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WO2000064961A1 - Copolyesters cristallisables - Google Patents

Copolyesters cristallisables Download PDF

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Publication number
WO2000064961A1
WO2000064961A1 PCT/US2000/011009 US0011009W WO0064961A1 WO 2000064961 A1 WO2000064961 A1 WO 2000064961A1 US 0011009 W US0011009 W US 0011009W WO 0064961 A1 WO0064961 A1 WO 0064961A1
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WO
WIPO (PCT)
Prior art keywords
glycol
poly
polyester
acid
alkylene
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Ceased
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PCT/US2000/011009
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English (en)
Inventor
Martin Emerson Rogers
Sara Stanley Wells
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Eastman Chemical Co
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Eastman Chemical Co
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Filing date
Publication date
Application filed by Eastman Chemical Co filed Critical Eastman Chemical Co
Priority to AU48017/00A priority Critical patent/AU4801700A/en
Publication of WO2000064961A1 publication Critical patent/WO2000064961A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/66—Polyesters containing oxygen in the form of ether groups
    • C08G63/668—Polyesters containing oxygen in the form of ether groups derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/672—Dicarboxylic acids and dihydroxy compounds

Definitions

  • Thermoplastic polyesters are often modified by the addition of a comonomer to enhance some useful property such as gas barrier, toughness, or impact strength. Copolymer modification is also widely used to slow the rate of crystallization from the melt to enable the molding of thick amorphous parts having good optical transparency. If molded from a rapidly crystallizing homopolymer, these parts would be partially crystalline and consequently optically hazy or opaque due to the slow heat transfer characteristic of a thick part.
  • Copolymer modification also slows the rate of crystallization from the glass, and this is often undesirable because it interferes with the manufacture or processing of the polymer. Some polyester homopolymers are also slow to crystallize from the glass, creating the same difficulties.
  • polyesters for blow molded container applications are typically manufactured in two stages: melt phase polymerization to a moderate molecular weight followed by polymerization in the solid state to further increase molecular weight.
  • the melt phase intermediate must be pelletized and partially crystallized prior to solid state polymerization. Crystallization of the amorphous melt phase pellets is accomplished by heating them to above their glass transition temperature (crystallization from the glass) while agitating them to prevent sticking and agglomeration. It is highly desirable that the pellets crystallize rapidly; if they are slow to crystallize, agglomeration is difficult to avoid and the production rate is reduced.
  • the pellets must attain a certain degree of crystallinity prior to introduction into the solid state polymerization reactor to avoid sticking and agglomeration in the reactor.
  • Polyesters highly modified with a comonomer often undergo solid state polymerization at lower temperatures to avoid sticking and agglomeration in the reactor.
  • the slow crystallization rate characteristic of polyester copolymers (and some homopolymers) may therefore slow the production rate.
  • polyester copolymers and homopolymers that are slow to crystallize from the glass create manufacturing difficulties during pellet crystallization and slow the rate of production.
  • EP 822,213 discloses polyester compositions comprising terephthalic acid, up to 15 weight percent of a second acid component and polyalkylene glycol in amounts 0.001 to 10 percent by weight of the glycol component.
  • the compositions are disclosed to have improved crystallization from the glass during heat setting.
  • EP 822,213 does not disclose crystallizable polyesters having more than 15 weight percent acid component modification which can be fabricated into useful articles such as films or bottles.
