WO2000065672A1 - Boitier de batterie et tole d'acier traitee en surface pour boitier de batterie - Google Patents
Boitier de batterie et tole d'acier traitee en surface pour boitier de batterie Download PDFInfo
- Publication number
- WO2000065672A1 WO2000065672A1 PCT/JP2000/002602 JP0002602W WO0065672A1 WO 2000065672 A1 WO2000065672 A1 WO 2000065672A1 JP 0002602 W JP0002602 W JP 0002602W WO 0065672 A1 WO0065672 A1 WO 0065672A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- battery case
- semi
- nickel plating
- plating layer
- steel sheet
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/545—Terminals formed by the casing of the cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
- H01M50/126—Primary casings; Jackets or wrappings characterised by the material having a layered structure comprising three or more layers
- H01M50/128—Primary casings; Jackets or wrappings characterised by the material having a layered structure comprising three or more layers with two or more layers of only inorganic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/117—Inorganic material
- H01M50/119—Metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/131—Primary casings; Jackets or wrappings characterised by physical properties, e.g. gas permeability, size or heat resistance
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Definitions
- the present invention relates to a container for enclosing an alkaline liquid, and more particularly to a battery case such as an alkaline manganese battery or a nickel-cadmium battery, and a surface-treated steel sheet for a battery case that can be suitably used for manufacturing the case.
- a battery case such as an alkaline manganese battery or a nickel-cadmium battery
- a surface-treated steel sheet for a battery case that can be suitably used for manufacturing the case.
- the barrel plating method is difficult to apply nickel plating evenly, especially on the inner surface of the case, and the plating thickness varies widely.
- the pre-plating method has become the mainstream.
- a method of performing a heat diffusion treatment after nickel plating has been applied.
- the relationship between the battery performance of alkaline manganese batteries and the positive electrode case (battery case)
- the positive electrode mixture for alkaline manganese batteries manganese dioxide as the positive electrode active material, graphite as the conductive agent, and the hydroxide power of the electrolyte
- the positive electrode case is a conductor that exchanges electrons with the battery container. Therefore, when the contact resistance between the positive electrode mixture and the inner surface of the positive electrode case is high, the internal resistance of the battery increases, resulting in a decrease in the operating voltage and a decrease in the discharge duration, which impairs the battery performance. Therefore, it is desired to reduce the contact resistance between the positive electrode mixture and the inner surface of the positive electrode case. Therefore, in order to reduce the contact resistance between the positive electrode mixture and the positive electrode case,
- a DI (draw ng an dironing) forming method has been used as a method for reducing the thickness.
- This DI molding method and DTR (draw ingthin and redr aw) molding method allow the positive electrode and negative electrode active material to be filled in as much as the case side wall thickness is smaller than the bottom surface thickness, and increase the battery capacity, Since the case bottom is thick, there is an advantage that the pressure resistance of the battery can be improved.
- the DI molding method and the DTR molding method are effective molding methods for increasing the battery capacity.
- the DI molding method and the DTR molding method are effective molding methods for increasing the battery capacity.
- in terms of moldability compared with the conventional multistage deep drawing method, Since the material has high deformation resistance, it has an adverse aspect in continuous formability.
- the powdering properties (powdering of the plating layer) in the cutting process of the DI molding method or the DTR molding method are poor, they adhere to the die and punch in the ironing process, and as a result, flaws are formed on the case side wall. Will happen. This phenomenon is caused by deep drawing However, the DI molding method and the DTR molding method have a smaller surface roughness on the case wall and a glossier appearance, so the above-mentioned flaws are more noticeable, and However, DI molding and DTR molding are more important.
- the contact surface pressure between the material and the tool is higher in the DI forming method and the DTR forming method than in the draw forming, good lubricity is required from the viewpoint of tool life. Therefore, from the material aspect, a material having good padding properties and good press lubricant retention is required.
- the present inventors have studied various battery case materials having excellent moldability and battery performance in the DI molding method and the DTR molding method from such a viewpoint. It has been found that the bright nickel plating layer shows excellent characteristics in padding resistance.
