WO1997009029A1 - Hair treatment composition - Google Patents
Hair treatment composition Download PDFInfo
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- WO1997009029A1 WO1997009029A1 PCT/JP1996/002559 JP9602559W WO9709029A1 WO 1997009029 A1 WO1997009029 A1 WO 1997009029A1 JP 9602559 W JP9602559 W JP 9602559W WO 9709029 A1 WO9709029 A1 WO 9709029A1
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/49—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds
- A61K8/4906—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom
- A61K8/4913—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing heterocyclic compounds with one nitrogen as the only hetero atom having five membered rings, e.g. pyrrolidone carboxylic acid
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/36—Carboxylic acids; Salts or anhydrides thereof
- A61K8/365—Hydroxycarboxylic acids; Ketocarboxylic acids
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
Definitions
- the present invention relates to an aqueous hair treatment composition, and more particularly, to imparting gloss and volume to hair, improving combability, and particularly, when applied to hair that has become dry due to damage, has improved gloss and flexibility. And a hair conditioning composition.
- Some hair conditioning compositions left the ingredients in the hair, and some were rinsed after application.
- compositions had insufficient conditioning effects, especially when used on hair that had become dry due to damage.
- an object of the present invention is to provide a hair treatment composition which imparts gloss and volume to hair, improves combability, and imparts flexibility.
- an aqueous hair treatment composition containing a fixed amount of lactic acid, citric acid, and pyrrolidone carboxylic acid has a sufficient hair conditioning effect. That is, the present invention has been completed.
- the present invention provides the following components (a), (b) and (c)
- the present invention provides a water or water-based hair treatment composition containing the following.
- the hair treatment composition of the present invention is used for the final treatment of hair after shampooing, perming, hair dyeing and the like.
- the above-mentioned weight% refers to the weight% in the whole composition.
- the lactic acid as the component (a) is contained in an amount of not less than 0.01% by weight in the whole composition. It is preferable to include them.
- citric acid of the component (b) should be contained in an amount of not less than 0.01% by weight in the total composition. Is preferred.
- the component (c), pyrrolidone carboxylic acid is 5-oxo-pyrrolidine-12-carboxylic acid known as pyroglutamic acid, which is contained in an amount of not less than 0.01% by weight in the total composition. However, it is particularly preferable to add 0.05 to 2% by weight, more preferably 0.1 to 1% by weight.
- the hair treatment composition of the present invention may further contain an organic acid in order to further increase the hair conditioning effect.
- organic acids include one or more selected from glycolic acid, malic acid, glyoxylic acid, tartaric acid, mandelic acid, and pyruvic acid. It is preferable that the organic acid is contained in the entire composition in an amount of at least 0.01% by weight, particularly at least 0.05% by weight.
- the upper limit of the content of the organic acid is not particularly limited, but in the composition of the present invention, it is determined mainly by the desired pH of the composition. Preferred pH values are between 2 and 7, especially between 4 and 5.5. In general, the upper limit of the content of the organic acid is preferably about 5% by weight, particularly about 2.5% by weight in the total composition. On the other hand, the lower limit of the content of the organic acid is preferably about 0.05% by weight, particularly preferably about 0.25% by weight in the whole composition. These organic acids may be obtained from plants, juices or extracts thereof.
- Another preferable optional component is glycerin, which is added in an amount of 0.5% by weight or more, particularly preferably 1 to 10% by weight, in the composition of the present invention.
- hair treatment is used here for shampoo, permanent treatment or after hair dyeing This definition is described in K. Schrader, "Grundlagen und printeduren der Kosmetika", 2nd Ed. (1989), Huthing Buchverlag Heidelberg, pp. 722-724.
- composition of the present invention may be water-based or water-alcohol-based, may be emulsified or dispersed, or may be an aerosol, particularly an aerosol sol form.
- the amount of the cationic surfactant to be added is preferably 0.1 to 7.5% by weight, particularly preferably 0.25 to 5% by weight in the whole composition.
- Preferred examples of the cationic surfactant include one or a mixture of two or more long-chain quaternary ammonium salts, and in particular, cetyltrimethylammonium chloride, dimethyldicetylammonium chloride, Trimethylcetylammonium amide, stearyltrimethylammonium chloride, dimethylstearylbenzylbenzylammonium chloride, benzyltetradecyldimethylammonium chloride, dimethyldihydrogenated tallow ammonium chloride, laurylpyri Preferred are divinyl chloride, lauryldimethylbenzylammonium chloride, laurinoretrimethylammonium chloride, tris (oligoxitytyl) alkyl ammonium phosphate, cetylpyridinium chloride and the like.
- composition of the present invention can be blended with known components used in ordinary hair conditioning compositions. These include those described in K. Schrader, "Grundlagen und printeduren der Kosmetika", 2nd Ed. (1989), Huthing Buchverlag Heidelberg. PP. 722-771.
- nonionic surfactant can be used in the composition of the present invention, it is preferable to use a nonionic surfactant together with a cationic surfactant.
- the nonionic surfactant, aminoxide be used in an amount of 0.25 to 5% by weight, preferably 0.5 to 3.5% by weight in the total composition.
- Aminoxides include those already known.
- C 12 -C 18 alkyl dimethyl aminoxides such as lauryl dimethyl aminoxide, C 12 -C 18 alkyl aminaminopropyl or ethyl aminoxide, C ] 2 -C 18 alkyl di (hydroxicetyl) or (hydroxydipropyl)
- Examples include aminoxide, ethylenoxide in the alkyl chain, or aminoquinide having Z and propylene oxide.
