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WO1997030953A1 - Method of manufacturing building material by using volcanic ash - Google Patents

Method of manufacturing building material by using volcanic ash Download PDF

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Publication number
WO1997030953A1
WO1997030953A1 PCT/JP1996/003321 JP9603321W WO9730953A1 WO 1997030953 A1 WO1997030953 A1 WO 1997030953A1 JP 9603321 W JP9603321 W JP 9603321W WO 9730953 A1 WO9730953 A1 WO 9730953A1
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Prior art keywords
volcanic ash
clay
building materials
glaze
base soil
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PCT/JP1996/003321
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French (fr)
Japanese (ja)
Inventor
Kikuzi Eguchi
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EGUCHI KOICHIRO
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EGUCHI KOICHIRO
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Publication of WO1997030953A1 publication Critical patent/WO1997030953A1/en
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Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/009After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone characterised by the material treated
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/021Ash cements, e.g. fly ash cements ; Cements based on incineration residues, e.g. alkali-activated slags from waste incineration ; Kiln dust cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/45Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements
    • C04B41/50Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials
    • C04B41/5022Coating or impregnating, e.g. injection in masonry, partial coating of green or fired ceramics, organic coating compositions for adhering together two concrete elements with inorganic materials with vitreous materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/60After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only artificial stone
    • C04B41/61Coating or impregnation
    • C04B41/65Coating or impregnation with inorganic materials
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B41/00After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone
    • C04B41/80After-treatment of mortars, concrete, artificial stone or ceramics; Treatment of natural stone of only ceramics
    • C04B41/81Coating or impregnation
    • C04B41/85Coating or impregnation with inorganic materials
    • C04B41/86Glazes; Cold glazes

Definitions

  • the present invention relates to a method for manufacturing building materials using volcanic ash.
  • the content key component of the ash, alumina and Kei acid, small amounts of iron in the other, lime, magnesia, contains potash equipotent s.
  • the present invention has been made in order to effectively utilize such volcanic ash, and an object of the present invention is to provide a method of manufacturing building materials using volcanic ash which is inexpensive and easily available. Disclosure of the invention
  • a mixture of pio power and water is heated to 100 ° C for tl to form a paste, which is then mixed with gypsum, lime, volcanic ash, and clay.
  • unbaking was performed at 660 degrees, and this was further baked at 1,250 degrees.
  • a mixture of tapio force and persimmon astringent is heated to 100 ° C to form a paste, which is then kneaded with volcanic ash and clay to form a ground. After forming, it was unbaked at 660 ° C, coated with glaze, and further fired at 125 ° C.
  • the first to seventh methods for producing a building material using volcanic ash are characterized in that the non-ferrous metal powder is used as the material of the base soil. Adopted.
  • alumina and clay are kneaded to form a base earth, which is molded into a predetermined shape, then baked at 660 ° C, and glaze is applied thereto.
  • a configuration was adopted in which coating was performed and firing was performed at 125 ° C.
  • persimmon juice collected from persimmons such as astringent persimmon is used as a coagulant
  • tapi talent collected from underground stems of cassava is used as an adhesive
  • building materials such as tiles and blocks can be manufactured using volcanic ash, so that manufacturing costs can be reduced.
  • the volcanic ash Since it can be used in large quantities, volcanic ash deposited in various places can be used effectively.
  • inner and outer walls (flowers, etc.) imitating marble, figurines, tea sets, vases, and pottery.
  • the above 1 and 2 are kneaded to form a base soil. Next, it was molded into a tile of a predetermined size, baked at 660 ° C, coated with glaze, and baked at 1250 ° C to produce a tile.
  • the above 1 and 2 are kneaded to form a base soil. Next, this was formed into a tile of a predetermined size, baked at 660 °, coated with glaze, and baked at 125 ° to produce a tile.
  • inner and outer walls (flowers, etc.) imitating marble, inner and outer walls with white spots, doll-shaped objects, tea sets, vases, and pottery.
  • the above 1 and 2 are kneaded to form a base soil. Next, this was formed into a tile of a predetermined size, baked at 660 °, coated with glaze, and baked at 125 ° to produce a tile.
  • inside and outside walls (flowers, etc.) imitating marble, clouds and flower-shaped inner and outer walls, doll-shaped objects, tea sets, vases, and pottery can be manufactured.
  • the above-mentioned 1 is kneaded to form a base soil, an underlay of the same type and the same shape as that of the above-mentioned 1 base soil is formed by the above-mentioned clay, and the above-mentioned base soil is overlaid on the above-mentioned underlay. After unglaring at 60 degrees, a glaze was applied, and final firing was performed at 125 degrees to produce tiles.
  • inside and outside walls imitating marble can also be manufactured.
  • the above-mentioned 1 is kneaded to form a base soil, an underlay of the same type and the same shape as that of the above-mentioned 1 base soil is formed by the above-mentioned clay, and the above-mentioned base soil is overlaid on the above-mentioned underlay. After unglaring at 60 degrees, glaze was applied, and the main firing force was applied at 125 degrees to produce black artificial ore.
  • the above-mentioned 1 is kneaded to form a base soil, an underlay of the same type and the same shape as that of the above-mentioned 1 base soil is formed by the above-mentioned clay, and the above-mentioned base soil is overlaid on the above-mentioned underlay. After unglaring at 60 degrees, glaze was applied and main firing at 125 degrees to produce plate tiles with green spots.
  • inner and outer walls (flowers, etc.) imitating marble, sculptures, tea sets, vases, and pottery.
  • Examples 1 to 7 in addition to the materials of volcanic ash and clay, materials such as non-ferrous metal powders can be used.
  • the inner and outer walls (flowers) imitating tiles and marbles can be used in the same manner as in the previous examples. Patterns, etc.), doll-shaped objects, tea sets, vases, and pottery can be manufactured.
  • tile is manufactured in the present embodiment, it is also possible to manufacture inner and outer walls (flower pattern, etc.) imitating marble, figurines, tea sets, vases, and pottery.
  • base earth 150 g 150 g.
  • this is formed into a flat plate with a thickness of 2 to 3 mm by press working, unglazed at 660 degrees, and then coated with glaze. Next, this was fired at 125 ° C to produce an artificial ore with orange spots.
  • the artificial ore was manufactured. Can make dolls, sculptures, tea sets, vases, and pottery.
  • Table 1 shows the ash cement compressive strength test of this base soil at the Fukuoka Laboratory of the China Testing Laboratory, Building Materials Testing Center (Receiver No. 1-685). This base soil is good for building concrete mix and slate material. The specimen age was 30 days and the test method was based on JISA II 08. Table 1 Straightness Maximum load Compressive strength Specimen number kgf / cm 'kg cm cm tf ⁇ NI mm 2 ⁇
  • the base earth was formed on a flat plate, and high-pressure breathing or compression was performed to produce interior decoration type and slates.
  • decorative tiles and slate for interior are manufactured, but blocks, pots, aquariums, concrete for construction, etc. can be manufactured in addition to these.
  • materials such as sand can be used in addition to the materials of volcanic ash and clay.
  • materials such as sand can be used in addition to the materials of volcanic ash and clay.
  • tiles and inner and outer walls (flower pattern, etc.) imitating a marble.
  • the main constituents of volcanic ash are alumina and caicic acid, and a small amount of iron, lime, magnesite, potash and similar to pumice.
  • building materials such as tiles and blocks can be manufactured using volcanic ash, so that the manufacturing cost can be reduced, and a large amount of volcanic ash can be produced. Since it can be used, volcanic ash deposited in various places can be used effectively.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Finishing Walls (AREA)
  • Compositions Of Oxide Ceramics (AREA)