- temper rolling may be performed. Temper rolling increases the gloss and improves the appearance. For example, a sample whose glossiness after semi-bright nickel plating (JISZ8741, specular glossiness measurement method) was 900, was subjected to temper rolling at a rolling rate of 0.5%, Increases to 960. In addition, the corrosion resistance of the processed part is the same without being deteriorated by temper-rolling.
- the present invention has been made based on such knowledge, and has been made of a battery case having high quality and excellent continuous formability, and a surface-treated steel sheet which can be suitably used for manufacturing the battery case. Making it a technical issue.
- the battery case of the present invention has a semi-bright nickel plating layer formed on the inner surface of the battery case, a semi-bright nickel plating layer formed on the lower layer, and a bright nickel plating layer formed on the upper layer, on the outer surface of the battery case. It is characterized by being.
- the battery case of the present invention is characterized in that a semi-bright nickel plating layer is formed on the inner and outer surfaces of the battery case.
- a matte nickel plating layer is formed on the inner surface of the battery case, a semi-bright nickel plating layer is formed on the lower layer on the outer surface of the battery case, and a bright nickel plating layer is formed on the upper layer. It is characterized by having been done.
- the battery case of the present invention is characterized in that a matte nickel plating layer is formed on the inner surface of the battery case, and a semi-gloss nickel plating layer is formed on the outer surface of the battery case.
- the battery case of the present invention is characterized in that it is obtained by forming a surface-treated steel sheet having a nickel-plated nickel-plated layer formed on at least one surface of an original plate made of a steel sheet by a DI forming method or a DTR forming method. I do.
- the surface-treated steel sheet for a battery case of the present invention has a semi-gloss nickel plating layer formed on the inner side of the battery case and a semi-glossy lower layer on the outer side of the battery case. A nickel plating layer is formed, and a bright nickel plating layer is formed on an upper layer.
- the surface-treated steel sheet for a battery case according to the present invention is characterized in that a semi-bright nickel plating layer is formed on the side that becomes the inner and outer surfaces of the battery case.
- the surface-treated steel sheet for a battery case of the present invention has a matte nickel plating layer formed on the inner side of the battery case and a semi-bright nickel plated layer formed on the lower side of the battery case outer side. And a bright nickel plating layer is formed on the upper layer.
- the surface-treated steel sheet for a battery case of the present invention has a matte nickel plating layer formed on the inner surface of the battery case, and a semi-bright nickel plated layer formed on the outer surface of the battery case. It is characterized by the following.
- the semi-bright nickel-plated layer contains one or more of unsaturated carboxylic acid formaldehyde, polyoxy-ethylene adduct, nitrogen-containing complex compound, or nitrogen-containing aliphatic compound as a brightener. It is characterized in that it is formed using a plating bath.
- the plating surface hardness of the nickel sulfate bath is about 340 to 370 (pickas hardness) when the semi-brightening agent is not added, whereas the semi-brightening agent is 2 to 3 cc. / 1 / When added, it becomes as high as about 350 to 420 (picker hardness).
- the semi-bright nickel-plated steel sheet is manufactured in this manner, and the semi-bright nickel-plated steel sheet is formed by a DI forming method and a DTR forming method to form a battery case ( Alkaline manganese battery LR6 type) was fabricated.
- the prepared battery case was removed with an organic solvent to remove the lubricant on the inside and outside surfaces of the case, and the powder with the plated layer was attached to the cellophane tape. 25 times), the powdering properties
- the powdering properties were measured by three methods, namely, the deep drawing method, the DI method, and the DTR method. As a result, they found that the surface-treated steel sheet having the semi-bright nickel-plated layer according to the present invention had a lower punch load than the bright nickel-plated single-layer steel sheet.
- the punch load when the surface-treated steel sheet according to the present invention is formed is lower than that of the bright nickel-plated single layer because it does not contain the sulfur-containing semi-brightening agent. It is considered that in the ironing process of DI molding and the stretching process of DTR molding, the frictional resistance is reduced and the punch load is reduced. As a result, the punch load is reduced and the die and punch flaws are generated due to metal contact.