- These aminoxides can be obtained commercially. This includes, for example, those with the registered trademarks "Ammonyx", "Aromox” or "Genaminox".
- C 8 -C 18 alkyl glucosides having a degree of condensation of 1.2 to 2.5 are also preferable nonionic surfactants.
- the composition of the present invention may further contain an amphoteric or zwitterionic surfactant, but is preferably used together with a cationic surfactant.
- the content of the amphoteric or zwitterionic surfactant is preferably from 0.1 to 5% by weight, preferably from 0.5 to 3% by weight in the whole composition.
- Examples of the amphoteric or zwitterionic surfactant include known betaines such as fatty acid amide alkyl betaines and sulfobetaine, and specific examples include lauryl hydroxysulfobetaine.
- composition of the present invention includes complexing agents, dyes, preservatives, ⁇ regulators, thickeners such as inorganic salts, fragrances, pearling agents, sizing agents, wetting agents, plant and animal oils such as jojoba oil, etc. Can be added.
- Particularly preferred additives are hair conditioning agents, especially cationic polymers, which are added in an amount of 0.05 to 2.5% by weight, especially 0.2 to 1.5% by weight in the total composition. % Is preferable.
- EP 337,354 discloses the use of alkylpolyglycoside surfactants in conjunction with cationic polymers, but the cationic polymers described on pages 3 to 7 also apply to the invention. And can be suitably used as a conditioning agent. Also, the ones listed under the name “Polyquaternium” in the “CTFA Cosmetic Ingredient Dictionary, 4th. Ed. Can be.
- composition J of the present invention may further contain a protein hydrolyzate as a conditioning agent, in an amount of 0.25 to 5% by weight, preferably 0.5 to 2.5% by weight of the total composition. Preferably it is 5% by weight.
- a protein hydrolyzate as a conditioning agent
- Conductors can also be used.
- various polysiloxanes may be used as a conditioning agent, and the added amount is 0.25 to 5% by weight, particularly 0.5 to 2% by weight of the whole composition. 5% by weight is preferred.
- the polysiloxane may be volatile or non-volatile, cyclic or linear. Examples of polysiloxanes include those known under the names “dimethicone”, “phenyldimethicone” and “cyclomethicone”.
- silicone derivatives described in EP 398,177 with alkylpolyglycosides can also be used in the present invention.
- composition of the present invention various components may be mixed in water or water-alcohol by a conventional method, and it may be used as a premix.
- Hair treatment compositions were prepared with the compositions shown in Examples 1 to 5 below.
- Isopropyl alcohol 150 Isopropyl myristate 1 2 0 Panthenol 0 5 0 Flavor 0 4 0 Lactic acid 0 5 5 Cunic acid 0 0 5 Pyrrolidone carboxylic acid 0 0 2 Tartaric acid 0 0 2 Lingic acid 0 0 1 Preservative
- the hair after shampooing was treated with the compositions of Examples 1 to 3 and subjected to a half-side test.As a result, the product of the present invention had better combability than the composition not containing the mixture of hydroxycarboxylic acids. Improves both wet and dry, making your hair soft and shiny I was able to.
- Example 4 In addition to the conditioning effect of the compositions of Examples 1-3, the composition of Example 4 further restored the shine of the hair.
- the hair treatment composition of the present invention imparts gloss to hair, and further imparts combability and flexibility.
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Abstract
Description
明 細 書 毛髪処理剤組成物 Description Hair treatment composition
技術分野 Technical field
本発明は、 水系の毛髪処理剤組成物に関し、 詳細には毛髪に光沢とボリューム- 与え、 櫛通り性を改善し、 特にダメージにより乾燥性になった髪に用いたとき、 光沢と柔軟性を与えるヘアコンディ ショニング剤組成物に関する。 The present invention relates to an aqueous hair treatment composition, and more particularly, to imparting gloss and volume to hair, improving combability, and particularly, when applied to hair that has become dry due to damage, has improved gloss and flexibility. And a hair conditioning composition.
背景技術 Background art
毛髪のコンディ ショ ンを整える、 すなわち、 髪に光沢とボリュームを与え、 櫛 通り性を改善したり柔軟性を与えるため、 近年、 種々のへアーコンディショニン グ剤組成物が用いられている。 In recent years, various hair conditioning compositions have been used in order to condition hair, that is, to give gloss and volume to hair, to improve combability and to give flexibility.
ヘアーコンディ ショニング剤組成物には、 毛髪にその成分を残存させるもの、 及び塗布の後、 すすぐタイプのものがあった。 Some hair conditioning compositions left the ingredients in the hair, and some were rinsed after application.
しかしながら、 いずれの組成物も、 そのコンディ ショニング効果が不十分であ り、 特にダメージにより乾燥性になった髪に用いた場合には、 そのコンディ ショ 二ング効果は不十分であつた。 However, all the compositions had insufficient conditioning effects, especially when used on hair that had become dry due to damage.
従って、 本発明の目的は、 髪に光沢とボリュームを与え、 櫛通り性を改善し、 柔軟性を付与する毛髪処理剤組成物を提供することにある。 Accordingly, an object of the present invention is to provide a hair treatment composition which imparts gloss and volume to hair, improves combability, and imparts flexibility.