Abstract

A method of manufacturing a building material uses volcanic ash which is inexpensive and easily available. Volcanic ash and clay are kneaded to form body soil. The ground soil is subjected to biscuit firing at 660 degrees, and is applied with glaze to be further subjected to glost firing at 1250 degrees.

Description

明細書 火山灰を利用した建築資材の製造方法 技術分野  Description Method for manufacturing building materials using volcanic ash

本発明は火山灰を利用した建築資材の製造方法に関する。 背景技術  The present invention relates to a method for manufacturing building materials using volcanic ash. Background art

最近、 家屋の改革が急速に進み、 特に外装の建具及び内部の衛生設備 及び間仕切りの変革にあたり、 目新しい大小のタイルが必要とされてい る。  Recently, the reform of houses has progressed rapidly, and new large and small tiles are needed, especially for exterior fittings and internal sanitary facilities and partitioning reforms.

そして現在、 無益、 無用にされている安価な火山灰にタピオ力、 柿 渋、 その他の副材料を加入利用してアルミナと共に建築材料が製作さ れ、 高級の大理石を模したタイルや、 新たな壁、 及びビルの内外の装飾 の需要が高まっている。  At present, building materials are produced with inexpensive and useless inexpensive volcanic ash together with alumina using tapio power, Kakishibu and other auxiliary materials, and tiles imitating high-grade marble and new walls There is a growing demand for interior and exterior decorations for buildings.

尚、 火山灰の含有主要成分は、 アルミナ及びケィ酸で、 他に少量の 鉄、 石灰、 苦土、 カリ等力 s含まれている。 The content key component of the ash, alumina and Kei acid, small amounts of iron in the other, lime, magnesia, contains potash equipotent s.

本発明はかかる火山灰を有効利用するためになされたものであって、 その目的とするところは、 安価で入手力簡便な火山灰を利用した建築資 材の製造方法を提供することにある。 発明の開示  The present invention has been made in order to effectively utilize such volcanic ash, and an object of the present invention is to provide a method of manufacturing building materials using volcanic ash which is inexpensive and easily available. Disclosure of the invention

従来、 火山の噴火により住民はその被害に苦しみ、 それによつて生ず る火山灰は無益、 迷惑のものとして放置していた。  Traditionally, volcanic eruptions have caused residents to suffer the damage, and the resulting volcanic ash has been left unprofitable and annoying.

しかし、 僅かに陶器製作の釉薬として使用されている。 そして、 その 火山灰に粘土を加入して日用使用の茶器、 陶器を造り、 又は副材料を加 入して建築材料を製作して貢献するものである。 すなわち、 前記目的を解決するための手段として、 第 1の火山灰を利 用した建築資材の製造方法では、 火山灰と粘土を混練して素地土を形成 し、 これを 6 6 0度で素焼きをし、 これに釉薬を塗布して更に 1 2 5 0度で本焼きする構成を採用した。 However, it is slightly used as a glaze for pottery production. Then, clay is added to the volcanic ash to make tea utensils and pottery for daily use, or to add auxiliary materials to produce building materials to contribute. That is, as a means for solving the above-mentioned object, in the first method for producing building materials using volcanic ash, volcanic ash and clay are kneaded to form a base earth, which is then sintered at 660 ° C. However, a configuration was adopted in which glaze was applied to this and the final firing was performed at 125 ° C.

また、 第 2の火山灰を利用した建築資材の製造方法では、 火山灰と夕 ピオ力及び水を混合したものを 1 0 0度に加熱して糊状とし、 これに石 灰と粘土を混練して素地土を形成したのち 6 6 0度で素焼きをし、 これ に釉薬を塗布して更に 1 2 5 0度で本焼きする構成を採用した。  In the second method for manufacturing building materials using volcanic ash, a mixture of volcanic ash, evening power and water is heated to 100 ° C to form a paste, which is then kneaded with lime and clay. After forming the base soil, unglazing was performed at 660 ° C, glaze was applied to this, and firing was performed at 125 ° C.