  • US 3,663,653 discloses polyester compositions having up to 10 weight percent copolymer modification and 0.5 to 15 weight percent polytetrahydrofuran have good crystallization from the melt. However, crystallizable polyesters having more than 15 weight percent copolymer modification are not disclosed.
  • This invention relates to new polyester compositions, processes to prepare the new polyester compositions, and articles, film, and sheet made from the new polyester compositions by molding, extrusion, or other melt processing techniques. Specifically, this invention relates to thermoplastic copolyester compositions comprising at least 15 weight percent acid component modification, an inherent viscosity of greater than 0.5 dl/g, and containing at least one poly(alkylene glycol) having an alkylene chain of 2 to 10 carbon atoms.
  • This invention also relates to procedures for incorporating the poly(alkylene glycol) into the polyester composition at any point in the polymerization, by any one of several methods, including but not limited to (1) addition directly into the melt phase reactor, (2) addition of the poly(alkylene glycol) into the molten polyester composition after completion of melt phase polymerization but prior to strand extrusion and pelletizing, (3) compounding the poly(alkylene glycol) with polyester pellets to form a concentrate which is subsequently blended with additional polyester in the final molding or extrusion process, (4) addition of the poly(alkylene glycol) directly into the feed hopper or feed throat of the molding machine or extruder used to manufacture the final article, and (5) blending the poly(alkylene glycol) with polyester pellets prior to molding or extrusion.
  • a polyester copolymer modified with at least 15 weight percent, based upon the weight percent of all acid components, and preferably 15 to about 25 weight percent of a dibasic acid and about 0.01 to about 5.0 weight percent of a poly(alkylene glycol) such as poly(tetramethylene glycol) and poly(ethylene oxide) can be produced in a crystalline form with a high IhN of 0.5 to 1.3 dl/g.
  • 0.01 to 5.0 weight percent of a poly(alkylene glycol) incorporated in a thermoplastic polyester greatly increases the crystallization rate from the glass while increasing the crystallization rate from the melt only moderately or not at all.
  • a polyester with about 0.01 to about 5.0 weight percent of a poly(alkylene glycol) allowed the polyester to solid state polymerized at a higher temperature and rate while successfully reducing or preventing sticking during solid state polymerization at the higher temperature.
  • a polyester copolymer modified with up to 25 weight percent of a dibasic acid and 0.01 to 5.0 weight percent of a poly(alkylene glycol) such as poly(tetramethylene glycol) and poly(ethylene oxide) can be fabricated into a hollow vessel such as a bottle.
  • the poly(alkylene glycol) does not degrade the optical properties such as clarity, transparency, and color of the polyester, both in the amorphous state and after crystallization via mechanical orientation or stretch blow molding.
  • the invention is particularly effective in poly(alkylene arylates) such as poly(alkylene terephthalates), poly(alkylene isophthalates), poly(alkylene naphthalates), and copolymers, blends, and mixtures thereof.
  • poly(alkylene arylates) such as poly(alkylene terephthalates), poly(alkylene isophthalates), poly(alkylene naphthalates), and copolymers, blends, and mixtures thereof.
  • polyester composition and process for producing the polyester are described below in detail.
  • Suitable polyesters comprise a glycol component and an acid component comprising a first dicarboxylic acid and at least 15 weight % of at least one second dicarboxylic acid, based upon the acid component.
  • the first dicarboxylic acids are terephthalic, isophthalic, naphthalenedicarboxylic, 1,4-cyclohexanedicarboxylic acid, phenylenedioxydiacetic acid and the like.
  • the first dicarboxylic acid is terephthalic acid.
  • the various isomers of naphthalenedicarboxylic acid or mixtures of isomers may be used but the 1,4-, 1,5-, 2,6-, and 2,7-isomers are preferred.
  • the 1 ,4-cyclohexanedicarboxylic acid may be in the form of cis, trans, or cis/trans mixtures.