発明の開示 Disclosure of the invention
斯かる実情に鑑み本発明者は、 鋭意研究を行った結果、 乳酸、 クェン酸、 ピロ リ ドンカルボン酸を一定量配合した水系の毛髪処理剤組成物が、 十分なへアーコ ンディショニング効果を有することを見出し、 本発明を完成した。 In view of such circumstances, the present inventor has conducted intensive studies, and as a result, an aqueous hair treatment composition containing a fixed amount of lactic acid, citric acid, and pyrrolidone carboxylic acid has a sufficient hair conditioning effect. That is, the present invention has been completed.
即ち本発明は、 次の （a ) 、 （b ) 及び （ c ) 成分 That is, the present invention provides the following components (a), (b) and (c)
( a ) 乳酸 0 . 0 1重量％以上 (a) Lactic acid 0.0 1% by weight or more
( b ) クェン酸 0 . 0 1重量％以上 (b) Cuic acid 0.0 1% by weight or more
( c ) ピロリ ドンカルボン酸 0 . 0 1重量％以上 を含有する水又は水-ァ儿コール系の毛髪処理剤組成物を提供するものである。 (c) Pyrrolidone carboxylic acid 0.0 1% by weight or more The present invention provides a water or water-based hair treatment composition containing the following.
発明を実施するための最良の形態 BEST MODE FOR CARRYING OUT THE INVENTION
本発明の毛髪処理剤組成物は、 洗髪、 パーマ、 染毛等の後、 毛髪の最終処理に 用いられるものである。 また上記の重量％は全組成物中の重量％をいう。 The hair treatment composition of the present invention is used for the final treatment of hair after shampooing, perming, hair dyeing and the like. The above-mentioned weight% refers to the weight% in the whole composition.
本発明の組成物において、 （a ) 成分の乳酸は、 全組成物中 0. 0 1重量％以 上含有せしめるが、 特に、 0. 0 5〜2重量％、 更に 0. 1〜 1重量％含有せし めることが好ましい。 In the composition of the present invention, the lactic acid as the component (a) is contained in an amount of not less than 0.01% by weight in the whole composition. It is preferable to include them.
また、 （b) 成分のクェン酸は、 全組成物中 0. 0 1重量％以上含有せしめる 力 \ 特に、 0. 0 5〜 1重量％、 更に 0. 1〜0. 5重量％含有せしめることが 好ましい。 In addition, the citric acid of the component (b) should be contained in an amount of not less than 0.01% by weight in the total composition. Is preferred.
( c ) 成分の、 ピロリ ドンカルボン酸は、 ピログルタミ ン酸の名で知られてい る 5 —ォキソ—ピロリジン一 2—カルボン酸であり、 これは全組成物中 0. 0 1 重量％以上含有せしめるが、 特に、 0. 0 5〜2重量％、 更に 0. 1〜 1重量％ 含有せしめることが好ましい。 The component (c), pyrrolidone carboxylic acid, is 5-oxo-pyrrolidine-12-carboxylic acid known as pyroglutamic acid, which is contained in an amount of not less than 0.01% by weight in the total composition. However, it is particularly preferable to add 0.05 to 2% by weight, more preferably 0.1 to 1% by weight.
本発明の毛髪処理剤組成物には、 更にへアーコンディショニング効果を増加さ せるために、 更に、 有機酸を加えてもよい。 このような有機酸としては、 グリコ —ル酸、 リンゴ酸、 グリオキシル酸、 酒石酸、 マンデル酸及びピルビン酸から選 ばれる一種又は二種以上が挙げられる。 有機酸は全組成物中 0. 0 1重量％以上、 特に、 0. 0 5重量％以上含有せしめることが好ましい。 有機酸の含有量の上限 は特に限定はないが、 本発明組成物においては、 主として組成物の望ましい pHに より決定される。 好ましい pH値は、 2〜7、 特に 4〜5. 5である。 一般的には、 有機酸の含有量の上限は全組成物中、 約 5重量％、 特に、 約 2. 5重量％とする ことが好ましい。 一方、 有機酸の含有量の下限は全組成物中、 約 0. 0 5重量％、 特に、 約 0. 2 5重量％とすることが好ましい。 これら有機酸は、 植物、 果汁又 はそれらの抽出物から得てもよい。 The hair treatment composition of the present invention may further contain an organic acid in order to further increase the hair conditioning effect. Examples of such organic acids include one or more selected from glycolic acid, malic acid, glyoxylic acid, tartaric acid, mandelic acid, and pyruvic acid. It is preferable that the organic acid is contained in the entire composition in an amount of at least 0.01% by weight, particularly at least 0.05% by weight. The upper limit of the content of the organic acid is not particularly limited, but in the composition of the present invention, it is determined mainly by the desired pH of the composition. Preferred pH values are between 2 and 7, especially between 4 and 5.5. In general, the upper limit of the content of the organic acid is preferably about 5% by weight, particularly about 2.5% by weight in the total composition. On the other hand, the lower limit of the content of the organic acid is preferably about 0.05% by weight, particularly preferably about 0.25% by weight in the whole composition. These organic acids may be obtained from plants, juices or extracts thereof.
他の好ましい任意成分として、 グリセリンが挙げられ、 これは、 本発明組成物 中 0. 5重量％以上、 特に、 1〜 1 0重量％添加することが好ましい。 Another preferable optional component is glycerin, which is added in an amount of 0.5% by weight or more, particularly preferably 1 to 10% by weight, in the composition of the present invention.
