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WO1998007816A1 - Compositions detergentes contenant un anticorps dirige contre une oxydoreductase - Google Patents

Compositions detergentes contenant un anticorps dirige contre une oxydoreductase Download PDF

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Publication number
WO1998007816A1
WO1998007816A1 PCT/US1996/013322 US9613322W WO9807816A1 WO 1998007816 A1 WO1998007816 A1 WO 1998007816A1 US 9613322 W US9613322 W US 9613322W WO 9807816 A1 WO9807816 A1 WO 9807816A1
Authority
WO
WIPO (PCT)
Prior art keywords
alkyl
detergent
hydrogen peroxide
detergent composition
antibody
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1996/013322
Other languages
English (en)
Inventor
Dimitris Lappas
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Priority to PCT/US1996/013322 priority Critical patent/WO1998007816A1/fr
Priority to AU68488/96A priority patent/AU6848896A/en
Priority to PCT/US1997/011545 priority patent/WO1998007824A1/fr
Priority to AU37938/97A priority patent/AU3793897A/en
Priority to CN97198730.0A priority patent/CN1233277A/zh
Priority to CA002263431A priority patent/CA2263431A1/fr
Priority to BR9713173-3A priority patent/BR9713173A/pt
Priority to JP10510728A priority patent/JP2000500819A/ja
Priority to EP97934875A priority patent/EP0925348A1/fr
Publication of WO1998007816A1 publication Critical patent/WO1998007816A1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/384—Animal products
    • C11D3/3845—Antibodies
    • C—CHEMISTRY; METALLURGY
    • C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/16—Organic compounds
    • C11D3/38—Products with no well-defined composition, e.g. natural products
    • C11D3/386—Preparations containing enzymes, e.g. protease or amylase
    • C11D3/38654—Preparations containing enzymes, e.g. protease or amylase containing oxidase or reductase