  • the various isomers of phenylenedioxydiacetic acid or mixtures of isomers may be used but the 1,2-, 1,3-, 1,4- isomers are preferred.
  • the lower alkyl esters or acid chlorides may be also be used.
  • the second dicarboxylic acid is present in an amount greater than 15 weight
  • Such additional dicarboxylic acids include dicarboxylic acids having from 6 to about 40 carbon atoms, and more preferably dicarboxylic acids selected from aromatic dicarboxylic acids preferably having 8 to 14 carbon atoms, aliphatic dicarboxylic acids preferably having 4 to 12 carbon atoms, or cycloaliphatic dicarboxylic acids preferably having 7 to 12 carbon atoms.
  • dicarboxylic acids examples include phthalic acid, isophthalic acid, naphthalene-2,6-dicarboxylic acid, cyclohexanedicarboxylic acid, cyclohexanediacetic acid, diphenyl-4,4'-dicarboxylic acid, 1,3- phenylenedioxydiacetic acid, 1,2-phenylenedioxydiacetic acid, 1,4- phenylenedioxydiacetic acid, succinic acid, glutaric acid, adipic acid, azelaic acid, sebacic acid, and the like.
  • isophthalic acid is the preferred second dicarboxylic acid.
  • Polyesters may be prepared from one or more of the above dicarboxylic acids.
  • Typical glycols used in the polyester include aliphatic glycols containing from two to about ten carbon atoms, and cycloaliphatic glycols containing 7 to 14 carbon atoms.
  • Preferred glycols include ethylene glycol, 1 ,4-butanediol, 1 ,6-hexanediol, 1,4-cyclohexanedimethanol, diethylene glycol and the like.
  • the glycol component may optionally be modified with up to about 25 weight percent, preferably up to about 20 weight percent and most preferably up to about 15 weight percent of one or more different diols.
  • Such additional diols include cycloaliphatic diols preferably having 6 to 20 carbon atoms, aromatic diols containing from 6 to 15 carbon atoms or aliphatic diols preferably having 3 to 20 carbon atoms.
  • diols include: diethylene glycol, triethylene glycol, 1,4-cyclohexanedimethanol (when using 1,4-cyclohexanedimethanol, it may be the cis, trans or cis/trans mixtures), propane- 1,3-diol, butane- 1 ,4-diol, pentane-l,5-diol, hexane-l,6-diol, 3-methylpentanediol-(2,4), 2-methylpentanediol-(l,4), 2,2,4- trimethylpentane-diol-(l ,3), 2-ethylhexanediol-(l ,3), 2,
  • Polyesters may be prepared from one or more of the above diols.
  • the poly(alkylene glycol) having an alkylene chain of 2 to 10 carbon atoms, which forms the diol constituent units, is poly(alkylene glycol) generally known.
  • the poly(alkylene glycols) can be obtained by method well known in the art.
  • the poly(alkylene glycol) desirably has a molecular weight of 100 to 10,000 g/mole, preferably 400 to 3000 g/mole.
  • Examples of poly(alkylene glycol)s include poly(ethylene glycol), poly(propylene glycol), poly(tetraemethylene glycol), poly(heptamethylene glycol), poly(hexamethylene glycol) and poly(octamethylene glycol). Of these, particularly preferable is poly (tetramethy lene glycol).
  • the constituent units derived from the poly(alkylene glycol) in the first polyester are contained in amounts of 0.01 to 10 percent by weight, preferably 0.01 to 8 percent by weight, more preferably 0.1 to 5 percent by weight, based on the constituent units.
  • the amounts of the constituent units derived from the poly(alkylene glycol) are less than 0.01 percent by weight, the improvement in the heat-up crystallization rate or solid state polymerization temperature of the polyester might be insufficient.
  • Difunctional components such as hydroxybenzoic acid may also be used.
  • multifunctional polyols such as trimethylolpropane, pentaerythritol, glycerol and the like may be used if desired.
  • the resin may also contain small amounts of trifunctional or tetrafunctional comonomers to provide controlled branching in the polymers.
  • comonomers include trimellitic anhydride, trimethylolpropane, pyromellitic dianhydride, pentaerythritol, trimellitic acid, trimellitic acid, pyromellitic acid and other polyester forming polyacids or polyols generally known in the art.
  • additives normally used in polyesters may be used if desired.
  • additives include, but are not limited to colorants, pigments, carbon black, glass fibers, fillers, impact modifiers, antioxidants, stabilizers, flame retardants, reheat aids, acetaldehyde reducing compounds, barrier enhancing compounds, UN absorbing compounds and the like.
