WO1997036839A1 - Addition d'accelerateurs de prise a de la gunite - Google Patents
Addition d'accelerateurs de prise a de la gunite Download PDFInfo
- Publication number
- WO1997036839A1 WO1997036839A1 PCT/NO1997/000082 NO9700082W WO9736839A1 WO 1997036839 A1 WO1997036839 A1 WO 1997036839A1 NO 9700082 W NO9700082 W NO 9700082W WO 9736839 A1 WO9736839 A1 WO 9736839A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- gunite
- mouthpiece
- accelerator
- aluminium
- constituents
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Ceased
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B40/00—Processes, in general, for influencing or modifying the properties of mortars, concrete or artificial stone compositions, e.g. their setting or hardening ability
- C04B40/0028—Aspects relating to the mixing step of the mortar preparation
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/02—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2103/00—Function or property of ingredients for mortars, concrete or artificial stone
- C04B2103/10—Accelerators; Activators
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/00034—Physico-chemical characteristics of the mixtures
- C04B2111/00146—Sprayable or pumpable mixtures
- C04B2111/00155—Sprayable, i.e. concrete-like, materials able to be shaped by spraying instead of by casting, e.g. gunite
Definitions
- the present invention relates to an accelerator or an accelerator constituent for addition to gunite. Moreover, the invention relates to a method of adding an accelerator and/or consistency adjusting or solidification adjusting means to gunite, and equipment for adding an accelerator and/or consistency adjusting or solidification adjusting means to gunite during spraying, comprising a spray- mouthpiece and a conduit coupled to the mouthpiece for admission of gunite.
- An accelerator is an additive which promotes curing of the concrete after spraying on a substrate. Liquid accelerator is added to the gunite immediately prior to spraying, by being admitted to a spray-mouthpiece for the gunite. Due to the use of an accelerator relatively thick layers can be sprayed, and the progress of the spraying may be faster than by spraying without any accelerator.
- non-alkalic accelerators are used, for instance on basis of aluminium hydroxide, but these accelerators are not liquid. Although such powder accelerators can be used to prepare a liquid slurry and dosed i a liquid state, - there are large problems related to durability during storage and the application.
- an accelerator or constituents in an accelerator can be used litium silicate and/or litium aluminate, and /or aluminium in acid or basic solution, with anions or cations which are not aggressive to concrete, and/or aluminium oxalate.
- the accelerator may comprise aluminium formiate and aluminium nitrate, in the form of pure salts or mixtures.
- accelerators By use of such accelerators alone, or mixed with sodium- or potassium silicate/sodium- or potassium aluminate, no or only a limited alkalic reaction in the concrete takes place.
- These accelerators may, thus, be used alone or together with sodium silicate and/or sodium aluminate and/ or potassium silicate and/or potassium aluminate, whereby the addition of silicates or aluminates which cause alkalic reactions is eliminated or reduced.
- the accelerator When the accelerator consists of or comprises oxalic acid or oxalate there will, when the accelerator is added to gunite, be formed potassium oxalate due to the potassium contents in the concrete.
- the potassium oxalate constitutes a nearly inert filler substituent, which is heavily soluble.
- the accelerator contains or consists of aluminium oxalate, aluminium iones are brought into the concrete.
- the aluminium oxalate may form a part of an aqueous solution, which may also contain other aluminium salts which in small amounts do not have any detrimental effect, for instance sulfate or nitrate.
- two or more accelerators are added selectively by being admitted to a spray mouthpiece for gunite in separate conduits, for adjusting of the rate of mixture between two or more -accelerators.
- substituents may be added to the gunite prior to the reaching of the spray mouthpiece, in order that the constituents have more time to react prior to the spraying of the gunite.
- viscosity- or consistency adjusters may be added, such as polyethylene oxides and small amounts of naphtalene sulphanates, for instance thixotropying means which by being added immediately prior to the spraying alter the consistency of the gunite from liquid and well pumpable and sprayable to viscous and thixotropic.
- the equipment according to the invention is adapted for addition of selective amounts of two or more accelerators, consistency adjusters or solidification adjusters during spraying of gunite.
- the equipment can permit addition to a spray mouthpiece and/or addition to the gunite prior to its arrival at the mouthpiece.
- litium silicate or- aluminate, aluminium in solution or aluminium oxalate, respectively can be added alone when it is desired to avoid any alcaline silicium reaction on the aggegates.
- litium silicate or- aluminate, or aluminium in solution, or aluminium oxalate may be added together with accelerators based on sodium or potassium, and the mixture rate can be determined automatically or by the spray operator.
- the equipment according to the invention comprises a gunite spray mouthpiece, to which is coupled a conduit for admission of gunite, and to which are coupled two or more conduits for accelerator, possibly consistency adjusters or solidification adjusters, with means for selective adjustment of the flow in each conduit, for instance valves which can be controlled automatically or operated manually by an operator.
- the spray mouthpiece may be extended rearwardly and be provided with one or more couplings spaced from the mouth of the mouthpiece, or one or more conduits may be provided with a coupling, which also is situated spaced from the mouth of the mouthpiece.
- Fig. 1 shows spray equipment for selective addition of two accelerators.
- Fig. 2 shows spray equipment for selective addition of three accelerators.
- Each of the three examples of spray equipment according to the invention comprises a spray mouthpiece 1 , a mixing chamber 2, a supply conduit 3 for liquid concrete and a pressurized air conduit 4.
- Fig. 1 shows two supply conduits 5, 7 for accelerator, with a control valve 6, 8 for each of the conduits 5, 7.