Definitions

  • EP 479 600, EP 453 097 and EP 450 800 relate to the use of antibodies or fragments thereof for the delivery of active ingredients to a target site.
  • EP 481 701 discloses treatment compositions for topical application containing microcapsules which enclose a beneficial agent at a target location, the microcapsules having an antibody or antibody fragment specific to the target location or a lectin.
  • compositions comprising antibodies as anti-carie or periodontal diseases treatment have been extensively described in WO95/01155, O95/00110, O95/10612, EP 140 498, GB 2 151 923, GB 2 176 400, GB 2 167 299, DE 4324859, US 5 401 723 and EP 280 576.
  • EP 673 683 and EP 542 309 disclose hair cosmetic compositions containing an antibody to hair or hair extract, obtained from egg yolk or poultry immunised with the hair or hair extract and a polymer emulsion to provide reduced hair damage, softness, moistened feel and smoothness, said composition being adsorbed only onto a specified part of the hair.
  • compositions containing antagonists (tyrphostins or antibodies) against epidermal and transforming growth factors, suitable for use in treatment of acne are described in W095/24896.
  • EP 400 569 discloses a method for preparing vaccine composition for dental caries in nasal drops comprising an antigen produced by integrating a protein antigen-expressing gene into the chromosomal gene of a streptococcus mutants GS-5 strain.
  • 094/25591 discloses the production of antibodies or functionalised fragments thereof derived from heavy chain immunoglobulins of camelidae.
  • Current detergent formulations generally include a bleaching system based on hydrogen peroxide or on hydrogen peroxide together with a bleach activator wherein a bleach activator is transformed into the active bleaching species
  • Donor hydrogen peroxide oxido-reductase are enzymes produced by microorganisms developed upon soils and stains found on fabrics, dishware and hard surfaces and by the human body and excreted in body fluids.
  • Donor hydrogen peroxide oxido- reductase enzyme are therefore found in body stains and/or soils found on fabrics, dishes and hard surfaces. These enzymes catalyse the direct conversion of hydrogen peroxide into water, reducing the amount of hydrogen peroxide available in the wash liquor for direct bleaching or for the perhydrolysis of the bleach activator into the bleaching active peracid.
  • Heavy and light chains are indeed composed of constant and variable domains .
  • the constant domains are very important for a number of functions, but for many applications in industrial processes and products their variable domains are sufficient. Consequently many methods have been described to produce antibody fragments.
  • Antibodies can be raised against any donor : hydrogen peroxide oxido-reductase of the class EC l.ll.l covering the hemo protein oxidoreductases, Seleno cystein oxidoreductase and Flavoprotein oxidoreductases and against cytochromes.
  • the cytochrome group includes all intracellular electron transfering heme proteins and includes cytochrome a, b, c and d.
  • the detergent compositions of the present invention include bleaching agents such as hydrogen peroxide, PB1 , PB4 and percarbonate with a particle size of 400-800 microns.
  • bleaching agent components can include one or more oxygen bleaching agents and, depending upon the bleaching agent chosen, one or more bleach activators. When present oxygen bleaching compounds will typically be present at levels of from about 1% to about 25%.
  • the bleaching agent component for use herein can be any of the bleaching agents useful for detergent compositions including oxygen bleaches as well as others known in the art .
  • the bleaching agent suitable for the present invention can be an activated or non-activated bleaching agen .
  • the detergent compositions according to the present invention comprise a surfactant system wherein the surfactant can be selected from nonionic and/or anionic and/or cationic and/or ampholytic and/or zwitterionic and/or semi -polar surfactants.
  • nonionic surfactant of the surfactant systems of the present invention are the alkylpolysaccharides disclosed in U.S. Patent 4,565,647, Llenado, issued January 21, 1986, having a hydrophobic group containing from about 6 to about 30 carbon atoms, preferably from about 10 to about 16 carbon atoms and a polysaccharide, e.g. a polyglycoside, hydrophilic group containing from about 1.3 to about 10, preferably from about 1.3 to about 3, most preferably from about 1.3 to about 2.7 saccharide units.
  • a hydrophobic group containing from about 6 to about 30 carbon atoms, preferably from about 10 to about 16 carbon atoms and a polysaccharide, e.g. a polyglycoside, hydrophilic group containing from about 1.3 to about 10, preferably from about 1.3 to about 3, most preferably from about 1.3 to about 2.7 saccharide units.
  • Any reducing saccharide containing 5 or 6 carbon atoms can be used, e.g., glucose, galactose and galactosyl moieties can be substituted for the glucosyl moieties (optionally the hydrophobic group is attached at the 2 - , 3-, 4-, etc. positions thus giving a glucose or galactose as opposed to a glucoside or galactoside) .
