WO2000053037A1 - Cigarette filter - Google Patents
Cigarette filter Download PDFInfo
- Publication number
- WO2000053037A1 WO2000053037A1 PCT/GB2000/000850 GB0000850W WO0053037A1 WO 2000053037 A1 WO2000053037 A1 WO 2000053037A1 GB 0000850 W GB0000850 W GB 0000850W WO 0053037 A1 WO0053037 A1 WO 0053037A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- rod
- filter
- tubular body
- cigarette
- filtering plug
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
Definitions
- the present invention concerns a filter suitable, for example, for papirosi-type cigarettes.
- a tobacco smoke filter which comprises a thermoformed filter rod having a tubular body of tobacco smoke filtering material which is open at at least one end and blocked by a filtering plug of said tobacco smoke filtering material integral with the tubular body.
- the tubular body may be open at one end and closed at the other by the filtering plug. It may instead be open at both ends and blocked between these ends by the filtering plug; in this case there are two tubular terminal portions joined by the integral filtering plug.
- the tubular length of the rod will usually be at least the same as the length of the filtering plug and will preferably be longer - e.g. two to three or more times as long; thus the tubular length : filtering plug length ratio might be 6:1 or about 4:1 but is often suitably about 5:2, particularly in a rod of about 70 mm total length.
- the integral thermoformed filter rod will usually be uniform in circumference and configuration from end to end; it will most usually have a uniform circular cylindrical outer surface from end to end.
- the bore of the tubular body may be circular in cross-section, but its cross-section might instead be non-circular, for example triangular or other polygonal, cruciform, or star-shaped (with for example 4, 5 or 6 points) .
- the filter rod of the invention may have a terminal integral filtering plug at the buccal end and the open end of the tubular body towards the tobacco.
- a filter rod according to the invention with a terminal or m-board integral filtering plug is joined to a wrapped tobacco rod to form a papirosi filter cigarette with an open tubular buccal end.
- a short wrapped tobacco rod e.g. 25-50 mm
- a long filter rod according to the invention e.g. 50 to 80 mm
- having only a short filtering plug e.g. 10 to 20 mm, or about 15 mm
- such cigarettes would suit smokers wanting only a short smoke (e.g. ust 2 to 5, preferably 3 or 4, puffs) and would be low tar (because of the consumption of a low quantity of tobacco rod) whilst giving a satisfying smoke (because filtration is limited predominantly to the filtering plug section) .
- the filter rod is preferably thermoformed from fibres or filamentary tow of plasticised cellulose acetate, but other thermoformable fibres or filaments (e.g. of polyolefm) or other thermoformable filter material, e.g. thermoformable open-cell foam, could be employed instead.
- the tubular body retains or develops firmness to resist collapse during subsequent handling (e.g. wrapping and/or assembly with a cigarette rod) or on smoking.
- thermoformed filter rod according to the invention can be manufactured reliably at commercial spee ⁇ s by a single-pass in-line procedure.
- thermoformable filter material e.g. plasticised tow or tow mix
- a rod- forming garniture to which heat is supplied and into which a central mandrel reciprocates longitudinally so that there issues continuously from the garniture outlet an integral thermoformed rod of tobacco smoke filtering material in which tubular body sections of the filtering material alternate longitudinally with filtering plug sections of the filtering material.
- a conventional rod wrapper may be fed simultaneously into and through the garniture to provide a wrapped rod product, though the rod may be stable without such a wrapper.
- the continuously emerging rod, wrapped or unwrapped, can be cut laterally mid-way through the tubular and filtering plug portions to form individual papirosi type filter rods according to the invention with the integral filtering plug at one end. It may be preferred instead to cut the emerging rod only through the tubular portions to give rods with the integral filtering plug spaced from both open ends; an advantage with this embodiment is that it facilitates production of rods of constant reproducible pressure drop and retention because the initially formed integral filtering plug remains complete and uncut; in embodiments where there is cutting through the filtering plug then off-centre cutting (which is difficult to avoid in practice) results m successive rods with filtering plugs of different lengths and hence different pressure drop and retention values.