- the present invention is not limited to the DI molding method Ud or DTR molding method as means for thinning the case wall of the battery case, and the powdering property can be improved by the conventional multi-stage deep drawing method, It can be suitably used.
- the semi-brightening agent for the sulfur-free semi-bright nickel plating bath is a mixture of a nitrogen-containing heterocyclic compound and a nitrogen-containing aliphatic compound, polyoxy-ethylene adduct of unsaturated alcohol or unsaturated carboxylic acid formaldehyde alone or two or more Is the mixture of good.
- the total amount of the semi-brightening agent is preferably in the range of 0.3 to 10 cc / 1.
- the powdered anti-powder If the amount of semi-brightener added is less than 0.3 cc / l, the powdered anti-powder When the amount of semi-brightening agent exceeds 10 cc / 1, on the other hand, the smoothness effect, which is a measure of the glossiness of the surface-treated steel sheet, reaches saturation and the semi-brightening agent is not used. It is expensive because it is expensive.
- the plating thickness of the surface-treated steel sheet of the present invention ranges from 0.5 to 3. for the semi-bright nickel plating on the inner surface side of the case, and 1.0 for the total nickel plating thickness on the outer surface side of the case. A range of ⁇ 4.0 m is desirable.
- the thickness of the inner surface of the case is less than 0.5 zm, in the case of batteries such as alkaline manganese batteries, the iron exposure of the steel base is large, the corrosion is poor, and the deterioration of the battery performance due to the elution of iron ions into the electrolytic solution may occur. Because it wakes up.
- the corrosion resistance 10 is not sufficient, and due to the occurrence of cracking during the battery case pressing process, battery manufacturing process and long-term storage, 1.0 im or more is obtained. Because it is necessary.
- the upper limit (3.0 m, 4.0 xm) of the plating thickness on the inner and outer surfaces of the case is, respectively, when the plating thickness is larger than these values, the effect has reached saturation and it is not possible to increase the thickness further. Because it is an economy.
- low carbon Almikild steel is suitably used as the base steel of the 15 "surface treated steel sheet, that is, the plating base sheet.
- niobium and titanium are added, and the non-aging ultra-low carbon steel (carbon Cold rolled steel strip manufactured from less than 0 1%) is also used.
- the steel strip that has been cold rolled, electrolytically cleaned, annealed, and temper rolled is used as the original plate after cold rolling. Semi-bright nickel plating is performed on the original plate to produce a surface treated steel sheet.After plating, temper rolling may be performed.
- the plating bath may be any of a known sulfuric acid bath and a sulfamic acid bath, but a sulfuric acid bath, which is relatively easy to manage, is suitable.
- the plated original plate was subjected to alkaline electrolytic degreasing, water washing, sulfuric acid immersion, and water washing by a conventional method (after pretreatment of D, and then semi-bright nickel plating under the following conditions to produce a surface-treated steel plate.
- Anode S pellets (product name, spherical, manufactured by INCO) are loaded into a titanium basket and covered with a polypropylene bag.
- the semi-brightening agent an unsaturated carboxylic acid formaldehyde or a polyoxyethylene adduct was used. Under the above conditions, the glossiness and the plating thickness were changed by changing the addition amount of the semi-brightener and the electrolysis time. 2) Bright nickel plating
- a brightening agent was added to the sulfuric acid Nigel bath to perform a glossy Nigel plating.
- a benzenesulfonic acid derivative was used as a sulfur-containing brightener, and a mixture of a nitrogen-containing complex compound and a nitrogen-containing aliphatic compound was used as a sulfur-free brightener.
- S pellets product name, spherical, manufactured by INCO
- a titanium basket and covered with a polypropylene bag.
- the plating thickness was changed by changing the amount of brightener and the electrolysis time.
- the plating thickness and the plating film alloy composition and the plating layer were dissolved in 3% nitric acid and analyzed by ICP (inductively coupled plasma emission spectroscopy). The plating thickness was determined by dividing the amount of each dissolved element by the plating area and taking the specific gravity of each element into account. Table 1 shows the results.