また、 第 3の火山灰を利用した建築資材の製造方法では、 夕ピオ力と 水を混合したものを 1 0 0度に力 tl熱して糊状とし、 これに石膏、 石灰、 火山灰、 粘土を混練して素地土を形成したのち 6 6 0度で素焼きをし、 これを更に 1 2 5 0度で本焼きする構成を採用した。  In the third method of manufacturing building materials using volcanic ash, a mixture of pio power and water is heated to 100 ° C for tl to form a paste, which is then mixed with gypsum, lime, volcanic ash, and clay. After forming the base soil, unbaking was performed at 660 degrees, and this was further baked at 1,250 degrees.

また、 第 4の火山灰を利用した建築資材の製造方法では、 タピオ力と 柿渋を混合したものを 1 0 0度に加熱して糊状とし、 これに火山灰、 粘 土を混練して素地土を形成したのち 6 6 0度で素焼きをし、 これに釉薬 を塗布して更に 1 2 5 0度で本焼きする構成とした。  In the fourth method for manufacturing building materials using volcanic ash, a mixture of tapio force and persimmon astringent is heated to 100 ° C to form a paste, which is then kneaded with volcanic ash and clay to form a ground. After forming, it was unbaked at 660 ° C, coated with glaze, and further fired at 125 ° C.

また、 第 5の火山灰を利用した建築資材の製造方法では、 火山灰と柿 渋と粘土を混練して素地土を形成し、 これと同量、 同型の下敷きを粘土 によつて形成し、 前記素地土を下敷きの粘土の上に重ね合わせて火山灰 の癒着を防ぎ、 これを 6 6 0度で素焼きをした後、 更に 1 2 5 0度で本 焼きする構成を採用した。  In the fifth method of manufacturing building materials using volcanic ash, volcanic ash, kakishibu and clay are kneaded to form a base soil, and the same amount and the same type of underlay is formed of clay. The soil was layered on the underlying clay to prevent the adhesion of volcanic ash, which was unglazed at 660 ° C, and then fired at 125 ° C.

また、 第 6の火山灰を利用した建築資材の製造方法では、 夕ピオ力、 柿渋、 火山灰を混練したものに粘土を加入して再び混練して素地土を形 成し、 これと同量、 同型の下敷きを粘土によって形成し、 前記素地土を 下敷きの粘土の上に重ね合わせて火山灰の癒着を防ぎ、 これを 6 6 0度 で素焼きした後、 更に 1 2 5 0度で本焼きする構成を採用した。  In the sixth method of manufacturing building materials using volcanic ash, kneading Pio power, persimmon shibu, and volcanic ash was added to clay, and then kneaded again to form a base soil. The underlay is made of clay, the base soil is overlaid on the underlay clay to prevent the adhesion of volcanic ash, which is unbaked at 660 ° C, and then fired at 1250 ° C. Adopted.

また、 第 7の火山灰を利用した建築資材の製造方法では、 火山灰と柿 渋、 石膏、 石灰、 粘土を混練して素地土を形成し、 これと同量、 同型の 下敷きを粘土によつて形成し、 前記素地土を下敷きの粘土の上に重ね合 わせて火山灰の癒着を防ぎ、 これを 6 6 0度で素焼きした後、 更に 1 2 5 0度で本焼きする構成を採用した。 In the seventh method of manufacturing building materials using volcanic ash, volcanic ash and persimmon Astringent, gypsum, lime, and clay are kneaded to form a base soil, and the same amount and the same type of underlay is formed of clay, and the base soil is overlaid on the underlying clay to coalesce volcanic ash This was followed by unglazing at 660 degrees and then firing at 125 degrees.

また、 第 8の火山灰を利用した建築資材の製造方法では、 前記第 1〜 7の火山灰を利用した建築資材の製造方法において、 前記素地土の材料 として非鉄金属の粉末が使用されている構成を採用した。  Further, in the eighth method for producing a building material using volcanic ash, the first to seventh methods for producing a building material using volcanic ash are characterized in that the non-ferrous metal powder is used as the material of the base soil. Adopted.

また、 第 9の火山灰を利用した建築資材の製造方法では、 アルミナと 粘土を混練して素地土を形成し、 これを所定形状に成形したのち 6 6 0度で素焼きをし、 これに釉薬を塗布して更に 1 2 5 0度で本焼き する構成を採用した。  In the ninth method for manufacturing building materials using volcanic ash, alumina and clay are kneaded to form a base earth, which is molded into a predetermined shape, then baked at 660 ° C, and glaze is applied thereto. A configuration was adopted in which coating was performed and firing was performed at 125 ° C.

また、 第 1 0の火山灰を利用した建築資材の製造方法では、 アルミ ナ、 乳白釉、 スーパーパックス、 水、 粘土を混練して素地土を形成し、 これを 6 6 0度で素焼きしたのち、 釉薬を塗布して更に 1 2 5 0度で本 焼きする構成を採用した。  In addition, in the 10th method of manufacturing building materials using volcanic ash, alumina, milky glaze, superpax, water, and clay are kneaded to form a base earth, which is unglazed at 660 ° C. A configuration was adopted in which glaze was applied and firing was performed at 125 ° C.

また、 第 1 1の火山灰を利用した建築資材の製造方法では、 アルミ ナ、 荒砂、 火山灰、 粘土、 水を混練して素地土を形成し、 これを 6 6 0度で素焼きしたのち、 釉薬を塗布して更に 1 2 5 0度で本焼きす る構成を採用した。  Also, in the first method of manufacturing building materials using volcanic ash, alumina, rough sand, volcanic ash, clay, and water are kneaded to form a base soil, which is unglazed at 660 degrees Celsius, and then glaze is applied. A configuration was adopted in which coating was performed and firing was performed at 125 ° C.