毛髪処理剤の語は、 ここでは、 シャンプー、 パーマネン ト処理又は染毛後用い るものをいい、 この定義については、 K. Schrader, "Grundlagen und Rezepturen der Kosmetika", 2nd Ed. (1989), Huthing Buchverlag Heidelberg, pp. 722- 724.に記載されている。 The term hair treatment is used here for shampoo, permanent treatment or after hair dyeing This definition is described in K. Schrader, "Grundlagen und Rezepturen der Kosmetika", 2nd Ed. (1989), Huthing Buchverlag Heidelberg, pp. 722-724.
本発明組成物は水系又は水一アルコール系であり、 乳化系又は分散系であるか、 エアロゾル特にエア口ゾルフォ一厶としてもよい。 The composition of the present invention may be water-based or water-alcohol-based, may be emulsified or dispersed, or may be an aerosol, particularly an aerosol sol form.
本発明の組成物には、 少なく とも一種のカチオン性界面活性剤を添加すること が望ましい。 カチオン性界面活性剤の添加量は、 全組成物中 0. 1〜7. 5重量 %、 特に 0. 2 5〜 5重量％とすることが好ましい。 It is desirable to add at least one cationic surfactant to the composition of the present invention. The amount of the cationic surfactant to be added is preferably 0.1 to 7.5% by weight, particularly preferably 0.25 to 5% by weight in the whole composition.
カチオン性界面活性剤としては、 長鎖第 4級アンモニゥム塩の一種又は二種以 上の混合物が好ましいものとして挙げられ、 特に、 セチルトリ メチルアンモニゥ 厶クロリ ド、 ジメチルジセチルアンモニゥ厶クロリ ド、 トリ メチルセチルアンモ 二ゥムブ口ミ ド、 ステアリルトリメチルアン乇ニゥムクロリ ド、 ジメチルステア リルべンジルアンモニゥムクロリ ド、 ベンジルテトラデシルジメチルアンモニゥ 厶クロリ ド、 ジメチルジ水素添加牛脂ァンモニゥ厶クロリ ド、 ラウリルピリジニ ゥ厶クロリ ド、 ラウリルジメチルベンジルアンモニゥ厶クロリ ド、 ラウリノレトリ メチルアンモニゥムクロリ ド、 トリス （オリゴォキシェチル） アルキルアンモニ ゥ厶フォスフェート、 セチルピリジニゥムクロリ ド等が好ましいものとして例示 される。 このうちジメチルジセチルアンモニゥ厶クロリ ドとステアリルトリ メチ ルアンモニゥ厶クロリ ドの 1 ： 5から 5 ： 1の重量比の混合物が特に好ましい。 また欧州特許第 4 7 2, 1 0 7号に開示された長鎖第 4級アンモニゥ厶塩も用い ることができる。 また、 原則として、 「CTFA Cosmetic Ingredient Dictionary. 4th. Ed. (1991)」 に 「Quaternium」 の名で掲載されている第 4級アンモニゥ厶塩 も用いることができる。 Preferred examples of the cationic surfactant include one or a mixture of two or more long-chain quaternary ammonium salts, and in particular, cetyltrimethylammonium chloride, dimethyldicetylammonium chloride, Trimethylcetylammonium amide, stearyltrimethylammonium chloride, dimethylstearylbenzylbenzylammonium chloride, benzyltetradecyldimethylammonium chloride, dimethyldihydrogenated tallow ammonium chloride, laurylpyri Preferred are divinyl chloride, lauryldimethylbenzylammonium chloride, laurinoretrimethylammonium chloride, tris (oligoxitytyl) alkyl ammonium phosphate, cetylpyridinium chloride and the like. It is exemplified. Of these, a mixture of dimethyl dicetyl ammonium chloride and stearyl trimethyl ammonium chloride in a weight ratio of 1: 5 to 5: 1 is particularly preferred. Also, long-chain quaternary ammonium salts disclosed in European Patent No. 472,107 can be used. Also, in principle, a quaternary ammonium salt listed under the name “Quaternium” in the “CTFA Cosmetic Ingredient Dictionary. 4th. Ed. (1991)” can be used.
更に、 本発明組成物には、 通常のヘアーコンディショニング組成物に用いられ る公知の成分を配合することができる。 これには K. Schrader, "Grundlagen und Rezepturen der Kosmetika", 2nd Ed. (1989)， Huthing Buchverlag Heidelberg. PP. 722- 771.記載のものが挙げられる。 Further, the composition of the present invention can be blended with known components used in ordinary hair conditioning compositions. These include those described in K. Schrader, "Grundlagen und Rezepturen der Kosmetika", 2nd Ed. (1989), Huthing Buchverlag Heidelberg. PP. 722-771.
本発明の組成物には、 非イオン性界面活性剤も用いることができるが、 非ィォ ン性界面活性剤はカチオン性界面活性剤と共に用いることが好ましい。 例えば、 非ィォン性界面活性剤であるアミ ンォキシドは全組成物中 0. 2 5〜 5重量％、 好ましくは 0. 5〜3. 5重量％用いることが好ましい。 Although a nonionic surfactant can be used in the composition of the present invention, it is preferable to use a nonionic surfactant together with a cationic surfactant. For example, it is preferred that the nonionic surfactant, aminoxide, be used in an amount of 0.25 to 5% by weight, preferably 0.5 to 3.5% by weight in the total composition.