  • polyester monomer diglycol esters of dicarboxylic acids
  • oligomers Prior to the polycondensation of the melt-phase process, a mixture of polyester monomer (diglycol esters of dicarboxylic acids) and oligomers are produced by conventional, well-known processes.
  • One such process is the esterification of one or more dicarboxylic acids with one or more glycols; in another process, one or more dialkyl esters of dicarboxylic acids undergo transesterification with one or more glycols in the presence of a catalyst.
  • the monomer and oligomer mixture is typically produced continuously in a series of one or more reactors operating at elevated temperature and pressures at one atmosphere or greater. Alternately, the monomer and oligomer mixture could be produced in one or more batch reactors.
  • Suitable conditions for esterification and transesterification include temperatures between 200 to about 250°C and pressures of about 0 to about 80 psig. It should be understood that generally the lower the reaction temperature, the longer the
  • the mixture of polyester monomer and oligomers undergoes melt-phase polycondensation to produce a low molecular weight precursor polymer.
  • the precursor is produced in a series of one or more reactors operating at elevated temperatures.
  • the polycondensation reactors are run under a vacuum or purged with an inert gas.
  • Inert gas is any gas not causing unwanted reaction. Suitable gases include, but are not limited to partially or fully dehumidified air, CO 2 , argon, helium and nitrogen.
  • Catalysts for the polycondensation reaction include salts of antimony, germanium, tin, lead, or gallium, preferably antimony or germanium.
  • Reactions conditions for polycondensation include a temperature less than about 290°C, and preferably between about 240°C and 290°C at a pressure sufficient to aid in removing undesirable reaction products such as ethylene glycol.
  • Precursor IhN is generally below about 0.7 to maintain good color. The target IhN is generally selected to balance good color and minimize the amount of solid stating required.
  • Inherent viscosity (IhN) was measured at 25°C using 0.50 grams of polymer per 100 ml of a solvent consisting of 60 percent by weight phenol and 40 percent by weight tetrachloroethane.
  • the low molecular weight precursor polymer is typically produced continuously in a series of one or more reactors operating at elevated temperature and pressures less than one atmosphere.
  • low molecular weight precursor polymer could be produced in one or more batch reactors.
  • the pellets may be fed directly into an extruder, or solid stated at conventional conditions until the desired molecular weight is attained.
  • the precursor is crystallized and undergoes further polycondensation in the solid state by conventional, well-known processes, such as those disclosed in U.S. Pat. No. 4,064,112.
  • Solid state polycondensation can be conducted in the presence of an inert gas as defined above, or under vacuum conditions, and in a batch or continuous process.
  • the polyester can be in the form of pellets, granules, chips or powder. Temperature during the solid state polycondensation process should be about 1 to 60°C below the melting point of the polyester as measured by differential scanning calorimetry (DSC).
  • the low molecular weight precursor polymer containing low levels of poly(alkylene glycol)s can be solid state polymerized at temperatures nearer to its melting point without sticking or agglomeration.
  • Polyesters containing poly(alkylene glycol)s can be solid state polymerized at a rate higher than the same polyester without the poly(alkylene glycol). Thus polyesters containing poly(alkylene glycol)s can be produced more efficiently.
  • Polyesters displaying selectively improved crystallization from the glass may be produced by any one of several methods.
  • the poly(alkylene glycol) may be added at nearly any point in the polyester manufacturing process or during article fabrication. Some of the most beneficial aspects of the improved crystallization are seen during crystallization prior to solid stating and during solid stating. Thus, for improvement in pellet crystallization, addition is preferably made prior to pelletizating the low molecular weight precursor polymer.