また、 第 1 2の火山灰を利用した建築資材の製造方法では、 火山灰、 セメント、 石灰、 水を混練したものに、 加熱した塩化カルシウム及び水 を加入して混練する構成を採用した。  In addition, in the method for manufacturing building materials using volcanic ash, a configuration was adopted in which heated calcium chloride and water were added to kneaded volcanic ash, cement, lime, and water, and kneaded.

本発明では渋柿等の柿から採取した柿渋を凝結剤、 キヤッサバの地下 茎から採取したタピ才力を接着剤として使用している。  In the present invention, persimmon juice collected from persimmons such as astringent persimmon is used as a coagulant, and tapi talent collected from underground stems of cassava is used as an adhesive.

前記構成を採用したため、 本発明の火山灰を利用した建築資材の製造 方法では、 火山灰を利用してタイル、 ブロック等の建築資材を製造する ことができるので、 製造コストを下げることができるし、 又、 火山灰を 大量に使用することができるので各地に堆積している火山灰を有効に利 用することができる。 発明を実施するための最良の形態 By adopting the above configuration, in the method for manufacturing building materials using volcanic ash of the present invention, building materials such as tiles and blocks can be manufactured using volcanic ash, so that manufacturing costs can be reduced. The volcanic ash Since it can be used in large quantities, volcanic ash deposited in various places can be used effectively. BEST MODE FOR CARRYING OUT THE INVENTION

以下、 本発明の実施例を詳細に説明する。  Hereinafter, embodiments of the present invention will be described in detail.

(実施例 1 )  (Example 1)

1. 火山灰 24 g  1. 24 g of volcanic ash

粘土 108 g  108 g clay

これらを混練して素地土 130 gを形成する。 次に、 これをプレス 加工により厚さ 2 mn!〜 3 mmの平板状とし、 660度で素焼きした 後、 白色、 透明その他の釉薬を塗布する。 次に、 これを 1250度で本 焼きして白色のタイルを製作した。  These are kneaded to form a base earth of 130 g. Next, this is pressed to a thickness of 2 mn! Apply a white, transparent, or other glaze after baking at 660 degrees, making it a flat plate of ~ 3 mm. Next, this was fired at 1250 degrees to produce white tiles.

尚、 これ以外に大理石を模した内外の壁 (花柄等) 、 人形造形物、 茶 器、 花瓶、 陶器類を製作することができる。  In addition, we can manufacture inner and outer walls (flowers, etc.) imitating marble, figurines, tea sets, vases, and pottery.

(実施例 2)  (Example 2)

1. 火山灰 20 g  1. Volcanic ash 20 g

夕ピオ力 5 g  Evening pio power 5 g

水 30 c c  Water 30 c c

これらを混合し 100度に加熱して糊状とする。  These are mixed and heated to 100 degrees to form a paste.

2. 石灰 20 g  2. Lime 20 g

粘土 100 g  100 g clay

前記 1と前記 2を混練して素地土を形成する。 次に、 これを所定大 のタイルの大きさに成形し、 660度にて素焼きした後、 釉薬を塗布し 1 250度にて本焼き加工してタイルを製作した。  The above 1 and 2 are kneaded to form a base soil. Next, it was molded into a tile of a predetermined size, baked at 660 ° C, coated with glaze, and baked at 1250 ° C to produce a tile.

尚、 これ以外に大理石を模して内外の壁 (花柄等) 、 人形造形物、 茶 器、 花瓶、 陶器類を製作することができる。  In addition, it is possible to manufacture inner and outer walls (flowers, etc.), figurines, tea sets, vases, and pottery by imitating marble.

(実施例 3 ) 1 . 夕ピオ力 5 g (Example 3) 1. Evening pio power 5 g

水 3 0 c c  Water 3 0 c c

これらを混合し 1 0 0度に加熱して糊状とする。  These are mixed and heated to 100 ° C. to form a paste.

2 . 石膏 2 0 g  2.Plaster 20 g

石灰 1 0 g  Lime 10 g

火山灰 2 5 g Volcanic ash 25 g

粘土 1 0 0 g 100 g of clay

前記 1と前記 2を混練して素地土を形成する。 次に、 これを所定大 のタイルの大きさに成形し、 6 6 0度にて素焼きした後、 釉薬を塗布し 1 2 5 0度にて本焼き加工してタイルを製作した。  The above 1 and 2 are kneaded to form a base soil. Next, this was formed into a tile of a predetermined size, baked at 660 °, coated with glaze, and baked at 125 ° to produce a tile.

尚、 これ以外に大理石を摸した内外の壁 (花柄等) 、 白色に斑点のあ る内外の壁、 人形造形物、 茶器、 花瓶、 陶器類を製作することができ る。  In addition, it is possible to manufacture inner and outer walls (flowers, etc.) imitating marble, inner and outer walls with white spots, doll-shaped objects, tea sets, vases, and pottery.

(実施例 4 )  (Example 4)

1 . 夕ピオ力 5 g  1. Evening pio power 5 g

柿渋 3 0 c c  Kakishibu 3 0 c c

これらを混合し 1 0 0度に力 α熱して糊状とする。  These are mixed and heated to a temperature of 100 ° to form a paste.

2 . 火山灰 2 5 g  2. Volcanic ash 2 5 g

粘土 1 0 0 g  100 g of clay

前記 1と前記 2を混練して素地土を形成する。 次に、 これを所定大 のタイルの大きさに成形し、 6 6 0度にて素焼きした後、 釉薬を塗布し 1 2 5 0度にて本焼き加工してタイルを製作した。  The above 1 and 2 are kneaded to form a base soil. Next, this was formed into a tile of a predetermined size, baked at 660 °, coated with glaze, and baked at 125 ° to produce a tile.