- Example 8 the unsaturated carboxylic acid formaldehyde as brightener or semi-brightener is A
- the polyoxymonoethylene adduct is B
- the mixture of the nitrogen-containing heterocyclic compound and the nitrogen-containing aliphatic compound is C
- Benzenesulfonic acid derivatives are indicated by a D in each case.
- the rolling ratio of Example 8 and Example 11 was reduced to 0.
- the battery case is formed by the DI molding method using the above-mentioned plated steel sheet having a thickness of 0.4 mm, cutting from a blank diameter of 41 mm to a diameter of 20.5 mm, and then redrawing with a DI molding machine. And two-stage ironing was performed to form an outer diameter of 13.8 mm, a case wall of 0.20 mm, and a height of 56 mm. Finally trim the upper part, height 4 A 9.3 mm LR 6 type battery case was fabricated.
- the evaluation of the powdering property is based on the powdering before and after the molding in the process of manufacturing the battery case, that is, blanking ⁇ cutting ⁇ degreasing-weight measurement (1)-molding-degreasing-weight measurement (2).
- the sex was evaluated.
- the degreasing was carried out by ultrasonic cleaning with acetone following degreasing with dipping in Al ⁇ . Since the weight loss has a large error in the measurement of each case, the measurement was repeated three times using 30 cases as a unit of measurement. The results are shown in Table 1.
- the amount of the dropped powder was as large as 170 to 180 mg / 30 cases, whereas Examples 1 to 12 of the present invention were not.
- the battery case of the present invention is characterized in that the semi-bright nickel plating layer does not contain a sulfur-containing semi-bright agent.
- semi-bright nickel plating can significantly reduce the powdering property, lower the punch load in the cutting process, suppress die and punch flaws due to metal contact, and extend die life. Therefore, the continuous productivity of the battery case can be improved.
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- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Electroplating Methods And Accessories (AREA)
Abstract
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000614520A JP3678347B2 (ja) | 1999-04-23 | 2000-04-20 | 電池ケース及び電池ケース用表面処理鋼板 |
| AU38411/00A AU3841100A (en) | 1999-04-23 | 2000-04-20 | Battery case and surface treated steel sheet for battery case |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP11/116672 | 1999-04-23 | ||
| JP11667299 | 1999-04-23 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2000065672A1 true WO2000065672A1 (fr) | 2000-11-02 |
Family
ID=14693046
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP2000/002602 Ceased WO2000065672A1 (fr) | 1999-04-23 | 2000-04-20 | Boitier de batterie et tole d'acier traitee en surface pour boitier de batterie |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP3678347B2 (fr) |
| AU (1) | AU3841100A (fr) |
| WO (1) | WO2000065672A1 (fr) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003098718A1 (fr) * | 2002-04-22 | 2003-11-27 | Toyo Kohan Co., Ltd. | Feuille d'acier traitee en surface pour un boitier de batterie, boitier de batterie et batterie faisant appel a ce boitier |
| JP2008226795A (ja) * | 2007-03-15 | 2008-09-25 | Fdk Energy Co Ltd | 電池用金属部品及び電池 |
| WO2018052009A1 (fr) * | 2016-09-13 | 2018-03-22 | 東洋鋼鈑株式会社 | Procédé de fabrication de tôle d'acier à traitement de surface pour boîtier de batterie |
