinal axis thereof.
  • an electrochemical cell 10 having a first electrode referred to herein as a cathode, and second and third electrodes, each referred to herein as an anode. While the cathode serves as the positive electrode and the anodes serve as negative electrodes, it should be appreciated that the teachings of the present invention are not intended to be limited to the embodiments shown.
  • the electrochemical cell 10 is shown and described as a cylindrical alkaline cell, it should be appreciated that the principles of the present invention can also be applied to various types of electrochemical cells having various sizes and configurations.
  • the electrochemical cell 10 as shown in the exploded view of FIG. 1, has a cylindrical steel can 12 with a closed bottom end 14 and an open top end 16.
  • the act of assembly of cell 10 includes disposing a cathode 18 within the interior volume of steel can 1 * 2 and forming a cylindrical anode cavity 20 within a substantially inner cylindrical volume of cathode 18.
  • cathode 18 extends about the interior side surface of steel can 12 in the shape of a cylindrical ring.
  • the cathode 18 is preferably formed of a mixture of manganese dioxide, graphite, potassium hydroxide solution, deionized water, and a TEFLON ® suspension.
  • a tubular separator 22 which is preferably formed of a non- oven fabric that prevents migration of any solid particles in the cell 10. Preferably, it has a length substantially twice the longitudinal length of the cathode 18.
  • the tubular separator 22 may include a rolled-up sheet of non-woven fabric that is hollow with open ends. Alternatively, a one-piece tube made of regenerated cellulose may be employed with or without a paper backing.
  • a conductive plate 28 is also shown, which is preferably made of a perforated metal. Conductive plate 28 preferably contains a coating of active cathode materials, such as manganese dioxide, that is bonded to the conductive plate 28.
  • conductive plate 28 allows for electric conductivity to allow electron transfer between manganese dioxide coating and cathode 18 to enhance discharge uniformity.
  • the assembly of cell 10 includes forcibly inserting the conductive plate 28, with manganese dioxide coating, against the mid portion of tubular separator 22 so as to cause plate 28 and separator 22 to be disposed within cylindrical cavity 20. In doing so, the conductive plate 28 causes tubular separator 22 to bend into a V-shape as it is forcefully inserted within cylindrical cavity 20.
  • the tubular separator 22 is formed into two separators 22A and 22B having substantially semi-cylindrical anode cavities 24A and 24B, respectively, which may or may not have a joining passage at the bottom side, depending upon the length of insertion of conductive plate 28.
  • the conductive plate 28 is preferably interference fit with cathode 18 such that plate 28 contacts the cathode 18 at opposite ends.
  • anode compartments 24A and 24B are substantially filled with anode mix.
  • the anode materials could be injected or otherwise dispensed into separators 22A and 22B, either prior to insertion of tubular separator 22 into cavity 20 or after insertion of tubular separator 22 to form the two separators 22 A and 22B.
  • Anodes 26 A and 26B may include a gel-type anode formed of non-amalgamated zinc powder, a gelling agent, and other additives, and mixed with an electrolyte solution which may be formed of potassium hydroxide, zinc oxide, and water. It should be appreciated that various types of anodes and cathodes may be employed without departing from the teachings of the present invention.
  • an inner cover and seal assembly 30 is also shown containing a two-prong current collector 34 having a pair of current collector rods 34 A and 34B.
  • the collector rods 34A and 34B can be formed of a single conductive wire or foil that is electrically coupled to the negative terminal of the cell 10.
  • the first current collector rod 34A is inserted into the first anode and the second current collector rod 34B is ' inserted into the second anode, with both rods in contact with anode zinc.
  • Cover and seal assembly 30 further includes a seal body 32 for sealably closing the open end 16 of steel can 12.
  • An inner metal cover 38 is disposed on top of the seal body 32.
  • the collector rods 34A and 34B extend through passages in the inner cover 38 and the seal body 32 prevents leakage through the open end of can 12.
  • FIG. 3 a cross section of the fully assembled electrochemical cell 10 is shown.
  • an outer contact cover 40 is disposed on top thereof to form the negative contact terminal of cell 10.
  • the outer contact cover 40 is in contact with the top surface of current collector 34 and may be connected thereto via a spot weld 35.
  • Assembled to the closed end of steel can 12 is a positive cover 42 preferably formed of plated steel with a protruding nub 44 at its center region, which forms the positive contact terminal of cell 10.
  • the first anode 26 A and corresponding separator 22A, as well as the second anode 26B and corresponding separator 22B, are each formed into a substantially semi-cylindrical configuration with a semi-circular radial cross section defined by the inner surface of cathode 18 and side surface of manganese dioxide-coated
  • SUBST ⁇ UTE SHEET (RULE 26) conductive plate 28 The conductive plate 28 is interference fit such that it extends in contact with cathode 18 along its side edge walls. Accordingly, the conductivity of conductive plate 28 allows electrical conductivity from electrically conductive material, such as graphite, found in the cathode 18 to pass along plate 28 and to the manganese dioxide coating that faces the flat surface of separators 22A and 22B. This allows for the manganese dioxide in cathode 18 to charge the coated manganese dioxide on separator plate 28 and therefore realize substantially uniform discharge.
  • electrically conductive material such as graphite
  • the electrochemical cell 10 is assembled as set forth above, except the conductive plate 28 is foreshortened and therefore does not extend fully to the bottom closed end 14 of steel can 12.
  • the first and second anodes 26A and 26B are interconnected via a passage on the bottom end below conductive plate 28 and extending above closed bottom end 14 of steel can 12.
  • a single anode is provided, while realizing an enlarged anode-to-cathode interface area.