尚、 これ以外に大理石を模した内外の壁 (花柄等) 、 雲形、 花形模様 の内外の壁、 人形造形物、 茶器、 花瓶、 陶器類を製作することができ る。  In addition, inside and outside walls (flowers, etc.) imitating marble, clouds and flower-shaped inner and outer walls, doll-shaped objects, tea sets, vases, and pottery can be manufactured.

(実施例 5 )  (Example 5)

1 . 火山灰 2 3 g 柿渋 2 0 c c 1. Volcanic ash 2 3 g Persimmon Shibu 20 cc

粘土 5 0 g  50 g of clay

これらを混練する。  These are kneaded.

2 . 粘土 9 0 g  2. Clay 90 g

前記 1を混練して素地土を形成し、 前記 1の素地土と同量、 同型の 下敷きを前記 2の粘土によつて形成し、 前記素地土を前記下敷きの上に 重ね合わせ、 これを 6 6 0度にて素焼きした後、 釉薬を塗布し 1 2 5 0度にて本焼き加工してタイルを製作した。  The above-mentioned 1 is kneaded to form a base soil, an underlay of the same type and the same shape as that of the above-mentioned 1 base soil is formed by the above-mentioned clay, and the above-mentioned base soil is overlaid on the above-mentioned underlay. After unglaring at 60 degrees, a glaze was applied, and final firing was performed at 125 degrees to produce tiles.

本実施例では下敷きを設けているので、 火山灰が他に癒着するのを防 ぐことができる。  In this embodiment, since the underlay is provided, it is possible to prevent the volcanic ash from adhering to other parts.

尚、 大理石を模した内外の壁も製作することができる。  In addition, inside and outside walls imitating marble can also be manufactured.

(実施例 6 )  (Example 6)

1 . タピオ力 4 g  1. Tapio power 4 g

柿渋 3 0 c c  Kakishibu 3 0 c c

火山灰 8 0 g  Volcanic ash 80 g

以上を混練する。  The above is kneaded.

2 . 粘土 1 2 0 g  2. Clay 1 20 g

前記 1を混練して素地土を形成し、 前記 1の素地土と同量、 同型の 下敷きを前記 2の粘土によつて形成し、 前記素地土を前記下敷きの上に 重ね合わせ、 これを 6 6 0度にて素焼きした後、 釉薬を塗布し 1 2 5 0度にて本焼き力 Qェして黒色の人工鉱石を製作した。  The above-mentioned 1 is kneaded to form a base soil, an underlay of the same type and the same shape as that of the above-mentioned 1 base soil is formed by the above-mentioned clay, and the above-mentioned base soil is overlaid on the above-mentioned underlay. After unglaring at 60 degrees, glaze was applied, and the main firing force was applied at 125 degrees to produce black artificial ore.

本実施例では下敷きを設けているので、 火山灰が他に癒着するのを防 ぐことができる。  In this embodiment, since the underlay is provided, it is possible to prevent the volcanic ash from adhering to other parts.

尚、 本実施例では人工鉱石を製作したが、 これ以外に黒色の装飾品 類、 人形造形物、 茶器、 花瓶、 陶器類を製作することができる。  Although artificial ores were manufactured in this embodiment, black ornaments, figurines, tea sets, vases, and pottery can also be manufactured.

(実施例 7 )  (Example 7)

1 . 火山灰 2 5 g 柿渋 3 0 c c 1. Volcanic ash 2 5 g Kakishibu 30 cc

石膏 2 0 g  Plaster 20 g

石灰 l o s  Lime l os

粘土 8 0 g  80 g of clay

以上を混練する。  The above is kneaded.

2 . 粘土 1 6 5 g  2. Clay 1 6 5 g

前記 1を混練して素地土を形成し、 前記 1の素地土と同量、 同型の 下敷きを前記 2の粘土によつて形成し、 前記素地土を前記下敷きの上に 重ね合わせ、 これを 6 6 0度にて素焼きした後、 釉薬を塗布し 1 2 5 0度にて本焼き加工して緑色の斑点のある板状タイルを製作し た。  The above-mentioned 1 is kneaded to form a base soil, an underlay of the same type and the same shape as that of the above-mentioned 1 base soil is formed by the above-mentioned clay, and the above-mentioned base soil is overlaid on the above-mentioned underlay. After unglaring at 60 degrees, glaze was applied and main firing at 125 degrees to produce plate tiles with green spots.

本実施例では下敷きを設けているので、 火山灰が他に癒着するのを防 ぐことができる。  In this embodiment, since the underlay is provided, it is possible to prevent the volcanic ash from adhering to other parts.

尚、 これ以外に大理石を摸した内外の壁 (花柄等) 、 人形造形物、 茶 器、 花瓶、 陶器類を製作することができる。  In addition, we can manufacture inner and outer walls (flowers, etc.) imitating marble, sculptures, tea sets, vases, and pottery.

(実施例 8 )  (Example 8)

実施例 1〜7において、 火山灰、 粘土の材料に加えて非鉄金属の粉末 等の材料を使用することもでき、 この場合も前記実施例と同様にタイ ル、 大理石を模した内外の壁 (花柄等) 、 人形造形物、 茶器、 花瓶、 陶 器類を製作することができる。  In Examples 1 to 7, in addition to the materials of volcanic ash and clay, materials such as non-ferrous metal powders can be used. In this case as well, the inner and outer walls (flowers) imitating tiles and marbles can be used in the same manner as in the previous examples. Patterns, etc.), doll-shaped objects, tea sets, vases, and pottery can be manufactured.