  • the poly(alkylene glycol) may be added directly into the melt phase reactor during esterification, prepolymer or polycondensation stages. If this method is used it is desirable to add the poly(alkylene glycol) at a point in the reactors where there is good mixing to insure homogeneous distribution of the poly(alkylene glycol) throughout the polymer melt.
  • the poly(alkylene glycol) may be added undiluted directly to the polymer melt or incorporated into a liquid carrier and added to the polymer melt. If a liquid carrier is used the poly(alkylene glycol) may incorporated into the liquid carrier at concentrations of 1 to 99 weight percent.
  • the liquid carrier may be any organic solvent or water.
  • the liquid carrier is ethylene glycol.
  • poly(alkylene glycol) may be undiluted or incorporated into a low molecular weight, polymeric or liquid carrier and added to the molten polyester composition after completion of polycondensation but prior to strand extrusion and pelletizing.
  • the desired amount of the poly(alkylene glycol) or a poly(alkylene glycol) concentrate may be fed directly with the polyester pellets into the feed hopper or feed throat of the molding machine or extruder used to manufacture the final article.
  • the poly(alkylene glycol) may also be incorporated in a liquid carrier and introduced into an extruder. Suitable liquid carrier systems include those made by Colormatrix, Inc. Addition of the poly(alkylene glycol) after pelletization is particularly useful for making shaped articles, such as containers, which require thermal treatments after being formed.
  • Stretch blow molded containers made from the polyester of the present invention may be produced by either the one step extrusion blow molding method or the two step reheat blow mold method.
  • the stretching temperature is 70° to 120° C, preferably 80° to 110° C, and the stretching ratio is 1.5 to 3.5 times in the machine direction and 2 to 5 times in the hoop direction.
  • the stretched bottles may be used as is or heatset in a mold at a temperature of not lower than 100°C.
  • the finish of the preform of the heatset bottles may be thermally crystallized before stretch blow molding or the finish may be thermally crystallized after stretch blow molding.
  • the polyester of the present invention may make up one or more layers of a multilayer that includes one or more barrier layers such as a polyamide, ENOH or a layer containing an oxygen scavenger.
  • a uniaxially or biaxially stretched film from a polyester of the present invention or a can-shaped container, a tray or the like by vacuum forming or air-pressure forming after it is formed into a sheet by injection molding. It is also possible to form a polyester of the present invention into a multi-layered sheet of the polyester and polyethylene terephthalate, for example, by a multi-layer extruder and thereafter form the sheet into a uniaxially or biaxially stretched film, a can-shaped container or a tray.
  • a polyester composition of the present invention can and formed into a film, sheet, container, and other packaging material by a melt molding method which is generally used in molding polyethylene terephthalate.
  • the polyester composition is usable as a material having a high gas barrier property in an unstretched state.
  • stretching the polyester composition at least uniaxially it is possible to improve the gas barrier property and the mechanical strength.
  • a stretched sheet of a polyester composition of the present invention is produced by stretching a polyester of the present invention which has been formed into a sheet by injection molding or extrusion molding.
  • the stretching method adopted may be freely selected from uniaxially stretching, sequential biaxially stretching and simultaneous biaxially stretching. It is also possible to form a stretched sheet of a polyester composition of the present invention into a cup or a tray by air-pressure forming.
  • the inherent viscosity, IhN was measured at 25 °C at a concentration of 0.5 g/dL in a 60/40 weight percent mixture of phenol/tetrachloroethane.