  • the intersaccharide bonds can be, e.g., between the one position of the additional saccharide units and the 2 - , 3-, 4-, and/or 6- positions on the preceding saccharide units.
  • the preferred alkylpolyglycosides have the formula
  • R 2 is selected from the group consisting of alkyl, alkylphenyl, hydroxyalkyl , hydroxyalkylphenyl , and mixtures thereof in which the alkyl groups contain from about 10 to about 18, preferably from about 12 to about 14, carbon atoms; n is 2 or , preferably 2; t is from 0 to about 10, preferably 0; and x is from about 1.3 to about 10, preferably from about 1.3 to about 3, most preferably from about 1.3 to about 2.7.
  • the glycosyl is preferably derived from glucose.
  • alkyl sulfate surfactants which are water soluble salts or acids of the formula ROSO3M wherein R preferably is a C 10 _ C24 hydrocarbyl, preferably an alkyl or hydroxyalkyl having a c 10" c 20 alkyl component, more preferably a C12-C13 alkyl or hydroxyalkyl, and M is H or a cation, e.g., an alkali metal cation (e.g. sodium, potassium, lithium), or ammonium or substituted ammonium (e.g.
  • R preferably is a C 10 _ C24 hydrocarbyl, preferably an alkyl or hydroxyalkyl having a c 10" c 20 alkyl component, more preferably a C12-C13 alkyl or hydroxyalkyl
  • M is H or a cation, e.g., an alkali metal cation (e.g. sodium, potassium, lithium), or ammonium or substituted am
  • alkylpolyglycolethersulfates (containing up to 10 moles of ethylene oxide) ; alkyl glycerol sulfonates, fatty acyl glycerol sulfonates, fatty oleyl glycerol sulfates, alkyl phenol ethylene oxide ether sulfates, paraffin sulfonates, alkyl phosphates, isethionates such as the acyl isethionates, N-acyl taurates, alkyl succinamates and sulfosuccinates, monoesters of sulfosuccinates (especially saturated and unsaturated CJ L 2 ⁇ C ⁇ Q monoesters) and diesters of sulfosuccinates (especially saturated and unsaturated c 6" c 12 diesters) , acyl sarcosinates, sulfates of alkylpolys
  • alkyl alkoxylated sulfate surfactants hereof are water soluble salts or acids of the formula RO(A) m S03M wherein R is an unsubstituted C 1 o _ 24 alkyl or hydroxyalkyl group having a 10" 24 alkyl component, preferably a C 12 -C2o alkyl or hydroxyalkyl, more preferably C 1 " 18 alkyl or hydroxyalkyl, A is an ethoxy or propoxy unit, m is greater than zero, typically between about 0.5 and about 6, more preferably between about 0.5 and about 3, and M is H or a cation which can be, for example, a metal cation (e.g., sodium, potassium, lithium, calcium, magnesium, etc.), ammonium or substituted-ammonium cation.
  • R is an unsubstituted C 1 o _ 24 alkyl or hydroxyalkyl group having a 10" 24 alkyl component, preferably a C 12
  • Cationic detersive surfactants suitable for use in the detergent compositions of the present invention are those having one long-chain hydrocarbyl group.
  • cationic surfactants include the ammonium surfactants such as alkyltrimethylammonium halogenides, and those surfactants having the formula :
  • Quaternary ammonium surfactant suitable for the present invention has the formula (I) :
  • Rl is a short chainlength alkyl (C6-C10) or alkylamidoalkyl of the formula (II) :
  • Preferred amines according to the formula herein above are n-alkyl amines.
  • Suitable amines for use herein may be selected from 1-hexylamine, l-octylamine, 1-decylamine and laurylamine.
  • Other preferred primary amines include C8-C10 oxypropylamine, octyloxypropylamine, 2-ethylhexyl- oxypropylamine, lauryl amido propylamine and amido propylamine .
  • Most preferred amines of the present invention include 1-octylamine, 1-hexylamine, 1-decylamine, 1- dodecylamine, C8 -lOoxypropylamine, N coco l-3diaminopropane, coconutalkyldimethylamine, lauryldimethylamine, lauryl bis (hydroxyethyl) amine, coco bis (hydroxyehtyl) amine, lauryl amine 2 moles propoxylated, octyl amine 2 moles propoxylated, lauryl amidopropyldimethylamine, C8-10 amidopropyldimethylamine and CIO amidopropyldimethylamine.
  • Said enzymes include enzymes selected from cellulases, hemicellulases , proteases, gluco-a ylases , amylases, xylanases, lipases, phospholipases, esterases, cutinases, pectinases, keratanases, reductases, oxidases, phenoloxidases , lipoxygenases , ligninases, pullulanases , tannases, pentosanases, malanases, ⁇ -glucanases , arabinosidases, hyaluronidase , chondroitinase , laccase or mixtures thereof .
  • Said cellulases are normally incorporated in the detergent composition at levels from 0.0001% to 2% of active enzyme by weight of the detergent composition.
  • cutinases [EC 3.1.1.50] which can be considered as a special kind of lipase, namely lipases which do not require interfacial activation. Addition of cutinases to detergent compositions have been described in e.g. WO-A-88/09367 (Genencor) .
  • Amylases can be included for removal of carbohydrate-based stains.
  • WO94/02597 Novo Nordisk A/S published February 03, 1994, describes detergent compositions which incorporate mutant amylases. See also W094/18314, Genencor, published August 18, 1994 and WO95/10603, Novo Nordisk A/S, published April 20, 1995.
  • Other amylases known for use in detergent compositions include both - and ⁇ -amylases.
  • ⁇ -Amylases are known in the art and include those disclosed in US Pat. no.