(実施例 9 )  (Example 9)

1 . アルミナ 2 4 g  1.Alumina 2 4 g

粘土 (白) 1 0 8 g  Clay (white) 1 0 8 g

これらを混練して素地土 1 3 0 gを形成する。 次に、 これをプレス 加工により厚さ 2 mn!〜 3 mmの平板状とし、 6 6 0度で素焼きした 後、 釉薬を塗布する。  These are kneaded to form a base earth 130 g. Next, this is pressed to a thickness of 2 mn! Apply a glaze after sintering at a temperature of 660 ° C.

次に、 これを 1 2 5 0度で本焼きしてタイルを製作した。 尚、 本実施例ではタイルを製作したが、 これ以外に大理石を模した内 外の壁 (花柄等) 、 人形造形物、 茶器、 花瓶、 陶器類を製作することが できる。 Next, this was baked at a temperature of 125 ° C to produce a tile. Although tiles are manufactured in the present embodiment, it is also possible to manufacture inner and outer walls (flower pattern, etc.) imitating marble, figurines, tea sets, vases, and pottery.

(実施例 1 0 )  (Example 10)

1 . アルミナ 3 0 g  1. Alumina 30 g

乳白釉 2 0 g  Milk white glaze 20 g

スーパ一パックス 1 0 g  Super Pack 10 g

粘土 8 0 g  80 g of clay

水 8 c c  Water 8 c c

これらを混練して素地土を形成する。 次に、 これをブレス加工によ り厚さ 1 mm〜3 mmの平板状とし、 6 6 0度で素焼きした後、 白色の 釉薬を塗布する。 次に、 これを 1 2 5 0度で本焼きして人工白曜石を製 作した。  These are kneaded to form a base soil. Next, this is made into a flat plate with a thickness of 1 to 3 mm by blessing, unglazed at 660 degrees, and then coated with white glaze. Next, this was baked at 125 ° C to produce an artificial obsidian.

尚、 本実施例では人工白曜石を製作したが、 これ以外にタイル、 大理 石を模した内外の壁 (花柄等) 、 人形造形物、 茶器、 花瓶、 陶器類を製 作することができる。  In this example, artificial obsidian was manufactured, but tiles, inner and outer walls (flower pattern etc.) imitating marble, figurines, tea sets, vases, and pottery could also be manufactured. it can.

(実施例 1 1 )  (Example 11)

1 . アルミナ 4 0 g  1. Alumina 40 g

荒砂 3 0 g  Rough sand 30 g

火山灰 2 0 g  Volcanic ash 20 g

粘土 (白) 4 0 g  Clay (white) 40 g

水 2 0 c c  Water 20 c c

これらを混練して素地土 1 5 0 gを形成する。 次に、 これをプレス 加工により厚さ 2 m m〜 3 m mの平板状とし、 6 6 0度で素焼きした 後、 釉薬を塗布する。 次に、 これを 1 2 5 0度で本焼きしてオレンジ色 の斑点模様の人工鉱石を製作した。  These are kneaded to form a base earth 150 g. Next, this is formed into a flat plate with a thickness of 2 to 3 mm by press working, unglazed at 660 degrees, and then coated with glaze. Next, this was fired at 125 ° C to produce an artificial ore with orange spots.

尚、 本実施例では人工鉱石を製作したが、 これ以外にタイル、 装飾 類、 人形造形物、 茶器、 花瓶、 陶器類を製作することができる。 In this example, the artificial ore was manufactured. Can make dolls, sculptures, tea sets, vases, and pottery.

(実施例 1 2 )  (Example 12)

1. 火山灰 1 20 g 1. Volcanic ash 1 20 g

セメント 1 50 g  1 50 g of cement

石灰 30 g Lime 30 g

これらを混合攪拌する。  These are mixed and stirred.

2. 水 70 g  2. 70 g of water

これを前記 1に力 [3えて混練する。  This is mixed with the above [1] with force.

3. 塩化カルシウム 55 g  3. 55 g of calcium chloride

水 65 c c  Water 65 c c

前記 3を 100度で溶かして、 前記し 前記 2に加えこれをミキサ -で 25秒間攪拌混練して素地土を形成する。  Melt 3 at 100 °, add to 2 and stir and knead it with a mixer for 25 seconds to form a green soil.

この素地土を使用して財団法人建材試験センター中国試験所福岡試 験室 (受付番号ェ試第一 685号) でアッシュセメン卜圧縮強度試験 をしたところ表 1の通りであった。 この素地土は建築コンクリ―ト配合 及びスレート資料として良好である。 尚、 試験体の材令は 30日で、 試 験方法は J I S A l l 08によった。 表 1 直 ί圣 さ 最大荷重 圧縮強度 試験体番号 kgf/cm' kg cm cm tf {N I mm2}Table 1 shows the ash cement compressive strength test of this base soil at the Fukuoka Laboratory of the China Testing Laboratory, Building Materials Testing Center (Receiver No. 1-685). This base soil is good for building concrete mix and slate material. The specimen age was 30 days and the test method was based on JISA II 08. Table 1 Straightness Maximum load Compressive strength Specimen number kgf / cm 'kg cm cm tf {NI mm 2 }

0. 319 4.98 9.96 4.85 2490.319 4.98 9.96 4.85 249

0. 305 5.00 9.93 3.60 1830.305 5.00 9.93 3.60 183

3 0.315 4.99 9.96 4.48 229 3 0.315 4.99 9.96 4.48 229

220 平  220 flat

{ 21.6 } 次に、 前記素地土を平面板に形成し、 高圧ブレス又は圧縮して内装用 ィ匕粧タイプ及びスレ—卜を製作した。 {21.6} Next, the base earth was formed on a flat plate, and high-pressure breathing or compression was performed to produce interior decoration type and slates.