アミ ンォキシドとしては、 すでに公知のものが挙げられる。 例えば、 ラウリル ジメチルァミ ンォキシド等の C 12— C 18アルキルジメチルァミ ンォキシド、 C12 一 C 18アルキルァミノプロピル又はェチルァミ ンォキシド、 C ] 2— C 18アルキル ジ （ヒ ドロキシェチル） 又は （ヒ ドロキジプロピル） アミ ンォキシド、 アルキル 鎖中ェチレンォキシド又は Z及びプロピレンォキシドを持つァミ ンォキンド等が 挙げられる。 これらアミ ンォキシドは市販のものを入手することができる。 これ には例えば、 "Ammonyx", "Aromox"又は" Genaminox"という登録商標のものが例示 される。 Aminoxides include those already known. For example, C 12 -C 18 alkyl dimethyl aminoxides such as lauryl dimethyl aminoxide, C 12 -C 18 alkyl aminaminopropyl or ethyl aminoxide, C ] 2 -C 18 alkyl di (hydroxicetyl) or (hydroxydipropyl) Examples include aminoxide, ethylenoxide in the alkyl chain, or aminoquinide having Z and propylene oxide. These aminoxides can be obtained commercially. This includes, for example, those with the registered trademarks "Ammonyx", "Aromox" or "Genaminox".
また、 縮合度が 1. 2〜2. 5の C8— C18アルキルグルコシドも好ましい非 イオン性界面活性剤として挙げられる。 In addition, C 8 -C 18 alkyl glucosides having a degree of condensation of 1.2 to 2.5 are also preferable nonionic surfactants.
本発明の組成物には、 更に、 両性又は双イオン界面活性剤を含有せしめてもよ いが、 カチオン性界面活性剤と共に用いることが好ましい。 両性又は双イオン界 面活性剤の含有量は、 全組成物中 0. 1〜5重量％、 好ましくは 0. 5〜3重量 とすることが好ましい。 両性又は双イオン界面活性剤としては、 脂肪酸アミ ド アルキルべタイン類、 スルホベタイン等の公知のベタインが挙げられ、 具体的に は、 ラウリルヒ ドロキシスルホべタイン等が挙げられる。 The composition of the present invention may further contain an amphoteric or zwitterionic surfactant, but is preferably used together with a cationic surfactant. The content of the amphoteric or zwitterionic surfactant is preferably from 0.1 to 5% by weight, preferably from 0.5 to 3% by weight in the whole composition. Examples of the amphoteric or zwitterionic surfactant include known betaines such as fatty acid amide alkyl betaines and sulfobetaine, and specific examples include lauryl hydroxysulfobetaine.
本発明の組成物には、 錯化剤、 染料、 防腐剤、 ΡΗ調整剤、 無機塩等の増粘剤、 香料、 パール化剤、 糊料、 湿潤剤、 ホホバ油等の植物及び動物油、 その他の公知 の任意成分を添加することもできる。 The composition of the present invention includes complexing agents, dyes, preservatives, ΡΗ regulators, thickeners such as inorganic salts, fragrances, pearling agents, sizing agents, wetting agents, plant and animal oils such as jojoba oil, etc. Can be added.
特に、 好ましい添加剤としては、 ヘアーコンディショニング剤、 特に、 カチォ ン性ポリマーであり、 この添加量は、 全組成物中 0. 0 5〜2. 5重量％、 特に 0. 2〜 1. 5重量％とすることが好ましい。 Particularly preferred additives are hair conditioning agents, especially cationic polymers, which are added in an amount of 0.05 to 2.5% by weight, especially 0.2 to 1.5% by weight in the total composition. % Is preferable.
欧州特許第 3 3 7， 3 5 4号には、 カチオン性ポリマーと共にアルキルポリグ リコシド界面活性剤を用いることが開示されているが、 この 3〜 7ページに記載 されているカチオン性ポリマーも、 本発明でコンディショニング剤として好適に 使用することができる。 また、 「CTFA Cosmetic Ingredient Dictionary, 4th. Ed. (1990」 に 「Polyquaternium」 の名で掲載されているものも同様に用いるこ とができる。 EP 337,354 discloses the use of alkylpolyglycoside surfactants in conjunction with cationic polymers, but the cationic polymers described on pages 3 to 7 also apply to the invention. And can be suitably used as a conditioning agent. Also, the ones listed under the name “Polyquaternium” in the “CTFA Cosmetic Ingredient Dictionary, 4th. Ed. Can be.
本発明の組 J¾物には、 更にコンディ ショニング剤として、 蛋白質加水分解物を 添加してもよく、 添加量は、 全組成物中 0 . 2 5〜 5重量％、 特に 0 . 5〜 2 . 5重量％とすることが好ましい。 また、 水溶性コラーゲン又はコラーゲン誘 The composition J of the present invention may further contain a protein hydrolyzate as a conditioning agent, in an amount of 0.25 to 5% by weight, preferably 0.5 to 2.5% by weight of the total composition. Preferably it is 5% by weight. In addition, water-soluble collagen or collagen
,導体も用いることができる。 , Conductors can also be used.