- accelerators can be added selectively through the conduits 5 and 7.
- One of the conduits 5, 7 can be shut off, for addition of only one accelerator, through the other conduit.
- Fig. 2 also shows a supply conduit 9 coupled to the conduit 7, and the conduit 9 also has a control valve 10. This gives increased possibilities for selective addition.
- One of the conduits 5, 7, 9 can be used for addition of a consistency adjusting means or a thixotropying means.
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- On-Site Construction Work That Accompanies The Preparation And Application Of Concrete (AREA)
- Medicinal Preparation (AREA)
Abstract
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AU24135/97A AU2413597A (en) | 1996-03-29 | 1997-03-25 | Addition of accelerators in gunite |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NO961277 | 1996-03-29 | ||
| NO961277A NO961277D0 (no) | 1996-03-29 | 1996-03-29 | Akselerator for spröytebetong, og fremgangsmåte og utstyr for tilsetning til spröytebetong |
| NO962925A NO962925L (no) | 1996-03-29 | 1996-07-12 | Akselerator for spröytebetong, og fremgangsmåte og utstyr for tilsetning til spröytebetong |
| NO962925 | 1996-07-12 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1997036839A1 true WO1997036839A1 (fr) | 1997-10-09 |
Family
ID=26648653
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/NO1997/000082 Ceased WO1997036839A1 (fr) | 1996-03-29 | 1997-03-25 | Addition d'accelerateurs de prise a de la gunite |
Country Status (3)
| Country | Link |
|---|---|
| AU (1) | AU2413597A (fr) |
| NO (1) | NO962925L (fr) |
| WO (1) | WO1997036839A1 (fr) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1095922A1 (fr) | 1999-10-29 | 2001-05-02 | Sika AG, vorm. Kaspar Winkler & Co. | Accélérateurs de prise et de durcissement stabilisés à faible viscosité |
| US6251892B1 (en) | 1997-02-28 | 2001-06-26 | Gpi Nil Holdings, Inc. | N-oxides of heterocyclic esters, amides, thioesters, and ketones |
| WO2013006662A1 (fr) * | 2011-07-06 | 2013-01-10 | Fmc Corporation | Adjuvants pour béton à base de lithium pour lutter contre des réactions alcali-silice à commande amélioré de temps de prise |
| WO2014048871A1 (fr) * | 2012-09-25 | 2014-04-03 | Yara International Asa | Composition antigel permettant la production d'un béton durable à basse température |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4046357A (en) * | 1976-12-03 | 1977-09-06 | Construction Systems & Equipment, Inc. | Shotcrete accelerator injection apparatus and method |
| EP0289721A2 (fr) * | 1987-04-30 | 1988-11-09 | Degussa Aktiengesellschaft | Procédé et dispositif de dosage continu des matières pulvérulentes au moyen d'un gaz sous pression |
| US5246163A (en) * | 1990-06-20 | 1993-09-21 | Toagosei Chemical Industry Co., Ltd. | Method of applying quick setting spray materials |
| DE19534929A1 (de) * | 1994-09-20 | 1996-03-21 | Sandoz Ag | Rasche abbindende Zementzubereitungen |
-
1996
- 1996-07-12 NO NO962925A patent/NO962925L/no unknown
-
1997
- 1997-03-25 AU AU24135/97A patent/AU2413597A/en not_active Abandoned
- 1997-03-25 WO PCT/NO1997/000082 patent/WO1997036839A1/fr not_active Ceased
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4046357A (en) * | 1976-12-03 | 1977-09-06 | Construction Systems & Equipment, Inc. | Shotcrete accelerator injection apparatus and method |
| EP0289721A2 (fr) * | 1987-04-30 | 1988-11-09 | Degussa Aktiengesellschaft | Procédé et dispositif de dosage continu des matières pulvérulentes au moyen d'un gaz sous pression |
| US5246163A (en) * | 1990-06-20 | 1993-09-21 | Toagosei Chemical Industry Co., Ltd. | Method of applying quick setting spray materials |
| DE19534929A1 (de) * | 1994-09-20 | 1996-03-21 | Sandoz Ag | Rasche abbindende Zementzubereitungen |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6251892B1 (en) | 1997-02-28 | 2001-06-26 | Gpi Nil Holdings, Inc. | N-oxides of heterocyclic esters, amides, thioesters, and ketones |
| US6486151B2 (en) | 1997-02-28 | 2002-11-26 | Gpi Nil Holdings Inc. | N-oxides of heterocyclic esters, amides, thioesters, and ketones |
| EP1095922A1 (fr) | 1999-10-29 | 2001-05-02 | Sika AG, vorm. Kaspar Winkler & Co. | Accélérateurs de prise et de durcissement stabilisés à faible viscosité |
| WO2013006662A1 (fr) * | 2011-07-06 | 2013-01-10 | Fmc Corporation | Adjuvants pour béton à base de lithium pour lutter contre des réactions alcali-silice à commande amélioré de temps de prise |
| WO2014048871A1 (fr) * | 2012-09-25 | 2014-04-03 | Yara International Asa | Composition antigel permettant la production d'un béton durable à basse température |
| US9376342B2 (en) | 2012-09-25 | 2016-06-28 | Yara International Asa | Antifreeze composition for producing a durable concrete in cold temperature conditions |
Also Published As
| Publication number | Publication date |
|---|---|
| NO962925D0 (no) | 1996-07-12 |
| AU2413597A (en) | 1997-10-22 |
| NO962925L (no) | 1997-09-30 |
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