  • Enzyme stabilisation techniques are disclosed and exemplified in U.S. 3,600,319, August 17, 1971, Gedge et al, EP 199,405 and EP 200,586, October 29, 1986, Venegas . Enzyme stabilisation systems are also described, for example, in U.S. 3,519,570. A useful Bacillus, sp . AC13 giving proteases, xylanases and cellulases, is described in WO 9401532 A to Novo.
  • Polycarboxylates containing three carboxy groups include, in particular, water-soluble citrates, aconitrates and citraconates as well as succinate derivatives such as the carboxymethyloxysuccinates described in British Patent No. 1,379,241, lactoxysuccinates described in Netherlands Application 7205873, and the oxypolycarboxylate materials such as 2-oxa-l, 1, 3 -propane tricarboxylates described in British Patent No. 1,387,447.
  • a preferred silicone suds controlling agent is disclosed in Bartollota et al . U.S. Patent 3 933 672.
  • Other particularly useful suds suppressors are the self- emulsifying silicone suds suppressors, described in German Patent Application DTOS 2 646 126 published April 28, 1977.
  • An example of such a compound is DC-544, commercially available from Dow Corning, which is a siloxane-glycol copolymer.
  • Especially preferred suds controlling agent are the suds suppressor system comprising a mixture of silicone oils and 2-alkyl-alcanols .
  • Suitable 2-alkyl-alkanols are 2- butyl-octanol which are commercially available under the trade name Isofol 12 R.
  • detergent compositions may be employed, such as soil -suspending agents, soil-release agents, optical brighteners, abrasives, bactericides, tarnish inhibitors, coloring agents, and/or encapsulated or non-encapsulated perfumes.
  • PEG is - (OC 2 H 4 ) O-
  • PO is (OC 3 HgO)
  • T is (pcOC 6 H 4 CO) .
  • chlorine scavenger such as perborate, ammonium sulfate, sodium sulphite or polyethyleneimine at a level above 0.1% by weight of total composition, in the formulas will provide improved through the wash stability of the detergent enzyme.
  • Compositions comprising chlorine scavenger are described in the European patent application 92870018.6 filed January 31, 1992.
  • Polymers of this type are disclosed in GB-A-1, 596 , 756.
  • Examples of such salts are polyacrylates of MW 2000-5000 and their copolymers with maleic anhydride, such copolymers having a molecular weight of from 1,000 to 100,000.
  • copolymer of acrylate and methylacrylate such as the 480N having a molecular weight of 4000, at a level from 0.5-20% by weight of composition can be added in the detergent compositions of the present invention.
  • Surfactants having good lime soap peptiser capability will include certain amine oxides, betaines, sulfobetaines, alkyl ethoxysulfates and ethoxylated alcohols.
  • polymeric dye transfer inhibiting agents are polyamine N-oxide polymers, copolymers of N- vinylpyrrolidone and N-vinylimidazole, polyvinylpyrrolidone polymers, polyvinyloxazolidones and polyvinylimidazoles or mixtures thereof.
  • polyamine N-oxides are the polyamine oxides whereto the N-0 group is attached to the polymerisable unit .
  • polyamine oxides wherein R groups can be aromatic such as phenyl.
  • the amine N-oxide polymers of the present invention typically have a ratio of amine to the amine N-oxide of 10:1 to 1:1000000.
  • the amount of amine oxide groups present in the polyamine oxide polymer can be varied by appropriate copolymerization or by appropriate degree of N- oxidation.
  • the ratio of amine to amine N-oxide is from 2:3 to 1:1000000. More preferably from 1:4 to 1:1000000, most preferably from 1:7 to 1:1000000.
  • the polymers of the present invention actually encompass random or block copolymers where one monomer type is an amine N- oxide and the other monomer type is either an amine N-oxide or not.
  • Highly preferred polymers for use in detergent compositions according to the present invention comprise a polymer selected from N-vinylimidazole N-vinylpyrrolidone copolymers wherein said polymer has an average molecular weight range from 5,000 to 50,000 more preferably from 8,000 to 30,000, most preferably from 10,000 to 20,000.
  • the average molecular weight range was determined by light scattering as described in Barth H.G. and Mays J.W. Chemical Analysis Vol 113, "Modern Methods of Polymer Characterization" .
  • N-vinylimidazole N-vinylpyrrolidone copolymers have an average molecular weight range from 5,000 to 50,000; more preferably from 8,000 to 30,000; most preferably from 10,000 to 20,000.
  • compositions of the invention may be used in essentially any washing or cleaning methods, including soaking methods, pretreatment methods and methods with rinsing steps for which a separate rinse aid composition may be added.
  • a preferred machine dishwashing method comprises treating soiled articles with an aqueous liquid having dissolved or dispensed therein an effective amount of the machine diswashing or rinsing composition.
  • a conventional effective amount of the machine dishwashing composition means from 8-60 g of product dissolved or dispersed in a wash volume from 3-10 litres.
  • Hydroxide pH Measured as a 1% solution in distilled water at 20°C.
  • Brightener 1 0.05 - 0.04 0.04 0.04 Brightener 2 0.1 0.3 0.05 0.13 0.13 Water and Minors up to 100%
  • Granular fabric cleaning compositions which provide "softening through the wash” capability were prepared in accord with the present invention :