更に、 本発明の組成物には、 種々のポリシロキサンをコンディショニング'剤と して、 用いてもよく、 添加量は、 全組成物中 0 . 2 5〜5重量％、 特に 0 . 5〜 2 . 5重量％が好ましい。 ポリ シロキサンは揮発性でも不揮発性でも、 環状でも 鎖状であってもよい。 ポリシロキサンの例としては、 「ジメチコ一ン」 、 「フエ 二ルジメチコ一ン」 及び 「シクロメチコーン」 の名で知られているものが挙げら れる。 Further, in the composition of the present invention, various polysiloxanes may be used as a conditioning agent, and the added amount is 0.25 to 5% by weight, particularly 0.5 to 2% by weight of the whole composition. 5% by weight is preferred. The polysiloxane may be volatile or non-volatile, cyclic or linear. Examples of polysiloxanes include those known under the names "dimethicone", "phenyldimethicone" and "cyclomethicone".
欧州特許第 3 9 8 , 1 7 7号にアルキルポリグリコシドと共に記載されている シリコーン誘導体もまた本発明に用いることができる。 The silicone derivatives described in EP 398,177 with alkylpolyglycosides can also be used in the present invention.
本発明の組成物を調製するには、 常法により、 水又は水一アルコール中で種々 の成分を混合すればよく、 また、 プレミ ックスとして用いることもできる。 実施例 In order to prepare the composition of the present invention, various components may be mixed in water or water-alcohol by a conventional method, and it may be used as a premix. Example
次に実施例を挙げて本発明を更に詳細に説明するが本発明はこれらに限定され るものではない。 Next, the present invention will be described in more detail with reference to examples, but the present invention is not limited thereto.
下記、 実施例 1〜 5に示す組成で、 毛髪処理剤組成物を調製した。 Hair treatment compositions were prepared with the compositions shown in Examples 1 to 5 below.
実施例 1 Example 1
ヘアーケア口一ショ ン Hair care mouth
(重量 セチルステアリルアルコール 5 0 0 (Weight cetyl stearyl alcohol 500
ジセチルジメチルアンモニゥムクロライ ド 1 6 0 Dicetyl dimethyl ammonium chloride 1 60
ごぼう根油抽出物 1 0 0 Burdock root oil extract 1 0 0
ヒ ドロキシプロピルグァーヒ ドロキシプロピル Hydroxypropyl guar hydroxypropyl
ト リ メチルアンモニゥムクロライ ド 0 4 0 Trimethylammonium chloride 0 4 0
イソプロピルアルコール 1 5 0 ィソプロピルミ リステ一ト 1 2 0 パンテノール 0 5 0 香料 0 4 0 乳酸 0 5 5 クェン酸 0 0 5 ピロリ ドンカルボン酸 0 0 2 酒石酸 0 0 2 リ ンゴ酸 0 0 1 防腐剤 Isopropyl alcohol 150 Isopropyl myristate 1 2 0 Panthenol 0 5 0 Flavor 0 4 0 Lactic acid 0 5 5 Cunic acid 0 0 5 Pyrrolidone carboxylic acid 0 0 2 Tartaric acid 0 0 2 Lingic acid 0 0 1 Preservative
水 バランス
実施例 2 Example 2
ヘアーケア トニック Hair care tonic
(重量 ごぼう根油抽出物 0 . 5 0 フィ タン ト リオール 0 . 1 0 パンテノール 0 . 2 0 o ベヘン ト リ メチルアンモニゥ厶ク口ライ ド 0 . 1 0 ヒ ドロキシプロピルグァ一ヒ ドロキシプロピル (Weight burdock root oil extract 0.50 phytantriol 0.10 panthenol 0.20 o behentrimethylammonium mouth mouth 0.10 hydroxypropyl guar hydroxy Propyl
ト リ メチルアンモニゥ厶ク口ライ ド 0 . 0 3 イソステアリルグリセリルペン夕エリ ト リノレ Trimethylammonium mouth mouth 0.0 3 Isostearyl glyceryl pen
エーテル 0 . 1 0 第 4級ポリ シロキサン 0 . 1 5 乳酸 0 . 2 5 ピロリ ドンカルボン酸 0 . 0 5 クェン酸 0 . 1 5 リ ンゴ酸 0 . 0 5 Ether 0.10 Quaternary polysiloxane 0.15 Lactic acid 0.25 Pyrrolidonecarboxylic acid 0.05 Cunic acid 0.15 Lingoic acid 0.05
0 . 0 5 香料 0 . 4 0 エタノール 3 5. 0 0 0 .05 Fragrance 0.40 Ethanol 35.0 0
水 バランス Water balance
計 1 0 0. 0 0 Total 1 0 0. 0 0
実施例 3 Example 3
コンディショナー （傷みがひどく、 多孔質になった乾燥性の髪用） Conditioner (for severely damaged, porous, dry hair)
(重量％) セチルステアリルアルコール 5. 5 0 (Wt%) cetylstearyl alcohol 5.50
ジセチルジメチルアンモニゥ厶クロライ ド 0. 5 0 Dicetyl dimethyl ammonium chloride 0.50
ステアリノレトリメチルアンモニゥ厶クロライ ド 0. 4 0 Stearinoretrimethylammonium chloride 0.40
イソステアリルグリセリルぺン夕エリ トリル Isostearyl glyceryl ester
エーテル 0 2 0 Ether 0 2 0
小麦ぬか油 0 1 0 Wheat bran oil 0 1 0
小麦タンパク加水分解物 0 5 0 Wheat protein hydrolyzate 0 5 0
ィソプロピルミ リステート 0 5 0 Isopropyl myristate 0 5 0
パンテノール 0 2 0 Panthenol 0 2 0
乳酸 0 1 5 Lactic acid 0 1 5
クェン酸 0 1 5 Cuenoic acid 0 1 5
ピロリ ドンカルボン酸 0 0 5 Pyrrolidone carboxylic acid 0 0 5
リ ンゴ酸 0 0 5 Lingoic acid 0 0 5
グリコール酸 0 0 2 Glycolic acid 0 0 2
ピルビン酸 0 0 2 Pyruvic acid 0 0 2
酒石酸 0 0 6 Tartaric acid 0 0 6
香料 0 3 5 Perfume 0 3 5
防腐剤 Preservative
水 バランス Water balance
計 1 0 0. 0 0 Total 1 0 0. 0 0
実施例 1〜 3の組成物により、 シャンプー後の毛髪を処理し、 ハーフサイ ドテ ストを行ったところ、 本発明品はヒ ドロキシカルボン酸の混合物を含まない組成 物に比べ、 櫛通り性が、 ウエッ トでも ドライでも向上し、 柔軟で輝いた髪にする ことができた。 The hair after shampooing was treated with the compositions of Examples 1 to 3 and subjected to a half-side test.As a result, the product of the present invention had better combability than the composition not containing the mixture of hydroxycarboxylic acids. Improves both wet and dry, making your hair soft and shiny I was able to.