  • the crystallization behavior of the films was characterized using a differential scanning calorimeter (DSC).
  • the isothermal crystallization halftime was measured by heating rapidly from the glassy state (after an initial heat/quench to destroy any pre-existing crystallinity) to either 140, 150 or 160°C and then maintaining that temperature, and also by cooling rapidly from the molten state to either 140, 160, or 180°C and then maintaining that temperature. The shorter the crystallization halftime, the faster the rate of crystallization.
  • the film was heated in the DSC to 290°C to destroy any pre-existing crystallinity, then quenched to room temperature to create a glassy amorphous sample, then heated at a rate of 20°C/min.
  • the crystallization temperature on heatmg, T C h was determined from the peak of the exothermic transition.
  • the crystallization temperature from the melt (T cc ) was determined from the peak of the exothermic transition observed while cooling the sample from 290°C at 20°C per minute.
  • Dimethyl terephthalate (0.425 mol, 82.45 g), dimethyl isophthalate (0.075 mol., 14.55 g), ethylene glycol (1.0 mol, 62 g), manganese acetate ( 0.095 mmol, 0.017 g) and antimony(III)oxide (0.086 mmol, 0.025 g) were placed in a 0.5 L polymerization reactor under a nitrogen atmosphere.
  • the mixture was heated with stirring at 200°C for 90 min. The temperature was increased to 220°C and maintained for 70 min.
  • Phosphoric acid (0.28 mmol, 0.027 g) was added to the mixture. The temperature was increased to 280°C, the nitrogen flow was stopped and vacuum applied.
  • the polymer was stirred under vacuum (0.2 mm Hg) for
  • the polymer was cooled and ground to pass through a 3 mm screen.
  • the polymer had an IhN of 0.65 dL/g.
  • Thermal analysis results are listed in Table 1.
  • the ground polymer was crystallized at 150°C for two hours.
  • the ground polymer was sifted over a 850 micron sieve.
  • the polymer (12 grams) was then placed in a solid state unit having a nitrogen purge and heated at 197°C. The ground polymer was stuck together after 9 hours in the solid state unit.
  • Example 2 PET copolymer modified with 15.0 weight percent dimethyl isophthalate and 0.5 wt. percent PTMG
  • Dimethyl terephthalate (0.425 mol, 82.45 g), dimethyl isophthalate (0.075 mol., 14.55 g), poly(tetramethylene glycol) ( ⁇ Mn> 1000 g/mole, 0.48 mmol, 0.48 g), ethylene glycol (1.0 mol, 62 g), manganese acetate ( 0.095 mmol, 0.017 g) and antimony(III)oxide (0.086 mmol, 0.025 g) were placed in a 0.5 L polymerization reactor under a nitrogen atmosphere. The mixture was heated with stirring at 200°C for 90 min. The temperature was increased to 220°C and maintained for 70 min.
  • Example 3 PET copolymer modified with 15.0 weight percent dimethyl isophthalate and 1.0 wt. percent PTMG
  • Dimethyl terephthalate (0.425 mol, 82.45 g), dimethyl isophthalate (0.075 mol., 14.55 g), poly(tetramethylene glycol) ( ⁇ Mn> 1000 g/mole, 0.97 mmol, 0.97 g), ethylene glycol (1.0 mol, 62 g), manganese acetate ( 0.095 mmol, 0.017 g) and antimony(III)oxide (0.086 mmol, 0.025 g) were placed in a 0.5 L polymerization reactor under a nitrogen atmosphere. The mixture was heated with stirring at 200°C for 90 min. The temperature was increased to 220°C and maintained for 70 min.
  • Example 4 PET copolymer modified with 18.0 weight percent dimethyl isophthalate
  • Example 5 PET copolymer modified with 18.0 weight percent dimethyl isophthalate and 0.5 weight percent PTMG
  • Example 6 PET copolymer modified with 18.0 weight percent dimethyl isophthalate and 1.5 weight percent PTMG
  • the data in Table 2 shows that crystallization from the glass is improved for copolymer modifications greater than 15 weight percent. Below 15 weight percent modification, the copolymers can be crystallized in a reasonable time using commercial processes. For example, we measured the crystallization halftime of PET modified with 12 weight percent dimethyl isophthalate to be 4.2 seconds at 160°C from the glass without any crystallization aids. Thus, PET modified with 12 weight percent dimethyl isophthalate crystallizes much faster than Example 4 (18 weight % modification). Copoly esters containing greater than 15 weight percent of a comonomer are undesirably slow to crystallize.