| WO2019111556A1 (fr) * | 2017-12-07 | 2019-06-13 | 株式会社豊田自動織機 | Dispositif de stockage d'électricité, procédé de production de dispositif de stockage d'électricité et procédé de placage électrolytique |
| CN115787004A (zh) * | 2022-10-18 | 2023-03-14 | 邯郸市金泰包装材料有限公司 | 一种新能源汽车电池壳用高速预镀镍钢带及其制造方法 |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5325538B2 (fr) * | 1974-02-28 | 1978-07-27 | ||
| WO1997042667A1 (fr) * | 1996-05-09 | 1997-11-13 | Toyo Kohan Co., Ltd. | Bac de batterie et tole d'acier traitee en surface pour bac de batterie |
| WO1997042668A1 (fr) * | 1996-05-09 | 1997-11-13 | Toyo Kohan Co., Ltd. | Tole d'acier traitee en surface pour logement de batterie, sa fabrication, logement de batterie et batterie |
| WO1997044835A1 (fr) * | 1996-05-23 | 1997-11-27 | Toyo Kohan Co., Ltd. | Tole d'acier plaque pour bacs d'accumulateurs, procede de fabrication de cette tole, bac d'accumulateur et accumulateur |
| WO1998010475A1 (fr) * | 1996-09-03 | 1998-03-12 | Toyo Kohan Co. Ltd. | Plaque d'acier a surface traitee pour boitier de batterie, boitier de batterie et batterie obtenue a partir de ce boitier |
-
2000
- 2000-04-20 AU AU38411/00A patent/AU3841100A/en not_active Abandoned
- 2000-04-20 JP JP2000614520A patent/JP3678347B2/ja not_active Expired - Lifetime
- 2000-04-20 WO PCT/JP2000/002602 patent/WO2000065672A1/fr not_active Ceased
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5325538B2 (fr) * | 1974-02-28 | 1978-07-27 | ||
| WO1997042667A1 (fr) * | 1996-05-09 | 1997-11-13 | Toyo Kohan Co., Ltd. | Bac de batterie et tole d'acier traitee en surface pour bac de batterie |
| WO1997042668A1 (fr) * | 1996-05-09 | 1997-11-13 | Toyo Kohan Co., Ltd. | Tole d'acier traitee en surface pour logement de batterie, sa fabrication, logement de batterie et batterie |
| WO1997044835A1 (fr) * | 1996-05-23 | 1997-11-27 | Toyo Kohan Co., Ltd. | Tole d'acier plaque pour bacs d'accumulateurs, procede de fabrication de cette tole, bac d'accumulateur et accumulateur |
| WO1998010475A1 (fr) * | 1996-09-03 | 1998-03-12 | Toyo Kohan Co. Ltd. | Plaque d'acier a surface traitee pour boitier de batterie, boitier de batterie et batterie obtenue a partir de ce boitier |
Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003098718A1 (fr) * | 2002-04-22 | 2003-11-27 | Toyo Kohan Co., Ltd. | Feuille d'acier traitee en surface pour un boitier de batterie, boitier de batterie et batterie faisant appel a ce boitier |
| JP2008226795A (ja) * | 2007-03-15 | 2008-09-25 | Fdk Energy Co Ltd | 電池用金属部品及び電池 |
| WO2018052009A1 (fr) * | 2016-09-13 | 2018-03-22 | 東洋鋼鈑株式会社 | Procédé de fabrication de tôle d'acier à traitement de surface pour boîtier de batterie |
| KR20190049738A (ko) * | 2016-09-13 | 2019-05-09 | 도요 고한 가부시키가이샤 | 전지 용기용 표면 처리 강판의 제조 방법 |
| JPWO2018052009A1 (ja) * | 2016-09-13 | 2019-06-24 | 東洋鋼鈑株式会社 | 電池容器用表面処理鋼板の製造方法 |
| JP7187313B2 (ja) | 2016-09-13 | 2022-12-12 | 東洋鋼鈑株式会社 | 電池容器用表面処理鋼板の製造方法 |
| KR102479919B1 (ko) * | 2016-09-13 | 2022-12-20 | 도요 고한 가부시키가이샤 | 전지 용기용 표면 처리 강판의 제조 방법 |
| WO2019111556A1 (fr) * | 2017-12-07 | 2019-06-13 | 株式会社豊田自動織機 | Dispositif de stockage d'électricité, procédé de production de dispositif de stockage d'électricité et procédé de placage électrolytique |
| JPWO2019111556A1 (ja) * | 2017-12-07 | 2020-12-24 | 株式会社豊田自動織機 | 蓄電装置、蓄電装置の製造方法、及び電解メッキ方法 |
| CN115787004A (zh) * | 2022-10-18 | 2023-03-14 | 邯郸市金泰包装材料有限公司 | 一种新能源汽车电池壳用高速预镀镍钢带及其制造方法 |
Also Published As
| Publication number | Publication date |
|---|---|
| JP3678347B2 (ja) | 2005-08-03 |
| AU3841100A (en) | 2000-11-10 |
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