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Immunology (AREA)
  • Zoology (AREA)
  • Detergent Compositions (AREA)
  • Enzymes And Modification Thereof (AREA)

Abstract

La présente invention se rapporte à des compositions détergentes comportant une source de peroxyde d'hydrogène, éventuellement un activateur de blanchiment et un anticorps destiné à réguler la désactivation du blanchiment au peroxyde d'hydrogène, provoquée par la présence de l'enzyme donneur qu'est l'oxydoréductase de peroxyde d'hydrogène, et tout particulièrement la catalase.
PCT/US1996/013322 1996-08-16 1996-08-16 Compositions detergentes contenant un anticorps dirige contre une oxydoreductase Ceased WO1998007816A1 (fr)

Priority Applications (9)

Application Number Priority Date Filing Date Title
PCT/US1996/013322 WO1998007816A1 (fr) 1996-08-16 1996-08-16 Compositions detergentes contenant un anticorps dirige contre une oxydoreductase
AU68488/96A AU6848896A (en) 1996-08-16 1996-08-16 Detergent compositions comprising oxido-reductase antibody
PCT/US1997/011545 WO1998007824A1 (fr) 1996-08-16 1997-08-13 Compositions detergentes comprenant un anticorps d'oxydo-reductase
AU37938/97A AU3793897A (en) 1996-08-16 1997-08-13 Detergent compositions comprising oxido-reductase antibody
CN97198730.0A CN1233277A (zh) 1996-08-16 1997-08-13 含有氧化还原酶抗体的洗涤剂组合物
CA002263431A CA2263431A1 (fr) 1996-08-16 1997-08-13 Compositions detergentes comprenant un anticorps d'oxydo-reductase
BR9713173-3A BR9713173A (pt) 1996-08-16 1997-08-13 Composições detergentes compreendendo anticorpo óxido-reduitase
JP10510728A JP2000500819A (ja) 1996-08-16 1997-08-13 オキシドレダクターゼ抗体を含む洗剤組成物
EP97934875A EP0925348A1 (fr) 1996-08-16 1997-08-13 Compositions detergentes comprenant un anticorps d'oxydo-reductase

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
PCT/US1996/013322 WO1998007816A1 (fr) 1996-08-16 1996-08-16 Compositions detergentes contenant un anticorps dirige contre une oxydoreductase

Publications (1)

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WO1998007816A1 true WO1998007816A1 (fr) 1998-02-26

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Family Applications (2)

Application Number Title Priority Date Filing Date
PCT/US1996/013322 Ceased WO1998007816A1 (fr) 1996-08-16 1996-08-16 Compositions detergentes contenant un anticorps dirige contre une oxydoreductase
PCT/US1997/011545 Ceased WO1998007824A1 (fr) 1996-08-16 1997-08-13 Compositions detergentes comprenant un anticorps d'oxydo-reductase

Family Applications After (1)