尚、 本実施例では内装用化粧タイル及びスレートを製作したが、 これ 以外にブロック、 鉢、 水槽、 建築用コンクリ—卜等を製作することがで きる。  In this embodiment, decorative tiles and slate for interior are manufactured, but blocks, pots, aquariums, concrete for construction, etc. can be manufactured in addition to these.

尚、 本実施例においては、 火山灰、 粘土の材料に加えて砂等の材料も 使用することができ、 この場合も前記実施例と同様にタイル、 大理石を 模した内外の壁 (花柄等) 、 人形造形物、 茶器、 花瓶、 陶器類を作成す ることができる。  In this embodiment, materials such as sand can be used in addition to the materials of volcanic ash and clay. In this case, similarly to the above-described embodiment, tiles and inner and outer walls (flower pattern, etc.) imitating a marble. Can make dolls, tea sets, vases, and pottery.

尚、 火山灰の含有主要物は、 アルミナ及びケィ酸で、 他に少量の鉄、 石灰、 苦土、 カリで軽石同様のものである。 産業上の利用可能性  The main constituents of volcanic ash are alumina and caicic acid, and a small amount of iron, lime, magnesite, potash and similar to pumice. Industrial applicability

本発明の火山灰を利用した建築資材の製造方法では、 火山灰を利用し てタイル、 ブロック等の建築資材を製造することができるので、 製造コ ストを下げることができるし、 又、 火山灰を大量に使用することができ るので各地に堆積している火山灰を有効に利用することができる。  In the method for manufacturing building materials using volcanic ash of the present invention, building materials such as tiles and blocks can be manufactured using volcanic ash, so that the manufacturing cost can be reduced, and a large amount of volcanic ash can be produced. Since it can be used, volcanic ash deposited in various places can be used effectively.

Claims

請求の範囲 The scope of the claims 1 . 火山灰と粘土を混練して素地土を形成し、 これを 6 6 0度で素焼き をし、 これに釉薬を塗布して更に 1 2 5 0度で本焼きすることを特徴と する火山灰を利用した建築建材の製造方法。 1. Volcanic ash is formed by kneading volcanic ash and clay to form a clay, which is then baked at 660 ° C, coated with glaze, and then baked at 1250 ° C. Manufacturing method of building materials used. 2 . 火山灰とタピオ力及び水を混合したものを 1 0 0度にカロ熱して糊状 とし、 これに石灰と粘土を混練して素地土を形成したのち 6 6 0度で素 焼きをし、 これに釉薬を塗布して更に 1 2 5 0度で本焼きすることを特 徴とする火山灰を利用した建築資材の製造方法。  2. A mixture of volcanic ash, tapio force and water is calo-heated to 100 ° C to form a paste, which is then kneaded with lime and clay to form a base soil, which is then sintered at 660 ° C. This is a method for manufacturing building materials using volcanic ash, which is characterized by applying glaze to this and firing it further at 1250 ° C. 3 . 夕ピオ力と水を混合したものを 1 0 0度に加熱して糊状とし、 これ に石膏、 石灰、 火山灰、 粘土を混練して素地土を形成したのち 6 6 0度 で素焼きをし、 これを更に 1 2 5 0度で本焼きすることを特徴とする火 山灰を利用した建築資材の製造方法。  3. Mix the mixture of Pio power and water to 100 ° C to form a paste, knead it with gypsum, lime, volcanic ash, and clay to form a base soil, then bake it at 660 ° C. A method for producing building materials using fire ash, which is further baked at a temperature of 125 ° C. 4 . タピオ力と柿渋を混合したものを 1 0 0度に加熱して糊状とし、 こ れに火山灰、 粘土を混練して素地土を形成したのち 6 6 0度で素焼きを し、 これに釉薬を塗布して更に 1 2 5 0度で本焼きすることを特徴とす る火山灰を利用した建築資材の製造方法。  4. Heat the mixture of tapio and persimmon astringent to 100 ° C to form a paste, knead it with volcanic ash and clay to form a base earth, and then bake it at 660 ° C. A method of manufacturing building materials using volcanic ash, characterized by applying glaze and firing at a temperature of 125 ° C. 5 . 火山灰と柿渋と粘土を混練して素地土を形成し、 これと同量、 同型 の下敷きを粘土によつて形成し、 前記素地土を下敷きの粘土の上に重ね 合わせて火山灰の癒着を防ぎ、 これを 6 6 0度で素焼きをした後、 更に 5. Kneading the volcanic ash, persimmon astringent and clay to form a base soil, forming an underlay of the same amount and the same type with clay, and overlaying the base soil on the underlying clay to adhere the volcanic ash Prevent this, and after unglazing at 660 degrees, 1 2 5 0度で本焼きすることを特徴とする火山灰を利用した建築資材の 製造方法。 A method for producing building materials using volcanic ash, which is characterized by firing at 125 ° C. 6 . 夕ピオ力、 柿渋、 火山灰を混練したものに粘土を加入して再び混練 して素地土を形成し、 これと同量、 同型の下敷きを粘土によって形成 し、 前記素地土を下敷きの粘土の上に重ね合わせて火山灰の癒着を防 ぎ、 これを 6 6 0度で素焼きした後、 更に 1 2 5 0度で本焼きすること を特徴とする火山灰を利用した建築資材の製造方法。 6. Add clay to the mixture of evening pio power, persimmon astringent, and volcanic ash, knead it again to form a base soil, and form the same amount of the same type of underlay with clay. A method of manufacturing building materials using volcanic ash, characterized by preventing the adhesion of volcanic ash by overlaying it on top of it, baking it at 660 ° C, and then firing it at 1250 ° C. 7 . 火山灰と柿渋、 石膏、 石灰、 粘土を混練して素地土を形成し、 これ と同量、 同型の下敷きを粘土によって形成し、 前記素地土を下敷きの粘 土の上に重ね合わせて火山灰の癒着を防ぎ、 これを 6 6 0度で素焼きし た後、 更に 1 2 5 0度で本焼きすることを特徴とする火山灰を利用した 建築資材の製造方法。 7. Kneading volcanic ash with persimmon astringent, gypsum, lime, and clay to form a base soil, forming the same amount and the same type of underlay with clay, and overlaying the base soil on the underlying clay A method for manufacturing building materials using volcanic ash, characterized by preventing union and sintering at 660 ° C, followed by firing at 1250 ° C. 8 - 前記素地土の材料として非鉄金属の粉末力 s使用されていることを特 徴とする前記 1〜 7記載の火山灰を利用した建築資材の製造方法。 8-The method for producing a building material using volcanic ash according to any one of 1 to 7 above, wherein a powdery force of a non-ferrous metal is used as a material of the base soil. 9 . アルミナと粘土を混練して素地土を形成し、 これを所定形状に成形 したのち 6 6 0度で素焼きをし、 これに釉薬を塗布して更に 1 2 5 0度 で本焼きすることを特徴とする火山灰を利用した建築資材の製造方法。9. Alumina and clay are kneaded to form a base earth, formed into a predetermined shape, then fired at 660 ° C, coated with glaze, and fired at 1250 ° C. A method for producing building materials using volcanic ash, characterized by the following. 1 0 . アルミナ、 乳白釉、 スーパーパックス、 水、 粘土を^して素地 土を形成し、 これを 6 6 0度で素焼きしたのち、 釉薬を塗布して更に10. Alumina, milky glaze, Super Pax, water, and clay are used to form a clay, which is then baked at 660 ° C and then coated with glaze. 1 2 5 0度で本焼きすることを特徴とする火山灰を利用した建築資材の 製造方法。 A method for producing building materials using volcanic ash, which is characterized by firing at 125 ° C. 1 1 - アルミナ、 荒砂、 火山灰、 粘土、 水を混練して素地土を形成し、 これを 6 6 0度で素焼きしたのち、 釉薬を塗布して更に 1 2 5 0度で本 焼きすることを特徴とする火山灰を利用した建築資材の製造方法。 1 2 . 火山灰、 セメント、 石灰、 水を混練したものに、 加熱した塩化力 ルシゥム及び水を加入して混練することを特徴とする火山灰を利用した 建築資材の製造方法。  1 1-Alumina, rough sand, volcanic ash, clay, and water are kneaded to form a base earth, which is then fired at 660 ° C, then coated with glaze and fired at 1250 ° C. A method for manufacturing building materials using the characteristic volcanic ash. 1 2. A method for manufacturing building materials using volcanic ash, characterized by mixing and kneading heated chlorination water and water into a mixture of volcanic ash, cement, lime and water.
PCT/JP1996/003321 1996-02-20 1996-11-11 Method of manufacturing building material by using volcanic ash Ceased WO1997030953A1 (en)