- the initial continuously produced rod can be cut first into integral double or other multiple length rods which are subsequently cut further into individual rods.
- a double length integral rod can be abutted between and in longitudinal alignment with two wrapped tobacco rods and joined to them by a tipping overwrap extending over the double length rod and the adjacent ends of the tobacco rods, and the assembly is then cut centrally of the double length rod to give two filter cigarettes.
- the resulting filter cigarettes will be papirosi filter cigarettes with the tubular body open at the buccal end; the double length rod could instead be cut to have a double length filtering plug between and integral with two tubular bodies open at opposite ends, in which case the resulting filter cigarettes would have the filtering plug at the buccal end and the tubular body open to the tobacco rod.
- the initial double or multiple length rods may be produced with or without their own wrapper.
- integral double or multiple length rods from which the individual rods can be cut, are included within the invention; such multiple length rods comprise a plurality of the individual rods according to the invention joined integrally end-to-end in mirror image fashion, and can for example have a filtering plug exposed at each end or a tubular body open at each end.
- the lengths of the tubular and filtering plug portions can be chosen to give a papirosi-type product having a desired filtering effect.
- the degree of filtering will also depend on the identity and degree of compaction of the smoke filtering material, and to a small extent on the surface area of the bore of the tubular body.
- the length of a filter rod according to the invention would typically be about 70 mm, but it can vary widely - e.g. from 20 to 90 mm.
- the length of the filtering plug portion would normally be from 8 or 10 to 50 mm, but as indicated above is preferably less than that of the tubular port ⁇ on(s).
- the filtering plug will usually not be less than 8 or 10 mm long (since otherwise its filtration effect may be too low) , and it will not usually be longer than 20 or 25 or 30 mm (since otherwise its filtration effect or resistance to draw may be too great) ; particularly for a papirosi filter cigarette, the tubular length is usually of less technical consequence and may be set by the overall length required of the final product, and so as indicated above may be 2 or 3 (e.g. about 2.5) times as long as the filtering plug.
- the wall of the tubular portion (s) of rods according to the invention is preferably relatively thin, e.g. from about one quarter to one eighth or less of the rod diameter, so that the tube bore is about one half to three quarters or more of the rod outer diameter.
- the tube wall of the integral rod should be sufficiently strong to resist collapse during manufacture, handling, storage and use.
- the wall thickness of the tubular portions may for example be from 1 to 2 mm, preferably about 1.5 mm.
- the outer diameter of the rod is preferably between 7 and 9 mm, similar to that of conventional papirosi cigarettes.
- One manufactured filter rod according to the invention had a total length of 74 mm with a terminal plug 18 mm long integral with a tubular body 56 mm long, the wall of the tubular body being about 1.5 mm thick.
- This filter rod had a pressure drop (measured on the enclosed rod as usual) of 64 mm water gauge.
- This rod of 24.5 mm circumference, was attached to a wrapped tobacco rod 50 mm long with the filter plug against the tobacco to give an unventilated filter cigarette having a tar retention of 40% and a nicotine retention of 38%.
- the thermoformed filter rod according to the invention may be manufactured unwrapped or with its own wrapper, longitudinally coterminous with the rod.
- ring tipping may be employed to oin it to a wrapped tobacco rod to form a filter cigarette; in this case the filter wrapper, exposed n the final cigarette assembly, is preferably water-resistant or water-repellant to avoid adherence to the lips during smoking.
- the filter rod is unwrapped or provided with its own wrapper, it can instead be incorporated in the filter cigarette product by a full tipping overwrap which covers the whole length of the filter rod and the adjacent end of the wrapped tobacco rod; in this case the tipping overwrap is preferably water- repellant or water-resistant.
- the wrapped tobacco rod of the filter cigarette would usually be 30 or 40 mm long, but could for example be up to 90 mm long.
