[go: up one dir, main page]

WO1996036650B1 - Metallation et fonctionnalisation de polymeres et de copolymeres - Google Patents

Metallation et fonctionnalisation de polymeres et de copolymeres

Info

Publication number
WO1996036650B1
WO1996036650B1 PCT/US1996/007278 US9607278W WO9636650B1 WO 1996036650 B1 WO1996036650 B1 WO 1996036650B1 US 9607278 W US9607278 W US 9607278W WO 9636650 B1 WO9636650 B1 WO 9636650B1
Authority
WO
WIPO (PCT)
Prior art keywords
halides
metalation
alkyl
copolymer
chlorides
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Ceased
Application number
PCT/US1996/007278
Other languages
English (en)
Other versions
WO1996036650A3 (fr
WO1996036650A2 (fr
Filing date
Publication date
Priority claimed from US08/476,753 external-priority patent/US5670581A/en
Application filed filed Critical
Priority to BR9609135A priority Critical patent/BR9609135A/pt
Priority to JP8535131A priority patent/JPH11505287A/ja
Priority to EP96916512A priority patent/EP0832138A2/fr
Publication of WO1996036650A2 publication Critical patent/WO1996036650A2/fr
Publication of WO1996036650A3 publication Critical patent/WO1996036650A3/fr
Publication of WO1996036650B1 publication Critical patent/WO1996036650B1/fr
Anticipated expiration legal-status Critical
Ceased legal-status Critical Current

Links

Abstract

Cette invention concerne un procédé d'introduction de fonctionnalité dans un copolymère d'une isooléfine et d'un alkylstyrène au niveau de l'atome de carbone d'alkylbenzyle. Ce procédé comprend les étapes suivantes: former une solution dudit copolymère dans un solvant à base d'hydrocarbure; ajouter à ladite solution de polymère un alcoxyde de métal alcalin Cs, K, Na et un composé d'alkyle-lithium afin de former une superbase avec la solution de polymère; enfin, ajouter un électrophile à ladite solution de polymère de base. Cette invention concerne également les copolymères métallatés et leur dérivé fonctionnalisé.
PCT/US1996/007278 1995-05-19 1996-05-20 Metallation et fonctionnalisation de polymeres et de copolymeres Ceased WO1996036650A2 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
BR9609135A BR9609135A (pt) 1995-05-19 1996-05-20 Metalização e funcionalização de polímeros e copolímeros
JP8535131A JPH11505287A (ja) 1995-05-19 1996-05-20 ポリマー及びコポリマーのメタル化及び官能化
EP96916512A EP0832138A2 (fr) 1995-05-19 1996-05-20 Metallation et fonctionnalisation de polymeres et de copolymeres

Applications Claiming Priority (6)

Application Number Priority Date Filing Date Title
US44495095A 1995-05-19 1995-05-19
US08/444,950 1995-05-19
US44713195A 1995-05-22 1995-05-22
US08/447,131 1995-05-22
US08/476,753 US5670581A (en) 1995-05-19 1995-06-07 Metalation and functionalization of polymers and copolymers
US08/476,753 1995-06-07

Publications (3)

Publication Number Publication Date
WO1996036650A2 WO1996036650A2 (fr) 1996-11-21
WO1996036650A3 WO1996036650A3 (fr) 1996-12-19
WO1996036650B1 true WO1996036650B1 (fr) 1997-02-13

Family

ID=27412231

Family Applications (1)

Application Number Title Priority Date Filing Date
PCT/US1996/007278 Ceased WO1996036650A2 (fr) 1995-05-19 1996-05-20 Metallation et fonctionnalisation de polymeres et de copolymeres

Country Status (11)

Country Link
US (2) US5840810A (fr)
EP (1) EP0832138A2 (fr)
JP (1) JPH11505287A (fr)
KR (1) KR19990014901A (fr)
CN (1) CN1304941A (fr)
BR (1) BR9609135A (fr)
CA (1) CA2219464A1 (fr)
CZ (1) CZ363797A3 (fr)
MX (1) MX9708904A (fr)
PL (1) PL323380A1 (fr)
WO (1) WO1996036650A2 (fr)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AT410546B (de) * 1996-12-23 2003-05-26 Exxon Chemical Patents Inc Verfahren zum einführen von ethylenisch ungesättigter funktionalität in ein alkylstyrol enthaltendes polymer
US6011120A (en) * 1996-12-23 2000-01-04 Exxon Chemical Patents, Inc. Alkenyl silane functionalization of alkylstyrene homopolyers and copolymers
JP4410868B2 (ja) * 1998-03-04 2010-02-03 株式会社ブリヂストン ゴム組成物及びそれを用いた空気入りタイヤ
RU2233847C2 (ru) 1999-03-02 2004-08-10 Эксонмобил Кемикэл Пейтентс Инк. Сополимеры альфа-олефина и винилового ароматического мономера с привитым силаном
US6451935B1 (en) * 2000-05-10 2002-09-17 Bridgestone Corporation Highly functionalized polymers and a process for making the same
AU2003243337A1 (en) * 2002-07-05 2004-01-23 Exxonmobil Chemical Patents Inc. Functionalized elastomer nanocomposite
WO2004005388A1 (fr) * 2002-07-05 2004-01-15 Exxonmobil Chemical Patents Inc. Nanocomposite elastomere fonctionnalise
JPWO2006013637A1 (ja) * 2004-08-04 2008-05-01 株式会社日立製作所 電子タグ、リーダ、及びその製造方法
TW200630449A (en) * 2004-12-21 2006-09-01 Dow Global Technologies Inc Polypropylene-based adhesive compositions
ZA200707865B (en) 2005-03-17 2008-12-31 Dow Global Technologies Inc Polymer blends from interpolymer of ethyene/alpha-olefin with improved compatibility
JP5385129B2 (ja) 2006-06-15 2014-01-08 ダウ グローバル テクノロジーズ エルエルシー 官能化されたオレフィンインターポリマー、組成物及びそれから作製された製品、ならびにそれを作製するための方法
KR101455425B1 (ko) * 2006-12-21 2014-10-27 다우 글로벌 테크놀로지스 엘엘씨 폴리올레핀 조성물 및 그로부터 제조된 물품 및 그의 제조 방법
WO2010008371A1 (fr) * 2008-06-30 2010-01-21 Dow Global Technologies Inc. Compositions de polyoléfine, articles préparés à partir de celles-ci et leurs procédés de fabrication
SG10201509914VA (en) 2011-12-14 2016-01-28 Dow Global Technologies Llc Functionalized block composite and crystalline block composite compositions
JP6527862B2 (ja) 2013-07-01 2019-06-05 ローム アンド ハース カンパニーＲｏｈｍ Ａｎｄ Ｈａａｓ Ｃｏｍｐａｎｙ 複合ポリマー組成物
EP3894451A4 (fr) 2018-12-13 2022-12-14 ExxonMobil Chemical Patents Inc. Polymérisation par greffage anionique sur une chaîne polymère existante par activation de base organométallique