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Primary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

Pile électrochimique et procédé permettant d'obtenir une superficie d'interface accrue anode-à-cathode pour accroître les performances de fonctionnement de ladite pile. Une première électrode, telle qu'une cathode, est placée dans une enveloppe, et une cavité est ménagée dans la première électrode. Un séparateur tubulaire est placé dans la cavité par introduction d'une plaque conductrice contre le séparateur pour former des premier et second compartiments de séparateur. La plaque conductrice, qui est de préférence revêtue d'une matière active de première électrode, telle que du dioxyde de manganèse, est introduite par la force dans la cavité. Une seconde électrode, telle qu'une anode, est placée dans chacun des premier et second compartiments de séparateur. Un collecteur est monté en contact avec les deuxième et troisième électrodes et un ensemble couvercle et joint d'étanchéité est monté sur la partie supérieure de l'enveloppe.
PCT/US1998/024742 1998-11-18 1998-11-18 Pile electrochimique et procede de montage de ladite pile Ceased WO2000030197A1 (fr)

Priority Applications (6)

Application Number Priority Date Filing Date Title
CA002318073A CA2318073A1 (fr) 1998-11-18 1998-11-18 Pile electrochimique et procede de montage de ladite pile
CN98813871A CN1286813A (zh) 1998-11-18 1998-11-18 电化学电池和装配方法
PCT/US1998/024742 WO2000030197A1 (fr) 1998-11-18 1998-11-18 Pile electrochimique et procede de montage de ladite pile
EP98958093A EP1048092A1 (fr) 1998-11-18 1998-11-18 Pile electrochimique et procede de montage de ladite pile
AU14202/99A AU1420299A (en) 1998-11-18 1998-11-18 Electrochemical cell and method of assembly
JP2000583106A JP2002530814A (ja) 1998-11-18 1998-11-18 電気化学的セル及びその組立て方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1998/024742 WO2000030197A1 (fr) 1998-11-18 1998-11-18 Pile electrochimique et procede de montage de ladite pile

Publications (1)

Publication Number Publication Date
WO2000030197A1 true WO2000030197A1 (fr) 2000-05-25

Family

ID=22268330

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1998/024742 Ceased WO2000030197A1 (fr) 1998-11-18 1998-11-18 Pile electrochimique et procede de montage de ladite pile

Country Status (6)

Country Link
EP (1) EP1048092A1 (fr)
JP (1) JP2002530814A (fr)
CN (1) CN1286813A (fr)
AU (1) AU1420299A (fr)
CA (1) CA2318073A1 (fr)
WO (1) WO2000030197A1 (fr)

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE121933C (fr) *
US2980747A (en) * 1959-08-10 1961-04-18 Union Carbide Corp Sealed nickel cadmium cell
US3043899A (en) * 1959-02-02 1962-07-10 Servel Inc Magnesium battery
GB2136193A (en) * 1983-03-03 1984-09-12 Yeh Chun Tsai Closed cylindrical storage battery
US4669183A (en) * 1986-04-10 1987-06-02 Duracell Inc. Method and apparatus for sizing galvanic cell separators
US5869205A (en) * 1997-11-12 1999-02-09 Eveready Battery Company, Inc. Electrochemical cell having multiple anode compartments

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2000030196A1 (fr) * 1998-11-16 2000-05-25 Eveready Battery Company, Inc. Pile electrochimique a compartiments multiples pour anodes

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE121933C (fr) *
US3043899A (en) * 1959-02-02 1962-07-10 Servel Inc Magnesium battery
US2980747A (en) * 1959-08-10 1961-04-18 Union Carbide Corp Sealed nickel cadmium cell
GB2136193A (en) * 1983-03-03 1984-09-12 Yeh Chun Tsai Closed cylindrical storage battery
US4669183A (en) * 1986-04-10 1987-06-02 Duracell Inc. Method and apparatus for sizing galvanic cell separators
US5869205A (en) * 1997-11-12 1999-02-09 Eveready Battery Company, Inc. Electrochemical cell having multiple anode compartments

Also Published As

Publication number Publication date
JP2002530814A (ja) 2002-09-17
AU1420299A (en) 2000-06-05
CA2318073A1 (fr) 2000-05-25
CN1286813A (zh) 2001-03-07
EP1048092A1 (fr) 2000-11-02

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