- the tobacco would be wrapped m a conventional combustible cigarette paper.
- Tar delivery by the filter cigarette product can oe reduced by ventilating the thermoformed filter rod through the wrapper (s) around the rod.
- the rod wrapper may be pre-perforated to provide, during smoking, air dilution into the filter rod; similarly, where a tipping overwrap is employed this may be pre-perforated in the region to cover the rod (with the rod wrap, if any, between the overwrap and the rod being air permeable) .
- On-line laser techniques could instead be used during assembly of the filter cigarette product to provide ventilation holes through the wrapper (s) around the thermoformed filter rod.
- the tar delivery of the filter cigarette product depends on the tar yield of the tobacco element, the filtration efficiency of the filter rod and the degree (if any) of ventilation.
- the tar delivery might for example oe from 1 to 65 mg under standard ISO conditions, but can be controlled to under 15 mg .
- a papirosi filter cigarette according to the invention suffers minimal staining of the buccal end of the filter, whatever the tar delivery.
- FIGURE 1 is a schematic side sectional view of a thermoformed filter rod according to the invention
- FIGURES 2 and 3 are similar views of the Figure 1 filter rod incorporated in papirosi filter cigarettes by ring tipping and a tipping overwrap respectively;
- FIGURE 4 is a similar view of the Figure 1 filter rod incorporated in a filter cigarette with its filtering plug at the buccal end;
- FIGURE 5 is a schematic side sectional view of a different thermoformed filter rod according to the invention.
- thermoformed filter rod [2] shown in Figure 1 has a tubular body [4] of filtering material integral with a filtering plug [6] of said filtering material.
- the integral thermoformed rod [2] is of plasticised cellulose acetate filamentary tow.
- the overall length 1 of the rod is typically about 70 mm, with the length t of the tubular body [4] being for example about 50 mm.
- the wall [8] of the tubular body [4] is about 1.5 mm thick and the outer surface [10] of the rod is of constant circular section throughout its length, with a diameter of about 8 mm.
- the bore [12] of the tubular body is also of circular section.
- Figure 2 shows the Figure 1 rod, having a rod wrap [20] longitudinally coterminous therewith, joined to a wrapped tobacco rod [14] by means of ring tipping [16] .
- Figure 3 shows the Figure 1 rod, without wrapper [20], joined to wrapped tobacco rod [14] by a tipping overwrap [18] .
- the tobacco rod [14] is aoout 40 mm. long.
- thermoformed filter rod [2] is in the opposite orientation to that in Figure 3, being joined by tipping overwrap [18] to wrapped tobacco rod [14] with the open end of its tubular body against the tobacco and its filtering plug at the buccal end.
- the dimensions are as indicated for Figures 1 to 3.
- wrappers [20 and 18] are air impermeable, but m each case they could instead be ventilating wraps.
- thermoformed filter rod [3] shown m Fig.5 is essentially the same as rod [2] of Fig.l except that the filtering plug [6] is centrally placed between and integral with two tubular body portions [5] which are open to the two ends of the rod.
- the rod is of plasticised cellulose acetate filamentary tow and has an overall length of 70 mm; the integral filtering plug [6] is about 20 mm long so that the total tubular length is about 50 mm with each tubular portion [5] being about 25 mm long.
- the tubular wall [8] is about 1.5 mm thick w th an outer diameter of about 8 mm, the outer surface [10] of the rod being of constant circular section and the bore [12] also being of circular section.
- the rod [3] of Fig.5 could be provided with a rod wrap (impermeable or ventilating) longitudinally coterminous therewith, and be joined to a wrapped tobacco rod by means of ring tipping, in the manner illustrated in Fig.2.
- the rod [3] without such coterminous rod wrap, could be joined to a tobacco rod by a tipping overwrap (impermeable or ventilating) extending the length of the rod and over the downstream end of the wrapped tobacco rod, m the manner illustrated m Fig.3.
- thermoformed filter rods and filter cigarettes according to the invention are set out in the Table below.