実施例 4 Example 4
ドライヘア一用コンディ ショナー Conditioner for dry hair
(重量％) セチルステアリルアルコール 5 0 0 (% By weight) Cetyl stearyl alcohol 500
ジセチルジメチルアンモニゥ厶クロライ ド 1 0 0 Dicetyl dimethyl ammonium chloride 1 0 0
ィソプロピルミ リステ一 ト 0 4 0 Isopropyl myristate 0 4 0
ィソプロピルアルコール 0 5 0 Isopropyl alcohol 0 5 0
イソステアリルグリセリルペン夕エリ ト リル Isostearyl glyceryl pen
エーテル 0 2 0 Ether 0 2 0
アロエベラ葉抽出物 0 5 0 Aloe vera leaf extract 0 5 0
レシチン 0 5 0 Lecithin 0 5 0
パンテノール 0 2 0 Panthenol 0 2 0
乳酸 0 1 5 Lactic acid 0 1 5
クェン酸 0 1 5 Cuenoic acid 0 1 5
ピロリ ドンカルボン酸 0 . 1 0 Pyrrolidone carboxylic acid 0.10
リ ンゴ酸 0 . 0 3 Lingoic acid 0.03
ピルビン酸 0 0 2 Pyruvic acid 0 0 2
酒石酸 0 0 5 Tartaric acid 0 0 5
グリコ一ル酸 0 0 5 Glycolic acid 0 0 5
香料 0 4 5 Perfume 0 4 5
防腐剤 Preservative
水 バランス Water balance
計 1 0 0 . 0 0 1 0 0 .0 0
実施例 1〜3の組成物のコ ショニング効果に加え、 実施例 4の組成物は 髪の輝きを更に回復させた。 In addition to the conditioning effect of the compositions of Examples 1-3, the composition of Example 4 further restored the shine of the hair.
実施例 5 Example 5
パーマネン トウエーブヘアー用コンディ ショナ一 Conditioner for permanen tow hair
(重量％) セチルステアリルアルコール 5 . 0 0 (weight%) Cetylstearyl alcohol 5.0 0
ジセチルジメチルアンモニゥ厶クロライ ド 1 . 2 0 Dicetyl dimethyl ammonium chloride 1.2 0
アーモン ド油 0 . 5 0 Armando oil 0.50
レシチン 0 . 5 0 Lecithin 0.5 0
ァ一モンド夕ンパク加水分解物 0 . 5 0 Almonds hydrolyzate 0.5 0.5
パンテノール 0 . 2 0 Panthenol 0.2 0
グリセロール 0 . 5 0 Glycerol 0.5 0
乳酸 0 . 2 0 Lactic acid 0.20
ピ口 リ ドンカルボン酸 0 . 0 3 Lipidone carboxylic acid 0.03
クェン酸 0 . 0 3 Cuenoic acid 0.0 3
リ ンゴ酸 0 . 0 2 Lingoic acid 0.02
0 . 0 1 0. 0 1
酒石酸 5 0 . 0 1 Tartaric acid 5 0 .01
香料 0 . 4 0 Perfume 0.40
防腐剤 o Preservatives o
o o
水 バランス Water balance
o o
o 産業上の利用可能性 o Industrial availability
本発明の毛髪処理剤組成物は、 毛髪に光沢を付与し、 更に櫛通り性、 柔軟性を 付与する。 The hair treatment composition of the present invention imparts gloss to hair, and further imparts combability and flexibility.