Application Number Title Priority Date Filing Date
PCT/US1997/011545 Ceased WO1998007824A1 (fr) 1996-08-16 1997-08-13 Compositions detergentes comprenant un anticorps d'oxydo-reductase

Country Status (7)

Country Link
EP (1) EP0925348A1 (fr)
JP (1) JP2000500819A (fr)
CN (1) CN1233277A (fr)
AU (2) AU6848896A (fr)
BR (1) BR9713173A (fr)
CA (1) CA2263431A1 (fr)
WO (2) WO1998007816A1 (fr)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001007555A1 (fr) * 1999-07-27 2001-02-01 Unilever N.V. Fr0002098ons detergentes de blanchiment
WO2002061068A3 (fr) * 2001-01-31 2003-05-01 Novozymes As Oxydase exempte d'activite laterale de la catalase
US7319112B2 (en) 2000-07-14 2008-01-15 The Procter & Gamble Co. Non-halogenated antibacterial agents and processes for making same
US8114169B2 (en) 2006-08-25 2012-02-14 Advanced Enzyme Technologies Limited Compositions for biobleaching coupled with stone washing of indigo dyed denims and process thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0298654A2 (fr) * 1987-07-07 1989-01-11 Hybrisens Ltd. Utilisation des interactions entre anticorps et antigènes pour protéger ou moduler l'activité biologique
WO1991006574A1 (fr) * 1989-11-02 1991-05-16 Novo Nordisk A/S Procede de preparation d'acides peroxycarboxyliques
EP0540784A1 (fr) * 1991-11-06 1993-05-12 The Procter & Gamble Company Compositions empêchant le transfert de colorant
WO1994023637A1 (fr) * 1993-04-09 1994-10-27 The Procter & Gamble Company Procede de lavage en lave-vaisselle utilisant un catalyseur organometallique et une enzyme pour produire du peroxyde d'hydrogene
US5451337A (en) * 1994-05-31 1995-09-19 The Procter & Gamble Co. Dye transfer inhibition system containing a peroxidase/accelerator system

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0298654A2 (fr) * 1987-07-07 1989-01-11 Hybrisens Ltd. Utilisation des interactions entre anticorps et antigènes pour protéger ou moduler l'activité biologique
WO1991006574A1 (fr) * 1989-11-02 1991-05-16 Novo Nordisk A/S Procede de preparation d'acides peroxycarboxyliques
EP0540784A1 (fr) * 1991-11-06 1993-05-12 The Procter & Gamble Company Compositions empêchant le transfert de colorant
WO1994023637A1 (fr) * 1993-04-09 1994-10-27 The Procter & Gamble Company Procede de lavage en lave-vaisselle utilisant un catalyseur organometallique et une enzyme pour produire du peroxyde d'hydrogene
US5451337A (en) * 1994-05-31 1995-09-19 The Procter & Gamble Co. Dye transfer inhibition system containing a peroxidase/accelerator system

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2001007555A1 (fr) * 1999-07-27 2001-02-01 Unilever N.V. Fr0002098ons detergentes de blanchiment
US6596679B1 (en) 1999-07-27 2003-07-22 Unilever Home & Personal Care Usa Division Of Conopco, Inc. Bleaching detergent compositions
US7319112B2 (en) 2000-07-14 2008-01-15 The Procter & Gamble Co. Non-halogenated antibacterial agents and processes for making same
WO2002061068A3 (fr) * 2001-01-31 2003-05-01 Novozymes As Oxydase exempte d'activite laterale de la catalase
US8114169B2 (en) 2006-08-25 2012-02-14 Advanced Enzyme Technologies Limited Compositions for biobleaching coupled with stone washing of indigo dyed denims and process thereof

Also Published As

Publication number Publication date
EP0925348A1 (fr) 1999-06-30
JP2000500819A (ja) 2000-01-25
CN1233277A (zh) 1999-10-27
AU6848896A (en) 1998-03-06
BR9713173A (pt) 2000-02-08
AU3793897A (en) 1998-03-06
CA2263431A1 (fr) 1998-02-26
WO1998007824A1 (fr) 1998-02-26

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