- Examples A to C are integral filter rods of the type shown m Fig.l; each has a length of 70 mm made up of substantially 50 mm of tubular body and substantially 20 mm of filtering plug.
- Examples A, B and C were made using a 50/50 mix of 5Y40 and 7Y34 cellulose acetate tows; a "dYn" tow is one of n x 10 total tow denier made up of Y-shaped cross-section filaments each of individual filament denier d.
- the plasticised tow and air-impermeable wrapper therefor are fed longitudinally into and through a heated rod-forming garniture with reciprocating mandrel as described above to give a wrapped integral rod of thermoformed tow m which 100 mm long tubular sections of the tow alternate with 40 mm long filtering plugs of the tow; tne cross-sectional shape of the bore of the tubular body is dictated by the cross- sectional shape of the mandrel.
- the continuously produced wrapped rod is cut laterally mid-way througn the tubular body and filtering plug portions to form the individual papirosi type filter rods according to the invention.
- the hardness measurements were made on the filtering plug portion of the filter rod; the wall of the tubular body portion has a slightly higher hardness than the filtering plug.
- Examples L and T involve rods made as for Examples A to
- each wrapped rod was attached to a standard wrapped tobacco rod by ring tipping with filtering plug against the tobacco and tubular body open at the buccal end, to give a papirosi filter cigarette.
- the tar and nicotine retention were measured under standard conditions; in each case tar delivery was reduced to about 13 mg .
- the values quoted, other than for retention, are those of the unattached filter rods.
- rods of the type shown in Fig.5 were made wholly of 8Y/39 cellulose acetate tow.
- Examples D and E illustrate filter cigarettes according to the invention with a short tobacco column and a long filter, suitable for a brief "smoking break". Apart from its cooling effect, a long filter is desirable since the end of the cigarette is a comfortable distance from the nose and face of the smoker when lighting up.
- the tobacco columns, in conventional cigarette paper are 30 rtvr long
- the filter rods according to the invention are 51 mm long and joined to the tobacco rods by conventional tipping overwrap which is impermeable m the case of Example D and perforated to give ventilation in the case of Example E.
- the filter rods are integral thermoformed bodies of plasticised cellulose acetate tow of 5 filament denier having a tubular body extending from an open buccal end to a filtering plug 17 mm long abutting against the tobacco rod and closing the tubular body at that upstream end.
- the outer diameter of the tobacco and filter rods is 24.5 mm, and the tubular wall thickness of the filter rod is 1.5 mm.
- the preferred embodiments of the present invention involve the thermoforming of filter material (preferably bonded fibrous and/or filamentary material) to provide an integral body having a relatively long and thm-walled tubular body closed (terminally or at an intermediate region) by a relatively short filtering plug.
- filter material preferably bonded fibrous and/or filamentary material
- This combination of features provides a readily and economically manufacturable filter which is robust enough to survive manufacture, handling, storage and use undamaged, and which gives a cool but satisfying smoke of controlled filtering efficiency and which is especially suitable for use in conjunction with a relatively short tobacco rod (giving, for example, just two or three or four puffs) .