Claims
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB9803642A GB2321595B (en) | 1995-09-08 | 1996-09-09 | Hair conditioning composition |
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE1995133211 DE19533211B4 (en) | 1995-09-08 | 1995-09-08 | Hair aftertreatment preparations |
| DE19533211.3 | 1995-09-08 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| WO1997009029A1 true WO1997009029A1 (en) | 1997-03-13 |
Family
ID=7771605
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| PCT/JP1996/002559 Ceased WO1997009029A1 (en) | 1995-09-08 | 1996-09-09 | Hair treatment composition |
Country Status (6)
| Country | Link |
|---|---|
| JP (1) | JPH09110650A (en) |
| CN (1) | CN1199332A (en) |
| DE (1) | DE19533211B4 (en) |
| GB (1) | GB2321595B (en) |
| TW (1) | TW427910B (en) |
| WO (1) | WO1997009029A1 (en) |
Families Citing this family (25)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9704050D0 (en) * | 1997-02-27 | 1997-04-16 | Unilever Plc | Hair treatment composition |
| DE19720366A1 (en) * | 1997-05-15 | 1998-11-19 | Wella Ag | Hair cleanser with gloss-enhancing properties |
| EP0978272A1 (en) * | 1998-08-07 | 2000-02-09 | Kao Corporation | Medulla care preparation |
| JP3208381B2 (en) | 1998-12-28 | 2001-09-10 | 花王株式会社 | Hair cosmetics |
| DE10009439A1 (en) * | 2000-02-29 | 2001-08-30 | Schwarzkopf Gmbh Hans | Use of cationic protein hydrolyzates as agents for improving the wash-fastness of dyed fibers, especially human hair |
| DE10009438A1 (en) * | 2000-02-29 | 2001-08-30 | Schwarzkopf Gmbh Hans | Use of combination of pyrrolidinone carboxylic acid derivative and cationic or amphoteric polymer to improve wash-fastness of dyed fibers, especially human hair |
| ATE336226T1 (en) * | 2002-07-05 | 2006-09-15 | Unilever Nv | HAIR TREATMENT COMPOSITIONS CONTAINING XANTHINE AND ALPHA-HYDROXY ACID |
| DE60332386D1 (en) * | 2002-11-26 | 2010-06-10 | Kao Corp | COSMETIC HAIR PREPARATION |
| JP4926371B2 (en) * | 2002-11-26 | 2012-05-09 | 花王株式会社 | Hair cosmetics |
| CN100444821C (en) * | 2003-08-01 | 2008-12-24 | 花王株式会社 | hair cosmetics |
| WO2005011623A1 (en) * | 2003-08-01 | 2005-02-10 | Kao Corporation | Hair grooming preparation |
| JP2006193461A (en) * | 2005-01-13 | 2006-07-27 | Pola Chem Ind Inc | Hair detergent |
| JP5168996B2 (en) | 2007-04-13 | 2013-03-27 | 味の素株式会社 | Preserved aqueous solution with high amino acid content |
| JP5496456B2 (en) * | 2007-12-28 | 2014-05-21 | 花王株式会社 | Hair cosmetics |
| ATE524160T1 (en) * | 2008-02-14 | 2011-09-15 | Kpss Kao Gmbh | HAIR CARE PRODUCTS CONTAINING PCA AND PCA ESTERS |
| JP2010065022A (en) * | 2008-08-12 | 2010-03-25 | Kao Corp | Hair treatment composition |
| WO2011124560A2 (en) * | 2010-04-09 | 2011-10-13 | Dsm Ip Assets B.V. | Hair care compositions |
| US20230190633A1 (en) * | 2016-05-23 | 2023-06-22 | Symrise Ag | A wheat bran extract in a hair care blend |
| CN108403554B (en) * | 2018-04-27 | 2021-03-05 | 北京杼宸医学研究院 | Hair nourishing shampoo and preparation method thereof |
| MX2021010606A (en) | 2019-03-08 | 2021-09-28 | Colgate Palmolive Co | Personal care compositions. |
| US11331253B2 (en) | 2019-11-14 | 2022-05-17 | Colgate-Palmolive Company | Personal care compositions for treating odor causing bacteria and methods for the same |
| US20210275419A1 (en) * | 2020-03-09 | 2021-09-09 | Colgate-Palmolive Company | Personal Care Compositions |
| CA3229423A1 (en) | 2021-09-01 | 2023-03-09 | Min Li | Personal care compositions containing post-biotic blends for rebalancing skin microbiome |
| US12251584B2 (en) | 2021-09-03 | 2025-03-18 | Colgate-Palmolive Company | Personal care compositions |
| CN114712267A (en) * | 2022-04-06 | 2022-07-08 | 王洪伟 | Hair waving buffering agent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07112921A (en) * | 1993-10-13 | 1995-05-02 | Sunstar Inc | Hair cosmetic |
| JPH08239312A (en) * | 1995-02-15 | 1996-09-17 | Kao Corp | Hair shampoo composition |
-
1995
- 1995-09-08 DE DE1995133211 patent/DE19533211B4/en not_active Expired - Fee Related
-
1996
- 1996-09-05 JP JP23502596A patent/JPH09110650A/en active Pending
- 1996-09-09 TW TW85111071A patent/TW427910B/en not_active IP Right Cessation
- 1996-09-09 CN CN 96196810 patent/CN1199332A/en active Pending
- 1996-09-09 GB GB9803642A patent/GB2321595B/en not_active Expired - Fee Related
- 1996-09-09 WO PCT/JP1996/002559 patent/WO1997009029A1/en not_active Ceased
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH07112921A (en) * | 1993-10-13 | 1995-05-02 | Sunstar Inc | Hair cosmetic |
| JPH08239312A (en) * | 1995-02-15 | 1996-09-17 | Kao Corp | Hair shampoo composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1199332A (en) | 1998-11-18 |
| GB2321595A (en) | 1998-08-05 |
| GB9803642D0 (en) | 1998-04-15 |
| JPH09110650A (en) | 1997-04-28 |
| TW427910B (en) | 2001-04-01 |
| DE19533211A1 (en) | 1996-02-08 |
| DE19533211B4 (en) | 2005-12-01 |
| GB2321595B (en) | 2000-01-26 |
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