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1566343A (fr) * 1968-02-05 1969-05-09
GB1254220A (en) * 1968-03-14 1971-11-17 Firestone Tire & Rubber Co Method of metalating unsaturated polymers
US3978161A (en) * 1973-10-01 1976-08-31 The General Tire & Rubber Company Metalation of polymers
US4145490A (en) * 1975-09-25 1979-03-20 E. I. Du Pont De Nemours And Company Carboxylated copolymers of isobutylene and a vinylbenzene
US4603148A (en) * 1983-05-12 1986-07-29 Hercules Incorporated Macroreticulate polymer scavengers for the removal of impurities from inert fluids
JPS61151203A (ja) * 1984-12-26 1986-07-09 Toa Nenryo Kogyo Kk スチレン系重合体への前駆物質の製造法
US5162445A (en) * 1988-05-27 1992-11-10 Exxon Chemical Patents Inc. Para-alkylstyrene/isoolefin copolymers and functionalized copolymers thereof
US5077346A (en) * 1989-10-03 1991-12-31 Exxon Chemical Patents Inc. Functionalization of polymeric organolithium compounds by carbonation
US5461118A (en) * 1993-04-06 1995-10-24 Exxon Chemical Patents Inc. Para-alkylstyrene/isoolefin copolymers functionalized with an amine alkylthioethers or hydroxy-alkylthioethers and their use in polymer blends
WO1995010544A1 (fr) * 1993-10-15 1995-04-20 University Of Massachusetts At Lowell Coiffe de polymeres vivants

Similar Documents

Publication Publication Date Title
WO1996036650B1 (fr) Metallation et fonctionnalisation de polymeres et de copolymeres
EP0509357A1 (fr) Copolymères séquences à base de polyisobutène
US3925511A (en) Metallation of polymers and subsequent reaction to form modified or grafted polymers
EP0501957B1 (fr) Copolymeres elastomeres de greffe et leur utilisation comme agents de compatibilite
CN1215412A (zh) 含有烷基苯乙烯的聚合物的氧化官能化方法
WO1996036650A3 (fr) Metallation et fonctionnalisation de polymeres et de copolymeres
EP0946608B1 (fr) Fonctionnalisation par alkenylsilane d'homopolymeres et copolymeres d'alkylstyrene
WO1996040802B1 (fr) Metallation et fonctionnalisation de polymeres et de copolymeres
US4145490A (en) Carboxylated copolymers of isobutylene and a vinylbenzene
US4664700A (en) Selective extraction of metal ions with polymeric extractants by ion exchange/redox
KR101297451B1 (ko) 할로부틸 엘라스토머의 개질 방법
US5821308A (en) Metalation and functionalization of polymers and copolymers
KR20000029663A (ko) 중합체상의벤질할로겐작용기를다른작용기로전환시키기위한고형친핵성시약
US4594395A (en) Process for metalating halogenated polyolefins
Quirk et al. Functionalization of polymeric organolithium compounds with formaldehyde
US4596859A (en) Process for metalating vinylidene halide based polymers
AT410546B (de) Verfahren zum einführen von ethylenisch ungesättigter funktionalität in ein alkylstyrol enthaltendes polymer
JPH0551612B2 (fr)
AT409963B (de) Verfahren zur herstellung eines vernetzten polymers und dessen verwendung zur herstellung eines photoresists
WO1993003071A1 (fr) Preparation de polymeres fonctionnalises a l'aide d'une forme reactive de calcium
RU97121313A (ru) Металлирование и функционализация полимеров и сополимеров
Cheradame et al. Reply to “criticism hypotheses by Gandini and Cheradame regarding the initiation of carbocationic polymerization”(Pol. Bull. 10, 141 1983)
SU757546A1 (ru) Способ получения микрогеля 1
JPH11286507A (ja) アニオン重合開始剤
Janata et al. Selective Grafting of Block Copolymers, 3a. Multigraft Copolymers