Landscapes
- Cigarettes, Filters, And Manufacturing Of Filters (AREA)
Abstract
Description
Claims
Priority Applications (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2000603533A JP4444515B2 (en) | 1999-03-09 | 2000-03-08 | Cigarette filter |
| AU29314/00A AU2931400A (en) | 1999-03-09 | 2000-03-08 | Cigarette filter |
| EP00907850A EP1164879A1 (en) | 1999-03-09 | 2000-03-08 | Cigarette filter |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9905406.6 | 1999-03-09 | ||
| GB9905406A GB2347607B (en) | 1999-03-09 | 1999-03-09 | Papirosi cigarette filter |
| GB9921734A GB2356791B (en) | 1999-09-14 | 1999-09-14 | Cigarette filter |
| GB9921734.1 | 1999-09-14 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO2000053037A1 true WO2000053037A1 (en) | 2000-09-14 |
Family
ID=26315247
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/GB2000/000850 Ceased WO2000053037A1 (en) | 1999-03-09 | 2000-03-08 | Cigarette filter |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP1164879A1 (en) |
| JP (1) | JP4444515B2 (en) |
| CN (1) | CN100358447C (en) |
| AU (1) | AU2931400A (en) |
| RU (1) | RU2333712C2 (en) |
| WO (1) | WO2000053037A1 (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004014161A1 (en) * | 2002-08-09 | 2004-02-19 | British American Tobacco (Investments) Limited | Improvements relating to filter-tip cigarettes and method of manufacturing same |
| EP3457874B1 (en) | 2016-05-20 | 2020-05-13 | British American Tobacco (Investments) Limited | Article for use in apparatus for heating smokable material |
| US10730688B2 (en) | 2013-06-03 | 2020-08-04 | Essentra Filter Products Development Co. Pte. Ltd | Dispenser for particulate material |
| EP3512368B1 (en) | 2016-09-14 | 2022-03-30 | Nicoventures Trading Limited | A container |
| EP3920729A4 (en) * | 2019-02-08 | 2022-12-14 | Ysq International Pte. Ltd. | Method of producing filter elements for use with heatable tobacco products |
| US20230292818A1 (en) * | 2021-06-21 | 2023-09-21 | Kt&G Corporation | Tobacco rod, aerosol-generating article including the same, and aerosol generation device used therewith |
| EP3512361B1 (en) | 2016-09-14 | 2024-04-10 | Nicoventures Trading Limited | A container |
Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP2946677A4 (en) * | 2013-03-06 | 2016-10-05 | Japan Tobacco Inc | Cigarette production method, cigarette, and double cigarette |
| KR101764042B1 (en) * | 2013-03-06 | 2017-08-01 | 니뽄 다바코 산교 가부시키가이샤 | Cigarette production method |
| LT3003866T (en) | 2013-06-03 | 2019-04-10 | Essentra Filter Products Development Co. Pte. Ltd | Method of manufacture of a dispenser |
| GB2562764A (en) * | 2017-05-24 | 2018-11-28 | Robert Hopps Jason | Tobacco-containing consumable for aerosol generating devices |
| JP6864294B2 (en) * | 2018-04-12 | 2021-04-28 | 株式会社東亜産業 | Electronic cigarette cartridge |
| US11291242B2 (en) | 2019-08-28 | 2022-04-05 | Aiger Group Ag | Apparatus and method for forming a smoke filter |
| GB202106836D0 (en) * | 2021-05-13 | 2021-06-30 | Essentra Filter Products Dev Co Pte Ltd | Filter element, mouthpiece and cooling element |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4007745A (en) * | 1971-03-23 | 1977-02-15 | Celanese Corporation | Filter |
| US4388934A (en) * | 1980-06-18 | 1983-06-21 | British-American Tobacco Company Limited | Filters |
| US4583560A (en) * | 1982-07-07 | 1986-04-22 | Mitsubishi Acetate Co., Ltd | Tobacco smoke filter |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1341077A (en) * | 1971-09-16 | 1973-12-19 | Cigarette Components Ltd | Tobacco smoke filter element |
| CN2139364Y (en) * | 1992-09-26 | 1993-08-04 | 沈时谋 | Mouthpiece with tobacco smoke filter |
| US5509430A (en) * | 1993-12-14 | 1996-04-23 | American Filtrona Corporation | Bicomponent fibers and tobacco smoke filters formed therefrom |