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JP8058422A JPH09227213A (en) 1996-02-20 1996-02-20 Production of building material utilizing volcanic ash
JP8/58422 1996-02-20

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PCT/JP1996/003321 Ceased WO1997030953A1 (en) 1996-02-20 1996-11-11 Method of manufacturing building material by using volcanic ash

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WO (1) WO1997030953A1 (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100688874B1 (en) 2005-05-09 2007-03-02 김영수 Ceramic glaze using volcanic rock, manufacture and use method
CN111018503A (en) * 2019-12-20 2020-04-17 佛山欧神诺陶瓷有限公司 Ceramic sheet with high-strength green body and preparation method thereof

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20020041840A (en) * 2000-11-29 2002-06-05 마사노리 죠우야 power-generating device employing volcanic ashes
JP4537867B2 (en) * 2005-03-03 2010-09-08 秀之 桑山 Clay with excellent water resistance
CN102329152A (en) * 2011-06-21 2012-01-25 霍镰泉 Complete polishing glaze archaizing brick overglaze and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04240172A (en) * 1991-01-25 1992-08-27 Toto Ltd Production of ornamental pottery ware
JPH0514131U (en) * 1991-08-05 1993-02-23 三菱マテリアル株式会社 Glazed porous ceramic building material
JPH0725683A (en) * 1993-07-06 1995-01-27 Shiratsukusuu:Kk Pottery having microvoid and production thereof
JPH0725684A (en) * 1993-07-06 1995-01-27 Kagoshima Pref Gov Fine ceramic sintered compact having microvoid and production thereof
JPH0812405A (en) * 1994-06-21 1996-01-16 Shozo Takakura Fire and heat resistant building materials using volcanic ash

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04240172A (en) * 1991-01-25 1992-08-27 Toto Ltd Production of ornamental pottery ware
JPH0514131U (en) * 1991-08-05 1993-02-23 三菱マテリアル株式会社 Glazed porous ceramic building material
JPH0725683A (en) * 1993-07-06 1995-01-27 Shiratsukusuu:Kk Pottery having microvoid and production thereof
JPH0725684A (en) * 1993-07-06 1995-01-27 Kagoshima Pref Gov Fine ceramic sintered compact having microvoid and production thereof
JPH0812405A (en) * 1994-06-21 1996-01-16 Shozo Takakura Fire and heat resistant building materials using volcanic ash

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100688874B1 (en) 2005-05-09 2007-03-02 김영수 Ceramic glaze using volcanic rock, manufacture and use method
CN111018503A (en) * 2019-12-20 2020-04-17 佛山欧神诺陶瓷有限公司 Ceramic sheet with high-strength green body and preparation method thereof

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