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polyesters Or Polycarbonates (AREA)

Abstract

La présente invention concerne des compositions de copolyester thermoplastique ayant subi une modification d'au moins 15 % en poids de composant acide et/ou glycol, présentant une viscosité inhérente supérieure à 0,5 dl/g, et contenant au moins un poly(alkylène glycol) ayant une chaîne alkylène comprenant entre 2 et 10 atomes de carbone. En outre, cette invention concerne des techniques d'incorporation de poly(alkylène glycol) dans la composition polyester à n'importe quel stade de la polymérisation. En l'occurrence, les compositions de cette invention présentent une meilleure cristallisation à partir de l'état vitreux, avec de très faibles différences de cristallisation à partir de l'état fondu.
PCT/US2000/011009 1999-04-28 2000-04-24 Copolyesters cristallisables Ceased WO2000064961A1 (fr)

Priority Applications (1)

Application Number Priority Date Filing Date Title
AU48017/00A AU4801700A (en) 1999-04-28 2000-04-24 Crystallisable copolyesters

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
US13134999P 1999-04-28 1999-04-28
US60/131,349 1999-04-28
US52540600A 2000-03-15 2000-03-15
US09/525,406 2000-03-15

Publications (1)

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WO2000064961A1 true WO2000064961A1 (fr) 2000-11-02

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004104080A1 (fr) * 2003-05-21 2004-12-02 Wellman, Inc. Resines de polyester a cristallisation lente
US7094863B2 (en) 2003-05-21 2006-08-22 Wellman, Inc. Polyester preforms useful for enhanced heat-set bottles
US7192545B2 (en) 2003-10-10 2007-03-20 Eastman Chemical Company Thermal crystallization of a molten polyester polymer in a fluid
US7329723B2 (en) 2003-09-18 2008-02-12 Eastman Chemical Company Thermal crystallization of polyester pellets in liquid
US8791225B2 (en) 2008-06-06 2014-07-29 Dak Americas Mississippi Inc. Titanium-nitride catalyzed polyester

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4251652A (en) * 1978-06-05 1981-02-17 Toray Industries, Inc. Polyetherester block copolymer and process for producing the same
JPS56159220A (en) * 1980-05-15 1981-12-08 Mitsubishi Chem Ind Ltd High-crystallinity thermoplastic copolyester
EP0822213A1 (fr) * 1996-02-21 1998-02-04 Mitsui Petrochemical Industries, Ltd. Polyester, composition a base de polyester, stratifie polyester et procede de fabrication de bouteilles en polyester etirees bi-axialement

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4251652A (en) * 1978-06-05 1981-02-17 Toray Industries, Inc. Polyetherester block copolymer and process for producing the same
JPS56159220A (en) * 1980-05-15 1981-12-08 Mitsubishi Chem Ind Ltd High-crystallinity thermoplastic copolyester
EP0822213A1 (fr) * 1996-02-21 1998-02-04 Mitsui Petrochemical Industries, Ltd. Polyester, composition a base de polyester, stratifie polyester et procede de fabrication de bouteilles en polyester etirees bi-axialement

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
DATABASE WPI Week 198203, Derwent World Patents Index; AN 1982-05022e, XP002144638 *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2004104080A1 (fr) * 2003-05-21 2004-12-02 Wellman, Inc. Resines de polyester a cristallisation lente
US7094863B2 (en) 2003-05-21 2006-08-22 Wellman, Inc. Polyester preforms useful for enhanced heat-set bottles
US7129317B2 (en) 2003-05-21 2006-10-31 Wellman, Inc. Slow-crystallizing polyester resins
US7329723B2 (en) 2003-09-18 2008-02-12 Eastman Chemical Company Thermal crystallization of polyester pellets in liquid
US7192545B2 (en) 2003-10-10 2007-03-20 Eastman Chemical Company Thermal crystallization of a molten polyester polymer in a fluid
US8791225B2 (en) 2008-06-06 2014-07-29 Dak Americas Mississippi Inc. Titanium-nitride catalyzed polyester

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