| CN2221877Y (en) * | 1995-05-18 | 1996-03-13 | 王林 | Magnetization health care cigarette |
| US5839449A (en) * | 1996-01-29 | 1998-11-24 | R.J. Reynolds Tobacco Company | Low CO cigarette |
| CN2262809Y (en) * | 1996-03-01 | 1997-09-24 | 王林 | Activited low tar cigarette |
-
2000
- 2000-03-08 CN CNB008061726A patent/CN100358447C/en not_active Expired - Lifetime
- 2000-03-08 WO PCT/GB2000/000850 patent/WO2000053037A1/en not_active Ceased
- 2000-03-08 AU AU29314/00A patent/AU2931400A/en not_active Abandoned
- 2000-03-08 EP EP00907850A patent/EP1164879A1/en not_active Withdrawn
- 2000-03-08 RU RU2006134558/12A patent/RU2333712C2/en active
- 2000-03-08 JP JP2000603533A patent/JP4444515B2/en not_active Expired - Lifetime
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4007745A (en) * | 1971-03-23 | 1977-02-15 | Celanese Corporation | Filter |
| US4388934A (en) * | 1980-06-18 | 1983-06-21 | British-American Tobacco Company Limited | Filters |
| US4583560A (en) * | 1982-07-07 | 1986-04-22 | Mitsubishi Acetate Co., Ltd | Tobacco smoke filter |
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2004014161A1 (en) * | 2002-08-09 | 2004-02-19 | British American Tobacco (Investments) Limited | Improvements relating to filter-tip cigarettes and method of manufacturing same |
| AU2003249076B2 (en) * | 2002-08-09 | 2007-03-08 | British American Tobacco (Investments) Limited | Improvements relating to filter-tip cigarettes and method of manufacturing same |
| RU2314735C2 (en) * | 2002-08-09 | 2008-01-20 | Бритиш Америкэн Тобэкко (Инвестментс) Лимитед | Filter-tipped cigarettes and method for manufacturing the same |
| CN1674799B (en) * | 2002-08-09 | 2010-04-28 | 英美烟草(投资)有限公司 | Improvements in and relating to filter cigarettes |
| US8113217B2 (en) | 2002-08-09 | 2012-02-14 | British American Tobacco (Investments) Limited | Filter tip cigarettes and method of manufacturing same |
| US10730688B2 (en) | 2013-06-03 | 2020-08-04 | Essentra Filter Products Development Co. Pte. Ltd | Dispenser for particulate material |
| EP3457874B1 (en) | 2016-05-20 | 2020-05-13 | British American Tobacco (Investments) Limited | Article for use in apparatus for heating smokable material |
| EP4122332A1 (en) * | 2016-05-20 | 2023-01-25 | Nicoventures Trading Limited | Article for use in apparatus for heating smokable material |
| US12213514B2 (en) | 2016-05-20 | 2025-02-04 | Nicoventures Trading Limited | Article for use in an apparatus for heating smokable material |
| EP3457874B2 (en) † | 2016-05-20 | 2025-10-22 | Nicoventures Trading Limited | Article for use in apparatus for heating smokable material |
| EP3512368B1 (en) | 2016-09-14 | 2022-03-30 | Nicoventures Trading Limited | A container |
| EP3512361B1 (en) | 2016-09-14 | 2024-04-10 | Nicoventures Trading Limited | A container |
| US12376620B2 (en) | 2016-09-14 | 2025-08-05 | Nicoventures Trading Limited | Aerosol provision devices with a substance of 8-12 denier and a first and second tube portion extending therefrom |
| EP3920729A4 (en) * | 2019-02-08 | 2022-12-14 | Ysq International Pte. Ltd. | Method of producing filter elements for use with heatable tobacco products |
| US20230292818A1 (en) * | 2021-06-21 | 2023-09-21 | Kt&G Corporation | Tobacco rod, aerosol-generating article including the same, and aerosol generation device used therewith |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4444515B2 (en) | 2010-03-31 |
| CN100358447C (en) | 2008-01-02 |
| JP2002537863A (en) | 2002-11-12 |
| RU2006134558A (en) | 2008-04-20 |
| CN1347286A (en) | 2002-05-01 |
| RU2333712C2 (en) | 2008-09-20 |
| AU2931400A (en) | 2000-09-28 |
| EP1164879A1 (en) | 2002-01-02 |
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